JP4941313B2 - Gas adsorption device, vacuum heat insulating material and vacuum heat insulating box - Google Patents

Description

  The present invention relates to a gas adsorption device capable of storing a gas adsorbent in the atmosphere, and further requires heat insulation and heat insulation, such as a refrigerator, a heat insulation jacket material, a vending machine, an electric water heater, a vehicle The present invention relates to a vacuum heat insulating material and a vacuum heat insulating box that can be used as a heat insulating material.

  In recent years, expectations for industrial technology that requires high vacuum are increasing. For example, energy saving is strongly desired from the viewpoint of preventing global warming, and energy saving is an urgent issue for household appliances. In particular, a heat insulating material such as a refrigerator, a freezer, and a vending machine is required to have a heat insulating material and a vacuum heat insulating box having excellent heat insulating performance from the viewpoint of efficiently using heat.

  As general heat insulating materials, fiber materials such as glass wool and foams such as urethane foam are used. However, in order to improve the heat insulation performance of these heat insulating materials, it is necessary to increase the thickness of the heat insulating material, and it is applied when there is a limit to the space where the heat insulating material can be filled and space saving or effective use of the space is necessary. Can not do it.

  Therefore, vacuum heat insulating materials have been proposed as high performance heat insulating materials. The vacuum heat insulating material is a heat insulating material in which a core material serving as a spacer is inserted into a jacket material having a gas barrier property and the inside is decompressed and sealed.

  By increasing the degree of vacuum inside the vacuum heat insulating material, high-performance heat insulating performance can be obtained, but the gas existing inside the vacuum heat insulating material is roughly divided into the following three types. One is the gas that cannot be evacuated during the vacuum insulation material preparation, and the other is the gas generated from the core material and the jacket material after being sealed under reduced pressure (adsorbed on the core material and the jacket material). The remaining gas is a gas that passes through the jacket material and enters from the outside.

  In order to adsorb these gases, a method of filling the vacuum heat insulating material with the adsorbent has been devised.

  For example, there exists what adsorb | sucks the gas in a vacuum heat insulating material using a Ba-Li alloy (for example, refer patent document 1).

  Of the gases to be adsorbed by the adsorbent in the vacuum heat insulating material, one of the gases that are difficult to adsorb is nitrogen. This is because the nitrogen molecule is a nonpolar molecule having a large binding energy of about 940 kJ / mo1, and therefore it is difficult to activate. However, nitrogen can be adsorbed by the Ba-Li alloy, and the degree of vacuum inside the vacuum heat insulating material is maintained.

  For the purpose of further improving the performance of the vacuum heat insulating material, the vacuum degree inside the vacuum heat insulating material is further reduced, and it is more active than Ba-Li for equipment that requires a high vacuum such as a plasma display panel. The practical application of a gas adsorbent is desired.

Moreover, there exists patent document 2 as an example of a vacuum heat insulation box. In Patent Document 2, in a vacuum heat insulation box body in which a foam heat insulating material is filled between an outer box and an inner box of a refrigerator or the like, an open-celled hard polyurethane foam is used for the foam heat insulating material, and the outer box is insulated. There is a vacuum heat insulating box that is provided with a vacuum indicator and an open / close valve communicating with the inside of the wall and vacuum deaerated through the open / close valve. Since the vacuum degree inside can be monitored by the vacuum indicator communicating with the inside of the heat insulating wall, even if the vacuum degree deteriorates due to gas entering from the outside or gas remaining inside, by vacuum degassing through the open / close valve, The initial thermal insulation performance can be restored.
Japanese National Patent Publication No. 9-512088 JP-A-7-148752

  However, the conventional configuration described in Patent Document 1 does not require heat treatment for activation, can adsorb nitrogen even at room temperature, and can be handled in an air atmosphere for several minutes. A longer permissible time is desirable under the conditions of industrially manufacturing equipment using an adsorbent and vacuum insulation.

  This is to prevent nitrogen adsorption capacity from being exhausted due to contact with air in the manufacturing process, resulting in poor adsorption capacity for maintaining the equipment performance that is originally required, and preventing performance deterioration and performance variations from increasing. It is. In order to further improve the performance of vacuum insulation materials, etc., it was a major challenge to use adsorbents more stably and efficiently in order to maintain the degree of vacuum inside equipment and vacuum insulation materials. .

  The height of activity of the gas adsorbent, that is, the time until the adsorption is saturated when left in the atmosphere varies depending on the form and material specifications. For example, if the gas adsorbent is in the form of pellets, it will not saturate even if left in the atmosphere for a relatively long time. On the other hand, if the gas adsorbent is in powder form, the specific surface area becomes large, so that even if it is left in the atmosphere for a short time, it is saturated.

  Therefore, in the configuration of Patent Document 1, when a gas adsorbent having a higher activity than Ba-Li is used, the time in which the gas adsorbent can be contacted with the atmosphere may be very short.

  Further, in the configuration of Patent Document 2, in the vacuum heat insulating box, the gas that has entered from the outside and the gas generated from the inside are reduced again through the valve. The resistance is large and it takes a very long time to decompress.

  In Patent Document 2, open-celled hard polyurethane foam is used as a core material. However, if the powder has a finer particle size such as dry silica, the exhaust resistance is further increased, and the pressure can be reduced easily. Therefore, a considerable time is required for the decompression step.

  For this improvement, it is preferable to have a chemical vacuum pump function that encloses the gas adsorbing material, performs a rough pressure reduction by the vacuum pump, and adsorbs the remaining air by the gas adsorbing material.

  For that purpose, the handling time in air is long, the core material has high exhaust resistance such as dry silica, and it has high activity and excellent handling properties to remove residual air from large vacuum insulation materials. Gas adsorption device is required.

  It is conceivable that conventional Ba-Li has a large amount of use, has low activity as a chemical vacuum pump, and takes time.

  The present invention solves the above-described conventional problems by providing a gas adsorption device that can be stored in the atmosphere for a long time even when the highly active gas adsorbent is in powder form, and highly active gas adsorption. It aims at providing the vacuum heat insulation box using a device.

  In order to achieve the above object, the gas adsorption device of the present invention comprises a gas adsorbent, a jacket material made of a gas barrier material that encloses the gas adsorbent and shields it from an external gas, and a thermoplastic material that is softened. A control member that prevents a through-hole from being formed in the outer jacket material and prevents the gas adsorbent from adsorbing an external gas, and the control member that has not been softened does not pass through the control member. With respect to the control member that has continued to apply a piercing force to the control member with a certain level of force and has been softened by a predetermined temperature rise, the control member is deformed by the piercing force and penetrates the control member and the jacket material. And a member for opening a hole.

  By enclosing the gas adsorbent with a jacket material made of a gas barrier material, the gas adsorbent can be handled without touching the outside air, so that it is possible to suppress performance degradation and to easily change the shape and size.

  Furthermore, since communication between the gas adsorbing material and the outside is performed by heating, it is not necessary to control factors other than temperature when developing gas adsorbing ability, and productivity can be improved. In addition, even when it is impossible to apply force from the outside of the vacuum heat insulating box body, it is possible to select the timing at which the adsorptive capacity is developed, for example, after the roughing of the box decompression section is completed. .

  In order to make effective use of such adsorption devices, functions can be achieved by evacuating the interior, such as vacuum insulation casings and vacuum insulation jacket materials such as thermos bottles, vacuum insulation materials, etc. Any vacuum device can be used.

  The gas adsorbing device of the present invention can be easily changed in shape and size by enclosing the gas adsorbing material from the outside with a jacket material made of a gas barrier material, and further, storage of retort food, etc. It is also used at low cost. Moreover, even a highly active gas adsorbent can be handled easily and for a long time in the outside air.

  Furthermore, a member that opens a through hole that generates a through hole in the jacket material is controlled by a control member made of a thermoplastic material, and the control member is softened by heating, whereby a through hole is generated in the jacket material. Even if it is a box that cannot be stabbed from the outside, the adsorption ability can be expressed at a desired timing.

  In addition, by using such a gas adsorption device as a chemical vacuum pump to a vacuum heat insulation box using a core material with a fine particle size with high exhaust resistance, the time required for evacuation can be shortened and outside air can enter. Even if the gas adsorbent is adsorbed, the degree of vacuum can be maintained, and high reliability can be obtained.

  The invention of the gas adsorption device according to claim 1 of the present invention comprises a gas adsorbent, a jacket material made of a gas barrier material that encloses the gas adsorbent and shields it from external gas, and a thermoplastic material that is softened. A control member that prevents a through-hole from being formed in the outer jacket material and prevents the gas adsorbent from adsorbing an external gas, and the control member that has not been softened does not pass through the control member. For the control (with) material that has continued to apply a piercing force to the control member with a certain level of force and has been softened at a predetermined temperature rise, the control member is deformed by the piercing force, and the control member and the outer cover are deformed. And a member for making a through hole in the material.

The higher the activity of the gas adsorbent and the greater the specific surface area, the more severe the handling conditions. That is, in order to maintain the activity of the gas adsorbent, the time in which the gas adsorbent can be contacted is shortened, and the contactable pressure is also reduced. Therefore, such a gas adsorbing material also has a problem of deterioration when it is installed in a vacuum apparatus in addition to storage. However, by enclosing it with a jacket material made of a gas barrier material, it can be handled without touching the outside air, so that it is possible to suppress a decrease in vitality, and the shape and size can be easily changed, and it is inexpensive.

  Furthermore, since communication between the gas adsorbing material and the outside is performed by heating, it is not necessary to control factors other than temperature when developing gas adsorbing ability, and productivity can be improved. Moreover, even if it is impossible to apply a force from the outside of the vacuum heat insulating box, the adsorption ability can be expressed.

  As an example of vacuum equipment, when applying a gas adsorbent to a vacuum heat insulating material, a chamber with a core material and a gas adsorbent inserted into a gas barrier jacket material is placed in a thousand chamber, the chamber is decompressed, and the outer After decompressing the inside of the material, the opening of the material is sealed.

  At this time, the pressure in the chamber is reduced by a vacuum pump. In the normal pressure region, that is, before vacuum sealing, the pressure can be reduced by either a pump or an adsorbent. On the other hand, in the low pressure region, that is, inside the jacket material after vacuum sealing, there is a gas that could not be decompressed by the vacuum pump, a gas that penetrates through the jacket material after vacuum sealing, and a gas generated from the core material, These can be adsorbed only with a gas adsorbent. Therefore, in order to fully demonstrate the capability of the gas adsorbent inside the outer jacket material after vacuum sealing, it is necessary to communicate with the outside after vacuum sealing.

  Since the vacuum equipment is sealed after the gas adsorbing material is installed inside, it is difficult to switch the gas adsorbing device by applying a force directly from the outside. Therefore, it is desirable to switch the gas adsorbent by remote control. As a means for switching by remote operation, a method of releasing the sealing of the gas adsorption device by changing the temperature of the gas adsorption device is effective.

  After the vacuum apparatus is sealed, the temperature of the internal gas adsorption device is also changed by changing the temperature, and switching is possible by reaching a predetermined temperature. As a method of switching due to temperature change, a member that applies a piercing force in advance, and a piercing force is applied to the jacket material containing the gas adsorbent with a jacket material made of a gas barrier material, and at that time, the piercing force is applied. A member for generating a through-hole such as a needle is provided in the member, and a control member that is made of, for example, resin and prevents the through-hole from being formed before softening is provided at the end of the member. Then, although the strength of the control member is superior in a low temperature state, the control member does not penetrate, but the control member is softened and deformed by the temperature rise of the vacuum equipment, so that a through hole can also be generated in the jacket material.

  At this time, since the vacuum equipment itself is highly heat insulating, the gas adsorption device is closer to the heating surface, the penetration time can be shortened, and the penetration means and the penetration control means are particularly The one closer to the heating surface can shorten the penetration time.

  By using the method as described above, the gas adsorbing device can be deformed without applying external force, the sealing property can be released, and the adsorbing ability can be exhibited.

The gas barrier material preferably has a gas permeability of 10 ⁴ [cm ³ / m ² · day · atm] or less, and more desirably 10 ³ [cm ³ / m ² · day · atm] or less. It will be.

  Furthermore, it is preferable to use a laminate film obtained by laminating a metal foil such as aluminum on a resin film such as polyethylene terephthalate or polyethylene. Metal foil is very high in gas barrier property and highly reliable. Moreover, the barrier property which was excellent also in the vapor deposition layer instead of foil is produced.

  The vapor deposited layer has lower thermal conductivity, so the solid thermal conductivity of the device itself can be reduced. On the other hand, since the gas barrier property is applied to the foil, the foil is better for long-term or harsh storage. Is preferred. Moreover, it has a high gas barrier property even in inorganic vapor deposition such as silica instead of metal.

  A thermoplastic material is more easily deformed by the same piercing force due to an increase in temperature. Examples of materials that satisfy these conditions include metals, glass, and resins.

  The member that applies the piercing force is a member that constantly applies a force to the jacket material without applying an external force by being set in a predetermined situation. These means apply a force to the jacket material by the law of reaction by applying deformation to the elastic body and hindering the movement of the deformation to return by the jacket material.

  For example, it corresponds to enclosing the compression spring in a compressed state in a jacket material having a finite area. By trying to lengthen the compression, a stab force is applied to the jacket material, and a stab force is applied to the control member and the jacket material.

  The softening here means that the strength of the control member is lowered and a through hole can be generated. Therefore, the softening temperature of glass, the softening temperature of resin, and the like may be different from the normally defined temperatures. Accordingly, the softening temperature is not unique depending on the substance, and is determined in consideration of the piercing force applied to the control member. That is, when the piercing force applied to the control member is large, even if the strength of the control member is large, it can be deformed to generate a through-hole, so the softening temperature is lower than the normally defined temperature. When the force applied to the penetration control means is small, the softening temperature of the control member is close to the normally defined softening temperature.

  Moreover, a sharp metal is good for the member which opens a through-hole. It is desirable that the temperature at which the through hole is formed in the jacket material be as low as possible in order to reduce the temperature applied to the vacuum equipment. For this reason, it is desirable to increase the force applied per unit area of the jacket material so that a through hole is generated even if the degree of softening of the jacket material is small.

  Each time the force applied to the unit area of the jacket material is increased, the contact area between the member that applies the stab force to the jacket material and the jacket material is reduced. In order to reduce the contact area between the member that applies the piercing force to the outer jacket material and the outer jacket material, a portion where the member that applies the piercing force to the outer jacket material contacts the outer jacket material may be formed into a sharp shape.

  At this time, when the softening temperature of the portion where the member that applies the piercing force to the covering material is in contact with the covering material is lower than or equal to the softening temperature of the covering material, the sharpness is reduced at the softening temperature of the covering material. It will be lost. Accordingly, it is required that the softening temperature of the portion where the member that applies the piercing force to the jacket material comes into contact with the jacket material is significantly higher than the softening temperature of the jacket material. Since metal has a remarkably higher softening temperature than resin, the above conditions can be satisfied.

  As a metal, it is desirable to use what is normally used as a structure, such as iron, copper, and aluminum. In addition, an alloy that can be used as a structure, such as stainless steel and duralumin, may be used instead of a single metal.

Further, according to the present invention , when the member that opens the through-hole is applied to the control member in the softened state, a portion where the control member and the outer jacket material are deformed is limited to the outer jacket material. A support that prevents the container from being deformed so as not to form a through hole is provided so as to contact or be close to the inner surface of a portion of the jacket material that is to be prevented from being deformed by a member that opens the through hole. is there.

  Even if the penetration control means is softened due to an increase in temperature, if the gas adsorbing material inside the jacket material moves or deforms due to the piercing force, there is a possibility that the pressure by the piercing force does not penetrate. In order to ensure penetration, a strength that does not cause deformation due to the piercing force previously applied to the penetrating portion is required, and the gas adsorbent must be communicated. Therefore, if the inside of the jacket material is depressurized, the gas adsorbent is compressed by the atmospheric pressure and becomes a support, whereby the strength is maintained and a through hole can be easily generated.

According to a second aspect of the present invention, the control member is installed between the jacket material and the member that opens the through hole.

  The member for opening the through hole is not limited to one, but as a means for applying a piercing force in advance and softening the control member due to temperature rise to generate a through hole, for example, a penetrating means such as a needle, Applying a stab force to the outer cover material, press the outer cover material, install a control member such as resin between the needle and the outer cover material, and heat the means to soften and penetrate the resin, or For example, a member that pulls or blocks with a resinous thread so as to balance the piercing force, the thread expands with heating and opens a through hole, etc. can be considered, but between the jacket material and the member that opens the through hole Since it can be created easily and can be reliably controlled, the yield is high. In addition, it is possible to make the device thin by being closely attached, and the size can be reduced.

According to a third aspect of the present invention, the control member is made of a thermoplastic resin.

  The vacuum equipment maintains its shape against atmospheric pressure due to the strength of the components. For this reason, if a part of vacuum equipment becomes higher than a softening temperature, it will deform | transform by atmospheric pressure. Therefore, it is essential that the softening temperature of the control member is lower than the softening temperature of the components of the vacuum equipment.

  Thermoplastic resins have a remarkably lower softening temperature than thermoplastic materials such as metal and glass, and therefore it is easy for the softening temperature to be lower than components of vacuum equipment. Therefore, the freedom degree of the structure of a vacuum equipment can be improved by making a control member into a thermoplastic resin.

According to a fourth aspect of the present invention, the member that opens the through-hole applies a piercing force to the jacket material by an elastic force to generate the through-hole.

  In order for the member that applies the piercing force to the outer jacket material to continue to apply the piercing force to the outer jacket material, a part of it is made of an elastic body, and the outer shell is applied by the action of applying the piercing force and releasing the piercing force. The phenomenon of applying force to the material can be used. For example, the object is sandwiched between clips. Since the elastic body is a spring, the force applied to the jacket material can be easily controlled.

  As another example of the method of applying the piercing force with the elastic body, the piercing force is continuously applied to the outer jacket material by pressing the spring member in a contracted state, so that the temperature of the outer jacket material rises. As a result, the thermoplastic material of the penetration control means is softened, and a through hole is formed in the jacket material.

In the invention according to claim 5, the gas adsorbent is a ZSM-5 type zeolite subjected to copper ion exchange.

Since the ZSM-5 type zeolite subjected to copper ion exchange is very highly active, contact with air is impossible even slightly, and by increasing the temperature of the jacket material after installation in a vacuum device,
It is possible to prevent contact with air during installation in a vacuum device. In addition, ZSM-5 type zeolite with exchanged copper ions has higher air adsorption per unit weight at room temperature than other zeolites and metal adsorbents, and can absorb a large amount of air in a small amount, saving space. Can also be made.

Invention of Claim 6 is a vacuum heat insulating material provided with the core material, the jacket material which has gas-barrier property, and the gas adsorption device as described in any one of Claims 1-5. The core material and the gas adsorption device are decompressed and sealed inside the jacket material.

  By using the gas adsorption device according to any one of claims 1 to 6, it is possible to adsorb air entering from the outside for a longer period of time, so as to degrade the air adsorbent, A highly reliable vacuum heat insulating material can be configured.

The invention according to claim 7 is characterized in that a moisture adsorbing material is provided inside the jacket material.

  Many air adsorbents have reduced air adsorption capacity by absorbing moisture. Moisture has a property of being easily adsorbed due to its high polarity, and there is moisture remaining after being adsorbed on the jacket material and the core material in addition to those which enter from the outside air. As a result, the air adsorbing ability decreases. In order to suppress a decrease in air adsorbing capacity and to provide a more reliable vacuum heat insulating material, a moisture adsorbing material is provided inside the jacket material.

The invention according to claim 8 includes the gas adsorption device according to any one of claims 1 to 5 in a space between the outer box and the inner box .

  A vacuum heat insulating box is a container whose outer casing material is made of resin, metal, glass or the like and is not plastically deformed by a piercing force that is normally handled at room temperature, and has a box shape. Moreover, in such a vacuum heat insulation box, even if an air adsorption device is installed inside the box, it is difficult to exert an air adsorbing ability by applying a piercing force from the outside. Therefore, if it is a gas adsorption device as described in any one of Claims 1-6, even if it is a vacuum heat insulation box, it can express a vacuum adsorption capability and it can improve reliability. It is.

The invention according to claim 9 further includes a moisture adsorbent in the space.

  Many air adsorbents have reduced air adsorption capacity by absorbing moisture. Moisture has a property of being easily adsorbed due to its high polarity, and there is moisture remaining after adsorbing to the box and the core material, in addition to those that enter from outside air. As a result, the air adsorbing ability decreases. In order to suppress a decrease in air adsorbing capacity and to provide a more reliable vacuum heat insulating material, a moisture adsorbing material is provided inside the jacket material.

  In particular, the process of opening one side or one side and reducing the pressure as in the case of a vacuum heat insulating material is difficult. After that, the pressure is reduced from an exhaust port communicating with the space in advance, and after the pressure is reduced, it is sealed and sealed. In this case, since the cross-sectional area of the exhaust port is smaller than the space volume, the exhaust force is reduced, and the adsorbed moisture tends to remain. Therefore, by providing the moisture adsorbing material, a decrease in air adsorbing ability can be suppressed and reliability can be improved.

In the invention described in claim 10, the core material is dry silica having an average primary particle diameter of 100 nm or less.

  Dry silica having an average primary particle size of 100 nm or less is excellent as a core material of a vacuum heat insulating material, but has a problem of high exhaust resistance. If the pressure is reduced by opening one side or one side like a vacuum heat insulating material, there is no big problem, but if pressure is reduced from the exhaust port like a vacuum heat insulating box, it takes a considerable time for pressure reduction. For this reason, productivity is deteriorated.

  Therefore, after roughly evacuating the space, the exhaust port is sealed, and an air adsorption device is developed, so that it can be decompressed while being left by a chemical vacuum pump that decompresses with an air adsorbent. The process can be shortened.

  DESCRIPTION OF EMBODIMENTS Hereinafter, embodiments of the present invention will be described with reference to the drawings. The same reference numerals are given to the same configurations as those of the conventional example or the embodiments described above, and detailed descriptions thereof will be omitted. The present invention is not limited to the embodiments.

(Embodiment 1)
FIG. 1 is a cross-sectional view of a gas adsorption device according to Embodiment 1 of the present invention. Moreover, FIG. 2 is sectional drawing of the vacuum heat insulating material in Embodiment 1 of this invention. Moreover, FIG. 3 is sectional drawing of the vacuum heat insulation box in Embodiment 1 of this invention.

  In FIG. 1, a gas adsorbing device 1 is a member that inserts a gas adsorbing material 2 into a jacket material 3 made of a gas barrier material, depressurizes and seals and encloses it, and applies a clip-like piercing force to the jacket material 3. The piercing force is applied by 4. Further, a member 5 that opens a sharp through-hole is provided between the member 4 that applies the piercing force and the jacket material 3, and further, between the member 5 that opens the through-hole and the jacket material 3. Is provided with a control member 6 made of a thermoplastic material.

  In FIG. 2, the vacuum heat insulating material 7 is obtained by sealing the gas adsorbing device 1, the core material 8, and the moisture adsorbing material 9 into an outer cover material 10 having a gas barrier property and then sealing under reduced pressure.

  In FIG. 3, the vacuum heat insulating box 11 includes an outer box 12, an inner box 13, and a core material 14 each made of a gas barrier material, and the core material 14 is placed in a space 15 between the outer box 12 and the inner box 13. Installed, the outer box 12 and the inner box 13 are joined to seal the space 15, installed in the outer box 12, the air in the space 5 is exhausted from the exhaust port 16 that communicates the space 15 and the outside air, and after decompression The vacuum insulation box 1 is configured by sealing the exhaust port 16. The inner box 3 has an opening 17 for taking in and out hot water and cold water. Further, the gas adsorbing device 1 and the moisture adsorbing material 9 are installed in the space 15.

  The operation and action of the gas adsorption device, the vacuum heat insulating material, and the vacuum heat insulating box configured as described above will be described.

  When the gas adsorbing device 1 is heated, the control member 6 is softened, and the member 5 that pierces the through hole by the member 4 that applies the piercing force is always subjected to the piercing force. Furthermore, the gas adsorbent 2 communicates with the outside air and develops gas adsorbing ability by forming a through-hole in the jacket material 3.

In the case of adsorbing air, the gas adsorbent 2 is preferable because the ZSM-5 type zeolite subjected to copper ion exchange has a large amount of air adsorption per unit weight and can adsorb inert and hardly adsorbed nitrogen.

  Moreover, if it is for adsorbing carbon dioxide, an alkaline compound such as sodium hydroxide or potassium hydroxide is preferred.

  As the covering material 3, an AL foil laminated film and an AL vapor-deposited laminated film are preferable since they have high gas barrier properties, and even if a metal foil other than AL is used, the effect does not change. Further, a film material on which an inorganic material such as silica, diamond-like carbon, or alumina is deposited and coated may be used.

  Moreover, although gas barrier property is inferior to metal foil or inorganic coating, gas barrier resin, such as ethylene-vinyl alcohol copolymer, polyvinylidene chloride, polyacrylonitrile, MX nylon, and polyvinyl alcohol, may be used.

  In addition, the member that opens the through hole is preferably a sharp shape, and the strength is based on the correlation between the piercing force applied by the member 4 that applies the piercing force and the strength of the control member 6 and the jacket material 3, but the material is metal. The hard thing like this is preferable. Resin may be used, but the control member 6 and the jacket material 3 need to be strong enough to cause a through hole.

  The member 4 for applying the piercing force is not limited, but it is simple and preferable to use an elastic principle such as a clip or a spring. Moreover, the member which adds the piercing force by magnetic force can adjust the timing which applies a piercing force, and is preferable.

  The control member 6 is not particularly limited as long as it is a cold thermoplastic material, but is preferably a metal, glass, or resin, and more preferably a resin material has a low thermal softening temperature. Moreover, although the control member 6 may be inside the jacket material 3, it is preferable to install between the member 5 which opens a through-hole, and the jacket material 3 from handling property and reliability.

  The heat insulating performance of the vacuum heat insulating material 7 decreases due to the air and water remaining inside the core material 8 and the outer cover material 10 inside and the air and water that penetrates over time and enters the vacuum heat insulating material 7. By heating the gas, the gas adsorption ability of the gas adsorption device 1 is exhibited, the air component is adsorbed, the degree of vacuum is maintained, and the heat insulation performance can be maintained. In addition, since moisture reduces the air adsorption capacity of the gas adsorption device 1, the moisture adsorption material 9 is separately provided and adsorbed by the moisture adsorption material 9, thereby preventing the air adsorption capacity of the gas adsorption device 1 from being lowered.

  Moreover, after creating the vacuum heat insulating material 7, it is left still, the water | moisture content which remains in the core material 8 and the jacket material 10 is adsorb | sucked first, it heats, and the air adsorption ability of the gas adsorption device 1 is expressed. However, it has more gas adsorption capacity and is preferable.

  The moisture adsorbing material 9 is preferably chemically adsorbed like calcium oxide or calcium chloride.

  The outer covering material 10 is preferable because the AL foil laminated film and the AL vapor-deposited laminated film are excellent in gas barrier properties as in the outer covering material 3 of the gas adsorption device 1, and the effect is not changed even if it is a metal foil other than AL. . Further, a film material on which an inorganic material such as silica, diamond-like carbon, or alumina is deposited and coated may be used. Moreover, although gas barrier property is inferior to metal foil or inorganic coating, gas barrier resin, such as ethylene-vinyl alcohol copolymer, polyvinylidene chloride, polyacrylonitrile, MX nylon, and polyvinyl alcohol, may be used.

Moreover, although the core material 8 is not limited, inorganic powders, such as glass wool fiber and a silica powder, are preferable.

  The vacuum heat insulating box 11 is provided with a core material 14 between the outer box 12 and the inner box 13, sealed, then depressurized from the exhaust port 16, and sealed after being depressurized. Thereafter, the moisture adsorbing material 9 that develops the adsorbing ability of the gas adsorbing device 1 by heating and maintains the degree of vacuum prevents a decrease in the adsorbing ability of the gas adsorbing device 1 in the same manner as the vacuum heat insulating material 7.

  In particular, in the case of a shape such as the vacuum heat insulation box 11, since the cross-sectional area of the exhaust port 16 is small, the exhaust resistance is high and decompression takes time. Although the exhaust port may be enlarged, sealing becomes difficult in that case. Further, when the core material 8 is a fine material having an average primary particle diameter of T00 nm or less, such as dry silica, the heat insulation performance is excellent, and particularly the pressure dependency is high, but the exhaust resistance is high and the pressure reduction is very frequent. Takes more man-hours.

  Therefore, in such a case, the pressure from the exhaust port 16 is reduced to roughing of about 1333 Pa, which can be reduced in a short time, and after sealing, it is heated to develop the adsorption capacity of the gas adsorption device 1 and adsorb the remaining air. It is preferable to use as a chemical vacuum pump to reduce man-hours. When acting also as a chemical vacuum pump, it is necessary to increase the amount of the gas adsorbent 2.

  The outer box 12 and the inner box 13 need to maintain the shape of the box, and are preferably molded bodies of resin or metal. In the case of metal, since it is excellent in gas barrier property and durability, it is more preferable in terms of reliability.

  In the case of resin, since it is excellent in moldability, it is preferable when shape flexibility is required. When using a resin material, it is preferable to improve gas barrier properties by insert molding of metal foil, metal plating, metal vapor deposition, or vapor deposition / coating of inorganic materials such as silica, diamond-like carbon, and alumina.

  Further, the shape is not limited, but a shape having an opening 17 as shown in FIG. 3 is preferable when used for heat insulation. Moreover, you may use as an irregular-shaped vacuum heat insulating material with an unevenness | corrugation.

Example 1
Example 1 is a specific example of the gas adsorption device and the vacuum heat insulating material of the first embodiment. The same components as those of the first embodiment are denoted by the same reference numerals, and detailed description thereof is omitted.

  In the gas adsorption device 1 of Example 1, a powdery copper ion exchanged ZSM-5 type zeolite was used as the gas adsorbent 2. As the jacket material 3 of the gas adsorption device 1, a laminate film in which a nylon having a thickness of 15 μm, a nylon having a thickness of 25 μm, an aluminum foil having a thickness of 6 μm, and a low-density polyethylene film having a thickness of 50 μm were sequentially laminated.

  The shape of the jacket material 3 is a rectangle having a length of 50 mm and a width of 100 mm. The member 4 for applying the piercing force to the outer cover material 3 is a stainless steel clip, and a stainless steel needle which is a member 5 for making a through hole is attached to a portion to be sandwiched and contacted, and the needle tip has a diameter of 5 mm and a thickness. A polyethylene terephthalate piece having a thickness of 1 mm is attached as the control member 6 so that the control member 6 (polyethylene terephthalate piece) and the jacket material 3 are in contact with each other. A gas adsorbent 2 is contained inside the jacket material 3.

The vacuum heat insulating material 7 was produced using the gas adsorption device 1 comprised as mentioned above. As the core material 8 of the vacuum heat insulating material 7, a glass fiber aggregate having a plate shape was used. Cover material 1 of the air insulation 7
0 is a resin laminate film, which is laminated in the order of 15 μm thick nylon, 25 μm thick nylon, 6 μm thick aluminum, and 50 μm thick low density polyethylene film.

  The core material 8, the gas adsorbing device 1, and the moisture adsorbing material 9 encapsulating calcium oxide in a non-woven fabric are inserted into the envelope material 10 that has been sealed in three directions in advance, and is placed in a vacuum chamber and decompressed to 100 Pa. And sealed. At room temperature, the polyethylene terephthalate piece that is the control member 6 of the gas adsorbing device 1 has sufficient strength, so that even when atmospheric pressure is applied, the deformation is small and no through hole is generated.

  When the vacuum heat insulating material 7 is heated to 70 ° C. and left to stand for 2 hours, the heated control member 6 of the gas adsorption device 1 is softened, and the needle that is the member 5 that opens the through-hole applies the piercing force. Since it is pressed, the control member 6 becomes soft and cannot withstand this force, and a through hole is generated. As a result, the gas adsorbing material 2 in the gas adsorbing device 1 and the space in the vacuum heat insulating material 7 communicate with each other and can be adsorbed.

  When the pressure inside the vacuum heat insulating material 7 is measured, it is 5 Pa, and it can be seen that the internal pressure of the vacuum heat insulating material 7 is reduced as a result of the adsorption by the gas adsorbent 2.

  Further, when the internal pressure after the vacuum heat insulating material 7 is stored in the room temperature atmosphere for one month is again measured, it is 5 Pa, and it can be seen that the gas entering through the jacket material 10 is adsorbed.

(Example 2)
Example 2 is a specific example of the gas adsorption device and the vacuum heat insulation box of the first embodiment. The same components as those of the first embodiment are denoted by the same reference numerals, and detailed description thereof is omitted.

  In the gas adsorption device 1 of Example 2, a powdery copper ion exchanged ZSM-5 type zeolite was used as the gas adsorbent 2. As the jacket material 3 of the gas adsorption device 1, a laminate film in which a nylon having a thickness of 15 μm, a nylon having a thickness of 25 μm, an aluminum foil having a thickness of 6 μm, and a low-density polyethylene film having a thickness of 50 μm were sequentially laminated. The shape of the jacket material 3 is a rectangle having a length of 50 mm and a width of 100 mm.

  The member 4 for applying the piercing force to the outer cover material 3 is a stainless steel clip, and a stainless steel needle which is a member 5 for making a through hole is attached to a portion to be sandwiched and contacted, and the needle tip has a diameter of 5 mm and a thickness. A polyethylene terephthalate piece having a thickness of 1 mm is attached as the control member 6 so that the control member 6 (polyethylene terephthalate piece) and the jacket material 3 are in contact with each other. A gas adsorbent 2 is contained inside the jacket material 3.

  The vacuum heat insulation box 11 was produced using the gas adsorption device 1 comprised as mentioned above. As the core material 14 of the vacuum heat insulation box 11, a mixture of 95% by weight of dry silica and 5% by weight of carbon black was used. Stainless steel was used for the outer box 12 and the inner box 13, the space 15 had a thickness of 15 mm, the gas adsorbing device 1 and a moisture adsorbing material 9 made of calcium oxide were installed in advance, and then the core material 14 was filled. The outer box 12 and the inner box 13 were joined by TIG welding.

After sealing, the pressure was reduced to 1000 Pa by reducing the pressure from the exhaust port 16 previously attached to the outer box 12 for about 30 minutes. And after leaving at 40 degrees for 1 hour to remove residual moisture, the vacuum heat insulation box is heated to 70 ° C., and left for 2 hours, the control member 6 of the heated gas adsorption device 1 is softened, Since the needle, which is the member 5 that opens the through hole, is pressed by the member 4 that applies the piercing force, the control member 6 becomes soft and cannot withstand this force, and a through hole is generated. As a result, the gas adsorbent 2 in the gas adsorbing device 1 and the space 15 in the vacuum heat insulating box 11 communicate with each other and can be adsorbed.

  Then, when left at room temperature for 48 hours and measuring the internal pressure, it is 5 Pa, and it can be seen that the internal pressure of the vacuum heat insulating box 11 has decreased as a result of adsorption by the gas adsorbent 2.

  Furthermore, it can be seen that the internal pressure after storing the vacuum heat insulating box 11 in the atmosphere for 1 month is 5 Pa, and adsorbs the gas that enters through the outer box 12 and the inner box 13.

  Since the gas adsorbing device according to the present invention can handle a highly active gas adsorbing material without deteriorating under atmospheric pressure, the inside is evacuated like a vacuum heat insulating material or a vacuum heat insulating box. Therefore, it can be applied to a vacuum device that exhibits its function.

Sectional drawing of the gas adsorption device in Embodiment 1 of this invention Sectional drawing of the vacuum heat insulating material in Embodiment 1 of this invention Sectional drawing of the vacuum heat insulation box in Embodiment 1 of this invention

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Gas adsorption device 2 Gas adsorption material 3 Outer coating material 4 Member which applies piercing force 5 Member which opens through-hole 6 Control member 7 Vacuum heat insulating material 8 Core material 9 Moisture adsorption material 10 Outer material 11 Vacuum heat insulation box 12 Outer box 13 Inner box 14 Core material 15 Space 16 Exhaust port

Claims (10)

A gas adsorbing material, a jacket material made of a gas barrier material that encloses the gas adsorbing material and shields it from an external gas, and is made of a thermoplastic material to prevent a through-hole from being formed in the jacket material until softened. The control member that prevents the adsorbent from adsorbing external gas and the control member before softening continues to apply a piercing force to the control member with a force that does not penetrate the control member. A gas adsorbing device having a member that opens the through hole in the control member and the jacket material by deforming the control member with the piercing force with respect to the control member that has been softened due to the temperature rise. The gas adsorbing device according to claim 1, wherein the control member is installed between the jacket material and a member that opens the through hole. The gas adsorption device according to claim 1, wherein the control member is made of a thermoplastic resin. The gas adsorbing device according to any one of claims 1 to 3, wherein a member that opens the through-hole applies a piercing force to the jacket material by an elastic force to generate a through-hole. The gas adsorption device according to any one of claims 1 to 4, wherein the gas adsorbent is ZSM-5 type zeolite subjected to copper ion exchange. 6. The outer member in which the gas adsorbing device according to any one of claims 1 to 5 further includes a core material and a jacket material that has a gas barrier property and encloses the core material. A vacuum heat insulating material that is provided inside a covering material, and in which the covering material that encloses the core material by reducing the pressure of the core material and the gas adsorption device is sealed. The vacuum heat insulating material according to claim 6, further comprising a moisture adsorbing material inside the jacket material containing the core material. A vacuum heat insulating box comprising a box made of an outer box and an inner box, and the gas adsorption device according to any one of claims 1 to 5 in a space between the outer box and the inner box. . The vacuum heat insulating box according to claim 8, further comprising a moisture adsorbing material in the space between the outer box and the inner box. The vacuum heat insulating box according to claim 8 or 9 , wherein the core material is dry silica having an average primary particle diameter of 100 nm or less.