JPH10193508A - Pre-coated steel plate - Google Patents
Pre-coated steel plateInfo
- Publication number
- JPH10193508A JPH10193508A JP9003225A JP322597A JPH10193508A JP H10193508 A JPH10193508 A JP H10193508A JP 9003225 A JP9003225 A JP 9003225A JP 322597 A JP322597 A JP 322597A JP H10193508 A JPH10193508 A JP H10193508A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- weight
- parts
- coating
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、耐プレッシャーマ
ーク性と加工性に優れたプレコート鋼板とその製造方法
に関する。本発明のプレコート鋼板は、家庭用電気機
器、屋内外器物等に使用するのに適している。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a precoated steel sheet having excellent pressure mark resistance and workability, and a method for producing the same. The precoated steel sheet of the present invention is suitable for use in household electric appliances, indoor and outdoor equipment, and the like.
【0002】[0002]
【従来の技術】鋼板に予め塗料を塗布し、塗膜を乾燥ま
たは焼付けることにより樹脂被覆を施したプレコート鋼
板は、作業および環境面で問題の多い塗布作業を行わず
にユーザーが直ちに成形加工でき、かつ表面が美麗な光
沢を持つことから、冷蔵庫、洗濯機、電子レンジ等の屋
内で使用される家電製品や、エアコン室外機、自動販売
機等の屋外で使用される電気製品等に多く用いられてい
る。このような用途に使用されるプレコート鋼板は、外
面に向けられる表側には、比較的厚膜の表面が平滑で美
麗な光沢を持つ塗膜が形成され、裏面には耐食性付与の
ための比較的薄膜の塗装 (従って、塗膜の表面平滑性は
劣る) が施されることが多い。2. Description of the Related Art A pre-coated steel sheet coated with a resin by applying a paint to the steel sheet in advance and drying or baking the coating film is formed immediately by a user without performing coating work which is problematic in terms of work and environment. Because it is made and has a beautiful glossy surface, it is often used in household electrical appliances used indoors such as refrigerators, washing machines and microwave ovens, and electrical appliances used outdoors such as air conditioner outdoor units and vending machines. Used. In the precoated steel sheet used for such applications, a relatively thick film having a smooth surface and a beautiful gloss is formed on the front side facing the outer surface, and a relatively thick film for imparting corrosion resistance is formed on the back surface. Often, a thin film is applied (therefore the surface smoothness of the coating is inferior).
【0003】プレコート鋼板は、通常は鋼帯 (コイル)
または切板で出荷されるが、製造から使用されるまでの
間に数日ないしは数カ月保管されるのが一般的である。
例えばコイルの場合、約1〜5トンのコイル重量で切断
し、保管することが多いが、使用時に巻戻してみると、
保管中のコイル下側の自重のかかった部分の表側塗膜に
は、プレッシャーマーク (裏面塗膜の凹凸が表面に転写
された転写模様) が発生する。切板の場合には1ロット
につき2トン前後を積み重ねることが多いが、この場合
も、ロットの下側に積まれていた切板の表側塗膜には、
同様なプレッシャーマークが発生することがある。以
下、プレッシャーマークが問題となる塗膜(通常は表側
塗膜) を単に塗膜という。[0003] Precoated steel sheets are usually steel strips (coils).
Or, they are shipped in cut sheets, but are generally stored for several days or months between production and use.
For example, in the case of a coil, it is often cut and stored with a coil weight of about 1 to 5 tons.
A pressure mark (transfer pattern in which the unevenness of the back surface coating is transferred to the front surface) is generated on the front side coating film under its own weight under the coil during storage. In the case of cut sheets, it is common to stack around 2 tons per lot, but also in this case, the front side coating film of the cut sheets stacked under the lot,
A similar pressure mark may occur. Hereinafter, a coating film (usually a front coating film) in which a pressure mark is a problem is simply referred to as a coating film.
【0004】このプレッシャーマークの発生したプレコ
ート鋼板は、性能上は特に問題がないが、商品価値が著
しく低下する。なぜなら、プレッシャーマークによりプ
レコート鋼板が本来有している塗膜の美麗な光沢が失わ
れ、プレッシャーマークが肉眼でも健全部とは明確に区
別されるため、上述した用途のように厳しい外観品質が
要求される用途には使用できなくなるからである。[0004] The precoated steel sheet having the pressure mark has no particular problem in performance, but its commercial value is significantly reduced. This is because the pressure mark loses the beautiful gloss of the coating film originally possessed by the pre-coated steel sheet, and the pressure mark is clearly distinguished from the healthy part even to the naked eye, so strict appearance quality is required as in the above-mentioned applications. This is because it cannot be used for the intended use.
【0005】プレッシャーマークの防止対策として、プ
レコート鋼板の塗膜表面に厚さ60μm程度の保護フィル
ムを施す方法があるが、コスト高になるうえ、ユーザー
における成形加工の後に保護フィルムを除去し、廃棄す
るという手間のかかる工程が加わるという難点がある。As a measure to prevent the pressure mark, there is a method of applying a protective film having a thickness of about 60 μm to the surface of the coating film of the pre-coated steel sheet. However, the cost is increased, and the protective film is removed after the forming process by the user and discarded. There is a drawback in that a time-consuming step of performing the process is added.
【0006】また、プレッシャーマーク発生の防止対策
ではないが、プレッシャーマークの発生後に、加温によ
り元の光沢を復元させる方法がある。しかし、この方法
においても、加温工程の追加によりコスト高を招くとい
う問題点があり、また光沢の復元も完全ではない。Although not a measure to prevent the occurrence of a pressure mark, there is a method of restoring the original gloss by heating after the generation of the pressure mark. However, this method also has a problem that the cost is increased due to the addition of the heating step, and the restoration of the gloss is not perfect.
【0007】塗膜の硬度を高めるとプレッシャーマーク
を根本的に防止することができるが、この手段は、プレ
コート鋼板に求められる別の重要な性能である加工性の
低下が避けられないため、到底採用することができな
い。[0007] Increasing the hardness of the coating film can fundamentally prevent pressure marks. However, this method is unavoidable because another important performance required for precoated steel sheets, that is, deterioration in workability, cannot be avoided. Can not be adopted.
【0008】特開平8−53646 号公報には、ガラス転移
点40〜65℃、数平均分子量15,000〜30,000のポリエステ
ル樹脂と、メラミン樹脂またはイソシアネート樹脂から
なる架橋剤と、平均粒子径2〜50μmの有機樹脂粉末
と、滑剤とからなる、耐プレッシャーマーク性が良好な
プレコート鋼板用の塗料組成物が開示されている。この
塗料組成物から形成したプレコート鋼板は、低温加工性
が十分ではないうえ、耐プレッシャーマーク性を確実に
改善することができない。JP-A-8-53646 discloses a polyester resin having a glass transition point of 40 to 65 ° C. and a number average molecular weight of 15,000 to 30,000, a cross-linking agent comprising a melamine resin or an isocyanate resin, and a resin having an average particle diameter of 2 to 50 μm. There is disclosed a coating composition for a precoated steel sheet having good pressure-mark resistance, comprising an organic resin powder and a lubricant. The pre-coated steel sheet formed from this coating composition does not have sufficient low-temperature workability and cannot reliably improve the resistance to pressure marks.
【0009】[0009]
【発明が解決しようとする課題】このように、加工性と
耐プレッシャーマーク性とを両立させることは困難であ
り、満足できるプレッシャーマーク発生の防止対策は未
だ確立していないのが実状である。As described above, it is difficult to achieve both workability and resistance to pressure marks, and in fact, satisfactory measures for preventing the occurrence of pressure marks have not yet been established.
【0010】本発明の目的は、従来のプレッシャーマー
ク対策が持つ上記のような問題点を解消し、コスト高お
よび手間の増大を招くことなく、プレッシャーマークが
発生しにくく、しかも高度の加工性を有するプレコート
鋼板とその製造方法を提供することである。SUMMARY OF THE INVENTION An object of the present invention is to solve the above-mentioned problems of the conventional pressure mark countermeasure, to reduce the occurrence of pressure marks without increasing the cost and labor, and to improve the processability. It is an object of the present invention to provide a precoated steel sheet having the same and a method for producing the same.
【0011】[0011]
【課題を解決するための手段】前述したように、プレッ
シャーマークによる塗膜の光沢低下は、裏面塗膜の凹凸
の転写に由来する表面粗さの増大である。これを防止す
るには、先に述べたように、バルク (塗膜全体) の押し
込み硬度を高めることが有効であるが、この手段では加
工性の低下が避けられない。As described above, the decrease in gloss of the coating film due to the pressure mark is an increase in surface roughness resulting from the transfer of the unevenness of the back coating film. In order to prevent this, as described above, it is effective to increase the indentation hardness of the bulk (the entire coating film), but this method inevitably reduces the workability.
【0012】そこで、本発明者らは、押し込み硬度と加
工性を高度にバランスさせる手段について検討し、共重
合ポリエステル樹脂をアルキルエーテル化アミノホルム
アルデヒド樹脂を架橋剤として硬化させた塗膜におい
て、架橋剤を表面濃化させることにより耐プレッシャー
マーク性に優れたプレコート鋼板が得られることを、先
に提案した (特願平7−312678号) 。しかし、この手段
でも、加工性の若干の低下があり、耐プレッシャーマー
ク性の改善も完全に満足できる程度ではない。The present inventors have studied means for highly balancing indentation hardness and processability, and have found that a coating film obtained by curing a copolymerized polyester resin with an alkyl etherified aminoformaldehyde resin as a crosslinking agent is used. It has been previously proposed that a precoated steel sheet having excellent pressure mark resistance can be obtained by concentrating the surface of the steel (Japanese Patent Application No. 7-312678). However, even with this method, there is a slight decrease in workability, and the improvement in pressure mark resistance is not completely satisfactory.
【0013】そこでさらに検討を重ねた結果、ガラス転
移点が低い共重合ポリエステル樹脂をベース樹脂として
使用し、これに前記架橋剤に加えて、酸触媒と硬質の有
機樹脂ビーズとを配合することにより、加工性と耐プレ
ッシャーマーク性をさらに改善することができ、上記目
的を達成することができることを見出した。Therefore, as a result of further study, a copolymerized polyester resin having a low glass transition point was used as a base resin, and in addition to the crosslinking agent, an acid catalyst and hard organic resin beads were blended. It has been found that the workability and the resistance to pressure marks can be further improved, and the above object can be achieved.
【0014】ここに、本発明は、鋼板上に設けた最上層
の樹脂皮膜が、ガラス転移点が40℃未満の共重合ポリ
エステル樹脂100 重量部、アルキルエーテル化アミノ
ホルムアルデヒド樹脂10〜45重量部、酸触媒1〜3重
量部、およびビッカース硬度が6以上で、粒径が該最
上層樹脂皮膜の膜厚の1〜2倍の有機樹脂ビーズ1〜5
重量部、を必須成分として含む塗料組成物から形成され
た焼付け皮膜であることを特徴とする、耐プレッシャー
マーク性と加工性に優れたプレコート鋼板である。本明
細書において、樹脂の量はいずれも固形分基準の重量で
ある。Here, the present invention is characterized in that the uppermost resin film provided on the steel plate is composed of 100 parts by weight of a copolymerized polyester resin having a glass transition point of less than 40 ° C., 10 to 45 parts by weight of an alkyl etherified aminoformaldehyde resin, 1 to 5 parts by weight of an acid catalyst, and organic resin beads 1 to 5 having a Vickers hardness of 6 or more and a particle size of 1 to 2 times the thickness of the uppermost resin film.
A pre-coated steel sheet having excellent pressure mark resistance and workability, characterized in that it is a baked film formed from a coating composition containing, as an essential component, parts by weight. In the present specification, all amounts of resin are weights based on solid content.
【0015】通常の焼付け硬化型ポリエステル樹脂塗膜
のビッカース硬度は4以下程度と低い。このような塗膜
に、ビッカース硬度が6以上という硬質の有機樹脂ビー
ズを含有させることは、いわば堅固な柱を増設すること
に相当し、塗膜全体の強度を上げることができる。従っ
て、この硬質の樹脂ビーズの配合は、塗膜の押し込み硬
度の補強につながり、そのため耐プレッシャーマーク性
が向上する。The Vickers hardness of an ordinary bake-curable polyester resin coating film is as low as about 4 or less. Inclusion of hard organic resin beads having a Vickers hardness of 6 or more in such a coating film is equivalent to adding solid columns, so that the strength of the entire coating film can be increased. Therefore, the incorporation of the hard resin beads leads to reinforcement of the indentation hardness of the coating film, thereby improving the pressure mark resistance.
【0016】加工性については、ガラス転移点が40℃未
満と低く、極めて加工性に優れたポリエステル樹脂をベ
ース樹脂として使用することで、改善が図られる。本発
明で用いる架橋剤は、焼付け中に塗膜の外面側に移行し
易く、塗膜の内面側に比べて外面側の架橋密度が増大す
る。その結果、内面側は架橋密度があまり上がらず、ポ
リエステル樹脂本来の良好な加工性が保持される。同時
に、架橋密度が高くなる外面側は押し込み硬度が高くな
るので、良好な加工性を堅持しつつ、有機樹脂ビーズ添
加によるプレッシャーマーク性改善をより万全なものに
することができる。この架橋剤の表面濃化は、焼付けに
用いる熱風オーブンの風量により、適度の範囲に制御す
ることができる。The workability can be improved by using a polyester resin having a low glass transition point of less than 40 ° C. and excellent workability as a base resin. The crosslinking agent used in the present invention easily migrates to the outer surface side of the coating film during baking, and the crosslinking density on the outer surface side increases as compared with the inner surface side of the coating film. As a result, the crosslink density on the inner surface side does not increase so much, and the original good workability of the polyester resin is maintained. At the same time, since the indentation hardness increases on the outer surface side where the crosslink density increases, it is possible to improve the pressure mark property by adding organic resin beads while maintaining good workability. The surface concentration of the cross-linking agent can be controlled in an appropriate range by adjusting the air volume of a hot air oven used for baking.
【0017】従って、別の側面からは、本発明は、上記
の塗料組成物を塗布した後、板面での風速が 0.5〜3.0
m/sec になるように制御された熱風オーブンにより塗膜
を焼付けて最上層の樹脂皮膜を形成することを特徴とす
る、耐プレッシャーマーク性と加工性に優れたプレコー
ト鋼板の製造方法である。Accordingly, from another aspect, the present invention provides a method for applying the above-mentioned coating composition, wherein the wind speed on the plate surface is 0.5 to 3.0.
A method for producing a precoated steel sheet having excellent pressure-mark resistance and workability, characterized in that a coating film is formed by baking a coating film in a hot-air oven controlled to m / sec to form an uppermost resin film.
【0018】[0018]
【発明の実施の形態】以下に、本発明について詳述す
る。 (1) 母材鋼板 本発明のプレコート鋼板の母材として使用される鋼板の
種類は特に限定されない。冷延鋼板、亜鉛系めっき鋼板
やアルミニウム系めっき鋼板等の表面処理鋼板などが好
適に使用される。ステンレス鋼板等も使用できる。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail. (1) Base Material Steel Sheet The type of steel sheet used as the base material of the precoated steel sheet of the present invention is not particularly limited. Surface-treated steel sheets such as cold-rolled steel sheets, galvanized steel sheets and aluminum-coated steel sheets are preferably used. Stainless steel plates can also be used.
【0019】(2) 下地処理 下地処理は必須ではないが、耐食性や塗膜密着性の向上
を目的とする下地処理を行うことが好ましい。下地処理
は、プレコート鋼板に従来より使用されているものと同
様でよいが、通常は塗布型クロメート処理、電解クロメ
ート処理、反応型クロメート処理から選ばれたクロメー
ト処理、および/またはリン酸塩処理が実施される。ク
ロメート処理では金属Cr換算付着量で片面15〜100 mg/m
2 が好ましく、リン酸塩 (リン酸亜鉛) 処理では片面の
付着量で 0.2〜1.5 g/m2であるのが好ましい。(2) Undercoat Treatment Although the undercoat treatment is not essential, it is preferable to perform the undercoat treatment for the purpose of improving corrosion resistance and coating film adhesion. The undercoating treatment may be the same as that conventionally used for the precoated steel sheet, but usually includes a chromate treatment selected from a coating type chromate treatment, an electrolytic chromate treatment, and a reaction type chromate treatment, and / or a phosphate treatment. Will be implemented. In chromate treatment, 15 to 100 mg / m on one side in metal Cr equivalent
2 is preferable, and in the case of phosphate (zinc phosphate) treatment, the amount of adhesion on one side is preferably 0.2 to 1.5 g / m 2 .
【0020】(3) 下塗り樹脂皮膜 (プライマー) 下塗り樹脂皮膜も必ずしも必須ではないが、密着性向上
や隠蔽性向上、または耐食性保護のために設けておくの
が好ましい。乾燥膜厚で1〜10μm程度が好ましい。(3) Undercoat Resin Film (Primer) The undercoat resin film is not always essential, but is preferably provided for improving adhesion, hiding, or protecting corrosion resistance. The dry film thickness is preferably about 1 to 10 μm.
【0021】下塗り樹脂皮膜に使用される樹脂系は特に
限定されないが、加工性と密着性とのバランスから、ポ
リエステル樹脂系、ポリウレタン樹脂系、エポキシ樹脂
系、またはこれらの樹脂の併用系が好ましい。The resin system used for the undercoat resin film is not particularly limited, but a polyester resin system, a polyurethane resin system, an epoxy resin system, or a combination system of these resins is preferable from the balance between workability and adhesion.
【0022】(4) 上塗り樹脂皮膜 上塗り樹脂皮膜は、1層または2層以上の樹脂層から形
成することができる。1層の場合にはその層を、2層以
上の場合には最上層を、本発明で規定する共重合ポリ
エステル樹脂、アルキルエーテル化アミノホルムアル
デヒド樹脂、酸触媒、および有機樹脂ビーズを含む
塗料組成物から形成する。通常は、上塗り樹脂皮膜は1
層だけ (即ち、本発明で規定する塗料組成物から形成し
た焼付け皮膜だけ) でよい。こうして、最上層の樹脂皮
膜を本発明で規定する塗料組成物から形成することによ
り、加工性と耐プレッシャーマーク性とが両立したプレ
コート鋼板が得られる。(4) Topcoat Resin Film The topcoat resin film can be formed from one or more resin layers. A coating composition comprising a copolymerized polyester resin, an alkyl etherified aminoformaldehyde resin, an acid catalyst, and organic resin beads as defined in the present invention; Formed from Normally, the top coating resin film is 1
Only a layer (ie, a baked film formed from the coating composition as defined in the present invention) is sufficient. Thus, by forming the uppermost resin film from the coating composition specified in the present invention, a precoated steel sheet having both workability and pressure-mark resistance can be obtained.
【0023】共重合ポリエステル樹脂 塗膜のベース樹脂として、加工性に優れる、ガラス転移
点が40℃未満の共重合ポリエステル樹脂を使用する。共
重合ポリエステル樹脂とは、多塩基酸と多価アルコール
とから合成されたポリエステル樹脂のことであり、多様
な種類の共重合ポリエステル樹脂が製造され、市販され
ている。Copolyester Resin As the base resin of the coating film, a copolyester resin having excellent workability and having a glass transition point of less than 40 ° C. is used. The copolyester resin is a polyester resin synthesized from a polybasic acid and a polyhydric alcohol, and various types of copolyester resins are manufactured and commercially available.
【0024】特開平8−53646 号公報には、ポリエステ
ル樹脂のガラス転移点が40℃未満では、加工性が良好で
あるものの、耐プレッシャーマーク性が劣ると説明され
ている。本発明においては、架橋剤に酸触媒を併用する
ことで、架橋反応を促進させ、かつ後述する傾斜機能に
より塗膜外面側の架橋密度を高くすることにより、ガラ
ス転移点が40℃未満のポリエステル樹脂を使用して、良
好な耐プレッシャーマーク性を確保することができる。Japanese Patent Application Laid-Open No. 8-53646 describes that when the glass transition point of the polyester resin is lower than 40 ° C., the workability is good, but the pressure mark resistance is poor. In the present invention, by using an acid catalyst in combination with a crosslinking agent, the crosslinking reaction is promoted, and the cross-linking density on the outer surface side of the coating film is increased by a gradient function described later, whereby the polyester having a glass transition point of less than 40 ° C By using a resin, good pressure mark resistance can be ensured.
【0025】共重合ポリエステル樹脂のガラス転移点が
40℃以上と高くなると、加工性、特に、冬場の加工など
に求められる低温加工性が不足する。逆にガラス転移点
が極端に低いと、ブロッキング (塗装面同士がくっつく
現象) を起こす恐れがあるため、共重合ポリエステル樹
脂のガラス転移点は好ましくは0℃以上である。The glass transition point of the copolymerized polyester resin is
If the temperature is as high as 40 ° C. or higher, workability, particularly low-temperature workability required for processing in winter, etc., is insufficient. Conversely, if the glass transition point is extremely low, blocking (a phenomenon in which painted surfaces stick to each other) may occur. Therefore, the glass transition point of the copolymerized polyester resin is preferably 0 ° C. or higher.
【0026】共重合ポリエステル樹脂の数平均分子量に
ついては特に限定しないが、好ましい数平均分子範囲は
9,000〜25,000である。9,000 未満では加工性が不足す
ることがあり、25,000を越えると塗料の粘度が上昇し、
塗装性が低下する。加工性と塗装性の観点からより好ま
しくは 9,000〜15,000である。The number average molecular weight of the copolymerized polyester resin is not particularly limited, but the preferred number average molecular range is
9,000-25,000. If it is less than 9,000, workability may be insufficient, and if it exceeds 25,000, the viscosity of the paint will increase,
Paintability decreases. It is more preferably from 9,000 to 15,000 from the viewpoints of workability and coatability.
【0027】アルキルエーテル化アミノホルムアルデ
ヒド樹脂 (架橋剤) 焼付け工程において共重合ポリエステル樹脂と反応する
架橋剤として、自己縮合性があり、表面濃化を起こし易
いアルキルエーテル化アミノホルムアルデヒド樹脂を使
用する。これ以外の架橋剤、例えばイソシアネート化合
物は、自己縮合性を持たず、表面濃化による傾斜機能を
発現しにくく、本発明の目的には不適当である。Alkyl-etherified aminoformaldehyde resin (crosslinking agent) Alkyl-etherified aminoformaldehyde resin which has self-condensability and easily causes surface concentration is used as a crosslinking agent which reacts with the copolymerized polyester resin in the baking step. Other crosslinking agents, for example, isocyanate compounds, do not have self-condensing properties, do not easily exhibit a gradient function due to surface concentration, and are unsuitable for the purpose of the present invention.
【0028】アルキルエーテル化アミノホルムアルデヒ
ド樹脂としては、アルキルエーテル化メチロールメラミ
ン樹脂、例えば、メトキシ化メチロールメラミン、メト
キシ化ブトキシ化混合型メチロールメラミン、さらにア
ルキルエーテル化量の比較的少ないメトキシ化メラミン
あるいはイミノ基型メラミン等が用いられ、これらを単
独で使用しても、または2種以上を併用してもよい。Examples of the alkyl etherified aminoformaldehyde resin include alkyl etherified methylol melamine resins, for example, methoxylated methylol melamine, methoxylated butoxylated mixed methylol melamine, and methoxylated melamine or imino group having a relatively small amount of alkyl etherification. Melamine or the like is used, and these may be used alone or in combination of two or more.
【0029】このアルキルエーテル化アミノホルムアル
デヒド樹脂を共重合ポリエステルに配合した塗料の塗膜
を焼付け硬化させると、両者の表面自由エネルギー差と
相溶性によって、表面自由エネルギーが相対的に小さい
アルキルエーテル化アミノホルムアルデヒド樹脂が、焼
付け中により高温になる塗膜の表面 (外面側) の方向に
移行し、表面に濃化する傾向がある。When a coating film of a coating material in which this alkyl etherified amino formaldehyde resin is blended with a copolymerized polyester is baked and cured, the alkyl etherified amino formaldehyde having a relatively small surface free energy is obtained due to the difference in surface free energy and compatibility between the two. The formaldehyde resin tends to migrate toward the surface (outer side) of the coating film, which becomes hotter during baking, and concentrate on the surface.
【0030】架橋剤として用いるアルキルエーテル化ア
ミノホルムアルデヒド樹脂は自己縮合性を有する (完全
メトキシ化メチロールメラミンはそれ自身は自己縮合性
が小さいが、酸触媒を併用することにより、自己縮合反
応が促進される)ので、表面に濃化したアルキルエーテ
ル化アミノホルムアルデヒド樹脂は、周囲に共重合ポリ
エステル樹脂が少なくなってこれと縮合反応できなくて
も、架橋剤どうしで縮合して架橋することができ、表面
近傍での架橋密度が高くなる。こうして、樹脂組成 (ポ
リエステル樹脂と架橋剤との存在比率) や架橋密度が塗
膜の厚み方向に変化する傾斜機能が塗膜に付与される。
前述したように、架橋剤に自己縮合性がないと、この傾
斜機能はあまり付与されない。The alkyl etherified aminoformaldehyde resin used as a crosslinking agent has a self-condensing property. (Completely methoxylated methylolmelamine itself has a small self-condensing property, but the self-condensation reaction is accelerated by using an acid catalyst in combination. Therefore, the alkyl etherified amino formaldehyde resin concentrated on the surface can be cross-linked by cross-linking between cross-linking agents even if the amount of the copolyester resin is low and the condensation reaction cannot be performed with the resin. The crosslink density in the vicinity increases. In this manner, the coating film is provided with a gradient function in which the resin composition (the ratio of the polyester resin to the crosslinking agent) and the crosslinking density change in the thickness direction of the coating film.
As described above, if the cross-linking agent does not have self-condensability, the tilt function is not provided much.
【0031】この表面近傍での緻密な架橋構造により、
プレッシャーマークのような光沢変化が抑制できる。一
方、塗膜の内側では、架橋剤の濃度が低くなるので、共
重合ポリエステル樹脂の架橋があまり起こらず、共重合
ポリエステル樹脂の持つ良好な加工性が保持される。Due to the dense crosslinked structure near the surface,
A gloss change such as a pressure mark can be suppressed. On the other hand, since the concentration of the cross-linking agent is low inside the coating film, the cross-linking of the copolyester resin does not occur so much, and the good processability of the copolyester resin is maintained.
【0032】架橋剤のアルキルエーテル化アミノホルム
アルデヒド樹脂は、共重合ポリエステル樹脂100 重量部
に対して、10〜45重量部、好ましくは15〜40重量部、さ
らに好ましくは20〜30重量部の割合で使用する。この量
が10重量部未満では、架橋不足のために二次密着性や耐
食性の低下をきたし、45重量部を超えると加工性が低下
する。The alkyl etherified aminoformaldehyde resin as a crosslinking agent is used in an amount of 10 to 45 parts by weight, preferably 15 to 40 parts by weight, more preferably 20 to 30 parts by weight, based on 100 parts by weight of the copolymerized polyester resin. use. If this amount is less than 10 parts by weight, secondary adhesion and corrosion resistance will be reduced due to insufficient crosslinking, and if it exceeds 45 parts by weight, workability will be reduced.
【0033】酸触媒 酸触媒は、架橋剤であるアルキルエーテル化アミノホル
ムアルデヒド樹脂の自己縮合を促進させ、前述した傾斜
機能をより高度に発揮させるために添加する。それによ
り、完全メトキシ化メチロールメラミンのように自己縮
合性が小さいアルキルエーテル化アミノホルムアルデヒ
ド樹脂を使用する場合でも、その自己縮合による傾斜機
能、即ち、架橋剤の表面濃化と自己縮合により、内部の
架橋密度を低く抑えたまま、表面近傍の架橋密度を増大
させ、プレッシャーマークによる光沢変化を抑制する作
用を確実に発揮させることができる。Acid Catalyst An acid catalyst is added to promote self-condensation of the alkyl etherified aminoformaldehyde resin as a cross-linking agent, and to exhibit the above-mentioned gradient function to a higher degree. Thereby, even when using an alkyletherified aminoformaldehyde resin having a small self-condensation property such as fully methoxylated methylol melamine, the gradient function by the self-condensation, that is, the internal concentration of the crosslinking agent and the self-condensation, While keeping the crosslink density low, the crosslink density near the surface can be increased, and the effect of suppressing the gloss change due to the pressure mark can be reliably exhibited.
【0034】酸触媒としては、有機強酸、特にp−トル
エンスルホン酸、ドデシルベンゼンスルホン酸などのス
ルホン酸類が好ましい。酸触媒の添加量は、共重合ポリ
エステル樹脂100 重量部に対して、1〜3重量部、好ま
しくは 1.5〜2.5 重量部の範囲内とする。この量が1重
量部未満では、アルキルエーテル化アミノホルムアルデ
ヒド樹脂の自己縮合が起こりにくく、その表面濃化量が
不足して耐プレッシャーマーク性が低下することがあ
り、3重量部を超えると、架橋が進みすぎて加工性の低
下が起こる。As the acid catalyst, strong organic acids, especially sulfonic acids such as p-toluenesulfonic acid and dodecylbenzenesulfonic acid are preferred. The amount of the acid catalyst is in the range of 1 to 3 parts by weight, preferably 1.5 to 2.5 parts by weight, based on 100 parts by weight of the copolymerized polyester resin. If the amount is less than 1 part by weight, self-condensation of the alkyl etherified aminoformaldehyde resin is unlikely to occur, and the surface thickening amount may be insufficient to reduce the pressure mark resistance. If the amount exceeds 3 parts by weight, crosslinking may occur. Progresses too much, resulting in a reduction in workability.
【0035】有機樹脂ビーズ 塗膜全体を補強し、耐プレッシャーマーク性を向上させ
るため、ビッカース硬度6以上という硬質の有機樹脂ビ
ーズを塗膜中に含有させる。ここで、ビッカース硬度
は、正四角錘 (対面角136 度) のダイヤモンド圧子を試
料に押し込んだとき、荷重とくぼみの表面積から定義さ
れる硬さのことであり、本発明においては、荷重10gに
て測定される値を採用している。Organic Resin Beads Hard organic resin beads having a Vickers hardness of 6 or more are contained in the coating in order to reinforce the entire coating and improve the resistance to pressure marks. Here, the Vickers hardness is the hardness defined by the load and the surface area of the depression when a diamond indenter having a regular square pyramid (136 ° facing angle) is pushed into the sample, and in the present invention, the load is 10 g. The values measured are used.
【0036】ビッカース硬度で6未満の樹脂ビーズを使
用しても、十分なプレッシャーマーク性の向上効果が得
られない。樹脂ビーズのビッカース硬度は好ましくは6.
5 以上である。Even if resin beads having a Vickers hardness of less than 6 are used, a sufficient effect of improving the pressure mark property cannot be obtained. The Vickers hardness of the resin beads is preferably 6.
5 or more.
【0037】有機樹脂ビーズの材質は、硬度の条件を満
足していれば特に限定されないが、アクリル系、ポリウ
レタン系、ポリエステル系、ポリアミド系、ポリエチレ
ン系、ポリプロピレン系、シリコーン系、ポリフッ化ビ
ニリデン系、ポリフッ化テトラフロオロエチレン系等の
樹脂が例示できる。The material of the organic resin bead is not particularly limited as long as it satisfies the condition of hardness, but may be acrylic, polyurethane, polyester, polyamide, polyethylene, polypropylene, silicone, polyvinylidene fluoride, or the like. Examples thereof include polyfluorotetrafluoroethylene-based resins.
【0038】ビーズの形状についても特に限定されない
が、球形もしくはそれに近い形態が好ましい。ビーズの
粒径に関しては、これを含有させる最上層皮膜の膜厚と
同程度か、やや大きい程度が望ましい。最上層皮膜の膜
厚より小さいと、前記の補強効果が不足し、極端に大き
くなると、密着性が不足して脱落し易くなる。従って、
ビーズの粒径としては、最上層皮膜の膜厚の1〜2倍、
特に1〜1.5 倍が望ましい。The shape of the beads is not particularly limited, but a spherical shape or a shape close thereto is preferable. The particle size of the beads is desirably about the same as or slightly larger than the thickness of the uppermost layer film containing the beads. When the thickness is smaller than the thickness of the uppermost film, the above-mentioned reinforcing effect is insufficient, and when the thickness is extremely large, the adhesiveness is insufficient and the film tends to fall off. Therefore,
The particle size of the beads is 1 to 2 times the film thickness of the top layer film,
In particular, it is preferably 1 to 1.5 times.
【0039】ビーズの添加量は、共重合ポリエステル樹
脂100 重量部に対して1〜5重量部、好ましくは2〜4
重量部とする。この量が5重量部未満では、耐プレッシ
ャーマーク性が不足し、5重量部を上回ると加工性の劣
化を免れない。The amount of beads added is 1 to 5 parts by weight, preferably 2 to 4 parts by weight, per 100 parts by weight of the copolymerized polyester resin.
Parts by weight. If the amount is less than 5 parts by weight, the resistance to pressure mark is insufficient, and if it exceeds 5 parts by weight, deterioration of workability is inevitable.
【0040】最上層皮膜の形成の用いる塗料組成物は、
前述した〜の必須成分以外に、塗料に慣用される他
の成分を含有しうる。かかる他の成分としては、溶媒、
顔料、他の樹脂、消泡剤、表面硬化調整剤、艶消し剤、
ワックス成分等が挙げられる。通常は溶媒と顔料は必ず
使用する。The coating composition used for forming the uppermost film is as follows:
In addition to the above-mentioned essential components, other components commonly used in paints may be contained. Such other components include a solvent,
Pigments, other resins, defoamers, surface hardeners, matting agents,
And a wax component. Usually, solvents and pigments are always used.
【0041】適当な溶媒の例は、シクロヘキサノン、イ
ソホロン、N−メチル−2−ピロリドンなどのケトン系
溶媒、ソルベッソなどであり、共重合ポリエステル樹脂
とアルキルエーテル化アミノホルムアルデヒド樹脂の両
者を溶解できるが、使用する有機樹脂ビーズを実質的に
溶解しないものを選択する。Examples of suitable solvents include ketone solvents such as cyclohexanone, isophorone and N-methyl-2-pyrrolidone, Solvesso and the like, which can dissolve both the copolymerized polyester resin and the alkyl etherified aminoformaldehyde resin. Those that do not substantially dissolve the organic resin beads to be used are selected.
【0042】(5) 塗装焼付け方法 最上層皮膜を形成するための上記塗料組成物の塗装方法
は、プレコート鋼板の製造に使用可能な任意の方法でよ
い。例えば、ロールコート法、カーテンフローコート
法、スプレー法等が使用できる。最上層皮膜の膜厚は、
乾燥膜厚で5〜30μm、特に7〜25μmの範囲内が好ま
しい。塗装は通常は片面だけに行い、裏面側には別の簡
易な塗装 (サービスコート、例えば前述したプライマー
だけ) を施すことが多いが、両面に上記塗料組成物を塗
装しても構わない。(5) Coating baking method The coating method of the above-mentioned coating composition for forming the uppermost layer film may be any method that can be used for producing a precoated steel sheet. For example, a roll coating method, a curtain flow coating method, a spray method, or the like can be used. The film thickness of the top layer film is
The dry film thickness is preferably in the range of 5 to 30 μm, particularly 7 to 25 μm. Usually, coating is performed only on one side, and another simple coating (service coat, for example, only the above-described primer) is often applied on the back side, but the coating composition may be applied on both sides.
【0043】塗装後の焼付けは、熱風オーブン (即ち、
熱風加熱) により行い、その際の熱風の風速によって、
最上層皮膜の表面に濃化するアルキルエーテル化アミノ
ホルムアルデヒド樹脂の量を制御することができる。具
体的には、板面で測定した熱風風速が 0.5〜3.0 m/sec
となる条件の熱風オーブンで焼付けを行うことが好まし
い。The baking after painting is performed in a hot air oven (ie,
Hot air heating), and the speed of the hot air at that time,
It is possible to control the amount of the alkyl etherified aminoformaldehyde resin concentrated on the surface of the uppermost film. Specifically, the hot air velocity measured on the plate surface is 0.5 to 3.0 m / sec.
It is preferable to perform baking in a hot air oven under the following conditions.
【0044】この風速が0.5 m/sec 未満ではアルキルエ
ーテル化アミノホルムアルデヒド樹脂の表面濃化量が少
なく、耐プレッシャーマーク性が不足する場合がある。
一方、この風速が3m/sec を超えると、アルキルエーテ
ル化アミノホルムアルデヒド樹脂の表面濃化量が過剰に
なり、表面の架橋が進行しすぎて脆くなり、加工性が低
下することがある。If the wind speed is less than 0.5 m / sec, the amount of the alkyl etherified aminoformaldehyde resin concentrated on the surface is small, and the pressure mark resistance may be insufficient.
On the other hand, if the wind speed exceeds 3 m / sec, the surface concentration of the alkyl etherified aminoformaldehyde resin becomes excessive, and the surface cross-linking proceeds excessively, making the resin brittle, and the workability may be reduced.
【0045】板面での風速の測定は、熱式流速計の1種
である熱線式流速計、或いはサーミスター流速計等の慣
用の測定機を用いて行うことができる。焼付け温度は通
常のプレコート鋼板の焼付け温度と同様でよく、特に限
定されないが、PMT (最高到達板温度) 200〜250 ℃
程度で行われることが多い。The measurement of the wind speed on the plate surface can be performed by using a conventional measuring device such as a hot wire current meter, which is a kind of thermal current meter, or a thermistor current meter. The baking temperature may be the same as the baking temperature of a normal pre-coated steel sheet, and is not particularly limited, but PMT (maximum reached plate temperature) 200 to 250 ° C
Often done on a degree.
【0046】[0046]
【実施例】厚さ0.6 mmの溶融亜鉛めっき鋼板 (めっき付
着量:片面60 g/m2)を母材鋼板とし、その表面を常法に
より清浄化した後、下地処理として燐酸亜鉛溶液の浸漬
により燐酸亜鉛化成皮膜 (燐酸亜鉛付着量0.8 g/m2) を
形成した。次いで、下塗り用の塗料として、大日本イン
キ化学製のプライマー塗料PB10P を使用し、乾燥膜厚が
7μmになるようロールコーターで鋼板の片面に塗布し
た後、最高到達鋼板温度 (PMT) が210 ℃になるよう
50秒で焼付け硬化させた。この下塗り樹脂皮膜の上に、
次に述べるようにして上塗り樹脂皮膜を形成して、プレ
コート鋼板を作製した。Example: A hot-dip galvanized steel sheet having a thickness of 0.6 mm (amount of coating: 60 g / m 2 on one side) was used as a base steel sheet, the surface of which was cleaned by an ordinary method, and immersed in a zinc phosphate solution as a base treatment. As a result, a zinc phosphate conversion coating (a zinc phosphate coating weight of 0.8 g / m 2 ) was formed. Then, as a primer, a primer paint PB10P manufactured by Dainippon Ink and Chemicals was used and applied to one side of the steel sheet with a roll coater so that the dry film thickness became 7 μm, and the maximum temperature of the steel sheet (PMT) reached 210 ° C. To be
Bake hardened in 50 seconds. On this undercoat resin film,
A precoated steel sheet was produced by forming an overcoat resin film as described below.
【0047】上塗り樹脂皮膜の形成に用いた塗料組成物
は、表1に示す共重合ポリエステル樹脂100 重量部に対
し、表2の架橋剤、表3の酸触媒、そして表4の樹脂ビ
ーズを適宜組合わせて、表5または表6に示す量 (重量
部) で添加することにより調製した。表1、表2および
表4において、* を付したものは、本発明の範囲外の比
較用の材料である。この塗料組成物は、溶媒としてシク
ロヘキサノンを、顔料として酸化チタンを含有してい
た。The coating composition used for forming the overcoat resin film was prepared by appropriately adding the crosslinking agent shown in Table 2, the acid catalyst shown in Table 3, and the resin beads shown in Table 4 to 100 parts by weight of the copolymerized polyester resin shown in Table 1. They were prepared by adding them in the amounts (parts by weight) shown in Table 5 or Table 6 in combination. In Tables 1, 2 and 4, those marked with * are comparative materials outside the scope of the present invention. This coating composition contained cyclohexanone as a solvent and titanium oxide as a pigment.
【0048】この塗料組成物を、乾燥膜厚が18μmにな
るようにロールコーターで塗布した後、オーブン風速
(板面) を 0.3〜6 m/sに制御した熱風オーブンに入
れ、焼付け時間50秒でPMTが230 ℃になるように焼付
硬化を行い、プレコート鋼板を得た。The coating composition was applied by a roll coater so that the dry film thickness became 18 μm, and the
(Plate surface) was placed in a hot-air oven controlled at 0.3 to 6 m / s, and baked and hardened so that the PMT would be 230 ° C. in a baking time of 50 seconds to obtain a precoated steel sheet.
【0049】[0049]
【表1】 [Table 1]
【0050】[0050]
【表2】 [Table 2]
【0051】[0051]
【表3】 [Table 3]
【0052】[0052]
【表4】 [Table 4]
【0053】作製したプレコート鋼板の試験片を用い
て、下記要領でその性能評価を実施した。その試験結果
も表5および表6に一緒に示す。Using the test pieces of the prepared precoated steel sheets, their performance was evaluated in the following manner. The test results are also shown in Tables 5 and 6.
【0054】(1) 耐プレッシャーマーク性 実施例で作製したプレコート鋼板 (Aとする) の試験片
の塗膜面を、プレコート鋼板の裏面側を想定して作製し
た別のプレコート鋼板 (Bとする) の試験片の塗膜と加
圧下に面接触させて、耐プレッシャーマーク性を評価し
た。プレコート鋼板Bは、同じ母材鋼板に上記と同様に
下地処理板 (リン酸亜鉛処理板) した後、プレコート鋼
板の裏面塗装 (サービスコート) に用いられるエポキシ
系塗料を用いて、乾燥膜厚6μmで塗装と焼付けを行っ
て作製した。(1) Pressure Mark Resistance Another pre-coated steel sheet (B) was prepared by assuming that the coating surface of the test piece of the pre-coated steel sheet (A) prepared in the example was the reverse side of the pre-coated steel sheet. ) Was brought into surface contact with the coating film of the test piece under pressure to evaluate the resistance to pressure marks. The pre-coated steel sheet B is coated with a base material (zinc phosphate-treated sheet) in the same manner as described above on the same base steel sheet, and then dried using an epoxy-based paint used for painting the back surface (service coat) of the pre-coated steel sheet. And painted and baked.
【0055】プレコート鋼板AとBの同寸法の試験片の
塗膜面同士が面接触するように重ねて、40℃にて100 kg
/cm2×24時間の熱プレスを施し、熱プレス後のプレコー
ト鋼板Aの試験片の塗膜表面を目視で観察し、プレッシ
ャーマークの発生状況を下記基準により評価した。The precoated steel sheets A and B were overlaid so that the coating surfaces of the test specimens of the same dimensions were in surface contact with each other, and 100 kg at 40 ° C.
/ cm 2 × 24 hours, and the surface of the coating film of the test piece of the precoated steel sheet A after the hot pressing was visually observed, and the occurrence of the pressure mark was evaluated according to the following criteria.
【0056】 ◎:プレッシャーマークの発生が全くない、 ○:プレッシャーマークが発生したが、ごく軽微、 △:プレッシャーマーク発生が中程度、 ×:プレッシャーマーク発生が著しい。:: No pressure mark was generated at all, :: Pressure mark was generated but very slight, Δ: Moderate pressure mark was generated, ×: Pressure mark was significantly generated.
【0057】(2) 折曲げ加工性 プレコート鋼板の試験片に対し、塗膜面を外側にして板
挟み枚数を変えながら180°折曲げ加工を施した後、折
曲げ部を10倍ルーペで観察して塗膜の亀裂の有無を判定
した。折曲げ加工性は、亀裂が認められない最小の板挟
み枚数で表示した。(2) Bending workability A test piece of a precoated steel sheet was subjected to 180 ° bending while changing the number of sandwiched sheets with the coating surface outside, and the bent portion was observed with a 10-fold loupe. To determine the presence or absence of cracks in the coating film. The bending workability was indicated by the minimum number of sandwiched sheets where no crack was observed.
【0058】例えば、0Tは密着曲げ可能を示し、1T
は板挟み枚数が1枚、即ち、 180°曲げ時の板間隔が、
同じ厚みの板1枚分となるまで、亀裂を生じることなく
折曲げが可能であることを示す。従って、表示した数値
が大きいほど加工性が低い。この折曲げ加工性は温度に
依存し、一般に低温では低下する傾向がある。ここでは
0℃ (氷温) で折曲げ試験を実施した。For example, 0T indicates that close bending is possible, and 1T
Means that the number of sandwiched plates is one, that is, the interval between
This indicates that bending can be performed without cracking until a sheet having the same thickness is obtained. Therefore, the larger the displayed numerical value, the lower the workability. The bending workability depends on the temperature, and generally tends to decrease at low temperatures. Here, the bending test was performed at 0 ° C. (ice temperature).
【0059】[0059]
【表5】 [Table 5]
【0060】[0060]
【表6】 [Table 6]
【0061】表5からわかるように、本発明例のプレコ
ート鋼板は、プレッシャーマークが全く発生しないか、
発生してもごく軽微で、耐プレッシャーマーク性に優れ
ており、同時に折曲げ加工性も3T以内、多くは1Tか
2Tと良好であった。As can be seen from Table 5, the precoated steel sheet of the present invention does not show any pressure mark.
Even if it occurred, it was very slight, excellent in resistance to pressure mark, and at the same time, the bending workability was good within 3T, and often as good as 1T or 2T.
【0062】これに対し、表6に示した比較例を見る
と、酸触媒を添加しないか(No.35) 、架橋剤であるアル
キルエーテル化アミノホルムアルデヒド樹脂または樹脂
ビーズの配合量が少なすぎるか(No.39, 41) 、樹脂ビー
ズのビッカース硬度が小さすぎると(No.44) 、耐プレッ
シャーマーク性が低下した。一方、酸触媒、架橋剤、ま
たは樹脂ビーズの配合量が多すぎるか(No.36, 40, 42)
、共重合ポリエステル樹脂のガラス転移点が40℃より
高いと(No.43) 、加工性が低下した。また、別の架橋剤
を使用すると、耐プレッシャーマーク性の向上が得られ
なかった。On the other hand, the comparative examples shown in Table 6 show that the acid catalyst was not added (No. 35) or the amount of the alkyl etherified aminoformaldehyde resin or resin bead as the crosslinking agent was too small. (Nos. 39 and 41), when the Vickers hardness of the resin beads was too small (No. 44), the pressure mark resistance was reduced. On the other hand, whether the compounding amount of the acid catalyst, the crosslinking agent, or the resin beads is too large (No. 36, 40, 42)
On the other hand, when the glass transition point of the copolymerized polyester resin was higher than 40 ° C. (No. 43), the processability was lowered. In addition, when another crosslinking agent was used, improvement in pressure mark resistance could not be obtained.
【0063】試験No.45 は、樹脂ビーズの粒径が大きす
ぎたため、ビーズの脱落が認められたので、膜特性は評
価しなかった。樹脂ビーズの粒径が小さすぎても(No.4
6) 、耐プレッシャーマーク性は低下した。塗布後の焼
付け時のオーブン風速が低すぎると(No.37) 、架橋剤の
表面濃化が十分に起こらず、耐プレッシャーマーク性が
低下する傾向があり、この風速が高すぎると(No.38) 、
架橋剤の表面濃化が起こりすぎて、加工性がやや不足し
た。In Test No. 45, since the particle size of the resin beads was too large, and the beads fell off, the film properties were not evaluated. Even if the particle size of the resin beads is too small (No. 4
6), the resistance to pressure mark was reduced. If the oven wind speed during baking after application is too low (No. 37), the surface concentration of the crosslinking agent does not sufficiently occur, and the pressure-mark resistance tends to decrease.If the wind speed is too high (No. 37). 38),
The surface concentration of the cross-linking agent occurred too much, and the workability was slightly insufficient.
【0064】[0064]
【発明の効果】本発明のプレコート鋼板は、加工性のよ
いガラス転移点の低い共重合ポリエステル樹脂に、表面
濃化可能な自己縮合性の架橋剤と酸触媒を、硬質の有機
樹脂ビーズと一緒に配合した塗料組成物から最上層の皮
膜を形成することにより、加工性を低下させずに、この
種のプレコート鋼板の欠点であったプレッシャーマーク
発生をほぼ完全に防止することができる。従って、本発
明のプレコート鋼板は、美麗な光沢を持つ外観が求めら
れ、光沢が低下すると商品価値が大きく損なわれる、家
庭用電気機器や屋内外器物等の用途に最適である。According to the precoated steel sheet of the present invention, a self-condensable crosslinkable agent capable of concentrating the surface and an acid catalyst are combined with a hard organic resin bead on a copolyester resin having good workability and a low glass transition point. By forming the uppermost layer from the coating composition blended in the above, it is possible to almost completely prevent the occurrence of a pressure mark, which is a drawback of this type of precoated steel sheet, without reducing workability. Therefore, the precoated steel sheet of the present invention is required to have a beautiful glossy appearance, and when the gloss is reduced, the commercial value is greatly impaired.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 FI C09D 161:32) ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 6 Identification code FI C09D 161: 32)
Claims (2)
ガラス転移点が40℃未満の共重合ポリエステル樹脂100
重量部、アルキルエーテル化アミノホルムアルデヒド
樹脂10〜45重量部、酸触媒1〜3重量部、およびビ
ッカース硬度が6以上で、粒径が該最上層樹脂皮膜の膜
厚の1〜2倍の有機樹脂ビーズ1〜5重量部、を必須成
分として含む塗料組成物から形成された焼付け皮膜であ
ることを特徴とする、耐プレッシャーマーク性と加工性
に優れたプレコート鋼板。1. The resin coating of the uppermost layer provided on a steel plate,
Copolyester resin 100 with glass transition point less than 40 ° C
Parts by weight, 10 to 45 parts by weight of an alkyl etherified aminoformaldehyde resin, 1 to 3 parts by weight of an acid catalyst, and an organic resin having a Vickers hardness of 6 or more and a particle size of 1 to 2 times the thickness of the uppermost resin film. A precoated steel sheet having excellent pressure mark resistance and workability, characterized in that it is a baked film formed from a coating composition containing 1 to 5 parts by weight of beads as an essential component.
後、板面での風速が0.5〜3.0 m/sec になるように制御
された熱風オーブンにより塗膜を焼付けて最上層の樹脂
皮膜を形成することを特徴とする、耐プレッシャーマー
ク性と加工性に優れたプレコート鋼板の製造方法。2. After applying the coating composition according to claim 1, the coating film is baked by a hot air oven controlled so that the wind speed on the plate surface is 0.5 to 3.0 m / sec, and the uppermost resin layer is formed. A method for producing a precoated steel sheet having excellent pressure mark resistance and workability, characterized by forming a film.
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JP00322597A JP3503383B2 (en) | 1997-01-10 | 1997-01-10 | Pre-coated steel sheet and its manufacturing method |
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JP2005074963A (en) * | 2003-09-03 | 2005-03-24 | Sumitomo Light Metal Ind Ltd | Pre-coat aluminum alloy plate excellent in heat releasing, anti-injury ability and electrical conductivity |
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JP2012218401A (en) * | 2011-04-13 | 2012-11-12 | Jsr Corp | Surface protective film |
WO2015156285A1 (en) * | 2014-04-09 | 2015-10-15 | 新日鐵住金ステンレス株式会社 | Clear-coated stainless steel sheet |
JP2015199292A (en) * | 2014-04-09 | 2015-11-12 | 新日鐵住金ステンレス株式会社 | Clear-coated stainless steel sheet |
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JP2018199236A (en) * | 2017-05-26 | 2018-12-20 | 三菱アルミニウム株式会社 | Resin coated aluminum sheet |
JP2019111750A (en) * | 2017-12-25 | 2019-07-11 | 日鉄日新製鋼株式会社 | Coated metal plate and exterior building material using the same |
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