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JP2021049585A - Polishing pad for cutter - Google Patents

Polishing pad for cutter Download PDF

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JP2021049585A
JP2021049585A JP2019171990A JP2019171990A JP2021049585A JP 2021049585 A JP2021049585 A JP 2021049585A JP 2019171990 A JP2019171990 A JP 2019171990A JP 2019171990 A JP2019171990 A JP 2019171990A JP 2021049585 A JP2021049585 A JP 2021049585A
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polishing
polishing pad
blade
fiber
cutting tools
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JP7328529B2 (en
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堅一 小池
Kenichi Koike
小池  堅一
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Fujibo Holdins Inc
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  • Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
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Abstract

To provide a polishing pad for a cutter that can be easily handled and can obtain polishing performance equal to or better than polishing performance which a conventional polishing tool for a cutter made of a strop can obtain.SOLUTION: A polishing pad for a cutter has a disk-like shape and is provided rotatably, and polishes a cutting part of a cutter by a polishing surface formed on an outer peripheral edge thereof, which is constituted of a fiber base body constituted of hydrophobic fiber and polyurethane resin impregnated in the fiber base body, where the polyurethane resin has a flow starting temperature of 150-300°C.SELECTED DRAWING: Figure 3

Description

本発明は刃物用研磨パッドに関し、詳しくは円盤状を有するとともに回転可能に設けられ、その外周縁に形成された研磨面によって刃物の刃部を研磨する刃物用研磨パッドに関する。 The present invention relates to a polishing pad for a cutting tool, and more particularly to a polishing pad for a cutting tool which has a disk shape and is rotatably provided and polishes a blade portion of the blade by a polishing surface formed on the outer peripheral edge thereof.

従来、剃刀等の刃物を大量生産する場合、最初に帯状で送られる金属の端部を研削加工して刃部を形成し、その後形成された刃部の上下に円盤状の刃物用研磨工具を位置させ、当該刃物用研磨工具を回転させることにより刃部の仕上げ研磨(仕上げ研削)を行うようにした装置が知られている(特許文献1)。
特許文献1の刃物用研磨工具は、回転可能な回転部材の外周にらせん状に連続した状態で設けられており、上記刃物用研磨工具の外周縁の部分が刃物の刃部に接触して研磨を行う研磨面を構成している。
ここで、特許文献1における刃物研削装置では、最終的な磨き革による研磨工程が不要であるとされているものの、現在においても刃部の仕上げ研磨のために牛や馬の革からなる革砥を用いた刃物用研磨工具の需要は存在している。
Conventionally, when mass-producing blades such as shavings, first, the end of the metal sent in a strip shape is ground to form a blade, and then a disc-shaped polishing tool for blades is placed above and below the formed blade. There is known an apparatus for performing finish polishing (finish grinding) of a blade portion by positioning and rotating the blade polishing tool (Patent Document 1).
The blade polishing tool of Patent Document 1 is provided in a spirally continuous state on the outer periphery of a rotatable rotating member, and the outer peripheral edge portion of the blade polishing tool contacts the blade portion of the blade for polishing. Consists of a polished surface to perform.
Here, although it is said that the blade grinding device in Patent Document 1 does not require a final polishing process using polished leather, a leather strop made of cow or horse leather is still used for finish polishing of the blade portion. There is a demand for polishing tools for blades using.

特公昭47−9360号公報Special Publication No. 47-9360

ここで、上記革砥を用いた刃物用研磨工具の場合、当該革砥は天然物由来であることから、品質にばらつきがあり、加工する現場の温度や湿度などの環境により物性が変動しやすいという問題があることから、刃物用研磨工具として使用する場合には微妙な調整が必要とされている。
このような問題に鑑み、本発明は扱いやすく、また革砥からなる刃物用研磨工具と同等以上の研磨性能を得ることが可能な刃物用研磨パッドを提供するものとなっている。
Here, in the case of a polishing tool for cutting tools using the above-mentioned strop, since the strop is derived from a natural product, the quality varies, and the physical properties are likely to fluctuate depending on the environment such as temperature and humidity at the processing site. Therefore, delicate adjustment is required when using it as a polishing tool for cutting tools.
In view of such a problem, the present invention provides a polishing pad for cutting tools that is easy to handle and can obtain polishing performance equal to or higher than that of a polishing tool for cutting tools made of leather strop.

すなわち請求項1の発明にかかる刃物用研磨パッドは、円盤状を有するとともに回転可能に設けられ、その外周縁に形成された研磨面によって刃物の刃部を研磨する刃物用研磨パッドであって、
疎水性繊維によって構成された繊維基体と、当該繊維基体に含浸されたポリウレタン樹脂とによって構成され、
上記ポリウレタン樹脂の流動開始温度が150〜300℃であることを特徴としている。
That is, the polishing pad for a blade according to the invention of claim 1 is a polishing pad for a blade that has a disk shape and is rotatably provided and polishes the blade portion of the blade by a polishing surface formed on the outer peripheral edge thereof.
It is composed of a fiber substrate composed of hydrophobic fibers and a polyurethane resin impregnated in the fiber substrate.
The polyurethane resin is characterized in that the flow start temperature is 150 to 300 ° C.

上記請求項1の発明によれば、繊維基体に疎水性繊維を使用したことで、研磨の際に用いられる油性研磨剤との相性がよくなり、研磨面に研磨剤を保持しやすくなることから、革砥と同様以上の仕上げ研磨性能を得ることができ、また革砥よりも性質が安定しているため容易に使用することができる。
また、ポリウレタン樹脂の流動開始温度を上記範囲としたことで、刃物用研磨パッドを構成するポリウレタン樹脂が刃物の研磨を行う際の摩擦熱によって軟化することで、適度な弾性で刃物の研磨を行うことができる。
According to the invention of claim 1, by using the hydrophobic fiber for the fiber substrate, the compatibility with the oil-based abrasive used at the time of polishing is improved, and it becomes easy to hold the abrasive on the polished surface. It is possible to obtain finish polishing performance equal to or higher than that of strop, and it can be easily used because its properties are more stable than that of strop.
Further, by setting the flow start temperature of the polyurethane resin within the above range, the polyurethane resin constituting the polishing pad for the blade is softened by the frictional heat when polishing the blade, so that the blade is polished with appropriate elasticity. be able to.

剃刀製造装置の構成図Configuration diagram of razor manufacturing equipment 研磨手段の正面図Front view of polishing means 研磨手段の側面図Side view of polishing means 研磨使用後の実施例1、比較例1の刃物用研磨パッドの研磨面を200倍に拡大した電子顕微鏡による二次電子像写真Secondary electron image photograph by an electron microscope in which the polished surface of the polishing pad for cutting tools of Example 1 and Comparative Example 1 after the use of polishing is magnified 200 times. 研磨使用後の実施例1、比較例1の刃物用研磨パッドの研磨面を200倍に拡大した電子顕微鏡による反射電子像写真Photographs of reflected electrons by an electron microscope in which the polished surface of the polishing pad for cutting tools of Example 1 and Comparative Example 1 after polishing is magnified 200 times.

以下図示実施例について説明すると、図1は刃物としての剃刀刃1を製造する剃刀刃製造装置2の概略図を示し、剃刀刃製造装置2は、帯状の材料3を供給する材料供給手段4と、材料3の端部を研削して剃刀刃1の刃部1aを形成する研削手段5と、研削された刃部1aを仕上げ研磨する研磨手段6と、刃部1aの形成された材料3を所定間隔で切断して剃刀刃1とする切断手段7とを備えている。なお、このような剃刀刃製造装置2自体は従来公知であるため、以下に説明する構成を除き、詳細な説明については省略するものとする。
上記材料供給手段4には、材料としての帯状のステンレス鋼をロール状に巻回したコイルが装着されており、当該コイルから上記材料3を所定速度で送り出すようになっている。なお、上記材料3には必要に応じて予め所定位置に穴や切欠きが形成され、また焼き入れや焼きなましなどの処理も行われている。
研削手段5は、上記材料供給手段4によって送られる材料3の側部に沿った位置に複数の研削工具5a〜5cを備えており、この研削工具5a〜5cは搬送される材料3の端部の両側面を斜めに研削するように配置されている。
また研削手段5は、複数の研削工具5a〜5cを備え、これら研削工具5a〜5cが上流側から順に荒加工、中加工、仕上げ加工といった複数の過程で研削工程を行うことで、材料の端部を任意の形状の刃部1aへと研削するものとなっている。
Hereinafter, the illustrated embodiment will be described. FIG. 1 shows a schematic view of a razor blade manufacturing apparatus 2 for manufacturing a razor blade 1 as a blade, and the razor blade manufacturing apparatus 2 is a material supply means 4 for supplying a strip-shaped material 3. , The grinding means 5 for grinding the end portion of the material 3 to form the blade portion 1a of the razor blade 1, the polishing means 6 for finishing and polishing the ground blade portion 1a, and the material 3 on which the blade portion 1a is formed. It is provided with a cutting means 7 that cuts at predetermined intervals to form a razor blade 1. Since such a razor blade manufacturing apparatus 2 itself is conventionally known, detailed description thereof will be omitted except for the configuration described below.
The material supply means 4 is equipped with a coil in which a strip-shaped stainless steel as a material is wound in a roll shape, and the material 3 is sent out from the coil at a predetermined speed. If necessary, holes and notches are formed in the material 3 in advance at predetermined positions, and treatments such as quenching and annealing are also performed.
The grinding means 5 includes a plurality of grinding tools 5a to 5c at positions along the side portions of the material 3 sent by the material supply means 4, and the grinding tools 5a to 5c are end portions of the material 3 to be conveyed. It is arranged so that both sides of the surface are ground diagonally.
Further, the grinding means 5 includes a plurality of grinding tools 5a to 5c, and these grinding tools 5a to 5c perform grinding steps in a plurality of processes such as roughing, intermediate processing, and finishing in order from the upstream side, so that the edge of the material is edged. The portion is ground into a blade portion 1a having an arbitrary shape.

上記研磨手段6は、上記研削手段5の下流側に設けられており、上記研削手段5で、例えば刃部の先端から5μmにおける刃部の厚みが2μm未満、刃部先端から20μmにおける刃部の厚みが6μm前後となる程度に先鋭化された刃部1aの形状を崩さずに刃部1aの先端に生じたバリ(刃返り)を除去したり、刃部1aの表面をサブミクロンの表面粗さに滑らかに研磨することで剃刀刃1の切れ味を向上させるものとなっている。
図2は研磨手段6を正面から見た図を示しており、研磨手段6は回転可能に設けられた円筒状の回転治具11と、当該回転治具11に設けられた略円盤形状を有する複数の刃物用研磨パッド12と、刃物用研磨パッド12の外周縁に形成された研磨面12aに研磨剤を供給する図示しない研磨剤供給手段とを備えている。
図2に示すように、回転治具11は搬送される材料3の一面および他面に、当該材料3の搬送方向と平行に設けられ、材料3の両側の端部に刃部1aを形成する場合には、材料3の両側部にそれぞれ回転治具11が設けられるようになっている。
また刃物用研磨パッド12は回転治具11の軸方向に所定の間隔で複数枚設けられており、一方の回転治具11に設けられた刃物用研磨パッド12と他方の回転治具11に設けられた刃物用研磨パッド12とが干渉しないよう、偏倚した位置に交互に設けられている。
The polishing means 6 is provided on the downstream side of the grinding means 5. In the grinding means 5, for example, the thickness of the blade at 5 μm from the tip of the blade is less than 2 μm, and the thickness of the blade at 20 μm from the tip of the blade is less than 2 μm. The burr (return) generated at the tip of the blade 1a can be removed without breaking the shape of the blade 1a sharpened to a thickness of about 6 μm, and the surface of the blade 1a is roughened to a submicron surface. By polishing smoothly, the sharpness of the sword blade 1 is improved.
FIG. 2 shows a view of the polishing means 6 as viewed from the front, and the polishing means 6 has a rotatably provided cylindrical rotating jig 11 and a substantially disk shape provided on the rotating jig 11. A plurality of polishing pads 12 for cutting tools and a polishing agent supply means (not shown) for supplying polishing agents to the polishing surface 12a formed on the outer peripheral edge of the polishing pads 12 for cutting tools are provided.
As shown in FIG. 2, the rotary jig 11 is provided on one surface and the other surface of the material 3 to be transported in parallel with the transport direction of the material 3, and blade portions 1a are formed at both end portions of the material 3. In this case, rotating jigs 11 are provided on both sides of the material 3.
A plurality of polishing pads 12 for cutting tools are provided at predetermined intervals in the axial direction of the rotating jig 11, and the polishing pads 12 for cutting tools provided on one rotating jig 11 and the other rotating jig 11 are provided. The blade polishing pads 12 are alternately provided at uneven positions so as not to interfere with each other.

図3に示すように、刃物用研磨パッド12はそれぞれ所定厚さを有した略円盤状を有しており、中央には上記回転治具11に装着するための円形の貫通穴が設けられている。
そして回転治具11の刃物用研磨パッド12を軸方向に偏倚させて設けることで、上記刃部1aに対して各刃物用研磨パッド12の研磨面12aを刃の両面から接触させることが可能となっている。
また材料3の一面側に設けられた回転治具11は図示する矢印方向に反時計回りに回転し、他面側に設けられた回転治具11は図示する矢印方向に時計回りに回転し、接触した研磨面12aが刃部1aの先端部から基部に向けて移動しながら研磨を行うようになっている。
そして上記研磨剤供給手段は、各刃物用研磨パッド12の研磨面12aに油性成分を含む研磨剤を供給するようになっており、上記研磨剤としては従来公知のものを使用することができ、例えば油脂材料に酸化クロム(III)や酸化鉄、酸化セリウム、酸化ジルコニウム、酸化チタン、酸化マグネシウム、二酸化ケイ素、アルミナ、CBN、人工ダイヤモンドなどの研磨成分を混合したものを用いることができる。
As shown in FIG. 3, each of the blade polishing pads 12 has a substantially disk shape having a predetermined thickness, and a circular through hole for mounting on the rotating jig 11 is provided in the center. There is.
Then, by providing the polishing pad 12 for the blade of the rotating jig 11 so as to be offset in the axial direction, it is possible to bring the polishing surface 12a of each polishing pad 12 for the blade into contact with the blade portion 1a from both sides of the blade. It has become.
Further, the rotary jig 11 provided on one side of the material 3 rotates counterclockwise in the direction of the arrow shown, and the rotary jig 11 provided on the other side rotates clockwise in the direction of the arrow shown. Polishing is performed while the contacted polishing surface 12a moves from the tip end portion of the blade portion 1a toward the base portion.
The polishing agent supply means supplies a polishing agent containing an oily component to the polishing surface 12a of each cutting tool polishing pad 12, and a conventionally known polishing agent can be used as the polishing agent. For example, a fat or oil material mixed with abrasive components such as chromium (III) oxide, iron oxide, cerium oxide, zirconium oxide, titanium oxide, magnesium oxide, silicon dioxide, alumina, CBN, and artificial diamond can be used.

このような構成を有する研磨手段6により刃部1aの研磨を行うと、研削手段5によって形成された刃部1aのバリが除去され、また刃部1aの表面が滑らかに研磨されて、剃刀刃1の切れ味を向上させることが可能となっている。
なお、刃物用研磨パッド12の研磨面12aが刃部1aに接触する位置や角度は任意に設定可能であり、上記研削手段5と同様、複数回に分けて刃部1aの研磨を行うようにしてもよい。
また特許文献1に記載されているように、刃物用研磨パッド12の研磨面12aをらせん状に連続して設けることも可能であり、また刃物用研磨面12aの外径を異ならせて全体を円錐台形状とすることも可能である。
When the blade portion 1a is polished by the polishing means 6 having such a configuration, the burrs of the blade portion 1a formed by the grinding means 5 are removed, and the surface of the blade portion 1a is smoothly polished, so that the shaving blade It is possible to improve the sharpness of 1.
The position and angle at which the polishing surface 12a of the blade polishing pad 12 contacts the blade portion 1a can be arbitrarily set, and the blade portion 1a is polished in a plurality of times as in the case of the above-mentioned grinding means 5. You may.
Further, as described in Patent Document 1, it is also possible to continuously provide the polishing surfaces 12a of the blade polishing pad 12 in a spiral shape, and the outer diameters of the blade polishing surfaces 12a are different to form the whole. It is also possible to have a truncated cone shape.

上記切断手段7は上記材料3を等間隔に切断するようになっており、これにより剃刀刃1が得られるようになっている。
なお、研磨手段6と切断手段7との間や切断手段7の後に、刃部1aに錆防止などのコーティングを行うコーティング手段や、刃部1aに電解研磨加工を行う電解研磨手段を設けてもよい。
The cutting means 7 cuts the material 3 at equal intervals, whereby the razor blade 1 can be obtained.
Even if a coating means for coating the blade portion 1a to prevent rust or the like or an electrolytic polishing means for performing electrolytic polishing processing is provided between the polishing means 6 and the cutting means 7 or after the cutting means 7. Good.

そして、本実施例の剃刀刃製造装置2では、研磨手段6に用いる刃物用研磨パッド12として、疎水性繊維によって構成された繊維基体と、当該繊維基体に含浸されたポリウレタン樹脂とによって構成されたものを使用するものとなっている。
上記繊維基体としては、ポリエチレンテレフタレート繊維等のポリエステル繊維、ポリエチレン繊維、ポリプロピレン繊維等のポリオレフィン繊維、ナイロン6繊維、ナイロン66繊維等のポリアミド繊維などの油分とのなじみのよい親油性を有する疎水性繊維を使用することができ、これらの繊維を1種または2種以上用いることができる。
繊維は親水性繊維と疎水性繊維に大別される。親水性繊維はその分子構造中にヒドロキシル基(−OH)、アミノ基(−NH)、カルボキシル基(−COOH)、アミド基(−NHCO)の親水基を有し、水と馴染み易い反面、油と馴染みにくく、さらに、親水性繊維を刃物用研磨パッドとして使用した場合には研磨加工時の冷却水により繊維が膨潤、軟化し、繊維のコシがなくなるため刃部のバリを取り除くことができない。
一方、疎水性繊維は親水基を持たない、或いは、少量しか持たないため、疎水性・親油性を有し、ポリウレタン樹脂、および、油剤を含む研磨剤成分との馴染みがよく研磨剤を保持しやすいうえ、研磨加工時に膨潤、軟化によりコシがなくなることもない。
疎水性繊維のなかでも公定水分率の低い繊維が好ましく、公定水分率が5%未満の繊維が好ましく、3%以下の繊維がより好ましい。具体的には、特に親油性に優れ、公定水分率が1%未満の、ポリエステル繊維を使用することが望ましく、特にポリエチレンテレフタレート繊維の使用が好ましい。
刃物用研磨パッド12を構成する各繊維の繊度としては0.7〜30dtexのものを用いるのが望ましく、1.0〜20dtexのものを用いるのがより望ましく、2.0〜10dtexのものを用いるのがさらに望ましい。繊維と繊維との間に空隙を確保できるとともに不織布の剛性を高めることができ、研磨効率向上に寄与する。
繊度が30dtexより太すぎると、繊維の剛性が高くなりすぎて繊維の交絡が困難になるうえ、刃物用研磨パッド12が曲げ難く粗硬なものになってしまうので、研磨時に刃部1aへ研磨傷を生じさせる恐れがある。一方、繊度が0.7dtexに満たず細すぎると刃物用研磨パッド12が軟質化してしまい、研磨した刃部1aの先端が丸くなって切れ味が低下してしまう。
In the razor blade manufacturing apparatus 2 of the present embodiment, the blade polishing pad 12 used for the polishing means 6 is composed of a fiber substrate made of hydrophobic fibers and a polyurethane resin impregnated in the fiber substrate. It is supposed to use things.
The fiber substrate is a hydrophobic fiber having an oil-friendly property that is familiar with oils such as polyester fiber such as polyethylene terephthalate fiber, polyolefin fiber such as polyethylene fiber and polypropylene fiber, and polyamide fiber such as nylon 6 fiber and nylon 66 fiber. Can be used, and one or more of these fibers can be used.
Fibers are roughly classified into hydrophilic fibers and hydrophobic fibers. Hydrophilic fibers have hydroxyl group (-OH), amino group (-NH), carboxyl group (-COOH), and amide group (-NHCO) hydrophilic groups in their molecular structure, and while they are easily compatible with water, they are oils. Furthermore, when hydrophilic fibers are used as a polishing pad for cutting tools, the fibers swell and soften due to the cooling water during the polishing process, and the fibers lose their stiffness, so that burrs on the blade cannot be removed.
On the other hand, hydrophobic fibers do not have hydrophilic groups or have only a small amount, so they have hydrophobicity and lipophilicity, and are well compatible with polyurethane resins and abrasive components including oils, and retain the abrasives. In addition to being easy, it does not lose its elasticity due to swelling and softening during polishing.
Among the hydrophobic fibers, fibers having a low official moisture content are preferable, fibers having an official moisture content of less than 5% are preferable, and fibers having an official moisture content of 3% or less are more preferable. Specifically, it is desirable to use polyester fiber having particularly excellent lipophilicity and an official moisture content of less than 1%, and particularly preferably polyethylene terephthalate fiber.
As the fineness of each fiber constituting the polishing pad 12 for cutting tools, it is desirable to use 0.7 to 30 dtex, more preferably 1.0 to 20 dtex, and 2.0 to 10 dtex is used. Is even more desirable. It is possible to secure a gap between the fibers and increase the rigidity of the non-woven fabric, which contributes to the improvement of polishing efficiency.
If the fineness is too thicker than 30 dtex, the rigidity of the fiber becomes too high and it becomes difficult to entangle the fiber, and the polishing pad 12 for a blade becomes difficult to bend and becomes coarse and hard. May cause scratches. On the other hand, if the fineness is less than 0.7 dtex and is too thin, the blade polishing pad 12 is softened, and the tip of the polished blade portion 1a is rounded to reduce the sharpness.

各繊維の繊維長は40〜80mmの範囲であることが、不織布製造時に繊維の配向を揃えるカード機(梳綿機)の通過性や繊維間の絡合性が良好であるとともに、研磨加工時に研磨面12aが摩耗していった際に適度に繊維が脱落し、目詰まりを抑制できるため好ましい。
繊維長が40mm未満では、不織布の目付や厚みにもよるが、ニードルパンチの際に表面付近の繊維が裏面まで到達し難く、不織布シートの層間剥離が生じやすいので好ましくない。
また80mmを著しく超過する範囲では研磨時に繊維の端部が表れにくいことや、研磨加工により研磨面12aが摩耗した際に、繊維が脱離できずに目詰まりを形成し易く、刃部1aに研磨焼けが生じるため好ましくない。
When the fiber length of each fiber is in the range of 40 to 80 mm, the passability of the carding machine (carding machine) that aligns the fibers at the time of manufacturing the non-woven fabric and the entanglement between the fibers are good, and at the time of polishing. It is preferable because the fibers are appropriately removed when the polished surface 12a is worn and clogging can be suppressed.
If the fiber length is less than 40 mm, although it depends on the basis weight and thickness of the non-woven fabric, it is difficult for the fibers near the front surface to reach the back surface during needle punching, and the non-woven fabric sheet is likely to be delaminated, which is not preferable.
Further, in the range significantly exceeding 80 mm, the end portion of the fiber is unlikely to appear during polishing, and when the polished surface 12a is worn by the polishing process, the fiber cannot be detached and clogging is likely to occur, so that the blade portion 1a It is not preferable because it causes polishing burn.

次に、刃物用研磨パッド12を構成する繊維基体の構成としては、上記繊維を用いた不織布を用いることができる。不織布の作製は、フリースの形成と、フリースの繊維の絡合に分けることができる。
フリースの形成方法としては、特に制限されないが、例えば、乾式法、湿式法、スパンボンド法、メルトブローン法、エアレイド法などが挙げられる。また、フリースの繊維の絡合方法としては、特に制限されないが、例えば、ケミカルボンド法(浸漬法、スプレー法)、サーマルボンド法、ニードルパンチ法、水流交絡法(ウォータージェット法)などが挙げられる。
これら各方法は任意に組み合わせることが可能であり、例えば、乾式法によりカード機で繊維の方向性を整えたフリースを形成し、得られたフリースを複数枚積層させ、ニードルパンチにより繊維を交絡させて不織布を作製することができる。
このとき刃物用研磨パッド12として構成した際における繊維の方向は、回転治具11の軸方向に直交する面内を向くよう2次元平面上に配向されている。
このような構成とすることで、上記繊維の端部を刃物用研磨パッド12の外周縁の研磨面12aに露出させることができ、刃部1aを研磨する際に繊維の端部で刃部1aの研磨を行うことが可能となる。
また、このような構成とすることで、繊維の先端部と繊維の先端部との間に研磨剤が入り込みやすく、またこれを保持することができるため、研磨剤による効果を得やすいという効果も得られる。
Next, as the structure of the fiber substrate constituting the polishing pad 12 for cutting tools, a non-woven fabric using the above fibers can be used. The production of non-woven fabrics can be divided into fleece formation and fleece fiber entanglement.
The fleece forming method is not particularly limited, and examples thereof include a dry method, a wet method, a spunbond method, a melt blown method, and an airlaid method. The fleece fiber entanglement method is not particularly limited, and examples thereof include a chemical bond method (immersion method, spray method), a thermal bond method, a needle punch method, and a water flow entanglement method (water jet method). ..
Each of these methods can be combined arbitrarily. For example, a fleece in which the direction of the fibers is adjusted is formed by a card machine by a dry method, a plurality of the obtained fleeces are laminated, and the fibers are entangled by a needle punch. Can produce a non-woven fabric.
At this time, the direction of the fibers when configured as the polishing pad 12 for a cutting tool is oriented on a two-dimensional plane so as to face in a plane orthogonal to the axial direction of the rotating jig 11.
With such a configuration, the end portion of the fiber can be exposed to the polishing surface 12a on the outer peripheral edge of the polishing pad 12 for a blade, and when the blade portion 1a is polished, the blade portion 1a is exposed at the end portion of the fiber. It becomes possible to perform polishing.
In addition, with such a configuration, the abrasive can easily enter between the tip of the fiber and the tip of the fiber, and since this can be held, the effect of the abrasive can be easily obtained. can get.

不織布の絡合一体化方法は物理的絡合方法を用いることが望ましい。物理的絡合方法としてはニードルパンチ法の他、ウォータージェットパンチ法等が一般的であるが、本実施例ではニードルパンチ法を用いた。
ニードルパンチ法では糸を引っ掛けて絡ませる部分が複数ついた針(ニードル)又は先端がフォークのような形状になったフォーク針等を用いることができる。このときの機械の速度(ストローク数)や針密度、ストロークの距離等々の条件は、ウェブの目付や厚み等々に応じて適宜選定すればよい。
またサーマルボンド法やケミカルボンド法など、ウェブにバインダー繊維や接着剤を入れ、加圧下加熱して一体化する方法の場合、融着部が研磨面に露出した場合に刃部1aに対するあたりが強く、刃部1aに研磨焼けや研磨傷を生じさせやすいうえ、研磨加工時に繊維が脱離しづらく目詰まりが発生し、研磨焼けを起こしやすいため好ましくない。
It is desirable to use a physical entanglement method as the entanglement integration method of the non-woven fabric. As a physical entanglement method, a water jet punch method or the like is generally used in addition to the needle punch method, but in this example, the needle punch method was used.
In the needle punch method, a needle (needle) having a plurality of portions for hooking and entwining a thread, a fork needle having a tip shaped like a fork, or the like can be used. Conditions such as the speed (number of strokes), needle density, and stroke distance of the machine at this time may be appropriately selected according to the basis weight and thickness of the web.
Further, in the case of a method such as a thermal bond method or a chemical bond method in which a binder fiber or an adhesive is put in a web and heated under pressure to integrate, when the fused portion is exposed on the polished surface, the contact with the blade portion 1a is strong. In addition to being prone to polishing burns and polishing scratches on the blade portion 1a, it is not preferable because the fibers are not easily detached during the polishing process and clogging occurs, which is likely to cause polishing burns.

上記不織布に供するウェブは、公知のカード機を用いて繊維を配列させてシート状とすることにより、シートの平面に繊維が水平に配されることから、刃物用研磨パッド12の外周縁の研磨面12aに繊維端部が露出しやすいため好ましい。
一方、ウェブを作成せず、紡糸後直接不織布を得るスパンボンド法やメルトブロー法では、連続した長繊維となるため、研磨面12aに繊維端部が露出しにくく、剃刀刃研磨用パッドの基材として好ましくない。
The web used for the non-woven fabric is formed into a sheet by arranging the fibers using a known card machine, so that the fibers are horizontally arranged on the flat surface of the sheet. Therefore, the outer peripheral edge of the polishing pad 12 for cutting tools is polished. This is preferable because the fiber ends are easily exposed on the surface 12a.
On the other hand, in the spunbond method and the melt blow method in which the non-woven fabric is directly obtained after spinning without creating a web, the fiber ends are hard to be exposed on the polished surface 12a because the fibers are continuous long fibers, and the base material of the razor blade polishing pad Is not preferable.

次に、刃物用研磨パッド12を構成するポリウレタン樹脂としては、従来公知の方法で製造したものの他、市販品を使用することができる。例えばクリスボン(DIC株式会社)、サンプレン(三洋化成工業株式会社)、レザミン(大日本精化工業株式会社)があげられる。
またポリウレタン樹脂としては、流動開始温度を150〜300℃とすることが望ましく、さらには155〜250℃であることがより望ましい。流動開始温度をこのような範囲に設定することで、刃部1aの研磨をする際に摩擦によって樹脂部分を適度に軟質化させることができ、高い研磨結果を得ることができる。
これに対し、流動開始温度を150℃未満とすると、研磨加工時の発熱により樹脂成分が研磨面12aに付着しやすくなり、研磨した刃部1aの外観、及び、鋭利な先端形状が損なわれることとなり切れ味に影響を及ぼす。
一方、流動開始温度が300℃を超えると、樹脂部分が硬い状態を維持してしまい、刃部1aの形状に追従させることが難しく、刃部1aのバリを除去しにくくなる。
なお、樹脂の流動開始温度の導出方法としては、動的粘弾性測定装置を使用して得られる温度依存性曲線より、位相角の急激な上昇が起こる点の外挿点より導出することができる。なお動的粘弾性測定装置としてはRSA−III(ティー・エイ・インスツルメント・ジャパン株式会社)を使用することができる。
Next, as the polyurethane resin constituting the polishing pad 12 for cutting tools, a commercially available product can be used in addition to the one manufactured by a conventionally known method. Examples thereof include Chrisbon (DIC Corporation), Samplen (Sanyo Chemical Industries, Ltd.), and Resamine (Dainippon Fine Chemical Industries, Ltd.).
Further, as the polyurethane resin, it is desirable that the flow start temperature is 150 to 300 ° C, and more preferably 155 to 250 ° C. By setting the flow start temperature in such a range, the resin portion can be appropriately softened by friction when polishing the blade portion 1a, and a high polishing result can be obtained.
On the other hand, if the flow start temperature is less than 150 ° C., the resin component tends to adhere to the polished surface 12a due to heat generated during the polishing process, and the appearance of the polished blade portion 1a and the sharp tip shape are impaired. It affects the sharpness.
On the other hand, when the flow start temperature exceeds 300 ° C., the resin portion maintains a hard state, it is difficult to follow the shape of the blade portion 1a, and it is difficult to remove burrs on the blade portion 1a.
As a method for deriving the flow start temperature of the resin, it can be derived from the extrapolation point of the point where the phase angle sharply rises from the temperature dependence curve obtained by using the dynamic viscoelasticity measuring device. .. RSA-III (TA Instruments Japan Co., Ltd.) can be used as the dynamic viscoelasticity measuring device.

そして、上記素材を用いて作成された刃物用研磨パッド12の厚みとしては、2.0〜10.0mmの範囲とすることが好ましい。2.0mm未満では厚みが小さ過ぎ、刃物用研磨パッド12の剛性が低下し製品寿命が短くなるため好ましくない。
また10mmを超過する厚みでは、含浸処理する樹脂の付着量が不織布シートの厚み中央側と表面側で差ができやすく、研磨面12aにおいて樹脂の粗密が生じ、刃部1aに対する当たり方が不均一になるため好ましくない。
The thickness of the polishing pad 12 for cutting tools produced by using the above material is preferably in the range of 2.0 to 10.0 mm. If it is less than 2.0 mm, the thickness is too small, the rigidity of the polishing pad 12 for cutting tools is lowered, and the product life is shortened, which is not preferable.
Further, when the thickness exceeds 10 mm, the amount of the resin to be impregnated tends to be different between the center side and the surface side of the thickness of the non-woven fabric sheet, the resin becomes coarse and dense on the polished surface 12a, and the contact with the blade portion 1a is non-uniform. It is not preferable because it becomes.

上記刃物用研磨パッド12の密度は、0.3〜0.8g/cmとすることが望ましく、0.35〜0.75g/cmとすることがより望ましい。このような密度とすることで刃物用研磨パッド12の全体が適度な剛性を有し、研磨効率の向上に寄与する。
これに対し、密度が0.3g/cm未満となると刃物用研磨パッドの剛性が劣り、研磨の際に刃部1aのバリを除去する能力が低下する。また0.8g/cmを超えると構成する繊維と繊維との間の空隙が少なくなって、研磨時に研磨屑の目詰まりや研磨材の保持量が減ることから、研磨焼けが起きる原因となる。
The density of the polishing pad 12 for cutting tools is preferably 0.3 to 0.8 g / cm 3, and more preferably 0.35 to 0.75 g / cm 3. With such a density, the entire polishing pad 12 for cutting tools has appropriate rigidity, which contributes to the improvement of polishing efficiency.
On the other hand, if the density is less than 0.3 g / cm 3, the rigidity of the polishing pad for blades is inferior, and the ability to remove burrs on the blade portion 1a during polishing is reduced. Further, if it exceeds 0.8 g / cm 3 , the voids between the constituent fibers are reduced, and the clogging of the polishing debris and the holding amount of the abrasive material are reduced during polishing, which causes polishing burn. ..

刃物用研磨パッド12の厚み方向断面に対する圧縮率である断面圧縮率は、好ましくは1.0〜6.0%であり、より好ましくは1.3〜5.0%である。このような断面圧縮率とすることで刃部1aを研磨する際の研磨面12aの追従性を良好なものとすることができる。
これに対し、断面圧縮率が1.5%未満となると研磨面12aの変形量が少なくなって刃部1aに傷がつきやすくなり、5.0%を超えると変形しすぎてしまい、研磨の際に刃部1aの先端が丸くなって切れ味が低下してしまう。
なお、断面圧縮率は、実施例に記載の方法により測定することができる。また、断面圧縮率は、上記密度を調整することにより調整することができる。
The cross-sectional compression ratio, which is the compression ratio of the polishing pad 12 for cutting tools with respect to the cross section in the thickness direction, is preferably 1.0 to 6.0%, more preferably 1.3 to 5.0%. With such a cross-sectional compression ratio, the followability of the polished surface 12a when polishing the blade portion 1a can be improved.
On the other hand, if the cross-sectional compression ratio is less than 1.5%, the amount of deformation of the polished surface 12a is small and the blade portion 1a is easily scratched. At that time, the tip of the blade portion 1a is rounded and the sharpness is lowered.
The cross-sectional compression ratio can be measured by the method described in Examples. Further, the cross-sectional compressibility can be adjusted by adjusting the above density.

刃物用研磨パッド12の厚み方向断面に対する断面A硬度は、好ましくは50〜90°であり、より好ましくは53〜85°であり、さらに好ましくは55〜80°である。
断面A硬度が50°以上であることにより、刃物用研磨パッド12の寿命がより向上する傾向にある。また、断面A硬度が90°以下であることにより、研磨傷の発生を抑制し、得られる剃刀刃1の刃部1aの研磨品質がより向上する傾向にある。
なお、断面A硬度は、実施例に記載の方法により測定することができる。また、断面A硬度は、例えば、用いる樹脂の種類及び付着量により調整することができる。
The cross-sectional A hardness of the polishing pad 12 for cutting tools with respect to the cross section in the thickness direction is preferably 50 to 90 °, more preferably 53 to 85 °, and even more preferably 55 to 80 °.
When the cross-sectional A hardness is 50 ° or more, the life of the cutting tool polishing pad 12 tends to be further improved. Further, when the cross-sectional A hardness is 90 ° or less, the occurrence of polishing scratches is suppressed, and the polishing quality of the obtained blade portion 1a of the razor blade 1 tends to be further improved.
The danmen A hardness can be measured by the method described in Examples. Further, the hardness of the cross section A can be adjusted by, for example, the type of resin used and the amount of adhesion.

刃物用研磨パッド12の厚み方向断面に対する断面圧縮弾性率は、好ましくは70〜98%であり、より好ましくは75〜95%であり、さらに好ましくは80〜92%である。
断面圧縮弾性率が上記範囲内であることにより、刃物用研磨パッド12と刃部1aとの密着性がより良好となる。
なお、断面圧縮弾性率は、実施例に記載の方法により測定することができる。また、断面圧縮弾性率は、用いる樹脂の種類により調整することができる。
The cross-sectional compressive elastic modulus of the polishing pad 12 for cutting tools with respect to the cross section in the thickness direction is preferably 70 to 98%, more preferably 75 to 95%, and further preferably 80 to 92%.
When the cross-sectional compressive elastic modulus is within the above range, the adhesion between the blade polishing pad 12 and the blade portion 1a becomes better.
The cross-sectional compressive elastic modulus can be measured by the method described in Examples. Further, the cross-sectional compressive elastic modulus can be adjusted depending on the type of resin used.

刃物用研磨パッド12の全質量に占める上記繊維基体の含有量は30〜90wt%の割合とすることが望ましく、50〜85wt%の割合とすることがより望ましい。
繊維基体の含有量(樹脂溶液の繊維基体への付着量)は、繊維基体を浸漬させるポリウレタン樹脂溶液中のポリウレタン樹脂濃度を調整することや、ポリウレタン樹脂溶液に繊維基体を十分に浸漬した後、樹脂溶液が付着した繊維基体から、1対のローラ間で加圧可能なマングルローラを用いて樹脂溶液を絞り落とすことで、所望の量に調整することができる。
この範囲で繊維を含有させることで、上記ポリウレタン樹脂が付着した繊維と繊維との間に研磨剤を効率的に保持しやすく、繊維端部を研磨面12aに露出させることが可能となる。
The content of the fiber substrate in the total mass of the polishing pad 12 for cutting tools is preferably 30 to 90 wt%, and more preferably 50 to 85 wt%.
The content of the fiber substrate (the amount of the resin solution adhering to the fiber substrate) is determined after adjusting the polyurethane resin concentration in the polyurethane resin solution in which the fiber substrate is immersed or after sufficiently immersing the fiber substrate in the polyurethane resin solution. The resin solution can be adjusted to a desired amount by squeezing the resin solution from the fiber substrate to which the resin solution is attached using a mangle roller that can pressurize between a pair of rollers.
By containing the fibers in this range, it is easy to efficiently hold the abrasive between the fibers to which the polyurethane resin is attached, and the fiber ends can be exposed on the polished surface 12a.

刃物用研磨パッド12は、その厚み方向において特定の繊維密度を有する。本明細書において繊維密度とは、刃物用研磨パッド12の断面における単位面積当たりの繊維本数で表され、単位は、例えば、本/mmとすることができる。
刃物用研磨パッド12の繊維密度は、200〜2100本/mmであることが好ましく、350〜1650本/mmであることがより好ましい。
繊維密度が当該範囲であれば、研磨面12aに繊維端部が十分に露出し、繊維間の隙間に多くの研磨剤を保持することができるうえ、刃部1aに接触する接触点の数が増すことで刃部1aへの当たりがマイルドになり、研磨傷の発生が抑制される。
なお、下記実施例において、走査電子顕微鏡を用いる繊維密度の測定方法が詳しく説明されるが、実施例で採用された方法以外にも、反射型光学顕微鏡を用いた方法等、不織布の断面における一定面積の中に存在する繊維の本数を把握することによって繊維密度を算出することが可能な方法であれば、特に制限されない。
The cutting tool polishing pad 12 has a specific fiber density in the thickness direction thereof. In the present specification, the fiber density is represented by the number of fibers per unit area in the cross section of the polishing pad 12 for cutting tools, and the unit can be, for example, a line / mm 2 .
Fiber density of cutlery polishing pad 12 is preferably 200 to 2100 present / mm 2, and more preferably from 350 to 1,650 present / mm 2.
When the fiber density is within this range, the fiber ends are sufficiently exposed on the polished surface 12a, a large amount of abrasive can be held in the gaps between the fibers, and the number of contact points in contact with the blade 1a is large. By increasing the number, the contact with the blade portion 1a becomes mild, and the occurrence of polishing scratches is suppressed.
In the following examples, the method for measuring the fiber density using a scanning electron microscope will be described in detail, but in addition to the method adopted in the examples, a method using a reflective optical microscope and the like are constant in the cross section of the non-woven fabric. The method is not particularly limited as long as the fiber density can be calculated by grasping the number of fibers existing in the area.

以下、上記刃物用研磨パッド12の製造方法について説明する。
最初に、刃物用研磨パッド12を構成する上記疎水性繊維基体を準備する。上述したように疎水性繊維基体としては、ポリエステル、ポリアミド、ポリプロピレン、アクリルなどの疎水性、および、親油性を有する繊維を使用した不織布を用いることができ、従来公知の方法で得ることができる。
次に、ポリウレタン樹脂を上記疎水性繊維基体に含浸させ、含浸樹脂が乾燥したら円盤状にカットし、刃物用研磨パッド12が得られる。ここで厚みの均一化を図るため、上面視円形の面の一面側、或いは両面側をスライス処理や熱プレスしても良い。
Hereinafter, a method for manufacturing the polishing pad 12 for cutting tools will be described.
First, the hydrophobic fiber substrate constituting the polishing pad 12 for a knife is prepared. As described above, as the hydrophobic fiber substrate, a non-woven fabric using a fiber having hydrophobicity such as polyester, polyamide, polypropylene, acrylic, and lipophilicity can be used, and can be obtained by a conventionally known method.
Next, the polyurethane resin is impregnated into the hydrophobic fiber substrate, and when the impregnated resin is dried, it is cut into a disk shape to obtain a polishing pad 12 for a knife. Here, in order to make the thickness uniform, one side or both sides of a circular surface in terms of top view may be sliced or heat-pressed.

Figure 2021049585
Figure 2021049585

上記表1は、本発明にかかる実施例品1〜3と、比較に用いた比較品1、2に対して行った実験結果をまとめた表となっており、これら実施例品および比較品についてそれぞれ以下の3種類の実験を行った。 Table 1 above is a table summarizing the experimental results of Examples 1 to 3 according to the present invention and Comparative Products 1 and 2 used for comparison. The following three types of experiments were performed respectively.

実験1:研磨評価
研磨剤(ブッシュクラフト社製#12000 白)を使用しながら刃物用研磨パッド12を用いて剃刀刃1の刃部1aを30秒間研磨し、研磨後の刃部1aのバリや付着物の有無を、走査電子顕微鏡(日本電子株式会社製、JSM−5500LV)の反射電子像により観察し、付着物をガスクロマトグラフィー質量分析法(ガスクロマトグラフ装置:アジレントテクノロジー株式会社製:Agilent 6890N、質量分析装置:日本電子株式会社製:JMS-Q100OGCK9)で測定した。
Experiment 1: Evaluation of polishing The blade 1a of the sword blade 1 is polished for 30 seconds using the tool polishing pad 12 while using a polishing agent (Bushcraft # 12000 white), and burrs on the blade 1a after polishing are removed. The presence or absence of deposits is observed by a backscattered electron image of a scanning electron microscope (JSM-5500LV, manufactured by JEOL Ltd.), and the deposits are observed by gas chromatography mass spectrometry (gas chromatograph device: Agilent Technologies, Ltd .: Agilent 6890N). , Mass spectrometer: JEOL Ltd .: JMS-Q100OGCK9).

実験2:切れ味評価
切断荷重試験機により、試験片(細長いウールフェルト)の両端部を保持し、これに対して上方から実験1の研磨の結果得られた剃刀刃1を下降させて、試験片が切断されるときの抵抗値を測定し、これを革砥からなる刃物用研磨工具で研磨した剃刀刃の抵抗値と比較した。
Experiment 2: Sharpness evaluation A cutting load tester holds both ends of the test piece (elongated wool felt), and the razor blade 1 obtained as a result of polishing in Experiment 1 is lowered from above to the test piece. The resistance value at the time of cutting was measured and compared with the resistance value of a razor blade polished with a polishing tool for cutting tools consisting of a strop.

実験3:研磨後の刃物用研磨パッド12の研磨面12aに残留する研磨剤の状態の観察
実験1で研磨に使用した実施例品と比較例品の刃物用研磨パッド12の研磨面12aを走査電子顕微鏡(日本電子株式会社製、JSM−5500LV)で200倍に拡大した二次電子像、および、反射電子像によって観察し、研磨後の研磨面12aの表面状態と研磨面12aへの研磨剤の付着状態を観察した。
Experiment 3: Observation of the state of the polishing agent remaining on the polishing surface 12a of the polishing pad 12 for cutting tools after polishing Scanning the polishing surface 12a of the polishing pad 12 for cutting tools of the example product and the comparative example product used for polishing in Experiment 1 Observed by a secondary electron image magnified 200 times with an electron microscope (JSM-5500LV manufactured by Nippon Denshi Co., Ltd.) and a reflected electron image, the surface condition of the polished surface 12a after polishing and the polishing agent on the polished surface 12a. The state of adhesion was observed.

また上記実験に伴い、実施例1〜3および比較例1、2の刃物用研磨パッドについて、それぞれ以下の物性値を以下のように測定した。
〔断面A硬度〕
刃物用研磨パッドの上面視円形の面から5mm×10mmの試験片を切り取り、刃物用研磨パッドの厚み断面が上面(測定面)となるように試験片を測定台に設置する。続いて試験片の中央に押針(直径0.79mmの円柱状圧子)を押し付け、30秒後の押針の押し込み深さから、刃物用研磨パッドの断面A硬度を測定した。測定装置としては、デュロメータ タイプAを用いた。これを3回行って、相加平均から断面A硬度を求めた。
〔断面圧縮率及び断面圧縮弾性率〕
刃物用研磨パッドの上面視円形の面から5mm×10mmの試験片を切り取り、パッドの厚み断面が上面(測定面)となるように試験片をショッパー型厚さ測定器(加圧面:直径1cmの円形)に設置し、刃物用研磨パッドの圧縮率及び圧縮弾性率を測定した。
具体的には、初荷重で30秒間加圧した後の厚さt0を測定し、次に最終荷重のもとで5分間放置後の厚さt1を測定した。全ての荷重を除き、1分間放置後、再び初荷重で30秒間加圧した後の厚さt0’を測定した。このとき、初荷重は100g/cm、最終荷重は1120g/cmであった。
圧縮率は下記数式(1)で算出し、圧縮弾性率は下記数式(2)で算出した。
数式(1):圧縮率(%)=(t0−t1)/t0×100
数式(2):圧縮弾性率(%)=(t0’−t1)/(t0−t1)×100
〔厚さ〕
ショッパー型厚さ測定器(加圧面:直径1cmの円形)を用いて、日本工業規格(JIS K 6505)に準拠して、刃物用研磨パッドの厚さを測定した。
具体的には、刃物用研磨パッドを10cm×10cmに切り出した試料片3枚用意し、試料片ごとに、厚さ測定器の所定位置にセットした後、480g/cmの荷重をかけた加圧面を試料片の表面に載せ、5秒経過後に厚さを測定した。1枚の試料片につき、5箇所の厚さを測定し相加平均を算出し、さらに3枚の試料片の相加平均を求めた。
〔密度〕
刃物用研磨パッドを10cm×10cmに切り出し、試料片とし、その質量を測定し、上記サイズから求めた体積と上記質量から、刃物用研磨パッドの密度(かさ密度)(g/cm)を算出した。
〔繊維密度〕
刃物用研磨パッドの厚み断面について、走査型電子顕微鏡(日本電子株式会社製、JSM−5500LV)を用いて500倍に拡大し、ランダムに9か所を観察した。
この画像より露出した繊維端部の数を数え、その平均値繊維端部数を求め、これを単位面積(mm)あたりの繊維端部数に換算し、繊維密度を算出した。
Further, according to the above experiment, the following physical property values were measured for the polishing pads for cutting tools of Examples 1 to 3 and Comparative Examples 1 and 2, respectively, as follows.
[Cross-section A hardness]
A 5 mm × 10 mm test piece is cut out from the circular surface of the polishing pad for cutting tools, and the test piece is placed on the measuring table so that the thickness cross section of the polishing pad for cutting tools is the upper surface (measurement surface). Subsequently, a pressing needle (cylindrical indenter having a diameter of 0.79 mm) was pressed against the center of the test piece, and the cross-sectional A hardness of the polishing pad for cutting tools was measured from the pressing depth of the pressing needle 30 seconds later. As a measuring device, a durometer type A was used. This was performed three times, and the cross-sectional hardness A was determined from the arithmetic mean.
[Cross-section compressibility and cross-section compressibility]
A 5 mm x 10 mm test piece is cut out from the circular surface of the polishing pad for cutting tools, and the test piece is placed on the top surface (measurement surface) so that the thickness cross section of the pad is the top surface (measurement surface). It was installed in a circular shape), and the compressibility and compressive elastic modulus of the polishing pad for cutting tools were measured.
Specifically, the thickness t0 after being pressurized with the initial load for 30 seconds was measured, and then the thickness t1 after being left for 5 minutes under the final load was measured. After removing all the loads and leaving for 1 minute, the thickness t0'was measured after pressurizing again with the initial load for 30 seconds. At this time, the initial load was 100 g / cm 2 and the final load was 1120 g / cm 2 .
The compressibility was calculated by the following formula (1), and the compressive elastic modulus was calculated by the following formula (2).
Formula (1): Compression rate (%) = (t0-t1) / t0 × 100
Formula (2): Compressive modulus (%) = (t0'-t1) / (t0-t1) x 100
〔thickness〕
Using a shopper type thickness measuring instrument (pressurized surface: circular with a diameter of 1 cm), the thickness of the polishing pad for cutting tools was measured in accordance with Japanese Industrial Standards (JIS K 6505).
Specifically, three sample pieces cut out to a size of 10 cm × 10 cm were prepared, and each sample piece was set at a predetermined position on a thickness measuring instrument, and then a load of 480 g / cm 2 was applied. The pressure surface was placed on the surface of the sample piece, and the thickness was measured after 5 seconds. The thickness of one sample piece was measured at five points, the arithmetic mean was calculated, and the arithmetic mean of three sample pieces was obtained.
〔density〕
A polishing pad for cutting tools is cut into a size of 10 cm × 10 cm, used as a sample piece, and the mass thereof is measured, and the density (bulk density) (g / cm 3 ) of the polishing pad for cutting tools is calculated from the volume obtained from the above size and the above mass. did.
[Fiber density]
The thickness cross section of the polishing pad for cutting tools was magnified 500 times using a scanning electron microscope (JSM-5500LV, manufactured by JEOL Ltd.), and 9 places were randomly observed.
The number of exposed fiber ends was counted from this image, the average value of the number of fiber ends was obtained, and this was converted into the number of fiber ends per unit area (mm 2) to calculate the fiber density.

実施例1にかかる刃物用研磨パッド12については以下のように製造した。最初に、ポリエチレンテレフタレート繊維(繊度2.2dtex、平均繊維長51mm)からなる原綿を混打綿機に通したのち、カード(梳綿機)によりフリースを形成し繊維の方向性を整え、積層させ、ニードルパンチで繊維を絡めることにより、ポリエチレンテレフタレート不織布からなる疎水性繊維基体を作製した。
続いて、得られた不織布を、流動開始温度が160℃のエーテル系ポリウレタンの樹脂分散液に浸漬し、その後、1対のローラ間を加圧可能なマングルローラを用いて余剰の樹脂分散液を絞り落とし、不織布に樹脂分散液を略均一に含浸させた。次いで、樹脂分散液を乾燥させて樹脂含浸不織布を得た。
その後、得られた樹脂含浸不織布の一面側をスライスし、円盤状に切削加工することで、刃物用研磨パッド12を得た。
製造した実施例1の刃物用研磨パッド12は、厚み5.5mm、密度0.35g/cm、断面圧縮弾性率85.0%、断面圧縮率3.0%、断面A硬度68.0°、繊維密度1197本/mmであった。
また、刃物用研磨パッド12に占める疎水性繊維の含有量は全質量に対し70wt%の割合であった。
The polishing pad 12 for cutting tools according to Example 1 was manufactured as follows. First, raw cotton made of polyethylene terephthalate fiber (fineness 2.2 dtex, average fiber length 51 mm) is passed through a blending cotton machine, and then a fleece is formed by a card (carding machine) to adjust the direction of the fibers and laminate them. , A hydrophobic fiber substrate made of a polyethylene terephthalate non-woven fabric was prepared by entwining the fibers with a needle punch.
Subsequently, the obtained non-woven fabric is immersed in a resin dispersion of ether-based polyurethane having a flow start temperature of 160 ° C., and then a surplus resin dispersion is applied using a mangle roller capable of pressurizing between a pair of rollers. After squeezing, the non-woven fabric was impregnated with the resin dispersion almost uniformly. Then, the resin dispersion was dried to obtain a resin-impregnated nonwoven fabric.
Then, one side of the obtained resin-impregnated non-woven fabric was sliced and cut into a disk shape to obtain a polishing pad 12 for a knife.
The manufactured tool polishing pad 12 of Example 1 has a thickness of 5.5 mm, a density of 0.35 g / cm 3 , a cross-sectional compressibility of 85.0%, a cross-sectional compressibility of 3.0%, and a cross-sectional A hardness of 68.0 °. The fiber density was 1197 fibers / mm 2 .
The content of hydrophobic fibers in the polishing pad 12 for cutting tools was 70 wt% with respect to the total mass.

実施例2にかかる刃物用研磨パッド12について、当該刃物用研磨パッド12を構成する樹脂含浸不織布の製造の際に、流動開始温度が195℃のエーテル系ポリウレタンの樹脂分散液を使用する以外は、実施例1と同様にして樹脂含浸不織布を得た。
製造した実施例2の刃物用研磨パッド12は、厚み4.5mm、密度0.45g/cm、断面圧縮弾性率85.0%、断面圧縮率2.5%、断面A硬度75.0°、繊維密度392本/mmであった。
また、刃物用研磨パッド12に占める疎水性繊維の含有量は全質量に対し35wt%の割合であった。
Regarding the polishing pad 12 for cutting tools according to Example 2, except that a resin dispersion of ether-based polyurethane having a flow start temperature of 195 ° C. is used in the production of the resin-impregnated non-woven fabric constituting the polishing pad 12 for cutting tools. A resin-impregnated non-woven fabric was obtained in the same manner as in Example 1.
The manufactured polishing pad 12 for cutting tools of Example 2 has a thickness of 4.5 mm, a density of 0.45 g / cm 3 , a cross-sectional compressibility of 85.0%, a cross-sectional compressibility of 2.5%, and a cross-sectional A hardness of 75.0 °. The fiber density was 392 / mm 2 .
The content of hydrophobic fibers in the polishing pad 12 for cutting tools was 35 wt% with respect to the total mass.

実施例3にかかる刃物用研磨パッド12について、当該刃物用研磨パッド12を構成する樹脂含浸不織布の製造の際に、流動開始温度が225℃のポリカーボネート系ポリウレタンの樹脂分散液を使用する以外は、実施例1と同様にして刃物用研磨パッドを得た。続いて、得られた樹脂含浸不織布の一面側をスライスした後、温度130℃、圧力4MPaの条件下で300秒間熱プレスを行い、円盤状に切削加工することで、刃物用研磨パッドを得た。
製造した実施例3の刃物用研磨パッド12は、厚み4.51mm、密度0.5g/cm、断面圧縮弾性率84.1%、断面圧縮率1.4%、断面A硬度80.5°、繊維密度1362本/mmであった。
また、刃物用研磨パッド12に占める疎水性繊維の含有量は全質量に対し78wt%の割合であった。
Regarding the polishing pad 12 for cutting tools according to Example 3, except that a resin dispersion liquid of polycarbonate-based polyurethane having a flow start temperature of 225 ° C. is used in the production of the resin-impregnated non-woven fabric constituting the polishing pad 12 for cutting tools. A polishing pad for cutting tools was obtained in the same manner as in Example 1. Subsequently, after slicing one side of the obtained resin-impregnated non-woven fabric, heat pressing was performed for 300 seconds under the conditions of a temperature of 130 ° C. and a pressure of 4 MPa, and cutting was performed in a disk shape to obtain a polishing pad for cutting tools. ..
The manufactured polishing pad 12 for cutting tools of Example 3 has a thickness of 4.51 mm, a density of 0.5 g / cm 3 , a cross-sectional compressibility of 84.1%, a cross-sectional compressibility of 1.4%, and a cross-sectional A hardness of 80.5 °. The fiber density was 1362 fibers / mm 2 .
The content of hydrophobic fibers in the polishing pad 12 for cutting tools was 78 wt% with respect to the total mass.

比較例1にかかる刃物用研磨パッドについて、当該刃物用研磨パッド12を構成する樹脂含浸不織布の製造の際に、流動開始温度140℃のエーテル系ポリウレタンの樹脂分散液を使用し、刃物用研磨パッドに占める疎水性繊維の含有量は全質量に対し20wt%の割合とする以外は、実施例1と同様にして刃物用研磨パッドを製造した。
製造した比較例1の刃物用研磨パッドは、厚み4.5mm、密度0.34g/cm、断面圧縮弾性率94.0%、断面圧縮率1.7%、断面A硬度62.5°、繊維密度254本/mmであった。
また、刃物用研磨パッドに占める疎水性繊維の含有量は全質量に対し20wt%の割合であり、刃物用研磨パッドを構成するポリウレタン樹脂の流動開始温度は140℃であった。
Regarding the polishing pad for cutting tools according to Comparative Example 1, a resin dispersion of ether-based polyurethane having a flow start temperature of 140 ° C. was used in the production of the resin-impregnated non-woven fabric constituting the polishing pad 12 for cutting tools, and the polishing pad for cutting tools was used. A polishing pad for cutting tools was manufactured in the same manner as in Example 1 except that the content of the hydrophobic fiber in the non-woven fabric was 20 wt% with respect to the total mass.
The manufactured polishing pad for blades of Comparative Example 1 had a thickness of 4.5 mm, a density of 0.34 g / cm 3 , a cross-sectional compressibility of 94.0%, a cross-sectional compressibility of 1.7%, and a cross-sectional A hardness of 62.5 °. The fiber density was 254 fibers / mm 2 .
The content of hydrophobic fibers in the polishing pad for cutting tools was 20 wt% with respect to the total mass, and the flow start temperature of the polyurethane resin constituting the polishing pad for cutting tools was 140 ° C.

比較例2にかかる刃物用研磨パッドについて、当該刃物用研磨パッド12を構成する樹脂含浸不織布の製造の際に、流動開始温度140℃のエーテル系ポリウレタンの樹脂分散液を使用する以外は、実施例1と同様にして刃物用研磨パッドを製造した。
製造した比較例2の刃物用研磨パッドは、厚み4.54mm、密度0.35g/cm、断面圧縮弾性率94.0%、断面圧縮率1.7%、断面A硬度60.5°、繊維密度1176本/mmであった。
また、刃物用研磨パッドに占める疎水性繊維の含有量は全質量に対し70wt%の割合であり、刃物用研磨パッドを構成するポリウレタン樹脂の流動開始温度は140℃であった。
Examples of the polishing pad for cutting tools according to Comparative Example 2 except that a resin dispersion of ether-based polyurethane having a flow start temperature of 140 ° C. is used in the production of the resin-impregnated non-woven fabric constituting the polishing pad 12 for cutting tools. A polishing pad for cutting tools was manufactured in the same manner as in 1.
The manufactured polishing pad for blades of Comparative Example 2 had a thickness of 4.54 mm, a density of 0.35 g / cm 3 , a cross-sectional compressibility of 94.0%, a cross-sectional compressibility of 1.7%, and a cross-sectional A hardness of 60.5 °. The fiber density was 1176 fibers / mm 2 .
The content of hydrophobic fibers in the polishing pad for cutting tools was 70 wt% with respect to the total mass, and the flow start temperature of the polyurethane resin constituting the polishing pad for cutting tools was 140 ° C.

実験1の結果について説明すると、実験1では研磨剤を使用しながら刃物用研磨パッド12を用いて剃刀刃1の刃部1aを研磨し、研磨開始後30秒後における刃物の刃部1aのバリや付着物の有無を、光学顕微鏡やSEM反射電子像により観察したものとなっている。
評価方法としては、刃部1aにバリや付着物が認められなかった場合に○、バリや付着物が認められた場合に×と評価した。
実験の結果、実施例1〜3の刃物用研磨パッド12を用いて研磨を行った剃刀刃1については、刃部1aにバリや付着物は認められず、良好な研磨面を得られた。
これに対し比較例1、2の刃物用研磨パッド12で研磨した刃部1aにはバリおよび付着物が認められ、また比較例2の刃物用研磨パッド12で研磨した刃部1aには付着物が認められた。
ここで、比較例1、2の刃物用研磨パッド12を用いて研磨を行った剃刀刃1の付着物は、刃部1aの先端部に粉末状の凸状付着物や、帯状に色素が沈着した黒色付着物であった。この付着物が付着した刃物と比較例1、2の刃物用研磨パッド12をそれぞれガスクロマトグラフ質量分析法(GC/MS)により熱分析したところ、付着物と比較例1、2の刃物用研磨パッドとで同一の有機物質成分のピークが検出されたことから、上記付着物はパッドのポリウレタン樹脂成分の溶出物であることが判明した。
このことから、樹脂の流動開始温度が150℃より低い場合、研磨の際にポリウレタン樹脂の樹脂部分が溶解し、その結果溶出物が剃刀刃1に付着してしまうものと推察される。
Explaining the result of Experiment 1, in Experiment 1, the blade portion 1a of the razor blade 1 is polished using the polishing pad 12 for a blade while using a polishing agent, and the burr of the blade portion 1a of the blade 30 seconds after the start of polishing is performed. The presence or absence of deposits and deposits was observed with an optical microscope or SEM reflected electron image.
The evaluation method was evaluated as ◯ when no burrs or deposits were found on the blade portion 1a, and as x when burrs or deposits were found.
As a result of the experiment, with respect to the razor blade 1 which was polished using the polishing pads 12 for blades of Examples 1 to 3, no burrs or deposits were observed on the blade portion 1a, and a good polished surface was obtained.
On the other hand, burrs and deposits were observed on the blade portion 1a polished by the blade polishing pad 12 of Comparative Examples 1 and 2, and deposits were observed on the blade portion 1a polished by the blade polishing pad 12 of Comparative Example 2. Was recognized.
Here, in the deposits of the razor blade 1 polished by using the blade polishing pads 12 of Comparative Examples 1 and 2, powdery convex deposits and band-shaped pigments are deposited on the tip of the blade portion 1a. It was a black deposit. When the blades to which the deposits were attached and the blade polishing pads 12 of Comparative Examples 1 and 2 were thermally analyzed by gas chromatography-mass spectrometry (GC / MS), the deposits and the blade polishing pads of Comparative Examples 1 and 2 were obtained. Since the peak of the same organic substance component was detected in the above, it was found that the deposit was an eluate of the polyurethane resin component of the pad.
From this, it is presumed that when the flow start temperature of the resin is lower than 150 ° C., the resin portion of the polyurethane resin is melted during polishing, and as a result, the eluate adheres to the razor blade 1.

実験2の結果について説明すると、実験2では、切断荷重試験機を用いて、試験片(細長いウールフェルト)の両端部で保持し、これに対して上方から研磨の結果得られた刃物を下降させて、試験片が切断されるときの抵抗値を測定した。
そして、革砥からなる刃物用研磨パッドを用いて研磨した刃物による切断抵抗値を1とし、測定した切断抵抗値が1を下回った場合には従来よりも良好な切れ味が得られているものと考えられる。
実験の結果、実施例1〜3の刃物用研磨パッド12を用いて研磨を行った剃刀刃1については切断抵抗値がいずれも1以下であり、良好な切れ味が得られた。
これに対し比較品1、2の刃物用研磨パッド12を用いて研磨を行った剃刀刃1については切断抵抗値がいずれも1を超えており、革砥を用いた場合に比べて切れ味が低下するという結果が得られた。これは実験1において認識された刃部のバリや付着物に起因するものと考えられる。
To explain the results of Experiment 2, in Experiment 2, a cutting load tester was used to hold the test piece (elongated wool felt) at both ends, and the blade obtained as a result of polishing was lowered from above. The resistance value when the test piece was cut was measured.
Then, the cutting resistance value of the blade polished with the polishing pad for the blade made of leather strop is set to 1, and when the measured cutting resistance value is less than 1, the sharpness is better than the conventional one. Conceivable.
As a result of the experiment, the cutting resistance value of each of the razor blades 1 polished by using the blade polishing pads 12 of Examples 1 to 3 was 1 or less, and good sharpness was obtained.
On the other hand, the cutting resistance value of the razor blade 1 polished by using the blade polishing pads 12 of the comparative products 1 and 2 exceeds 1, and the sharpness is lower than that when the leather grind is used. The result was that it did. It is considered that this is due to the burrs and deposits on the blade recognized in Experiment 1.

実験3の結果について説明すると、実験1で研磨に使用した実施例1と比較例1の刃物用研磨パッド12の研磨面12aを走査電子顕微鏡の二次電子像(200倍)、反射電子像(200倍)によって観察し、研磨使用後の研磨パッド表面状態と研磨面12aへの研磨剤の付着状態を観察した。
反射電子像は原子番号依存性があることから、砥粒成分など原子番号の大きいものは明るく、有機成分など原子番号の小さいものは暗い像となることから、評価方法としては、刃物用研磨パッドの繊維が明るい場合を〇とし、繊維が明るくない場合を×と評価した。
実施例1〜3、比較例2については、疎水性繊維の含有量が、刃物用研磨パッドの全質量に対し30wt%より大きいため、図4の二次電子像写真からも明らかなように研磨面12aに繊維端部を確認することができ、また図5の反射電子像写真より明らかなように繊維表面に明るく示される砥粒成分が多く固着した状態を確認できた。
これに対し、比較品1は図4から明らかなように樹脂が多く空隙が少ないため、図5に示されるように砥粒成分が研磨面12a全体に薄く広がって存在していた。
以上のように、実験3によれば、実施例にかかる刃物用研磨パッド12は、繊維の先端部と繊維の先端部との間で研磨剤を保持するため、研磨中においても研磨剤を良好に保持することができ、切れ味向上に寄与するものと推察される。
Explaining the results of Experiment 3, the polishing surface 12a of the polishing pad 12 for cutting tools of Example 1 and Comparative Example 1 used for polishing in Experiment 1 was subjected to a secondary electron image (200 times) and a backscattered electron image (200 times) of a scanning electron microscope. 200 times), and the surface condition of the polishing pad after the use of polishing and the adhesion state of the polishing agent to the polishing surface 12a were observed.
Since the reflected electron image is atomic number dependent, those with a large atomic number such as abrasive grain components are bright, and those with a small atomic number such as organic components are dark images. When the fiber was bright, it was evaluated as ◯, and when the fiber was not bright, it was evaluated as ×.
In Examples 1 to 3 and Comparative Example 2, since the content of the hydrophobic fibers is larger than 30 wt% with respect to the total mass of the polishing pad for cutting tools, polishing is performed as is clear from the secondary electron image photograph of FIG. The fiber end portion could be confirmed on the surface 12a, and as is clear from the backscattered electron image photograph of FIG. 5, it was confirmed that a large amount of abrasive grain components brightly shown on the fiber surface were fixed.
On the other hand, as is clear from FIG. 4, the comparative product 1 has a large amount of resin and few voids, so that the abrasive grain component is thinly spread over the entire polished surface 12a as shown in FIG.
As described above, according to Experiment 3, since the polishing pad 12 for cutting tools according to the embodiment holds the polishing agent between the tip portion of the fiber and the tip portion of the fiber, the polishing agent is good even during polishing. It is presumed that it can be retained in the area and contributes to the improvement of sharpness.

なお、上記実施例の刃物用研磨パッド12では刃物として剃刀刃1の刃部1aを研磨するようになっているが、それ以外の刃物であっても研磨可能であることは言うまでもない。 The blade polishing pad 12 of the above embodiment is designed to polish the blade portion 1a of the razor blade 1 as a blade, but it goes without saying that other blades can also be polished.

1 剃刀刃(刃物) 1a 刃部
2 剃刀刃製造装置 3 材料
5 研削手段 6 研磨手段
11 回転治具 12 刃物用研磨パッド
12a 研磨面
1 Razor blade (cutlery) 1a Blade part 2 Razor blade manufacturing equipment 3 Material 5 Grinding means 6 Polishing means 11 Rotating jig 12 Polishing pad for cutting tool 12a Polished surface

Claims (3)

円盤状を有するとともにとともに、その外周縁に形成された研磨面によって刃物の刃部を研磨する刃物用研磨パッドであって、
疎水性繊維によって構成された繊維基体と、当該繊維基体に含浸されたポリウレタン樹脂とによって構成され、
上記ポリウレタン樹脂の流動開始温度が150〜300℃であることを特徴とする刃物用研磨パッド。
It is a polishing pad for blades that has a disk shape and also polishes the blade portion of the blade with the polishing surface formed on the outer peripheral edge thereof.
It is composed of a fiber substrate composed of hydrophobic fibers and a polyurethane resin impregnated in the fiber substrate.
A polishing pad for cutting tools, wherein the flow start temperature of the polyurethane resin is 150 to 300 ° C.
上記繊維基体を構成する疎水性繊維の少なくとも一部は、刃物用研磨パッドの平面な面に対して水平方向に配向し、当該繊維の端部が上記研磨面に露出することを特徴とする請求項1に記載の刃物用研磨パッド。 A claim characterized in that at least a part of the hydrophobic fibers constituting the fiber substrate is oriented horizontally with respect to a flat surface of a polishing pad for a cutting tool, and the end portion of the fiber is exposed to the polishing surface. Item 2. The polishing pad for cutting tools according to Item 1. 上記疎水性繊維の含有量は、刃物用研磨パッドの全質量に対し30〜90wt%の割合であることを特徴とする請求項1または請求項2のいずれかに記載の刃物用研磨パッド The polishing pad for cutting tools according to claim 1 or 2, wherein the content of the hydrophobic fibers is 30 to 90 wt% with respect to the total mass of the polishing pad for cutting tools.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08187655A (en) * 1986-03-25 1996-07-23 Rodel Inc Porous pad material and its preparation
JP2007290061A (en) * 2006-04-24 2007-11-08 Three M Innovative Properties Co Heat-resistant nonwoven abrasive cloth
JP2017538589A (en) * 2014-12-01 2017-12-28 スリーエム イノベイティブ プロパティズ カンパニー Nonwoven polishing wheel with moisture barrier layer

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08187655A (en) * 1986-03-25 1996-07-23 Rodel Inc Porous pad material and its preparation
JP2007290061A (en) * 2006-04-24 2007-11-08 Three M Innovative Properties Co Heat-resistant nonwoven abrasive cloth
JP2017538589A (en) * 2014-12-01 2017-12-28 スリーエム イノベイティブ プロパティズ カンパニー Nonwoven polishing wheel with moisture barrier layer

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