JPH02173171A - Heat-resistant antifouling coating compound - Google Patents
Heat-resistant antifouling coating compoundInfo
- Publication number
- JPH02173171A JPH02173171A JP33506088A JP33506088A JPH02173171A JP H02173171 A JPH02173171 A JP H02173171A JP 33506088 A JP33506088 A JP 33506088A JP 33506088 A JP33506088 A JP 33506088A JP H02173171 A JPH02173171 A JP H02173171A
- Authority
- JP
- Japan
- Prior art keywords
- polyborosiloxane
- heat
- coating compound
- paint
- resistance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000003373 anti-fouling effect Effects 0.000 title claims description 16
- 239000011248 coating agent Substances 0.000 title abstract description 11
- 238000000576 coating method Methods 0.000 title abstract description 11
- 150000001875 compounds Chemical class 0.000 title abstract 5
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 10
- 239000002966 varnish Substances 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 4
- 239000011347 resin Substances 0.000 claims abstract description 4
- 239000003973 paint Substances 0.000 claims description 25
- 239000003960 organic solvent Substances 0.000 claims description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052731 fluorine Inorganic materials 0.000 abstract description 3
- 239000011737 fluorine Substances 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000011521 glass Substances 0.000 description 4
- 235000019353 potassium silicate Nutrition 0.000 description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 4
- 239000000758 substrate Substances 0.000 description 3
- 239000010426 asphalt Substances 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- DJHGAFSJWGLOIV-UHFFFAOYSA-N Arsenic acid Chemical compound O[As](O)(O)=O DJHGAFSJWGLOIV-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229940000488 arsenic acid Drugs 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、耐熱性と防汚性とを兼備えたｆｉｌｖ４性防
汚塗料に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a filv4 antifouling paint that has both heat resistance and antifouling properties.
（従来の技１ｔｉ）
従来５耐熱性と、防汚性すなわち汚れが付着しにくくま
たたとえ１才着しても容易に除去しうろことが要求され
る用途に対しては、シリコーン樹脂を主成分とした有機
ポリマー系塗料と、水ガラスを主成分とした水ガラス系
塗料が主として使用されている。(Conventional Technique 1ti) Conventional 5 For applications that require heat resistance and stain resistance, that is, dirt does not stick easily, and is easy to remove even if worn for one year, silicone resin is the main component. Organic polymer-based paints containing water glass as a main component and water glass-based paints containing water glass as a main component are mainly used.
（発明が解決しようとする課題）
しかしながらこのような従来の塗料は、いずれも防汚性
は比較的良好であるものの、それぞれ次のような難点を
有している。(Problems to be Solved by the Invention) However, although all of these conventional paints have relatively good antifouling properties, they each have the following drawbacks.
すなわちシリコーン樹脂を用いたものは、常用１＝度は
２５０℃程度で、３００℃を越えると使用は不可能とな
る。まただと＾常用温度２５０℃のｉｌｌ囲内であって
も長時間使用すると煩き付は塗膜にクラックや剥離等を
生じるおそれがある。That is, products using silicone resin are normally used at a temperature of about 250°C, and cannot be used at temperatures exceeding 300°C. Furthermore, if used for a long time even at the normal temperature of 250°C, there is a risk that the paint film will crack or peel.
他方、水ガラス系塗料は耐熱温度が３００℃以上と高く
ガラス基を才との密着性も比較的良好だが、耐湿性に乏
しく、また可撓性が非常に悪い。On the other hand, water glass-based paints have a high heat resistance of 300° C. or higher and have relatively good adhesion between glass bases and substrates, but they have poor moisture resistance and very poor flexibility.
そこで本発明はこのような従来の難点を解決しようとす
るもので、４００’Ｃ以上の雰＠気下でも使用可能であ
って、しかも耐湿性が良く、防汚性を大幅に向上させた
耐熱性防７号塗料を提供することを目的とする。Therefore, the present invention aims to solve these conventional difficulties, and is a heat-resistant product that can be used in an atmosphere of 400'C or higher, has good moisture resistance, and has significantly improved stain resistance. The purpose is to provide No. 7 paint.
（課題を解決するための手段）
本発明は即ち、ポリボロシロキサン［１４と有機溶剤と
を混合させてなるポリボロシロキサン塗料１００重量部
に、フッ素変性シリコーンワニス２〜１０重量部を混合
してなることを特徴とする耐熱性防汚塗料に関する。な
お、本発明における塗料の１量部は３００℃Ｘｌｈの不
揮発分を基準にしている。(Means for Solving the Problems) The present invention consists of mixing 2 to 10 parts by weight of a fluorine-modified silicone varnish with 100 parts by weight of a polyborosiloxane paint prepared by mixing polyborosiloxane [14] and an organic solvent. This invention relates to a heat-resistant antifouling paint. Note that 1 part of the paint in the present invention is based on the nonvolatile content at 300°C.
本発明の耐熱性防汚塗料は、ポリボロシロキサン塗料を
用いることにより耐熱性、耐湿性に優れ、ざらにフン素
変性シリコーンワニスを併用するので防汚性を大幅に向
上させろことができる。The heat-resistant antifouling paint of the present invention has excellent heat resistance and moisture resistance by using a polyborosiloxane paint, and the use of a fluorine-modified silicone varnish can significantly improve the antifouling property.
本発明のポリボロシロキサン塗料には、主鎖にＢ、Ｓｉ
等の元素を持ち、測鎖にメチル基、フェニル基等の有機
基を有する公知のポリボロシロキサン樹脂ｌ脂と、Ｎ−
メチル−２−ピロリドン等の有Ｉｌｌ ｉｎ剤とを例え
ば５：４の比で混合したものを用いろことができる０本
発明に使用できろポリボロシロキサン樹脂の構造式の一
例を以下に示す。The polyborosiloxane paint of the present invention has B and Si in the main chain.
A well-known polyborosiloxane resin having elements such as, and organic groups such as methyl group and phenyl group in the chain, and N-
An example of the structural formula of a polyborosiloxane resin that can be used in the present invention is shown below.
ポリボロシロキサン塗料は、約３００℃以１の温度て焼
成するとその有機基が脱罷しセラミック化が進行して、
極めて優れた耐熱性を示す。When polyborosiloxane paint is fired at a temperature of about 300°C or higher, its organic groups are removed and ceramicization progresses.
Shows extremely excellent heat resistance.
本発明におけるフッ素変性シリコーンワニスは、変性用
シリコーンワニスにフッ素樹脂を反応させたものであり
、シリコーンワニスの耐熱性とフッ素樹脂の防汚性、離
形性等の特性を（ｌｔせ持つ。また、その配合量はポリ
ボロシロキサン塗￥４１００重量部に対して２〜Ｉ ０
ｍｍ部、さらに望ましくは３〜５重量部である。２重Ｆ
ＪＬ、ｌｌ！以下では防汚性の効果が少なく、１０＠量
部を越えると得られろ塗料の耐熱性が低下する。The fluorine-modified silicone varnish of the present invention is a product obtained by reacting a fluorine-containing silicone varnish with a fluororesin, and has the heat resistance of a silicone varnish and the antifouling properties and mold release properties of a fluororesin. , the blending amount is 2 to I0 per ¥4,100 parts by weight of polyborosiloxane coating.
mm parts, more preferably 3 to 5 parts by weight. Double F
JL,ll! If the amount is less than 10 parts, the antifouling effect will be small, and if it exceeds 10 parts, the heat resistance of the resulting paint will decrease.
本発明の耐熱性防りち塗料は、上述のポリボロシロキサ
ン塗料とフッ素変性シリコーンワニスを攪拌機で混合し
て得られろ。The heat-resistant anti-stick paint of the present invention can be obtained by mixing the above-mentioned polyborosiloxane paint and fluorine-modified silicone varnish using a stirrer.
なお１本発明おいては上述の成分の曲に、金属酸（ヒ物
、ガラス粉末、四フソイヒエチレン粉末等を加えて、耐
熱性や防汚性をざらに向上させることもできる。これら
の充填剤を加える時は、ミキサー等で１時間程度Ｐ＆拌
する。In addition, in the present invention, heat resistance and antifouling properties can be roughly improved by adding metal acids (arsenic acid, glass powder, tetrafluoroethylene powder, etc.) to the above-mentioned ingredients.These fillers When adding, mix with a mixer for about 1 hour.
このようにして得られた耐熱性防ＬＴ５塗料をガラス板
や金属基を才等の基材に常法により塗布し、３００℃程
度の温度で焼成することにより、耐熱性と防汚性を有し
、耐１皇性に優れ、ガラス基材に対する密着性も良好な
塗膜を製造することができる。The heat-resistant and antifouling LT5 paint obtained in this way is applied to a substrate such as a glass plate or a metal base by a conventional method and baked at a temperature of about 300°C, thereby achieving heat resistance and antifouling properties. Moreover, it is possible to produce a coating film that has excellent resistance to corrosion and has good adhesion to glass substrates.
（実施例） 本発明の実施例について説明する。(Example) Examples of the present invention will be described.
実施例１〜４
ボリボａｙａキサン樹ｆｆ１１００ｆＬｔＦｉＢをＮ−
メチル−２−ピロリドン８０重量部に溶解させて。Examples 1 to 4 N-
Dissolved in 80 parts by weight of methyl-2-pyrrolidone.
不揮発分４８％のポリボロシロキサン塗料を得た。A polyborosiloxane paint with a non-volatile content of 48% was obtained.
次いでこのポリボロシロキサン塗料にフッ素変性シリコ
ーンワニスとしてＹ−２１（信越化学工業株式会社製
商品名）を表に示す割合で配合し、攪拌して耐熱性防汚
塗料を得た。Next, this polyborosiloxane paint was coated with Y-21 (manufactured by Shin-Etsu Chemical Co., Ltd.) as a fluorine-modified silicone varnish.
(trade name) in the proportions shown in the table and stirred to obtain a heat-resistant antifouling paint.
得られた耐熱性防汚塗料を厚さ０．６ｍｍのステンレス
板（ＳＵＳ４３０）ｆ；［布し、３５０’ＣＸ３０分填
成して、厚さ２０ Ｂ ｍの塗膜を形成した。The obtained heat-resistant antifouling paint was applied to a stainless steel plate (SUS430) with a thickness of 0.6 mm and filled with 350'CX for 30 minutes to form a coating film with a thickness of 20 Bm.
得られた塗膜を用いて、次の試験を行った。The following tests were conducted using the obtained coating film.
耐熱性は、！ｊ！ＩＩに１−四方のマス目を１００マス
劾み、３００１．”、 Ｘ Ｉ ６８時間加熱７層にテ
ープテスト（片面に粘着性を有するテープをＬｉ膜に貼
りつけた後はがす）シ、９％存マス目数を調べた。耐湿
性は、得られた塗膜の硬度と、相対湿度９５％の雰囲ス
下で６０℃×２４時間後の硬度を鉛筆ひっかき硬度で示
した。防汚性は、億膜上ベアスフアルドをのせ１５０℃
Ｘ３０分加熱後の状態を調べ、アスファルトの跡が残ら
ずに除去できたものを０、少量の跡が残ったものを△、
除去できなかったものをＸとした。また、耐屈曲性は、
基を才を６ ｍ ｍ直径の巻枠で１８０′の折曲げを１
チー）た時のクラックの有−を調べた。Heat resistance! j! Fill II with 100 1-square squares, 3001. ”, X I 7 layers heated for 68 hours were subjected to a tape test (apply a tape with adhesive on one side to the Li film and then peeled off) to examine the number of squares remaining at 9%. Moisture resistance was determined by The hardness of the film and the hardness after 24 hours at 60°C in an atmosphere with relative humidity of 95% are shown by pencil scratch hardness.The stain resistance was determined by applying Beersfald on the film at 150°C.
X Check the condition after heating for 30 minutes, 0 if the asphalt was removed without leaving any traces, △ if a small amount of asphalt remained.
Those that could not be removed were marked as X. In addition, the bending resistance is
180' bend with a 6 mm diameter winding frame.
The presence of cracks was investigated when
比較例１〜２
表に示す配合で、実施例と同様にして塗膜を彫成し、同
様に試験した。Comparative Examples 1-2 Coating films were carved in the same manner as in the examples using the formulations shown in the table, and tested in the same manner.
耐屈曲性は、実施例、比較例のいずれにもクラックが発
生しなかった。As for the bending resistance, no cracks occurred in any of the examples and comparative examples.
（以下余白）
（発明の効果）
以上本発明の耐熱性防汚塗料による塗膜は、優れた１Ｉ
ｔｉ４熱性と耐γ寥性を有しているのみならず、防汚性
を大幅に向上させているので、耐熱性と防汚性が要求さ
れる用途に幅広く適用することができろ。(The following is a blank space) (Effects of the invention) As described above, the coating film made of the heat-resistant antifouling paint of the present invention has an excellent 1I
It not only has ti4 heat resistance and gamma resistance, but also has significantly improved stain resistance, so it can be widely applied to applications that require heat resistance and stain resistance.
Claims (1)
てなるポリボロシロキサン塗料１００重量部に、フッ素
変性シリコーンワニス２〜１０重量部を混合してなるこ
とを特徴とする耐熱性防汚塗料。(1) A heat-resistant antifouling paint characterized by mixing 2 to 10 parts by weight of a fluorine-modified silicone varnish with 100 parts by weight of a polyborosiloxane paint made by mixing a polyborosiloxane resin and an organic solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33506088A JPH02173171A (en) | 1988-12-27 | 1988-12-27 | Heat-resistant antifouling coating compound |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33506088A JPH02173171A (en) | 1988-12-27 | 1988-12-27 | Heat-resistant antifouling coating compound |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02173171A true JPH02173171A (en) | 1990-07-04 |
Family
ID=18284307
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP33506088A Pending JPH02173171A (en) | 1988-12-27 | 1988-12-27 | Heat-resistant antifouling coating compound |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02173171A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008138266A1 (en) * | 2007-05-16 | 2008-11-20 | Qingjin Zeng | High temperature enviromental-friendly and energy-saving coating for metal |
-
1988
- 1988-12-27 JP JP33506088A patent/JPH02173171A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008138266A1 (en) * | 2007-05-16 | 2008-11-20 | Qingjin Zeng | High temperature enviromental-friendly and energy-saving coating for metal |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS60118761A (en) | Organopolysiloxane mold-releasing paint and painted matter | |
| JPH032889B2 (en) | ||
| US7687150B2 (en) | Thermal barrier composition | |
| JPS62232471A (en) | Production of release paint and release film | |
| US7531242B2 (en) | Silicone-coated architectural glass | |
| JPS58117252A (en) | Method of bridging organopolysiloxane not containing si-h bondage nor activated ethylenic unsaturated organic group | |
| JPH02173171A (en) | Heat-resistant antifouling coating compound | |
| JP3245522B2 (en) | Paint composition | |
| JPS6254768A (en) | Heat-resistant paint | |
| JPH0765004B2 (en) | Heat and corrosion resistant paint | |
| JPS63291962A (en) | Heat-resistant member | |
| JP2006307124A (en) | Ordinary temperature-curable inorganic coating film and coating agent | |
| US3649307A (en) | Binder for zinc-rich paint | |
| JPH0335074A (en) | Manufacture of coating material based on polysiloxane and vitreous coating | |
| JPS62220565A (en) | Coating material composition for heat control | |
| JPH01104670A (en) | Heat-resistant paint | |
| JPS6248773A (en) | Heat-resistant coating material | |
| JP3140722B2 (en) | Butyl rubber adhesive composition and adhesive tape or sheet using the same | |
| JPS6324554B2 (en) | ||
| JPH01201378A (en) | Heat-resistant stainproof paint | |
| JPH0538480A (en) | Forming method for heat-resistant insulated coating film | |
| JPH0292969A (en) | Heat-resistant insulating paint | |
| JPH02202960A (en) | Heat-resistant antifouling coating | |
| KR950011507B1 (en) | In arganic coating composition | |
| JPH082940A (en) | Water-repellent treating agent for glass and treating method using the same |