JPS555969A - Preparation of propylene-ethylene block copolymer - Google Patents
Preparation of propylene-ethylene block copolymerInfo
- Publication number
- JPS555969A JPS555969A JP7938378A JP7938378A JPS555969A JP S555969 A JPS555969 A JP S555969A JP 7938378 A JP7938378 A JP 7938378A JP 7938378 A JP7938378 A JP 7938378A JP S555969 A JPS555969 A JP S555969A
- Authority
- JP
- Japan
- Prior art keywords
- propylene
- organo
- aluminum compound
- ticl
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Graft Or Block Polymers (AREA)
Abstract
PURPOSE: To prepare the title copolymer having high impact strength, rigidity and heat resistance, by polymerizing propylene in the presence of titanium trichloride and an organo-aluminum compound, and then carrying out the random copolymerization of propylene and ethylene in the presence of the above polymer.
CONSTITUTION: Propylene (which may contain a small amount of ehylene) is polymerized in liquid state, in the absence of an inert solvent, and then randomly copolymerized with propylene and ethylene in liquid propylene or in gaseous phase. The polymerization is carried out in the presence of a catalyst system comprising (A) a solid TiCl3 catalyst obtained by reducing TiCl4 with an organo-aluminum compound, and activating the product, (B) an organo-aluminum compound of formula (R is 1W8C straight chain alkyl, etc.; Y is halogen, etc.; l is 2W3), and if necessary, (C) an agent for improving the stereoregularity. The weight ratio of the polymer to the TiCl3 catalyst is ≥8000/1.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (13)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7938378A JPS555969A (en) | 1978-06-29 | 1978-06-29 | Preparation of propylene-ethylene block copolymer |
CA328,077A CA1129141A (en) | 1978-05-22 | 1979-05-18 | Process for producing propylene-ethylene block copolymers |
YU1187/79A YU40368B (en) | 1978-05-22 | 1979-05-21 | Process for preparing block copolymerisates of propylene-ethylene |
IT49104/79A IT1116210B (en) | 1978-05-22 | 1979-05-21 | PROCEDURE FOR PRODUCING PROPYLENE-ETHYLENE BLOCK COPOLYMERS |
NL7903979A NL7903979A (en) | 1978-05-22 | 1979-05-21 | PROCEDURE FOR PREPARING PROPENE ETHENE BLOCK COPOLYMERS. |
GB7917658A GB2027722B (en) | 1978-05-22 | 1979-05-21 | Catalyst for producing ethyenepopylene block copolymers |
FR7912980A FR2435487B1 (en) | 1978-05-22 | 1979-05-22 | PROCESS FOR PRODUCING SEQUENCE COPOLYMERS OF PROPYLENE AND ETHYLENE |
BR7903182A BR7903182A (en) | 1978-05-22 | 1979-05-22 | PROCESSING IN PROCESS TO PRODUCE COPOLYMER IN PROPYLENE-ETHYLENE BLOCK |
US06/041,462 US4259461A (en) | 1978-05-22 | 1979-05-22 | Process for producing propylene-ethylene block copolymers |
DD79213060A DD143915A5 (en) | 1978-05-22 | 1979-05-22 | PROCESS FOR THE PREPARATION OF PROPYLENEETHYLENE BLOCK COPOLYMERISES |
DE19792920729 DE2920729A1 (en) | 1978-05-22 | 1979-05-22 | PROCESS FOR MANUFACTURING PROPYLENE-ETHYLENE BLOCK COPOLYMERISATES |
CS448779A CS212324B2 (en) | 1978-06-29 | 1979-06-28 | Method of making the block ethylene and propylene copolymeres |
SG128/83A SG12883G (en) | 1978-05-22 | 1983-03-21 | Process for producing propylene-ethylene block copolymers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7938378A JPS555969A (en) | 1978-06-29 | 1978-06-29 | Preparation of propylene-ethylene block copolymer |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS555969A true JPS555969A (en) | 1980-01-17 |
JPS6150086B2 JPS6150086B2 (en) | 1986-11-01 |
Family
ID=13688337
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7938378A Granted JPS555969A (en) | 1978-05-22 | 1978-06-29 | Preparation of propylene-ethylene block copolymer |
Country Status (2)
Country | Link |
---|---|
JP (1) | JPS555969A (en) |
CS (1) | CS212324B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57100113A (en) * | 1980-12-15 | 1982-06-22 | Mitsubishi Chem Ind Ltd | Preparation of propylene-ethylene block copolymer |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01175990U (en) * | 1988-05-27 | 1989-12-14 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5291092A (en) * | 1976-01-27 | 1977-08-01 | Mitsubishi Chem Ind Ltd | Preparation of propylene block copolymers |
JPS533356A (en) * | 1976-06-30 | 1978-01-13 | Mitsubishi Heavy Ind Ltd | Laser interference |
JPS5310116A (en) * | 1976-07-15 | 1978-01-30 | Stocznia Szczecinska | Weld joints for corrosive solution tanks |
JPS54133587A (en) * | 1978-04-10 | 1979-10-17 | Mitsubishi Chem Ind Ltd | Preparation of block copolymer |
-
1978
- 1978-06-29 JP JP7938378A patent/JPS555969A/en active Granted
-
1979
- 1979-06-28 CS CS448779A patent/CS212324B2/en unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5291092A (en) * | 1976-01-27 | 1977-08-01 | Mitsubishi Chem Ind Ltd | Preparation of propylene block copolymers |
JPS533356A (en) * | 1976-06-30 | 1978-01-13 | Mitsubishi Heavy Ind Ltd | Laser interference |
JPS5310116A (en) * | 1976-07-15 | 1978-01-30 | Stocznia Szczecinska | Weld joints for corrosive solution tanks |
JPS54133587A (en) * | 1978-04-10 | 1979-10-17 | Mitsubishi Chem Ind Ltd | Preparation of block copolymer |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57100113A (en) * | 1980-12-15 | 1982-06-22 | Mitsubishi Chem Ind Ltd | Preparation of propylene-ethylene block copolymer |
JPS6364448B2 (en) * | 1980-12-15 | 1988-12-12 |
Also Published As
Publication number | Publication date |
---|---|
JPS6150086B2 (en) | 1986-11-01 |
CS212324B2 (en) | 1982-03-26 |
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