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JPH04217370A - Gate electrode of thin film transistor and manufacture thereof - Google Patents

Gate electrode of thin film transistor and manufacture thereof

Info

Publication number
JPH04217370A
JPH04217370A JP40353790A JP40353790A JPH04217370A JP H04217370 A JPH04217370 A JP H04217370A JP 40353790 A JP40353790 A JP 40353790A JP 40353790 A JP40353790 A JP 40353790A JP H04217370 A JPH04217370 A JP H04217370A
Authority
JP
Japan
Prior art keywords
metal layer
layer
film transistor
thin film
gate electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP40353790A
Other languages
Japanese (ja)
Inventor
田中 栄
Sakae Tanaka
白井 勝夫
Katsuo Shirai
荻原 芳久
Yoshihisa Ogiwara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Precision Circuits Inc
Seikosha KK
Original Assignee
Nippon Precision Circuits Inc
Seikosha KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Precision Circuits Inc, Seikosha KK filed Critical Nippon Precision Circuits Inc
Priority to JP40353790A priority Critical patent/JPH04217370A/en
Publication of JPH04217370A publication Critical patent/JPH04217370A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/43Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/49Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
    • H01L29/4908Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET for thin film semiconductor, e.g. gate of TFT

Landscapes

  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Electrodes Of Semiconductors (AREA)
  • Thin Film Transistor (AREA)

Abstract

PURPOSE:To reduce the manufacturing cost of the gate electrode of a thin-film transistor by making another kind of three-layer structured electrode allowing wet etching in place of the conventional Ta/Cu/Ta electrode requiring dry etching of Ta. CONSTITUTION:A gate electrode for a thin film transistor comprises a first metal layer 12, which is a bottom layer, a second metal layer 13 mainly composed of copper, and a third metal layer 14. The metal layer 14 is formed with metals, such as molybdenum(Mo) or chrome(Cr) which are easy to carry out wet etching.

Description

【発明の詳細な説明】[Detailed description of the invention]

【0001】0001

【産業上の利用分野】本発明は薄膜トランジスタのゲ−
ト電極およびその製造方法に関する。
[Industrial Application Field] The present invention relates to a thin film transistor gate.
The present invention relates to an electrode and a method for manufacturing the same.

【0002】0002

【従来の技術】薄膜トランジスタをアレイ状に形成した
もの(以下、薄膜トランジスタアレイという。)では、
ゲ−ト電極およびゲ−ト配線の抵抗値を低減するために
ゲ−ト電極およびゲ−ト配線に銅(Cu )を用いたも
のがある。通常は、銅層を保護するために、銅層の上下
にタンタル(Ta )層を形成し、Ta /Cu /T
a の3層構造としている。
[Prior Art] In an array of thin film transistors (hereinafter referred to as a thin film transistor array),
Some devices use copper (Cu) for the gate electrode and gate wiring in order to reduce the resistance value of the gate electrode and gate wiring. Usually, tantalum (Ta) layers are formed above and below the copper layer to protect the copper layer, and Ta/Cu/T
It has a three-layer structure.

【0003】0003

【発明が解決しようとする課題】しかしながら、上記従
来のゲ−ト電極構造では、タンタル層をドライエッチン
グ法を用いてエッチングしなければならず、製造コスト
が高くなるという問題点があった。
However, the conventional gate electrode structure described above has the problem that the tantalum layer must be etched using a dry etching method, which increases manufacturing costs.

【0004】本発明の目的は、ゲ−ト電極を3層構造に
しても安価に製造可能な薄膜トランジスタのゲ−ト電極
およびその製造方法を提供することである。
SUMMARY OF THE INVENTION An object of the present invention is to provide a gate electrode for a thin film transistor that can be manufactured at low cost even if the gate electrode has a three-layer structure, and a method for manufacturing the same.

【0005】[0005]

【課題を解決するための手段】本発明における薄膜トラ
ンジスタのゲ−ト電極は、銅層上にモリブデン(Mo)
やクロム(Cr )等のウエットエッチングが容易な金
属を主成分とする金属層を形成したものである。
[Means for Solving the Problems] The gate electrode of the thin film transistor in the present invention is made of molybdenum (Mo) on a copper layer.
A metal layer whose main component is a metal that can be easily wet-etched, such as chromium (Cr) or the like, is formed.

【0006】また、上記薄膜トランジスタのゲ−ト電極
の製造方法は、3層構造のゲ−ト電極を形成する際に、
フォトレジスト等のマスク層をマスクとして、銅層およ
び銅層上の金属層を同一のエッチング液を用いてエッチ
ングするものである。
[0006] Furthermore, in the method for manufacturing a gate electrode of a thin film transistor, when forming a gate electrode having a three-layer structure,
Using a mask layer such as photoresist as a mask, the copper layer and the metal layer on the copper layer are etched using the same etching solution.

【0007】[0007]

【実施例】図1〜図3は、薄膜トランジスタアレイのゲ
−ト電極およびゲ−ト配線の製造工程を示した断面図で
ある。
DESCRIPTION OF THE PREFERRED EMBODIMENTS FIGS. 1 to 3 are cross-sectional views showing the manufacturing process of gate electrodes and gate wiring of a thin film transistor array.

【0008】絶縁基板11にはガラスが用いられる。第
1金属層12にはチタン(Ti )層が用いられ、その
層厚は50〜100nmである。第2金属層13には銅
(Cu)層が用いられ、その層厚は200nmである。 第3金属層14にはモリブデン(Mo )層またはクロ
ム(Cr )層が用いられ、その層厚は50nmである
Glass is used for the insulating substrate 11. A titanium (Ti) layer is used for the first metal layer 12, and the layer thickness is 50 to 100 nm. A copper (Cu) layer is used for the second metal layer 13, and the layer thickness is 200 nm. A molybdenum (Mo 2 ) layer or a chromium (Cr 2 ) layer is used for the third metal layer 14, and the layer thickness is 50 nm.

【0009】つぎに、図1〜図3を用いて製造工程の説
明をする。
Next, the manufacturing process will be explained using FIGS. 1 to 3.

【0010】 (A)絶縁基板11上に、第1金属層12となるチタン
層をスパッタリング法で形成する。チタン層はガラス基
板11に対する付着力が強く、膜剥がれが生じ難い。引
き続き第1金属層12上に、第2金属層13となる銅層
をスパッタリング法で形成する。引き続き第2金属13
上に、第3金属層14となるモリブデン層またはクロム
層をスパッタリング法で形成する。第3金属層14上に
、ゲ−ト電極およびゲ−ト配線の平面形状を有するマス
ク層15を、フォトレジストを用いて形成する(図1参
照)。
(A) A titanium layer that will become the first metal layer 12 is formed on the insulating substrate 11 by sputtering. The titanium layer has strong adhesion to the glass substrate 11 and is unlikely to peel off. Subsequently, a copper layer that will become the second metal layer 13 is formed on the first metal layer 12 by sputtering. Continue with the second metal 13
A molybdenum layer or a chromium layer, which will become the third metal layer 14, is formed thereon by sputtering. A mask layer 15 having a planar shape of a gate electrode and a gate wiring is formed on the third metal layer 14 using a photoresist (see FIG. 1).

【0011】 (B)マスク層15をマスクとして、第1金属層12、
第2金属層13および第3金属層14をエッチングする
。第3金属層14および第2金属層13は同一のウエッ
トエッチング液を用いてウエットエッチングする。エッ
チング液には、硝酸+酢酸+硝酸第2セリウムアンモニ
ウム(Ce (NH4 )2 (NO3 )6 )の混
合水溶液を用いる。なお、第3金属層14としてモリブ
デン層を用いる場合には、必ずしも硝酸を混合する必要
はない。 第3金属層14および第2金属層13の側壁をテ−パ−
状に形成するには、エッチング液に含まれる酸化剤(酢
酸、硝酸)の混合割合を適宜選定し、第3金属層14の
エッチングレ−トを第2金属層13のエッチングレ−ト
よりも大にすればよい。第3金属層14および第2金属
層13をエッチング後、希フッ酸ボイルまたはリン酸水
溶液ボイルにより第1金属層12をエッチングする。な
お、CF4 ガス等を用いたドライエッチング法で第1
金属層12をエッチングしてもよい(図2参照)。
(B) Using the mask layer 15 as a mask, the first metal layer 12,
The second metal layer 13 and the third metal layer 14 are etched. The third metal layer 14 and the second metal layer 13 are wet-etched using the same wet etching solution. As the etching solution, a mixed aqueous solution of nitric acid + acetic acid + ceric ammonium nitrate (Ce (NH4) 2 (NO3) 6 ) is used. Note that when a molybdenum layer is used as the third metal layer 14, it is not necessarily necessary to mix nitric acid. The side walls of the third metal layer 14 and the second metal layer 13 are tapered.
In order to form the third metal layer 14, the mixing ratio of the oxidizing agent (acetic acid, nitric acid) contained in the etching solution is appropriately selected so that the etching rate of the third metal layer 14 is higher than that of the second metal layer 13. Just make it bigger. After etching the third metal layer 14 and the second metal layer 13, the first metal layer 12 is etched using dilute hydrofluoric acid boiling or phosphoric acid aqueous solution boiling. Note that the first step is performed using a dry etching method using CF4 gas, etc.
The metal layer 12 may also be etched (see FIG. 2).

【0012】 (C)マスク層15を除去し、テ−パ−形状を有するゲ
−ト電極およびゲ−ト配線が形成される(図3参照)。
(C) Mask layer 15 is removed, and a gate electrode and gate wiring having a tapered shape are formed (see FIG. 3).

【0013】図4は、薄膜トランジスタアレイにおける
薄膜トランジスタの断面図である。
FIG. 4 is a cross-sectional view of a thin film transistor in a thin film transistor array.

【0014】この薄膜トランジスタは、図1〜図3の工
程でゲ−ト電極およびゲ−ト配線を形成した後、ゲ−ト
絶縁層となる窒化シリコン層15(層厚100〜150
nm)および酸化シリコン層16(層厚400〜500
nm)、アモルファスシリコン層17、n+ アモルフ
ァスシリコン層18、ソ−ス電極およびドレイン電極と
なるITO(インジウム  ティン  オキサイド)層
19を形成することにより作成される。
This thin film transistor is manufactured by forming a silicon nitride layer 15 (thickness: 100 to 150 mm) to serve as a gate insulating layer after forming a gate electrode and a gate wiring in the steps shown in FIGS. 1 to 3.
nm) and silicon oxide layer 16 (layer thickness 400-500 nm)
nm), an amorphous silicon layer 17, an n+ amorphous silicon layer 18, and an ITO (indium tin oxide) layer 19 serving as a source electrode and a drain electrode.

【0015】図5は、薄膜トランジスタアレイにおける
ゲ−ト配線の終端部付近を示した断面図であり、図4に
示した薄膜トランジスタの形成と同時に作成されるもの
である。したがって、窒化シリコン層15、酸化シリコ
ン層16およびITO層19は、図4に同一番号を付し
たものと同時に形成されるものである。なお、図5に示
したITO層19は、ゲ−ト配線を外部回路と接続する
ための接続端子となるものである。
FIG. 5 is a cross-sectional view showing the vicinity of the terminal end of the gate wiring in the thin film transistor array, which is produced at the same time as the formation of the thin film transistor shown in FIG. Therefore, silicon nitride layer 15, silicon oxide layer 16, and ITO layer 19 are formed at the same time as those labeled with the same numbers in FIG. The ITO layer 19 shown in FIG. 5 serves as a connection terminal for connecting the gate wiring to an external circuit.

【0016】以上述べた実施例では、第3金属層14を
形成する金属をモリブデンまたはクロムとしたが、他の
金属を主成分としたものでもよい。ゲ−ト電極に関して
いえば、ウエットエッチングが容易な金属を主成分とす
るものであればよい。特に、第3金属層(銅層)14と
第2金属層13とを同一のウエットエッチング液を用い
てエッチングできるものが好ましい。また、ゲ−ト配線
に関していえば、ITO層19等を用いた導電性の接続
層に対して、良好なオ−ミックコンタクトが得られる金
属を主成分とするものであればよい。
In the embodiments described above, the metal forming the third metal layer 14 is molybdenum or chromium, but it may be made of other metals as the main component. As for the gate electrode, it may be one whose main component is a metal that can be easily wet-etched. In particular, it is preferable that the third metal layer (copper layer) 14 and the second metal layer 13 can be etched using the same wet etching solution. As for the gate wiring, any material may be used as long as the main component is a metal that can provide good ohmic contact with the conductive connection layer using the ITO layer 19 or the like.

【0017】[0017]

【発明の効果】本発明では、銅層上にモリブデン(Mo
 )やクロム(Cr )等のウエットエッチングが容易
な金属を主成分とする金属層を形成したため、ゲ−ト電
極を3層構造にしても安価に製造可能な薄膜トランジス
タのゲ−ト電極が形成できる。また、適当なエッチング
液を選択することにより、銅層および銅層上の金属層を
同一のエッチング液を用いてエッチングすることができ
る。
Effects of the Invention In the present invention, molybdenum (Mo
) and chromium (Cr), which are easy to wet-etch, the gate electrode of a thin film transistor can be formed at low cost even if the gate electrode has a three-layer structure. . Furthermore, by selecting an appropriate etching solution, the copper layer and the metal layer on the copper layer can be etched using the same etching solution.

【図面の簡単な説明】[Brief explanation of the drawing]

【図1】本発明に係わる実施例であり、薄膜トランジス
タアレイのゲ−ト電極およびゲ−ト配線の製造工程を示
した断面図である。
FIG. 1 is an embodiment of the present invention, and is a cross-sectional view showing the manufacturing process of a gate electrode and gate wiring of a thin film transistor array.

【図2】本発明に係わる実施例であり、薄膜トランジス
タアレイのゲ−ト電極およびゲ−ト配線の製造工程を示
した断面図である。
FIG. 2 is an embodiment of the present invention, and is a cross-sectional view showing the manufacturing process of a gate electrode and gate wiring of a thin film transistor array.

【図3】本発明に係わる実施例であり、薄膜トランジス
タアレイのゲ−ト電極およびゲ−ト配線の製造工程を示
した断面図である。
FIG. 3 is an embodiment of the present invention, and is a cross-sectional view showing the manufacturing process of a gate electrode and gate wiring of a thin film transistor array.

【図4】本発明に係わる実施例であり、薄膜トランジス
タアレイにおける薄膜トランジスタの断面図である。
FIG. 4 is an embodiment of the present invention, and is a cross-sectional view of a thin film transistor in a thin film transistor array.

【図5】本発明に係わる実施例であり、薄膜トランジス
タアレイにおけるゲ−ト配線の終端部付近を示した断面
図である。
FIG. 5 is an embodiment of the present invention, and is a cross-sectional view showing the vicinity of the terminal end of a gate wiring in a thin film transistor array.

【符号の説明】[Explanation of symbols]

11……絶縁基板 12……第1金属層 13……第2金属層 14……第3金属層 11...Insulating substrate 12...first metal layer 13...Second metal layer 14...Third metal layer

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】  絶縁基板の主表面側に形成された第1
金属層と、上記第1金属層上に上記第1金属層と略同一
形状で形成され、銅(Cu )を主成分とする第2金属
層と、上記第2金属層上に上記第2金属層と略同一形状
で形成され、モリブデン(Mo )やクロム(Cr )
等のウエットエッチングが容易な金属を主成分とする第
3金属層とからなる薄膜トランジスタのゲ−ト電極。
Claim 1: A first plate formed on the main surface side of an insulating substrate.
a metal layer, a second metal layer formed on the first metal layer in substantially the same shape as the first metal layer and mainly containing copper (Cu), and a second metal layer on the second metal layer, It is formed in approximately the same shape as the layer, and contains molybdenum (Mo) and chromium (Cr).
A gate electrode of a thin film transistor comprising a third metal layer whose main component is a metal that is easy to wet-etch.
【請求項2】  上記第3金属層はモリブデン(Mo 
)またはクロム(Cr )を主成分とした材料で構成さ
れている請求項1に記載の薄膜トランジスタのゲ−ト電
極。
2. The third metal layer is molybdenum (Mo
) or chromium (Cr) as a main component.
【請求項3】  絶縁基板の主表面側に第1金属層を堆
積し、上記第1金属層上に銅(Cu )を主成分とする
第2金属層を堆積し、上記第1金属層上にモリブデン(
Mo )やクロム(Cr )等のウエットエッチングが
容易な金属を主成分とする第3金属層を堆積する工程と
、フォトレジスト等のマスク層をマスクとして、上記第
3金属層および上記第2金属層を同一のエッチング液を
用いてエッチングする工程と上記マスク層をマスクとし
て、上記第1金属層をエッチングする工程とからなる薄
膜トランジスタのゲ−ト電極の製造方法。
3. Depositing a first metal layer on the main surface side of the insulating substrate, depositing a second metal layer containing copper (Cu) as a main component on the first metal layer, and depositing a second metal layer on the first metal layer. Molybdenum (
A step of depositing a third metal layer mainly composed of a metal that is easy to wet-etch, such as Mo) or chromium (Cr), and a step of depositing the third metal layer and the second metal using a mask layer such as photoresist as a mask. A method for manufacturing a gate electrode of a thin film transistor, comprising the steps of etching the layers using the same etching solution and etching the first metal layer using the mask layer as a mask.
【請求項4】  上記第3金属層の上記エッチング液に
対するエッチングレ−トは、上記第2金属層の上記エッ
チング液に対するエッチングレ−トよりも大である請求
項3に記載の薄膜トランジスタのゲ−ト電極の製造方法
4. The gate of the thin film transistor according to claim 3, wherein the etching rate of the third metal layer with the etching solution is higher than the etching rate of the second metal layer with the etching solution. A method for manufacturing an electrode.
【請求項5】  上記第3金属層はモリブデン(Mo 
)またはクロム(Cr )を主成分とした材料で構成さ
れている請求項3に記載の薄膜トランジスタのゲ−ト電
極の製造方法。
5. The third metal layer is made of molybdenum (Mo
) or chromium (Cr) as a main component.
JP40353790A 1990-12-19 1990-12-19 Gate electrode of thin film transistor and manufacture thereof Withdrawn JPH04217370A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP40353790A JPH04217370A (en) 1990-12-19 1990-12-19 Gate electrode of thin film transistor and manufacture thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP40353790A JPH04217370A (en) 1990-12-19 1990-12-19 Gate electrode of thin film transistor and manufacture thereof

Publications (1)

Publication Number Publication Date
JPH04217370A true JPH04217370A (en) 1992-08-07

Family

ID=18513269

Family Applications (1)

Application Number Title Priority Date Filing Date
JP40353790A Withdrawn JPH04217370A (en) 1990-12-19 1990-12-19 Gate electrode of thin film transistor and manufacture thereof

Country Status (1)

Country Link
JP (1) JPH04217370A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001044439A (en) * 1999-07-28 2001-02-16 Nec Corp Transistor and manufacture thereof
KR100303347B1 (en) * 1998-06-23 2001-11-22 박종섭 Manufacturing Method of Thin Film Transistor
KR100430950B1 (en) * 1998-09-01 2004-06-16 엘지.필립스 엘시디 주식회사 Thin film transistor and its manufacturing method
KR100670982B1 (en) * 2000-02-10 2007-01-17 샤프 가부시키가이샤 Thin film transistor and method for fabricating the same
KR20140070344A (en) * 2012-11-30 2014-06-10 삼성전자주식회사 Semiconductor material, transistor including semiconductor material and electronic device including transistor
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100303347B1 (en) * 1998-06-23 2001-11-22 박종섭 Manufacturing Method of Thin Film Transistor
KR100430950B1 (en) * 1998-09-01 2004-06-16 엘지.필립스 엘시디 주식회사 Thin film transistor and its manufacturing method
JP2001044439A (en) * 1999-07-28 2001-02-16 Nec Corp Transistor and manufacture thereof
KR100670982B1 (en) * 2000-02-10 2007-01-17 샤프 가부시키가이샤 Thin film transistor and method for fabricating the same
KR20140070344A (en) * 2012-11-30 2014-06-10 삼성전자주식회사 Semiconductor material, transistor including semiconductor material and electronic device including transistor
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