JP6887826B2 - Cosmetic composition - Google Patents

Description

The present invention relates to a cosmetic composition obtained by adding a strong acid to vegetable oil and heat-treating it, and a cosmetic using the cosmetic composition.

Hair is continuously damaged on a daily basis by chemical treatments such as perms, bleaching, and hair coloring, ultraviolet rays from sunlight, heat from hair dryers, and brushing. It is known that when hair is damaged in this way, hair components such as proteins, amino acids, and lipids are lost, which appears as a feeling of damage to the hair. These hair damages are perceived by changes in the feel of the hair, such as "no elasticity" and "dryness," and changes in the appearance, such as "dullness" and "uncoordinated." These changes have become a major concern for hair. As a method for improving such problems of hair, it has been proposed to supplement components such as proteins, amino acids, and lipids from the outside (Patent Documents 1 to 4). However, it has been difficult to obtain a lasting effect because it is washed away by washing hair with shampoo or the like.

In recent years, due to environmental considerations and increasing nature consciousness, attempts to add vegetable oils to hair cosmetics are increasing. In hair cosmetics, vegetable oils are used for the purpose of suppressing a feeling of dryness and stiffness, and imparting flexibility, finger passage, cohesiveness, luster, etc. (Patent Documents 5 and 6). However, it cannot be said that the effect of improving damaged hair is sufficient, and it is difficult to maintain the effect because it is easily washed away by washing hair or the like.

JP-A-2004-346005 JP 2006-062970 JP 2006-062972 Japanese Patent Application Laid-Open No. 10-152421 Japanese Patent Application Laid-Open No. 2008-273902 JP 2009-051817

An object of the present invention is a composition obtained from vegetable oil, which has an effect of improving the feeling of hair damage such as "no elasticity", "dullness", "uncoordinated", and "dry". Moreover, it is an object of the present invention to provide the composition for cosmetics which can sustain the effect.

As a result of diligent studies to solve the above problems, the present inventors have added 1 to 200 parts by weight of a strong acid to 100 parts by weight of vegetable oil and heat-treated at 50 to 150 ° C. to obtain a cosmetic composition. The present invention has been completed by finding that a product can solve the above-mentioned problems.

The cosmetic composition of the present invention has the effect of improving the feeling of damage to the hair, such as "no elasticity", "dullness", "uncoordinated", and "dry". Further, the effect is not lost by washing hair or the like, and can be continuously exerted.

The cosmetic composition used in the present invention is obtained by adding 1 to 200 parts by weight of a strong acid to 100 parts by weight of vegetable oil and heat-treating at 50 to 150 ° C.

The vegetable oil used in the cosmetic composition of the present invention is not particularly limited as long as it is a natural oil extracted from a plant, but preferred ones are palm oil, palm oil, palm kernel oil, and saflower. Oil, olive oil, castor oil, avocado oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rosehip oil, meadowfoam oil, camellia oil, grape seed oil, Argania spinosa kernel Oil, Babas oil, Persic oil, Tea tree oil, Hakka oil, Corn oil, Rapeseed oil, Sunflower seed oil, Wheat germ oil, Amani oil, Cotton seed oil, Soybean oil, Mountain tea flower oil, peanut oil, Rice bran oil, Cacao fat, Shea fat , Johova oil and the like, olive oil, camellia oil, sunflower seed oil, rice bran oil and jojoba oil are more preferable, and camellia oil and jojoba oil are most preferable.

Specific examples of the strong acid used in the cosmetic composition of the present invention include hydrogen chloride, nitric acid, sulfuric acid, hydrogen fluoride, hydrogen bromide, perchloric acid and the like, and reaction control and removal operations can be performed. Sulfuric acid is most preferable because it is easy to use.

As a method for producing a cosmetic composition of the present invention, 1 to 200 parts by weight of a strong acid may be added to 100 parts by weight of vegetable oil and heat-treated at 50 to 150 ° C., more preferably 10 to 100 parts by weight of the strong acid. It is 100 parts by weight and the temperature is 70 to 120 ° C. If the amount of strong acid is too small, the effect of the present invention is not sufficiently exhibited, and if the amount of strong acid is too large, it is economically disadvantageous. Further, if the temperature is too low, the effect of the present invention is not sufficiently exhibited, and if the temperature is too high, problems such as coloring occur, which is not preferable. The time of the heat treatment is not particularly limited, but it is preferably 0.5 to 100 hours, more preferably 2 to 50 hours. Further, the heat treatment may be performed while stirring in a nitrogen atmosphere. The cosmetic composition of the present invention thus obtained may be used as it is in cosmetics, or may be appropriately purified and used. For example, the remaining strong acid may be removed by deoxidation or washing with water, or decolorization or steam deodorization with activated carbon, activated clay, hydrogen peroxide, sodium borohydride or the like may be performed.

Since the cosmetic composition of the present invention obtained as described above may be obtained as a solid substance, it may be appropriately diluted with an oil agent so that it can be added to the cosmetic more easily. In this case, the oil used is not particularly limited as long as it dissolves the cosmetic composition of the present invention, and hydrocarbon oils, ester oils, animal and vegetable oils and the like can be used. Of these, vegetable oil can be used more preferably, and the same vegetable oil used for producing the cosmetic composition of the present invention may be used. Further, in order to improve the stability, an antioxidant such as tocopherols may be appropriately added.

The cosmetic composition of the present invention has the effect of improving the feeling of damage to the hair, such as "no elasticity", "dullness", "uncoordinated", and "dry". .. Further, it is preferable that the cosmetic composition of the present invention is applied to the hair and then further heat-treated on the hair. By applying the heat treatment, the effect of improving the feeling of damage to the hair is improved, and the effect can be exerted for a long period of time. When heat-treating hair, a hair iron, iron, digital perm, dryer or the like can be used. The conditions for heat treatment are about 1 to 10 times with a set temperature of 60 to 180 ° C for hair irons and irons, about 1 to 60 minutes at 60 to 120 ° C for digital perms, and 30 with hot air for dryers. It may be processed for about seconds to 10 minutes.

The amount of the cosmetic composition of the present invention to be blended in the cosmetic is not particularly limited as long as the effect of the present invention is not impaired, but is usually 0.001 to 50% by weight, preferably 0.005 to 20. By weight%.

The cosmetics of the present invention include additive components such as oily bases, surfactants, alcohols, moisturizers, polymers / thickening / gelling agents, and oxidations, which are added to water and ordinary cosmetics as needed. Inhibitors, preservatives, bactericides, chelating agents, pH regulators / acids / alkalis, UV absorbers, whitening agents, solvents, keratin stripping / dissolving agents, antipruritic agents, anti-inflammatory agents, antiperspirants, refreshing agents, antihistamines, Astringents, stimulants, hair growth agents / blood circulation promoters, reducing agents / oxidizing agents, polymer powders, hydroxy acids, vitamins and their derivatives, saccharides and their derivatives, organic acids, enzymes, nucleic acids, Can contain hormones, inorganic powders, fragrances, pigments, etc.

Oily bases include cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, araquil alcohol, behenyl alcohol, jojoba alcohol, chimil alcohol, seraquil alcohol, bacil alcohol, hexyldecanol, isostearyl alcohol, Higher alcohols such as 2-octyldodecanol and dimerdiol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, Higher grades such as palmitooleic acid, oleic acid, linoleic acid, linoleic acid, erucic acid, docosahexaenoic acid, eikosapentaenoic acid, isohexadecanoic acid, anteisohenicosanoic acid, long chain branched fatty acids, dimer acid, hydrogenated dimer acid, etc. Fatty acids and metal soaps such as aluminum salts, calcium salts, magnesium salts, zinc salts, potassium and sodium salts, and nitrogen-containing derivatives such as amides; liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin , Α-Olefin oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalane, vaseline, solid paraffin and other hydrocarbons; candelilla wax, carnauba wax, rice wax, wood wax, honey wax, montan wax , Ozokerite, Celesin, Paraffin wax, Microcrystalin wax, Petrolatum, Fishertroph wax, Polyethylene wax, Ethylene-propylene copolymer and other waxes; Palm oil, Palm oil, Palm kernel oil, Saflower oil, Olive oil, Himasi oil, Avocado Oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rose hip oil, meadowfoam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat Vegetable oils and fats such as germ oil, flaxseed oil, cottonseed oil, soybean oil, peanut oil, rice bran oil, cacao butter, shea butter, hydrogenated palm oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil; beef fat, milk fat, Animal oils and fats such as horse fat, egg yolk oil, mink oil and turtle oil; animal waxes such as whale wax, lanolin and orange raffy oil; liquid lanolin, reduced lanoli Lanolins such as adsorption-purified lanolin, lanolin acetate, liquid acetate lanolin, hydroxylanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin alcohol acetate, acetic acid (cetyl lanolyl) ester; lecithin, phosphatidylcholine , Phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingomyelin and other sphingolin lipids, phosphatidic acid, cyclic lysophosphatidic acid or salts thereof, phospholipids such as lysolecithin; hydrogenated soybean phospholipids, partially hydrogenated soybeans Phosphorlipid derivatives such as phospholipids, hydrogenated egg yolk phospholipids, partially hydrogenated egg yolk phospholipids; sterols such as cholesterol, dihydrocholesterol, lanosterol, dihydrolanosterol, phytosterol, cholic acid; sapogenins; saponins; cholesteryl acetate, Cholesteryl nonanoate, Cholesteryl stearate, Cholesteryl isostearate, Cholesteryl oleate, Di (cholesteryl / behenyl / octyldodecyl) N-lauroyl-L-glutamate, Di (cholesteryl / octyldodecyl) N-lauroyl-L-glutamate, N- Diacylsarcosine alkyl esters such as di-lauroyl-L-glutamate (phytosteryl / behenyl / octyldodecyl), di-lauroyl-L-glutamate (phytosteryl / octyldodecyl), N-lauroyl sarcosin isopropyl, cholesteryl 12-hydroxystearate, macadamia nuts. Sterol esters such as oil fatty acid cholesteryl, macadamia nut oil fatty acid phytosteryl, sunflower seed oil fatty acid phytosteryl, isostearate phytosteryl, soft lanolin fatty acid cholesteryl, hard lanolin fatty acid cholesteryl, long chain branched fatty acid cholesteryl, long chain α-hydroxy fatty acid cholesteryl; -Fatty acid complexes such as cholesterol complex, phospholipid-phytosterol complex; octyldodecyl myristate, hexyldecyl myristate, octyldodecyl isostearate, cetyl pariminate, octyldodecyl palmitate, cetyl octanate, hexyldecyl octanate, Isotridecyl isononanoate, isononyl isononanoate, octyl isononanoate, isotridecyl isononanoate, isodecil neopentanoate, ne Isotridecyl opentanate, isostearyl neopentate, octyldodecyl neodecanoate, oleyl oleate, octyldodecyl oleate, octyldodecyl ricinoleate, octyldodecyl lanolinic acid, dicapryryl carbonate, hexyldecyl dimethyloctanoate, octyldodecyl ercatate Himasi oil, ethyl oleate, ethyl avocado oil fatty acid, isopropyl myristate, isopropyl palmitate, octyl palmitate, isopropyl isostearate, isopropyl lanolin fatty acid, methylheptyl laurate, methylheptyl myristate, methylheptyl palmitate, methyl isostearate Monoalcoholic carboxylic acid esters such as heptyl, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, diisopropyl adipate, dibutyloctyl sebacate, diisobutyl adipate, dioctyl succinate, triethyl citrate; cetyl lactate, diiso malate Oxyate esters such as stearyl, hydrogenated monoisostearate castor oil, γ-ercalactone; glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, glyceryl diisostearate, tri (caprylic acid / capric acid) glyceryl, tri (Capricic acid / capric acid / myristic acid / stearic acid) Glyceryl, hydrogenated rosin triglyceride (hydrogenated ester gum), rosin triglyceride (ester gum), glyceryl beecosanate diate, trimethylol propane trioctanoate, triisostearate Methylolpropane, neopentyl glycol dioctanoate, neopentyl glycol dicaprate, 2-butyl-2-ethyl-1,3-propanediol dioctanoate, propylene glycol dioleate, pentaerythrityl tetraoctanoate, hydrogenated rosin pentaerythrityl , Triethylhexanoic acid ditrimethylolpropane, (isostearic acid / sebacic acid) ditrimethylolpropane, triethylhexanoate pentaerythricyl, (hydroxystearic acid / stearic acid / logonic acid) dipentaerythrityl, diisostearate diglyceryl, tetraisostearate polyglyceryl, nona Polyglyceryl isostearate-10, Deca (erucic acid / isostearic acid / ricinoleic acid) polyglyceryl-8, (Hexyldecanoic acid / sebacic acid) Diglyceryl oligoester, glycol distearate (ethylene glycol distearate), 3-methyl-1,5-pentanediol dineopenate, 2,4-diethyl-1,5-pentanediol dineopenate, etc. Polyhydric alcohol fatty acid esters; alkyl ethers such as dicaprylyl ether; diisopropyl dimergylinolate, diisostearyl dimersylinolate, dimersierlinolate di (isostearyl / phytosteryl), dimergylinol acid (phytosteryl /) Behenyl), dimergylinolic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl), dimerdilinolic acid dimerglinoleil, diisostearate dimerglinoleil, dimerglinoleil hydrogenated rosin condensate, dimerglinol acid Derivatives of dimeric acid or dimerdiol such as hardened castor oil, hydroxyalkyl dimer dilinoleil ether; palm oil fatty acid monoethanolamide (cocamide MEA), palm oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA) ), Laurate diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitate monoethanolamide (partamide MEA), palmitate diethanolamide (partamide DEA), coconut oil fatty acid methylethanolamide (cocamidomethyl MEA) Fatty acid alkanolamides such as; dimethicone (dimethylpolysiloxane), highly polymerized dimethicone (highly polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopentasiloxane), phenyltrimethicone, diphenyldimethicone, phenyldimethicone, ( Aminoethylaminopropylmethicone / dimethicone) copolymer, dimethiconol, dimethiconol crosspolymer, silicone resin, silicone rubber, amino-modified silicones such as aminopropyldimethicone and amodimethicone, cationic-modified silicones, polyether-modified silicones such as dimethicone copolyol, polyglycerin Modified silicone, sugar-modified silicone, carboxylic acid-modified silicone, phosphate-modified silicone, sulfuric acid-modified silicone, alkyl-modified silicone, fatty acid-modified silicone, alkyl ether-modified silicone, a. Minoic acid-modified silicone, peptide-modified silicone, fluorine-modified silicone, cationic-modified and polyether-modified silicone, amino-modified and polyether-modified silicone, alkyl-modified and polyether-modified silicone, amide alkyl-modified silicone, aminoglycol-modified silicone, aminophenyl-modified Silicones such as silicones and polysiloxane / oxyalkylene copolymers; fluorine-based oils such as perfluorodecane, perfluorooctane, and perfluoropolyether are preferable.

Examples of the moisturizing agent / feel improving agent include glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, and the like. Polyols such as trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol / propylene glycol copolymer and its polymers; diethylene glycol monoethyl ether Glycolalkyl ethers such as (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether; (eicosanedioic acid / tetradecanedioic acid) polyglyceryl-10, polyglyceryl-10 tetradecanedioate, cyclohexanedicarboxylic acid Water-soluble esters such as bisethoxydiglycol; sugar alcohols such as sorbitol, xylitol, erythritol, mannitol, martitol; glucose, fructose, galactose, mannose, treose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, Trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins (α-, β-, γ-cyclodextrin, and modified cyclodextrins such as maltosylation and hydroxyalkylation), β-glucan, chitin, chitosan, Heparin and derivatives, saccharides such as pectin, arabinogalactan, dextrin, dextran, glycogen, ethyl glucoside, glucosyl ethyl methacrylate polymer or copolymer and derivatives thereof; hyaluronic acid, sodium hyaluronate; sodium chondroitin sulfate; mucoitin sulfate , Caronine sulfate, keratosulfate, dermatan sulfate; white jellyfish extract, white jellyfish polysaccharide; fluctanes such as inulin, levan; fucoidan; tuberose polysaccharide, naturally occurring polysaccharide; organic acids such as citrate, tartaric acid, lactic acid and salts thereof. Urea; Salts such as 2-pyrrolidone-5-carboxylic acid and sodium thereof; betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threoni Amino acids such as peptides, glutamic acid, glutamine, asparagine, aspartic acid, cysteine, cystine, methionine, leucine, isoleucine, valine, tryptophan, histidine, taurine and their salts; collagen, fish-derived collagen, atelocollagen, gelatin, elastin, collagen degradation Peptide, hydrolyzed collagen, hydroxypropylammonium chloride hydrolyzed collagen, elastin-degraded peptide, keratin-degraded peptide, hydrolyzed keratin, conchiolin-degraded peptide, hydrolyzed conchiolin, silk proteolytic peptide, hydrolyzed silk, lauroyl hydrolyzed silk sodium, soybean Protein peptides and derivatives thereof such as proteolytic peptides, wheat proteolytic peptides, hydrolyzed wheat proteins, casein-degrading peptides, acylated peptides; acylated peptides such as palmitoyl oligopeptides, palmitoyl pentapeptides, palmitoyl tetrapeptides; Peptides; Lactobacillus culture, yeast extract, eggshell membrane protein, submandibular gland mutin, hypotaurine, sesame lignan glycoside, glutathione, albumin, lactose; choline chloride, phosphorylcholine; placenta extract, aerastin, collagen, aloe extraction Peptides, Hamamelis water, Hechima water, Camomila extract, Kanzo extract, Comfrey extract, Silk extract, Izayoi rose extract, Peptide extract, Eucalyptus extract, Melilot extract and other animal / plant extracts, Natural ceramide (Types 1, 2, 3, 4, 5, 6), hydroxyceramides, pseudo-ceramides, sphingoglycolipids, ceramides and ceramides such as sugar ceramide-containing extracts are preferable.

Preferred examples of the surfactant include anionic surfactants, nonionic surfactants, cationic surfactants, amphoteric surfactants, and polymer surfactants. The HLB of the surfactant is not particularly limited and can be used from a low HLB of about 1 to a high HLB of about 20, and it is also preferable to combine a low HLB and a high HLB. Examples of preferred surfactants include fatty acid salts such as potassium laurate and potassium myristate; alkyl sulfates such as sodium lauryl sulfate, triethanolamine lauryl sulfate and ammonium lauryl sulfate; laureth. Polyoxyethylene alkyl sulfates such as sodium sulphate and triethanolamine laureth sulfate; sodium cocoyl methyl taurine, potassium cocoyl methyl taurine, sodium lauroyl methyl taurine, sodium myristyl methyl taurine, sodium lauroyl methyl alanine, sodium lauroyl sarcosin, and lauroyl sarcosin triethanol. Acyl N-methyl amino acid salts such as amines and sodium methylalanine lauroyl glutamate; sodium cocoyl glutamate, triethanolamine cocoyl glutamate, sodium lauroyl glutamate, sodium myristyl glutamate, sodium stearoyl glutamate, ditriethanolamine palmitoyl aspartate, cocoylalanine triethanolamine. , Acyl amino acid salts such as lysine Na dilauroyl glutamate; Polyoxyethylene alkyl ether acetate salts such as sodium laures acetate; Sulfonic acid ester salts such as sodium lauroyl monoethanolamide succinate; Polyoxyethylene fatty amine sulfate; fatty acid alkanolamide sulfate; hardened coconut oil fatty acid fatty acid glyceride sulfate such as sodium glycerin sulfate; alkylbenzene polyoxyethylene sulfate; olefin sulfonate such as α-olefin sulfonate; Alkyl sulfosuccinates such as sodium lauryl sulphate, sodium dioctyl sulfosuccinate; alkyl ether sulfosuccinates such as sodium laures sulfosuccinate, monoethanolamide polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate; tetradecyl Alkyl benzene sulfonates such as sodium benzene sulfonate, triethanolamine tetradecyl benzene sulfonic acid; alkyl naphthalene sulfonate; alkane sulfonate; α-sulfo fatty acid methyl ester salt; acyl acetylionate; alkyl glycidyl ether sulfonate Alkyl sulfoacetate; Alkyl phosphate ester salts such as sodium laures phosphate, sodium dilaures phosphate, sodium trilaureth phosphate, sodium monooleth phosphate; Alkyl phosphate ester salts such as potassium lauryl phosphate; Sodium caseinate; Alkyl aryl ether Phosphate; fatty acid amide ether phosphate; phospholipids such as phosphatidylglycerol, phosphatidylinositol, phosphatidic acid, cyclic lysophosphatidic acid or salts thereof; Anionic surfactants, etc .; Among nonionic surfactants, laureth (polyoxyethylene lauryl ether), ceteth (polyoxyethylene cetyl ether), steares (polyoxyethylene stearyl ether), behenes (polyoxy) Polyoxyethylene alkyl ethers with various polyoxyethylene additions such as ethylene behenyl ether), isosteares (polyoxyethylene isostearyl ether), octyldodeces (polyoxyethylene octyldodecyl ether); polyoxyethylene alkylphenyl ether; Polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, polyoxyethylene hydrogenated castor oil monopyroglutamic acid monoisostearic acid diester, poly Oxyethylene hydrogenated castor oil and castor oil derivatives such as maleic acid; polyoxyethylene phytosterol; polyoxyethylene cholesterol; polyoxyethylene cholestanol; polyoxyethylene lanolin; polyoxyethylene reduced lanolin; polyoxyethylene polyoxy Polyethylene cetyl ether, polyoxyethylene / polyoxypropylene 2-decyltetradecyl ether, polyoxyethylene / polyoxypropylene monobutyl ether, polyoxyethylene / polyoxypropylene hydrogenated lanolin, polyoxyethylene / polyoxypropylene glycerin ether, etc. Polyoxyethylene / polyoxypropylene alkyl ether; polyoxyethylene / polyoxypropylene glycol; (poly) glycerin polyoxypropylene glycol such as PPG-9 diglyceryl; Glyceryl, glyceryl isostearate, glyceryl palmitate, glyceryl myristate, glyceryl oleate, coconut oil fatty acid glyceryl, monocotton oil fatty acid glycerin, glycerin monoercaate, glycerin sesquioleate, α, α'-glycerin oleate, monostearic acid Glycerin fatty acid partial esters such as acid glycerin malic acid; polyglyceryl-2, 3, 4, 4, 6, 8, 8, 10, polyglyceryl distearate-6, 10, polyglyceryl tristearate- 2. Polyglyceryl decastearate-10, polyglyceryl-2 isostearate-2, 3, 4, 4, 5, 6, 8, 10, diisostearate polyglyceryl-2 (diglyceryl diisostearate), 3, 10, 10 , Polyglyceryl-2 triisostearate, Polyglyceryl-2 tetraisostearate, Polyglyceryl-10 decaisostearate, Polyglyceryl-2 oleate, 3, 4, 5, 5, 6, 8, Polyglyceryl dioleate- 6. Polyglycerin fatty acid ester such as polyglyceryl-2 trioleate, polyglyceryl-10 decaoleate; ethylene glycol monofatty acid ester such as ethylene glycol monostearate; propylene glycol monofatty acid ester such as propylene glycol monostearate; pentaerythritol moiety Fatite ester; sorbitol partial fatty acid ester; martitol partial fatty acid ester; martitol ether; sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan Solbitan fatty acid esters such as trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate; partial esters of sugar derivatives such as sucrose fatty acid ester, methylglucoside fatty acid ester, trehalose undecylate; Alkyl glucosides such as glucosides; alkyl polyglycosides; glycolipids such as mannosyl erythritol lipid; lanolin alcohol; reduced lanolin; polyoxyethylene distearate, polytylene glycol diisostearate, polyoxyethylene monooleate, polyoxyethylene di Ole Polyoxyethylene fatty acid mono and diesters such as alcohol; polyoxyethylene / propylene glycol fatty acid ester; polyoxyethylene glycerin monostearate, polyoxyethylene glycerin monoisostearate, polyoxyethylene glycerin triisostearate, etc. Polyoxyethylene glycerin fatty acid esters such as monooleate; polyoxyethylene sorbitan fatty acid esters such as polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, and polyoxyethylene sorbitan tetraoleate. Polyoxyethylene sorbitol fatty acid esters such as polyoxyethylene sorbitol monolaurate, polyoxyethylene sorbitol monooleate, polyoxyethylene sorbitol pentaoleate, and polyoxyethylene sorbitol monostearate; polyoxyethylene methyl glucoside fatty acid esters; poly Oxyethylene alkyl ether fatty acid esters; polyoxyethylene animal and vegetable oils and fats such as polyoxyethylene sorbitol honey; alkyl glyceryl ethers such as isostearyl glyceryl ethers, chimil alcohols, ceracyl alcohols and batyl alcohols; polyhydric alcohol alkyl ethers; poly Oxyethylene alkylamines; tetrapolyoxyethylene / tetrapolyoxypropylene-ethylenediamine condensates; natural surfactants such as saponin and sophorolipid; polyoxyethylene fatty acid amides; coconut oil fatty acids monoethanolamide (cocamide MEA), coconut oil Fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitate monoethanolamide (partamide MEA), palmitate diethanolami Alcohol alkanolamides such as do (partamide DEA) and coconut oil fatty acid methylethanolamide (cocamidomethyl MEA); alkyldimethylamine oxides such as lauramine oxide, cocamine oxide, stearamine oxide, behenamine oxide; alkylethoxydimethylamine Oxide; polyoxyethylene alkyl mercaptan; polyether such as dimethicone copolypoly Silicone-based nonionic surfactants such as cell-modified silicones, polysiloxane / oxyalkylene copolymers, polyglycerin-modified silicones, and sugar-modified silicones; among cationic surfactants, betaine trimonium chloride and stealtrimonium chloride. Alkyltrimethylammonium chlorides such as cetrimonium chloride and lauryltrimonium chloride; alkyltrimethylammonium bromides such as stearyltrimonium bromide; dialkyldimethylammonium chlorides such as distearyldimonium chloride and dicocodimonium chloride; stearamidepropyldimethylamine, Fatty acid amidoamines such as stearamide ethyldiethylamine and salts thereof; alkyletheramines such as stearoxypropyldimethylamine and salts thereof or quaternary salts; long-chain ethylsulfate branched fatty acids (12-31) aminopropylethyldimethylammonium, lanolin ethylsulfate Fatty acid amide type quaternary ammonium salt such as fatty acid aminopropyl ethyl dimethyl ammonium; polyoxyethylene alkylamine and its salt or quaternary salt; alkylamine salt; fatty acid amide guanidium salt; alkyl etheraminemonium salt; Ammonium salt; benzalkonium salt; benzethonium salt; pyridinium salt such as cetylpyridinium chloride; imidazolinium salt; alkylisoquinolinium salt; dialkylmoriphonium salt; polyamine fatty acid derivative; aminopropyldimethicone and amodimethicone Silicone-based cationic surfactants such as modified silicones, cationically modified silicones, cationically modified and polyether-modified silicones, amino-modified and polyether-modified silicones; among amphoteric surfactants, lauryl betaine (lauryldimethylaminoacetic acid betaine) and the like. N-alkyl-N, N-dimethyl amino acid betaine; fatty acid amide alkyl-N, N-dimethyl amino acid betaine such as cocamidopropyl betaine and lauramidopropyl betaine; imidazoline type betaine such as sodium cocoamphoacetate and sodium lauroamphoacetate; alkyl Alkyl sulfobetaine such as dimethyl taurine; sulfuric acid betaine such as alkyl dimethylaminoethanol sulfate ester; phosphoric acid betaine such as alkyl dimethyl amino ethanol phosphate; phosphatidylcholine, phosphatidylethanola Sphingomyelin lipids such as min, phosphatidylserine, sphingomyelin, lysolecithin, hydrogenated soybean phospholipids, partially hydrogenated soybean phospholipids, hydrogenated egg yolk phospholipids, partially hydrogenated egg yolk phospholipids, phospholipids such as lecithin hydroxide; Silicone-based amphoteric surfactants and the like; As polymer surfactants, polyvinyl alcohol, sodium alginate, starch derivatives, tragant gum, acrylate / alkyl methacrylic acid copolymers; various silicone-based surfactants are preferable.

Examples of the polymer / thickener / gelling agent include guar gum, locust bean gum, queens seed, carrageenan, galactan, arabic gum, tara gum, tamarind, farcerelan, karaya gum, trolley aoi, cara gum, tragant gum, pectin, pectic acid and sodium. Salts such as salts, salts such as alginic acid and sodium salts, mannan; starches such as rice, corn, potatoes, wheat; xanthan gum, dextran, succinoglucan, curdran, hyaluronic acid and its salts, zansan gum, purulan, gellan gum, chitin , Chitosan, agar, casso extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl cellulose and salts such as sodium thereof, methyl hydroxypropyl cellulose, sodium cellulose sulfate, dialkyldimethyl Ammonium sulfate cellulose, crystalline cellulose, cellulose powder and other cellulose and derivatives thereof; starch-based polymers such as soluble starch, carboxymethyl starch, methylhydroxypropyl starch, methyl starch, hydroxypropyltrimonium chloride starch, corn starch aluminum octenyl succinate, etc. Alginic acid derivatives such as sodium alginate and propylene glycol alginate; polyvinylpyridone (PVP), polyvinyl alcohol (PVA), vinylpidridone / vinyl alcohol copolymer, polyvinylmethyl ether; polyethylene glycol, polypropylene glycol, polyoxyethylene Polyoxypropylene copolymer; amphoteric methacrylate copolymer such as (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer, (acrelites / stearyl acrylate / ethylamine methacrylate) copolymer; (dimethicone / vinyldimethicone) cloth Polymer, (alkyl acrylate / diacetone acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer AMP; polyvinyl acetate partially saponified product, maleic acid copolymer; vinylpyrrolidone / dialkylaminoalkyl methacrylate copolymer; Acrylic resin alkanolamine; polyester, water-dispersible polyester; polya Crylamide; polyacrylic acid ester copolymer such as ethyl polyacrylate, carboxyvinyl polymer, salt such as polyacrylic acid and sodium salt thereof, acrylic acid / methacrylic acid ester copolymer; acrylate / alkyl methacrylic acid Polymers: cationized cellulose such as polyquaternium-10, diallyldimethylammonium chloride / acrylamide copolymer such as polyquaternium-7, acrylic acid / diallyldimethylammonium chloride copolymer such as polyquaternium-22, acrylic acid such as polyquaternium-39. -Diallyldimethylammonium chloride-acrylamide copolymer, acrylic acid-cationized metaacrylic acid ester copolymer, acrylic acid-cationized metaacrylic acid amide copolymer, polyquaterium-47 and other acrylic acid-methyl acrylate-chloride Methacrylate propyltrimethylammonium copolymer, choline chloride methacrylate polymer; cationized oligosaccharides, cationized dextran, cationized polysaccharides such as guarhydroxypropyltrimonium chloride; polyethyleneimine; cationic polymers; polyquaternium-51 and the like. 2-Polymer of methacryloyloxyethyl phosphorylcholine, polymer with butyl methacrylate copolymer, etc .; acrylic resin emulsion, ethyl polyacrylate emulsion, polyacrylic alkyl ester emulsion, polyvinyl acetate resin emulsion, natural rubber latex, synthetic Polymer emulsions such as latex; nitrocellulose; polyurethanes and various copolymers; various silicones; various silicone-based copolymers such as acrylic-silicone graft copolymers; various fluoropolymers; 12-hydroxystearic acid and Its salts; dextrin fatty acid esters such as dextrin palmitate, dextrin myristinate; silicic anhydride, fuming silica (ultrafine anhydrous silicic acid), aluminum magnesium silicate, sodium magnesium silicate, metal soap, metal dialkyl phosphate, Bentonite, hectrite, organically modified clay minerals, sucrose fatty acid esters, fructo-oligosaccharide fatty acid esters are preferred.

Examples of solvents and propellants include lower alcohols such as ethanol, 2-propanol (isopropyl alcohol), butanol, and isobutyl alcohol; glycols such as propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, and isopentyldiol. Kind: Diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether Glycol ethers such as: ethylene glycol monoethyl ether acetate, diethylene glycol monoethyl ether acetate, glycol ether esters such as propylene glycol monoethyl ether acetate; glycol esters such as diethoxyethyl succinate and ethylene glycol disuccinate; benzyl Preferables include propellants such as alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate, acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbon, next-generation freon; LPG, dimethyl ether, and carbon dioxide.

Antioxidants include tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; bisulfite derivatives such as propyl bisulfite; vitamin C (ascorbic acid) and / or its derivatives; erythorbic acid and its derivatives; Sulfites such as sodium sulfite; hydrogen sulfites such as sodium hydrogen sulfite; thiosulfites such as sodium thiosulfite; metahydrosulfites; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, cysteine hydrochloride are preferable. Is listed as. As the reducing agent, thioglycolic acid, cysteine, cysteamine and the like are preferable. As the oxidizing agent, hydrogen peroxide solution, ammonium persulfate, sodium bromate, percarbonate and the like are preferable.

Examples of antibacterial agents or preservatives include parabens (hydroxybenzoic acid esters) such as methylparaben, ethylparaben, propylparaben, and butylparaben; phenoxyethanol; 1,2-pentanediol, 1,2-hexanediol, 1,2-octane. 1,2-Alcandiols such as diols; Alkylglyceryl ethers such as 2-ethylhexyl glyceryl ether (ethylhexyl glycerin); Salicylic acid; Sodium benzoate; Isothiazolinone derivatives such as methylchloroisothiazolinone and methylisothiazolinone; Linium urea; Dehydroacetic acid and its salts; Phenols; Halogenized bisphenols such as triclosan, acid amides, quaternary ammonium salts; trichlorocarbanide, zincpyrythion, benzalkonium chloride, benzethonium chloride, sorbic acid, chlorhexidine, glucon Chlorhexidine acid, halocarban, hexachlorophenol, hinokithiol; other phenols such as phenol, isopropylphenol, cresol, timol, parachlorophenol, phenylphenol, sodium phenylphenol; phenylethyl alcohol, photosensitizers, antibacterial zeolite, silver ion However, when used as an antibacterial agent or an antiseptic for the purpose of antiseptic, from the viewpoint of safety of cosmetics or external preparations for skin, phenoxyethanol; 1,2-pentanediol, 1,2-hexane It is more preferable to use 1,2-alkanediols such as diols and 1,2-octanediols; and alkylglyceryl ethers such as 2-ethylhexyl glyceryl ethers.

Examples of the chelating agent include edetates (ethylenediaminetetraacetate) such as EDTA, EDTA2Na, EDTA3Na, and EDTA4Na; hydroxyethylethylenediaminetriacetate such as HEDTA3Na; pentetate (diethylenetriaminepentaacetate); phytate; ethidroic acid and the like. Phosphonic acid and salts such as sodium salts thereof; sodium oxalate; polypolyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphate; sodium citrate, citric acid, alanine, dihydroxyethylglycine , Gluconic acid, ascorbic acid, succinic acid, tartrate acid are preferred. As pH adjusters / acids / alkalis, citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, monoethanol Amine, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, hydroxylated Preferred are sodium, potassium hydroxide, aqueous ammonia, guanidine carbonate and ammonium carbonate.

Powders include mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, white mica, gold mica, synthetic mica, red mica, black mica, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, cay. Barium acid, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluoroapatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, Metal soap (eg zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, red iron oxide, yellow iron oxide, black iron oxide, ultramarine, dark blue, carbon black, titanium oxide, fine and ultrafine titanium oxide, zinc oxide , Fine and ultrafine zinc oxide, alumina, silica, fumigant silica (ultrafine anhydrous silicic acid), mica titanium, fish scale foil, boron nitride, photochromic pigment, synthetic fluorine gold mica, fine particle composite powder, gold, aluminum, etc. Inorganic powders of various sizes and shapes, and these are treated with silicones such as hydrogen silicone and cyclic hydrogen silicone or other surface treatment agents such as silane or titanium coupling agents to make them hydrophobic or Inorganic powder such as hydrophilized powder; starch, cellulose, nylon powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, styrene and acrylic acid copolymer resin powder, polyester powder, benzoguanamine resin powder, polyethylene terephthalate -Polymethylmethacrylate laminated powder, polyethylene terephthalate, aluminum, epoxy laminated powder, etc., urethane powder, silicone powder, Teflon (registered trademark) powder, and other organic powders and surface treatment powders of various sizes and shapes, organic and inorganic Composite powders are preferred. Inorganic salts include sodium chloride-containing salts such as salt, normal salt, rock salt, sea salt, and natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, ginger, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, etc. Aluminum / potassium sulfate (myoban), aluminum / ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, copper sulfate; sodium phosphates such as 1Na / 2Na / 3Na phosphate, phosphoric acid Potassiums, calcium phosphates and magnesium phosphates are preferred.

Examples of the ultraviolet absorber include paraaminobenzoic acid, paraaminobenzoic acid monoglycerin ester, N, N-dipropoxyparaaminobenzoic acid ethyl ester, N, N-diethoxyparaaminobenzoic acid ethyl ester, and N, N-dimethylparaaminobenzoate ethyl. An benzoic acid-based ultraviolet absorber such as ester, N, N-dimethylparaaminobenzoic acid butyl ester, N, N-dimethylparaaminobenzoic acid ethyl ester; anthranilic acid-based ultraviolet absorber such as homomentyl-N-acetylanthranilate; salicylic acid And salicylic acid-based ultraviolet absorbers such as sodium salt, amylsalicylate, menthylsalicylate, homomentylsalicylate, octylsalicylate, phenylsalicylate, benzylsalicylate, p-isopropanol phenylsalicylate; octylcinnamate, ethyl-4-isopropylsinnamate, methyl. -2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl-p-methoxy cinnamate, isopropyl-p-methoxy cinnamate, isoamyl-p-methoxy Synnamete, 2-ethylhexyl p-methoxycinnamate (octyl paramethoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate (synoxate), cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenyl Cyraxic acid-based ultraviolet absorbers such as cinnamate, 2-ethylhexyl α-cyano-β-phenyl cinnamate (octocrine), glycerylmono-2-ethylhexanoyl-diparamethoxycinnamate, ferulic acid and derivatives thereof; 2, 4-Dihydroxybenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2,2', 4,4'-tetrahydroxybenzophenone, 2-hydroxy- 4-Methoxybenzophenone (oxybenzon-3), 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4' Benzophenones such as −phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone UV absorbers; 3- (4'-methylbenziliden) -d, l-phenyl, 3-benziliden-d, l-phenyl; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5 -Methylphenylbenzotriazole; 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole; 2- (2'-hydroxy-5'-methylphenylbenzotriazole; dibenzalazine; dianisoilmethane; 5-( 3,3-Dimethyl-2-norbornylidene) -3-pentan-2-one; dibenzoylmethane derivatives such as 4-t-butylmethoxydibenzoylmethane; octylriazone; urocanic acid derivatives such as urocanic acid and ethyl urocanate 2- (2'-Hydroxy-5'-methylphenyl) benzotriazole, 1- (3,4-dimethoxyphenyl) -4,4-dimethyl-1,3-pentandione, dimethoxybenzilidendioxoimidazolidine propionic acid Hydantin derivatives such as 2-ethylhexyl, phenylbenzimidazole sulfonic acid, terephthalylidene dicanfursulfonic acid, drometrizole trisiloxane, methyl anthranilate, rutin and its derivatives, oryzanol and its derivatives are preferred.

Examples of vitamins and derivatives thereof include vitamin A such as retinol, retinol acetate, and retinol palmitate; thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxin hydrochloride, pyridoxin dioctanoate, pyridoxin dipalmitate, etc. Vitamin B group such as flavin adenin dinucleotide, cyanocobalamine, folic acid, nicotinic acid such as nicotinic acid amide / benzyl nicotinate, choline; vitamin C such as ascorbic acid and its sodium salt; vitamin D; α, Vitamin E such as β, γ, δ-tocopherol; other vitamins such as pantothenic acid and biotin; ascorbic acid phosphate ester salt such as ascorbic acid phosphate sodium salt and ascorbic acid phosphate ester magnesium salt, tetra ascorbic acid Ascorbic acid fatty acid ester such as isoparmic acid ester, ascorbic stearate, ascorbic palmitate, ascorbic dipalmitate, alkyl ether ascorbic acid such as ethyl ether ascorbic acid, ascorbic acid glucoside such as -2-glucoside ascorbic acid and its fatty acid ester , Ascorbic acid derivatives such as tocopheryl ascorbic acid; tocopherol nicotinate, tocopherol acetate, tocopherol linoleate, tocopherol ferulate, tocopherol derivatives such as tocopherol phosphate, and other vitamin derivatives, tocotrienol, and other various vitamin derivatives are preferable. Is listed as.

Anti-inflammatory and anti-inflammatory agents include glycyrrhizic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokithiol, guaiazulene, allantoin, indomethacin, zinc oxide, hydrocortisone acetate, prednisone, diphedramine hydrochloride, chlorpheniramine maleate; peach leaf extract. , Plant extracts such as Honoha extract are preferred. As hair growth agents, blood circulation promoters, and stimulants, plant extracts and tinctures such as senburi extract, togarashi tincture, ginger tincture, ginger extract, and cantarist tincture; capsaicin, nonylate valenylamide, gingerone, ictamol, and tannic acid. , Borneol, cyclanderate, cinnaridine, trazoline, acetylcholine, verapamil, cepharanthin, γ-orizanol, cepharanthin, vitamin E and derivatives such as tocopherol nicotinate / tocopherol acetate, γ-orizanol, nicotinic acid and nicotinic acid amide / benzyl nicotinate. Derivatives such as ester inositol hexanicotinate and nicotine alcohol, allantin, photosensitizer 301, photosensitizer 401, capronium chloride, pentadecanoic acid monoglyceride, flavanonol derivative, stigmasterol or stigmasterol and its glycoside, minoxidil are preferable. Is listed as. As the hormones, estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone and the like are preferable. Other medicinal agents such as anti-wrinkle agents, anti-aging agents, tightening agents, cold sensitizers, warming agents, wound healing promoters, stimulant relievers, analgesics, cell activators, etc. include retinols, retinoic acids, retinoins. Tocopheryl acid; derivatives such as lactic acid, glycolic acid, gluconic acid, fruit acid, salicylic acid and its glycosides / esterified products, hydroxycapric acid, long-chain α-hydroxy fatty acid, long-chain α-hydroxy fatty acid cholesteryl and other α- or β-Hydroxy acids and their derivatives; γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid; carnitine; carnosin; creatin; ceramides, spingosins; caffeine, xanthin and its derivatives; coenzyme Q10, carotene, lycopene , Astaxanthin, lutein, α-lipoic acid, platinum nanocolloids, fullerene and other antioxidant / active oxygen scavengers; catechins; quercetin and other flavones; isoflavones; gallic acid and ester sugar derivatives; tannins, sesamine, proto Polyphenols such as anthocyanidin, chlorogenic acid, apple polyphenols; derivatives such as rutin and glycosides; derivatives such as hesperidin and glycosides; lignan glycosides; Glycoside, gingerol; fragrance substances such as menthol, camphor, sedrol and derivatives thereof; capsaicin, vanillin and derivatives; insect repellents such as diethyl toluamide; complexes of physiologically active substances and cyclodextrins are preferred. Can be mentioned.

Plant / animal / microbial extracts include iris extract, acitaba extract, asunaro extract, asparagus extract, avocado extract, flaxseed extract, almond extract, altea extract, arnica extract, aloe extract, apricot extract, apricot kernel extract, ginkgo extract. , Inchikou extract, Uikyo extract, Ukon extract, Woolong tea extract, Uwaurushi extract, Agetsu extract, Echinashi leaf extract, Enmeisou extract, Ogon extract, Oubaku extract, Ouren extract, Omugi extract, Otanenjinjin extract, Otogirisou extract, Odorikousou extract, Ononis extract , Dutch mustard extract, orange extract, dried seawater, seaweed extract, oyster leaf extract, oyster extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolyzed silk, cucumber extract, chamomile extract, oil-soluble chamomile extract, carrot extract, kawarayomogi Extract, crow wheat extract, calcade extract, kanzo extract, oil-soluble kanzo extract, kiwi extract, kiou extract, kikurage extract, kina extract, cucumber extract, kiri leaf extract, guanosine, guava extract, kujin extract, cutinashi extract, kumazasa extract, clara extract, walnut Extract, chestnut extract, grapefruit extract, clematis extract, black rice extract, brown sugar extract, black vinegar, chlorella extract, quail extract, gentiana extract, gennoshouko extract, tea extract, yeast extract, koboku extract, coffee extract, gobo extract, rice extract, rice Fermented extract, fermented rice bran extract, rice germ oil, comfrey extract, collagen, moss peach extract, saishin extract, psycho extract, saitai extract, saffron extract, salvia extract, sabonsou extract, sasa extract, sanzashi extract, sansha extract, sansho Extract, Shiitake extract, Jio extract, Shikon extract, Shiso extract, Shinanoki extract, Shimotsukesou extract, Jatoba extract, Shakuyaku extract, Shokyu extract, Shobu root extract, Shirakaba extract, White chrysanthemum extract, Sugina extract, Stevia extract, Stevia fermented product, Nishikawayanagi extract, Seiyoukizuta extract, Seiyousanzashi extract, Seiyouniwatoko extract, Seiyounokogirisou extract, Seiyouhakka extract, Sage extract, Zeniaoi extract, Senkyu extract, Senburi extract, Souhakuhi extract, Daiou extract, Dai Zu extract, Taisou extract, Thyme extract, Dandelion extract, Local clothing extract, Tea extract, Chouji extract, Chigaya extract, Chinpi extract, Tea tree oil, Jincha extract, Togarashi extract, Touki extract, Tokinsenka extract, Tounin extract, Tohi extract, Dokudami extract, Tomato Extract, Natto extract, Carrot extract, Carrot extract, Novara extract, Hibiscus extract, Bakumondou extract, Hass extract, Parsley extract, Birch extract, Honey, Hamamelis extract, Paris etalia extract, Hikiokoshi extract, Bisaborol, Hinoki extract, Bifizus bacterium extract, Biwa extract, Fukitanpopo extract, Fukinotou extract, Bukuryo extract, Butcher bloom extract, Grape extract, Grape seed extract, Propolis, Hechima extract, Benibana extract, Peppermint extract, Bodaiju extract, Button extract, Hop extract, Maikaika extract, Pine extract, Maronie extract , Mizubasho extract, Mukuroji extract, Melissa extract, Mozuku extract, Peach extract, Yagurumagiku extract, Eucalyptus extract, Yukinoshita extract, Yuzu extract, Yuri extract, Yokuinin extract, Yomogi extract, Lavender extract, Green tea extract, Eggshell membrane extract, Apple extract, Louis Boss tea extract , Reishi extract, lettuce extract, lemon extract, lotus extract, lotus extract, rose extract, rosemary extract, roman chamomile extract, royal jelly extract, crackle extract and the like are preferable.

Examples of the antipruritic agent include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, substance-P inhibitor and the like. Examples of the exfoliating / dissolving agent include salicylic acid, sulfur, resorcin, selenium sulfide, and pyridoxine. Examples of the antiperspirant include chlorohydroxyaluminum, aluminum chloride, zinc oxide, zinc paraphenol sulfonate and the like. Examples of the refreshing agent include menthol and methyl salicylate. Examples of the astringent include citric acid, tartaric acid, lactic acid, aluminum / potassium sulfate, tannic acid and the like. Examples of enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, protease and the like. Preferred examples of nucleic acids include ribonucleic acid and a salt thereof, deoxyribonucleic acid and a salt thereof, and disodium adenosine triphosphate.

As fragrances, acetylsedrene, amylcinnamaldehyde, allylamylglycolate, β-ionone, isoe super, isobutylquinolin, iris oil, iron, indol, ylang ylang oil, undecanal, undecenal, γ-undecalactone, Estragor, Eugenol, Oak Moss, Opoponax Resinoid, Orange Oil, Eugenol, Oranthiol, Galaxolid, Carbachlor, L-Carbon, Kamfer, Cannon, Carrot Seed Oil, Clove Oil, Methyl Cylate, Geraniol, Geranyl nitrile , Isobornyl acetate, Geranyl acetate, Dimethylbenzylcarbinate acetate, Styralyl acetate, Cedril acetate, Telepinel acetate, pt-butylcyclohexyl acetate, Vetiberyl acetate, benzyl acetate, Linaryl acetate, Isopentyl salicylate, benzyl salicylate, Sandalwood oil, Santa roll, Cyclamenaldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromilsenol, jasmine absolute, jasmine lactone, cis-jasmon, citral, citronenol, citroneral, cinnamon bark oil, 1,8-cineole, cinnamaldehyde, stylux Reginoid, Cedarwood Oil, Sedren, Sedrol, Celori Seed Oil, Thyme Oil, Damascon, Damasenon, Timor, Tuberose Absolute, Decanal, Decalactone, Terpineol, γ-Terpinen, Triplar, Nerol, Nonanar, 2,6-Nonadienor, Nonalactone, Pachori Alcohol, vanilla absolute, vanillin, basil oil, patcholi oil, hydroxycitroneral, α-pinene, piperitone, phenethyl alcohol, phenylacetaldehyde, petitgrain oil, hexylcinnamaldehyde, cis-3-hexenol, peruvian balsam, vetiver oil, vetiverol , Peppermint oil, pepper oil, heliotropin, bergamot oil, benzylbenzoate, borneol, milresinoid, muskketone, methylnonylacetaldehyde, γ-methylyonone, menthol, L-menthol, L-menton, eucalyptus oil, β-yonone, lime oil , Lavender oil, D-limonen, linalol, lylar, lilial, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, synthetic fragrances such as various essential oils and natural Fragrances and various blended fragrances are preferred.

Dyes / colorants / dyes / pigments include brown 201, black 401, purple 201, purple 401, blue 1, blue 2, blue 201, blue 202, blue 203, and blue 204. , Blue 205, Blue 403, Blue 404, Green 201, Green 202, Green 204, Green 205, Green 3, Green 401, Green 402, Red 102, Red 104-1 , Red 105-1, Red 106, Red 2, Red 201, Red 202, Red 203, Red 204, Red 205, Red 206, Red 207, Red 208, Red 213 , Red 214, Red 215, Red 218, Red 219, Red 220, Red 221, Red 223, Red 225, Red 226, Red 227, Red 228, Red 230-1 , Red 230-2, Red 231, Red 232, Red 3, Red 401, Red 404, Red 405, Red 501, Red 502, Red 503, Red 504, Red 505 , Red 506, Orange 201, Orange 203, Orange 204, Orange 205, Orange 206, Orange 207, Orange 401, Orange 402, Orange 403, Yellow 201, Yellow 202-1 , Yellow 202-2, Yellow 203, Yellow 204, Yellow 205, Yellow 4, Yellow 401, Yellow 402, Yellow 403-1, Yellow 404, Yellow 405, Yellow 406, Yellow Legal dyes such as No. 407 and Yellow No. 5; Other acidic dyes such as Acid Red 14; Basic dyes such as Arianor Sienna Brown, Arianor Madder Red, Arianor Steel Blue, Arianor Straw Yellow; HC Yellow 2, HC Yellow 5, HC Red 3, 4-hydoxypropylamino-3-nitrophenol, N, N'-bis (2-hydroxyethyl) -2-nitro-p- phenylenediamine, HC Blue 2, Basic Blue 26 and other nitro dyes; Disperse dyes; Titanium dioxide, Zinc oxide Inorganic white pigments such as; Inorganic red pigments such as iron oxide (Bengala) and iron titanate; Inorganic brown pigments such as γ-iron oxide; Inorganic yellow pigments such as yellow iron oxide and ocher; Black iron oxide, low Inorganic black pigments such as next titanium oxide; Inorganic purple pigments such as mango violet and cobalt violet; Inorganic green pigments such as dye, chromium hydroxide, cobalt titanate; inorganic blue pigments such as ultramarine and dark blue; titanium oxide coated mica, titanium oxide coated oxybismus chloride, titanium oxide coated talc, colored titanium oxide coated mica, oxy Pearl pigments such as bismuth chloride and fish scale foil; metal powder pigments such as aluminum powder, copper powder and gold; surface-treated inorganic and metal powder pigments; red 201, red 202, red 204, red 205, red 220 , Red 226, Red 228, Red 405, Orange 203, Orange 204, Yellow 205, Yellow 401, Blue 404, Red 3, Red 104, Red 106, Red 227, Red Organic pigments such as zirconium, barium or aluminum lakes such as 230, red 401, red 505, orange 205, yellow 4, yellow 5, yellow 202, yellow 203, green 3 and blue 1. Surface-treated organic pigments; anthraquinones such as astaxanthin and alizarin, anthocyanidins, β-carotene, catenal, capsantin, chalcone, calsamine, quercetin, crocin, chlorophyll, curcumin, cochineal, naphthoquinones such as ciconin, bixin, flavones, beta Natural pigments and dyes such as cyanidine, henna, hemoglobin, lycopene, riboflavin, rutin; p-phenylenediamine, toluene-2,5-diamine, o-, m-, or p-aminophenol, m-phenylenediamine, 5- Oxidation dye intermediates and couplers such as amino-2-methylphenol, resorcin, 1-naphthol, 2,6-diaminopyridine and salts thereof; auto-oxidation dyes such as indolin; dihydroxyacetones are preferred.

As the water, in addition to normal water and purified water, hard water, soft water, natural water, deep ocean water, electrolytic alkaline ionized water, electrolytically acidic ionized water, ionized water, and cluster water are preferable.

In addition to these, cosmetic raw material standards, compounding ingredient standards by cosmetic type, Japan Cosmetic Industry Association ingredient display name list, INCI dictionary (The International Cosmetic Ingredient Dictionary and Handbook), pharmaceutical non-pharmaceutical raw material standards, Japanese Pharmacy, pharmaceutical additives Ingredients described in standards, official food additive official documents, etc., and Japanese and foreign patent gazettes and patent publication gazettes (including publication gazettes and republishing) whose international patent classification IPC belongs to the classification of A61K7 and A61K8 It is possible to contain known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc., such as the described ingredients, in known combinations, blending ratios, and blending amounts.

Examples of the type of cosmetics of the present invention include hair cosmetics, basic cosmetics, make-up cosmetics, aromatic cosmetics, body cosmetics, skin external preparations such as ointments, and the like. From the viewpoint of exerting the effects of the present invention, it can be particularly preferably used for hair cosmetics and basic cosmetics. The cosmetic of the present invention can be produced according to a usual method.

Explaining the types of the cosmetics of the present invention in more detail, the hair cosmetics include oil shampoos, cream shampoos, conditioning shampoos, shampoos for indulgence, shampoos for hair coloring, shampoos such as rinse-integrated shampoos; rinses, treatments, Conditioners such as hair packs and hair mists; hair styling products such as hair foams, hair mousses, hair sprays, hair waxes, hair gels, hair creams, water greases, set lotions, pomades, tics; color lotions, hair tonics, hair liquids, hair blows, branches Hair coats, hair oils, permanent wave agents, straight perms, oxidative hair dyes, hair bleaches, hair color pretreatments, hair color aftertreatments, perma pretreatments, perma aftertreatments, hair manicures, and hair restorers are preferred. Be done.

Basic cosmetics include softening lotion, astringent lotion, cleansing lotion, multi-layered lotion, etc .; emollient lotion, moisture lotion, milky lotion, nourishing lotion, nourishing milk, skin moisturizer, moisturizer. -Emulsion, massage lotion, cleansing lotion, protect emulsion, sun protect, sun protector, UV care milk, sun screen, make-up lotion, horny smoother, elbow lotion, hand lotion, body lotion and other emulsions; emollient cream, nutrition cream, Nourishing cream, vanishing cream, moisture cream, night cream, massage cream, cleansing cream, make-up cream, base cream, pre-makeup cream, sunscreen cream, suntan cream, hair removal cream, deodorant cream, shaving cream, keratin softening Creams such as creams; Gels such as moisture gels; Essences such as moisturizing essences, whitening essences, and UV protection essences; Lipstick cosmetics such as liposome beauty liquids and liposome cosmetics; Peel-off packs, powder packs, washing packs, oil packs, cleansing Packs and masks such as masks; cleansing foam, cleansing cream, cleansing milk, cleansing lotion, cleansing gel, cleansing oil, cleansing mask, cleansing powder, facial cleansing powder, etc.; cosmetic soap, transparent soap, medicated soap, liquid soap, Soaps such as shaving soaps and synthetic cosmetic soaps are preferred.

Preferred makeup cosmetics include white powder / dusting powder, foundations, lipsticks, lip gloss, blusher, eyeliner, mascara, eye shadow, eyebrow, eyebrow, nail enamel, enamel remover, and nail treatment. ..

Preferable aromatic cosmetics include perfume, perfume, parfum, eau de parfum, eau de toilette, cologne, perfume paste, fragrance powder, perfume soap, body lotion, and bath oil.

Body cosmetics include body cleaners such as body shampoo, deodorant lotions, deodorant powders, deodorant sprays, deodorant cosmetics such as deodorant sticks, depigmenting agents, depilatory / depilatory agents, bathing agents, insect repellent sprays, etc. Repellers are preferred.

Further, as the external preparation for skin, it can be used in a dosage form such as an ointment, a patch, a lotion, a liniment, and a liquid coating agent. It can also be used as an oral cosmetic such as toothpaste and mouthwash.

As the dosage form of the cosmetic or skin external preparation of the present invention, emulsification of oil-in-water (O / W) type, water-in-oil (W / O) type, W / O / W type, O / W / O type and the like. Molded cosmetics, oil-based cosmetics, solid cosmetics, liquid cosmetics, paste-like cosmetics, stick-shaped cosmetics, volatile oil-based cosmetics, powdered cosmetics, jelly-like cosmetics, gel-like cosmetics, paste-like Pharmaceutical types such as cosmetics, emulsified polymer type cosmetics, sheet-like cosmetics, mist-like cosmetics, and spray-type cosmetics are preferable.

The present invention will be described in more detail with reference to the following examples, but the present invention is not limited thereto.

(Preparation of cosmetic composition)
Example 1
185.0 g of jojoba oil and 36.0 g of concentrated sulfuric acid were charged in a 300 mL reactor equipped with a stirrer, a thermometer and a gas introduction tube, and reacted at 85 ° C. for 22 hours in a nitrogen atmosphere. 450 g of heptane was charged into the obtained reaction solution, washed with water three times, deoxidized with a 2% sodium hydroxide solution, and further washed with water five times. The heptane phase was concentrated under reduced pressure to give 150.0 g of the desired cosmetic composition as a brown solid.

Example 2
100.0 g of camellia oil and 42.9 g of concentrated sulfuric acid were charged in a 300 mL reactor equipped with a stirrer, a thermometer and a gas introduction tube, and reacted at 85 ° C. for 22 hours in a nitrogen atmosphere. 250 g of heptane was charged into the obtained reaction solution, washed with water three times, deoxidized with a 2% sodium hydroxide solution, and further washed with water five times. The heptane phase was concentrated under reduced pressure to give 81.0 g of the desired cosmetic composition as a brown solid.

Comparative Example 1
An operation was carried out in the same manner as in Example 1 except that the amount of concentrated sulfuric acid was 0.5 g, to obtain a comparative cosmetic composition.

Comparative Example 2
The same operation as in Example 1 was carried out except that the temperature was set to 20 ° C. to obtain a comparative cosmetic composition.

Hair improvement effect (sensory evaluation)
Using the cosmetic compositions of Examples 1 and 2 and Comparative Examples 1 and 2, hair cosmetics (hair oils) were prepared with the compositions of Tables 1 and 2. For comparison, a hair oil containing no cosmetic composition was prepared. Using the obtained hair oils of Examples 3 to 4 and Comparative Examples 3 to 6, the effects of improving the firmness, luster, cohesiveness, dryness, and overall damage feeling of the hair were evaluated. The test method was as follows, and the results are shown in Table 3.

(Test method)
Healthy black hair was bleached once with a commercially available bleaching agent to prepare a bundle of damaged hair. Next, 1 g of each hair oil was uniformly applied to 5 g of the damaged hair bundle and air-dried to obtain a hair bundle A. A part of the hair bundle A was heat-treated with warm air from a dryer for 3 minutes to obtain a hair bundle B. Further, a part of the hair bundle B was washed with a 3% aqueous solution of sodium laureth sulfate, washed with water 5 times, and then air-dried to obtain a hair bundle C. For each of the prepared hair bundles, the effect of improving the firmness, luster, cohesiveness, dryness, and overall damage feeling of the hair was evaluated by sensory evaluation (5 panelists).

（調製方法）
Ｎｏ．１をＮｏ．２に溶解させた。得られた溶解液を室温でドデカンに添加し、よく攪拌した。

（調製方法）
Ｎｏ．１をＮｏ．２に溶解させた。得られた溶解液を室温でドデカンに添加し、よく攪拌した。

(Preparation method)
No. 1 is No. It was dissolved in 2. The obtained solution was added to dodecane at room temperature and stirred well.

(Preparation method)
No. 1 is No. It was dissolved in 2. The obtained solution was added to dodecane at room temperature and stirred well.

評価基準 ○：未処理の毛束（損傷毛）と比較して改善した
△：未処理の毛束（損傷毛）と比較してやや改善した
×：未処理の毛束（損傷毛）と比較して変化がない

Evaluation Criteria ○: Improved compared to untreated hair bundles (damaged hair)
Δ: Slightly improved compared to untreated hair bundles (damaged hair)
×: No change compared to untreated hair bundle (damaged hair)

From the results in Table 3, the hair cosmetics of Examples 3 and 4 containing the cosmetic composition of the present invention improved the overall feeling of damage to the hair such as firmness, luster, cohesiveness, and dryness, and heat treatment was performed. The effect was higher with the applied hair bundle B. In addition, the hair improving effect was not lost even in the hair bundle C in which the hair bundle B was washed. On the other hand, the hair cosmetics of Comparative Examples 3 to 6 did not sufficiently improve the feeling of damage to the hair, and the hair bundle C in which the hair bundle B was washed had almost no effect. From the above, it was confirmed that the hair improving effect can be obtained and the effect can be maintained by heat-treating the hair cosmetic containing the cosmetic composition of the present invention.

The cosmetic composition described below was prepared using the cosmetic composition of the present invention. The obtained cosmetics gave the hair firmness and luster, and the hair was cohesive, had good finger passage, and had a non-dry finish, and could improve the damage to the hair.

Example 5 Hair mist

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
The cosmetic composition of Example 1 0.2
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 0.2
Caprylyl glucoside 0.3
Camellia oil 0.1
Setrimonium chloride (30%) 6.0
Ethanol 8.0
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Each component was uniformly stirred and mixed.

Example 6 Hair Essence

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 0.5
Neosolue-Aqua (Nippon Fine Chemical Co., Ltd.) 0.2
Cetanol 1.0
Stealtrimonium chloride (63%) 0.8
Dicocodimonium chloride (75%) 2.8
Solves Tetraoleate-60 1.0
PEG-40 hydrogenated castor oil 0.2
Part B Methylparaben 0.1
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was heated to about 80 ° C. to dissolve it. Part B was placed in another container and heated to about 80 ° C. to dissolve it. Part B was gradually added to part A and mixed uniformly.

Example 7 Hair lotion

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A LP70H (Nippon Fine Chemical Co., Ltd.) 0.1
The cosmetic composition of Example 1 0.1
PEG-4 3.0
Menthol 0.05
Ethanol 50.0
Part B Pyridoxine HCl 0.1
Glycyrrhizinate 2K 0.1
BG 3.0
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was mixed uniformly. Part B was uniformly mixed in a separate container. Part B was added to part A and mixed uniformly.

Example 8 Fixing sleeping habits

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
The cosmetic composition of Example 1 0.05
NanoRepair-CMC5 (Nippon Fine Chemical Co., Ltd.) 2.0
Glycerin 2.0
Pentylene glycol 2.0
Behentrimonium chloride (80%) 0.6
Ethanol 20.0
Dimethicone Propyl PG Betaine 1.0
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
All components were uniformly dissolved.

Example 9 Hair cream

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 2.5
Cetanol 4.0
Dimethicone (500cs) 5.0
Glyceryl stearate 2.8
Oles-10 Phosphate 0.8
Glyceryl stearate (SE) 1.6
Part B Phenoxyethanol 0.4
Methylparaben 0.2
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part B was added to another container and heated to about 80 ° C. to dissolve it. Part B was added to part A, and the mixture was stirred and mixed.

Example 10 Hair treatment that does not wash away

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Neosolue-Aqualio (Nippon Fine Chemical Co., Ltd.) 0.2
The cosmetic composition of Example 1 0.1
Setrimonium chloride (25%) 3.8
Caprylyl glucoside (50%) 0.8
Glycerin 4.0
Phenoxyethanol 0.2
Part B Ethanol 20.0
Part C Polyquaternium-6 0.6
Polyquaternium-7 0.4
Snow fungus polysaccharide 0.05
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part C was heated to about 80 ° C. to dissolve it. Next, part A was heated to about 80 ° C. to dissolve it. Part C was added while stirring, and after mixing uniformly, the mixture was cooled to about 40 ° C. Then, part B was added and mixed uniformly.

Example 11 Leave-on treatment

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 1.0
Diethyl sebacate (Nippon Fine Chemical Co., Ltd.) 1.0
LUSPLAN SR-DM4 (Nippon Fine Chemical Co., Ltd.) 0.2
Myristyl Alcohol 5.0
Behenyl alcohol 1.0
Oleyl alcohol 1.0
Dimethylpropylamide stearate 2.0
Sodium cocoamphoacetate (30%) 2.0
Glyceryl stearate 0.4
Myristic acid 0.6
Phenoxyethanol 0.4
Part B Lactic acid 0.6
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was heated to about 80 ° C. and dissolved uniformly. Part B was heated to about 80 ° C. to dissolve it. Part B was gradually added to part A and mixed uniformly.

Example 12 Leave-on treatment

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 2.5
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 0.2
Isopropyl palmitate 4.0
Cetanol 5.0
Stealtrimonium chloride (63%) 3.2
Behentrimonium chloride (80%) 1.0
Squalene 1.0
Glycerin 1.0
Part B Methylparaben 0.10
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part B was heated to about 80 ° C. to dissolve it. Part B was gradually added to part A and mixed uniformly.

Example 13 Hair treatment that does not wash away

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 2.5
Plandoll-DP (Nippon Fine Chemical Co., Ltd.) 1.0
Polyquaternium-37 2.0
Squalene 2.0
PPG-3 Caprylyl Ether 2.0
Microcrystalline wax 0.1
Lanolin alcohol 0.2
Montan wax 0.1
Polyethylene wax 0.1
Beeswax 0.1
Japan wax 0.2
Celesin 0.1
Dicapric acid PG 1.0
Almond oil 0.5
Ethylhexyl ethylhexanoate 1.0
Candelilla low extract 0.1
Octyldodecyl erucate 4.5
Tocopherol acetate 0.02
γ-docosalactone, tri (caprylic acid / capric acid) glyceryl (ercalactone MCT: Nippon Fine Chemical Co., Ltd.) 2.0
Dipentaerythrityl tripolyhydroxystearate 1.5
PPG-5 Phytosteryl 0.5
Glycerin 4.0
Sorbitol 2.0
Phenoxyethanol 0.5
Part B Hydrolyzed Conchiolin 0.1
Panthenol 0.1
Hydroxypropyltrimonium hyaluronate 0.01
Polyquaternium-11 0.2
Glycosyl trehalose 0.1
Glyceryl glucoside 0.3
Arginine 0.1
Part C Purified water Total amount of 100 Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 0.3
Hydroxypropyl starch phosphate 1.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part C was uniformly dispersed and heated to about 80 ° C. Next, part A was heated to about 80 ° C. to dissolve it. Part C was added while stirring, and after mixing uniformly, the mixture was cooled to about 40 ° C. Then, each part B was added and mixed uniformly.

Example 14 Non-silicone hair treatment

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 3.0
Cetearyl alcohol 3.0
PPG-1 / PEG-1 stearamine 0.8
Behenamide propyl dimethylamine 1.0
Ethylhexyl palmitate 1.0
Dextrin palmitate 0.5
Inulin stearate 0.5
Neosolue-DE (Nippon Fine Chemical Co., Ltd.) 1.0
Hybrid sunflower oil 1.0
DPG 1.8
Glycerin 4.0
Mineral oil 0.5
Plandoll-DP (Nippon Fine Chemical Co., Ltd.) 1.0
LUSPLAN SR-DM4 (Nippon Fine Chemical Co., Ltd.) 0.2
PEG-160M 0.5
Rice bran wax 1.0
Part B Lecithin Hydroxide 0.2
Lactic acid 0.3
Hydrolyzed starch 0.4
Hyaluronic acid Na 0.05
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
Hydroxypropyl Methyl Cellulose 0.1
Amount of purified water totaling 100 Part C Polyquaternium-107 0.5
Neopentyl glycol diheptate 2.0
Ethylhexyl isononanoate 1.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was added to another container and heated to dissolve it. Part B was gradually added to part A, mixed uniformly, and cooled. Part C was added at around 50 ° C. and mixed uniformly.

Example 15 Non-silicone treatment

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 1.0
Plandoll-H (Nippon Fine Chemical Co., Ltd.) 0.5
Behentrimonium metosulfate 1.3
Setrimonium chloride 0.3
Paraffin 1.0
Hydroxypropyltrimonium hyaluronate 0.2
Isostearic acid hydrogenated castor oil 1.0
Squalene 2.0
Tocopherol acetate 0.05
Diethyl sebacate 2.0
Candelilla wax 0.3
Rice bran wax 0.2
Apricot kernel oil 1.0
DPG 2.0
Propanediol 1.0
Benzyl alcohol 0.5
Glycerin 1.0
PEG-7 propyl heptyl ether 0.8
PEG-180M 0.3
Part B Methylisothiazolinone 0.005
EDTA-2Na 0.03
Zinc chloride 0.1
Amount of purified water totaling 100 Polyquaternium-10 0.2
Part C LUSPLAN SR-DM4 (Nippon Fine Chemical Co., Ltd.) 0.2
Isodecyl neopentane (Nippon Fine Chemical Co., Ltd.) 0.5
Ethylhexyl sebacate (Nippon Fine Chemical Co., Ltd.) 0.7
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was added to another container and heated to dissolve it. Part B was gradually added to part A, mixed uniformly, and cooled. Part C was added at around 50 ° C. and mixed uniformly.

Example 16 Hair wax

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 1.0
Microcrystalline wax 12.0
Triethylhexanoin 5.0
Candelilla Row 6.0
Hydroxystearic acid 4.0
Glyceryl stearate (Leodor MS-60) 1.0
Glyceryl stearate (Nikkor MGS-BSE) 1.0
Behenes-2 4.0
Behenes-20 10.0
Cosmetic Composition of Example 1 5.0
Phenoxyethanol 0.6
Methylparaben 0.2
BG 3.0
Part B Alcox Z-240 (Meisei Kagaku) 0.20
Amount of purified water totaling 100 Part C Citric acid (1%) Appropriate amount Na citrate (1%) Appropriate amount ------------- −−−−−−−−−−−−
(Preparation method)
Take parts A and B, respectively, heat to about 80 ° C, and mix uniformly. Part B is gradually added to part A with stirring, mixed uniformly, and then cooled (part D). Add part C to part D to adjust the pH to 6.

Example 17 Moose

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Stock solution prescription)
Cosmetic Composition of Example 1 0.5
Ethanol 5.0
LUSPLAN PI-DA (Nippon Fine Chemical Co., Ltd.) 0.2
Ores-20 1.0
Acrylic resin alkanolamine solution 2.0
Yukaformer AM75W (manufactured by Mitsubishi Chemical Corporation) 1.0
Diethylaminoethylamide stearate 0.5
Pyrrolidone carboxylic acid 0.2
POE, POP modified silicone 1.0
Preservatives, fragrances Appropriate amount Purified water Amount that totals 100 ------------- −
(Preparation method)
Each component is uniformly stirred and mixed.
The above stock solution: petroleum liquefied gas = 92: 8 was mixed to obtain an injection type mousse.

Example 18 Hairspray

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Stock solution prescription)
Part A Cosmetic Composition of Example 1 2.0
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 1.0
LUSPLAN DA-R (Nippon Fine Chemical Co., Ltd.) 2.0
Part B PEG hydrogenated castor oil 0.02
Part C fragrance 0.05
Ethanol (anhydrous) A total amount of 100 (filling formulation)
Stock solution 55.0
LPG 45.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part B is added to part A (part D). Part C was added to and mixed with part D, and the stock solution was filled in a can and then filled with gas.

Example 19 Shampoo

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 0.5
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 0.3
Cocoyl Glutamic Acid TEA (30%) 50.0
Na tetradecene sulfonate (36%) 15.0
PEG-150 5.0 distearate
Methylparaben 0.2
Phenoxyethanol 0.5
Propylene glycol 1.0
(Icosane diic acid / tetradecane diic acid) Polyglyceryl-10 (Nippon Fine Chemical Co., Ltd.)
1.0
Part B cationized guar gum 0.2
Amount of purified water totaling 100 Part C Phosphoric acid (10%) Appropriate amount −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− −−−−−
(Preparation method)
Parts A and B were taken, heated to about 80 ° C., and mixed uniformly. Part A was added to part B, mixed uniformly, and then cooled (part D). The pH was adjusted to 6 to 6.5 by adding the C part to the D part.

Example 20 Rinse-in shampoo

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 1.0
Cocamidopropyl Betaine (30%) 20.0
Plandoll-ISS (Nippon Fine Chemical Co., Ltd.) 0.5
Lauryl Sulfate TEA (40%) 15.0
Cocamide DEA 2.0
Cocoyl Glutamic Acid TEA (30%) 30.0
Ethylene glycol distearate 1.2
Polyquaternium-10 1.6
Stearyltrimonium bromide (70%) 0.6
Phenoxyethanol 0.2
Part B Methylparaben 0.20
Na benzoate 0.40
Amount of purified water that is 100% -------------
(Preparation method)
Parts A and B were taken, heated to about 80 ° C., and mixed uniformly. Part A was added to part B, mixed uniformly, and then cooled.

Example 21 Shampoo for hair coloring

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Poly (HEMA Glucoside) (20%) 4.0
Cosmetic Composition of Example 1 0.5
Neosolue-Aqualio (Nippon Fine Chemical Co., Ltd.) 0.3
Cocoyl methyl taurine Na (30%) 15.0
Olefin (C14-16) Na Sulfonate (36%) 13.0
Sodium cocoamphoacetate (30%) 8.0
PPG-12-PEG-50 lanolin 2.5
Cocoyl glutamic acid (30%) 7.0
Polyquaternium-10 1.0
Lauramide propyl hydroxysultaine / water 4.0
PEG-20 hydrogenated castor oil 2.0
Etidronic acid 0.2
PG 0.2
Benzyl alcohol 2.0
Methylparaben 0.2
Phenoxyethanol 0.2
Amount of purified water that is 100% -------------
(Preparation method)
All components were leveled, heated to 80 ° C., stirred uniformly, mixed and then cooled.

Example 22 Rinse

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 5.0
Plandoll-H (Nippon Fine Chemical Co., Ltd.) 0.5
Setrimonium chloride (30%) 5.2
Octyldodecanol 4.7
Cetanol 2.8
Stealtrimonium chloride (63%) 0.6
Diethylhexyl sebacate (Nippon Fine Chemical Co., Ltd.) 0.3
Squalene 0.3
Myristyl Sulfate Na 0.2
Setes-40 0.1
Ores-5 0.1
Sodium cetyl sulfate 0.1
Part B citric acid 0.10
Methylparaben 0.10
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part B was heated to about 80 ° C. and dissolved. While stirring part B in part A, it was gradually added and mixed uniformly, stirred, and then rapidly cooled.

Example 23 Treatment

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 1.0
Behentrimonium chloride (80%) 2.4
Cetanol 5.2
Glyceryl stearate 1.2
LUSPLAN DA-R (Nippon Fine Chemical Co., Ltd.) 0.4
Dimethicone 2.0
(Aminoethylaminopropylmethicone / dimethicone) copolymer
0.5
Part B Methylparaben 0.1
Propylparaben 0.1
Amount of purified water totaling 100 Part C Adenosine monophosphate (10%) Appropriate amount ------------- −−−−−
(Preparation method)
Parts A and B were taken, heated to about 80 ° C., and mixed uniformly. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled (part D). The pH was adjusted to 5.2 to 5.7 by adding the C part to the D part.

Example 24 Treatment

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 5.0
Stealtrimonium chloride (63%) 3.8
Stealtrimonium bromide (70%) 1.0
Setes-18 0.8
Oleyl alcohol 3.0
Cetanol 4.0
LUSPLAN DD-DA5 (Nippon Fine Chemical Co., Ltd.) 0.1
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 0.3
Dimethylaminopropylamide stearate 2.0
Part B Hydrolyzed Collagen (Nippon Fine Chemical Co., Ltd.) 1.0
Appropriate amount of citric acid Amount of purified water totaling 100 -------------
(Preparation method)
Part A was heated to about 80 ° C. Part B was added to another container, and the mixture was heated and dissolved. Part A was gradually added to part B while stirring, mixed uniformly, stirred for 1 minute, and then rapidly cooled.

Example 25 Hair restorer

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
The cosmetic composition of Example 1 0.3
Belpole L-50 (Nippon Fine Chemical Co., Ltd.) 0.2
Menthol 0.1
Togarashi tinki 0.5
Swertia japonica extract 2.0
Ethanol 30.0
Preservatives Appropriate amount Fragrance Appropriate amount PPG-6 decyltetradeceth-30 0.3
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Production method)
Each component was uniformly stirred and mixed.

Example 26 Acidic hair dye (hair manicure)

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Cosmetic Composition of Example 1 1.0
N-Methylpyrrolidone 5.0
Benzyl alcohol 5.0
Citric acid 1.0
Brown No. 201 0.13
Black No. 401 0.05
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Each component was heated, dissolved and uniformly mixed.

Example 27 Hair bleaching agent (two-agent type)

(1 agent)
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Cosmetic Composition of Example 1 1.0
Polyoxyethylene oleyl ether 52.0
Ammonia water (25%) 25.5
Setrimonium chloride (30%) 10.0
Ethanol 10.0
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Each component was uniformly stirred and mixed.

(2 agents)
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Hydrogen peroxide solution 17.0
Setrimonium chloride (30%) 10.0
Cetanol 3.0
Setes-2 1.0
Setes-20 1.0
Na pyrophosphate 0.1
Diethylenetriamine pentaacetic acid 0.1
Citric acid (50%) Appropriate amount Purified water Amount that makes a total of 100 -------------
(Preparation method)
Each component was uniformly mixed and the pH was adjusted to 3.5-4.0 with citric acid.
(Mixing ratio)
1 agent: 2 agents = 1: 7

Example 28 Oxidation hair dye

(1 agent)
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Cosmetic Composition of Example 1 8.0
Setrimonium chloride (25%) 24.0
Cetanol 9.0
Octyldodecanol 9.0
Monoethanolamine 3.8
Ammonia water 2.0
Myristyl Sulfate Na 1.5
Ores-20 1.4
Toluene Hydrochloride-2, 5-Diamine 1.0
Resorcin 1.0
Metaaminophenol 0.5
Para-aminophenol 0.2
Orthoaminophenol 0.1
Ascorbic acid 0.2
Fragrance 0.1
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Each component was mixed uniformly.
(2 agents)
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Hydrogen peroxide solution 17.0
Setrimonium chloride (25%) 10.0
Cetanol 3.0
Ores-2 1.0
Ores-20 1.0
Na pyrophosphate 0.1
Diethylenetriamine pentaacetic acid 0.1
Citric acid (50%) Appropriate amount Purified water Amount that makes a total of 100 -------------
(Preparation method)
Each component was mixed uniformly and the pH was adjusted to 3.5-4.0 with citric acid.
(Mixing ratio)
1 agent: 2 agents = 1: 1

Example 29 Preperma solution

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Cosmetic Composition of Example 1 2.0
4-ethoxymethyl-1,3-dioxolane-2-one 1.0
Cation NH (Nippon Fine Chemical Co., Ltd.) 0.8
Caprylyl glucoside (50%) 1.0
Appropriate amount of citric acid Appropriate amount of Na citrate Methylparaben 0.2
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Dissolve each component uniformly.

Example 30 Hair oil

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
The cosmetic composition of Example 1 0.2
Elcalactone DES (Nippon Fine Chemical Co., Ltd.) 2.0
Neosolue-MP (Nippon Fine Chemical Co., Ltd.) 10.0
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 10.0
Neosolue-MCT (Nippon Fine Chemical Co., Ltd.) 20.0
Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 0.5
PPG-3 Caprylyl Ether 2.0
Tocopherol 0.1
Propylparaben 0.05
Carnauba wax 0.1
Amount of isododecane totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
All ingredients were heated and dissolved and mixed.

Example 31 Two-phase hair oil

Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Phase A Cosmetic Composition of Example 1 0.2
Rosehip oil 0.5
Jojoba oil 5.0
Elcalactone DES (Nippon Fine Chemical Co., Ltd.) 2.0
Neosolue-MP (Nippon Fine Chemical Co., Ltd.) 10.0
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 10.0
Neosolue-MCT (Nippon Fine Chemical Co., Ltd.) 20.0
Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 0.5
PPG-3 Caprylyl Ether 2.0
Tocopherol 0.1
Propylparaben 0.05
Carnauba wax 0.05
Isododecan Amount totaling 60 B-phase Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 0.2
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 0.2
Sea salt 0.05
NanoRepair-EL (Nippon Fine Chemical Co., Ltd.) 2.0
Methylparaben 0.1
Amount of water totaling 40 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
After mixing each phase uniformly, both phases were mixed.

In the above formulation, the details of the ingredients described by the product names are as follows.

〇Plandol-H: Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl)
〇Plandol-S: Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl)
〇Plandol-G: Dimer dilinoleyl bis (behenyl / isostearyl / phytosteryl)
〇Plandol-DP: Bisdiglyceryl polyacyl adipate-2
〇Plandol-ISS: Phytosteryl isostearate 〇Plandol-SUN: Sunflower seed oil fatty acid phytosteryl 〇Plandol-MAS: Macadamia nut oil fatty acid phytosteryl 〇Plandol-LG1: Di (phytosteryl / octyldodecyl) lauroyl glutamate
〇Plandol-LG2: Di lauroyl glutamate (phytosteryl / octyldodecyl)
〇Plandol-LG3: Di lauroyl glutamate (phytosteryl / octyldodecyl / behenyl)
〇Plandol-LG4: Di-lauroyl glutamate (phytosteryl / octyldodecyl / behenyl)
〇LUS PLAN PI-DA: Dimer dilinoleate di (isostearyl / phytosteryl)
〇LUS PLAN DD-DA5: DiMerlinolic acid Dimage linoleil 〇LUSPLAN DD-DA7: Dymage linoleic acid Dimage linoleil 〇LUS PLAN SR-DM4: Dimage linoleic acid Dimage linoleyl, tri (capric acid / capric acid) ) Glyceryl 〇LUS PLAN SR-DP4: Dimerdilinoleyl dimersylinoleate, pentaerythrityl tetraisostearate 〇Neosolue-Aquilo: bisethoxydiglycolcyclohexanedicarboxylic acid 〇Neosolue-Aqua: (eicosandioic acid / tetradecanedioic acid) polyglyceryl -10, Glycerin 〇 Neosolue-AquaS: (Eikosandioic acid / Tetradecanedioic acid) Polyglyceryl-10, Glycerin 〇 Neosolue-MP: Dineopentanemethylpentanediol 〇 Neosolue-DE: Dineopentate diethylpentanediol 〇 Neosolue-EHS: Diethylhexyl 〇 LP70H: Hydrogenated lysolecithin 〇 Tremoist-SL: White jellyfish polysaccharide aqueous solution (1%)
〇YOFCO MAC: Macadamia nut oil fatty acid cholesteryl 〇Cation NH: Quotanium-33
〇Elcalactone DES: γ-docosalactone, diethyl sebacate 〇Elcalactone MCT: γ-docosalactone, tri (caprylic acid / capric acid) glyceryl 〇NanoRepair-CMC5: ceramide 1, ceramide 2, ceramide 3, ceramide 5, ceramide 6. Cholesterol, quaternium-33, etc. 〇NanoRepair-EL: γ-docosalactone, phytosterols, quaternium-33, etc. 〇Belpole L-50: PEG-50 lanolin

Claims (6)

Against Tsu Baki Abura及beauty 100 parts by weight of vegetable oil selected from jojoba oil, plus 1 to 200 parts by weight of sulfuric acid, the cosmetic composition obtained by heat treatment at 50 to 150 ° C.. The cosmetic composition according to claim 1, wherein the vegetable oil is jojoba oil. A cosmetic containing the cosmetic composition according to claim 1 or 2. A hair cosmetic containing the cosmetic composition according to claim 1 or 2. The hair cosmetic according to claim 4, which is for improving hair damage. The hair cosmetic according to claim 5, wherein the hair cosmetic is used before the heat treatment in order to improve the hair damage by heat-treating the hair.