JP2546269B2 - Tocopheroic acid emulsion - Google Patents
Tocopheroic acid emulsionInfo
- Publication number
- JP2546269B2 JP2546269B2 JP62127696A JP12769687A JP2546269B2 JP 2546269 B2 JP2546269 B2 JP 2546269B2 JP 62127696 A JP62127696 A JP 62127696A JP 12769687 A JP12769687 A JP 12769687A JP 2546269 B2 JP2546269 B2 JP 2546269B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- tocopherol
- gum
- acidic
- acid monoglyceride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は酸性においても優れた安定性を示すトコフェ
ロール酸性乳化物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application] The present invention relates to an acidic emulsion of tocopherol which exhibits excellent stability even in acidic conditions.
トコフェロールを食品などの抗酸化剤として用いる場
合に、Ｌ−アスコルビン酸等の還元剤や、クエン酸、フ
ィチン酸等のキレート剤などの酸性成分を併用すると相
乗作用を示すことは良く知られている。一方、トコフェ
ロールを多水分系の食品などに利用する場合には、トコ
フェロールをO/W型の乳化物として水への分散性を高め
て用いられている。ところが、このとき上記の理由で相
乗剤として酸性成分を併用した製剤を作ると、必然的に
酸性となり、安定な乳化物が得にくくなる。It is well known that when tocopherol is used as an antioxidant for foods and the like, a reducing agent such as L-ascorbic acid and an acidic component such as a chelating agent such as citric acid and phytic acid exhibit a synergistic effect. . On the other hand, when the tocopherol is used for foods of high water content, etc., the tocopherol is used as an O / W type emulsion with high dispersibility in water. However, at this time, if a formulation containing an acidic component as a synergist is prepared for the above reason, the formulation is necessarily acidic, and it becomes difficult to obtain a stable emulsion.
従来はトコフェロールの酸性乳化物のための乳化剤と
して、ポリグリセリン脂肪酸エステルを水相に添加した
例が多かった。Conventionally, in many cases, polyglycerin fatty acid ester was added to the aqueous phase as an emulsifier for an acidic emulsion of tocopherol.
しかしながら、このような従来のポリグリセリン脂肪
酸エステルを乳化剤とするトコフェロールの酸性乳化物
においては、長期間乳化の破壊を防止することは困難で
あった。またポリグリセリン特有の風味や、展着性の低
さを嫌って、ポリグリセリン脂肪酸エステルを使用しな
かったり、添加量を減少すると、乳化自体が不可能にな
ってしまうという問題点があった。However, in such an acidic emulsion of tocopherol using a conventional polyglycerin fatty acid ester as an emulsifier, it was difficult to prevent the destruction of the emulsion for a long period of time. Further, there is a problem that emulsification itself becomes impossible if the polyglycerin fatty acid ester is not used or the addition amount is decreased because the flavor peculiar to polyglycerin and the low spreadability are disliked.
本発明の目的は、上記従来の問題点を解決し、ポリグ
リセリン無添加で、かつ安定なトコフェロール酸性乳化
物を得ることである。An object of the present invention is to solve the above-mentioned conventional problems and obtain a stable tocopherol acidic emulsion without addition of polyglycerin.
本発明は、トコフェロール１〜60重量％、酸性成分0.
1〜10重量％、有機酸モノグリセリド0.01〜10重量％、
ガム質0.01〜20重量％およびサポニン0.01〜２重量％を
含有することを特徴とするトコフェロール酸性乳化物で
ある。The present invention comprises 1 to 60% by weight of tocopherol and an acidic component of 0.
1-10% by weight, organic acid monoglyceride 0.01-10% by weight,
A tocopherol acidic emulsion containing 0.01 to 20% by weight of gum and 0.01 to 2% by weight of saponin.
本発明に用いるトコフェロールは、α，β，γ，δの
いずれの型のトコフェロールでも使用できるが、天然濃
縮トコフェロール、およびこれを油脂で希釈したものが
特に好ましい。これらのトコフェロールはいずれも市販
されており、単独でまたは適宜組合せて用いることがで
きる。トコフェロールの配合量は１〜60重量％とする。
１重量％未満ではトコフェロールの効果を発揮すること
が難しくなり、60重量％を越えると乳化が非常に困難と
なる。The tocopherol used in the present invention may be any type of α, β, γ, δ tocopherols, but natural concentrated tocopherols and those diluted with fats and oils are particularly preferable. All of these tocopherols are commercially available and can be used alone or in appropriate combination. The compounding amount of tocopherol is 1 to 60% by weight.
If it is less than 1% by weight, it becomes difficult to exert the effect of tocopherol, and if it exceeds 60% by weight, emulsification becomes very difficult.
本発明に用いる酸性成分としては、Ｌ−アスコルビン
酸、クエン酸、フィチン酸、没食子酸など、従来から用
いられているものが使用でき、これらは単独でまたは適
宜組合せて用いることができる。酸性成分の配合量は0.
1〜10重量％とする。0.1重量％未満では相乗作用が小さ
く、また10重量％を越えると乳化が困難となる。As the acidic component used in the present invention, those conventionally used such as L-ascorbic acid, citric acid, phytic acid, and gallic acid can be used, and these can be used alone or in an appropriate combination. The amount of acidic components is 0.
1 to 10% by weight. If it is less than 0.1% by weight, the synergistic effect is small, and if it exceeds 10% by weight, emulsification becomes difficult.
本発明に用いる有機酸モノグリセリドは、酢酸モノグ
リセリド、クエン酸モノグリセリド、ジアセチル酒石酸
モノグリセリド、コハク酸モノグリセリド、乳酸モノグ
リセリドなどであって、一般の市販のものが使用でき、
これらを単独でまたは適宜組合せて用いることができ
る。有機酸モノグリセリドの配合量は0.01〜10重量％と
する。0.01重量％未満では乳化の安定が難しく、10重量
％を越えるとコスト面で問題がでてくる。The organic acid monoglyceride used in the present invention is acetic acid monoglyceride, citric acid monoglyceride, diacetyl tartaric acid monoglyceride, succinic acid monoglyceride, lactic acid monoglyceride, etc.
These can be used alone or in appropriate combination. The blending amount of organic acid monoglyceride is 0.01 to 10% by weight. If it is less than 0.01% by weight, it is difficult to stabilize the emulsification, and if it exceeds 10% by weight, there is a problem in cost.
本発明に用いるガム質としては、アラビアゴム、キサ
ンタンガム、タマリンドガム、ローカストビーンガム、
グアーガム、カラギーナン、プルランなどであって、一
般の市販のものが使用でき、これらを単独でまたは適宜
組合せて用いることができるが、特に酸に強いアラビア
ガム、キサンタンガム、タマリンドガムなどが望まし
い。ガム質の配合量は0.01〜20重量％とする。0.01重量
％未満では乳化の安定に対して効果がなく、20重量％を
越えると乳化物の流動性が悪くなる。The gum used in the present invention, gum arabic, xanthan gum, tamarind gum, locust bean gum,
Common commercial products such as guar gum, carrageenan, and pullulan can be used, and these can be used alone or in an appropriate combination. Particularly, acid-resistant gum arabic, xanthan gum, tamarind gum and the like are preferable. The gum content is 0.01 to 20% by weight. If it is less than 0.01% by weight, it has no effect on the stability of emulsion, and if it exceeds 20% by weight, the fluidity of the emulsion is deteriorated.
本発明では上記の各成分に加えて、サポニンを0.01〜
２重量％添加する。このサポニンは乳化安定性を改善す
るとともに、生理活性成分として食品等の生理活性を高
める。In the present invention, in addition to the above components, saponin is added in an amount of 0.01-
Add 2% by weight. This saponin improves the emulsion stability and enhances the physiological activity of foods as a physiologically active ingredient.
本発明で用いるサポニンとしては、茶サポニン、大豆
サポニン、キラヤサポニンなど一般の市販のものがある
が、特にキラヤサポニンが好ましい。サポニンの配合量
は0.01〜２重量％とするが、0.01重量％未満では乳化が
困難であり、２重量％を越えるとコストの点で問題があ
る。As the saponin used in the present invention, there are general commercially available ones such as tea saponin, soybean saponin, and quillaja saponin, and quillaja saponin is particularly preferable. The content of saponin is 0.01 to 2% by weight, but if it is less than 0.01% by weight, emulsification is difficult, and if it exceeds 2% by weight, there is a problem in cost.
本発明のトコフェロール酸性乳化物は、上記各成分な
らびに必要により配合される他の添加剤を水に加えて乳
化したものである。水の量は10〜95重量％程度である。
乳化物は水の量に応じてO/W型またはW/O型になるが、一
般的にはO/W型の乳化物として多水分系の食品などに用
いられる。The tocopherol acidic emulsion of the present invention is obtained by emulsifying each of the above components and other additives optionally blended with water. The amount of water is about 10 to 95% by weight.
The emulsion becomes an O / W type or a W / O type depending on the amount of water, but it is generally used as an O / W type emulsion for high-moisture foods and the like.
本発明のトコフェロール酸性乳化物を調製するには、
水相に酸性成分、ガム質、サポニンなどの水溶性成分
を、また油相にトコフェロール、有機酸モノグリセリド
などの油溶性成分を加えて両者を混合し、乳化すること
により簡単に調製することができる。乳化するには高速
撹拌機、ホモジナイザーなど、通常の乳化手段を用いて
混合乳化すれば良い。To prepare the tocopherol acidic emulsion of the present invention,
It can be easily prepared by adding an acidic component, a gum substance, a water-soluble component such as saponin to the aqueous phase, and adding an oil-soluble component such as tocopherol or an organic acid monoglyceride to the oil phase, mixing the two and emulsifying them. . In order to emulsify, the mixed emulsification may be performed by using an ordinary emulsifying means such as a high speed stirrer and a homogenizer.
こうして得られたトコフェロール酸性乳化物は食品、
飼料等の抗酸化剤、その他の用途に用いられる。The tocopherol acidic emulsion thus obtained is a food,
Used for antioxidants such as feed, and other purposes.
本発明のトコフェロール酸性乳化物は、有機酸モノグ
リセリド、ガム質およびサポニンを用いることにより、
乳化状態が良好な乳化物が得られ、長期間保存後も乳化
が安定で、水への分散性も優れており、食品などの風味
を害することがないとともに、生理活性を高めることが
できる。Tocopherol acidic emulsion of the present invention, by using an organic acid monoglyceride, gum and saponin,
An emulsion having a good emulsified state can be obtained, the emulsion is stable even after long-term storage, and the dispersibility in water is excellent, the flavor of foods and the like is not impaired, and the physiological activity can be enhanced.
次に実施例および比較例により本発明を説明する。 Next, the present invention will be described with reference to Examples and Comparative Examples.
実施例１〜３、比較例１〜７ 第１表に示す配合割合を用いて、ホモジナイザーによ
り乳化物を調製し、これをガラス製のメスシリンダー中
に入れて室温中に放置した。そして10日後、20日後、30
日後の乳化安定性の良否を観察し、結果を第１表に示し
た。Examples 1 to 3 and Comparative Examples 1 to 7 Using the blending ratios shown in Table 1, emulsions were prepared by a homogenizer, placed in a glass graduated cylinder, and left at room temperature. And 10 days, 20 days, 30
The quality of emulsion stability after day was observed, and the results are shown in Table 1.
第１表の乳化安定性観察結果から明らかなように、本
発明のトコフェロール酸性乳化物の乳化安定性が非常に
優れていることがわかる。As is clear from the results of observation of emulsion stability shown in Table 1, the emulsion stability of the tocopherol acidic emulsion of the present invention is extremely excellent.
Claims (4)
1〜10重量％、有機酸モノグリセリド0.01〜10重量％、
ガム質0.01〜20重量％およびサポニン0.01〜２重量％を
含有することを特徴とするトコフェロール酸性乳化物。1. Tocopherol 1 to 60% by weight, acidic component 0.
1-10% by weight, organic acid monoglyceride 0.01-10% by weight,
Tocopherol acidic emulsion containing 0.01 to 20% by weight of gum and 0.01 to 2% by weight of saponin.
酸、フィチン酸または没食子酸である特許請求の範囲第
１項記載のトコフェロール酸性乳化物。2. The tocopherol acidic emulsion according to claim 1, wherein the acidic component is L-ascorbic acid, citric acid, phytic acid or gallic acid.
ド、クエン酸モノグリセリド、ジアセチル酒石酸モノグ
リセリド、コハク酸モノグリセリドまたは乳酸モノグリ
セリドである特許請求の範囲第１項または第２項記載の
トコフェロール酸性乳化物。3. The tocopherol acidic emulsion according to claim 1 or 2, wherein the organic acid monoglyceride is acetic acid monoglyceride, citric acid monoglyceride, diacetyltartaric acid monoglyceride, succinic acid monoglyceride or lactic acid monoglyceride.
タマリンドガム、ローカストビーンガム、グアーガム、
カラギーナンまたはプルランである特許請求の範囲第１
項ないし第３項のいずれかに記載のトコフェロール酸性
乳化物。4. Gum quality is gum arabic, xanthan gum,
Tamarind gum, locust bean gum, guar gum,
Claim 1 which is carrageenan or pullulan
Item 4. The tocopherol acidic emulsion according to any one of items 1 to 3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62127696A JP2546269B2 (en) | 1987-05-25 | 1987-05-25 | Tocopheroic acid emulsion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62127696A JP2546269B2 (en) | 1987-05-25 | 1987-05-25 | Tocopheroic acid emulsion |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63291979A JPS63291979A (en) | 1988-11-29 |
| JP2546269B2 true JP2546269B2 (en) | 1996-10-23 |
Family
ID=14966442
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62127696A Expired - Lifetime JP2546269B2 (en) | 1987-05-25 | 1987-05-25 | Tocopheroic acid emulsion |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2546269B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130142909A1 (en) * | 2011-12-06 | 2013-06-06 | Sensient Colors Europe Gmbh | Emulsion |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH676470A5 (en) * | 1988-02-03 | 1991-01-31 | Nestle Sa | |
| AUPM677594A0 (en) * | 1994-07-12 | 1994-08-04 | Daratech Pty Ltd | Preservation of exposed underground plant structures |
| EP2359702B1 (en) * | 2010-01-22 | 2014-06-04 | Symrise AG | Solubilization agent for solubilizing polyphenols, flavonoids and/or diterpenoid glucosides |
-
1987
- 1987-05-25 JP JP62127696A patent/JP2546269B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130142909A1 (en) * | 2011-12-06 | 2013-06-06 | Sensient Colors Europe Gmbh | Emulsion |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63291979A (en) | 1988-11-29 |
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