JP4464765B2 - Flocculant for contaminated water or contaminated water purification treatment - Google Patents

Description

The present invention is, for example, polluted water or polluted water that is dropped in polluted water or contaminated water generated in an industrial waste treatment plant, etc., and purifies the water quality by aggregating polluted water or contaminated water contained in the polluted water or polluted water Concerning the improvement of flocculants for water purification treatment, in particular, flocs such as pollutants are formed and settled in a short time, and heavy metals and some halogens, metalloid elements, etc. contained in the water to be treated are not eluted. in particular it relates.

  In general, there are organic flocculants and inorganic flocculants as flocculants for purifying water quality by aggregating polluted water or pollutants in water to be treated such as polluted water to form a floc. Among these, organic coagulants are mainly composed of organic polymers (see, for example, Patent Document 1). However, a large amount of organic matter remains in the treated water after treatment, and the treated waste water is discharged. Then, there is a possibility that new contamination is generated due to oxidation. At the same time, if wastewater containing a large amount of organic substances is discharged, there is a problem that the natural microbial environment is destroyed and the natural purification action of the microorganisms by decomposition and removal of organic sludge is greatly hindered.

  In addition, when treating the polluted water or contaminated water, the organic flocculant greatly fluctuates the pH value of the water to be treated, so that the neutralization tank neutralizes the pH value with chemicals in the treatment process. It is indispensable to install. For this reason, there is a problem that the number of steps of the purification treatment is increased and the treatment is troublesome, and in particular, it takes a considerable time for the pH value to reach a neutral range due to the addition of chemicals. As a result, it was necessary to sufficiently retain the waste water after the purification treatment in the neutralization tank before the discharge, and there was a problem that the water to be treated could not be continuously discharged and treated.

  Not only that, the organic flocculant tends to increase the viscosity of both the water and floc after purification, so the water does not drain well, and even after various dehydration steps, the floc is sufficiently dehydrated. There was a problem that the volume could not be reduced and the amount of sludge cake finally recovered could not be reduced sufficiently.

  On the other hand, inorganic coagulants mainly use cohesive force due to positively charged ions of aluminum ions and iron ions (see, for example, Patent Document 2), but cohesive force compared to organic coagulants. Tend to be weak. For this reason, in various subsequent dehydration processes, flocs were destroyed, and there was a problem that suspended particulate matter was remixed in the treated water. In addition, since inorganic flocculants generally lower the pH value of the water to be treated, as in the case of organic systems, it is still possible to solve the problem of requiring a lot of labor and time due to the installation of a neutralization tank. There wasn't.

  In particular, regardless of whether organic or inorganic, the conventional flocculants, even if the cohesive force is improved, flocs and water generated by the coagulation are not sufficiently separated, so the sludge is concentrated in the subsequent dehydration process. It was necessary to further dehydrate after passing through the step of collecting and finally collect the contaminated components as a dehydrated cake. That is, there is a problem that a very expensive and complicated dehydration system has to be used, which requires labor and high cost for the treatment, and takes time for the dehydration treatment.

Furthermore, with conventional flocculants, whether organic or inorganic, flocculants themselves are not oily, heavy metals such as mercury, cadmium, lead, hexavalent chromium, arsenic, halogen elements such as fluorine and metals. The metal intermediate element metalloid boron and the like could not be sufficiently removed, and in order to remove these oils and heavy metals, it was necessary to separately undergo various chemicals and processing steps.
JP 2001-129511 A JP 7-299500 A

  In view of the above-mentioned problems, the problem to be solved by the present invention is that it has a strong cohesive force and can remove heavy metals and the like, while not adversely affecting the natural environment, and continuously polluting in a short time. An object of the present invention is to provide a comprehensively excellent coagulant for purifying contaminated water or contaminated water, which can treat water or contaminated water and can easily and efficiently dewater sludge.

In the present invention, as a first means for solving the above-mentioned problems, a pH adjuster, a specific gravity increasing agent, and a chelating effect accelerator are mixed in a main agent composed of aluminum sulfate, calcium sulfate and sodium carbonate. A flocculating agent for purifying contaminated water or contaminated water , wherein the chelating effect accelerator comprises iron, sodium thiosulfate, chitosan, citric acid. It is to provide.

As a second means for solving the above-mentioned problems, the present invention provides the first solution, wherein the pH adjuster neutralizes the pH value of the water to be treated. The present invention provides a flocculant for water purification treatment.

According to the present invention, as a third means for solving the above-mentioned problems, in the first or second solving means, the pH adjusting agent is cement, or contaminated water or contaminated water. A flocculant for purification treatment is provided.

According to the present invention, as a fourth means for solving the above problems, in any one of the first to third solving means, the specific gravity increasing agent is one or both of cement and magnetic material. The coagulant | flocculant for contaminated water or the contaminated water purification process characterized by these is provided.

The present invention provides, as a fifth means for solving the above-mentioned problems, a polluted water or a coagulant for purifying contaminated water, wherein the magnetic material is ferrite in the fourth solution means. To do.

The present invention provides, as a sixth means for solving the above problems, a main agent composed of aluminum sulfate, calcium sulfate and sodium carbonate, cement powder, ferrite powder, iron, sodium thiosulfate , chitosan, citric acid. The present invention provides a polluted water or a flocculant for purifying contaminated water, characterized by being added to and mixed with a chelating effect accelerator composed of the above powder.

As a seventh means for solving the above-mentioned problems, the present invention provides a main agent comprising 20 to 50 parts by weight of aluminum sulfate, 10 to 40 parts by weight of calcium sulfate, and 5 to 20 parts by weight of sodium carbonate. 5-20 parts by weight of cement powder, 5-10 parts by weight of magnetic material powder such as ferrite powder, 5-20 parts by weight of iron powder, 5-20 parts by weight of sodium thiosulfate , and 1-10 parts by weight of chitosan Further, the present invention provides a polluted water or a flocculant for purification treatment of contaminated water, characterized by containing 5 to 20 parts by weight of citric acid.

The present invention provides, as an eighth means for solving the above-described problems, in the seventh solution means, a magnetic material powder of aluminum sulfate, calcium sulfate, sodium carbonate, cement powder, ferrite powder, iron powder, thiosulfuric acid Disclosed is a polluted water or a flocculant for purifying contaminated water, wherein sodium , chitosan and citric acid are uniformly dispersed and mixed.

  According to the present invention, as described above, since inorganic natural minerals such as aluminum sulfate, calcium sulfate, sodium carbonate and the like are used as the main raw material, organic matter does not remain in the treated wastewater and is discharged into the natural world. Since microbial environment is not destroyed, it is possible to realize environmental conservation, while calcium sulfate and sodium carbonate are opposed to each other with a large potential difference with respect to the potential of aluminum sulfate. There is an advantage that a cohesive force generated by collision of substances having distant potentials can generate a strong cohesive force to efficiently aggregate pollutants and the like. In addition, as a result, it is possible to efficiently treat water to be treated such as polluted water only by adding a small amount of a flocculant.

  According to the present invention, as described above, since the pH adjusting agent such as cement is added, the pH value of the water to be treated is not lowered by aluminum sulfate, which is the main factor for lowering the pH value of the water to be treated. Since the pH value is neutralized, there is no need to separately perform a neutralization treatment with a chemical or the like in a neutralization tank before and after the purification treatment with a flocculant, and a simple treatment can be achieved by reducing costs and processes. Of course, because it is not necessary to retain the treated water for a long time for neutralization, there is an actual benefit that the treated water can be purified efficiently by continuously treating the contaminated water and contaminated water. is there.

  In addition, according to the present invention, since cement is added, the cement strengthens flocs generated by aggregation, so that the flocs are not destroyed and re-mixed in moisture in the subsequent dehydration process or the like. In addition to improving the agglomeration efficiency, this cement constitutes the core of the floc and promotes the sedimentation speed of the floc generated by the high specific gravity of the cement itself, so that the floc and moisture can be sufficiently separated. Therefore, there is an advantage that it can be sufficiently dehydrated without going through a separate sludge concentration step and the processing steps and processing equipment can be greatly simplified.

  According to the present invention, since magnetic materials such as ferrite are mixed as described above, innumerable magnetic powders incorporated into the cross-linked flocs at the time of aggregation performed by the cross-linking effect of aluminum multivalent ions. The bodies attract each other with a weak magnetic force (the fine magnetic force of the ferrite powder itself) and can be made more flocked, and the high specific gravity of magnetic materials such as ferrite dramatically increases the specific gravity of the entire flock. In addition, there is an actual benefit that the floc sedimentation speed generated by agglomeration can be remarkably accelerated and the separation of floc and moisture can be further promoted without attracting by magnetic force.

  Furthermore, according to the present invention, as described above, since an inorganic natural mineral is used as a main raw material, unlike an organic flocculant, the floc viscosity does not increase, so that water drainage is good and water content is low. Since flocs can be obtained, the dehydration time can be greatly shortened, and at the same time, there is an advantage that sludge can be sufficiently reduced by simple treatment, especially in combination with the above-mentioned sedimentation promotion. There is a real advantage that a high dehydration effect can be obtained.

In addition, according to the present invention, as described above, a chelating effect accelerator comprising iron, sodium thiosulfate , chitosan, and citric acid powder is further mixed, so that the oil and metal contained in the water to be treated are mixed. Chitosan and iron powder, which have a high adsorption capacity for elements, reacts and adsorbs oil and metal elements to citric acid and promotes detoxification by sodium thiosulfate, thus removing oil, heavy metal elements, some halogens and metalloids In addition, the metal elements that have been converted into oxides become base oxides, which are chemically stable with strong covalent bonds made of ions, and are incorporated so as to cover these elements. Components that did not elute and could not be treated with conventional flocculants such as oils, heavy metals, halogen element fluorine and metalloid element boron , There is a practical benefits which can be removed only by flocculation treatment.

  The embodiment of the present invention will be described in detail. The coagulant for contaminated water or contaminated water purification treatment of the present invention comprises a main agent composed of aluminum sulfate, calcium sulfate and sodium carbonate, a pH adjuster, a specific gravity increasing agent, It consists of a chelating effect promoter.

  The main agent consisting of aluminum sulfate, calcium sulfate, and sodium carbonate is an inorganic natural mineral that is the central component of the action of aggregating contaminants in the treated water and removing the contaminants from the treated water. Organic matter does not remain in the treated wastewater, and the microbial environment is not destroyed even if the wastewater is discharged into the natural world, which is suitable for realizing environmental conservation.

  In addition, unlike organic flocculants, the viscosity of flocs after treatment does not increase, so flocs with good water drainage and low moisture content can be obtained, and at the same time the dehydration time can be greatly reduced. The sludge can be sufficiently reduced by a simple treatment, which is preferable.

  In this case, the use of aluminum sulfate, calcium sulfate, and sodium carbonate as the main agent is such that calcium sulfate and sodium carbonate are opposed to each other with a large potential difference with respect to the potential of aluminum sulfate. This is because a strong cohesive force can be generated by the coagulation effect generated by collision between substances having different potentials. Therefore, it is possible to overcome the weakness of the cohesive force that was also a weak point of the conventional inorganic coagulant while maintaining the high environmental conservation property of the conventional inorganic coagulant. For this reason, it is possible to efficiently agglomerate pollutants and the like, and to treat treated water such as polluted water efficiently only by adding a small amount of aggregating agent, thereby reducing costs. .

  The pH adjuster neutralizes the pH value of the water to be treated which tends to be lowered by aluminum sulfate, which is a component of the main agent. Specifically, cement can be used. In this case, the pH adjuster depends on the original pH value of the water to be treated, but at least the pH value of the water to be treated is a neutral range that does not affect the natural world. It is desirable to adjust the component and the component ratio (part by weight with respect to the whole flocculant) so as to be stable in the range of 9.0.

  Since the pH value of the water to be treated can be adjusted to a neutral range simultaneously with the coagulation treatment, this pH adjuster is separately neutralized with a chemical or the like in a neutralization tank before and after the purification treatment with the coagulant. It is no longer necessary, and it is possible to carry out simple treatment by reducing costs and processes, and it is not necessary to retain the treated water for a long time for neutralization. In addition, it can be purified efficiently by continuously treating contaminated water. That is, the present invention maintains the high environmental conservation of conventional inorganic flocculants, and at the same time, changes (decreases) in pH value, which are also weak points of conventional flocculants (whether inorganic or organic). It is a flocculant that can solve the problem.

  In addition, when cement is used as the pH adjuster, the cement strengthens flocs generated by agglomeration, so that the flocs are not destroyed and remixed in moisture in the subsequent dehydration process, and the agglomeration efficiency. Since this cement constitutes the core of the floc and promotes the sedimentation speed of the floc generated by the high specific gravity of the cement itself, the floc and moisture can be sufficiently separated. That is, cement not only plays a role as a pH adjuster (neutralizing agent) that prevents a decrease in the pH value of water to be treated, but also acts as a specific gravity increasing agent described below, that is, strengthens flocs generated by aggregation. In addition, it can also serve to promote the sedimentation speed of floc.

  The specific gravity increasing agent promotes the coarsening of flocs generated by agglomeration and the speed of sedimentation of flocs, and promotes separation of moisture and flocs. Specifically, a magnetic material such as ferrite can be used. it can. When this agglomeration is performed by the cross-linking effect of the aluminum multivalent ions, innumerable magnetic powders incorporated in the cross-linked floc attract each other by a weak magnetic force (a micro magnetic force of the ferrite powder itself), and more The flocs can be made huge, and the high specific gravity of magnetic materials such as ferrite (high specific gravity compared to flocs) dramatically increases the specific gravity of the entire flocs. It is possible to dramatically accelerate the sedimentation speed of the floc generated by the above, and further promote the separation of the floc and moisture.

  In this way, the floc and moisture can be sufficiently separated by the specific gravity increasing agent, so that it can be sufficiently dehydrated without going through a sludge concentration step later, and sludge that has been conventionally performed after agglomeration. Since the same volume reduction rate can be ensured by the steps of concentration and dehydration only by the dehydration step, the treatment steps and treatment facilities can be greatly simplified.

  Note that the specific gravity increasing agent is not limited to ferrite as long as it is a magnetic material, and other magnetic materials can be used as long as they can exhibit the same industry capabilities. Cement can also be used as a specific gravity increasing agent alone or with a magnetic material.

The chelating effect accelerator is specifically composed of iron, sodium thiosulfate , chitosan, and citric acid, and these are removed by removing the oil and metal elements and chelating effect that covers these components. This prevents the re-elution of the components into water and removes components that could not be treated with these conventional flocculants from the water to be treated.

  Specifically, this chelating effect accelerator is a sodium thiosulfate that adsorbs oil and metal elements by reacting with citric acid with chitosan and iron powder having a high adsorption capacity for oil and metal elements contained in the water to be treated. It promotes the detoxification action by, and removes oils, heavy metal elements, some halogens and metalloids, and the metal elements that have become oxides become base oxides, resulting in strong covalent bonds made by ions. Because they are chemically stable and covered so as to cover these elements, they do not elute again and are treated with conventional flocculants such as oils, heavy metals, halogens such as fluorine and metalloid elements such as boron. Components that could not be removed can be removed only by agglomeration treatment.

As described above, the flocculant of the present invention comprises, as components, a main agent composed of aluminum sulfate, calcium sulfate and sodium carbonate, cement powder, ferrite powder, iron, sodium thiosulfate , chitosan, and citric acid powder. It can be said that the best mode is carried out by adding and mixing a chelating effect accelerator.

Next, the preferred proportions of these components will be described. Aluminum sulfate is 20 to 50 parts by weight (parts by weight relative to the whole flocculant: the same in any case of the present invention), calcium sulfate is 10 to 40 parts by weight, 5 to 20 parts by weight of cement powder, 5 to 10 parts by weight of magnetic material powder such as ferrite powder, 5 to 20 parts by weight of iron powder, and sodium thiosulfate It can be adjusted by blending 5 to 20 parts by weight, 1 to 10 parts by weight of chitosan, and 5 to 20 parts by weight of citric acid.

  In this case, in particular, the aluminum sulfate which is the center of the aggregating action is used in the above-mentioned mixing ratio. When the aluminum sulfate is 20 parts by weight or less, the aggregating force is reduced. This is because it has been confirmed.

  In this case, it is desirable to uniformly disperse and mix the respective components in order to appropriately exhibit the public use of the respective components. Further, in actual production, after forming a main agent composed of aluminum sulfate, calcium sulfate, and sodium carbonate, cement powder, ferrite powder, and chelating effect accelerator are added to and mixed with this, thereby the present invention. However, it is also possible to produce all flocculants by mixing them simultaneously.

  Next, several examples for confirming the efficacy of various components included in the present invention will be described. Specifically, four types of flocculants are set, and each flocculant is added in an amount of 20 ppm to 1 liter of solution having a particle size of 1,000 ppm silt (water to be treated). It was confirmed. As these flocculants, the Example of this invention and the comparative example for confirming the effect were set. Specifically, as Comparative Example 1, a flocculant composed only of aluminum sulfate (A agent), and as Comparative Example 2, a flocculant obtained by mixing aluminum sulfate with calcium sulfate and sodium carbonate (B agent: equivalent to the main agent in the present invention) ) As an Example 1 of the present invention, an aggregating agent (C agent) obtained by adding cement powder to the above B agent (main agent of the present invention), and as an Example 2 of the present invention, the above C agent is further added as a magnetic material. The flocculant (D agent) which added the ferrite powder was set.

  In this case, the D agent which is Example 2 was uniformly mixed with 40 parts by weight of aluminum sulfate, 30 parts by weight of calcium sulfate, 10 parts by weight of sodium carbonate, 10 parts by weight of cement powder, and 10 parts by weight of ferrite powder. Produced by dispersing and mixing.

  Then, these four examples were added to the water to be treated, and the state (diameter) of flocs generated by aggregation and the clarity of the supernatant water after aggregation were confirmed and evaluated. The results are shown in Table 1 below.

  As can be seen from Table 1, with the flocculant (agent A) consisting only of aluminum sulfate, although the flocculant effect itself is recognized, the generated floc is very fine and the floc cannot be made sufficiently large. Was confirmed. Further, it was confirmed that fine particles were also suspended in the supernatant water, and sufficient sedimentation speed and strong cohesive force could not be obtained.

  In this regard, the B agent of Comparative Example 2 (corresponding to the main agent of the present invention) in which calcium sulfate and sodium carbonate are also added to the A agent which is Comparative Example 1, has a larger floc diameter and a cohesive force than the A agent. It turned out to be expensive. From this, it was confirmed that the cohesive force could be increased by adding calcium sulfate and sodium carbonate to aluminum sulfate. This is because calcium sulfate and sodium carbonate are opposed to each other with a large potential difference with respect to the potential of aluminum sulfate, so that the coagulation effect generated by collision between a base and an acid or substances having numerically separated potentials is strong. It is considered that the cohesive force could be generated. However, in the supernatant water, although a small amount of suspended fine particles were still confirmed, it was also confirmed that the agent B as Comparative Example 2 has a small specific gravity of the generated floc and does not give sufficient results for the sedimentation speed. did it.

  Then, when paying attention to C agent which is Example 1 of this invention next, compared with B agent, both the state of the flock and the clarity of the supernatant water were favorable. This is considered to be a result of cement forming the floc nucleus to form a strong floc and at the same time increasing the specific gravity of the floc to accelerate the sedimentation speed. Therefore, the cement powder as the pH adjuster can also serve as a specific gravity increasing agent, and it is not always necessary to add another magnetic material as the specific gravity increasing agent, and further to the B agent, the pH adjusting agent. It was also found that good results that are satisfactory to some extent can be obtained by adding cement powder that also functions as a specific gravity increasing agent.

  Furthermore, when the experimental result was confirmed about the D agent which is Example 2 which added the ferrite powder which is a magnetic material as a specific gravity increasing agent to the C agent, the floc is sufficiently large and the floc is enlarged with a strong cohesive force. At the same time, it was confirmed that the specific gravity of the floc was further increased and the clarification of the supernatant water was significantly improved as compared with the C agent, and very good results were obtained. From this, according to the present invention, sufficient cohesive force and sedimentation speed can be obtained, and in particular, the D agent which is Example 2 is an optimal example for increasing the cohesive force and sedimentation speed. Can do.

The present invention provides various water purification treatments, specifically industrial wastewater discharged from various factories such as food processing factories, metal processing factories, plating factories, chemical factories, tunnel wastewaters, excavations, It can be applied to wastewater associated with civil engineering work such as pile driving and quarrying, estimation of fishery washing, fish processing, pig farms, poultry farms, etc., and purification of wastewater associated with livestock production. Because it is not given, it can be applied to water purification of rivers, lakes, etc., and can be used for environmental conservation.

Claims (8)

The main agent consisting of aluminum sulfate and calcium and sodium carbonate sulfate, and pH adjusting agent, a specific gravity increasing agent, a polluted water or polluted water purification treatment flocculant comprising a mixture of a chelating effect enhancer, the chelating The effect promoter is composed of iron, sodium thiosulfate, chitosan, and citric acid. The polluted water or polluted water purifying flocculant according to claim 1 , wherein the pH adjuster neutralizes the pH value of the water to be treated. Agent. The polluted water or contaminated water purifying flocculant according to claim 1 or 2 , wherein the pH adjusting agent is cement. Agent. 4. The polluted water or the flocculant for purifying contaminated water according to claim 1 , wherein the specific gravity increasing agent is one or both of cement and a magnetic material. Flocculant for purification treatment of contaminated water or contaminated water. 5. The polluted water or polluted water purifying flocculant according to claim 4 , wherein the magnetic material is ferrite. It is characterized by adding and mixing cement powder, ferrite powder, and chelating effect accelerator consisting of iron, sodium thiosulfate , chitosan, and citric acid powder into the main agent consisting of aluminum sulfate, calcium sulfate and sodium carbonate. A flocculant for purifying contaminated water or contaminated water. In the main agent composed of 20 to 50 parts by weight of aluminum sulfate, 10 to 40 parts by weight of calcium sulfate, and 5 to 20 parts by weight of sodium carbonate, 5 to 20 parts by weight of cement powder, and magnetic material powder such as ferrite powder. 5 to 10 parts by weight, 5 to 20 parts by weight of iron powder, 5 to 20 parts by weight of sodium thiosulfate , 1 to 10 parts by weight of chitosan, and 5 to 20 parts by weight of citric acid Flocculant for purification treatment of contaminated water or contaminated water. The coagulant for contaminated water or contaminated water purification treatment according to claim 7 , comprising aluminum sulfate, calcium sulfate, sodium carbonate, cement powder, ferrite powder magnetic material powder, iron powder, sodium thiosulfate , chitosan, and quencher. A coagulant for treating contaminated water or contaminated water, wherein the acid is uniformly dispersed and mixed.