JP2002003344A - Composition to be formulated with hair-treating agent, and hair-treating agent - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a composition to be formulated with a hair-treating agent, capable of allowing the hair-treating agent such as a hair conditioner, a hairdye, a waving agent and a finishing agent to be prepared easily and inexpensively, and further to obtain the hair-treating agent excellent in greasy feeling of the hair, soft feeling, moist feeling, good combing properties, powdery feeling, setting properties of the hair, slip of a cream, nondrip properties of liquid, or the like. SOLUTION: This composition to be formulated with the hair-treating agent is characterized in that the composition contains (A) esters, (B) alcohols, (C) a nonionic surfactant and (D) fatty acids. Especially, the components A, B, C and D is regulated so as to satisfy the formulas 3<=A<=45, 5<=B<=80, 3<=C<=25, 1<=D<=15 and A+B+C+D<=100.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

TECHNICAL FIELD The present invention relates to a composition for blending a hair treatment agent and a hair treatment agent. In particular, the present invention relates to a composition for blending a hair treatment agent for preparing a hair treatment agent, and a hair treatment agent obtained therefrom, such as a hair conditioner such as a rinse, a hair dye, a waving agent, and a finishing agent. About.

[0002]

2. Description of the Related Art In recent years, there has been an increasing demand for aesthetics for hair and a demand for a hair treatment agent, and the hair has a slimy feeling, a soft feeling, a crisp feeling, a good combability, a smooth feeling, a hair setting property, an extension of cream, There is a strong demand for no dripping and the like.

[0003] Conventionally, hair conditioners containing various compounding components to satisfy such demands of consumers,
Hair treatment agents such as hair dyes, waving agents and finishing agents have been proposed.

[0004] However, in the conventional preparation of a hair treatment agent, since each compounding component is weighed, added and mixed one by one, there is a problem that the process is very complicated and it takes time and cost. there were.

[0005] Further, in conventional hair treatment agents, specific components such as specific fatty acid esters, surfactants, silicones, and the like are added to the hair treatment agent in order to exhibit various hair treatment effects. .

[0006] However, these compounds are often uncommon because they have a special structure. For this reason, there are problems that it is difficult to obtain and expensive. There is also a problem that the hair treatment effect is not sufficient.

[0007]

DISCLOSURE OF THE INVENTION The present invention relates to a composition for compounding a hair treatment agent, which can easily and inexpensively prepare a hair treatment agent such as a hair conditioner, a hair dye, a waving agent, a finishing agent, and a slimy feeling of hair. It is an object of the present invention to provide the above-mentioned hair treating agent which is excellent in softness, softness, good combability, smoothness, hair setting property, spread of cream, no dripping and the like.

[0008]

Means for Solving the Problems In order to solve the above-mentioned problems, the present inventors have conducted intensive studies and found that a composition containing both esters, alcohols, nonionic surfactants and fatty acids was used. For example, they have found that a hair treatment agent having an excellent hair treatment effect can be easily and inexpensively prepared, and have completed the present invention.

That is, the present invention provides a composition for blending a hair treatment agent, which contains an ester, an alcohol, a nonionic surfactant, and a fatty acid.

According to the present invention, the esters are preferably mono- or diglyceride stearate oleate, lipophilic glyceryl monostearate, glycerin oleate, isononyl isononanoate, isopropyl myristate, isopropyl palmitate, stearyl stearate, and diisobutyl adipate. Wherein the alcohols are myristyl alcohol, hexyldecanol, cetanol, behenyl alcohol, aralkyl alcohol, 1,3-butylene glycol, dipropylene glycol, and cetostearyl alcohol. One to three compounds selected from
The group consisting of polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene hydrogenated castor oil, coconut oil fatty acid monoethanolamide, sorbitan monostearate, polyoxyethylene stearamide, and dimethylstearylamine The above hair treatment agent, wherein the hair treatment agent is one or two compounds selected from the group consisting of lauric acid, myristic acid, stearic acid, oleic acid, and lanolin fatty acid. A compounding composition is provided.

[0011] The present invention provides any of the above-mentioned compositions for blending hair treatment agents, wherein the esters are mono-diglyceride oleate and / or isopropyl myristate.

[0012] The present invention provides the composition for blending a hair treatment agent according to any one of the above, wherein the alcohol is cetanol, behenyl alcohol, or cetostearyl alcohol.

According to the present invention, there is provided one or two compounds wherein the nonionic surfactant is selected from the group consisting of polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, coconut fatty acid monoethanolamide, and polyoxyethylene stearamide. A composition for blending any of the above hair treatment agents is provided.

The present invention provides any of the above-mentioned compositions for blending hair treatment agents, wherein the fatty acid is stearic acid.

According to the present invention, the composition for blending a hair treatment agent further comprises sodium tetradecenesulfonate, sodium palmitoylmethyltaurine, sulfated castor oil, N-coconut fatty acid acyl-L-glutamate triethanolamine, mink wax, Any of the above hair treatment agents containing one to seven compounds selected from the group consisting of shea butter, paraffin, liquid paraffin, rice bran wax, candelilla wax, methyl polysiloxane, polypropylene glycol oligosuccinate succinate, and water. A compounding composition is provided.

According to the present invention, in the composition of the composition for formulating a hair treatment agent, the contents of esters, alcohols, nonionic surfactants, and fatty acids are adjusted to A, B, C, and D (% by weight), respectively. ) Is the following formula: 3 ≦ A ≦ 4
5. The composition for blending a hair treatment agent according to any one of the above, which satisfies 5, 5 ≦ B ≦ 80, 3 ≦ C ≦ 25, 1 ≦ D ≦ 15, and A + B + C + D ≦ 100.

The present invention provides a composition for blending a hair treatment composition, a composition for blending a hair conditioner, a composition for blending a hair dye,
Any of the above compositions for blending a hair treatment agent, which is a composition for blending a waving agent or a composition for blending a finish, is provided.

The present invention provides a hair treatment composition containing any of the above-mentioned compositions for blending a hair treatment composition.

The present invention provides the above-mentioned hair treatment agent, wherein the hair treatment agent is a hair conditioner, a hair dye, a waving agent, or a finishing agent.

[0020]

BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail.
The composition for mixing a hair treatment agent of the present invention contains esters. Examples of the esters include fatty acid esters of polyhydric alcohols (eg, glycerin), higher fatty acid esters, and polybasic acid esters. Specifically, it is selected from the group consisting of mono- and diglycerides of stearic acid, lipophilic glyceryl monostearate, glycerin oleate, isononyl isononanoate, isopropyl myristate, isopropyl palmitate, stearyl stearate, and diisobutyl adipate. One or two compounds.

For example, a lipophilic glyceryl monostearate and / or isopropyl myristate is added to a composition for blending a hair conditioner, a composition for blending a hair dye, a composition for blending a waving agent, and a composition for blending a finish. May be contained.

The composition for compounding a hair treatment composition of the present invention contains alcohols. Examples of alcohols include higher alcohols, polyhydric alcohols, and natural alcohols. Specifically, myristyl alcohol,
One to three compounds selected from the group consisting of hexyldecanol, cetanol, behenyl alcohol, aralkyl alcohol, 1,3-butylene glycol, dipropylene glycol, and cetostearyl alcohol.

For example, the composition for blending a hair conditioner, the composition for blending a hair dye, and the composition for blending a finish may contain cetanol. The composition for formulating a hair conditioner and the composition for formulating a finish may contain, for example, behenyl alcohol. The composition for blending a hair conditioner, the composition for blending a hair dye, the composition for blending a waving agent, and the composition for blending a finishing agent may contain, for example, cetostearyl alcohol.

The composition for compounding a hair treatment composition of the present invention contains a nonionic surfactant. Examples of the nonionic surfactant include polyoxyethylene alkyl ether, polyoxyethylene derivatives of natural fats and oils, alkylolamide, sorbitan fatty acid ester, and polyoxyethylene fatty acid amide. In addition, the degree of polymerization of EO (ethylene oxide) of polyoxyethylene may be, for example, 3 to 45. Specifically, the group consisting of polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene hydrogenated castor oil, coconut oil fatty acid monoethanolamide, sorbitan monostearate, polyoxyethylene stearamide, and dimethyl stearylamine One or more compounds selected from the group consisting of:

For example, the composition for blending hair dyes may contain polyoxyethylene lauryl ether. The composition for blending a hair conditioner, the composition for blending a hair dye, the composition for blending a waving agent, and the composition for blending a finish may contain, for example, polyoxyethylene cetyl ether. The hair dye composition may contain, for example, coconut oil fatty acid monoethanolamide. The composition for blending a hair conditioner, the composition for blending a hair dye, and the composition for blending a waving agent may contain, for example, polyoxyethylene stearamide.

The composition for blending a hair treatment composition of the present invention contains fatty acids. Examples of the fatty acids include higher fatty acids and natural fatty acids. Specific examples include one or two compounds selected from the group consisting of lauric acid, myristic acid, stearic acid, oleic acid, and lanolin fatty acid.

For example, the composition for blending hair dyes and the composition for blending finishes may contain stearic acid.

Further, various additives may be appropriately added to the composition for compounding a hair treatment agent of the present invention according to the type and purpose of the hair treatment agent. For example, the composition for blending a hair treatment agent of the present invention contains anionic surfactants, oils and fats, hydrocarbons, waxes, silicons (Si-containing substances), oligoesters, water and the like as additives. May be.

Specifically, sodium tetradecenesulfonate, sodium palmitoylmethyltaurine, sulfated castor oil, N-coconut oil fatty acyl-L-glutamate triethanolamine, mink wax, shea butter, paraffin, liquid paraffin, rice bran wax , Candelilla wax, methylpolysiloxane, polypropylene glycol succinate oligoester, and water.

For example, the composition for blending a hair conditioner, the composition for blending a hair dye, and the composition for blending a waving agent may contain an anionic surfactant and / or fats and oils. The composition for blending a hair conditioner, the composition for blending a hair dye, the composition for blending a waving agent, and the composition for blending a finish may contain, for example, hydrocarbons.

The composition for blending a hair conditioner, the composition for blending a hair dye, the composition for blending a waving agent, and the composition for blending a finish may contain, for example, waxes. The hair dye composition may contain, for example, silicones.
The composition for formulating a hair conditioner may contain, for example, oligoesters. The composition for formulating a hair conditioner, the composition for formulating a hair dye, and the composition for formulating a waving agent may contain, for example, water.

In the composition of the hair treatment composition of the present invention, the contents of esters, alcohols, nonionic surfactants, and fatty acids are respectively A, B, C, and D (% by weight). A to D are represented by the following formula: 3 ≦ A ≦ 45,
5 ≦ B ≦ 80, 3 ≦ C ≦ 25, 1 ≦ D ≦ 15, and A
+ B + C + D ≦ 100 is preferable.

For example, in the composition of the composition for blending a hair conditioner and the composition for blending a waving agent, 5 ≦
A ≦ 20, 50 ≦ B ≦ 70, 1 ≦ C ≦ 25, 1 ≦ D ≦ 1
0 and A + B + C + D ≦ 100.

In the composition of the composition for blending hair dyes, 5
≦ A ≦ 15, 45 ≦ B ≦ 55, 10 ≦ C ≦ 20, 1 ≦ D
≦ 15 and A + B + C + D ≦ 100.

In the composition of the composition for finishing agent blending,
5 ≦ A ≦ 45, 5 ≦ B ≦ 80, 5 ≦ C ≦ 25, 1 ≦ D ≦
15, and A + B + C + D ≦ 100.

In the method for preparing the composition for compounding a hair treating agent of the present invention, for example, the compounding components such as esters, alcohols, nonionic surfactants, fatty acids, and various additives as necessary are mixed. The mixture is stirred with heating until completely dissolved. The heating temperature is lower than the temperature at which the mixture does not decompose, for example, 100 ° C or lower, preferably 95 ° C or lower. The order of addition of the respective components is not particularly limited.

The hair treatment composition of the present invention contains the above-mentioned composition for compounding a hair treatment composition of the present invention. Hereinafter, a hair conditioner, a hair dye, a waving agent, a finishing agent, and the like will be described as examples of the hair treatment agent.

[0038] The hair conditioner of the present invention contains the above composition for blending a hair conditioner. As the composition for blending a hair conditioner, one type or two or more types may be used.

Further, the hair conditioner of the present invention comprises water as an additive, an additive composition, a preservative, a fragrance, a pigment, an organic acid, a gum, an antioxidant, a sequestering agent,
It may contain a pH adjuster and the like.

Examples of the additive composition include esters,
Mixtures of oils and fats, polyethers, silicones, inorganic and organic acids, solvents and the like are included. Preservatives include parabens such as methylparaben and propylparaben. Dyes and fragrances may be those commonly used in hair conditioners.

Examples of the organic acid include lactic acid and citric acid. Examples of the gum include xanthan gum and the like. Examples of the antioxidant include dibutylhydroxytoluene. Examples of sequestering agents include disodium edetate. Examples of the pH adjuster include levulinic acid, citric acid, phosphoric acid, and salts thereof.

In the composition of the hair conditioner of the present invention, the composition for blending the hair conditioner is, for example, 5 to 5%.
30% by weight is contained.

The method of preparing the hair conditioner of the present invention is not particularly limited. For example, an antiseptic, an additive composition, an organic acid, etc. may be added, if necessary, to water heated by adding an organic acid, gum or the like. The composition for mixing hair conditioner, which has been heated and uniformly dissolved, may be added and emulsified while stirring, and then cooled, followed by adding a fragrance, a coloring matter, a preservative and the like, if necessary. The heating temperature of the composition for blending water and the hair conditioner is a temperature at which the blended components do not decompose, for example, 9
0 ° C. or lower is preferred.

The hair dye of the present invention includes an oxidative hair dye. The oxidative hair dye comprises a first agent and a second agent (in the present invention, the oxidative hair dye first agent alone and the oxidative hair dye second agent alone also include the hair dye of the present invention). include.). The oxidative hair dye first agent of the present invention, in addition to the hair dye composition of the present invention, a solvent, a dye intermediate, an antioxidant,
It may contain an alkali agent, a sequestering agent, water and the like.

Examples of the solvent include cetanol and N-methylpyrrolidone (NMP). Examples of dye intermediates include phenylenediamines (such as ortho-meta-para-phenylenediamine), phenols (such as ortho-meta-para-aminophenol and nitrophenol),
And aminocresols.

Examples of the antioxidant include those commonly used in oxidative hair dyes, for example, sodium sulfite, ammonium thioglycolate, ascorbic acid, cysteine and the like. Examples of the alkaline agent include MEA (monoethanolamine) and ammonia. Examples of the sequestering agent include edetate, hydroxyethanediphosphonic acid and the like.

In the composition of the first part of the oxidative hair dye, the composition for blending the hair dye is, for example, 10 to 35% by weight, preferably 2% by weight.
You may contain 0-30 weight%.

As a method for preparing the first oxidative hair dye, for example, a dye intermediate and an antioxidant are added to heated water,
After the aqueous solution is formed, a hair dye composition for heating and uniformly dissolved by heating and the like may be added and mixed, and after cooling, additives such as an alkali agent and a sequestering agent may be added with stirring.
The heating temperature of the composition for mixing water and the hair dye is preferably a temperature at which the components are not decomposed, for example, 95 ° C. or lower.

The second oxidative hair dye of the present invention may contain a sequestering agent, a pH adjuster, an oxidizing agent, water and the like, in addition to the composition of the present invention. Examples of the sequestering agent include hydroxyethanediphosphonic acid. Examples of the pH adjuster include a phosphate (for example, sodium monohydrogen phosphate) and the like. Examples of the oxidizing agent include hydrogen peroxide.

In the composition of the oxidative hair dye second agent, the composition for compounding the hair dye is, for example, 1 to 15% by weight, preferably 2 to 15% by weight.
It may contain 10% by weight.

As a method of preparing the oxidative hair dye second agent, for example, a hair dye composition for heating and uniformly dissolved in heated water is added, stirred and emulsified, cooled with stirring, and then sequestered with metal ions. It may be carried out by adding additives such as an agent, a pH adjuster, and an oxidizing agent. The heating temperature of the composition for mixing water and the hair dye is preferably a temperature at which the components are not decomposed, for example, 95 ° C. or lower.

The oxidative hair dye of the present invention uses at least one of the first oxidative hair dye of the present invention and the second oxidative hair dye of the present invention.

For example, the oxidative hair dye of the present invention includes the oxidative hair dye of the present invention and the oxidative hair dye of the present invention, and the oxidative hair dye of the present invention. Included are those comprising the first agent and the second oxidative hair dye, other than the above, and those comprising the first oxidative hair dye other than the above and the second oxidative hair dye of the present invention.

Examples of the “first agent for oxidative hair dyes other than those described above” and the “second agent for oxidative hair dyes other than those described above” include, for example, a first agent and a second agent each of which are generally used for hair dyes. No.

Another hair dye of the present invention includes an acidic hair dye. The acidic hair dye may contain an additive composition, a gum, an organic solvent, a preservative, a pigment, a fragrance, water, and the like, in addition to the hair dye composition of the present invention. Additive composition, gum,
Examples of the preservative, coloring matter, fragrance and the like include those exemplified in the composition for blending a hair conditioner. Examples of the organic solvent include benzyl alcohol and the like.

In the composition of the acidic hair dye, the composition for compounding the hair dye is, for example, 10 to 30% by weight, preferably 10 to 2% by weight.
It may contain 0% by weight.

As a method for preparing an acidic hair dye, for example, a tar dye and gum are added to heated water to prepare an aqueous solution.
On the other hand, the additive composition and the like are added to the hair dye composition, heated and uniformly dissolved, added to the heated aqueous solution, stirred and emulsified, and then, after cooling, an organic solvent, a flavor,
Preservatives and the like may be added. The heating temperature of the composition for mixing water and the hair dye is a temperature at which the components do not decompose, for example,
0 ° C. or lower is preferred.

Another hair coloring agent of the present invention includes a hair bleaching agent. Hair bleaching agents usually consist of a first agent and a second agent. Examples of the first agent for a hair bleaching agent include the first agent for an oxidative hair dye which does not contain a dye intermediate. The composition and preparation method of the composition for compounding a hair dye in the first agent for hair bleaching agent may be the same as that of the first agent for oxidative hair dye. As the hair bleaching agent second agent, an oxidative hair dye second agent can be used.

Examples of the waving agent of the present invention include those comprising a first agent and a second agent. (In the present invention, the first waving agent alone and the second waving agent alone are also used. , Included in the hair treatment composition of the present invention). The waving agent first agent of the present invention may contain a reducing agent, an alkali agent, water and the like in addition to the waving agent blending composition of the present invention.

As the reducing agent, thioglycolic acid, cysteine and the like, or salts thereof (ammonium salt, ME
A salt, hydrochloride, etc.). As the alkaline agent,
Examples include ammonia, amines (eg, MEA, isopropanolamine), ammonium salts (eg, ammonium bicarbonate), and basic amino acids.

In the composition of the first waving agent of the present invention, the waving agent blending composition may contain, for example, 10 to 25% by weight, preferably 15 to 20% by weight.

As a method for preparing the first agent of the waving agent of the present invention, for example, a composition for mixing a waving agent, which is heated and uniformly dissolved in heated water, is emulsified with stirring, cooled, and then stirred with a reducing agent and an alkali. It may be performed by adding an agent or the like. The heating temperature of the composition for mixing water and the waving agent is preferably a temperature at which the components are not decomposed, for example, 95 ° C. or lower.

The second waving agent of the present invention includes, in addition to the composition for blending a waving agent of the present invention, an oxidizing agent, a surfactant,
It may contain an organic / inorganic acid, a sequestering agent, water and the like. As oxidizing agents, bromates, hydrogen peroxide, etc., as surfactants, lauryl trimethyl ammonium halides (lauryl trimethyl ammonium chloride, lauryl trimethyl ammonium bromide, etc.), as organic acids, citric acid, tartaric acid, etc., as inorganic acids. Examples include phosphoric acid and sodium monohydrogen phosphate, and examples of sequestering agents include hydroxyethanediphosphonic acid.

In the composition of the second agent for the waving agent of the present invention, the composition for compounding the waving agent is, for example, 10 to 25% by weight.
May be contained.

As a method for preparing the second agent for the waving agent of the present invention, for example, a composition for blending a waving agent, which is heated and uniformly dissolved in heated water, is added and stirred and emulsified. This may be performed by adding a surfactant or the like. The heating temperature of the composition for mixing water and the waving agent is preferably a temperature at which the components are not decomposed, for example, 95 ° C. or lower.

The waving agent of the present invention uses at least one of the first waving agent of the present invention and the second waving agent of the present invention. For example, as the waving agent of the present invention, those comprising the above-mentioned waving agent first agent of the present invention and the above waving agent second agent, the above-mentioned waving agent first agent of the present invention and other waving agents other than the above And the above-mentioned waving agent second agent of the present invention and the like.

Examples of the "first agent other than the above-mentioned agents" and the "second agent other than the above-mentioned agents" include, for example, the first agent and the second agent each usually used for the waving agent. Specifically, "the second wave agent other than the above"
Examples thereof include those prepared by uniformly dissolving an oxidizing agent and a surfactant in water.

The finish of the present invention contains a finish compounding composition and usually further contains water. In addition, depending on various purposes, silicones, alkali agents, nonionic surfactants (such as polyoxyethylene derivatives of natural fats and oils), waxes, glycols, esters (such as higher fatty acid esters), and hair conditioners. Those exemplified as additives may be appropriately added.

For example, by adding silicones, the burnishing property, the spread of cream, the setting property, and the feeling (gloss, slipping feeling, oily feeling, etc.) can be further improved, and furthermore, flaking (so-called, Powder blowing) can be further suppressed.

Examples of such silicones include silicone oil. As the silicone oil, those having a viscosity of 10 to 1000 cs, particularly 20 to 500 cs are preferable. Specific examples of the silicone oil include methyl polysiloxane and methyl phenyl polysiloxane, and one or more of these may be added.

Examples of the alkali agent include an inorganic alkali agent and an organic alkali agent. Specific examples of the inorganic alkali agent include sodium hydroxide and potassium hydroxide. Examples of the organic alkali agent include a primary amine, a secondary amine, and a tertiary amine. Specifically, examples of the organic alkali agent include monoethanolamine, triethanolamine (TEA), 2-amino-2-methyl-1-propanol, and the like.

In the finish composition of the present invention, the finish composition may contain, for example, 1 to 35% by weight.

As a method for preparing the finishing agent of the present invention, for example, an inorganic alkali agent or the like is dissolved in water and heated. On the other hand, if necessary, a nonionic surfactant, waxes, glycols, preservatives, and the like are added to the finish compounding composition, and the mixture is uniformly stirred and dissolved while heating.
Esters and the like are added to disperse them.

The obtained homogeneous dispersion is added to the heated aqueous alkali solution with stirring to emulsify. Next, after cooling the emulsion, a flavor may be added as necessary. The heating temperature of the composition for mixing water and the finish is preferably a temperature at which the components are not decomposed, for example, 95 ° C. or lower.

[0075]

The present invention will be described more specifically with reference to the following examples. (Preparation of composition for compounding hair treatment agent) Examples 1 to 10 The components shown in Tables 1 and 2 (kg) were mixed in a container, and the mixture was mixed at a temperature shown in Tables 1 and 2. , And completely dissolved by stirring to prepare compositions for blending each hair treatment agent of the present invention (Examples 1 to 10).

[0076]

[Table 1]

[0077]

[Table 2]

Tables 1 and 2 in Tables 1 and 2 show the following. 1) 23EO, 2) 30EO, 3) 4EO, 4) 7E
0, 5) 5EO + 40EO (1: 1 mixture by weight),
6) 40 EO, 7) 25 EO, 8) containing 50% by weight of water,
9) Contains 70% by weight of water.

(Preparation of hair conditioner) Examples 11 to 13 Initial water was heated to 80 to 85 ° C. On the other hand, the composition for hair conditioner formulation (Example 1) obtained above was heated to 80 to 85 ° C. to be uniformly dissolved, and an additive composition, a preservative, lactic acid, and the like were added thereto to obtain a homogeneously dissolved product.

This homogeneous solution was added to the heated initial water while stirring to emulsify the mixture, and then the emulsion was cooled to 50 ° C. while stirring, a fragrance was added, and water (water supplement) was added.
To adjust the total weight to 100 kg, and uniformly mixed to obtain each hair conditioner of the present invention (Example 11).
To 13) were prepared. Table 3 shows the components and amounts (k
g).

Example 14 A preservative and lactic acid were added to initial water and heated to 80 to 85 ° C. to obtain an aqueous solution. On the other hand, the additive composition was added to the composition for blending a hair conditioner (Example 1) obtained above, and the mixture was heated to 80 to 85 ° C to be uniformly dissolved. The homogeneous solution is added to the heated aqueous solution with stirring to emulsify, then cooled to 50 ° C. with stirring, a fragrance is added, and water (refilling water) is added to add a total weight of 1%.
The hair conditioner (Example 14) of the present invention was prepared by adjusting the mixture to 00 kg and uniformly mixing. Table 3 shows the components and amounts (kg).

Example 15 A hair conditioner-mixing composition (Example 2) heated to 80 to 85 ° C. and uniformly dissolved was added to initial water heated to 80 to 85 ° C. with stirring to emulsify. The obtained emulsion is cooled to 45 ° C. or lower while stirring, and then lactic acid and an additive composition are added, and water (supplemented water) is further added to adjust the total weight to 100 kg and uniformly mixed. Was prepared (Example 15). Table 3 shows the components and amounts (kg).

Examples 16 to 21 Xanthan gum was added to the initial water, and the mixture was heated to 83 to 88 ° C. to dissolve the coloring matter to form an aqueous solution. On the other hand, the composition for compounding the hair conditioner obtained above (Example 8 or 1)
0) and the preservative were heated to 83-88 ° C. and uniformly dissolved.

The homogeneous solution was added to the heated aqueous solution with stirring to emulsify, then cooled to 48 ° C. with stirring, the added composition was added, and water (refilling water) was further added to reduce the total weight. The hair conditioners of the present invention (Examples 16 to 2) were adjusted to 100 kg, mixed uniformly, and mixed.
1) was prepared. Tables 3 and 4 show the components and amounts (kg).

[0085]

[Table 3]

[0086]

[Table 4]

In Tables 3 and 4, 1) to 10) represent the following. 1) Ingredients (% by weight): propylene glycol dicaprate (75), tri (caprylic / capric acid) glycerin (12.5), polyoxypropylene butyl ether [52PO (propylene oxide) polymer] (1)
2.5).

2) Trade name "CAE" (manufactured by Ajinomoto Co.). 3) Ingredients (% by weight): dimethylsiloxane / methylstearoxysiloxane copolymer (50), diisopropyl adipate (25), diisobutyl adipate (25).

4) Component (% by weight): Shea butter (4% by weight)
5), rice germ oil (45), 2-hexyldecyl isostearate (10). 5) Trade name “Mercoat 100” (CALGON CO
RPORATION). 6) NMP (38), benzyl alcohol (20), polyoxypropylene methyl glucoside (20), phosphoric acid (8), tartaric acid (8), water (6).

7) Parabens. 8) Orange No. 205. 9) Orange No. 205 (0.029 kg) + Purple No. 401 (0.011 kg) + Black No. 401 (0.01 kg).

10) Red No. 106 (0.0008 kg)
+ Orange 205 (0.016 kg) + blue 1 (0.0
016 kg) + purple 401 (0.016 kg) + black 401 (0.016 kg).

(Preparation of Oxidative Hair Dye) Examples 22 and 23 Preparation of First Agent Dye intermediates (resorcinol, p-phenylenediamine, m-aminophenol, and A mixture of p-aminophenol), an antioxidant and, if necessary, NMP were added and stirred to obtain an aqueous solution. Separately, cetanol was added to the hair dye composition (Example 5) and uniformly dissolved at 80 to 85 ° C., and this was added to the heated aqueous solution and stirred and emulsified.

After the emulsion was cooled to 50 to 55 ° C. while stirring, MEA, strong aqueous ammonia, edetate, 60% hydroxyethanediphosphonic acid and the like were added as necessary.
Further, water (rehydration) was added to adjust the total weight to 100 kg to prepare a first agent. Table 5 shows the components and the amount (kg) of each component.

Preparation of Second Agent The hair dye composition (Example 8) was uniformly dissolved at 80 to 85 ° C., added to initial water heated to 80 to 85 ° C., and stirred and emulsified. The emulsion was then cooled to 45 ° C. with stirring, 60% hydroxyethanediphosphonic acid and sodium monohydrogen phosphate (decahydrate) were added, and 35% by weight hydrogen peroxide was added. The second agent was prepared by adjusting the total weight to 100 kg by adding water (rehydration). Ingredients and amount (kg)
Are shown in Table 5.

[0095]

[Table 5]

(Preparation of Acid Hair Dye) Example 24 Same as the additive composition (1 in Table 3 above). ) 4 kg was added to 15 kg of the hair dye composition (Example 8), and this mixture was uniformly dissolved at 82 to 87 ° C. On the other hand, tar dye (0.5 kg of orange No. 205 + 0.3 of purple No. 401)
kg + 0.3 kg of black 401) and 0.2 kg of xanthan gum were added to about 60 kg of initial water, and heated to 82 to 87 ° C. to form an aqueous solution.

The mixture was added to the heated aqueous solution while stirring, and emulsified. After cooling this emulsion to 50 ° C., it is the same as the additive composition (6 in Table 3 above). ) 8k
g, benzyl alcohol 5 kg, parabens 0.15 k
g, perfume and the like were added, and water (refilling water) was further added to adjust the total weight to 100 kg, thereby preparing an acidic hair dye.

(Preparation of Waving Agent) Example 25 Preparation of First Agent The composition for mixing a waving agent (Example 8) was heated to 80 to 85 ° C. to be uniformly dissolved, and heated to 80 to 85 ° C. The mixture was added to the initial water and stirred and emulsified. This emulsion was cooled to 45 ° C., 50% ammonium thioglycolate, strong aqueous ammonia and ammonium bicarbonate were added, and water (rehydration) was added to adjust the total weight to 100 kg. An agent was prepared. Table 6 shows the components and the amount (kg).

Preparation of Second Agent The composition for blending a waving agent (Example 8) was heated to 80 to 85 ° C. to be uniformly dissolved, and this was added to the initial water heated to 80 to 85 ° C. and stirred and emulsified. The emulsion was cooled to 45 ° C., sodium bromate was added, and water (rehydration) was further added to adjust the total weight to 100 kg to prepare a second agent. Table 6 shows the components and the amount (kg).

Example 26 Preparation of First Agent The first agent was prepared in the same manner as in Example 25.

Preparation of Second Agent Water was added to sodium bromate and lauryltrimethylammonium chloride to adjust the total weight to 100 kg, followed by stirring and mixing to prepare an aqueous solution. Table 6 shows the components and the amount (kg).

[0102]

[Table 6]

(Preparation of Finishing Agent) Examples 27 to 29 A sodium hydroxide solution was added to initial water and heated to 90 to 95 ° C. On the other hand, polyoxyethylene hydrogenated castor oil, polyethylene wax, dipropylene glycol (or propylene glycol), and parabens were added to the finish compounding composition (Example 3) heated to 90 to 95 ° C. and uniformly dissolved, followed by mixing. Thereafter, methyl polysiloxane and isononyl isononanoate were further added, and the mixture was stirred and dispersed.

This dispersion was added to the heated aqueous alkali solution with stirring to emulsify. Thereafter, the emulsion was cooled to 45 ° C. with stirring, a fragrance was added, and water (refilled water) was further added to adjust the total weight to 100 kg and uniformly mixed to prepare a finish of the present invention. . Table 7
Table 2 shows the components and the amount (kg).

Example 30 A sodium hydroxide solution was added to initial water and heated to 83 to 86 ° C. On the other hand, the finish compounding composition (Example 4) was heated to 83 to 86 [deg.] C. to be uniformly dissolved, and this was added to the heated aqueous alkaline solution with stirring to emulsify.

Thereafter, the emulsion was stirred at 45 ° C.
Then, water (refilling water) was added to adjust the total weight to 100 kg and uniformly mixed to prepare a finish of the present invention. Table 7 shows the components and amounts (kg).

[0107]

[Table 7]

In Table 7, 1) to 6) represent the following. 1) 10,000 cs. 2) 50% concentration. 3) 25EO. 4) 20EO. 5) 30% concentration. 6) 10% concentration.

(Preparation of Composition for Mixing Hair Treatment Agent) Example 31 11.67 kg of lipophilic glyceryl monostearate, 8.75 kg of cetanol, 8.33 k of behenyl alcohol
g, 18.75 kg of dipropylene glycol, 16.67 kg of polyoxyethylene (6EO) cetyl ether,
Polyoxyethylene (40EO) cetyl ether 2.0
8 kg, 13.33 kg of stearic acid and 20.42 kg of candelilla wax were placed in a container and mixed. Then
This mixture was heated to 80 ° C., stirred and completely dissolved to prepare a composition for blending a hair treatment composition of the present invention.

(Preparation of Finishing Agent) Examples 32-35 Initial water and TEA were mixed and heated to 80-85 ° C. to form an aqueous solution. On the other hand, a finish compounding composition (Example 31), parabens (methylparaben, propylparaben), and, if necessary, methylpolysiloxane and methylphenylpolysiloxane were mixed and mixed with 80
The mixture was heated to ８５85 ° C. and uniformly dissolved.

The homogeneous solution was added to the heated aqueous solution with stirring to emulsify. Thereafter, the emulsion was cooled to 45 ° C. while stirring, an appropriate amount of flavor was added, and water (supplemented water) was further added to adjust the total weight to 100 kg and uniformly mixed. (Each Example 32)
~ 35) were prepared. Table 8 shows the components and amounts (k
g).

[0112]

[Table 8]

In Table 8, 1) to 3) represent the following. 1) 20cs. 2) 14cs. 3) 1000 cs.

(Sensory Evaluation on Hair Treatment Effect of Hair Treatment Agent) Fifty test subjects were subjected to hair treatment according to the following method, and sensory evaluation was performed on the hair treatment effect (feeling of use) of the hair treatment agent. I was asked to. Table 9 shows the evaluation results.

Hair treatment method of hair conditioner After normal shampooing, a hair conditioner (Examples 11 to 15) was applied to the hair, combed, and allowed to spread. It was then rinsed and dried in a dryer.

In the case of color rinse After the hair was shampooed, a hair conditioner (Examples 16 to 21) was applied to the hair, rinsed, and dried with a dryer. This process was repeated a plurality of times.

Hair treatment method of hair dye The first and second agents of the hair dye (Examples 22 and 23) were mixed at a ratio of 1: 1 (weight ratio) and applied to the hair. . Next, after leaving at room temperature for 30 minutes, it was rinsed and dried with a dryer.

When Acid Hair Dye is Used The hair was coated with an acid hair dye (Example 24), heated at 45 ° C. for 15 minutes, and rinsed. Thereafter, it was shampooed, rinsed and dried in a dryer.

Hair treatment method of waving agent In the case of straight perm The first waving agent (Example 25) was applied to the hair and combed to spread the hair, so that the hair was straightened. Then, it was left for 10 minutes. Next, the second agent was applied to the hair, combed, allowed to spread, and left for 10 minutes. Finally, it was rinsed and dried in the dryer.

In the case of a permanent that gives a wave The first agent of the wave (Example 26) was applied to the hair, combed and allowed to spread, the hair was wound around a rod, and allowed to stand at room temperature for 7 minutes. Next, the second agent was applied with an applicator and allowed to stand for 7 minutes, and then the second agent was applied again with an applicator and allowed to stand for 7 minutes. Then remove the rod, rinse,
Dryer was dried.

Hair Treatment Method for Finishing Agent Finishing agents (Examples 27 to 30, 32 to 35) were applied to the hair and allowed to spread.

[0122]

[Table 9]

In Table 9, ◎ indicates very good, ○ indicates good, and Δ indicates normal. As is evident from the results in Table 9, the hair treatment composition of the present invention shows that the hair has a slimy feeling, a soft feeling, a crisp feeling, a good combability, a smooth feeling, a hair setting property, an extension of cream, and no dripping. It can be seen that flaking is less likely to occur and burnishing properties are excellent.

[0124]

The composition for compounding a hair treating agent of the present invention is prepared by appropriately selecting and combining inexpensive and readily available compounding ingredients so as to exhibit an excellent hair treating effect. Therefore, the composition for blending a hair treatment agent of the present invention can be easily produced at low cost. Since the hair treatment composition of the present invention is prepared from the above composition, it is inexpensive, and has a slimy feeling, a soft feeling, a crisp feeling, good combability, a smooth feeling, a hair setting property, and a cream extension. It has an excellent hair treatment effect without dripping. Also, in the manufacturing process of the hair treatment agent, esters, alcohols, nonionic surfactants, fatty acids and the like can be compounded at a time, and the process can be greatly simplified.

 ────────────────────────────────────────────────── ─── Continuing on the front page (72) Katsuhiro Watanabe, Inventor 1-31-16 Horifune, Kita-ku, Tokyo Yamaei Chemical Co., Ltd. F-term (reference) AC021 AC022 AC061 AC062 AC071 AC072 AC111 AC121 AC122 AC181 AC182 AC241 AC242 AC251 AC252 AC302 AC331 AC351 AC352 AC372 AC391 AC392 AC431 AC432 AC441 AC442 AC472 AC482 AC531 AC532 AC552 AC641 AC642 AC661 AC662 AC692 AC781 AC782 AC791 AC792 AD1522 AD512 BB04 CC31 CC32 CC33 CC34 CC36 CC39 EE21 EE25 EE26 EE28

Claims (11)

[Claims] 1. A composition for compounding a hair treatment agent, comprising an ester, an alcohol, a nonionic surfactant, and a fatty acid. 2. The method according to claim 1, wherein the esters are mono- or diglyceride stearate oleate, lipophilic glyceryl monostearate, glycerin oleate, isononyl isononanoate,
One or two compounds selected from the group consisting of isopropyl myristate, isopropyl palmitate, stearyl stearate, and diisobutyl adipate, wherein the alcohols are myristyl alcohol, hexyldecanol, cetanol, behenyl alcohol, aralkyl alcohol, One or three compounds selected from the group consisting of 3-butylene glycol, dipropylene glycol, and cetostearyl alcohol, wherein the nonionic surfactant is polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene cured castor Oil, selected from the group consisting of coconut oil fatty acid monoethanolamide, sorbitan monostearate, polyoxyethylene stearamide, and dimethyl stearylamine That is one or two compounds, fatty acids are lauric acid, myristic acid, stearic acid,
2. The composition according to claim 1, wherein the composition is one or two compounds selected from the group consisting of oleic acid and lanolin fatty acid. 3. The composition according to claim 1, wherein the esters are mono-diglyceride stearate oleate and / or isopropyl myristate. 4. The composition according to claim 1, wherein the alcohol is cetanol, behenyl alcohol or cetostearyl alcohol. 5. The nonionic surfactant is one or two compounds selected from the group consisting of polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, coconut fatty acid monoethanolamide, and polyoxyethylene stearamide. The composition for blending a hair treatment agent according to any one of claims 1 to 4, wherein: 6. The composition for blending a hair treatment agent according to claim 1, wherein the fatty acid is stearic acid. 7. The composition for blending a hair treatment agent, further comprising sodium tetradecenesulfonate, sodium palmitoylmethyltaurine, sulfated castor oil, N-coconut oil fatty acid acyl-L-glutamate triethanolamine, mink wax, and shea fat. , Paraffin, liquid paraffin, rice bran wax, candelilla wax, methylpolysiloxane,
The composition according to any one of claims 1 to 6, comprising one to seven compounds selected from the group consisting of succinic acid polypropylene glycol oligoester and water. . 8. In the composition of the composition for blending a hair treatment agent, an ester, an alcohol, a nonionic surfactant,
And the contents of fatty acids A, B, C, and D, respectively.
A to D are expressed by the following formula: 3 ≦ A ≦ 45,5
≤B≤80, 3≤C≤25, 1≤D≤15, and A +
The composition according to any one of claims 1 to 7, wherein the composition satisfies B + C + D ≦ 100. 9. The composition for blending a hair treatment agent, the composition for blending a hair conditioner, the composition for blending a hair dye, the composition for blending a waving agent, or the composition for blending a finishing agent. 8. The composition for blending a hair treatment agent according to any one of 8. 10. A hair treatment agent comprising the composition for compounding a hair treatment agent according to claim 1. 11. The hair conditioner, wherein the hair treatment agent is a hair conditioner.
The hair treatment agent according to claim 10, which is a hair dye, a waving agent, or a finishing agent.