JPH0456044B2 - - Google Patents

Info

Publication number: JPH0456044B2
Authority: JP; Japan
Prior art keywords: weight; parts; monomer mixture; vinyl; compound
Prior art date: 1986-12-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP30605186A

Other languages

English (en)

Japanese (ja)

Other versions

JPS63156847A (ja

Inventor

Shigemi Matsumoto

Takao Shibata

Kazuhito Wada

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Kanegafuchi Chemical Industry Co Ltd

Original Assignee

Kanegafuchi Chemical Industry Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-12-22

Filing date

1986-12-22

Publication date

1992-09-07

1986-12-22 Application filed by Kanegafuchi Chemical Industry Co Ltd filed Critical Kanegafuchi Chemical Industry Co Ltd

1986-12-22 Priority to JP30605186A priority Critical patent/JPS63156847A/ja

1988-06-29 Publication of JPS63156847A publication Critical patent/JPS63156847A/ja

1992-09-07 Publication of JPH0456044B2 publication Critical patent/JPH0456044B2/ja

Status Granted legal-status Critical Current

Links

239000000203 mixture Substances 0.000 claims description 34
239000000178 monomer Substances 0.000 claims description 31
-1 vinyl cyanide compound Chemical class 0.000 claims description 17
229920002554 vinyl polymer Polymers 0.000 claims description 12
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 11
229920001971 elastomer Polymers 0.000 claims description 10
230000000379 polymerizing effect Effects 0.000 claims description 8
238000004519 manufacturing process Methods 0.000 claims description 4
229920005992 thermoplastic resin Polymers 0.000 claims description 4
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
125000003118 aryl group Chemical group 0.000 claims 2
MPDDTAJMJCESGV-CTUHWIOQSA-M (3r,5r)-7-[2-(4-fluorophenyl)-5-[methyl-[(1r)-1-phenylethyl]carbamoyl]-4-propan-2-ylpyrazol-3-yl]-3,5-dihydroxyheptanoate Chemical compound C1([C@@H](C)N(C)C(=O)C2=NN(C(CC[C@@H](O)C[C@@H](O)CC([O-])=O)=C2C(C)C)C=2C=CC(F)=CC=2)=CC=CC=C1 MPDDTAJMJCESGV-CTUHWIOQSA-M 0.000 claims 1
LVDRREOUMKACNJ-BKMJKUGQSA-N N-[(2R,3S)-2-(4-chlorophenyl)-1-(1,4-dimethyl-2-oxoquinolin-7-yl)-6-oxopiperidin-3-yl]-2-methylpropane-1-sulfonamide Chemical compound CC(C)CS(=O)(=O)N[C@H]1CCC(=O)N([C@@H]1c1ccc(Cl)cc1)c1ccc2c(C)cc(=O)n(C)c2c1 LVDRREOUMKACNJ-BKMJKUGQSA-N 0.000 claims 1
229940125773 compound 10 Drugs 0.000 claims 1
ZLVXBBHTMQJRSX-VMGNSXQWSA-N jdtic Chemical compound C1([C@]2(C)CCN(C[C@@H]2C)C[C@H](C(C)C)NC(=O)[C@@H]2NCC3=CC(O)=CC=C3C2)=CC=CC(O)=C1 ZLVXBBHTMQJRSX-VMGNSXQWSA-N 0.000 claims 1
235000021122 unsaturated fatty acids Nutrition 0.000 claims 1
150000004670 unsaturated fatty acids Chemical class 0.000 claims 1
229920005989 resin Polymers 0.000 description 7
239000011347 resin Substances 0.000 description 7
238000006116 polymerization reaction Methods 0.000 description 6
239000002253 acid Substances 0.000 description 5
238000007720 emulsion polymerization reaction Methods 0.000 description 5
238000000034 method Methods 0.000 description 5
150000007513 acids Chemical class 0.000 description 4
229920000126 latex Polymers 0.000 description 4
238000002156 mixing Methods 0.000 description 4
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000004816 latex Substances 0.000 description 3
238000000465 moulding Methods 0.000 description 3
229920002857 polybutadiene Polymers 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
239000000843 powder Substances 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
239000005062 Polybutadiene Substances 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
150000008360 acrylonitriles Chemical class 0.000 description 2
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
238000012662 bulk polymerization Methods 0.000 description 2
239000001110 calcium chloride Substances 0.000 description 2
229910001628 calcium chloride Inorganic materials 0.000 description 2
229920003244 diene elastomer Polymers 0.000 description 2
239000003999 initiator Substances 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 2
229940082004 sodium laurate Drugs 0.000 description 2
239000000126 substance Substances 0.000 description 2
238000010557 suspension polymerization reaction Methods 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
IYMZEPRSPLASMS-UHFFFAOYSA-N 3-phenylpyrrole-2,5-dione Chemical compound O=C1NC(=O)C(C=2C=CC=CC=2)=C1 IYMZEPRSPLASMS-UHFFFAOYSA-N 0.000 description 1
JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 1
ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
229920002943 EPDM rubber Polymers 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 1
229920000800 acrylic rubber Polymers 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
229910001870 ammonium persulfate Inorganic materials 0.000 description 1
YIEXROAWVNRRMJ-UHFFFAOYSA-N buta-1,3-diene;butyl prop-2-enoate Chemical compound C=CC=C.CCCCOC(=O)C=C YIEXROAWVNRRMJ-UHFFFAOYSA-N 0.000 description 1
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
230000001112 coagulating effect Effects 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000004040 coloring Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000002845 discoloration Methods 0.000 description 1
235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 1
239000002612 dispersion medium Substances 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
239000011790 ferrous sulphate Substances 0.000 description 1
235000003891 ferrous sulphate Nutrition 0.000 description 1
239000000945 filler Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
238000010528 free radical solution polymerization reaction Methods 0.000 description 1
VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
238000005259 measurement Methods 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
239000002530 phenolic antioxidant Substances 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920005668 polycarbonate resin Polymers 0.000 description 1
239000004431 polycarbonate resin Substances 0.000 description 1
229920006124 polyolefin elastomer Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
AZIQALWHRUQPHV-UHFFFAOYSA-N prop-2-eneperoxoic acid Chemical compound OOC(=O)C=C AZIQALWHRUQPHV-UHFFFAOYSA-N 0.000 description 1
239000011342 resin composition Substances 0.000 description 1
XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
239000005060 rubber Substances 0.000 description 1
238000010058 rubber compounding Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
229920003048 styrene butadiene rubber Polymers 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)
Graft Or Block Polymers (AREA)

JP30605186A 1986-12-22 1986-12-22 艶消し性熱可塑性樹脂の製造方法 Granted JPS63156847A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP30605186A JPS63156847A (ja)	1986-12-22	1986-12-22	艶消し性熱可塑性樹脂の製造方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP30605186A JPS63156847A (ja)	1986-12-22	1986-12-22	艶消し性熱可塑性樹脂の製造方法

Publications (2)

Publication Number	Publication Date
JPS63156847A JPS63156847A (ja)	1988-06-29
JPH0456044B2 true JPH0456044B2 (zh)	1992-09-07

Family

ID=17952462

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP30605186A Granted JPS63156847A (ja)	1986-12-22	1986-12-22	艶消し性熱可塑性樹脂の製造方法

Country Status (1)

Country	Link
JP (1)	JPS63156847A (zh)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0721096B2 (ja) *	1987-12-18	1995-03-08	日本合成ゴム株式会社	熱可塑性樹脂組成物
JPH075814B2 (ja) *	1988-07-05	1995-01-25	東レ株式会社	繊維強化熱可塑性樹脂組成物
JPH02214712A (ja) *	1989-02-15	1990-08-27	Hitachi Chem Co Ltd	艶消し剤および艶消し熱可塑性樹脂組成物
US5026777A (en) *	1989-11-17	1991-06-25	General Electric Company	Low gloss thermoplastic molding compositions
EP0700971A3 (en)	1994-09-12	1996-07-17	Gen Electric	Polycarbonate mixture for casting objects with low gloss
US20110077355A1 (en)	2007-08-21	2011-03-31	Yoshifumi Shikisai	Method Of Producing Enlarged Rubber, Graft Copolymer, Thermoplastic Resin Composition And Molded Article
JP5139195B2 (ja) *	2008-08-08	2013-02-06	日本エイアンドエル株式会社	ゴム強化スチレン系樹脂を製造する方法

1986
- 1986-12-22 JP JP30605186A patent/JPS63156847A/ja active Granted

Also Published As

Publication number	Publication date
JPS63156847A (ja)	1988-06-29

Publication	Publication Date	Title
JPH0576500B2 (zh)	1993-10-22
JPH0456044B2 (zh)	1992-09-07
JPH0423661B2 (zh)	1992-04-22
US4694032A (en)	1987-09-15	Process for preparing thermoplastic resin composition
JPS6234069B2 (zh)	1987-07-24
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JPH08143768A (ja)	1996-06-04	耐熱性熱可塑性樹脂組成物
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JP2787340B2 (ja)	1998-08-13	耐熱性熱可塑性樹脂組成物
KR940011156B1 (ko)	1994-11-24	내열성 공중합체의 제조 방법
US11339237B2 (en)	2022-05-24	Method of preparing thermoplastic resin, thermoplastic resin prepared therfrom and thermoplastic resin composition comprising the same
JPH0424379B2 (zh)	1992-04-24
JP2558135B2 (ja)	1996-11-27	優れた艶消し性を有する熱可塑性樹脂組成物
JPH06299045A (ja)	1994-10-25	艶消し性熱可塑性樹脂組成物
JPH0273841A (ja)	1990-03-13	強化熱可塑性樹脂組成物
US4100126A (en)	1978-07-11	Stabilization of nitrile resins with half acid salts of maleic acid
KR100402281B1 (ko)	2003-10-22	내충격성, 광택도 및 내후성이 우수한 열가소성 수지조성물 및 그 제조방법
JPS624713A (ja)	1987-01-10	熱可塑性成形材料の変性のためのグラフトゴム
JPS639545B2 (zh)	1988-02-29
JPH0411585B2 (zh)	1992-02-28
JPS6246564B2 (zh)	1987-10-02
JPH0735462B2 (ja)	1995-04-19	艶消し性を有する熱可塑性樹脂組成物