JPH04119979A - Ceramic-grain sheet and ornamenting method - Google Patents
Ceramic-grain sheet and ornamenting methodInfo
- Publication number
- JPH04119979A JPH04119979A JP23836790A JP23836790A JPH04119979A JP H04119979 A JPH04119979 A JP H04119979A JP 23836790 A JP23836790 A JP 23836790A JP 23836790 A JP23836790 A JP 23836790A JP H04119979 A JPH04119979 A JP H04119979A
- Authority
- JP
- Japan
- Prior art keywords
- sheet
- ceramic
- mesh
- base material
- grain
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title description 6
- 239000000919 ceramic Substances 0.000 claims abstract description 49
- 239000000463 material Substances 0.000 claims abstract description 39
- 239000011347 resin Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 10
- 239000004566 building material Substances 0.000 claims abstract description 8
- 239000004744 fabric Substances 0.000 claims abstract description 3
- 229910052751 metal Inorganic materials 0.000 claims abstract description 3
- 239000002184 metal Substances 0.000 claims abstract description 3
- 239000002245 particle Substances 0.000 claims description 51
- 238000010276 construction Methods 0.000 claims description 9
- 238000005034 decoration Methods 0.000 claims description 7
- 239000000956 alloy Substances 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 claims description 2
- 229910010272 inorganic material Inorganic materials 0.000 claims description 2
- 239000011147 inorganic material Substances 0.000 claims description 2
- 239000000123 paper Substances 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 12
- 230000001070 adhesive effect Effects 0.000 abstract description 12
- 229910052782 aluminium Inorganic materials 0.000 abstract description 2
- 239000000835 fiber Substances 0.000 abstract description 2
- 239000003365 glass fiber Substances 0.000 abstract description 2
- 239000002241 glass-ceramic Substances 0.000 abstract description 2
- 229910052742 iron Inorganic materials 0.000 abstract description 2
- 229920002689 polyvinyl acetate Polymers 0.000 abstract 1
- 239000002699 waste material Substances 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004570 mortar (masonry) Substances 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920006311 Urethane elastomer Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical group C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Finishing Walls (AREA)
- Laminated Bodies (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
この発明は、セラミック粒子シートとこれを用いての加
飾施工法に関するものである。さらに詳しくは、この発
明は、土木、建築材料および／または構造物表面を加飾
するのに有用な新しいセラミック粒子シートとその加飾
施工法に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a ceramic particle sheet and a decoration method using the same. More specifically, the present invention relates to a new ceramic particle sheet useful for decorating the surfaces of civil engineering, building materials, and/or structures, and a method for applying the decoration.
（従来の技術とその課題）
従来より、外観意匠性の向上を目的とした建築材料等と
して各種の加飾手段が知られており、近年の都市景観の
向上への要望の高まりにともなって、これらの加飾手段
への期待が高まっている。(Conventional techniques and their issues) Various decorative means have been known as building materials for the purpose of improving exterior design, and with the recent increase in demand for improving urban landscapes, Expectations for these decorative means are increasing.
また、建設業にたずされる労働者不足を１反映してその
施工法が容易で、かつ作業性の良好な軽量な加飾材の開
発が求められている。In addition, reflecting the shortage of workers in the construction industry, there is a need for the development of lightweight decorative materials that are easy to apply and have good workability.
たとえば、これまでにも、タイルの軽量化が進み、プレ
キャストされた二次製品にあらかじめ塗装やタイル貼り
を施したりして、現場での作業手間を出来るだけ省くよ
うな工法が普及して主流になりつつある。For example, as the weight of tiles has progressed, construction methods that reduce on-site work as much as possible, such as pre-painting or tiling precast secondary products, have become popular and mainstream. It is becoming.
しかしながら、一方では、加飾材料の高級化も進み、こ
れとともに、タイルや石材が多く使われる傾向にあり、
これら材料を用いた加飾施工法は煩雑で、かつ重労働で
ある等の欠点がある。このため、これまでは、施工法が
簡便、かつ容易で、しかも軽量な加飾材を使用すること
と、高級感のあるタイルや石材等の加飾材を多用して加
飾効果を増大させることが矛盾する状況にあった。However, on the other hand, decorative materials have become more sophisticated, and along with this, there is a tendency for tiles and stones to be used more frequently.
Decoration construction methods using these materials have drawbacks such as being complicated and requiring heavy labor. For this reason, conventional methods have been to use decorative materials that are simple and easy to install and are lightweight, and to increase the decorative effect by frequently using decorative materials such as high-class tiles and stones. I was in a contradictory situation.
このような問題を解決するために、この発明の発明者ら
は、従来のタイルや石材と同等の高品位で高級感を備え
、しかも施工が容易な加飾材としてセラミック材を使用
することを提案してもいる。In order to solve these problems, the inventors of this invention have developed the idea of using ceramic materials as a decorative material that has the same high quality and luxurious feel as conventional tiles and stones, and is easy to install. I also make suggestions.
この加飾材は、たとえば第３図に示したように、樹脂等
からなるシート（ア）に、セラミック粒（イ）を配設し
、コンクリート（つ）打設等の後にこのシート（ア）を
剥離して、表面にセラミック粒子を配設した加飾材とし
たものからなることを特徴としていた。For example, as shown in Fig. 3, this decorative material is made by disposing ceramic grains (B) on a sheet (A) made of resin, etc. It was characterized by being made of a decorative material that was peeled off and ceramic particles were arranged on the surface.
しかしながら、この加飾材は、いわゆる反転・転写工法
を採用しているため、剥離したシート（ア）が転用不可
能な廃材として出てくるため、その処理が必要となるこ
とや、セラミック粒かシート状に不規則に並ぶために、
端部の粒子が真直ぐに並ばず、しかも、シート間のジヨ
イント部がきれいに揃わないという欠点があった。However, since this decorative material uses a so-called inversion/transfer method, the peeled sheet (A) comes out as waste material that cannot be reused, so it must be disposed of, and ceramic particles may Because they are arranged irregularly in a sheet,
There were disadvantages in that the particles at the edges were not lined up straight and the joints between the sheets were not aligned neatly.
この発明は、以上の通りの事情に鑑みてなされたもので
あり、従来の加飾材とその工法の問題点を解決し、色彩
が豊かで、耐久特性に優れ、施工が容易でジヨイント部
も目立ちに＜＜、かつ、シート廃材を出すことのない新
しいセラミック粒子シートを提供することを目的として
いる。This invention was made in view of the above circumstances, and it solves the problems of conventional decorative materials and their construction methods, and provides rich colors, excellent durability, easy construction, and joint parts. The purpose is to provide a new ceramic particle sheet that is conspicuous and does not generate sheet waste.
また、この発明は、このセラミック粒子シートを用いて
の加飾施工法を提供することも目的としている。Another object of the present invention is to provide a decoration method using this ceramic particle sheet.
（課題を解決するための手段）
この発明は、上記課題を解決するものとして、柔軟なメ
ツシュ状基材のメツシュ孔にセラミック粒子を嵌入して
なることを特徴とするセラミック粒子シートと、これを
建築材や構造物表面に適用する加飾施工法を提供する。(Means for Solving the Problems) In order to solve the above problems, the present invention provides a ceramic particle sheet characterized in that ceramic particles are inserted into mesh holes of a flexible mesh-like base material, and We provide decorative construction methods that can be applied to building materials and structure surfaces.
また、この発明は、メツシュ基材に、セラミック粒子を
貼着してなる上記セラミック粒子シートを好ましい態様
としても提供する。The present invention also provides, as a preferred embodiment, the ceramic particle sheet described above, which is formed by adhering ceramic particles to a mesh base material.
この発明に用いる基材シートとしては、紙、布はもちろ
んのこと、ポリエチレン、酢酸ビニル樹脂、酢ビ−エチ
レン共重合体、ポリプロピレン、塩化ビニル、樹脂、ア
クリル樹脂、フッ素樹脂等の有機樹脂、または、鉄、ア
ルミニウム、ステンレス、銅、ガラス繊維、セラミック
繊維等の金属、合金や無機物等の適宜なものを使用する
ことができる。The base sheet used in this invention includes not only paper and cloth, but also organic resins such as polyethylene, vinyl acetate resin, vinyl acetate-ethylene copolymer, polypropylene, vinyl chloride, resin, acrylic resin, fluororesin, etc. Appropriate metals such as iron, aluminum, stainless steel, copper, glass fiber, and ceramic fiber, alloys, and inorganic materials can be used.
この基材シートのメツシュの大きさや、その形状につい
ては、特に制限はないが、施工性を考慮に入れるとその
メツシュの大きさは２〜１５ｍｍ程度で、メツシュ孔の
形状は円形に近いものが好ましいものとして例示される
。There are no particular restrictions on the size or shape of the mesh in this base sheet, but considering workability, the size of the mesh is about 2 to 15 mm, and the shape of the mesh holes is close to circular. This is exemplified as a preferable example.
セラミック粒子としては、顔料、釉薬等によって、ある
いはセラミック特有の色として着色した粘土系、あるい
はその他の各種のセラミ、ツクの粒子、さらには天然鉱
物等の粒子の任意のものを使用することができる。もち
ろん、着色していなくともよい。As the ceramic particles, any clay-based particles colored with pigments, glazes, etc. or as a color unique to ceramics, particles of other various ceramics, tsuku particles, and even particles of natural minerals can be used. . Of course, it does not have to be colored.
ガラス質のものであってもよい。It may be glassy.
これらセラミック粒子のメツシュ状の基材への嵌入は、
予めメツシュ孔より多少大きめのセラミック粒子をメツ
シュ基村上に投下し、万遍なく粒子がメツシュ孔に嵌入
し、動きが停止するまで振動を与えるか、あるいは押圧
する方法等により、容易、かつ迅速に行なうことができ
る。また模様を入れる場合には、模様を入れたい部分に
マスキングを行なうことによりパターンニングが可能と
なる。Insertion of these ceramic particles into the mesh-like base material is
Ceramic particles that are slightly larger than the mesh holes are dropped onto the mesh base in advance, and the particles are evenly inserted into the mesh holes and vibrated or pressed until they stop moving, easily and quickly. can be done. Furthermore, when adding a pattern, patterning is possible by masking the area where the pattern is desired.
この場合、接着剤を予めメツシュ状シート基材に塗布し
ておいてもよいし、セラミック粒子がこのシート上に並
んでから吹付けまたは塗布してもよい。メツシュ状シー
ト基材が熱溶融する素材であれば、セラミック粒子をこ
のシート上に並べた後に、加熱してシート基材とセラミ
ック粒子を融着させてもよい。これらの方法の二つ以上
の方法を用いてセラミック粒子をメツシュ状基材に固定
することもできる。In this case, the adhesive may be applied to the mesh-like sheet base material in advance, or the adhesive may be sprayed or applied after the ceramic particles are arranged on the sheet. If the mesh-like sheet base material is a material that can be thermally melted, the ceramic particles may be arranged on the sheet and then heated to fuse the sheet base material and the ceramic particles. Ceramic particles can also be fixed to a mesh-like substrate using two or more of these methods.
このようにして成形されたセラミック粒子シートは、シ
ート上にセラミック粒子か整然と並ぶため、構造物の形
状に応じて、現場でカッティングを行なう際、カッター
ナイフ等で容易に真直ぐ切ることか＝：Ｊ能で、ジヨイ
ント部の仕上りも美しい。The ceramic particle sheet formed in this way has ceramic particles arranged in an orderly manner on the sheet, so depending on the shape of the structure, when cutting it on site, it is easy to cut it straight with a cutter knife, etc.=:J It is a Noh piece, and the joint part has a beautiful finish.
このセラミック粒子シートは、そのまま建築材や構造物
表面に貼着してもよいし、またはその貼着後にメツシュ
状シート基材を剥離して加飾してもよい。This ceramic particle sheet may be attached as it is to the surface of a building material or structure, or after attachment, the mesh-like sheet base material may be peeled off and decorated.
以下、実施例を示し、さらに詳しく、この発明のセラミ
ック粒子シートについて説明する。EXAMPLES Hereinafter, examples will be shown and the ceramic particle sheet of the present invention will be explained in more detail.
実施例１
第１図に例示したように、メツシュ状シート基材（１）
として、ポリエチレン製メツシュシート（目開き６＋＋
＋ｍ、納経２ｍｍ）を用い、予めこのメツシュ状シート
基材（１）にＥＶＡ系の接着材を塗布しておく。このメ
ツシュ状シート基材（１）は固定枠（２）を用いて、垂
み等かかからないように固定しておく。振動を与えなが
ら、粒径６．５〜７皿の青色のセラミック粒子（３）を
投入し、完全にメツシュ状シート基材（１）の番孔に嵌
入する。Example 1 As illustrated in FIG. 1, a mesh-like sheet base material (1)
As a polyethylene mesh sheet (6++
EVA-based adhesive is applied in advance to this mesh-like sheet base material (1) using a mesh-like sheet base material (1). This mesh-like sheet base material (1) is fixed using a fixing frame (2) so that it does not sag. While applying vibration, blue ceramic particles (3) having a particle size of 6.5 to 7 plates are introduced and completely inserted into the holes of the mesh-like sheet base material (1).
完全にメツシュ状シート基材（１）の番孔にセラミック
粒子（３）が嵌入され、接着剤が固化して、セラミック
粒子（３）が固定されたところで、固定枠（２）を外す
。セラミック粒子（３）が整然と並んだ美しいセラミッ
ク粒子シートか得られた。When the ceramic particles (3) are completely inserted into the holes of the mesh-like sheet base material (1), the adhesive is solidified, and the ceramic particles (3) are fixed, the fixing frame (2) is removed. A beautiful ceramic particle sheet in which ceramic particles (3) were arranged in an orderly manner was obtained.
次に、コンクリート壁に樹脂モルタル（セメント：砂：
水：ＥＶＡ系接着剤＝４０：１２０１２：６で調合）を
７ ｍｍ厚で塗布し、これに上記のセラミック粒子シー
トを貼り付けた。（メツシュ状シート基材側を接着面に
した。）
この時、セラミック粒子シートのジヨイントもあったか
、ジヨイントはきれいに揃っており、全く目立つことは
なかった。また、メツシュ状シート基材（１）は除去せ
ずとも、美しい加飾面が得られるため、従来のように廃
材も全く生じなかった。Next, resin mortar (cement: sand:
Water: EVA adhesive (prepared in a ratio of 40:12012:6) was applied to a thickness of 7 mm, and the above ceramic particle sheet was attached to this. (The mesh-like sheet base material side was used as the adhesive surface.) At this time, perhaps there were joints in the ceramic particle sheet, but the joints were neatly aligned and not noticeable at all. Moreover, since a beautiful decorated surface can be obtained without removing the mesh-like sheet base material (1), no waste material is generated as in the conventional method.
実施例２
実施例１と同様の方法で作成したセラミック粒子シート
（３００Ｘ３００ ｍｍ） （目開き８＋ｎｍ、網径
２ ｍｍのものに粒径８．５〜９ ｍｍの粘土系緑色の
セラミック粒子を嵌入させ固着させた。）上に、厚さ２
ｍｍ程度に、すなわち、第２図に示したように、メツ
シュ状シート基材（１）にセラミック粒子（３）を嵌入
・固着したセラミック粒子シートにウレタンゴム（４）
を、吹付け、または塗布を行ない硬化させた。Example 2 Ceramic particle sheet (300 x 300 mm) prepared in the same manner as in Example 1 (8+ nm opening, 2 mm mesh diameter) was filled with clay-based green ceramic particles with a particle size of 8.5 to 9 mm. ) on top, thickness 2
As shown in FIG.
was sprayed or applied and cured.
ウレタンゴムにより、物理的に強力に接着されたこのセ
ラミック粒子貼着シートをＥＶＡ系の接着剤を用いてコ
ンクリート床に貼り詰めた所、美しく磨耗に強いフロア
−が出来た。When this ceramic particle adhesive sheet, which was physically strongly bonded with urethane rubber, was attached to a concrete floor using an EVA adhesive, a beautiful and abrasion-resistant floor was created.
実施例３
実施例１と同様の方法で作成したセラミック粒子貼着シ
ートをセラミック粒子側を接着面にして、樹脂モルタル
を（実施例１と同様の配合）コンクリート側壁に７ｆｆ
１ｍ厚で塗布した面に貼着した。樹脂モルタルが硬化し
た後メツシュ状基材のみを除去すると、セラミック粒子
が整然と配列した美しい加飾面が得られた。除去したメ
ツシュ状基材は同様の用途で４．５回の転用をすること
ができた。Example 3 A ceramic particle adhesive sheet prepared in the same manner as in Example 1 was used with the ceramic particle side as the adhesive surface, and 7ff of resin mortar (same composition as in Example 1) was applied to the concrete side wall.
It was attached to the coated surface with a thickness of 1 m. When only the mesh-like base material was removed after the resin mortar had hardened, a beautiful decorated surface with ceramic particles arranged in an orderly manner was obtained. The removed mesh-like base material could be reused for similar purposes 4.5 times.
（発明の効果）
この発明により、以上詳しく説明した通り、加飾の自由
度、効果ともに大きく、しかも施工時に廃材を全く生じ
ることのない、施工性の良好な、土木・建築構造物への
適用性に優れた加飾が実現される。(Effects of the Invention) As explained in detail above, this invention can be applied to civil engineering and architectural structures that have a large degree of freedom and effect in decoration, do not generate any waste materials during construction, and are easy to construct. Decoration with excellent quality is realized.
第１図および第２図は、この発明のセラミック粒シート
を説明した斜視図と断面図である。
第３図は、従来の加飾材を例示した製造工程の断面図で
ある。
■・・・メツシュ状シート基材
２・・・固定枠
３・・・セラミック粒子FIGS. 1 and 2 are a perspective view and a cross-sectional view illustrating the ceramic grain sheet of the present invention. FIG. 3 is a cross-sectional view of a manufacturing process illustrating a conventional decorative material. ■...Mesh-like sheet base material 2...Fixed frame 3...Ceramic particles
Claims (6)
粒子を嵌入してなることを特徴とするセラミック粒子シ
ート。(1) A ceramic particle sheet characterized by being formed by fitting ceramic particles into mesh holes of a flexible mesh-like base material.
求項（１）記載のセラミック粒子シート。(2) The ceramic particle sheet according to claim (1), wherein the ceramic particles are adhered to a mesh base material.
を配設してなるセラミック粒子シート。(3) A ceramic particle sheet according to claim (1) or (2), wherein a resin layer is provided on the surface of the sheet.
、あるいは無機質材からなる請求項（１）、（２）また
は（３）記載のセラミック粒子シート。(4) The ceramic particle sheet according to claim (1), (2) or (3), wherein the mesh-like base material is made of resin, metal, alloy, paper, cloth, or inorganic material.
表面に貼着することを特徴とする加飾施工法。(5) A decorative construction method comprising adhering the ceramic particle sheet according to claim (1), (2), (3) or (4) to the surface of a building material or structure.
表面に貼着後に、メッシュ状基材を剥離することを特徴
とする加飾施工法。(6) Decoration characterized by peeling off the mesh-like base material after adhering the ceramic particle sheet of claim (1), (2), (3) or (4) to the surface of a building material or structure. Construction method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23836790A JPH04119979A (en) | 1990-09-07 | 1990-09-07 | Ceramic-grain sheet and ornamenting method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23836790A JPH04119979A (en) | 1990-09-07 | 1990-09-07 | Ceramic-grain sheet and ornamenting method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04119979A true JPH04119979A (en) | 1992-04-21 |
Family
ID=17029138
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23836790A Pending JPH04119979A (en) | 1990-09-07 | 1990-09-07 | Ceramic-grain sheet and ornamenting method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04119979A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001172618A (en) * | 1999-12-16 | 2001-06-26 | Ekuteii Kk | Tape type cool storage medium, method for producing the same, cold reserving tool and refrigerator using the same |
-
1990
- 1990-09-07 JP JP23836790A patent/JPH04119979A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001172618A (en) * | 1999-12-16 | 2001-06-26 | Ekuteii Kk | Tape type cool storage medium, method for producing the same, cold reserving tool and refrigerator using the same |
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