JPH0551887B2 - - Google Patents
Info
- Publication number
- JPH0551887B2 JPH0551887B2 JP62170794A JP17079487A JPH0551887B2 JP H0551887 B2 JPH0551887 B2 JP H0551887B2 JP 62170794 A JP62170794 A JP 62170794A JP 17079487 A JP17079487 A JP 17079487A JP H0551887 B2 JPH0551887 B2 JP H0551887B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- silver halide
- groups
- general formula
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 silver halide Chemical class 0.000 claims description 68
- 229910052709 silver Inorganic materials 0.000 claims description 31
- 239000004332 silver Substances 0.000 claims description 31
- 239000000839 emulsion Substances 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 24
- 125000000217 alkyl group Chemical group 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 18
- 230000035945 sensitivity Effects 0.000 claims description 15
- 125000003118 aryl group Chemical group 0.000 claims description 11
- 230000001235 sensitizing effect Effects 0.000 claims description 11
- 125000003342 alkenyl group Chemical group 0.000 claims description 7
- 230000003595 spectral effect Effects 0.000 claims description 6
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000003277 amino group Chemical group 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 125000000565 sulfonamide group Chemical group 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 19
- 238000000034 method Methods 0.000 description 17
- 239000000975 dye Substances 0.000 description 16
- 108010010803 Gelatin Proteins 0.000 description 12
- 239000008273 gelatin Substances 0.000 description 12
- 229920000159 gelatin Polymers 0.000 description 12
- 235000019322 gelatine Nutrition 0.000 description 12
- 235000011852 gelatine desserts Nutrition 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- 239000000084 colloidal system Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 239000004065 semiconductor Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 239000002202 Polyethylene glycol Substances 0.000 description 6
- 206010070834 Sensitisation Diseases 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 6
- 230000008313 sensitization Effects 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 4
- 229920003171 Poly (ethylene oxide) Chemical class 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- ODIRBFFBCSTPTO-UHFFFAOYSA-N 1,3-selenazole Chemical compound C1=C[se]C=N1 ODIRBFFBCSTPTO-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 229910021607 Silver chloride Inorganic materials 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 230000005070 ripening Effects 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 2
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 229910021612 Silver iodide Inorganic materials 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- JEHKKBHWRAXMCH-UHFFFAOYSA-N benzenesulfinic acid Chemical compound O[S@@](=O)C1=CC=CC=C1 JEHKKBHWRAXMCH-UHFFFAOYSA-N 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 150000002344 gold compounds Chemical class 0.000 description 2
- CPBQJMYROZQQJC-UHFFFAOYSA-N helium neon Chemical compound [He].[Ne] CPBQJMYROZQQJC-UHFFFAOYSA-N 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 2
- 229940045105 silver iodide Drugs 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- 125000004964 sulfoalkyl group Chemical group 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- LUMLZKVIXLWTCI-NSCUHMNNSA-N (e)-2,3-dichloro-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Cl)=C(/Cl)C=O LUMLZKVIXLWTCI-NSCUHMNNSA-N 0.000 description 1
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical class C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 1
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical compound C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical class C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- YLVACWCCJCZITJ-UHFFFAOYSA-N 1,4-dioxane-2,3-diol Chemical compound OC1OCCOC1O YLVACWCCJCZITJ-UHFFFAOYSA-N 0.000 description 1
- SIQZJFKTROUNPI-UHFFFAOYSA-N 1-(hydroxymethyl)-5,5-dimethylhydantoin Chemical compound CC1(C)N(CO)C(=O)NC1=O SIQZJFKTROUNPI-UHFFFAOYSA-N 0.000 description 1
- GGZHVNZHFYCSEV-UHFFFAOYSA-N 1-Phenyl-5-mercaptotetrazole Chemical compound SC1=NN=NN1C1=CC=CC=C1 GGZHVNZHFYCSEV-UHFFFAOYSA-N 0.000 description 1
- FYBFGAFWCBMEDG-UHFFFAOYSA-N 1-[3,5-di(prop-2-enoyl)-1,3,5-triazinan-1-yl]prop-2-en-1-one Chemical compound C=CC(=O)N1CN(C(=O)C=C)CN(C(=O)C=C)C1 FYBFGAFWCBMEDG-UHFFFAOYSA-N 0.000 description 1
- LBKZKSWKRXFZLR-UHFFFAOYSA-N 1-ethenylsulfonylpropan-2-ol Chemical compound CC(O)CS(=O)(=O)C=C LBKZKSWKRXFZLR-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- JAAIPIWKKXCNOC-UHFFFAOYSA-N 1h-tetrazol-1-ium-5-thiolate Chemical class SC1=NN=NN1 JAAIPIWKKXCNOC-UHFFFAOYSA-N 0.000 description 1
- YKUDHBLDJYZZQS-UHFFFAOYSA-N 2,6-dichloro-1h-1,3,5-triazin-4-one Chemical compound OC1=NC(Cl)=NC(Cl)=N1 YKUDHBLDJYZZQS-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- OCVLSHAVSIYKLI-UHFFFAOYSA-N 3h-1,3-thiazole-2-thione Chemical class SC1=NC=CS1 OCVLSHAVSIYKLI-UHFFFAOYSA-N 0.000 description 1
- GIQKIFWTIQDQMM-UHFFFAOYSA-N 5h-1,3-oxazole-2-thione Chemical compound S=C1OCC=N1 GIQKIFWTIQDQMM-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920008347 Cellulose acetate propionate Polymers 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical class OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- QPFYXYFORQJZEC-FOCLMDBBSA-N Phenazopyridine Chemical compound NC1=NC(N)=CC=C1\N=N\C1=CC=CC=C1 QPFYXYFORQJZEC-FOCLMDBBSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N Taurine Natural products NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000005041 acyloxyalkyl group Chemical group 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 229940023476 agar Drugs 0.000 description 1
- 235000010419 agar Nutrition 0.000 description 1
- 238000007754 air knife coating Methods 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 1
- 125000005078 alkoxycarbonylalkyl group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 229910001864 baryta Inorganic materials 0.000 description 1
- 150000001556 benzimidazoles Chemical class 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 125000004181 carboxyalkyl group Chemical group 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 229920003090 carboxymethyl hydroxyethyl cellulose Polymers 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229920006265 cellulose acetate-butyrate film Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 125000000068 chlorophenyl group Chemical group 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- WYYQVWLEPYFFLP-UHFFFAOYSA-K chromium(3+);triacetate Chemical compound [Cr+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WYYQVWLEPYFFLP-UHFFFAOYSA-K 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 125000005594 diketone group Chemical group 0.000 description 1
- 150000002012 dioxanes Chemical class 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 108010025899 gelatin film Proteins 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- AKCUHGBLDXXTOM-UHFFFAOYSA-N hydroxy-oxo-phenyl-sulfanylidene-$l^{6}-sulfane Chemical class SS(=O)(=O)C1=CC=CC=C1 AKCUHGBLDXXTOM-UHFFFAOYSA-N 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 125000001841 imino group Chemical group [H]N=* 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- ZAKLKBFCSHJIRI-UHFFFAOYSA-N mucochloric acid Natural products OC1OC(=O)C(Cl)=C1Cl ZAKLKBFCSHJIRI-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 description 1
- 229950005308 oxymethurea Drugs 0.000 description 1
- CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 229940070891 pyridium Drugs 0.000 description 1
- HBCQSNAFLVXVAY-UHFFFAOYSA-N pyrimidine-2-thiol Chemical class SC1=NC=CC=N1 HBCQSNAFLVXVAY-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007763 reverse roll coating Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical group 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 235000017709 saponins Nutrition 0.000 description 1
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229940032147 starch Drugs 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- JJJPTTANZGDADF-UHFFFAOYSA-N thiadiazole-4-thiol Chemical class SC1=CSN=N1 JJJPTTANZGDADF-UHFFFAOYSA-N 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 125000005323 thioketone group Chemical group 0.000 description 1
- NBOMNTLFRHMDEZ-UHFFFAOYSA-N thiosalicylic acid Chemical compound OC(=O)C1=CC=CC=C1S NBOMNTLFRHMDEZ-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/28—Sensitivity-increasing substances together with supersensitising substances
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
Description
(A) ç£æ¥äžã®å©çšåé
æ¬çºæã¯ãèµ€å€åãåå
å¢æãããããã²ã³å
éåçæå ææã«é¢ãããã®ã§ããã (B) åŸæ¥æè¡åã³ãã®åé¡ç¹ è¿å¹Žã®è¿ éãªæ å ±äŒéã·ã¹ãã ã®çºéã«äŒŽã€
ãŠãããã²ã³åéåçæå ææã¯ãçã é«æ床ã
èŠæ±ãããããã«ãªã€ãŠãããäŸãã°ãé»åèšç®
æ©ããã¢ãŠãããããããæ å ±ãçŽã¡ã«æåãŸã
ã¯å³åœ¢ãšããŠé°æ¥µç·ç®¡ã«ãã衚瀺ããé«é床åç
æ€åã·ã¹ãã ãæ°èåçš¿ãé éå°ãžéããã«éã
ããã®ãã¬ã¹ãã¢ã¯ã·ããªã·ã¹ãã ãªã©ã§ããã ãã®ãããªçšéã®ããã²ã³åéåçæå ææã«
èŠæ±ãããç¹æ§ãšããŠã¯ãé°æ¥µç·ç®¡ïŒCRTïŒãã
ãªãŠã âããªã³ã¬ã¹çã®ã¬ãŒã¶ãŒãçºå ãã€ãªãŒ
ãïŒLEDïŒãªã©ã®å æºã§10-4ç§ä»¥äžã®ããããã
é«ç §åºŠçæéé²å ïŒéå é²å ãšããïŒã«å¯ŸããŠé«
æ床ã§ãããããã«é«ã³ã³ãã©ã¹ããé«è§£ååãª
ã©ã®ç¹æ§ãå¿ èŠãšãããã ããªãŠã âããªã³ãã¢ã«ãŽã³ãªã©ã®ã¬ãŒã¶ãŒå
æºãã¹ãã€ãæ¹åŒã®å æºãšããŠçšããæ¹æ³ã¯ãé«
åºåãåŸãããããè£ çœ®ã倧åã§é«äŸ¡ã§ããã
ãšãæ¶è²»é»åå¹çãäœãçã®æ¬ ç¹ããããããã«
察ããŠåå°äœã¬ãŒã¶ãŒã¯ãå°åã§å®äŸ¡ãå€èª¿ã容
æãé·å¯¿åœã§ããçã®å©ç¹ãæããŠãããåå°äœ
ã¬ãŒã¶ãŒã«ã¯ãGaïŒAsïŒïŒ°ïŒGaïŒAlïŒAsïŒ
GaïŒAsïŒInïŒïŒ°ïŒInïŒAsãªã©ã®ç³»ã®åå°äœãçš
ãããããã®ã¬ãŒã¶ãŒå ã®æ³¢é·ã¯äžè¬ã«700nmã
ãé·æ³¢ã§ããšãã«750nmããé·æ³¢ã®ãã®ãå€ãã ãã®ããæããã»ãŒãã©ã€ãã䜿çšã§ããã®
ã§ãåæ±ãäœæ¥æ§ãè¯ããªããšããå©ç¹ãæããŠ
ãããããããªãããèµ€å€å çšã®æå ææã¯ãäž
è¬ã«ãæ床ãå åã«é«ããªããä¿åæ§ãæªãçã®
åé¡ãæããŠããããããŸã§çš®ã ã®ææ¡ããããŠ
ãããäŸãã°ãåå å¢æè²çŽ ã®ä»ã«ç¬¬äºã®ããçš®
ã®ç¹ç°çã«éžæãããææ©ååç©ãå ããããšã«
ããåå æ床ãèããäžæããããããã匷è²å¢
æå¹æãšåŒã°ããæè¡ã®ææ¡ããããäŸãã°ç±³åœ
ç¹èš±ç¬¬2785058å·ãå第3695888å·çã«èšèŒã®ããª
ã¢ãžã³èªå°äœãç±³åœç¹èš±ç¬¬3457078å·ã«èšèŒã®é»
æ°é°æ§åºãæããã¡ã«ã«ããååç©ãç¹éæ51â
81613å·ã«èšèŒã®ãã³ãŸããªã¢ãŸãŒã«èªå°äœãç¹
éæ59â191032å·ã«èšèŒã®åçŽå¡©ããã®ä»ç¹éæ
61â69063å·ãå61â27884å·ãçã ãåèã«ãã
ããšãã§ããããããããããã®åŒ·è²å¢ææè¡
ã¯ãå¢æãååã§ãªããã«ããªãå¢å ãããä¿å
æ§ãæªããããçã®äžæºè¶³ãªçµæãäžãããã®ã
å€ãã®ãå®æ ã§ããã æ¬çºæè çã¯ããã®ãããªåé¡ã®ãªãåå°äœã¬
ãŒã¶ãŒå çšã®ããã²ã³åéåçæå ææãéæç
究ããçµæãããçš®ã®ååç©ã®çµã¿åããããã®
ç®çã«æ¥µããŠæå¹ã§ããããšãèŠåºããã (C) çºæã®ç®ç æ¬çºæã®ç®çã¯ã700nmããšãã«750nm以äžã®
åå°äœã¬ãŒã¶ãŒã®åŠãèµ€å€åã®æ床ãé«ãããã
ããã²ã³åéåçæå ææãæäŸããããšã§ã
ãã æ¬çºæã®å¥ã®ç®çã¯ãã«ããªãä¿åæ§çã«åé¡
ããªããèµ€å€åã®æ床ãé«ããããããã²ã³åé
åçæå ææãæäŸããããšã§ããã (D) çºæã®æ§æ æ¬çºæã®äžèšç®çã¯ã700nm以äžã«æ¥µå€§åå æ
床ãæããå¢æè²çŽ ã§å åŠå¢æããããã²ã³åé
ä¹³å€å±€ãæããæå ææã«ãããŠã該乳å€å±€ã«äž
èšäžè¬åŒïŒïŒåã³äžè¬åŒïŒïŒã§è¡šããããå
åç©ãããããå°ãªããšãïŒã€å«æããããšãç¹
城ãšããããã²ã³åéåçæå ææã«ãã€ãŠéæ
ãããã äžè¬åŒïŒïŒ ïŒåŒäžãR1åã³R2ã¯ãããããæ°ŽçŽ ååãã¢ã«
ãã«åºãã¢ãªãŒã«åºãã¢ã©ã«ãã«åºãã¢ã«ã±ãã«
åºãã¢ããåºãã¢ã·ã«ã¢ããåºãã¹ã«ãã³ã¢ãã
åºãè¡šãããR1åã³R2ã®ççŽ æ°ã®åã¯ïŒä»¥äžã§
ãããïŒ äžè¬åŒïŒïŒ ïŒåŒäžãR3ã¯ãççŽ ååïŒå以äžãæããã¢ã«
ãã«åºãã¢ãªãŒã«åºãè¡šãããïŒ ä»¥äžã«æ¬çºæã«çšããããäžè¬åŒïŒïŒã®åå
ç©ã®å ·äœäŸã瀺ããäœããäžè¬åŒïŒïŒã®R1å
ã³R2ã®ã¿ã瀺ããŠããã
éåçæå ææã«é¢ãããã®ã§ããã (B) åŸæ¥æè¡åã³ãã®åé¡ç¹ è¿å¹Žã®è¿ éãªæ å ±äŒéã·ã¹ãã ã®çºéã«äŒŽã€
ãŠãããã²ã³åéåçæå ææã¯ãçã é«æ床ã
èŠæ±ãããããã«ãªã€ãŠãããäŸãã°ãé»åèšç®
æ©ããã¢ãŠãããããããæ å ±ãçŽã¡ã«æåãŸã
ã¯å³åœ¢ãšããŠé°æ¥µç·ç®¡ã«ãã衚瀺ããé«é床åç
æ€åã·ã¹ãã ãæ°èåçš¿ãé éå°ãžéããã«éã
ããã®ãã¬ã¹ãã¢ã¯ã·ããªã·ã¹ãã ãªã©ã§ããã ãã®ãããªçšéã®ããã²ã³åéåçæå ææã«
èŠæ±ãããç¹æ§ãšããŠã¯ãé°æ¥µç·ç®¡ïŒCRTïŒãã
ãªãŠã âããªã³ã¬ã¹çã®ã¬ãŒã¶ãŒãçºå ãã€ãªãŒ
ãïŒLEDïŒãªã©ã®å æºã§10-4ç§ä»¥äžã®ããããã
é«ç §åºŠçæéé²å ïŒéå é²å ãšããïŒã«å¯ŸããŠé«
æ床ã§ãããããã«é«ã³ã³ãã©ã¹ããé«è§£ååãª
ã©ã®ç¹æ§ãå¿ èŠãšãããã ããªãŠã âããªã³ãã¢ã«ãŽã³ãªã©ã®ã¬ãŒã¶ãŒå
æºãã¹ãã€ãæ¹åŒã®å æºãšããŠçšããæ¹æ³ã¯ãé«
åºåãåŸãããããè£ çœ®ã倧åã§é«äŸ¡ã§ããã
ãšãæ¶è²»é»åå¹çãäœãçã®æ¬ ç¹ããããããã«
察ããŠåå°äœã¬ãŒã¶ãŒã¯ãå°åã§å®äŸ¡ãå€èª¿ã容
æãé·å¯¿åœã§ããçã®å©ç¹ãæããŠãããåå°äœ
ã¬ãŒã¶ãŒã«ã¯ãGaïŒAsïŒïŒ°ïŒGaïŒAlïŒAsïŒ
GaïŒAsïŒInïŒïŒ°ïŒInïŒAsãªã©ã®ç³»ã®åå°äœãçš
ãããããã®ã¬ãŒã¶ãŒå ã®æ³¢é·ã¯äžè¬ã«700nmã
ãé·æ³¢ã§ããšãã«750nmããé·æ³¢ã®ãã®ãå€ãã ãã®ããæããã»ãŒãã©ã€ãã䜿çšã§ããã®
ã§ãåæ±ãäœæ¥æ§ãè¯ããªããšããå©ç¹ãæããŠ
ãããããããªãããèµ€å€å çšã®æå ææã¯ãäž
è¬ã«ãæ床ãå åã«é«ããªããä¿åæ§ãæªãçã®
åé¡ãæããŠããããããŸã§çš®ã ã®ææ¡ããããŠ
ãããäŸãã°ãåå å¢æè²çŽ ã®ä»ã«ç¬¬äºã®ããçš®
ã®ç¹ç°çã«éžæãããææ©ååç©ãå ããããšã«
ããåå æ床ãèããäžæããããããã匷è²å¢
æå¹æãšåŒã°ããæè¡ã®ææ¡ããããäŸãã°ç±³åœ
ç¹èš±ç¬¬2785058å·ãå第3695888å·çã«èšèŒã®ããª
ã¢ãžã³èªå°äœãç±³åœç¹èš±ç¬¬3457078å·ã«èšèŒã®é»
æ°é°æ§åºãæããã¡ã«ã«ããååç©ãç¹éæ51â
81613å·ã«èšèŒã®ãã³ãŸããªã¢ãŸãŒã«èªå°äœãç¹
éæ59â191032å·ã«èšèŒã®åçŽå¡©ããã®ä»ç¹éæ
61â69063å·ãå61â27884å·ãçã ãåèã«ãã
ããšãã§ããããããããããã®åŒ·è²å¢ææè¡
ã¯ãå¢æãååã§ãªããã«ããªãå¢å ãããä¿å
æ§ãæªããããçã®äžæºè¶³ãªçµæãäžãããã®ã
å€ãã®ãå®æ ã§ããã æ¬çºæè çã¯ããã®ãããªåé¡ã®ãªãåå°äœã¬
ãŒã¶ãŒå çšã®ããã²ã³åéåçæå ææãéæç
究ããçµæãããçš®ã®ååç©ã®çµã¿åããããã®
ç®çã«æ¥µããŠæå¹ã§ããããšãèŠåºããã (C) çºæã®ç®ç æ¬çºæã®ç®çã¯ã700nmããšãã«750nm以äžã®
åå°äœã¬ãŒã¶ãŒã®åŠãèµ€å€åã®æ床ãé«ãããã
ããã²ã³åéåçæå ææãæäŸããããšã§ã
ãã æ¬çºæã®å¥ã®ç®çã¯ãã«ããªãä¿åæ§çã«åé¡
ããªããèµ€å€åã®æ床ãé«ããããããã²ã³åé
åçæå ææãæäŸããããšã§ããã (D) çºæã®æ§æ æ¬çºæã®äžèšç®çã¯ã700nm以äžã«æ¥µå€§åå æ
床ãæããå¢æè²çŽ ã§å åŠå¢æããããã²ã³åé
ä¹³å€å±€ãæããæå ææã«ãããŠã該乳å€å±€ã«äž
èšäžè¬åŒïŒïŒåã³äžè¬åŒïŒïŒã§è¡šããããå
åç©ãããããå°ãªããšãïŒã€å«æããããšãç¹
城ãšããããã²ã³åéåçæå ææã«ãã€ãŠéæ
ãããã äžè¬åŒïŒïŒ ïŒåŒäžãR1åã³R2ã¯ãããããæ°ŽçŽ ååãã¢ã«
ãã«åºãã¢ãªãŒã«åºãã¢ã©ã«ãã«åºãã¢ã«ã±ãã«
åºãã¢ããåºãã¢ã·ã«ã¢ããåºãã¹ã«ãã³ã¢ãã
åºãè¡šãããR1åã³R2ã®ççŽ æ°ã®åã¯ïŒä»¥äžã§
ãããïŒ äžè¬åŒïŒïŒ ïŒåŒäžãR3ã¯ãççŽ ååïŒå以äžãæããã¢ã«
ãã«åºãã¢ãªãŒã«åºãè¡šãããïŒ ä»¥äžã«æ¬çºæã«çšããããäžè¬åŒïŒïŒã®åå
ç©ã®å ·äœäŸã瀺ããäœããäžè¬åŒïŒïŒã®R1å
ã³R2ã®ã¿ã瀺ããŠããã
ãè¡šã
ãè¡šã
次ã«äžè¬åŒïŒïŒã®ååç©ã®å
·äœäŸã瀺ããäœ
ããR3ã®ã¿ã瀺ããŠããã
ããR3ã®ã¿ã瀺ããŠããã
ãè¡šã
ãè¡šã
ãŸããæ¯èŒã«çšããååç©ã以äžã«ç€ºããŠã
ãã ïŒæ¯èŒïœïŒ ïŒæ¯èŒïœïŒ ïŒæ¯èŒïœïŒ æ¬çºæã«çšããããäžè¬åŒïŒïŒåã³äžè¬åŒ
ïŒïŒã®ååç©ã¯ãããã²ã³åéä¹³å€ã®å¡åžãŸã§
ã®ä»»æã®ææã«ãããããïŒçš®ãããã¯ïŒçš®ä»¥äž
ãæ·»å ããã®ã§ããããå Žåã«ãã€ãŠã¯å¡åžæã«
é£æ¥ãã芪氎æ§ã³ãã€ãå±€ããæ¡æ£ãããŠãã
ãã æ·»å éã¯ãããããããã²ã³åéïŒã¢ã«åœãïŒ
Ã10-3ããªã¢ã«ãïŒããªã¢ã«ã奜ãŸããã¯ïŒÃ
10-2ããªã¢ã«ãïŒããªã¢ã«ã®ç¯å²ã§ãããã¢ã«æ¯
ãšããŠïŒïŒïŒãïŒïŒïŒã®ç¯å²ã§ä»»æã«å€åããã
ããšãåºæ¥ããæ·»å ã«éããŠã¯ãé©åœãªæº¶åªãã
ãšãã°ã¡ã¿ããŒã«ããšã¿ããŒã«ããããããŒã«ã
ã¢ã»ãã³ããžã¡ãã«ãã«ã ã¢ããçã®æº¶æ¶²ãšããŠ
æ·»å ããã®ãæå©ã§ããããŸããäžè¬åŒïŒïŒã®
ååç©ãšäžè¬åŒïŒïŒã®ååç©ã¯ãïŒã€ã®æº¶æ¶²ãš
ããŠæ·»å ããŠãããããããã¯å¥ã ã®æº¶æ¶²ãšããŠ
å¥ã ã®ææã«æ·»å ããŠãããã æ¬çºæã«çšãããã700nmããé·æ³¢é·é åã«æ¥µ
倧åå æ床ãæããå¢æè²çŽ ã¯ãäŸãã°ç±³åœç¹èš±
第2095854å·ãå第2095856å·ãå第2955939å·ã
å第3482978å·ãå第3552974å·ãå第3573921å·ã
å第3582344å·ãå第3623881å·æ现æžçã«èšèŒã
ãããã®ã§ããããšãåºæ¥ãã 奜ãŸããã¯ãäŸãã°æ¬¡ã®äžè¬åŒïŒïŒãïŒïŒ
ã§è¡šããããè²çŽ ãçšããããã äžè¬åŒïŒïŒãïŒïŒã«æŒãŠãZ1åã³Z2ã¯ã
åã åäžã§ãç°ãªã€ãŠããŠããããããããïŒå¡
ãŸãã¯ïŒå¡å«çªçŽ è€çŽ ç°ã圢æããã®ã«å¿ èŠãªå
å矀ãè¡šãããR1åã³R2ã¯ãåã åäžã§ãç°ãª
ã€ãŠããŠããããããããã¢ã«ãã«åºãã¢ã«ã±ã
ã«åºãè¡šãããR3ã¯ãã¢ã«ãã«åºãã¢ã«ã±ãã«
åºãã¢ãªãŒã«åºãè¡šãããR4ãR10ã¯ãåã åäž
ã§ãç°ãªã€ãŠããŠããããããããæ°ŽçŽ ååãã
ãã²ã³ååãã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã³ã
ã·åºãè¡šãããäœããR6ãšR7ãããã¯R8ãšR9ãš
ã¯äºã«é£çµããŠïŒå¡åã¯ïŒå¡ç°ã圢æããããšã
ã§ãããR11åã³R12ã¯ãåã åäžã§ãç°ãªã€ãŠ
ããŠããããããããã¢ã«ãã«åºãã¢ãªãŒã«åºã
è¡šãããR11ãšR12ãšã¯äºã«é£çµããŠïŒå¡åã¯ïŒ
å¡ç°ã圢æããããšãã§ãããã¯ãç¡«é»ååã
é žçŽ ååãâR13ïŒR13ã¯ã¢ã«ãã«åºïŒãè¡šã
ããã¯é žã¢ããªã³ãè¡šãããïœïŒïœïŒïœïŒïœå
ã³ïœã¯ããããïŒåã¯ïŒãè¡šããã Z1åã³Z2ã®å ·äœäŸãšããŠã¯ããã¢ãŸãŒã«ããã³
ãŸãã¢ãŸãŒã«ãããããïŒïŒïŒâαããã¢ãŸãŒ
ã«ãããããïŒïŒïŒâαããã¢ãŸãŒã«ãããã
ãïŒïŒïŒâαããã¢ãŸãŒã«ãã»ã¬ããŸãŒã«ããã³
ãŸã»ã¬ããŸãŒã«ãããããïŒïŒïŒâαãã»ã¬ããŸ
ãŒã«ãããããïŒïŒïŒâαãã»ã¬ããŸãŒã«ããªã
ãµãŸãŒã«ããã³ãŸãªããµãŸãŒã«ãããããïŒïŒïŒ
âαããªããµãŸãŒã«ãããããïŒïŒïŒâαããªã
ãµãŸãŒã«ãããããïŒïŒïŒâαããªããµãŸãŒã«ã
ïŒâãããªã³ãïŒâãããªã³ãïŒïŒïŒâãžã¢ã«ã
ã«ã€ã³ãã¬ãã³ãã€ãããŸãŒã«ããã³ãºã€ãããŸ
ãŒã«ãããããïŒïŒïŒâαãã€ãããŸãŒã«ãããª
ãžã³çã®å«çªçŽ è€çŽ ç°ãæããããšãã§ãããã
ããã®è€çŽ ç°ã¯ãã¢ã«ãã«åºïŒäŸãã°ãã¡ãã«ã
ãšãã«ãããã«ãããªãã«ãªãã¡ãã«çïŒãã¢ãª
ãŒã«åºïŒäŸãã°ãããšãã«ãããªã«çïŒãããã
ãã·åºãã¢ã«ã³ãã·åºïŒäŸãã°ãã¡ããã·ããšã
ãã·ããããã·çïŒãã«ã«ããã·åºãã¢ã«ã³ãã·
ã«ã«ããã«åºïŒäŸãã°ãã¡ããã·ã«ã«ããã«ããš
ããã·ã«ã«ããã«çïŒãããã²ã³ååïŒäŸãã°ã
ããçŽ ãå¡©çŽ ãèçŽ ãæ²çŽ ïŒãã¢ã©ã«ãã«åºïŒäŸ
ãã°ããã³ãžã«ãããšããã«çïŒãã·ã¢ãåºãã¢
ã«ã±ãã«åºïŒäŸãã°ãã¢ãªã«çïŒçã®çœ®æåºãïŒ
ãŸãã¯ïŒä»¥äžæããŠãããã R1ïŒR2ã«æŒãŠãã¢ã«ãã«åºãšããŠã¯ãã¡ãã«ã
ãšãã«ããããã«ãããã«çã®äœçŽã¢ã«ãã«åºã
βâããããã·ãšãã«ãγâããããã·ãããã«
çã®ããããã·ã¢ã«ãã«åºãβâã¡ããã·ãšã
ã«ãγâã¡ããã·ãããã«çã®ã¢ã«ã³ãã·ã¢ã«ã
ã«åºãβâã¢ã»ããã·ãšãã«ãγâã¢ã»ããã·ã
ããã«ãβâãã³ãŸã€ã«ãªãã·ãšãã«çã®ã¢ã·ã«
ãªãã·ã¢ã«ãã«åºãã«ã«ããã·ã¡ãã«ãβâã«ã«
ããã·ãšãã«çã®ã«ã«ããã·ã¢ã«ãã«åºãã¡ãã
ã·ã«ã«ããã«ã¡ãã«ããšããã·ã«ã«ããã«ã¡ã
ã«ãβâãšããã·ã«ã«ããã«ãšãã«çã®ã¢ã«ã³ã
ã·ã«ã«ããã«ã¢ã«ãã«åºãβâã¹ã«ããšãã«ãγ
âã¹ã«ããããã«ããâã¹ã«ãããã«çã®ã¹ã«ã
ã¢ã«ãã«åºããã³ãžã«ãããšããã«ãã¹ã«ããã³
ãžã«çã®ã¢ã©ã«ãã«åºçãã¢ã«ã±ãã«åºãšããŠã¯
ã¢ãªã«çãæããããã R3ãšããŠã¯ãäžèšR1ïŒR2ã§è¿°ã¹ããããªã¢ã«
ãã«åºãã¢ã«ã±ãã«åºããªãã³ã«ããšãã«ãããª
ã«ãã¡ããã·ããšãã«ãã¯ããããšãã«ãããã
ã«çã®ã¢ãªãŒã«åºãæããããã R4ãR10ã¯ãæ°ŽçŽ ååãããã²ã³ååïŒäŸãã°
å¡©çŽ ãèçŽ ãæ²çŽ ãããçŽ ïŒãR1ïŒR2ã§è¿°ã¹ãã
ããªã¢ã«ãã«åºãã¢ãªãŒã«åºãããã¯R1ïŒR2ã§
è¿°ã¹ããããªã¢ã«ãã«ããã€ã¢ã«ã³ãã·åºïŒããª
ãã¡OR1åºïŒã§ãããR6ãšR7ãããã¯R8ãšR9ãš
ã§åœ¢æãããïŒå¡ãŸãã¯ïŒå¡ç°ã¯ãäœçŽã¢ã«ãã«
åºçã§çœ®æãããŠããŠããããR11åã³R12ã¯ã
R1ïŒR2ã§è¿°ã¹ããããªã¢ã«ãã«åºãã¢ãªãŒã«åº
ãè¡šãããR11ãšR12ãšã¯äºã«é£çµããŠïŒå¡åã¯
ïŒå¡ç°ã圢æããããšãã§ãããR13ã¯R1ïŒR2ã§
è¿°ã¹ããããªã¢ã«ãã«åºãæããããã ã®é žã¢ããªã³ãšããŠã¯ãã¡ãã«ç¡«é žããšãã«
ç¡«é žçã®ã¢ã«ãã«ç¡«é žã€ãªã³ãããªã·ã¢ã³é žã€ãª
ã³ããã«ãšã³ã¹ã«ãã³é žã€ãªã³ãå¡©çŽ ãèçŽ ãæ²
çŽ çã®ããã²ã³ã€ãªã³ãéå¡©çŽ é žã€ãªã³çã§ã
ããè²çŽ ããã¿ã€ã³é¡äŒŒæ§é ããšãå Žåã«ã¯ååš
ããªãã æ¬çºæã«çšããããå¢æè²çŽ ã®å ·äœäŸã以äžã«
äŸç€ºããã æ¬çºæã«çšããããå¢æè²çŽ ã¯ãåœæ¥è ã«å ¬ç¥
ã®æ¹æ³ã§åæããããšãã§ãããããã²ã³åéä¹³
å€ã«æ·»å ããææã¯ãä¹³å€ãå¡åžãããŸã§ã®ä»»æ
ã®ææã§ããããšãã§ããåèšäžè¬åŒïŒïŒåã³
äžè¬åŒïŒïŒã®ååç©ãæ·»å ããåãåŸãããã¯
åæã§ãã€ãŠããã æ¬çºæã«çšããããå¢æè²çŽ ã®æ·»å éã¯ããã
ã²ã³åéïŒã¢ã«åœãïŒÃ10-6ã¢ã«ãïŒÃ10-3ã¢
ã«ã奜ãŸããã¯ïŒÃ10-6ã¢ã«ãïŒÃ10-4ã¢ã«ã®ç¯
å²ã§ããã å¢æè²çŽ ã¯ãçŽæ¥ã«ä¹³å€ã«åæ£ããããšãã§
ãããããã¯ã¡ã¿ããŒã«ããšã¿ããŒã«ãããªãž
ã³ãã¡ãã«ã»ããœã«ããã¢ã»ãã³ããžã¡ãã«ãã«
ã ã¢ãããªã©ïŒãŸãã¯ãããã®æ··å溶åªïŒã®æ°Žæ··
åæ§æº¶åªã«æº¶è§£ããããå Žåã«ã¯æ°Žã«ãŠåžéãã
ãŸãããå Žåã«ã¯æ°Žã®äžã§æº¶è§£ãããããã®æº¶æ¶²
ã®åœ¢ã§ä¹³å€ãžæ·»å ããããšãã§ããããã®è²çŽ 溶
液ã«è¶ é³æ³¢æ¯åãçšããããšãã§ããããç±³åœç¹
蚱第3469987å·ãç¹å ¬æ46â24185ã«èšèŒã®æ¹æ³ã§
ãæ·»å ããããããã«ã¯ç±³åœç¹èš±ç¬¬2912345å·ã
å3342605å·ãå2996287å·ãå3425835å·ãªã©ã«
èšèŒã®æ¹æ³ãçšãããã æ¬çºæã«çšããããã²ã³åéä¹³å€ã¯ãå ¬ç¥ã®
çš®ã ã®æ¹æ³ã«ãã€ãŠèª¿è£œããããšãã§ããã æ¬çºæã«çšããããããã²ã³åéä¹³å€ã¯ããã
ããã·ã³ã°ã«ãžãšããæ¹åŒãããã¯ããã«ãžãšã
ãæ¹åŒãšããããæ··åæ³ã®ããããçšããŠèª¿è£œã
ããŠããããã奜ãŸããã¯åŸè ãçšããŠèª¿è£œãã
ãååæ£ä¹³å€ãçšããã®ãè¯ãããŸããæ¬çºæã«
çšããããããã²ã³åéçµæ¶ã®æ¶çã¯ãç«æ¹äœã
å «é¢äœãååé¢äœãå¹³æ¿ç¶çµæ¶ã®ãããã§ãã
ãã æ¬çºæã«çšããããããã²ã³åéã®ããã²ã³çµ
æã¯ãå¡©åéãèåéãå¡©çŽ åéãããã¯ããã
ã«æ²åéãå«ãä»»æã®ãã®ã§ãã€ãŠããã ããã²ã³åéã®æ²æŸ±ãããã¯ç©ççæäžã«ã¯ã
ããžãŠã ãã€ãªãžãŠã çã®éå±ãçšããããšãã§
ããã ãããã®ä¹³å€ã¯å ¬ç¥ã®æ¹æ³ã«ãã€ãŠååŠçæã
æœãäºãåºæ¥ããå³ã¡ç±³åœç¹èš±ç¬¬1574944å·ãå
2278947å·ãå2410689å·ãå3189458å·ãå
3501313å·çã«èšèŒãããŠããã€ãªãŠååç©åã¯
ã€ãªãŠååç©ãå«ãå¢æåãŒã©ãã³ã«ããã€ãªãŠ
å¢æãæœãäºãåºæ¥ããåç±³åœç¹èš±ç¬¬2597856å·ã
å2597915å·ãå2399083å·çã«èšèŒãããŠããé
ååç©ã«ããéå¢æãæœãããšãåºæ¥ããåãç±³
åœç¹èš±ç¬¬2518698ãå2521925ãå2487850ãå
2694637å·ã«èšèŒã®åŠãéå å¢æãæœãããšãåº
æ¥ãããããŠãããã®å¢ææ³ã¯åäžã§ãªãçµåã
ãŠè¡ãäºãåºæ¥ãã æ¬çºæã«çšããããåçä¹³å€ã¯åã第ïŒçŽã¢ã³
ã¢ããŠã å¡©ãããªãšãŒãã«ååç©ãããªãšãã¬ã³
ãªããµã€ãèªå°äœããžã±ãã³é¡ãªã©ãçšããŠå¢æ
ããããšãåºæ¥ãããããã®æ¹æ³ã¯ç±³åœç¹èš±ç¬¬
2708162å·ãå3046132å·ãå3046133å·ãå
3046134å·ãå3046135å·ãè±åœç¹èš±ç¬¬939357å·ç
ã«èšèŒãããŠããã æ¬çºæã®åçæå ææã«ã¯çš®ã ã®èŠªæ°Žæ§ã³ãã€
ããçšããããåçä¹³å€çšããã³ïŒåã¯ä»ã®åç
æ§æå±€çšã®ããã¯ã«ãšããŠäœ¿çšãã芪氎æ§ã³ãã€
ãã«ã¯äŸãã°ãŒã©ãã³ãã³ãã€ãæ§ã¢ã«ããã³ã
ã«ãŒã€ã³ãã«ã«ããã·ã¡ãã«ã»ã«ããŒã°ãããã
ãã·ãšãã«ã»ã«ããŒãºçã®ã»ã«ããŒã¹èªå°äœãå¯
倩ãã¢ã«ã®ã³é žãœãŒãã柱ç²èªå°äœãªã©ã®ç³èªå°
äœãåæ芪氎æ§ã³ãã€ããäŸãã°ããªããã«ã¢ã«
ã³ãŒã«ãããªïŒ®âããã«ãããªãã³ãããªã¢ã¯ãª
ã«é žå ±éåäœãããªã¢ã¯ãªã«ã¢ãããŸãã¯ããã
ã®èªå°äœãéšåå æ°Žå解ç©çãããããããå¿ èŠ
ã«å¿ããŠããããã®ã³ãã€ãã®äºã€ä»¥äžã®çžæº¶æ§
æ··åç©ã䜿çšããããã®äžã§æãäžè¬çã«çšãã
ããã®ã¯ãŒã©ãã³ã§ãããããŒã©ãã³ã¯äžéšãŸã
ã¯å šéšãåæé«ååç©è³ªã§çœ®ããããããšãã§ã
ãã»ãããããããŒã©ãã³èªå°äœããªãã¡ååäž
ã«å«ãŸããå®èœåºãšããŠã®ã¢ããåºãã€ããåºã
ããããªãã·åºãã«ã«ããã·ã«åºãããããšåå¿
ãåŸãåºãäžåæã€ãè©Šè¬ã§åŠçãæ¹è³ªãããã®
æã¯ä»ã®é«ååç©è³ªã®ååéãçµåãããã°ã©ã
ãããªããŒã§çœ®ãæããŠäœ¿çšããŠãããã æ¬çºæã®åçæå ææã«ã¯ãåçä¹³å€å±€ãã®ä»
ã®èŠªæ°Žæ§ã³ãã€ãå±€ã«ç¡æ©ãŸãã¯ææ©ã®ç¡¬èå€ã
å«æããŠãããäŸãã°ã¯ãã å¡©ïŒã¯ãã æã°ãã
é ¢é žã¯ãã ãªã©ïŒãã¢ã«ãããé¡ïŒãã«ã ã¢ã«ã
ãããã°ãªãªããµãŒã«ãã°ã«ã¿ãŒã«ã¢ã«ããããª
ã©ïŒãâã¡ãããŒã«ååç©ïŒãžã¡ãããŒã«å°¿çŽ ã
ã¡ãããŒã«ãžã¡ãã«ããã³ãã€ã³ãªã©ïŒããžãªã
ãµã³èªå°äœïŒïŒïŒïŒâãžããããã·ãžãªããµã³ãª
ã©ïŒã掻æ§ããã«ååç©ïŒïŒïŒïŒïŒïŒâããªã¢ã¯
ãªãã€ã«âãããµãããââããªã¢ãžã³ãïŒïŒ
ïŒâããã«ã¹ã«ããã«âïŒâãããããŒã«ãªã©ïŒã
掻æ§ããã²ã³ååç©ïŒïŒïŒïŒâãžã¯ãã«âïŒâã
ãããã·ââããªã¢ãžã³ãªã©ïŒãã ã³ããã²ã³
é žé¡ïŒã ã³ã¯ãã«é žãã ã³ããšããã·ã¯ãã«é žãª
ã©ïŒããªã©ãåç¬ãŸãã¯çµåãããŠçšããããšã
ã§ããã æ¬çºæã®æå ææã®åçä¹³å€å±€ãŸãã¯ä»ã®èŠªæ°Ž
æ§ã³ãã€ãå±€ã«ã¯å¡åžå©å€ã垯é»é²æ¢ãã¹ããªæ§
æ¹è¯ãä¹³ååæ£ãæ¥çé²æ¢ãªã©çš®ã ã®ç®çã§çš®ã
ã®çé¢æŽ»æ§å€ãå«ãã§ãããã ããšãã°ãµããã³ïŒã¹ããã€ãç³»ïŒãã¢ã«ãã¬
ã³ãªããµã€ãèªå°äœïŒäŸãã°ããªãšãã¬ã³ã°ãªã³
ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ïŒããªãããã¬ã³
ã°ãªã³ãŒã«çž®åç©ãããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ãšãŒãã«é¡ãŸãã¯ããªãšãã¬ã³ã°ãªã³ãŒã«ã¢
ã«ãã«ã¢ãªãŒã«ãšãŒãã«é¡ãããªãšãã¬ã³ã°ãªã³
ãŒã«ãšã¹ãã«é¡ãããªãšãã¬ã³ã°ãªã³ãŒã«ãœã«ã
ã¿ã³ãšã¹ãã«é¡ãããªã¢ã«ãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ã¢ãã³ãŸãã¯ã¢ããé¡ãã·ãªã³ãŒã³ã®ããªãš
ãã¬ã³ãªããµã€ãä»å ç©é¡ïŒãã°ãªã·ããŒã«èªå°
äœïŒããšãã°ã¢ã«ã±ãã«ã³ãã¯é žããªã°ãªã»ãª
ããã¢ã«ãã«ãœãšããŒã«ããªã°ãªã»ãªãïŒãå€äŸ¡
ã¢ã«ã³ãŒã«ã®èèªé žãšã¹ãã«é¡ãç³ã®ã¢ã«ãã«ãš
ã¹ãã«é¡ãªã©ã®éã€ãªã³æ§çé¢æŽ»æ§å€ãã¢ã«ãã«
ã«ã«ãã³é žå¡©ãã¢ã«ãã«ã¹ã«ããªã³é žå¡©ãã¢ã«ã
ã«ãã³ãŒã³ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ããã¿ã¬ã³
ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ç¡«é žãšã¹ãã«é¡ãã¢ã«
ãã«ãªã³é žãšã¹ãã«é¡ãâã¢ã·ã«ââã¢ã«ã
ã«ã¿ãŠãªã³é¡ãã¹ã«ãã³ãã¯é žãšã¹ãã«é¡ãã¹ã«
ãã¢ã«ãã«ããªãªãã·ãšãã¬ã³ã¢ã«ãã«ããšãã«
ãšãŒãã«é¡ãããªãªãã·ãšãã¬ã³ã¢ã«ãã«ãªã³é ž
ãšã¹ãã«é¡ãªã©ã®ãããªãã«ã«ããã·åºãã¹ã«ã
åºããã¹ãåºãç¡«é žãšã¹ãã«åºãçé žãšã¹ãã«åº
çã®é žæ§åºãå«ãã¢ããªã³çé¢æŽ»æ§å€ïŒã¢ããé ž
é¡ãã¢ããã¢ã«ãã«ã¹ã«ãã³é žé¡ãã¢ããã¢ã«ã
ã«ç¡«é žãŸãã¯çé žãšã¹ãã«é¡ãã¢ã«ãã«ãã¿ã€ã³
é¡ãã¢ãã³ãªãã·ãé¡ãªã©ã®äž¡æ§çé¢æŽ»æ§å€ïŒã¢
ã«ãã«ã¢ãã³å¡©é¡ãèèªæãããã¯è³éŠæ第ïŒçŽ
ã¢ã³ã¢ããŠã å¡©é¡ãããªãžãŠã ãã€ãããŸãªãŠã
ãªã©ã®è€çŽ ç°ç¬¬ïŒçŽã¢ã³ã¢ããŠã å¡©é¡ãããã³è
èªæãŸãã¯è€çŽ ç°ãå«ããã¹ãããŠã ãŸãã¯ã¹ã«
ãããŠã å¡©é¡ãªã©ã®ã«ããªã³çé¢æŽ»æ§å€ãçšãã
ããšãã§ãããåãã©ããã¯ã¹ããªããŒçãæ·»å
ããŠãŒã©ãã³èã®ç©æ§ãæ¹è³ªããããã·ãªã«ãã
ã³ãã³ç²ããã³ãã€ãã«ã·ãªã«ãã¬ã©ã¹ç²ãªã©ã
æ·»å ããŠèé¢ããããåãããããããšãã§ã
ãã æ¬çºæã®æå ææã®åçä¹³å€å±€åã¯ä»ã®èŠªæ°Žæ§
ã³ãã€ãå±€ã«ã¯ãæå ææã®è£œé å·¥çšãä¿åäžã
ããã¯åçåŠçäžã®ã«ããªãé²æ¢ãããããã¯å
çæ§èœãå®å®åãããç®çã§ãåèšäžè¬åŒïŒïŒ
ã®ååç©ä»¥å€ã®çš®ã ã®ååç©ãå«æãããããšã
ã§ãããããªãã¡ã¢ãŸãŒã«é¡ãããšãã°ãã³ãŸã
ã¢ãŸãªãŠã å¡©ããããã€ã³ããŸãŒã«é¡ãããªã¢ãŸ
ãŒã«é¡ããã³ãŸããªã¢ãŸãŒã«é¡ããã³ãºã€ãããŸ
ãŒã«é¡ïŒç¹ã«ãããããŸãã¯ããã²ã³çœ®æäœïŒïŒ
ãããç°ã¡ã«ã«ããååç©é¡ãããšãã°ã¡ã«ã«ã
ããã¢ãŸãŒã«é¡ãã¡ã«ã«ãããã³ãŸãã¢ãŸãŒã«
é¡ãã¡ã«ã«ãããã³ãºã€ãããŸãŒã«é¡ãã¡ã«ã«ã
ããã¢ãžã¢ãŸãŒã«é¡ãã¡ã«ã«ããããã©ãŸãŒã«é¡
ïŒç¹ã«ïŒâããšãã«âïŒâã¡ã«ã«ããããã©ãŸãŒ
ã«ïŒãã¡ã«ã«ããããªããžã³é¡ïŒã«ã«ããã·ã«åº
ãã¹ã«ãã³åºãªã©ã®æ°Žæº¶æ§åºãæããäžèšã®ãã
ãç°ã¡ã«ã«ããååç©é¡ïŒããªã±ãååç©ãããš
ãã°ãªããµãŸãªã³ããªã³ïŒã¢ã¶ã€ã³ãã³é¡ãããš
ãã°ããã©ã¢ã¶ã€ã³ãã³é¡ïŒç¹ã«ïŒâããããã·
眮æïŒïŒïŒïŒïŒ3aïŒïŒïŒããã©ã¢ã¶ã€ã³ãã³
é¡ïŒïŒãã³ãŒã³ããªã¹ã«ãã³é žé¡ïŒãã³ãŒã³ã¹ã«
ãã€ã³é žïŒãªã©ã®ãããªã«ããªé²æ¢å€ãŸãã¯å®å®
å€ãšããŠç¥ãããå€ãã®ååç©ãå ããããšãã§
ããã æ¬çºæã®æå ææã¯ãåèšä»¥å€ã®çš®ã ã®åå
ç©ãäŸãã°åž¯é»é²æ¢å€ã玫å€ç·åžåå€ãå¯å¡å€ã
çŸåäž»è¬ããã¬ãŒã·ãšã³é²æ¢ææãèå ææãçŸ
åä¿é²å€ãã«ãã©ãŒçãã䜿çšããããšãã§ã
ãã æ¬çºæã®åçæå ææã«ãããŠã¯ãéåžžåçæ
å ææã®æ¯æäœãšããŠçšãããããã®ããã¹ãŠçš
ãããããäŸãã°ã»ã«ããŒã¹ãã€ãã¬ãŒããã€ã«
ã ãã»ã«ããŒã¹ã¢ã»ããŒããã€ã«ã ãã»ã«ããŒã¹
ã¢ã»ããŒãããã¬ãŒããã€ã«ã ãã»ã«ããŒã¹ã¢ã»
ããŒãããããªããŒããã€ã«ã ãããªã¹ãã¬ã³ã
ã€ã«ã ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€ã«ã ã
ããªã«ãŒãããŒããã€ã«ã ããã®ä»ãããã®ç©å±€
ç©ãçŽãªã©ãããããã©ã€ã¿åã¯Î±âãªã¬ãã€ã³
ããªããŒãç¹ã«ããªãšãã¬ã³ãããªãããã¬ã³ãª
ã©ççŽ ååïŒã10ã®Î±âãªã¬ãã€ã³ã®ããªããŒã
å¡åžãŸãã¯ã©ãããŒãããçŽãç¹å ¬æ47â19068
å·ã«ç€ºãããŠãããããªè¡šé¢ãç²é¢åããããšã«
ãã€ãŠãä»ã®é«ååç©è³ªãšã®å¯çæ§ãè¯åããäž
ã€å°å·é©æ§ãããããã©ã¹ããã¯ãã€ã«ã çã®æ¯
æäœãªã©ã奜é©ã§ããã åãæ¬çºæã®èŠªæ°Žæ§ã³ãã€ãå±€ã®å¡åžæ¹æ³ãšã
ãŠã¯ããšã¢ãŒãã¯ã¿ãŒããã¬ãŒãã³ãŒããã¹ã¯ã€
ãºã³ãŒãããšã¢ãŒãã€ãã³ãŒãããªããŒã¹ããŒã«
ã³ãŒãããã€ã¹ãã³ãŒãããšã¯ã¹ãã«ãŒãžãšã³ã³
ãŒãçã®æ¹æ³ãçšããããããããŠå¡åžéã¯ïŒã
15ÎŒïœããã奜ãŸããã¯ïŒã10ÎŒïœãšããããšã
奜ãŸããã æ¬çºæã®æå ææã¯ãåå°äœã¬ãŒã¶ãŒçšã®é»çœ
åçæå ææãéé¯å¡©æ¡æ£è»¢åæ³ãå©çšããå¹³ç
å°å·çãªã©ã«æçšã§ãããããã®ä»ã®çšéã«ã䜿
çšããããšãã§ããã (E) å®æœäŸ å®æœäŸ ïŒ éåžžã®ã³ã³ãããŒã«ããã«ãžãšããæ³ã«ããã
å¹³åç²åŸçŽ0.23ÎŒïœã®å¡©èåéïŒèåé10ã¢ã«ïŒ ïŒ
ä¹³å€ã調補ããæ²æŸ±ãæ°ŽæŽå溶解ããåŸããŒã©ã
ã³å¯Ÿéã0.6察1.0ã«åãããç¡«é»ïŒéå¢æããã
çµäºåŸãå¢æè²çŽ ãšããŠäŸç€ºè²çŽ (10)ãããã²ã³å
éïŒã¢ã«åœãïŒÃ10-4ã¢ã«æ·»å ãã硬èå€ãšçé¢
掻æ§å€ãå ããããã®ä¹³å€ãçåãã第ïŒè¡šã«ç€º
ãååç©ãæ·»å ããŠä»äžãä¹³å€ãšããã ãããã®ä¹³å€ãä¿è·å±€ïŒãŒã©ãã³ïŒïœïŒm2ïŒãš
å ±ã«ããªãšã¹ãã«ãã€ã«ã äžã«éïŒïœïŒm2ãšãªã
ããã«éå±€å¡åžããŠè©Šæãäœè£œããã ãããã®è©Šæã780nmã®å¹²æžãã€ã«ã¿ãŒãéã
ãŠ10-5ç§éã®ã»ã³ã·ãã¡ããªãŒé²å ãæœããã
PQçŸå液ã§çŸåããå®çãæ°ŽæŽã也ç¥ããŠç¹æ§
ãæ±ãããçµæã第ïŒè¡šã«ç€ºããæ床ã¯ãè©ŠæïŒ
ã100ãšããçžå¯Ÿå€ã§ç€ºããŠãããæ·»å éã¯ãã
ãã²ã³åéïŒã¢ã«åœãã®éïŒmgïŒã§ããã
ãã ïŒæ¯èŒïœïŒ ïŒæ¯èŒïœïŒ ïŒæ¯èŒïœïŒ æ¬çºæã«çšããããäžè¬åŒïŒïŒåã³äžè¬åŒ
ïŒïŒã®ååç©ã¯ãããã²ã³åéä¹³å€ã®å¡åžãŸã§
ã®ä»»æã®ææã«ãããããïŒçš®ãããã¯ïŒçš®ä»¥äž
ãæ·»å ããã®ã§ããããå Žåã«ãã€ãŠã¯å¡åžæã«
é£æ¥ãã芪氎æ§ã³ãã€ãå±€ããæ¡æ£ãããŠãã
ãã æ·»å éã¯ãããããããã²ã³åéïŒã¢ã«åœãïŒ
Ã10-3ããªã¢ã«ãïŒããªã¢ã«ã奜ãŸããã¯ïŒÃ
10-2ããªã¢ã«ãïŒããªã¢ã«ã®ç¯å²ã§ãããã¢ã«æ¯
ãšããŠïŒïŒïŒãïŒïŒïŒã®ç¯å²ã§ä»»æã«å€åããã
ããšãåºæ¥ããæ·»å ã«éããŠã¯ãé©åœãªæº¶åªãã
ãšãã°ã¡ã¿ããŒã«ããšã¿ããŒã«ããããããŒã«ã
ã¢ã»ãã³ããžã¡ãã«ãã«ã ã¢ããçã®æº¶æ¶²ãšããŠ
æ·»å ããã®ãæå©ã§ããããŸããäžè¬åŒïŒïŒã®
ååç©ãšäžè¬åŒïŒïŒã®ååç©ã¯ãïŒã€ã®æº¶æ¶²ãš
ããŠæ·»å ããŠãããããããã¯å¥ã ã®æº¶æ¶²ãšããŠ
å¥ã ã®ææã«æ·»å ããŠãããã æ¬çºæã«çšãããã700nmããé·æ³¢é·é åã«æ¥µ
倧åå æ床ãæããå¢æè²çŽ ã¯ãäŸãã°ç±³åœç¹èš±
第2095854å·ãå第2095856å·ãå第2955939å·ã
å第3482978å·ãå第3552974å·ãå第3573921å·ã
å第3582344å·ãå第3623881å·æ现æžçã«èšèŒã
ãããã®ã§ããããšãåºæ¥ãã 奜ãŸããã¯ãäŸãã°æ¬¡ã®äžè¬åŒïŒïŒãïŒïŒ
ã§è¡šããããè²çŽ ãçšããããã äžè¬åŒïŒïŒãïŒïŒã«æŒãŠãZ1åã³Z2ã¯ã
åã åäžã§ãç°ãªã€ãŠããŠããããããããïŒå¡
ãŸãã¯ïŒå¡å«çªçŽ è€çŽ ç°ã圢æããã®ã«å¿ èŠãªå
å矀ãè¡šãããR1åã³R2ã¯ãåã åäžã§ãç°ãª
ã€ãŠããŠããããããããã¢ã«ãã«åºãã¢ã«ã±ã
ã«åºãè¡šãããR3ã¯ãã¢ã«ãã«åºãã¢ã«ã±ãã«
åºãã¢ãªãŒã«åºãè¡šãããR4ãR10ã¯ãåã åäž
ã§ãç°ãªã€ãŠããŠããããããããæ°ŽçŽ ååãã
ãã²ã³ååãã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã³ã
ã·åºãè¡šãããäœããR6ãšR7ãããã¯R8ãšR9ãš
ã¯äºã«é£çµããŠïŒå¡åã¯ïŒå¡ç°ã圢æããããšã
ã§ãããR11åã³R12ã¯ãåã åäžã§ãç°ãªã€ãŠ
ããŠããããããããã¢ã«ãã«åºãã¢ãªãŒã«åºã
è¡šãããR11ãšR12ãšã¯äºã«é£çµããŠïŒå¡åã¯ïŒ
å¡ç°ã圢æããããšãã§ãããã¯ãç¡«é»ååã
é žçŽ ååãâR13ïŒR13ã¯ã¢ã«ãã«åºïŒãè¡šã
ããã¯é žã¢ããªã³ãè¡šãããïœïŒïœïŒïœïŒïœå
ã³ïœã¯ããããïŒåã¯ïŒãè¡šããã Z1åã³Z2ã®å ·äœäŸãšããŠã¯ããã¢ãŸãŒã«ããã³
ãŸãã¢ãŸãŒã«ãããããïŒïŒïŒâαããã¢ãŸãŒ
ã«ãããããïŒïŒïŒâαããã¢ãŸãŒã«ãããã
ãïŒïŒïŒâαããã¢ãŸãŒã«ãã»ã¬ããŸãŒã«ããã³
ãŸã»ã¬ããŸãŒã«ãããããïŒïŒïŒâαãã»ã¬ããŸ
ãŒã«ãããããïŒïŒïŒâαãã»ã¬ããŸãŒã«ããªã
ãµãŸãŒã«ããã³ãŸãªããµãŸãŒã«ãããããïŒïŒïŒ
âαããªããµãŸãŒã«ãããããïŒïŒïŒâαããªã
ãµãŸãŒã«ãããããïŒïŒïŒâαããªããµãŸãŒã«ã
ïŒâãããªã³ãïŒâãããªã³ãïŒïŒïŒâãžã¢ã«ã
ã«ã€ã³ãã¬ãã³ãã€ãããŸãŒã«ããã³ãºã€ãããŸ
ãŒã«ãããããïŒïŒïŒâαãã€ãããŸãŒã«ãããª
ãžã³çã®å«çªçŽ è€çŽ ç°ãæããããšãã§ãããã
ããã®è€çŽ ç°ã¯ãã¢ã«ãã«åºïŒäŸãã°ãã¡ãã«ã
ãšãã«ãããã«ãããªãã«ãªãã¡ãã«çïŒãã¢ãª
ãŒã«åºïŒäŸãã°ãããšãã«ãããªã«çïŒãããã
ãã·åºãã¢ã«ã³ãã·åºïŒäŸãã°ãã¡ããã·ããšã
ãã·ããããã·çïŒãã«ã«ããã·åºãã¢ã«ã³ãã·
ã«ã«ããã«åºïŒäŸãã°ãã¡ããã·ã«ã«ããã«ããš
ããã·ã«ã«ããã«çïŒãããã²ã³ååïŒäŸãã°ã
ããçŽ ãå¡©çŽ ãèçŽ ãæ²çŽ ïŒãã¢ã©ã«ãã«åºïŒäŸ
ãã°ããã³ãžã«ãããšããã«çïŒãã·ã¢ãåºãã¢
ã«ã±ãã«åºïŒäŸãã°ãã¢ãªã«çïŒçã®çœ®æåºãïŒ
ãŸãã¯ïŒä»¥äžæããŠãããã R1ïŒR2ã«æŒãŠãã¢ã«ãã«åºãšããŠã¯ãã¡ãã«ã
ãšãã«ããããã«ãããã«çã®äœçŽã¢ã«ãã«åºã
βâããããã·ãšãã«ãγâããããã·ãããã«
çã®ããããã·ã¢ã«ãã«åºãβâã¡ããã·ãšã
ã«ãγâã¡ããã·ãããã«çã®ã¢ã«ã³ãã·ã¢ã«ã
ã«åºãβâã¢ã»ããã·ãšãã«ãγâã¢ã»ããã·ã
ããã«ãβâãã³ãŸã€ã«ãªãã·ãšãã«çã®ã¢ã·ã«
ãªãã·ã¢ã«ãã«åºãã«ã«ããã·ã¡ãã«ãβâã«ã«
ããã·ãšãã«çã®ã«ã«ããã·ã¢ã«ãã«åºãã¡ãã
ã·ã«ã«ããã«ã¡ãã«ããšããã·ã«ã«ããã«ã¡ã
ã«ãβâãšããã·ã«ã«ããã«ãšãã«çã®ã¢ã«ã³ã
ã·ã«ã«ããã«ã¢ã«ãã«åºãβâã¹ã«ããšãã«ãγ
âã¹ã«ããããã«ããâã¹ã«ãããã«çã®ã¹ã«ã
ã¢ã«ãã«åºããã³ãžã«ãããšããã«ãã¹ã«ããã³
ãžã«çã®ã¢ã©ã«ãã«åºçãã¢ã«ã±ãã«åºãšããŠã¯
ã¢ãªã«çãæããããã R3ãšããŠã¯ãäžèšR1ïŒR2ã§è¿°ã¹ããããªã¢ã«
ãã«åºãã¢ã«ã±ãã«åºããªãã³ã«ããšãã«ãããª
ã«ãã¡ããã·ããšãã«ãã¯ããããšãã«ãããã
ã«çã®ã¢ãªãŒã«åºãæããããã R4ãR10ã¯ãæ°ŽçŽ ååãããã²ã³ååïŒäŸãã°
å¡©çŽ ãèçŽ ãæ²çŽ ãããçŽ ïŒãR1ïŒR2ã§è¿°ã¹ãã
ããªã¢ã«ãã«åºãã¢ãªãŒã«åºãããã¯R1ïŒR2ã§
è¿°ã¹ããããªã¢ã«ãã«ããã€ã¢ã«ã³ãã·åºïŒããª
ãã¡OR1åºïŒã§ãããR6ãšR7ãããã¯R8ãšR9ãš
ã§åœ¢æãããïŒå¡ãŸãã¯ïŒå¡ç°ã¯ãäœçŽã¢ã«ãã«
åºçã§çœ®æãããŠããŠããããR11åã³R12ã¯ã
R1ïŒR2ã§è¿°ã¹ããããªã¢ã«ãã«åºãã¢ãªãŒã«åº
ãè¡šãããR11ãšR12ãšã¯äºã«é£çµããŠïŒå¡åã¯
ïŒå¡ç°ã圢æããããšãã§ãããR13ã¯R1ïŒR2ã§
è¿°ã¹ããããªã¢ã«ãã«åºãæããããã ã®é žã¢ããªã³ãšããŠã¯ãã¡ãã«ç¡«é žããšãã«
ç¡«é žçã®ã¢ã«ãã«ç¡«é žã€ãªã³ãããªã·ã¢ã³é žã€ãª
ã³ããã«ãšã³ã¹ã«ãã³é žã€ãªã³ãå¡©çŽ ãèçŽ ãæ²
çŽ çã®ããã²ã³ã€ãªã³ãéå¡©çŽ é žã€ãªã³çã§ã
ããè²çŽ ããã¿ã€ã³é¡äŒŒæ§é ããšãå Žåã«ã¯ååš
ããªãã æ¬çºæã«çšããããå¢æè²çŽ ã®å ·äœäŸã以äžã«
äŸç€ºããã æ¬çºæã«çšããããå¢æè²çŽ ã¯ãåœæ¥è ã«å ¬ç¥
ã®æ¹æ³ã§åæããããšãã§ãããããã²ã³åéä¹³
å€ã«æ·»å ããææã¯ãä¹³å€ãå¡åžãããŸã§ã®ä»»æ
ã®ææã§ããããšãã§ããåèšäžè¬åŒïŒïŒåã³
äžè¬åŒïŒïŒã®ååç©ãæ·»å ããåãåŸãããã¯
åæã§ãã€ãŠããã æ¬çºæã«çšããããå¢æè²çŽ ã®æ·»å éã¯ããã
ã²ã³åéïŒã¢ã«åœãïŒÃ10-6ã¢ã«ãïŒÃ10-3ã¢
ã«ã奜ãŸããã¯ïŒÃ10-6ã¢ã«ãïŒÃ10-4ã¢ã«ã®ç¯
å²ã§ããã å¢æè²çŽ ã¯ãçŽæ¥ã«ä¹³å€ã«åæ£ããããšãã§
ãããããã¯ã¡ã¿ããŒã«ããšã¿ããŒã«ãããªãž
ã³ãã¡ãã«ã»ããœã«ããã¢ã»ãã³ããžã¡ãã«ãã«
ã ã¢ãããªã©ïŒãŸãã¯ãããã®æ··å溶åªïŒã®æ°Žæ··
åæ§æº¶åªã«æº¶è§£ããããå Žåã«ã¯æ°Žã«ãŠåžéãã
ãŸãããå Žåã«ã¯æ°Žã®äžã§æº¶è§£ãããããã®æº¶æ¶²
ã®åœ¢ã§ä¹³å€ãžæ·»å ããããšãã§ããããã®è²çŽ 溶
液ã«è¶ é³æ³¢æ¯åãçšããããšãã§ããããç±³åœç¹
蚱第3469987å·ãç¹å ¬æ46â24185ã«èšèŒã®æ¹æ³ã§
ãæ·»å ããããããã«ã¯ç±³åœç¹èš±ç¬¬2912345å·ã
å3342605å·ãå2996287å·ãå3425835å·ãªã©ã«
èšèŒã®æ¹æ³ãçšãããã æ¬çºæã«çšããããã²ã³åéä¹³å€ã¯ãå ¬ç¥ã®
çš®ã ã®æ¹æ³ã«ãã€ãŠèª¿è£œããããšãã§ããã æ¬çºæã«çšããããããã²ã³åéä¹³å€ã¯ããã
ããã·ã³ã°ã«ãžãšããæ¹åŒãããã¯ããã«ãžãšã
ãæ¹åŒãšããããæ··åæ³ã®ããããçšããŠèª¿è£œã
ããŠããããã奜ãŸããã¯åŸè ãçšããŠèª¿è£œãã
ãååæ£ä¹³å€ãçšããã®ãè¯ãããŸããæ¬çºæã«
çšããããããã²ã³åéçµæ¶ã®æ¶çã¯ãç«æ¹äœã
å «é¢äœãååé¢äœãå¹³æ¿ç¶çµæ¶ã®ãããã§ãã
ãã æ¬çºæã«çšããããããã²ã³åéã®ããã²ã³çµ
æã¯ãå¡©åéãèåéãå¡©çŽ åéãããã¯ããã
ã«æ²åéãå«ãä»»æã®ãã®ã§ãã€ãŠããã ããã²ã³åéã®æ²æŸ±ãããã¯ç©ççæäžã«ã¯ã
ããžãŠã ãã€ãªãžãŠã çã®éå±ãçšããããšãã§
ããã ãããã®ä¹³å€ã¯å ¬ç¥ã®æ¹æ³ã«ãã€ãŠååŠçæã
æœãäºãåºæ¥ããå³ã¡ç±³åœç¹èš±ç¬¬1574944å·ãå
2278947å·ãå2410689å·ãå3189458å·ãå
3501313å·çã«èšèŒãããŠããã€ãªãŠååç©åã¯
ã€ãªãŠååç©ãå«ãå¢æåãŒã©ãã³ã«ããã€ãªãŠ
å¢æãæœãäºãåºæ¥ããåç±³åœç¹èš±ç¬¬2597856å·ã
å2597915å·ãå2399083å·çã«èšèŒãããŠããé
ååç©ã«ããéå¢æãæœãããšãåºæ¥ããåãç±³
åœç¹èš±ç¬¬2518698ãå2521925ãå2487850ãå
2694637å·ã«èšèŒã®åŠãéå å¢æãæœãããšãåº
æ¥ãããããŠãããã®å¢ææ³ã¯åäžã§ãªãçµåã
ãŠè¡ãäºãåºæ¥ãã æ¬çºæã«çšããããåçä¹³å€ã¯åã第ïŒçŽã¢ã³
ã¢ããŠã å¡©ãããªãšãŒãã«ååç©ãããªãšãã¬ã³
ãªããµã€ãèªå°äœããžã±ãã³é¡ãªã©ãçšããŠå¢æ
ããããšãåºæ¥ãããããã®æ¹æ³ã¯ç±³åœç¹èš±ç¬¬
2708162å·ãå3046132å·ãå3046133å·ãå
3046134å·ãå3046135å·ãè±åœç¹èš±ç¬¬939357å·ç
ã«èšèŒãããŠããã æ¬çºæã®åçæå ææã«ã¯çš®ã ã®èŠªæ°Žæ§ã³ãã€
ããçšããããåçä¹³å€çšããã³ïŒåã¯ä»ã®åç
æ§æå±€çšã®ããã¯ã«ãšããŠäœ¿çšãã芪氎æ§ã³ãã€
ãã«ã¯äŸãã°ãŒã©ãã³ãã³ãã€ãæ§ã¢ã«ããã³ã
ã«ãŒã€ã³ãã«ã«ããã·ã¡ãã«ã»ã«ããŒã°ãããã
ãã·ãšãã«ã»ã«ããŒãºçã®ã»ã«ããŒã¹èªå°äœãå¯
倩ãã¢ã«ã®ã³é žãœãŒãã柱ç²èªå°äœãªã©ã®ç³èªå°
äœãåæ芪氎æ§ã³ãã€ããäŸãã°ããªããã«ã¢ã«
ã³ãŒã«ãããªïŒ®âããã«ãããªãã³ãããªã¢ã¯ãª
ã«é žå ±éåäœãããªã¢ã¯ãªã«ã¢ãããŸãã¯ããã
ã®èªå°äœãéšåå æ°Žå解ç©çãããããããå¿ èŠ
ã«å¿ããŠããããã®ã³ãã€ãã®äºã€ä»¥äžã®çžæº¶æ§
æ··åç©ã䜿çšããããã®äžã§æãäžè¬çã«çšãã
ããã®ã¯ãŒã©ãã³ã§ãããããŒã©ãã³ã¯äžéšãŸã
ã¯å šéšãåæé«ååç©è³ªã§çœ®ããããããšãã§ã
ãã»ãããããããŒã©ãã³èªå°äœããªãã¡ååäž
ã«å«ãŸããå®èœåºãšããŠã®ã¢ããåºãã€ããåºã
ããããªãã·åºãã«ã«ããã·ã«åºãããããšåå¿
ãåŸãåºãäžåæã€ãè©Šè¬ã§åŠçãæ¹è³ªãããã®
æã¯ä»ã®é«ååç©è³ªã®ååéãçµåãããã°ã©ã
ãããªããŒã§çœ®ãæããŠäœ¿çšããŠãããã æ¬çºæã®åçæå ææã«ã¯ãåçä¹³å€å±€ãã®ä»
ã®èŠªæ°Žæ§ã³ãã€ãå±€ã«ç¡æ©ãŸãã¯ææ©ã®ç¡¬èå€ã
å«æããŠãããäŸãã°ã¯ãã å¡©ïŒã¯ãã æã°ãã
é ¢é žã¯ãã ãªã©ïŒãã¢ã«ãããé¡ïŒãã«ã ã¢ã«ã
ãããã°ãªãªããµãŒã«ãã°ã«ã¿ãŒã«ã¢ã«ããããª
ã©ïŒãâã¡ãããŒã«ååç©ïŒãžã¡ãããŒã«å°¿çŽ ã
ã¡ãããŒã«ãžã¡ãã«ããã³ãã€ã³ãªã©ïŒããžãªã
ãµã³èªå°äœïŒïŒïŒïŒâãžããããã·ãžãªããµã³ãª
ã©ïŒã掻æ§ããã«ååç©ïŒïŒïŒïŒïŒïŒâããªã¢ã¯
ãªãã€ã«âãããµãããââããªã¢ãžã³ãïŒïŒ
ïŒâããã«ã¹ã«ããã«âïŒâãããããŒã«ãªã©ïŒã
掻æ§ããã²ã³ååç©ïŒïŒïŒïŒâãžã¯ãã«âïŒâã
ãããã·ââããªã¢ãžã³ãªã©ïŒãã ã³ããã²ã³
é žé¡ïŒã ã³ã¯ãã«é žãã ã³ããšããã·ã¯ãã«é žãª
ã©ïŒããªã©ãåç¬ãŸãã¯çµåãããŠçšããããšã
ã§ããã æ¬çºæã®æå ææã®åçä¹³å€å±€ãŸãã¯ä»ã®èŠªæ°Ž
æ§ã³ãã€ãå±€ã«ã¯å¡åžå©å€ã垯é»é²æ¢ãã¹ããªæ§
æ¹è¯ãä¹³ååæ£ãæ¥çé²æ¢ãªã©çš®ã ã®ç®çã§çš®ã
ã®çé¢æŽ»æ§å€ãå«ãã§ãããã ããšãã°ãµããã³ïŒã¹ããã€ãç³»ïŒãã¢ã«ãã¬
ã³ãªããµã€ãèªå°äœïŒäŸãã°ããªãšãã¬ã³ã°ãªã³
ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ïŒããªãããã¬ã³
ã°ãªã³ãŒã«çž®åç©ãããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ãšãŒãã«é¡ãŸãã¯ããªãšãã¬ã³ã°ãªã³ãŒã«ã¢
ã«ãã«ã¢ãªãŒã«ãšãŒãã«é¡ãããªãšãã¬ã³ã°ãªã³
ãŒã«ãšã¹ãã«é¡ãããªãšãã¬ã³ã°ãªã³ãŒã«ãœã«ã
ã¿ã³ãšã¹ãã«é¡ãããªã¢ã«ãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ã¢ãã³ãŸãã¯ã¢ããé¡ãã·ãªã³ãŒã³ã®ããªãš
ãã¬ã³ãªããµã€ãä»å ç©é¡ïŒãã°ãªã·ããŒã«èªå°
äœïŒããšãã°ã¢ã«ã±ãã«ã³ãã¯é žããªã°ãªã»ãª
ããã¢ã«ãã«ãœãšããŒã«ããªã°ãªã»ãªãïŒãå€äŸ¡
ã¢ã«ã³ãŒã«ã®èèªé žãšã¹ãã«é¡ãç³ã®ã¢ã«ãã«ãš
ã¹ãã«é¡ãªã©ã®éã€ãªã³æ§çé¢æŽ»æ§å€ãã¢ã«ãã«
ã«ã«ãã³é žå¡©ãã¢ã«ãã«ã¹ã«ããªã³é žå¡©ãã¢ã«ã
ã«ãã³ãŒã³ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ããã¿ã¬ã³
ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ç¡«é žãšã¹ãã«é¡ãã¢ã«
ãã«ãªã³é žãšã¹ãã«é¡ãâã¢ã·ã«ââã¢ã«ã
ã«ã¿ãŠãªã³é¡ãã¹ã«ãã³ãã¯é žãšã¹ãã«é¡ãã¹ã«
ãã¢ã«ãã«ããªãªãã·ãšãã¬ã³ã¢ã«ãã«ããšãã«
ãšãŒãã«é¡ãããªãªãã·ãšãã¬ã³ã¢ã«ãã«ãªã³é ž
ãšã¹ãã«é¡ãªã©ã®ãããªãã«ã«ããã·åºãã¹ã«ã
åºããã¹ãåºãç¡«é žãšã¹ãã«åºãçé žãšã¹ãã«åº
çã®é žæ§åºãå«ãã¢ããªã³çé¢æŽ»æ§å€ïŒã¢ããé ž
é¡ãã¢ããã¢ã«ãã«ã¹ã«ãã³é žé¡ãã¢ããã¢ã«ã
ã«ç¡«é žãŸãã¯çé žãšã¹ãã«é¡ãã¢ã«ãã«ãã¿ã€ã³
é¡ãã¢ãã³ãªãã·ãé¡ãªã©ã®äž¡æ§çé¢æŽ»æ§å€ïŒã¢
ã«ãã«ã¢ãã³å¡©é¡ãèèªæãããã¯è³éŠæ第ïŒçŽ
ã¢ã³ã¢ããŠã å¡©é¡ãããªãžãŠã ãã€ãããŸãªãŠã
ãªã©ã®è€çŽ ç°ç¬¬ïŒçŽã¢ã³ã¢ããŠã å¡©é¡ãããã³è
èªæãŸãã¯è€çŽ ç°ãå«ããã¹ãããŠã ãŸãã¯ã¹ã«
ãããŠã å¡©é¡ãªã©ã®ã«ããªã³çé¢æŽ»æ§å€ãçšãã
ããšãã§ãããåãã©ããã¯ã¹ããªããŒçãæ·»å
ããŠãŒã©ãã³èã®ç©æ§ãæ¹è³ªããããã·ãªã«ãã
ã³ãã³ç²ããã³ãã€ãã«ã·ãªã«ãã¬ã©ã¹ç²ãªã©ã
æ·»å ããŠèé¢ããããåãããããããšãã§ã
ãã æ¬çºæã®æå ææã®åçä¹³å€å±€åã¯ä»ã®èŠªæ°Žæ§
ã³ãã€ãå±€ã«ã¯ãæå ææã®è£œé å·¥çšãä¿åäžã
ããã¯åçåŠçäžã®ã«ããªãé²æ¢ãããããã¯å
çæ§èœãå®å®åãããç®çã§ãåèšäžè¬åŒïŒïŒ
ã®ååç©ä»¥å€ã®çš®ã ã®ååç©ãå«æãããããšã
ã§ãããããªãã¡ã¢ãŸãŒã«é¡ãããšãã°ãã³ãŸã
ã¢ãŸãªãŠã å¡©ããããã€ã³ããŸãŒã«é¡ãããªã¢ãŸ
ãŒã«é¡ããã³ãŸããªã¢ãŸãŒã«é¡ããã³ãºã€ãããŸ
ãŒã«é¡ïŒç¹ã«ãããããŸãã¯ããã²ã³çœ®æäœïŒïŒ
ãããç°ã¡ã«ã«ããååç©é¡ãããšãã°ã¡ã«ã«ã
ããã¢ãŸãŒã«é¡ãã¡ã«ã«ãããã³ãŸãã¢ãŸãŒã«
é¡ãã¡ã«ã«ãããã³ãºã€ãããŸãŒã«é¡ãã¡ã«ã«ã
ããã¢ãžã¢ãŸãŒã«é¡ãã¡ã«ã«ããããã©ãŸãŒã«é¡
ïŒç¹ã«ïŒâããšãã«âïŒâã¡ã«ã«ããããã©ãŸãŒ
ã«ïŒãã¡ã«ã«ããããªããžã³é¡ïŒã«ã«ããã·ã«åº
ãã¹ã«ãã³åºãªã©ã®æ°Žæº¶æ§åºãæããäžèšã®ãã
ãç°ã¡ã«ã«ããååç©é¡ïŒããªã±ãååç©ãããš
ãã°ãªããµãŸãªã³ããªã³ïŒã¢ã¶ã€ã³ãã³é¡ãããš
ãã°ããã©ã¢ã¶ã€ã³ãã³é¡ïŒç¹ã«ïŒâããããã·
眮æïŒïŒïŒïŒïŒ3aïŒïŒïŒããã©ã¢ã¶ã€ã³ãã³
é¡ïŒïŒãã³ãŒã³ããªã¹ã«ãã³é žé¡ïŒãã³ãŒã³ã¹ã«
ãã€ã³é žïŒãªã©ã®ãããªã«ããªé²æ¢å€ãŸãã¯å®å®
å€ãšããŠç¥ãããå€ãã®ååç©ãå ããããšãã§
ããã æ¬çºæã®æå ææã¯ãåèšä»¥å€ã®çš®ã ã®åå
ç©ãäŸãã°åž¯é»é²æ¢å€ã玫å€ç·åžåå€ãå¯å¡å€ã
çŸåäž»è¬ããã¬ãŒã·ãšã³é²æ¢ææãèå ææãçŸ
åä¿é²å€ãã«ãã©ãŒçãã䜿çšããããšãã§ã
ãã æ¬çºæã®åçæå ææã«ãããŠã¯ãéåžžåçæ
å ææã®æ¯æäœãšããŠçšãããããã®ããã¹ãŠçš
ãããããäŸãã°ã»ã«ããŒã¹ãã€ãã¬ãŒããã€ã«
ã ãã»ã«ããŒã¹ã¢ã»ããŒããã€ã«ã ãã»ã«ããŒã¹
ã¢ã»ããŒãããã¬ãŒããã€ã«ã ãã»ã«ããŒã¹ã¢ã»
ããŒãããããªããŒããã€ã«ã ãããªã¹ãã¬ã³ã
ã€ã«ã ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€ã«ã ã
ããªã«ãŒãããŒããã€ã«ã ããã®ä»ãããã®ç©å±€
ç©ãçŽãªã©ãããããã©ã€ã¿åã¯Î±âãªã¬ãã€ã³
ããªããŒãç¹ã«ããªãšãã¬ã³ãããªãããã¬ã³ãª
ã©ççŽ ååïŒã10ã®Î±âãªã¬ãã€ã³ã®ããªããŒã
å¡åžãŸãã¯ã©ãããŒãããçŽãç¹å ¬æ47â19068
å·ã«ç€ºãããŠãããããªè¡šé¢ãç²é¢åããããšã«
ãã€ãŠãä»ã®é«ååç©è³ªãšã®å¯çæ§ãè¯åããäž
ã€å°å·é©æ§ãããããã©ã¹ããã¯ãã€ã«ã çã®æ¯
æäœãªã©ã奜é©ã§ããã åãæ¬çºæã®èŠªæ°Žæ§ã³ãã€ãå±€ã®å¡åžæ¹æ³ãšã
ãŠã¯ããšã¢ãŒãã¯ã¿ãŒããã¬ãŒãã³ãŒããã¹ã¯ã€
ãºã³ãŒãããšã¢ãŒãã€ãã³ãŒãããªããŒã¹ããŒã«
ã³ãŒãããã€ã¹ãã³ãŒãããšã¯ã¹ãã«ãŒãžãšã³ã³
ãŒãçã®æ¹æ³ãçšããããããããŠå¡åžéã¯ïŒã
15ÎŒïœããã奜ãŸããã¯ïŒã10ÎŒïœãšããããšã
奜ãŸããã æ¬çºæã®æå ææã¯ãåå°äœã¬ãŒã¶ãŒçšã®é»çœ
åçæå ææãéé¯å¡©æ¡æ£è»¢åæ³ãå©çšããå¹³ç
å°å·çãªã©ã«æçšã§ãããããã®ä»ã®çšéã«ã䜿
çšããããšãã§ããã (E) å®æœäŸ å®æœäŸ ïŒ éåžžã®ã³ã³ãããŒã«ããã«ãžãšããæ³ã«ããã
å¹³åç²åŸçŽ0.23ÎŒïœã®å¡©èåéïŒèåé10ã¢ã«ïŒ ïŒ
ä¹³å€ã調補ããæ²æŸ±ãæ°ŽæŽå溶解ããåŸããŒã©ã
ã³å¯Ÿéã0.6察1.0ã«åãããç¡«é»ïŒéå¢æããã
çµäºåŸãå¢æè²çŽ ãšããŠäŸç€ºè²çŽ (10)ãããã²ã³å
éïŒã¢ã«åœãïŒÃ10-4ã¢ã«æ·»å ãã硬èå€ãšçé¢
掻æ§å€ãå ããããã®ä¹³å€ãçåãã第ïŒè¡šã«ç€º
ãååç©ãæ·»å ããŠä»äžãä¹³å€ãšããã ãããã®ä¹³å€ãä¿è·å±€ïŒãŒã©ãã³ïŒïœïŒm2ïŒãš
å ±ã«ããªãšã¹ãã«ãã€ã«ã äžã«éïŒïœïŒm2ãšãªã
ããã«éå±€å¡åžããŠè©Šæãäœè£œããã ãããã®è©Šæã780nmã®å¹²æžãã€ã«ã¿ãŒãéã
ãŠ10-5ç§éã®ã»ã³ã·ãã¡ããªãŒé²å ãæœããã
PQçŸå液ã§çŸåããå®çãæ°ŽæŽã也ç¥ããŠç¹æ§
ãæ±ãããçµæã第ïŒè¡šã«ç€ºããæ床ã¯ãè©ŠæïŒ
ã100ãšããçžå¯Ÿå€ã§ç€ºããŠãããæ·»å éã¯ãã
ãã²ã³åéïŒã¢ã«åœãã®éïŒmgïŒã§ããã
ãè¡šã
第ïŒè¡šã¯ãæ¬çºæã®è©ŠæïŒãé«æ床ã§äœã«ããª
ã§ããããšã瀺ããŠããã å®æœäŸ ïŒ æ²åéïŒã¢ã«ïŒ ã®æ²èåéïŒå¹³åç²åŸ0.3ÎŒïœïŒ
ä¹³å€ãçšãã第ïŒè¡šã«ç€ºãååç©ãæ·»å ãã以å€
ã¯å®æœäŸïŒã«åŸã€ãã
ã§ããããšã瀺ããŠããã å®æœäŸ ïŒ æ²åéïŒã¢ã«ïŒ ã®æ²èåéïŒå¹³åç²åŸ0.3ÎŒïœïŒ
ä¹³å€ãçšãã第ïŒè¡šã«ç€ºãååç©ãæ·»å ãã以å€
ã¯å®æœäŸïŒã«åŸã€ãã
ãè¡šã
ãè¡šã
第ïŒè¡šã®çµæã¯ãæ¬çºæã®è©Šæ24ã29ãå®æœäŸ
ïŒãšåæ§ã«é«æ床ã§äœã«ããªã§ããããšã瀺ããŠ
ããã å®æœäŸ ïŒ äž¡é¢ãããªãšãã¬ã³æš¹èã§è¢«èŠããæ¯æäœã®ç
é¢ã«å¹³åç²åãµã€ãº5ÎŒã®ã·ãªã«ç²åãå«æãã
ãããåå±€ãèšããå察åŽã®é¢ã«ã«ãŒãã³ãã©ã
ã¯åã³ããšããã³ãå«ã¿ãåççšãŒã©ãã³ã«å¯Ÿã
ãŠ20ééïŒ ã®å¹³åç²åŸ7ÎŒïœã®ã·ãªã«ç²æ«ãå«ã
äžå¡å±€ïŒPH4.5ã«èª¿æŽïŒãšãéååç©ããã³ãã€
ãã§ååŠå¢æãããåŸã«ãïŒâã¡ã«ã«ããå®æ¯éŠ
é žãããã«å¹³åç²åŸ7ÎŒïœã®ã·ãªã«ç²æ«ãåççš
ãŒã©ãã³ã«å¯ŸããŠïŒééïŒ ã®å²åã§å«ãããã²ã³
åéä¹³å€å±€ïŒPH4.5ã«èª¿æŽïŒãšãèšããã ããã²ã³åéä¹³å€ã¯ãå¢æè²çŽ (13)ãããã²ã³å
éïŒã¢ã«åœã1.0Ã10-4ã¢ã«ãå«ãã§ããããŸã
ç©ççææã«ããã²ã³åéïŒã¢ã«åœãïŒÃ10-7ã¢
ã«ã®ã€ãªãžãŠã ãæ·»å ãããã®ã§ãããå¹³åç²åŸ
0.42ãã¯ãã³ã§ãå¹³åç²åŸã®Â±30ïŒ ã®ç¯å²ã«å šç²
åæ°ã®90ïŒ ä»¥äžãååžããŠãããå®è³ªçã«ç«æ¹äœ
ã®å¡©åéçµæ¶ã§ãã€ãã äžå¡å±€ã®ãŒã©ãã³ã¯3.0ïœïŒm2ãä¹³å€å±€ã®ãŒã©
ãã³ã¯1.0ïœïŒm2ãç¡é žéã«æç®ããããã²ã³å
é1.0ïœïŒm2ã®å²åã§å¡åžãããããã®äžå¡å±€ãš
ä¹³å€å±€ã¯ç¡¬åå€ãšããã«ããªã³ããŒã©ãã³ã«å¯Ÿã
ãŠ5.0mgïŒïœãŒã©ãã³ã®éã§å«ãã§ããã äžå¡å±€ã®780nmã«ãããå åŠåå°æ¿åºŠã¯ã0.83
ã§ãã€ãã也ç¥åŸã40âã§14æ¥éå æž©ããåŸãã
ã®ä¹³å€å±€ã®äžã«ãç¹éæ54â103104å·æ现æžã®å®
æœäŸïŒã«æŒãããã¬ãŒãNo.11ã®æ žå¡æ¶²ã«ãã€ãã
ããã³0.8ïœïŒm2ãšãªãããã«å ãã液ãåæ§ã«
ããŠèª¿è£œããå¡åžããïŒæ¯èŒå¹³çå°å·çïŒã æ¯èŒå¹³çå°å·çã®ããã²ã³åéä¹³å€ã«ç¬¬ïŒè¡š
ã«ç€ºãååç©ãæ·»å ããŠåæ§ã«ïŒçš®ã®å¹³çå°å·ç
ãäœè£œããã å æºã«çŽ700nmããé·æ³¢é·ã®å ãééããæèµ€
è²ãã€ã«ã¿ãŒãã€ããæ¿åºŠå·®0.15ã®ãŠãšããžãé
ããŠåã ã®å¹³çå°å·çã10-5ç§ã§é²å ããã 次ãã§åå°å·çãå ¬ç¥ã®DTRçŸå液ã§çŸåãã
é žæ§ã®äžå液ã§åŠçãããçµæã第ïŒè¡šã«ç€ºãã
ïŒãšåæ§ã«é«æ床ã§äœã«ããªã§ããããšã瀺ããŠ
ããã å®æœäŸ ïŒ äž¡é¢ãããªãšãã¬ã³æš¹èã§è¢«èŠããæ¯æäœã®ç
é¢ã«å¹³åç²åãµã€ãº5ÎŒã®ã·ãªã«ç²åãå«æãã
ãããåå±€ãèšããå察åŽã®é¢ã«ã«ãŒãã³ãã©ã
ã¯åã³ããšããã³ãå«ã¿ãåççšãŒã©ãã³ã«å¯Ÿã
ãŠ20ééïŒ ã®å¹³åç²åŸ7ÎŒïœã®ã·ãªã«ç²æ«ãå«ã
äžå¡å±€ïŒPH4.5ã«èª¿æŽïŒãšãéååç©ããã³ãã€
ãã§ååŠå¢æãããåŸã«ãïŒâã¡ã«ã«ããå®æ¯éŠ
é žãããã«å¹³åç²åŸ7ÎŒïœã®ã·ãªã«ç²æ«ãåççš
ãŒã©ãã³ã«å¯ŸããŠïŒééïŒ ã®å²åã§å«ãããã²ã³
åéä¹³å€å±€ïŒPH4.5ã«èª¿æŽïŒãšãèšããã ããã²ã³åéä¹³å€ã¯ãå¢æè²çŽ (13)ãããã²ã³å
éïŒã¢ã«åœã1.0Ã10-4ã¢ã«ãå«ãã§ããããŸã
ç©ççææã«ããã²ã³åéïŒã¢ã«åœãïŒÃ10-7ã¢
ã«ã®ã€ãªãžãŠã ãæ·»å ãããã®ã§ãããå¹³åç²åŸ
0.42ãã¯ãã³ã§ãå¹³åç²åŸã®Â±30ïŒ ã®ç¯å²ã«å šç²
åæ°ã®90ïŒ ä»¥äžãååžããŠãããå®è³ªçã«ç«æ¹äœ
ã®å¡©åéçµæ¶ã§ãã€ãã äžå¡å±€ã®ãŒã©ãã³ã¯3.0ïœïŒm2ãä¹³å€å±€ã®ãŒã©
ãã³ã¯1.0ïœïŒm2ãç¡é žéã«æç®ããããã²ã³å
é1.0ïœïŒm2ã®å²åã§å¡åžãããããã®äžå¡å±€ãš
ä¹³å€å±€ã¯ç¡¬åå€ãšããã«ããªã³ããŒã©ãã³ã«å¯Ÿã
ãŠ5.0mgïŒïœãŒã©ãã³ã®éã§å«ãã§ããã äžå¡å±€ã®780nmã«ãããå åŠåå°æ¿åºŠã¯ã0.83
ã§ãã€ãã也ç¥åŸã40âã§14æ¥éå æž©ããåŸãã
ã®ä¹³å€å±€ã®äžã«ãç¹éæ54â103104å·æ现æžã®å®
æœäŸïŒã«æŒãããã¬ãŒãNo.11ã®æ žå¡æ¶²ã«ãã€ãã
ããã³0.8ïœïŒm2ãšãªãããã«å ãã液ãåæ§ã«
ããŠèª¿è£œããå¡åžããïŒæ¯èŒå¹³çå°å·çïŒã æ¯èŒå¹³çå°å·çã®ããã²ã³åéä¹³å€ã«ç¬¬ïŒè¡š
ã«ç€ºãååç©ãæ·»å ããŠåæ§ã«ïŒçš®ã®å¹³çå°å·ç
ãäœè£œããã å æºã«çŽ700nmããé·æ³¢é·ã®å ãééããæèµ€
è²ãã€ã«ã¿ãŒãã€ããæ¿åºŠå·®0.15ã®ãŠãšããžãé
ããŠåã ã®å¹³çå°å·çã10-5ç§ã§é²å ããã 次ãã§åå°å·çãå ¬ç¥ã®DTRçŸå液ã§çŸåãã
é žæ§ã®äžå液ã§åŠçãããçµæã第ïŒè¡šã«ç€ºãã
ãè¡šã
äžæ¹ãåå¹³çå°å·çã®æ床ã«å¿ããé©æ£é²å
ã
780nmã§çºå ããã¬ãŒã¶ãŒãã€ãªãŒãã»ã¹ãã€ã
ãŒãUltre SetterïŒç±³åœUltre瀟補ïŒã«ãŠäžããã 以åŸåæ§ã«ããŠçŸåãäžååŠçããŠè£œçããå°
å·ãããšãããæ¬çºæã®å¹³çå°å·çåã³ïŒ§ã¯ã
æ¯èŒã®å¹³çå°å·çããèå·åã«åªããŠããã å®æœäŸ ïŒ äŸç€ºè²çŽ (13)ã®ä»£ãã«äŸç€ºè²çŽ (15)ãïŒ23ïŒåã¯
ïŒ28ïŒãçšãã以å€ã¯å®æœäŸïŒãšåæ§ã«è¡ã€ãã
å®æœäŸïŒãšåæ§ãªçµæãåŸãããã (F) çºæã®å¹æ æ¬çºæã«ããã°ã700nmããšãã«750nm以äžã®
èµ€å€åã«æ¥µå€§åå æ床ãæããå¢æè²çŽ ã®æ床ã
ç¹å®ã®ã¡ã«ã«ããååç©ã®çµã¿åããã«ããäžæ
ãããããšãåºæ¥ããŸãã«ããªãæžå°ãããããš
ãåºæ¥ãã®ã§ãåå°äœã¬ãŒã¶ãŒçšã«é©ããé«æ床
ã®ããã²ã³åéåçæå ææãåŸãããšãåºæ¥
ãã
780nmã§çºå ããã¬ãŒã¶ãŒãã€ãªãŒãã»ã¹ãã€ã
ãŒãUltre SetterïŒç±³åœUltre瀟補ïŒã«ãŠäžããã 以åŸåæ§ã«ããŠçŸåãäžååŠçããŠè£œçããå°
å·ãããšãããæ¬çºæã®å¹³çå°å·çåã³ïŒ§ã¯ã
æ¯èŒã®å¹³çå°å·çããèå·åã«åªããŠããã å®æœäŸ ïŒ äŸç€ºè²çŽ (13)ã®ä»£ãã«äŸç€ºè²çŽ (15)ãïŒ23ïŒåã¯
ïŒ28ïŒãçšãã以å€ã¯å®æœäŸïŒãšåæ§ã«è¡ã€ãã
å®æœäŸïŒãšåæ§ãªçµæãåŸãããã (F) çºæã®å¹æ æ¬çºæã«ããã°ã700nmããšãã«750nm以äžã®
èµ€å€åã«æ¥µå€§åå æ床ãæããå¢æè²çŽ ã®æ床ã
ç¹å®ã®ã¡ã«ã«ããååç©ã®çµã¿åããã«ããäžæ
ãããããšãåºæ¥ããŸãã«ããªãæžå°ãããããš
ãåºæ¥ãã®ã§ãåå°äœã¬ãŒã¶ãŒçšã«é©ããé«æ床
ã®ããã²ã³åéåçæå ææãåŸãããšãåºæ¥
ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ 700nm以äžã«æ¥µå€§åå æ床ãæããå¢æè²çŽ
ã§å åŠå¢æããããã²ã³åéä¹³å€å±€ãæããæå
ææã«ãããŠã該乳å€å±€ã«äžèšäžè¬åŒïŒïŒåã³
äžè¬åŒïŒïŒã§è¡šããããååç©ãããããå°ãª
ããšãäžã€å«æããããšãç¹åŸŽãšããããã²ã³å
éåçæå ææã äžè¬åŒïŒïŒ ïŒåŒäžãR1åã³R2ã¯ãããããæ°ŽçŽ ååãã¢ã«
ãã«åºãã¢ãªãŒã«åºãã¢ã©ã«ãã«åºãã¢ã«ã±ãã«
åºãã¢ããåºãã¢ã·ã«ã¢ããåºãã¹ã«ãã³ã¢ãã
åºãè¡šãããR1åã³R2ã®ççŽ æ°ã®åã¯ïŒä»¥äžã§
ãããïŒ äžè¬åŒïŒïŒ ïŒåŒäžãR3ã¯ãççŽ ååïŒå以äžãæããã¢ã«
ãã«åºãã¢ãªãŒã«åºãè¡šãããïŒ
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP17079487A JPS6413539A (en) | 1987-07-07 | 1987-07-07 | Silver halide photographic sensitive material |
US07/181,008 US4910129A (en) | 1987-04-17 | 1988-04-13 | Silver halide photographic light sensitive material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP17079487A JPS6413539A (en) | 1987-07-07 | 1987-07-07 | Silver halide photographic sensitive material |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6413539A JPS6413539A (en) | 1989-01-18 |
JPH0551887B2 true JPH0551887B2 (ja) | 1993-08-03 |
Family
ID=15911479
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP17079487A Granted JPS6413539A (en) | 1987-04-17 | 1987-07-07 | Silver halide photographic sensitive material |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6413539A (ja) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0778611B2 (ja) * | 1988-11-15 | 1995-08-23 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéåçä¹³å€ |
JPH03156443A (ja) * | 1989-11-15 | 1991-07-04 | Fuji Photo Film Co Ltd | ããã²ã³åéåçæå ææ |
JPH03202849A (ja) * | 1989-12-28 | 1991-09-04 | Konica Corp | ã¬ãŒã¶ãŒå æºçšããã²ã³åéåçæå ææ |
IT1237964B (it) * | 1990-02-01 | 1993-06-19 | Minnesota Mining & Mfg | Elementi fotografici agli alogenuri d'argento sensibili all'infrarosso |
JP2663033B2 (ja) * | 1990-02-22 | 1997-10-15 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéä¹³å€ |
JP2597432B2 (ja) * | 1991-04-26 | 1997-04-09 | äžè±è£œçŽæ ªåŒäŒç€Ÿ | ããã²ã³åéåçæå ææ |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5714836A (en) * | 1980-07-01 | 1982-01-26 | Fuji Photo Film Co Ltd | Photographic sensitive silver halide material |
JPS5968732A (ja) * | 1982-10-13 | 1984-04-18 | Fuji Photo Film Co Ltd | ããã²ã³åéåçæå ææ |
-
1987
- 1987-07-07 JP JP17079487A patent/JPS6413539A/ja active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5714836A (en) * | 1980-07-01 | 1982-01-26 | Fuji Photo Film Co Ltd | Photographic sensitive silver halide material |
JPS5968732A (ja) * | 1982-10-13 | 1984-04-18 | Fuji Photo Film Co Ltd | ããã²ã³åéåçæå ææ |
Also Published As
Publication number | Publication date |
---|---|
JPS6413539A (en) | 1989-01-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPH10197978A (ja) | ããã²ã³åéåçæå ææ | |
US4948699A (en) | Silver halide photographic light sensitive material and light sensitive lithographic printing plate material | |
JPH0551887B2 (ja) | ||
US4910129A (en) | Silver halide photographic light sensitive material | |
JP2593878B2 (ja) | ããã²ã³åéåçæå ææ | |
JPS6232444A (ja) | ããã²ã³åéåçæå ææ | |
JP3030259B2 (ja) | ã¬ãŒã¶ãŒèšé²å»ççšããŒãã³ããŒææãšããŠäœ¿çšããããã®å¡©åéãªããã®æå æ§åçææäžã«é»åçã«è²¯èµãããå»ççšç»åãåçããæ¹æ³ | |
JPS63292125A (ja) | ããã²ã³åéåçæå ææ | |
JP3238777B2 (ja) | èµ€å€ç·ã«é«æ床ã®åçèŠçŽ | |
JPH03276152A (ja) | èå§æ§ãæ¹è¯ãããããã²ã³åéåçæå ææåã³åŠçæ¹æ³ | |
JP2597440B2 (ja) | ããã²ã³åéåçæå ææ | |
JP2572257B2 (ja) | ããã²ã³åéåçæå ææã·ãŒããŠããã | |
JP2597429B2 (ja) | ããã²ã³åéåçæå ææ | |
EP0351077B1 (en) | Bright safe light handleable high contrast photographic materials | |
JPH09222687A (ja) | ããã²ã³åéåçæå ææ | |
JPH05307220A (ja) | ããã²ã³åéåçæå ææ | |
JPH11202442A (ja) | ããã²ã³åéåçæå ææ | |
JPH05313271A (ja) | ããã²ã³åéåçä¹³å€ã®è£œé æ¹æ³ | |
JP2577595B2 (ja) | ã¬ãŒã¶ãŒå æºçšããã²ã³åéåçæå ææå è£ ãŠããã | |
JP3995823B2 (ja) | ããã²ã³åéåçæå ææ | |
JPH11295850A (ja) | ããã²ã³åéåçæå ææã®è£œé æ¹æ³ | |
JPH07234466A (ja) | ããã²ã³åéåçæå ææ | |
JPH02110543A (ja) | ããã²ã³åéåçæå ææ | |
JPH06273879A (ja) | ããã²ã³åéåçææ | |
JPH06130539A (ja) | ããã²ã³åéåçæå ææ |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
EXPY | Cancellation because of completion of term |