JP5426569B2 - 湿分硬化性組成物 - Google Patents
湿分硬化性組成物 Download PDFInfo
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- JP5426569B2 JP5426569B2 JP2010538449A JP2010538449A JP5426569B2 JP 5426569 B2 JP5426569 B2 JP 5426569B2 JP 2010538449 A JP2010538449 A JP 2010538449A JP 2010538449 A JP2010538449 A JP 2010538449A JP 5426569 B2 JP5426569 B2 JP 5426569B2
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- composition
- polymer
- kaolin
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- reactive
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- 239000000203 mixture Substances 0.000 title claims description 129
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- 235000012211 aluminium silicate Nutrition 0.000 claims description 66
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 17
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- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
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- MCZCJVXEOMJCBE-UHFFFAOYSA-N [dimethyl(triacetyloxysilyloxy)silyl] acetate Chemical compound CC(=O)O[Si](C)(C)O[Si](OC(C)=O)(OC(C)=O)OC(C)=O MCZCJVXEOMJCBE-UHFFFAOYSA-N 0.000 description 1
- BEIRWWZHJZKPCX-UHFFFAOYSA-N [phenyl-di(propanoyloxy)silyl] propanoate Chemical compound CCC(=O)O[Si](OC(=O)CC)(OC(=O)CC)C1=CC=CC=C1 BEIRWWZHJZKPCX-UHFFFAOYSA-N 0.000 description 1
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- 125000003342 alkenyl group Chemical group 0.000 description 1
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- 229910001586 aluminite Inorganic materials 0.000 description 1
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- DQBAOWPVHRWLJC-UHFFFAOYSA-N barium(2+);dioxido(oxo)zirconium Chemical compound [Ba+2].[O-][Zr]([O-])=O DQBAOWPVHRWLJC-UHFFFAOYSA-N 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
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- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 1
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- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
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- 239000006013 carbendazim Substances 0.000 description 1
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- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
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- WTVAYLQYAWAHAX-UHFFFAOYSA-J cerium(4+);tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Ce+4] WTVAYLQYAWAHAX-UHFFFAOYSA-J 0.000 description 1
- FXNONNRUNQPNLF-UHFFFAOYSA-N cerium;2-ethylhexanoic acid Chemical compound [Ce].CCCCC(CC)C(O)=O.CCCCC(CC)C(O)=O.CCCCC(CC)C(O)=O FXNONNRUNQPNLF-UHFFFAOYSA-N 0.000 description 1
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- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 description 1
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- KSFBTBXTZDJOHO-UHFFFAOYSA-N diaminosilicon Chemical compound N[Si]N KSFBTBXTZDJOHO-UHFFFAOYSA-N 0.000 description 1
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- YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical group CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
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- 230000000694 effects Effects 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
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- GBFVZTUQONJGSL-UHFFFAOYSA-N ethenyl-tris(prop-1-en-2-yloxy)silane Chemical compound CC(=C)O[Si](OC(C)=C)(OC(C)=C)C=C GBFVZTUQONJGSL-UHFFFAOYSA-N 0.000 description 1
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- 238000002474 experimental method Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 125000005816 fluoropropyl group Chemical group [H]C([H])(F)C([H])([H])C([H])([H])* 0.000 description 1
- 229920001002 functional polymer Polymers 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
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- 230000009477 glass transition Effects 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
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- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
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- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
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- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
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- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical group CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 description 1
- ZWXYOPPJTRVTST-UHFFFAOYSA-N methyl-tris(prop-1-en-2-yloxy)silane Chemical compound CC(=C)O[Si](C)(OC(C)=C)OC(C)=C ZWXYOPPJTRVTST-UHFFFAOYSA-N 0.000 description 1
- 125000002816 methylsulfanyl group Chemical group [H]C([H])([H])S[*] 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- MYADPEFFMQPOQC-UHFFFAOYSA-N n-[[acetyl(ethyl)amino]-dimethylsilyl]-n-ethylacetamide Chemical compound CCN(C(C)=O)[Si](C)(C)N(CC)C(C)=O MYADPEFFMQPOQC-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 description 1
- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 1
- CBFCDTFDPHXCNY-UHFFFAOYSA-N octyldodecane Natural products CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229910052609 olivine Inorganic materials 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- QSGNIZYSOOADSE-UHFFFAOYSA-N penta-1,4-dienylbenzene Chemical compound C=CCC=CC1=CC=CC=C1 QSGNIZYSOOADSE-UHFFFAOYSA-N 0.000 description 1
- 125000005003 perfluorobutyl group Chemical group FC(F)(F)C(F)(F)C(F)(F)C(F)(F)* 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 1
- BXRNXXXXHLBUKK-UHFFFAOYSA-N piperazine-2,5-dione Chemical compound O=C1CNC(=O)CN1 BXRNXXXXHLBUKK-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920003251 poly(α-methylstyrene) Polymers 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 150000004032 porphyrins Chemical class 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000012712 reversible addition−fragmentation chain-transfer polymerization Methods 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical class OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000004590 silicone sealant Substances 0.000 description 1
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 1
- UQMGAWUIVYDWBP-UHFFFAOYSA-N silyl acetate Chemical class CC(=O)O[SiH3] UQMGAWUIVYDWBP-UHFFFAOYSA-N 0.000 description 1
- GRJISGHXMUQUMC-UHFFFAOYSA-N silyl prop-2-enoate Chemical compound [SiH3]OC(=O)C=C GRJISGHXMUQUMC-UHFFFAOYSA-N 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- 125000004205 trifluoroethyl group Chemical group [H]C([H])(*)C(F)(F)F 0.000 description 1
- XYJRNCYWTVGEEG-UHFFFAOYSA-N trimethoxy(2-methylpropyl)silane Chemical compound CO[Si](OC)(OC)CC(C)C XYJRNCYWTVGEEG-UHFFFAOYSA-N 0.000 description 1
- JLGNHOJUQFHYEZ-UHFFFAOYSA-N trimethoxy(3,3,3-trifluoropropyl)silane Chemical compound CO[Si](OC)(OC)CCC(F)(F)F JLGNHOJUQFHYEZ-UHFFFAOYSA-N 0.000 description 1
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
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Description
X1−A’−X2 (1)
(式中、X1及びX2は独立して、ヒドロキシル置換基又は加水分解性置換基を含有するケイ素含有基から選択され、A’はポリマー鎖を表す)を有し得る。ヒドロキシル置換基及び/又は加水分解性置換基を組み込んだX1基又はX2基の例としては、下記:
−Si(OH)3、−(Ra)Si(OH)2、−(Ra)2SiOH、−RaSi(ORb)2、−Si(ORb)3、−Ra 2SiORb又は−Ra 2Si−Rc−SiRd p(ORb)3-p(式中、Raはそれぞれ独立して、一価のヒドロカルビル基、例えば特に1個〜8個の炭素原子を有するアルキル基を表し(且つ、好ましくはメチルであり)、Rb基及びRd基はそれぞれ独立してアルキル基又はアルコキシ基であり、該アルキル基は適宜6個までの炭素原子を有し、Rcは、6個までのケイ素原子を有する1つ又は複数のシロキサンスペーサが介在し得る二価の炭化水素基であり、pは0、1又は2の値を有する)のように終端する基が挙げられる。
−(R5 sSiO(4-s)/2)− (2)
(式中、R5はそれぞれ独立して、1個〜18個の炭素原子を有する炭化水素基、1個〜18個の炭素原子を有する置換炭化水素基、又は18個までの炭素原子を有するヒドロカルボノキシ基等の有機基であり、sは平均して1〜3、好ましくは1.8〜2.2の値を有する)のシロキサン単位を含む。置換炭化水素基において、炭化水素基中の1つ又は複数の水素原子は、別の置換基で置き換えられている。かかる置換基の例としては、塩素、フッ素、臭素及びヨウ素等のハロゲン原子;クロロメチル、ペルフルオロブチル、トリフルオロエチル及びノナフルオロヘキシル等のハロゲン原子含有基;酸素原子;(メタ)アクリル及びカルボキシル等の酸素原子含有基;窒素原子;アミノ官能基、アミド官能基及びシアノ官能基等の窒素原子含有基;硫黄原子;並びに、メルカプト基等の硫黄原子含有基が挙げられるが、これらに限定されない。
両方ともアルキル基(好ましくは両方ともメチル若しくはエチル)、又は
アルキル基及びフェニル基、又は
アルキル及びフルオロプロピル、又は
アルキル及びビニル、又は
アルキル基及び水素基である。
典型的に、少なくとも1つのブロックはシロキサン単位を含み、ここでR5基は両方ともアルキル基である。
−[−Re−O−(−Rf−O−)h−Pn−CRg 2−Pn−O−(−Rf−O−)q−Re]−
(式中、Pnは1,4−フェニレン基であり、Reはそれぞれ同じであるか又は異なり、2個〜8個の炭素原子を有する二価の炭化水素基であり、Rfはそれぞれ同じであるか又は異なり、エチレン基又はプロピレン基であり、Rgはそれぞれ同じであるか又は異なり、水素原子又はメチル基であり、下付き文字のh及びqはそれぞれ、3〜30の範囲の正の整数である)を含み得る。
「引張」は、MPa単位の引張強度(破壊応力)を意味する。「100%モジュラス」は、100%の伸張における公称応力(又は見かけの応力(MPa))である。
伸張はASTM D412−98に準拠して2mmのシートについて%単位で示す。
表1に示す配合を用いて湿分硬化性シーラント組成物を調製した。焼成カオリンAは、メジアン粒径1.5μm(Malvern)、表面積BET 16g/m2(BET)及び吸油量80ml/100g(ISO 787)を有していた。比較例C1及び比較例C2では、既知の触媒であるジブチルスズジラウレート(DBTDL)を含有する以外は同様の配合から湿分硬化性シーラント組成物を調製した。
表2に示す配合を用いて湿分硬化性シーラント組成物を調製した。該湿分硬化性シーラント組成物中では、第2の充填剤であるタルクAと併せて焼成カオリンが存在しており、該タルクAは、Alpha Calcitにより商標Alpha CT 15Pとして販売されているタルクである。上記のように試験した場合の組成物の特性も表2に示す。
表3中でタルクBと記載されているタルクは、Rio Tinto Mineralsから商標Mistron Monomix Gとされているものを入手した。
カオリンの代わりに表3に列挙されるような、充填剤として既知の多様な他の材料を用いて、実施例2を繰り返した。タルクB及びタルクCは、Rio Tinto Mineralsによりそれぞれ商標Mistron Monomix G及びMistron 754Gとして販売されている板状タルクとした。クリストバライトは、Sibelcoにより商標M3000として供給されているものとした。上記のように試験した場合の組成物の特性も表4に示す。
Hausschild実験室用ミキサー内で列挙される成分を混合することによって、湿分硬化性シーラント組成物を調製した。用いた硬化系はオキシム硬化であった。使用したポリマーは、25℃で50000mPaSの粘度を有するジヒドロキシ末端ポリジメチルシロキサンとした。架橋剤はビニル−トリス(メチルエチルケトキシモ)シラン(VOS)とした。比較例C7で使用した触媒はジブチルスズジラウレート(DBTDL)とした。比較例C9で使用した粉末炭酸カルシウム(GCC)は、Provencaleにより商品名Mikhart ACとして供給されているものとした。比較例C7及び比較例C8で使用したシリカは、およそ150m2/gのBET表面積を有するヒュームドシリカとした。シリコーン油は、25℃で100mPasの粘度のトリメチルシリル末端ポリジメチルシロキサンとした。カオリンは、実施例1に記載したものと同様の焼成カオリンAとした。
Claims (18)
- 湿分の存在下で互いに又は組成物中に存在する架橋剤(B)中の基と反応性である、ケイ素に結合した反応性ヒドロキシル基又は加水分解性基を含有するポリマー(A)を含む湿分硬化性組成物であって、スズの有機化合物を含まず、ポリマー(A)の前記反応性基の反応のための触媒としてカオリンを含有することを特徴とする、湿分硬化性組成物。
- ポリマー(A)の前記反応性基と反応性である基を含有する架橋剤(B)を含有し、前記カオリンが、湿分の存在下における架橋剤(B)とポリマー(A)との反応性基の反応のための触媒として作用することを特徴とする、請求項1に記載の組成物。
- 前記カオリンが焼成カオリンであることを特徴とする、請求項1に記載の組成物。
- 前記カオリンが、0.1μm〜40μmの重量基準メジアン粒径を有し、及び/又はポリマー(A)100重量部当たり3重量部〜400重量部の範囲で存在することを特徴とする、請求項1〜3のいずれか一項に記載の組成物。
- 前記ポリマー(A)が、ヒドロキシ末端ポリジオルガノシロキサンであるか、又はポリエーテル、炭化水素ポリマー、アクリレートポリマー、ポリウレタン及びポリ尿素から選択される有機ポリマーであることを特徴とする、請求項1〜4のいずれか一項に記載の組成物。
- 前記有機ポリマーが、末端加水分解性シリル基を有するテレケリックポリマーであることを特徴とする、請求項5に記載の組成物。
- 前記架橋剤がアセトキシシラン、オキシム官能性ケイ素化合物またはアルコキシシランから選択されることを特徴とする、請求項2〜6のいずれか一項に記載の組成物。
- 前記ポリマー(A)又は前記架橋剤(B)と反応性でないシリコーン又は有機流体をさらに含むことを特徴とする、請求項1〜7のいずれか一項に記載の組成物。
- 請求項3に記載の組成物であって、該組成物が一液型組成物であり、かつ、前記ポリマー(A)、架橋剤(B)及び焼成カオリンが、湿分の非存在下でまとめて収容される、請求項3に記載の組成物。
- 請求項2〜8のいずれか一項に記載の組成物であって、該組成物は二液型組成物であり、かつ、前記ポリマー(A)及び前記架橋剤(B)が別々に収容され、前記カオリンが(A)と一緒に収容され、(B)が水と一緒に収容されるか、または前記カオリンが(B)と一緒に収容され、(A)が水と一緒に収容される、請求項2〜8のいずれか一項に記載の組成物。
- 請求項2〜10のいずれか一項に記載の組成物を硬化させて得られるエラストマー体であって、前記組成物はさらに充填剤を含み、前記カオリンが、該組成物中の充填剤の75重量%〜100重量%を形成することを特徴とする、エラストマー体。
- 請求項2〜10のいずれか一項に記載の組成物を硬化させて得られるエラストマー体であって、前記組成物は更に充填剤を含み、前記カオリンが、該組成物中の充填剤の10重量%〜75重量%を形成し、前記組成物がまた、シリカ、炭酸カルシウム、及びカオリン以外のシリケート充填剤から選択される充填剤を含有することを特徴とする、エラストマー体。
- 前記シリケート充填剤が、タルク、クリストバライト、マイカ、長石又はウォラストナイトであることを特徴とする、請求項12に記載のエラストマー体。
- シーラントであることを特徴とする、請求項12又は13に記載のエラストマー体。
- ポリマー(A)の前記ヒドロキシル基又は加水分解性基が湿分の存在下で互いに反応性であり、前記組成物が別個の架橋剤を含有しないことを特徴とする、請求項1に記載の組成物。
- 湿分の存在下で互いに又は組成物中に存在する架橋剤(B)中の基と反応性である、ケイ素に結合した反応性ヒドロキシル基又は加水分解性基を含有するポリマー(A)を含む組成物の湿分硬化のための触媒としてのカオリンの使用。
- 前記カオリンが焼成カオリンであることを特徴とする、請求項16に記載の使用。
- 請求項1〜10のいずれか一項に記載の組成物中における、ポリマー(A)の前記反応性基の反応のための触媒としてのカオリンの使用。
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GB9919083D0 (en) * | 1999-08-13 | 1999-10-13 | Dow Corning | Silicone coated textile fabrics |
JP3580356B2 (ja) * | 1999-08-25 | 2004-10-20 | 信越化学工業株式会社 | 室温硬化性オルガノポリシロキサン組成物の製造方法 |
JP3705344B2 (ja) * | 2000-08-17 | 2005-10-12 | 信越化学工業株式会社 | 導電性シリコーンゴム組成物 |
JP2003049063A (ja) * | 2001-08-09 | 2003-02-21 | Kanegafuchi Chem Ind Co Ltd | 硬化性組成物 |
JP2003197377A (ja) * | 2001-10-18 | 2003-07-11 | Fuji Xerox Co Ltd | 有機電界発光素子 |
DE10214137A1 (de) * | 2002-03-28 | 2003-10-16 | Wacker Chemie Gmbh | Siliconmassen mit verbesserter Hitzestabilität |
US20050203236A1 (en) * | 2004-03-09 | 2005-09-15 | Christina Prowell | Reinforcing filler for silicone rubber and sealants |
GB0512193D0 (en) * | 2005-06-15 | 2005-07-20 | Dow Corning | Silicone rubber compositions |
US7625976B2 (en) * | 2006-01-09 | 2009-12-01 | Momemtive Performance Materials Inc. | Room temperature curable organopolysiloxane composition |
US7569653B2 (en) * | 2006-02-01 | 2009-08-04 | Momentive Performance Materials Inc. | Sealant composition having reduced permeability to gas |
FR2899905B1 (fr) * | 2006-04-12 | 2008-07-18 | Rhodia Recherches & Tech | Compositions polyorganosiloxanes vulcanisables a chaud utilisables notamment pour la fabrication de fils ou cables electriques |
GB0724943D0 (en) * | 2007-12-21 | 2008-01-30 | Dow Corning | Sealant composition |
-
2007
- 2007-12-21 GB GBGB0724914.7A patent/GB0724914D0/en not_active Ceased
-
2008
- 2008-12-17 CN CN200880122055.2A patent/CN101903448B/zh not_active Expired - Fee Related
- 2008-12-17 EP EP08864863A patent/EP2222768A1/en not_active Withdrawn
- 2008-12-17 WO PCT/EP2008/010754 patent/WO2009080266A1/en active Application Filing
- 2008-12-17 KR KR1020107013779A patent/KR101203405B1/ko not_active IP Right Cessation
- 2008-12-17 US US12/809,308 patent/US20110178220A1/en not_active Abandoned
- 2008-12-17 JP JP2010538449A patent/JP5426569B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
GB0724914D0 (en) | 2008-01-30 |
WO2009080266A1 (en) | 2009-07-02 |
CN101903448A (zh) | 2010-12-01 |
CN101903448B (zh) | 2012-12-26 |
JP2011510103A (ja) | 2011-03-31 |
KR20100087232A (ko) | 2010-08-03 |
KR101203405B1 (ko) | 2012-11-23 |
US20110178220A1 (en) | 2011-07-21 |
EP2222768A1 (en) | 2010-09-01 |
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