JP6634199B2 - Method for producing candelilla wax dispersion composition and hair treating agent - Google Patents
Method for producing candelilla wax dispersion composition and hair treating agent Download PDFInfo
- Publication number
- JP6634199B2 JP6634199B2 JP2014008538A JP2014008538A JP6634199B2 JP 6634199 B2 JP6634199 B2 JP 6634199B2 JP 2014008538 A JP2014008538 A JP 2014008538A JP 2014008538 A JP2014008538 A JP 2014008538A JP 6634199 B2 JP6634199 B2 JP 6634199B2
- Authority
- JP
- Japan
- Prior art keywords
- candelilla wax
- mass
- cetyl ether
- hair
- dispersion composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004204 candelilla wax Substances 0.000 title claims description 79
- 235000013868 candelilla wax Nutrition 0.000 title claims description 79
- 229940073532 candelilla wax Drugs 0.000 title claims description 78
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 title claims description 78
- 239000000203 mixture Substances 0.000 title claims description 68
- 239000003795 chemical substances by application Substances 0.000 title claims description 54
- 239000006185 dispersion Substances 0.000 title claims description 30
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 claims description 41
- 239000002736 nonionic surfactant Substances 0.000 claims description 28
- -1 polyoxyethylene cetyl ether Polymers 0.000 claims description 26
- 239000002245 particle Substances 0.000 claims description 19
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 14
- 239000000194 fatty acid Substances 0.000 claims description 14
- 229930195729 fatty acid Natural products 0.000 claims description 14
- 150000004665 fatty acids Chemical class 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000003945 anionic surfactant Substances 0.000 claims description 10
- 238000013329 compounding Methods 0.000 claims description 9
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 8
- 239000002280 amphoteric surfactant Substances 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 7
- 238000011282 treatment Methods 0.000 description 38
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 19
- 239000002994 raw material Substances 0.000 description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 239000003093 cationic surfactant Substances 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000003755 preservative agent Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- 239000001993 wax Substances 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 5
- 238000004040 coloring Methods 0.000 description 5
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 5
- 150000005846 sugar alcohols Polymers 0.000 description 5
- 239000007844 bleaching agent Substances 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 229940057995 liquid paraffin Drugs 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 230000002335 preservative effect Effects 0.000 description 4
- 239000002453 shampoo Substances 0.000 description 4
- 229940058015 1,3-butylene glycol Drugs 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 235000013871 bee wax Nutrition 0.000 description 3
- 239000012166 beeswax Substances 0.000 description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 229960000541 cetyl alcohol Drugs 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 238000007561 laser diffraction method Methods 0.000 description 3
- 235000013336 milk Nutrition 0.000 description 3
- 239000008267 milk Substances 0.000 description 3
- 210000004080 milk Anatomy 0.000 description 3
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 238000002203 pretreatment Methods 0.000 description 3
- 238000000790 scattering method Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- SZEMGTQCPRNXEG-UHFFFAOYSA-M trimethyl(octadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C SZEMGTQCPRNXEG-UHFFFAOYSA-M 0.000 description 3
- JPPRXACMNPYJNK-UHFFFAOYSA-N 1-docosoxydocosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCCCCCC JPPRXACMNPYJNK-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 2
- 241001553290 Euphorbia antisyphilitica Species 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 230000037308 hair color Effects 0.000 description 2
- 239000000118 hair dye Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000004200 microcrystalline wax Substances 0.000 description 2
- 235000019808 microcrystalline wax Nutrition 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 1
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 1
- KZVIUXKOLXVBPC-UHFFFAOYSA-N 16-methylheptadecanamide Chemical compound CC(C)CCCCCCCCCCCCCCC(N)=O KZVIUXKOLXVBPC-UHFFFAOYSA-N 0.000 description 1
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 1
- UOFCAQWHTQFNHS-UHFFFAOYSA-N 2-[2-[2-[2-[2-(2-hexadecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCCCCCOCCOCCOCCOCCOCCOCCO UOFCAQWHTQFNHS-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- FXQCFDGMELPXHM-UHFFFAOYSA-N 4-(3-ethyloctan-3-yloxy)-4-oxobutanoic acid Chemical compound CCCCCC(CC)(CC)OC(=O)CCC(O)=O FXQCFDGMELPXHM-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- BIVBRWYINDPWKA-VLQRKCJKSA-L Glycyrrhizinate dipotassium Chemical compound [K+].[K+].O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@H]1CC[C@]2(C)[C@H]3C(=O)C=C4[C@@H]5C[C@](C)(CC[C@@]5(CC[C@@]4(C)[C@]3(C)CC[C@H]2C1(C)C)C)C(O)=O)C([O-])=O)[C@@H]1O[C@H](C([O-])=O)[C@@H](O)[C@H](O)[C@H]1O BIVBRWYINDPWKA-VLQRKCJKSA-L 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 1
- 240000000912 Macadamia tetraphylla Species 0.000 description 1
- 235000003800 Macadamia tetraphylla Nutrition 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 241000047703 Nonion Species 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 1
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 1
- SHZIWNPUGXLXDT-UHFFFAOYSA-N caproic acid ethyl ester Natural products CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 229940082500 cetostearyl alcohol Drugs 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- ZCPCLAPUXMZUCD-UHFFFAOYSA-M dihexadecyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCC ZCPCLAPUXMZUCD-UHFFFAOYSA-M 0.000 description 1
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 229940101029 dipotassium glycyrrhizinate Drugs 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- QIVLQXGSQSFTIF-UHFFFAOYSA-M docosyl(trimethyl)azanium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C QIVLQXGSQSFTIF-UHFFFAOYSA-M 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- SFFVATKALSIZGN-UHFFFAOYSA-N hexadecan-7-ol Chemical compound CCCCCCCCCC(O)CCCCCC SFFVATKALSIZGN-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y5/00—Nanobiotechnology or nanomedicine, e.g. protein engineering or drug delivery
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
- A61K2800/262—Transparent; Translucent
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/413—Nanosized, i.e. having sizes below 100 nm
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5422—Polymers characterized by specific structures/properties characterized by the charge nonionic
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Engineering & Computer Science (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Nanotechnology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Biophysics (AREA)
- Biotechnology (AREA)
- General Engineering & Computer Science (AREA)
- Medical Informatics (AREA)
- Medicinal Chemistry (AREA)
- Molecular Biology (AREA)
- Pharmacology & Pharmacy (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
Description
本発明は、毛髪用処理剤の原料などとして用いられるキャンデリラロウ分散組成物に関するものである。 The present invention relates to a candelilla wax dispersion composition used as a raw material of a hair treatment agent and the like.
キャンデリラロウは、整髪剤などの毛髪用処理剤の原料として使用されている。整髪剤においては、整髪成分としてキャンデリラロウが配合され、キャンデリラロウを分散させる界面活性剤としてノニオン界面活性剤と共に高級脂肪酸系アニオン界面活性剤を使用することが汎用的である(例えば、特許文献1の段落0014参照)。整髪性を高めるためにキャンデリラロウの配合量を増加させるときには、高級脂肪酸系アニオン界面活性剤の使用頻度が高まる。また、特許文献2には、POE(20)ベヘニルエーテル単独よりも、POE(20)ベヘニルエーテル及びラウリルジメチルアミノ酢酸ベタインの併用が、キャンデリラロウを分散させる界面活性剤として優れるとされている(段落0017)。 Candelilla wax is used as a raw material for hair treatment agents such as hair styling agents. In hair styling compositions, it is general to use candelilla wax as a hair styling component, and use a higher fatty acid-based anionic surfactant together with a nonionic surfactant as a surfactant for dispersing the candelilla wax (for example, see Patent See paragraph 0014 of document 1). When the compounding amount of candelilla wax is increased in order to enhance hair styling properties, the use frequency of higher fatty acid-based anionic surfactant increases. Patent Document 2 states that the combined use of POE (20) behenyl ether and betaine lauryl dimethylaminoacetate is superior to POE (20) behenyl ether alone as a surfactant for dispersing candelilla wax. Paragraph 0017).
キャンデリラロウを分散させる際に適した界面活性剤の提案があるのは、上記の通りである。界面活性剤の種類は、キャンデリラロウを配合した組成物の用途に応じても選定されるから、特定の界面活性剤の配合を制限した上で、ノニオン界面活性剤を使用してキャンデリラロウを分散させる提案も、望まれる場合がある。 It is as described above that a surfactant suitable for dispersing candelilla wax is proposed. Since the type of surfactant is selected according to the use of the composition containing the candelilla wax, the formulation of the specific surfactant is limited, and then the candelilla wax is used using a nonionic surfactant. A proposal to disperse is also sometimes desirable.
本発明は、上記事情に鑑み、高級脂肪酸系アニオン界面活性剤を配合せず、アミドベタイン型両性界面活性剤を所定量以下にした上で、キャンデリラロウの分散性をノニオン界面活性剤を用いて高めた組成物の提供を目的とする。 In view of the above circumstances, the present invention does not include a higher fatty acid-based anionic surfactant, and uses a nonionic surfactant to reduce the dispersibility of candelilla wax after reducing the amidobetaine-type amphoteric surfactant to a predetermined amount or less. The purpose is to provide an enhanced composition.
本発明者等が鋭意検討を行った結果、所定のポリオキシエチレンセチルエーテル又はポリオキシエチレンポリオキシプロピレンセチルエーテルを使用すれば、キャンデリラロウの分散性が良い知見を得た。また、その分散性を高めるには、キャンデリラロウの配合量を調整して粘度を抑えるのが良い知見を得た。これらの知見に基づき、本発明を完成するに至った。 As a result of intensive studies by the present inventors, it has been found that the use of a predetermined polyoxyethylene cetyl ether or polyoxyethylene polyoxypropylene cetyl ether has good dispersibility of candelilla wax. Further, in order to enhance the dispersibility, it has been found that it is preferable to adjust the amount of candelilla wax to suppress the viscosity. Based on these findings, the present invention has been completed.
すなわち、本発明に係るキャンデリラロウ分散組成物は、キャンデリラロウ、ポリオキシエチレンセチルエーテル及びポリオキシエチレンポリオキシプロピレンセチルエーテルから選ばれた一種又は二種以上のセチルエーテル系ノニオン界面活性剤、並びに水が配合され、前記セチルエーテル系ノニオン界面活性剤のHLB値が11.0以上16.0以下であり、高級脂肪酸系アニオン界面活性剤が配合されず、アミドベタイン型両性界面活性剤が1.5質量%未満の配合量又は配合されず、粘度が20000mPa・sであることを特徴とする。 That is, the candelilla wax dispersion composition according to the present invention is a candelilla wax, one or two or more cetyl ether nonionic surfactants selected from polyoxyethylene cetyl ether and polyoxyethylene polyoxypropylene cetyl ether, Water is blended, the HLB value of the cetyl ether nonionic surfactant is 11.0 or more and 16.0 or less, no higher fatty acid anionic surfactant is blended, and 1 amide betaine type amphoteric surfactant is used. It is characterized by a blending amount of less than 0.5% by mass or not blended, and a viscosity of 20,000 mPa · s.
前記キャンデリラロウの配合量(A)に対する前記セチルエーテル系ノニオン界面活性剤の配合量(B)の比(B)/(A)は、0.2以上が良い。この比率であると、キャンデリラロウの分散性に特に好適である。 The ratio (B) / (A) of the blending amount (B) of the cetyl ether nonionic surfactant to the blending amount (A) of the candelilla wax is preferably 0.2 or more. This ratio is particularly suitable for the dispersibility of candelilla wax.
本発明に係るキャンデリラロウ分散組成物において、キャンデリラロウの体積平均粒子径は、500nm以下であると良い。その体積平均粒子径は、レーザー回折・散乱法による測定で求められる値である。 In the candelilla wax dispersion composition according to the present invention, the volume average particle diameter of the candelilla wax is preferably 500 nm or less. The volume average particle diameter is a value determined by measurement by a laser diffraction / scattering method.
本発明に係るキャンデリラロウ分散組成物は、透明又は半透明のものであると良い。ここで、「半透明」とは、直径4cmの有底円筒状ガラス容器内のキャンデリラロウ分散組成物を正面から目視確認したときに、背景を確認可能である透明性をいう。 The candelilla wax dispersion composition according to the present invention is preferably transparent or translucent. Here, “semi-transparent” refers to transparency in which the background can be confirmed when the candelilla wax dispersion composition in a bottomed cylindrical glass container having a diameter of 4 cm is visually confirmed from the front.
また、本発明に係るキャンデリラロウ分散組成物は、整髪剤などの毛髪用処理剤に配合する原料として用いると良い。キャンデリラロウの分散性が良い本発明に係る組成物を原料として用いることで、毛髪用処理剤におけるキャンデリラロウの分散性を良好にすることが容易となり、毛髪用処理剤に配合するキャンデリラロウの増量も容易となる。 Further, the candelilla wax dispersion composition according to the present invention is preferably used as a raw material to be blended with a hair treatment agent such as a hair styling agent. By using the composition according to the present invention having good dispersibility of candelilla wax as a raw material, it becomes easy to improve the dispersibility of candelilla wax in a hair treatment agent, and candelilla compounded in a hair treatment agent The amount of wax can be easily increased.
本発明に係るキャンデリラロウ分散組成物は、キャンデリラロウの配合量制限により粘度を抑え、所定のHLB値範囲のセチルエーテル系ノニオン界面活性剤によりキャンデリラロウを水中に分散させるので、高級脂肪酸系アニオン界面活性剤が配合されず、かつ、アミドベタイン型両性界面活性剤が1.5質量%未満の配合量であっても、キャンデリラロウの分散性が高いものとなる。 The candelilla wax dispersion composition according to the present invention suppresses the viscosity by limiting the amount of the candelilla wax, and disperses the candelilla wax in water with a cetyl ether nonionic surfactant having a predetermined HLB value range. Even when the anionic surfactant is not blended and the amidobetaine-type amphoteric surfactant is blended in an amount of less than 1.5% by mass, the dispersibility of the candelilla wax is high.
本発明の実施形態に係るキャンデリラロウ分散組成物(以下、「本実施形態に係るキャンデリラロウ分散組成物」を「本組成物」と称することがある。)に基づき、本発明を以下に説明する。本組成物は、キャンデリラロウ、所定のセチルエーテル系ノニオン界面活性剤、及び水が配合されたものである(水の配合量は、例えば50質量%以上)。 The present invention is described below based on the candelilla wax dispersion composition according to the embodiment of the present invention (hereinafter, the “candelilla wax dispersion composition according to the present embodiment” may be referred to as “the present composition”). explain. The present composition contains candelilla wax, a predetermined cetyl ether-based nonionic surfactant, and water (the amount of water is, for example, 50% by mass or more).
なお、本組成物は、キャンデリラロウを分散させるために好適であると知られている高級脂肪酸系アニオン界面活性剤(高級脂肪酸塩、並びに/又は、高級脂肪酸及びこれを中和する水酸化ナトリウム、2−アミノ−2−メチル−1−プロパノールなどのアルカリによるもの)を配合せずとも同ロウを分散させるものなので、高級脂肪酸系アニオン界面活性剤を配合しないものとする。 The present composition may be a higher fatty acid-based anionic surfactant known to be suitable for dispersing candelilla wax (higher fatty acid salt and / or higher fatty acid and sodium hydroxide for neutralizing the same). , 2-amino-2-methyl-1-propanol, etc.) are dispersed therein, so that no higher fatty acid-based anionic surfactant is blended.
(キャンデリラロウ)
本組成物には、キャンデリラロウを分散させる。キャンデリラロウの配合量は、配合するセチルエーテル系ノニオン界面活性剤の種類に応じて適宜設定すると良いが、3質量%以上30質量%以下が良く、5質量%以上25質量%以下が好ましく、10質量%以上20質量%以下がより好ましい。3質量%以上にすることで、本組成物の保管面積の拡張を防止でき、30質量%以下にすることで、キャンデリラロウの分散性及び本組成物のハンドリング性に不利な高粘度化を抑えることができる。
(Candelilla Row)
In this composition, candelilla wax is dispersed. The blending amount of the candelilla wax may be appropriately set according to the type of the cetyl ether nonionic surfactant to be blended, but is preferably 3% by mass or more and 30% by mass or less, and more preferably 5% by mass or more and 25% by mass or less. The content is more preferably from 10% by mass to 20% by mass. By setting the content to 3% by mass or more, the storage area of the present composition can be prevented from being expanded, and by setting the content to 30% by mass or less, a high viscosity that is disadvantageous to the dispersibility of the candelilla wax and the handleability of the present composition can be obtained. Can be suppressed.
本組成物におけるキャンデリラロウの体積平均粒子径は、500nm以下であると良く、300nm以下が好ましく、200nm以下がより好ましく、100nm以下が更に好ましく、50nm以下がより更に好ましい。この体積平均粒子径は、セチルエーテル系ノニオン界面活性剤の配合量を増やすことで500nm以下となり、当該粒子径範囲である共にキャンデリラロウの配合量を抑えることで、本組成物の外観を透明又は半透明にできる。なお、上記体積平均粒子径は、レーザー回折・散乱法により測定することで求められる。 The volume average particle diameter of the candelilla wax in the present composition is preferably 500 nm or less, preferably 300 nm or less, more preferably 200 nm or less, still more preferably 100 nm or less, and even more preferably 50 nm or less. The volume average particle diameter becomes 500 nm or less by increasing the blending amount of the cetyl ether nonionic surfactant, and by suppressing the blending amount of candelilla wax in the particle size range, the appearance of the present composition becomes transparent. Or it can be translucent. In addition, the said volume average particle diameter is calculated | required by measuring by a laser diffraction / scattering method.
(セチルエーテル系ノニオン界面活性剤)
本組成物には、キャンデリラロウを分散させるためにセチルエーテル系ノニオン界面活性剤が配合される。当該セチルエーテル系ノニオン界面活性剤は、ポリオキシエチレンセチルエーテル及びポリオキシエチレンポリオキシプロピレンセチルエーテルから選ばれた一種又は二種以上であり、所定のHLB値のものである(以下において、「ポリオキシエチレン」を「POE」と称することがあり、「ポリオキシエチレンポリオキシプロピレン」を「POE・POP」と称することがある)。
(Cetyl ether nonionic surfactant)
The composition is blended with a cetyl ether nonionic surfactant to disperse the candelilla wax. The cetyl ether nonionic surfactant is one or two or more selected from polyoxyethylene cetyl ether and polyoxyethylene polyoxypropylene cetyl ether, and has a predetermined HLB value (hereinafter, referred to as “Polyethylene”). “Oxyethylene” may be referred to as “POE”, and “polyoxyethylene polyoxypropylene” may be referred to as “POE.POP”).
本組成物に配合するPOEセチルエーテルとしては、例えば、POEセチルエーテル(6E.O.)、POEセチルエーテル(7E.O.)、POEセチルエーテル(10E.O.)、POEセチルエーテル(15E.O.)、POEセチルエーテル(20E.O.)が挙げられる(以下において、「E.O.」の前に記載した数値は、POEの平均付加モル数を表す。)。市販のPOEセチルエーテルとしては、日光ケミカル社製の「NIKKOL BC−5.5」、「NIKKOL BC−7」、「NIKKOL BC−10」、「NIKKOL BC−15」、「NIKKOL BC−20」などが挙げられる。 Examples of the POE cetyl ether blended in the composition include POE cetyl ether (6EO), POE cetyl ether (7EO), POE cetyl ether (10EO), and POE cetyl ether (15EO.). O.) and POE cetyl ether (20EO). (Hereinafter, the value described before "EO" indicates the average number of moles of POE added.) As commercially available POE cetyl ethers, "NIKKOL BC-5.5", "NIKKOL BC-7", "NIKKOL BC-10", "NIKKOL BC-15", "NIKKOL BC-20", etc., manufactured by Nikko Chemical Co., Ltd. Is mentioned.
本組成物に配合するPOE・POPセチルエーテルとしては、例えば、POE・POPセチルエーテル(10E.O.)(4P.O.)、POE・POPセチルエーテル(20E.O.)(4P.O.)、POE・POPセチルエーテル(20E.O.)(8P.O.)が挙げられる(以下において、「P.O.」の前に記載した数値は、POPの平均付加モル数を表す。)。市販のPOE・POPセチルエーテルとしては、日光ケミカル社製の「NIKKOL PBC−33」、「NIKKOL PBC−34」、「NIKKOL PBC−44」などが挙げられる。 Examples of the POE / POP cetyl ether blended in the composition include POE / POP cetyl ether (10EO) (4PO) and POE / POP cetyl ether (20EO) (4PO). ), And POE.POP cetyl ether (20EO) (8PO). (Hereinafter, the value described before “PO” indicates the average number of moles of POP added.) . Commercially available POE / POP cetyl ethers include "NIKKOL PBC-33", "NIKKOL PBC-34", and "NIKKOL PBC-44" manufactured by Nikko Chemical Co., Ltd.
本組成物に配合するセチルエーテル系ノニオン界面活性剤のHLB(Hydrophile―Lipophile Balance)値は、配合するセチルエーテル系ノニオン界面活性剤が一種である場合には、乳化試験により算出されるものである(算出方法の詳細は後記)。また、配合するセチルエーテル系ノニオン界面活性剤が二種以上である場合には、加重平均したHLB値をセチルエーテル系ノニオン界面活性剤のHLB値とする。 The HLB (Hydrophile-Lipophile Balance) value of the cetyl ether nonionic surfactant blended in the present composition is calculated by an emulsification test when one cetyl ether nonionic surfactant is blended. (Details of the calculation method will be described later). When two or more cetyl ether nonionic surfactants are used, the weighted average HLB value is defined as the HLB value of the cetyl ether nonionic surfactant.
上記の乳化試験によるHLB値の算出は、次の通り行う。すなわち、(1)a質量部のセチルエーテル系ノニオン界面活性剤と、b質量部のソルビタンモノステアリン酸エステル(日光ケミカル社製「NIKKOL
SS −10MV」、HLB値=4.7)を使用し、aとbを様々な比率とした下記組成、調製法で複数の乳化物を得る、(2)一日放置した後のこれら乳化物における油滴の粒径が最小となるaとbの比率に基づき、HLB値を「(10.5−4.7×b/4)4/a」により算出する。
乳化物の組成:
流動パラフィン(油相) 40質量%
乳化剤 a+b=4質量%
水 56質量%
乳化物の調製法:
流動パラフィンを80℃程度に加温して、攪拌しながら80℃以上の水相を加えて乳化する。その後、冷却しながら、攪拌を続けて40℃で放置する。
The calculation of the HLB value by the above emulsification test is performed as follows. That is, (1) a mass part of a cetyl ether-based nonionic surfactant and b mass parts of a sorbitan monostearate (“NIKKOL” manufactured by Nikko Chemical Co., Ltd.)
SS-10MV ", HLB value = 4.7) and obtain a plurality of emulsions by the following composition and preparation method with various ratios of a and b. (2) These emulsions after standing for one day The HLB value is calculated from “(10.5−4.7 × b / 4) 4 / a” based on the ratio of “a” and “b” at which the particle diameter of the oil droplet in FIG.
Emulsion composition:
Liquid paraffin (oil phase) 40% by mass
Emulsifier a + b = 4% by mass
56% by mass of water
Preparation of emulsion:
The liquid paraffin is heated to about 80 ° C., and an aqueous phase of 80 ° C. or higher is added thereto while stirring to emulsify. Thereafter, stirring is continued while cooling, and the mixture is left at 40 ° C.
本組成物におけるセチルエーテル系ノニオン界面活性剤の配合量は、キャンデリラロウに対する比率として設定すると良い。キャンデリラロウの配合量を(A)とし、セチルエーテル系ノニオン界面活性剤の配合量を(B)としたとき、比(B)/(A)は、0.2以上3.0以下が良く、0.4以上2.5以下が好ましく、0.6以上1.5以下がより好ましい。比(B)/(A)を0.2以上にすることで、キャンデリラロウの粒子径の小さな分散性及び低温放置した後の分散性に有利であり、3.0以下であっても、3.0を超える場合に比してキャンデリラロウの分散性が顕著に異ならない。 The amount of the cetyl ether-based nonionic surfactant in the present composition is preferably set as a ratio to the candelilla wax. When the compounding amount of the candelilla wax is (A) and the compounding amount of the cetyl ether nonionic surfactant is (B), the ratio (B) / (A) is preferably 0.2 or more and 3.0 or less. , 0.4 or more and 2.5 or less, more preferably 0.6 or more and 1.5 or less. By making the ratio (B) / (A) 0.2 or more, it is advantageous for the dispersibility of the small particle size of the candelilla wax and the dispersibility after being left at a low temperature, and even if it is 3.0 or less, The dispersibility of the candelilla wax is not significantly different from the case where it exceeds 3.0.
(その他配合原料)
キャンデリラロウ及びセチルエーテル系ノニオン界面活性剤以外の原料を、本組成物に配合しても良い。
(Other ingredients)
Raw materials other than the candelilla wax and the cetyl ether nonionic surfactant may be added to the composition.
エチレングリコール、プロピレングリコール、グリセリン、1,3−ブチレングリコールなどの多価アルコール、又はソルビトールなどの糖アルコールを本組成物に配合すれば、低温下に置かれた後のキャンデリラロウの分散性が向上する。本組成物における多価アルコール及び糖アルコールの配合量は、例えば1質量%以上6質量%以下である。 If a polyhydric alcohol such as ethylene glycol, propylene glycol, glycerin, or 1,3-butylene glycol, or a sugar alcohol such as sorbitol is added to the composition, the dispersibility of the candelilla wax after being placed at a low temperature is reduced. improves. The compounding amount of the polyhydric alcohol and the sugar alcohol in the present composition is, for example, 1% by mass or more and 6% by mass or less.
また、アミドベタイン型両性界面活性剤などの両性界面活性剤を配合しても良いが、配合量を1.5質量%未満又は未配合としても、キャンデリラロウの分散性を高くできる。 Further, an amphoteric surfactant such as an amidobetaine-type amphoteric surfactant may be blended, but the dispersibility of the candelilla wax can be increased even if the blending amount is less than 1.5% by mass or not blended.
(粘度)
本組成物の粘度は、キャンデリラロウの分散性及びハンドリング性の観点から、20000mPa・s以下が良く、10000mPa・s以下が好ましく、3000mPa・s以下がより好ましく、1000mPa・s以下が更により好ましい。ここで、本組成物の粘度は、B型粘度計において粘度に応じて選定したローターを使用して25℃で計測した60秒後の値を採用する。測定する際のローター回転速度は、12rpmであると良い。
(viscosity)
The viscosity of the composition is preferably 20,000 mPa · s or less, more preferably 10,000 mPa · s or less, more preferably 3,000 mPa · s or less, and still more preferably 1,000 mPa · s or less, from the viewpoints of the dispersibility and handling properties of the candelilla wax. . Here, as the viscosity of the present composition, a value after 60 seconds measured at 25 ° C. using a rotor selected according to the viscosity in a B-type viscometer is adopted. The rotor rotation speed at the time of measurement is preferably 12 rpm.
(用途)
本組成物を、毛髪用処理剤の原料などとして使用すると良い。この場合、毛髪用処理剤の原料として公知のものが、毛髪用処理剤の用途、目的に応じて適宜に選定される。
(Application)
This composition is preferably used as a raw material of a hair treatment agent. In this case, known materials for the hair treating agent are appropriately selected according to the use and purpose of the hair treating agent.
毛髪用処理剤は、特に限定されず、整髪剤、ヘアケア剤、パーマ剤、カラーリング剤、ブリーチ剤等である。「整髪剤」とは、髪型を一時的に保持するために用いられる毛髪用処理剤である。「ヘアケア剤」とは、毛髪の手入れ、手当て等を行うために用いられる毛髪用処理剤である。ヘアケア剤としては、例えばシャンプー、リンス、コンディショナー、トリートメント(例えば、洗い流さないトリートメント、洗い流すトリートメント、整髪兼用トリートメント、多剤式トリートメントの一構成剤、パーマの前処理のためのトリートメント、パーマの後処理のためのトリートメント、カラーリングの前処理のためのトリートメント、カラーリングの後処理のためのトリートメント、ブリーチの前処理のためのトリートメント、ブリーチの後処理のためのトリートメント)が挙げられる。「パーマ剤」とは、還元反応、酸化反応等の化学反応を利用して毛髪形状を変化させるために用いられる毛髪用処理剤である。パーマ剤としては、例えば毛髪をウェーブ状に形成するためのウェーブ剤、ウェーブ状等の毛髪を直毛に近づけるためのストレート剤が挙げられ、1剤式パーマ剤、2剤式パーマ剤の還元剤が配合された第1剤及び2剤式パーマ剤の酸化剤が配合された第2剤のいずれも毛髪用処理剤に該当する。「カラーリング剤」とは、毛髪を着色するために用いられる毛髪用処理剤である。カラーリング剤としては、例えば直接染料が配合された染毛料、毛髪の染毛時に反応が必要になる反応型染料が配合された染毛剤、毛髪への着色を一時的に施す毛髪着色料が挙げられる。「ブリーチ剤」とは、毛髪の色素を脱色させるために用いられる毛髪用処理剤である。 Hair treatment agents are not particularly limited, and include hair styling agents, hair care agents, perm agents, coloring agents, bleaching agents and the like. "Hairdressing agent" is a hair treatment agent used to temporarily hold a hairstyle. "Hair care agent" is a hair treatment agent used for care and treatment of hair. Hair care agents include, for example, shampoos, rinses, conditioners, treatments (eg, non-rinse treatments, rinse-out treatments, hair treatments, combined hair treatments, one component of multi-drug treatments, treatments for pre-treatment of perm, post-treatment of perm Treatment for coloring, pre-treatment for coloring, treatment for post-treatment of coloring, treatment for pre-treatment of bleach, treatment for post-treatment of bleach). The “perm agent” is a hair treatment agent used to change the shape of hair by using a chemical reaction such as a reduction reaction and an oxidation reaction. Examples of the perm agent include a waving agent for forming hair in a wavy shape, and a straightening agent for bringing wavy hair into straight hair, and include a one-agent type perm agent and a two-agent perm reducing agent. Both the first agent in which is incorporated and the second agent in which an oxidizing agent of a two-part perm is included correspond to a hair treatment agent. "Coloring agent" is a hair treatment agent used for coloring hair. Examples of the coloring agent include a hair dye containing a direct dye, a hair dye containing a reactive dye that requires a reaction during hair coloring, and a hair coloring agent for temporarily coloring hair. No. "Bleach agent" is a hair treatment agent used to decolorize hair pigments.
毛髪用処理剤の使用時の剤型は、特に限定されず、例えば液状、ローション状、クリーム状、ワックス状、ゲル状、フォーム状(泡状)、霧状が挙げられる。 The dosage form at the time of using the hair treatment agent is not particularly limited, and examples thereof include liquid, lotion, cream, wax, gel, foam (foam), and mist.
本組成物と共に毛髪用処理剤に配合する原料は、アニオン界面活性剤、カチオン界面活性剤、両性界面活性剤、ノニオン界面活性剤、高級アルコール、低級アルコール、多価アルコール、糖類、油脂、エステル油、脂肪酸、炭化水素、ロウ、シリコーン、合成高分子化合物、半合成高分子化合物、天然高分子化合物、蛋白、アミノ酸、動植物抽出物、微生物由来物、無機化合物、香料、防腐剤、金属イオン封鎖剤、紫外線吸収剤、色素、還元剤、酸化剤、染料、顔料などである。 Raw materials to be added to the hair treatment agent together with the composition include anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, higher alcohols, lower alcohols, polyhydric alcohols, saccharides, fats, and ester oils. , Fatty acids, hydrocarbons, waxes, silicones, synthetic high-molecular compounds, semi-synthetic high-molecular compounds, natural high-molecular compounds, proteins, amino acids, animal and plant extracts, microorganism-derived products, inorganic compounds, fragrances, preservatives, sequestering agents , An ultraviolet absorber, a dye, a reducing agent, an oxidizing agent, a dye, a pigment and the like.
本組成物を配合する毛髪処理剤の一例としては、高級アルコール及びカチオン界面活性剤を配合したものが挙げられる。また、本組成物を使用すれば、高級アルコール及びカチオン界面活性剤の配合量が少ない整髪剤などの毛髪用処理剤(高級脂肪酸系アニオン界面活性剤を配合しないもの)においても、キャンデリラロウの分散と増量が容易となる。 As an example of a hair treatment agent to which the present composition is added, a hair treatment agent to which a higher alcohol and a cationic surfactant are added may be mentioned. Further, if the present composition is used, even in a hair treatment agent such as a hair styling agent in which the amount of the higher alcohol and the cationic surfactant is small (one in which the higher fatty acid-based anionic surfactant is not added), the use of candelilla wax is also possible. Dispersion and weight increase are easy.
上記高級アルコールは、炭素数数16以上22以下のものを用いると良く、当該高級アルコールとしては、例えば、セチルアルコール、ステアリルアルコール、アラキルアルコール、ベヘニルアルコールなどの直鎖状飽和アルコール;オレイルアルコールなどの直鎖状不飽和アルコール;ヘキシルデカノール、オクチルドデカノール、イソセチルアルコール、イソステアリルアルコールなどの分岐状飽和アルコール;が挙げられる。毛髪用処理剤における高級アルコールの配合量は、例えば0.1質量%以上10質量%以下である。カチオン界面活性剤の配合量が少ない整髪剤などにおいては、カチオン界面活性剤に対する高級アルコールの配合量を多くし過ぎると剤の粘度が低下するので、高級アルコールの配合量は、5質量%以下が良く、1質量%以下が好ましい。 The higher alcohol is preferably one having 16 to 22 carbon atoms. Examples of the higher alcohol include linear saturated alcohols such as cetyl alcohol, stearyl alcohol, aralkyl alcohol, and behenyl alcohol; and oleyl alcohol. Linear unsaturated alcohols; branched saturated alcohols such as hexyldecanol, octyldodecanol, isocetyl alcohol, and isostearyl alcohol. The blending amount of the higher alcohol in the hair treatment agent is, for example, 0.1% by mass or more and 10% by mass or less. In a hair styling agent or the like having a small amount of the cationic surfactant, if the amount of the higher alcohol is too large relative to the cationic surfactant, the viscosity of the agent is reduced. Therefore, the amount of the higher alcohol is 5% by mass or less. It is preferably 1% by mass or less.
上記カチオン界面活性剤としては、例えば、ジステアリルジメチルアンモニウムクロリド、ジセチルジメチルアンモニウムクロリド、ジココイルジメチルアンモニウムクロリド等のジ長鎖アルキルジメチルアンモニウム塩;ベヘニルトリメチルアンモニウムクロリド、ベヘニルトリメチルアンモニウムメトサルフェート、ステアリルトリメチルアンモニウムクロリド、ステアリルトリメチルアンモニウムブロミド、セチルトリメチルアンモニウムブロミド等のモノ長鎖アルキルトリメチルアンモニウム塩;ステアロキシプロピルトリメチルアンモニウムクロリド等の長鎖アルコキシアルキルトリメチルアンモニウム塩;が挙げられる。ここでの「長鎖アルキル」とは、炭素数が8以上の直鎖状又は分枝状のアルキル基を意味し、その炭素数が16以上22以下であると皮膚への刺激の抑制や毛髪に付与する感触の観点から好ましい。毛髪用処理剤におけるカチオン界面活性剤の配合量は、例えば0.1質量%以上5質量%以下である。整髪剤などにおいてカチオン界面活性剤の配合量が多いと、頭皮に刺激を与える可能性があるので、カチオン界面活性剤の配合量は、3質量%以下が良く、1質量%以下が好ましい。 Examples of the above cationic surfactant include di-long chain alkyldimethyl ammonium salts such as distearyl dimethyl ammonium chloride, dicetyl dimethyl ammonium chloride, dicoyl dimethyl ammonium chloride; behenyl trimethyl ammonium chloride, behenyl trimethyl ammonium methosulfate, stearyl trimethyl Mono-long alkyltrimethylammonium salts such as ammonium chloride, stearyltrimethylammonium bromide and cetyltrimethylammonium bromide; and long-chain alkoxyalkyltrimethylammonium salts such as stearoxypropyltrimethylammonium chloride. As used herein, the term “long-chain alkyl” refers to a linear or branched alkyl group having 8 or more carbon atoms. When the number of carbon atoms is 16 or more and 22 or less, suppression of skin irritation and hair It is preferable from the viewpoint of the feel given to the toner. The amount of the cationic surfactant in the hair treatment agent is, for example, 0.1% by mass or more and 5% by mass or less. A large amount of the cationic surfactant in a hairdressing agent or the like may cause irritation to the scalp. Therefore, the amount of the cationic surfactant is preferably 3% by mass or less, more preferably 1% by mass or less.
以下、実施例に基づき本発明を詳述するが、この実施例の記載に基づいて本発明が限定的に解釈されるものではない。 Hereinafter, the present invention will be described in detail with reference to examples. However, the present invention is not to be construed as being limited based on the description of the examples.
実施例、比較例、及び参考例のキャンデリラロウなどの分散組成物を製造し、粘度、平均粒子径(一部の組成物の粘度及び平均粒子径については、測定しなかった。)、外観を確認した。平均粒子径については、組成物における体積平均粒子径を、日機装社製の測定装置「Microtrac MT3000」を用いて、レーザー回折・散乱法により測定することで求めた。 Dispersion compositions such as candelilla wax of Examples, Comparative Examples, and Reference Examples were produced, and the viscosity, average particle size (the viscosity and average particle size of some compositions were not measured), and appearance. It was confirmed. The average particle diameter was determined by measuring the volume average particle diameter of the composition by a laser diffraction / scattering method using a measuring device “Microtrac MT3000” manufactured by Nikkiso Co., Ltd.
(キャンデリラロウ分散組成物)
キャンデリラロウ分散組成物の詳細は、次の通りである。
キャンデリラロウ、マイクロクリスタリンワックス、ポリオキシエチレンセチルエーテル(6E.O.)、ポリオキシエチレンセチルエーテル(10E.O.)、ポリオキシエチレンセチルエーテル(15E.O.)、ポリオキシエチレンセチルエーテル(20E.O.)、ポリオキシエチレンラウリルエーテル(9E.O.)、ポリオキシエチレンラウリルエーテル(4E.O.)、ポリオキシエチレンベヘニルエーテル(10E.O.)、ポリオキシエチレンベヘニルエーテル(20E.O.)、ポリオキシエチレン硬化ヒマシ油(50E.O.)、ポリオキシエチレンポリオキシプロピレンセチルエーテル(20E.O.)(4P.O.)、ポリオキシエチレンポリオキシプロピレンセチルエーテル(20E.O.)(8P.O.)、プロピレングリコール、1,3−ブチレングリコール、グリセリン、及びソルビトールから選択した原料を使用した(原料の配合濃度は、下記表1〜4の通り。)。そして、原料を混合した80℃程度の油相に、当該油相を撹拌しながら、80℃程度の水を徐々に混合した。その後、自然冷却したものを実施例、比較例、及び参考例のキャンデリラロウなどの分散組成物として得た。
(Candelilla wax dispersion composition)
The details of the candelilla wax dispersion composition are as follows.
Candelilla wax, microcrystalline wax, polyoxyethylene cetyl ether (6EO), polyoxyethylene cetyl ether (10EO), polyoxyethylene cetyl ether (15EO), polyoxyethylene cetyl ether ( 20EO), polyoxyethylene lauryl ether (9EO), polyoxyethylene lauryl ether (4EO), polyoxyethylene behenyl ether (10EO), polyoxyethylene behenyl ether (20EO). O.), polyoxyethylene hydrogenated castor oil (50 EO), polyoxyethylene polyoxypropylene cetyl ether (20 EO) (4 PO), polyoxyethylene polyoxypropylene cetyl ether (20 EO) .) (8PO), B propylene glycol, 1,3-butylene glycol was used glycerol, and the selected material from the sorbitol (formulation concentration of raw materials, as shown in Table 1-4.). Then, water of about 80 ° C. was gradually mixed with the oil phase of about 80 ° C. into which the raw materials were mixed while stirring the oil phase. Thereafter, those naturally cooled were obtained as dispersion compositions such as candelilla waxes of Examples, Comparative Examples, and Reference Examples.
下表1〜4に、組成物の調製に使用した原料及び配合濃度と共に、粘度、平均粒子径、外観の結果を示す。ここで、粘度の結果における「100以下」とは、測定可能な粘度下限以下であることを意味し、平均粒子径の結果における「50以下」とは、測定装置で表示される体積平均粒子径の下限値以下であることを意味する。また、外観の結果は目視確認した結果であり、「×」は析出又は分離が認められ、キャンデリラロウが十分に分散していなかったことを表す。 Tables 1 to 4 below show the results of viscosity, average particle size, and appearance, together with the raw materials and compounding concentrations used in preparing the compositions. Here, “100 or less” in the result of the viscosity means that the viscosity is equal to or less than the lower limit of the measurable viscosity, and “50 or less” in the result of the average particle diameter means that the volume average particle diameter displayed by the measuring device is Means lower than the lower limit. In addition, the results of the appearance were visually confirmed, and "x" indicates that precipitation or separation was observed, and that the candelilla wax was not sufficiently dispersed.
表1
Table 1
上記表1においては、(1)実施例1a〜1dと比較例1a〜1bの対比により、HLB値が11.0以上16.0以下であれば、キャンデリラロウの分散性が良い傾向があること、(2)実施例1dと比較例1cの粘度及び平均粒子径の対比により、粘度が20000mPa・s以上になるほどにキャンデリラロウの配合量を増やした比較例1cは、平均粒子径が大きく、キャンデリラロウの分散性が良くないこと、(3)HLB値が11.0以上16.0以下である実施例1a〜1dと比較例1d〜1fの外観等の対比により、セチルエーテル系ノニオン界面活性剤の配合が、キャンデリラロウの分散性が良い傾向があること、を確認できる。 In the above Table 1, (1) the dispersibility of candelilla wax tends to be good if the HLB value is 11.0 or more and 16.0 or less by comparison between Examples 1a to 1d and Comparative Examples 1a to 1b. (2) By comparison of the viscosity and the average particle diameter of Example 1d and Comparative Example 1c, Comparative Example 1c in which the blending amount of candelilla wax was increased so that the viscosity became 20000 mPa · s or more, the average particle diameter was large. The dispersibility of the candelilla wax is not good, and (3) the cetyl ether-based nonion is determined by comparing the appearance and the like of Examples 1a to 1d having an HLB value of 11.0 to 16.0 and Comparative Examples 1d to 1f. It can be confirmed that the compounding of the surfactant tends to improve the dispersibility of the candelilla wax.
上記表2においては、HLB値が11.0以上16.0以下のセチルエーテル系ノニオン界面活性剤を使用した実施例2a〜2cでは、キャンデリラロウの分散性が実施例1a等と同様であったことを確認できる。 In Table 2 above, in Examples 2a to 2c using a cetyl ether nonionic surfactant having an HLB value of 11.0 or more and 16.0 or less, the dispersibility of candelilla wax was similar to that of Example 1a. You can confirm that.
上記表3において、(B)/(A)を0.2以上にすると、粘度低下、平均粒子径の微細化、乳化状態の透明化傾向を確認できるから、キャンデリラロウの分散性が向上することが分かる。なお、実施例3dに防腐剤を適量添加したものを整髪剤として用いたところ、整髪力が良く、整髪後の髪型を長時間維持できたことが確認されている。 In Table 3, when (B) / (A) is 0.2 or more, a decrease in viscosity, a reduction in the average particle diameter, and a tendency of transparency of the emulsified state can be confirmed, so that the dispersibility of candelilla wax is improved. You can see that. In addition, it was confirmed that a hair styling agent obtained by adding an appropriate amount of preservative to Example 3d had good hair styling ability and that the hairstyle after hair styling could be maintained for a long time.
下記原料、配合量のクリーム状O/W型乳化物を整髪剤として3種類製造した。この製造においては、キャンデリラロウ分散組成物を最後に配合した。製造した整髪剤は、キャンデリラロウを2〜4質量%含むものであるが、キャンデリラロウの分散性が安定していた。
セトステアリルアルコール 3質量%
4級アンモニウム塩 1.5質量%
イソプロピルアルコール 0.2質量%
1,3−ブチレングリコール 0.1質量%
固形エステル油 2質量%
グリセリン 5質量%
デカメチルシクロペンタシロキサン 10質量%
キャンデリラロウ分散組成物 20質量%、30質量%、又は40質量%
(キャンデリラロウ分散組成物:実施例3aと同じ)
Three types of creamy O / W emulsions having the following raw materials and compounding amounts were produced as hair styling agents. In this production, the candelilla wax dispersion composition was compounded last. Although the manufactured hair styling agent contained 2 to 4% by mass of candelilla wax, the dispersibility of candelilla wax was stable.
3% by weight of cetostearyl alcohol
Quaternary ammonium salt 1.5% by mass
0.2 mass% of isopropyl alcohol
1,3-butylene glycol 0.1% by mass
2% by mass of solid ester oil
Glycerin 5% by mass
Decamethylcyclopentasiloxane 10% by mass
Candelilla wax dispersion composition 20% by mass, 30% by mass, or 40% by mass
(Candelilla wax dispersion composition: same as in Example 3a)
上記キャンデリラロウ分散組成物を配合する毛髪用処理剤の例として、シャンプー、洗い流すトリートメント、フォーム状整髪剤、整髪用ヘアワックス、整髪用ヘアミルクを以下に示す。 As examples of the hair treating agent to which the above-mentioned candelilla wax dispersion composition is blended, shampoo, wash-out treatment, foam-like hair styling agent, hair styling hair wax, and hair styling hair milk are shown below.
シャンプーの配合組成例は、以下の通りである。
1.N−ヤシ油脂肪酸アシル−L−グルタミン酸ナトリウム 6質量%
2.ポリオキシエチレンラウリルエーテル酢酸ナトリウム 4質量%
3.ポリオキシエチレンラウリルエーテル硫酸ナトリウム 3質量%
4.イソステアラミドプロピルベタイン 3質量%
5.ヤシ油脂肪酸アミドプロピルベタイン液 2質量%
6.ヤシ油脂肪酸N−メチルエタノールアミド 1質量%
7.塩化O−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]ヒドロキシエチルセルロース 0.5質量%
8.キャンデリラロウ分散組成物 0.5質量%
9.グリチルリチン酸ジカリウム 0.01質量%
10.クエン酸 適量
11.クエン酸ナトリウム 適量
12.防腐剤 適量
13.香料 適量
14.水 全量が100質量%となる量
An example of the composition of the shampoo is as follows.
1. N-coconut oil fatty acid acyl-sodium L-glutamate 6% by mass
2. Sodium polyoxyethylene lauryl ether acetate 4% by mass
3. Sodium polyoxyethylene lauryl ether sulfate 3% by mass
4. 3% by mass of isostearamide propyl betaine
5. Palm oil fatty acid amidopropyl betaine solution 2% by mass
6. Coconut oil fatty acid N-methylethanolamide 1% by mass
7. O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose 0.5% by mass
8. Candelilla wax dispersion composition 0.5% by mass
9. Dipotassium glycyrrhizinate 0.01% by mass
10. Citric acid qs. Sodium citrate qs 12. Preservative appropriate amount 13. Perfume appropriate amount 14. Amount of water to be 100% by mass
上記シャンプーを製造するには、上記1〜6及び13の一部を80℃まで加熱して溶解させたものと、14の一部及び7を80℃に加熱して溶解させたものとを混合し、30℃まで冷却した後に、8〜12を添加すると良い。 In order to manufacture the shampoo, a part of the above 1 to 6 and 13 was dissolved by heating to 80 ° C, and a part of 14 and 7 were dissolved by heating to 80 ° C. Then, after cooling to 30 ° C., 8 to 12 may be added.
洗い流すトリートメントの配合組成例は、以下の通りである。
1.臭化ステアリルトリメチルアンモニウム 2質量%
2.塩化ステアリルトリメチルアンモニウム 1質量%
3.セタノール 3質量%
4.ステアリルアルコール 2質量%
5.マカデミアナッツ油 3質量%
6.流動パラフィン 2質量%
7.アミノエチルアミノプロピルメチルシロキサン・ジメチルシロキサン共重合体 1質量%
8.ジメチルポリシロキサン 1質量%
9.キャンデリラロウ分散組成物 5質量%
10.フェノキシエタノール 0.3質量%
11.乳酸 適量
12.香料 適量
13.水 全量が100質量%となる量
An example of the composition of the treatment to be washed away is as follows.
1. Stearyl trimethyl ammonium bromide 2% by mass
2. Stearyl trimethyl ammonium chloride 1% by mass
3. Cetanol 3% by mass
4. Stearyl alcohol 2% by mass
5. Macadamia nut oil 3% by mass
6. Liquid paraffin 2% by mass
7. Aminoethylaminopropylmethylsiloxane / dimethylsiloxane copolymer 1% by mass
8. 1% by mass of dimethylpolysiloxane
9. Candelilla wax dispersion composition 5% by mass
10. Phenoxyethanol 0.3% by mass
11. Lactic acid appropriate amount12. Suitable amount of fragrance 13. Amount of water to be 100% by mass
上記洗い流すトリートメントーを製造するには、上記1〜6を80℃まで加熱して溶解させたものを、80℃まで加熱した13に混合して乳化させ、30℃まで冷却した後に、7〜12を添加すると良い。 In order to manufacture the treatment to be washed away, the above-mentioned 1 to 6 dissolved by heating to 80 ° C. are mixed and emulsified in 13 heated to 80 ° C., cooled to 30 ° C., and then cooled to 7 to 12 ° C. Should be added.
フォーム状整髪剤の原液の配合組成例は、以下の通りである。
1.ミリスチン酸 3質量%
2.ミツロウ 2質量%
3.PEG−40(平均分子量200) 1.2質量%
4.プロピレングリコール 1質量%
5.ポリオキシエチレン硬化ヒマシ油(80E.O) 1質量%
6.ポリオキシエチレンセチルエーテル(15E.O) 1質量%
7.ミリスチルアルコール 1質量%
8.エチルヘキサン酸アルキル(C14−18) 1質量%
9.2−アミノ−2−メチル−1−プロパノール 0.8質量%
10.キャンデリラロウ分散組成物 5質量%
11.防腐剤 適量
12.香料 適量
13.水 全量が100質量%となる量
Examples of the composition of the stock solution of the foam-shaped hair styling agent are as follows.
1. Myristic acid 3% by mass
2. Beeswax 2% by mass
3. PEG-40 (average molecular weight 200) 1.2 mass%
4. 1% by mass of propylene glycol
5. Polyoxyethylene hydrogenated castor oil (80EO) 1% by mass
6. 1% by mass of polyoxyethylene cetyl ether (15EO)
7. Myristyl alcohol 1% by mass
8. Alkyl ethyl hexanoate (C14-18) 1% by mass
9.2-amino-2-methyl-1-propanol 0.8% by mass
10. Candelilla wax dispersion composition 5% by mass
11. Preservatives proper amount 12. Fragrance proper amount 13. Water Amount that the total amount becomes 100% by mass
上記フォーム状整髪剤の原液を製造するには、上記1〜8を80℃まで加熱して溶解させたものを、80℃まで加熱して混合した9及び13に添加して乳化させ、35℃まで冷却した後に、10〜12を添加すると良い。フォーム状整髪剤は、原液:噴射剤(LPG)の質量比を90:10として容器に充填して製造すると良く、この場合の25℃における容器からの噴射圧は、例えば0.3MPa程度であると良い。 In order to manufacture the stock solution of the foam hair styling agent, the above-mentioned 1 to 8 dissolved by heating to 80 ° C. was added to 9 and 13 mixed by heating to 80 ° C. and emulsified at 35 ° C. After cooling to 10 to 12, it is advisable to add 10 to 12. The foam-shaped hairdressing agent is preferably prepared by filling a container with a mass ratio of undiluted solution: propellant (LPG) of 90:10. In this case, the injection pressure from the container at 25 ° C. is, for example, about 0.3 MPa. And good.
整髪用ヘアワックスの配合組成例は、以下の通りである。
1.ステアリン酸 4質量%
2.ヒドロキシステアリン酸 1質量%
3.ミツロウ 2質量%
4.マイクロクリスタリンワックス 2質量%
5.流動パラフィン 8質量%
6.コハク酸ジ2−エチルヘキシル 2質量%
7.ポリオキシエチレンセチルエーテル(5.5E.O) 1質量%
8.ポリオキシエチレンセチルエーテル(10E.O) 4質量%
9.1.3−ブチレングリコール 3質量%
10.アクリル樹脂アルカノールアミン液 2質量%
11.カルボキシビニルポリマー 0.1質量%
12.キャンデリラロウ分散組成物 5質量%
13.水酸化ナトリウム 0.35質量%
14.防腐剤 適量
15.香料 適量
16.水 合計100質量%となる量
Examples of the composition of the hair wax for hair styling are as follows.
1. Stearic acid 4% by mass
2. 1% by mass of hydroxystearic acid
3. Beeswax 2% by mass
4. 2% by mass of microcrystalline wax
5. Liquid paraffin 8% by mass
6. Di-ethylhexyl succinate 2% by mass
7. 1% by mass of polyoxyethylene cetyl ether (5.5EO)
8. Polyoxyethylene cetyl ether (10EO) 4% by mass
9.1.3 3-butylene glycol 3% by mass
10. Acrylic resin alkanolamine liquid 2% by mass
11. Carboxyvinyl polymer 0.1% by mass
12. Candelilla wax dispersion composition 5% by mass
13. Sodium hydroxide 0.35% by mass
14. Preservative appropriate amount 15. Fragrance appropriate amount 16. Water Amount that totals 100% by mass
上記整髪用ヘアワックスを製造するには、上記1〜8を80℃まで加熱して溶解させる。これとは別に、10及び11を16に添加してから80℃まで加熱し、13を加える。この13を加えたものに、上記1〜8を溶解させたものを添加して乳化させ、35℃まで冷却した後に、12、14及び15を添加すると良い。 In order to manufacture the hair wax for hair styling, the above 1 to 8 are dissolved by heating to 80 ° C. Separately, add 10 and 11 to 16, then heat to 80 ° C and add 13. It is advisable to add a solution obtained by dissolving the above 1 to 8 to the solution obtained by adding 13 to emulsify the solution, cool the solution to 35 ° C., and then add 12, 14, and 15 to the solution.
整髪用ヘアミルクの配合組成例は、以下の通りである。
1.デカメチルシクロペンタシロキサン 5質量%
2.ミツロウ 1質量%
3.ステアリルアルコール 1.5質量%
4.セタノール 1質量%
5.ジメチルポリシロキサン 1質量%
6.臭化ステアリルトリメチルアンモニウム 1質量%
7.キャンデリラロウ分散組成物 5質量%
8.防腐剤 適量
9.香料 適量
10.水 合計100質量%となる量
Examples of the composition of the hair styling hair milk are as follows.
1. 5% by mass of decamethylcyclopentasiloxane
2. Beeswax 1 mass%
3. Stearyl alcohol 1.5% by mass
4. 1% by mass of cetanol
5. 1% by mass of dimethylpolysiloxane
6. Stearyl trimethyl ammonium bromide 1% by mass
7. Candelilla wax dispersion composition 5% by mass
8. Preservative proper amount 9. Perfume proper amount 10. Water Amount that totals 100% by mass
上記整髪用ヘアミルクを製造するには、上記1〜6を80℃まで加熱して溶解させたものを、80℃まで加熱した10に混合して乳化させ、35℃まで冷却した後に、7〜9を添加すると良い。
In order to manufacture the above hair milk for hair styling, the above 1 to 6 dissolved by heating to 80 ° C. are mixed with 10 heated to 80 ° C. to emulsify, and after cooling to 35 ° C., 7 to 9 Should be added.
Claims (6)
前記セチルエーテル系ノニオン界面活性剤のHLB値が11.0以上16.0以下であり、
前記セチルエーテル系ノニオン界面活性剤としてポリオキシエチレンセチルエーテルが配合され、
高級脂肪酸系アニオン界面活性剤が配合されず、
アミドベタイン型両性界面活性剤が配合されず、
粘度が20000mPa・s以下であることを特徴とする
キャンデリラロウ分散組成物。 Candelilla wax, one or two or more cetyl ether nonionic surfactants selected from polyoxyethylene cetyl ether and polyoxyethylene polyoxypropylene cetyl ether, and water,
The HLB value of the cetyl ether nonionic surfactant is 11.0 or more and 16.0 or less,
Polyoxyethylene cetyl ether is blended as the cetyl ether nonionic surfactant,
Higher fatty acid based anionic surfactant is not blended,
Amidobetaine-type amphoteric surfactant is not blended,
A candelilla wax dispersion composition having a viscosity of 20,000 mPa · s or less.
A method for producing a hair treating agent comprising the candelilla wax dispersion composition according to any one of claims 1 to 5.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014008538A JP6634199B2 (en) | 2013-02-12 | 2014-01-21 | Method for producing candelilla wax dispersion composition and hair treating agent |
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013024183 | 2013-02-12 | ||
JP2013024183 | 2013-02-12 | ||
JP2013034319 | 2013-02-25 | ||
JP2013034319 | 2013-02-25 | ||
JP2014008538A JP6634199B2 (en) | 2013-02-12 | 2014-01-21 | Method for producing candelilla wax dispersion composition and hair treating agent |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2018186936A Division JP6739493B2 (en) | 2013-02-12 | 2018-10-01 | Candelilla wax dispersion composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2014185142A JP2014185142A (en) | 2014-10-02 |
JP6634199B2 true JP6634199B2 (en) | 2020-01-22 |
Family
ID=51746942
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014008538A Active JP6634199B2 (en) | 2013-02-12 | 2014-01-21 | Method for producing candelilla wax dispersion composition and hair treating agent |
JP2018186936A Active JP6739493B2 (en) | 2013-02-12 | 2018-10-01 | Candelilla wax dispersion composition |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2018186936A Active JP6739493B2 (en) | 2013-02-12 | 2018-10-01 | Candelilla wax dispersion composition |
Country Status (2)
Country | Link |
---|---|
JP (2) | JP6634199B2 (en) |
KR (1) | KR20140101660A (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6230805B2 (en) * | 2013-04-10 | 2017-11-15 | 株式会社 資生堂 | Hair cosmetics |
JP6798828B2 (en) * | 2016-09-01 | 2020-12-09 | 株式会社アリミノ | Foam hair cosmetic concentrate and foam hair cosmetic |
MX2019005581A (en) * | 2017-04-13 | 2019-07-08 | Procter & Gamble | Method of preparing a product composition comprising a discrete particle and an aqueous base composition. |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001072551A (en) * | 1999-09-01 | 2001-03-21 | Shiseido Co Ltd | Hair cosmetic |
JP2002003344A (en) * | 2001-03-12 | 2002-01-09 | Sanei Kagaku Kk | Composition to be formulated with hair-treating agent, and hair-treating agent |
JP2007015935A (en) * | 2005-07-05 | 2007-01-25 | Kanebo Home Products Kk | Hair dressing agent |
JP5132248B2 (en) * | 2007-10-23 | 2013-01-30 | 株式会社 資生堂 | Perfume-containing wax solubilized composition |
JP2010202621A (en) * | 2009-03-06 | 2010-09-16 | Kracie Home Products Ltd | Hairdo agent |
JP4646269B2 (en) * | 2009-03-31 | 2011-03-09 | 株式会社資生堂 | Skin preparation |
JP5550259B2 (en) * | 2009-05-20 | 2014-07-16 | 株式会社ミルボン | Cosmetic composition for hair |
JP5517567B2 (en) * | 2009-11-06 | 2014-06-11 | 株式会社ミルボン | Hairdressing composition |
JP5700926B2 (en) * | 2009-11-09 | 2015-04-15 | 株式会社ミルボン | Hairdressing composition |
-
2013
- 2013-12-18 KR KR1020130158290A patent/KR20140101660A/en not_active Application Discontinuation
-
2014
- 2014-01-21 JP JP2014008538A patent/JP6634199B2/en active Active
-
2018
- 2018-10-01 JP JP2018186936A patent/JP6739493B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
JP2014185142A (en) | 2014-10-02 |
KR20140101660A (en) | 2014-08-20 |
JP2019023211A (en) | 2019-02-14 |
JP6739493B2 (en) | 2020-08-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5439185B2 (en) | Conditioning shampoo composition | |
JP5047369B2 (en) | Method for producing O / W fine emulsion external preparation | |
KR20110119774A (en) | Oily hair cosmetic | |
JP2010509261A (en) | Conditioning shampoo composition | |
JP2019510803A (en) | Personal care compositions and methods of using the compositions | |
JPH10513179A (en) | Roll-on antiperspirant composition | |
JP6739493B2 (en) | Candelilla wax dispersion composition | |
JP2017066068A (en) | Fine emulsion-type cosmetic and method for producing the same | |
JP2001213737A (en) | Composition for compounding hair treatment agent, and hair treatment agent | |
KR102395902B1 (en) | Transparent cosmetic composition | |
JP2002003344A (en) | Composition to be formulated with hair-treating agent, and hair-treating agent | |
JP2011251953A (en) | Hairdressing composition | |
JPWO2018061854A1 (en) | Cosmetic composition | |
JP5189836B2 (en) | Oil-containing cosmetic composition | |
JP2019517456A (en) | Antibacterial personal cleaning composition | |
TW201408327A (en) | Hair cosmetic composition | |
KR20140141431A (en) | Hair treating agent | |
JP6591960B2 (en) | Alkoxylated fatty alcohol alkyl ethers and products containing the same | |
JP6640556B2 (en) | Oil-in-water liquid bath agent and method for producing the same | |
JP2016185916A (en) | Emulsion composition for ceramide-containing cosmetic, method for producing the same, and cosmetic in which emulsion composition for cosmetic is blended | |
JP7158872B2 (en) | hair cosmetics | |
JP5832930B2 (en) | Composition for external use | |
JP6279218B2 (en) | Hairdresser | |
JP4456778B2 (en) | Gel composition and external preparation for skin comprising the same | |
Iwata et al. | Raw materials of cosmetics |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20161212 |
|
RD03 | Notification of appointment of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7423 Effective date: 20161213 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20171019 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20171114 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180112 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20180115 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20180703 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20181001 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20181009 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20181002 |
|
A912 | Re-examination (zenchi) completed and case transferred to appeal board |
Free format text: JAPANESE INTERMEDIATE CODE: A912 Effective date: 20181228 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20190729 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20191216 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6634199 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |