JP2017088742A - ポリプロピレン系樹脂組成物 - Google Patents
ポリプロピレン系樹脂組成物 Download PDFInfo
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- JP2017088742A JP2017088742A JP2015220960A JP2015220960A JP2017088742A JP 2017088742 A JP2017088742 A JP 2017088742A JP 2015220960 A JP2015220960 A JP 2015220960A JP 2015220960 A JP2015220960 A JP 2015220960A JP 2017088742 A JP2017088742 A JP 2017088742A
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- JP
- Japan
- Prior art keywords
- mass
- propylene
- resin composition
- polypropylene resin
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- -1 Polypropylene Polymers 0.000 title claims abstract description 71
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 63
- 239000011342 resin composition Substances 0.000 title claims abstract description 52
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 47
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 62
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 62
- 239000005977 Ethylene Substances 0.000 claims abstract description 47
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000011256 inorganic filler Substances 0.000 claims abstract description 34
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 34
- 239000002245 particle Substances 0.000 claims abstract description 27
- 239000004711 α-olefin Substances 0.000 claims abstract description 26
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 20
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims abstract description 18
- 229920000642 polymer Polymers 0.000 claims abstract description 18
- 238000000465 moulding Methods 0.000 claims abstract description 11
- 238000001746 injection moulding Methods 0.000 claims abstract description 9
- 229920005604 random copolymer Polymers 0.000 claims abstract description 4
- 229920001384 propylene homopolymer Polymers 0.000 claims description 31
- 239000000454 talc Substances 0.000 claims description 21
- 229910052623 talc Inorganic materials 0.000 claims description 21
- 239000000155 melt Substances 0.000 claims description 18
- 229920001400 block copolymer Polymers 0.000 claims description 16
- 239000002667 nucleating agent Substances 0.000 claims description 16
- 229920001577 copolymer Polymers 0.000 claims description 13
- 238000012360 testing method Methods 0.000 claims description 9
- 238000009863 impact test Methods 0.000 claims description 3
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 abstract description 50
- 238000004519 manufacturing process Methods 0.000 abstract description 18
- 239000000203 mixture Substances 0.000 abstract description 11
- 239000000243 solution Substances 0.000 abstract description 6
- 238000006116 polymerization reaction Methods 0.000 description 70
- 239000003054 catalyst Substances 0.000 description 56
- 239000010936 titanium Substances 0.000 description 54
- 229910052719 titanium Inorganic materials 0.000 description 47
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 44
- 239000007787 solid Substances 0.000 description 39
- 238000000034 method Methods 0.000 description 31
- 150000001875 compounds Chemical class 0.000 description 24
- 239000001257 hydrogen Substances 0.000 description 20
- 229910052739 hydrogen Inorganic materials 0.000 description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 17
- 150000002681 magnesium compounds Chemical class 0.000 description 17
- 239000000047 product Substances 0.000 description 15
- 239000002002 slurry Substances 0.000 description 15
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 14
- 150000001336 alkenes Chemical class 0.000 description 14
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 14
- 150000002430 hydrocarbons Chemical group 0.000 description 12
- 239000007788 liquid Substances 0.000 description 12
- 238000002156 mixing Methods 0.000 description 12
- 150000003609 titanium compounds Chemical class 0.000 description 12
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 10
- 239000007789 gas Substances 0.000 description 10
- 238000005259 measurement Methods 0.000 description 10
- 150000002902 organometallic compounds Chemical class 0.000 description 10
- 239000000460 chlorine Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- 229910052749 magnesium Inorganic materials 0.000 description 8
- 239000011777 magnesium Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 150000003961 organosilicon compounds Chemical class 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 229930195733 hydrocarbon Natural products 0.000 description 7
- 230000006872 improvement Effects 0.000 description 7
- 239000012071 phase Substances 0.000 description 7
- 239000002685 polymerization catalyst Substances 0.000 description 7
- 230000000379 polymerizing effect Effects 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
- 238000012685 gas phase polymerization Methods 0.000 description 6
- 238000007561 laser diffraction method Methods 0.000 description 6
- 230000000704 physical effect Effects 0.000 description 6
- 238000010298 pulverizing process Methods 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 5
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical class CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 5
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- KOFGHHIZTRGVAF-UHFFFAOYSA-N n-ethyl-n-triethoxysilylethanamine Chemical compound CCO[Si](OCC)(OCC)N(CC)CC KOFGHHIZTRGVAF-UHFFFAOYSA-N 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000000600 sorbitol Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Chemical class 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 238000012662 bulk polymerization Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 3
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 3
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- UUEVFMOUBSLVJW-UHFFFAOYSA-N oxo-[[1-[2-[2-[2-[4-(oxoazaniumylmethylidene)pyridin-1-yl]ethoxy]ethoxy]ethyl]pyridin-4-ylidene]methyl]azanium;dibromide Chemical compound [Br-].[Br-].C1=CC(=C[NH+]=O)C=CN1CCOCCOCCN1C=CC(=C[NH+]=O)C=C1 UUEVFMOUBSLVJW-UHFFFAOYSA-N 0.000 description 3
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 3
- 229920000570 polyether Chemical class 0.000 description 3
- 235000013849 propane Nutrition 0.000 description 3
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 3
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000010557 suspension polymerization reaction Methods 0.000 description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 3
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 3
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 3
- MEPSBRTXOHFWCF-UHFFFAOYSA-N (2-cyclohexyl-1,3-dimethoxypropan-2-yl)cyclohexane Chemical compound C1CCCCC1C(COC)(COC)C1CCCCC1 MEPSBRTXOHFWCF-UHFFFAOYSA-N 0.000 description 2
- USWVUBUQOUONFU-UHFFFAOYSA-N (3-cyclohexyl-1,4-diethoxybutan-2-yl)cyclohexane Chemical compound C1CCCCC1C(COCC)C(COCC)C1CCCCC1 USWVUBUQOUONFU-UHFFFAOYSA-N 0.000 description 2
- UUAMLBIYJDPGFU-UHFFFAOYSA-N 1,3-dimethoxypropane Chemical compound COCCCOC UUAMLBIYJDPGFU-UHFFFAOYSA-N 0.000 description 2
- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical compound CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- RGHIYOCUMCUWAQ-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,5-dimethylhexane Chemical compound COCC(COC)(CC(C)C)C(C)C RGHIYOCUMCUWAQ-UHFFFAOYSA-N 0.000 description 2
- PVWCLOAAEFMTLH-UHFFFAOYSA-N 4,4-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(COC)(CC(C)C)CC(C)C PVWCLOAAEFMTLH-UHFFFAOYSA-N 0.000 description 2
- ZFAGXQVYYWOLNK-UHFFFAOYSA-N CCO[Mg] Chemical compound CCO[Mg] ZFAGXQVYYWOLNK-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000001186 cumulative effect Effects 0.000 description 2
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- ZVMRWPHIZSSUKP-UHFFFAOYSA-N dicyclohexyl(dimethoxy)silane Chemical compound C1CCCCC1[Si](OC)(OC)C1CCCCC1 ZVMRWPHIZSSUKP-UHFFFAOYSA-N 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000012456 homogeneous solution Substances 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methylcycloheptane Chemical compound CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 2
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920005673 polypropylene based resin Polymers 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 239000011949 solid catalyst Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
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- SNAQARSCIHDMGI-UHFFFAOYSA-M sodium;bis(4-tert-butylphenyl) phosphate Chemical compound [Na+].C1=CC(C(C)(C)C)=CC=C1OP([O-])(=O)OC1=CC=C(C(C)(C)C)C=C1 SNAQARSCIHDMGI-UHFFFAOYSA-M 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- ASEHKQZNVUOPRW-UHFFFAOYSA-N tert-butyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C(C)(C)C ASEHKQZNVUOPRW-UHFFFAOYSA-N 0.000 description 1
- JHVNMGWNEQGGDU-UHFFFAOYSA-N tert-butyl-diethoxy-methylsilane Chemical compound CCO[Si](C)(C(C)(C)C)OCC JHVNMGWNEQGGDU-UHFFFAOYSA-N 0.000 description 1
- NETBVGNWMHLXRP-UHFFFAOYSA-N tert-butyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C(C)(C)C NETBVGNWMHLXRP-UHFFFAOYSA-N 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229920000428 triblock copolymer Polymers 0.000 description 1
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
- IOPAQHDEQBHWEB-UHFFFAOYSA-N trimethoxy-(2-methylcyclopentyl)silane Chemical compound CO[Si](OC)(OC)C1CCCC1C IOPAQHDEQBHWEB-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C08F210/06—Propene
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- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
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- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
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- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/17—Viscosity
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- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
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Abstract
Description
メルトフローレート(230℃、2.16kg荷重)が10〜500g/10分であるプロピレン単独重合体(B)0〜30質量部、
エチレンと炭素原子数が4〜8のα−オレフィンとのランダム共重合体であり、密度が0.850〜0.890g/cm3、メルトフローレート(230℃、2.16kg荷重)が0.5〜30g/10分であるエチレン・α−オレフィン共重合体(C)23〜30質量部、および、
平均粒子径が3.0μmを超え、5.0μm未満である無機充填剤(D)30〜40質量部
[但し、成分(A)〜(D)の合計量を100質量部とする。]
を含有するポリプロピレン系樹脂組成物。
[3]無機充填剤(D)がタルクであり、そのアスペクト比が3以上15未満である前記[1]または[2]に記載のポリプロピレン系樹脂組成物。
[4]さらに核剤(E)を、成分(A)〜(D)の合計100質量部に対して0.05〜0.5質量部含む前記[1]〜[3]のいずれかに記載のポリプロピレン系樹脂組成物。
[5]JISK5600−5−3に準拠したデュポン式面衝撃試験において、塗装を施していないポリプロピレン系樹脂組成物の成形体からなる試験片の−40℃の面衝撃強度が10J以上である前記[1]〜[4]のいずれかに記載のポリプロピレン系樹脂組成物。
[6]自動車外装部材に用いられる前記[1]〜[5]のいずれかに記載のポリプロピレン系樹脂組成物。
[7]前記[6]に記載のポリプロピレン系樹脂組成物を射出成型もしくはプレス成型して得られる自動車外装部材。
本発明に用いるプロピレン系重合体(A)は、メルトフローレート(230℃、2.16kg荷重)が50〜150g/10分、デカン可溶部量が6質量%以上であるプロピレン系重合体である。
オレフィン重合用触媒を構成する固体状チタン触媒成分(I)は、例えば、チタン、マグネシウム、ハロゲン及び必要に応じて電子供与体を含む。この固体状チタン触媒成分(I)には公知の成分を制限無く用いることができる。
Ti(OR)gX4−g
(式中、Rは炭化水素基であり、Xはハロゲン原子であり、gは0≦g≦4である。)
(P−1)マグネシウム化合物及びアルコール等の電子供与体成分(1)からなる固体状付加物と、後述する電子供与体成分(2)と、液状状態のチタン化合物とを、不活性炭化水素溶媒共存下、懸濁状態で接触させる方法。
(P−2)マグネシウム化合物及び電子供与体成分(1)からなる固体状付加物と、電子供与体成分(2)と、液状状態のチタン化合物とを、複数回に分けて接触させる方法。
(P−3)マグネシウム化合物及び電子供与体成分(1)からなる固体状付加物と、電子供与体成分(2)と、液状状態のチタン化合物とを、不活性炭化水素溶媒共存下、懸濁状態で接触させ、且つ複数回に分けて接触させる方法。
(P−4)マグネシウム化合物及び電子供与体成分(1)からなる液状状態のマグネシウム化合物と、液状状態のチタン化合物と、電子供与体成分(2)とを接触させる方法。
有機金属化合物触媒成分(II)は、周期表の第1族、第2族及び第13族から選ばれる金属元素を含む成分である。例えば、第13族金属を含む化合物(有機アルミニウム化合物等)、第1族金属とアルミニウムとの錯アルキル化物、第2族金属の有機金属化合物等を用いることができる。中でも、有機アルミニウム化合物が好ましい。
RnSi(OR’)4−n
(式中、R及びR’は炭化水素基であり、nは0<n<4の整数である。)
Si(ORa)3(NRbRc)
RNSi(ORa)3
プロピレン系重合体(A)の好ましい態様であるプロピレン・エチレンブロック共重合体は、上述したオレフィン重合用触媒の存在下にプロピレンを重合し、次いでプロピレンとエチレンを共重合させるか、又は予備重合させて得られる予備重合触媒の存在下にプロピレンを重合し、次いでプロピレンとエチレンの共重合を行う等の方法で製造できる。
(重合工程1)
固体状チタン触媒成分の存在下でプロピレンを重合し、プロピレン単独重合体成分を製造する工程(プロピレン単独重合体製造工程)。
(重合工程2)
固体状チタン触媒成分の存在下でプロピレン及びエチレンを共重合してエチレン・プロピレン共重合体成分を製造する工程(共重合体ゴム製造工程)。
本発明に用いるプロピレン単独重合体(B)は、メルトフローレート(230℃、2.16kg荷重)が10〜500g/10分であるプロピレン単独重合体である。
本発明に用いるエチレン・α−オレフィン共重合体(C)は、エチレンと炭素原子数が4〜8のα−オレフィンとのランダム共重合体であり、密度が0.850〜0.890g/cm3、メルトフローレート(230℃、2.16kg荷重)が0.5〜30g/10分であるエチレン・α−オレフィン共重合体である。このエチレン・α−オレフィン共重合体(C)は、他成分との相乗効果によって、成形体の寸法安定性の向上(線膨張係数の低減)に寄与することが予想されると共に、その他の物性の向上にも寄与し成形品に高度な物性バランスが発現する。
本発明に用いる無機充填剤(D)は、平均粒子径が3.0μmを超え、5.0μm未満である無機充填剤である。
本発明のポリプロピレン系樹脂組成物は、本発明の目的を損なわない範囲で、必要に応じてさらに核剤(E)を含有してもよい。
本発明のポリプロピレン系樹脂組成物は、プロピレン系重合体(A)5〜47質量部、プロピレン単独重合体(B)0〜30質量部、エチレン・α−オレフィン共重合体(C)23〜30質量部、および、無機充填剤(D)30〜40質量部[但し、成分(A)〜(D)の合計量を100質量部とする。]を含有する。
本発明の自動車外装部材は、本発明のポリプロピレン系樹脂組成物を射出成型もしくはプレス成型して得られる成形体である。
ISO 1133に準拠し、試験荷重2.16kg、試験温度230℃の条件で測定した。
サンプル約20mgをデカリン15mlに溶解し、135℃のオイルバス中で比粘度ηspを測定した。このデカリン溶液にデカリン溶媒を5ml追加して希釈し、その後同様にして比粘度ηspを測定した。この希釈操作をさらに2回繰り返し、濃度(C)を0に外挿した時のηsp/Cの値を極限粘度[η]として求めた。
[η]=lim(ηsp/C) (C→0)
ガラス製の測定容器に試料[成分(A)]約3g(10-4gの単位まで測定した。また、この質量を下式においてx2(g)と表した。)、n−デカン500ml、およびn−デカンに可溶な耐熱安定剤を少量装入し、窒素雰囲気下、スターラーで攪拌しながら2時間で150℃に昇温して試料を溶解させ、150℃で2時間保持した後、8時間かけて23℃まで徐冷した。得られた析出物を含む液を、磐田ガラス社製25G−4規格のグラスフィルターで減圧ろ過した。ろ液の100mlを採取し、これを減圧乾燥してデカン可溶成分の一部を得、この質量を10-4gの単位まで測定した(この質量を下式においてx1(g)と表した)。この測定値を用いて、室温(すなわち23℃)におけるデカン可溶部量(Dsol)および不溶部量(Dinsol)を下記式によって決定した。
Dsol(質量%)=100×(500×x1)/(100×x2)
Dinsol(質量%)=100−Dsol
ASTM D790に準拠し、以下の条件で測定した。
温度:23℃
試験片:127mm(長さ)×12.7mm(幅)×6.35mm(厚み)
曲げ速度:30mm/min
スパン間:100cm
ASTM D 696に準拠し、TMA法(測定範囲−30〜80℃)にて評価した。具体的には、長さ240mm、幅80mm、厚み3mmの金型キャビティーを用いて樹脂温度210℃、金型温度40℃で射出成形して平板を得て、これを10×5×3mm厚の形状に切り出し、試験片として用いた。
JIS K5600−5−3に準拠し、−10℃、−20℃、−30℃及び−40℃の各温度で、塗装を施していない試験片の面衝撃強度を測定した。
JIS R1620およびJIS R1622に準拠し、レーザー回折法によって測定した粒度累積曲線から読み取った累積量50質量%の粒径値を平均粒径とした。
電子顕微鏡を用いて写真撮影を行い、粉体の長径と厚みを測定し、平均値を求め、平均粒径/平均厚みの比からアスペクト比を求めた。
(1)固体状チタン触媒成分の調製
無水塩化マグネシウム95.2g、デカン442mLおよび2−エチルヘキシルアルコール390.6gを130℃で2時間加熱反応を行って均一溶液とし、この溶液中に無水フタル酸21.3gを添加し、さらに130℃にて1時間攪拌混合を行い、無水フタル酸を溶解させた。
前記の固体状チタン触媒成分100g、トリエチルアルミニウム131mL、ジエチルアミノトリエトキシシラン37.3ml、ヘプタン14.3Lを内容量20Lの攪拌機付きオートクレーブに挿入し、内温15〜20℃に保ちプロピレンを1000g挿入し、120分間攪拌しながら反応させた。重合終了後、固体成分を沈降させ、上澄み液の除去およびヘプタンによる洗浄を2回行った。得られた前重合触媒を精製ヘプタンに再懸濁して、固体触媒成分濃度で1.0g/Lとなるようヘプタンにより濃度調整を行って、前重合触媒スラリーを得た。
内容量58Lのジャケット付循環式管状重合器にプロピレンを43kg/時間、水素を256NL/時間、前記(2)で製造した前重合触媒スラリーを固体状チタン触媒成分として0.49g/時間、トリエチルアルミニウム4.5mL/時間、ジエチルアミノトリエトキシシラン1.8mL/時間で連続的に供給し、気相の存在しない満液の状態にて重合した。管状重合器の温度は70℃であり、圧力は3.57MPa/Gであった。
まず、製造例1の(1)固体状チタン触媒成分の調製、(2)前重合触媒の製造と同様にして前重合触媒スラリーを得た。
内容量1000Lの攪拌機付きベッセル重合器に、プロピレンを131kg/時間、前重合触媒スラリーを遷移金属触媒成分として0.70g/時間、トリエチルアルミニウム19.6mL/時間、ジエチルアミノトリエトキシシラン4.2mL/時間を連続的に供給し、水素を気相部の水素濃度が5.3mol%になるように供給し、重合温度75℃、圧力3.5MPa/Gで重合を行った。
製造例1の(1)固体状チタン触媒成分の調製と同様にして固体状チタン触媒成分を得た。
固体状チタン触媒成分100g、トリエチルアルミニウム39.3mL、ヘプタン100Lを内容量200Lの攪拌機付きオートクレーブに挿入し、内温15〜20℃に保ちプロピレンを600g挿入し、60分間攪拌しながら反応させて、前重合触媒スラリーを得た。
内容量58Lのジャケット付循環式管状重合器にプロピレンを43kg/時間、水素を177NL/時間、(2)で製造した前重合触媒スラリーを固体状チタン触媒成分として0.58g/時間、トリエチルアルミニウム3.1ml/時間、ジシクロペンチルジメトキシシラン3.3ml/時間で連続的に供給し、気相の存在しない満液の状態にて重合した。管状重合器の温度は70℃であり、圧力は3.53MPa/Gであった。
タルク(D−1):
平均粒径(レーザー回折法)=4.3μm、アスペクト比(SEM採寸)=6.7
タルク(D−2):
平均粒径(レーザー回折法)=3.7μm、アスペクト比(SEM採寸)=9.0
タルク(D−3):
平均粒径(レーザー回折法)=4.5μm、アスペクト比(SEM採寸)=9.0
タルク(D−4):
平均粒径(レーザー回折法)=12μm、アスペクト比(SEM採寸)=15.3
プロピレン系重合体(A)、プロピレン単独重合体(B)、エチレン・α−オレフィン共重合体(C)、無機充填剤(D)および核剤(E)を、表1に示す配合量で混合し、二軸押出機((株)日本製鋼所製、TEX(登録商標)30α)により、シリンダ温度180℃、スクリュー回転750rpm、押出し量60kg/hの条件で押出し、ポリプロピレン系樹脂組成物を得た。
Claims (7)
- メルトフローレート(230℃、2.16kg荷重)が50〜150g/10分、デカン可溶部量が6質量%以上であるプロピレン系重合体(A)5〜47質量部、
メルトフローレート(230℃、2.16kg荷重)が10〜500g/10分であるプロピレン単独重合体(B)0〜30質量部、
エチレンと炭素原子数が4〜8のα−オレフィンとのランダム共重合体であり、密度が0.850〜0.890g/cm3、メルトフローレート(230℃、2.16kg荷重)が0.5〜30g/10分であるエチレン・α−オレフィン共重合体(C)23〜30質量部、および、
平均粒子径が3.0μmを超え、5.0μm未満である無機充填剤(D)30〜40質量部
[但し、成分(A)〜(D)の合計量を100質量部とする。]
を含有するポリプロピレン系樹脂組成物。 - プロピレン系重合体(A)がプロピレンとエチレンから得られるブロック共重合体であり、該共重合体のデカン可溶部の極限粘度[η]が2〜9dl/gである請求項1に記載のポリプロピレン系樹脂組成物。
- 無機充填剤(D)がタルクであり、そのアスペクト比が3以上15未満である請求項1または2に記載のポリプロピレン系樹脂組成物。
- さらに核剤(E)を、成分(A)〜(D)の合計100質量部に対して0.05〜0.5質量部含む請求項1〜3のいずれかに記載のポリプロピレン系樹脂組成物。
- JISK5600−5−3に準拠したデュポン式面衝撃試験において、塗装を施していないポリプロピレン系樹脂組成物の成形体からなる試験片の−40℃の面衝撃強度が10J以上である請求項1〜4のいずれかに記載のポリプロピレン系樹脂組成物。
- 自動車外装部材に用いられる請求項1〜5のいずれかに記載のポリプロピレン系樹脂組成物。
- 請求項6に記載のポリプロピレン系樹脂組成物を射出成型もしくはプレス成型して得られる自動車外装部材。
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JP2020158554A (ja) * | 2019-03-25 | 2020-10-01 | 株式会社プライムポリマー | ポリプロピレン系樹脂組成物 |
WO2022004551A1 (ja) * | 2020-06-30 | 2022-01-06 | 住友化学株式会社 | ポリプロピレン系樹脂組成物 |
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Publication number | Priority date | Publication date | Assignee | Title |
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Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0598128A (ja) * | 1991-10-09 | 1993-04-20 | Tonen Chem Corp | 自動車用樹脂組成物 |
JPH06240097A (ja) * | 1993-02-19 | 1994-08-30 | Sekisui Chem Co Ltd | 射出成形用樹脂組成物 |
JPH083394A (ja) * | 1994-06-21 | 1996-01-09 | Mitsubishi Chem Corp | ウレタン接着用プロピレン系樹脂組成物 |
JPH09151294A (ja) * | 1995-09-29 | 1997-06-10 | Mitsubishi Chem Corp | タルク含有プロピレン系樹脂組成物 |
JP2009062526A (ja) * | 2007-08-10 | 2009-03-26 | Toyoda Gosei Co Ltd | 樹脂組成物及び樹脂製品 |
WO2009060738A1 (ja) * | 2007-11-09 | 2009-05-14 | Prime Polymer Co., Ltd. | 自動車材用ポリプロピレン系樹脂組成物 |
JP2010537039A (ja) * | 2007-09-26 | 2010-12-02 | 株式会社プライムポリマー | ポリプロピレン系樹脂組成物 |
JP2013159709A (ja) * | 2012-02-06 | 2013-08-19 | Japan Polypropylene Corp | 自動車外装部材用ポリプロピレン系樹脂組成物及び自動車外装部材 |
JP2014074102A (ja) * | 2012-10-03 | 2014-04-24 | Prime Polymer Co Ltd | ポリプロピレン系樹脂組成物 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3177709B2 (ja) | 1991-02-15 | 2001-06-18 | 住友化学工業株式会社 | 熱可塑性樹脂組成物およびその射出成形体 |
JP4088373B2 (ja) | 1998-09-22 | 2008-05-21 | チッソ株式会社 | 自動車サイドモール成形用樹脂組成物及び自動車サイドモール |
EP1767578B1 (en) * | 2004-07-12 | 2013-11-06 | DSM IP Assets B.V. | Thermoplastic resin composition |
KR100878869B1 (ko) * | 2005-03-18 | 2009-01-15 | 미쓰이 가가쿠 가부시키가이샤 | 프로필렌계 중합체 조성물, 그 용도, 및 열가소성 중합체조성물의 제조 방법 |
JP2007091789A (ja) | 2005-09-27 | 2007-04-12 | Japan Polypropylene Corp | 塗装外観に優れるポリプロピレン系樹脂組成物及び成形体 |
CN101965379B (zh) | 2007-08-10 | 2012-12-26 | 丰田合成株式会社 | 树脂组合物以及树脂制品 |
JP2010077396A (ja) | 2008-08-28 | 2010-04-08 | Japan Polypropylene Corp | プロピレン系樹脂組成物およびその成形体 |
JP6038163B2 (ja) * | 2012-09-18 | 2016-12-07 | 株式会社プライムポリマー | ポリプロピレン系樹脂組成物およびその用途 |
JP6006058B2 (ja) | 2012-09-18 | 2016-10-12 | 日本ポリプロ株式会社 | 自動車外装部材用ポリプロピレン系樹脂組成物および自動車外装部材 |
JP6360698B2 (ja) * | 2014-03-19 | 2018-07-18 | 株式会社プライムポリマー | プロピレン系ブロック共重合体 |
JP2016084386A (ja) | 2014-10-23 | 2016-05-19 | 株式会社プライムポリマー | タルク含有ポリプロピレン系樹脂組成物 |
-
2015
- 2015-11-11 JP JP2015220960A patent/JP6566842B2/ja active Active
-
2016
- 2016-11-10 US US15/774,822 patent/US11873392B2/en active Active
- 2016-11-10 WO PCT/JP2016/083400 patent/WO2017082358A1/ja active Application Filing
- 2016-11-10 MX MX2018005941A patent/MX2018005941A/es unknown
- 2016-11-10 CN CN201680066122.8A patent/CN108699303B/zh active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0598128A (ja) * | 1991-10-09 | 1993-04-20 | Tonen Chem Corp | 自動車用樹脂組成物 |
JPH06240097A (ja) * | 1993-02-19 | 1994-08-30 | Sekisui Chem Co Ltd | 射出成形用樹脂組成物 |
JPH083394A (ja) * | 1994-06-21 | 1996-01-09 | Mitsubishi Chem Corp | ウレタン接着用プロピレン系樹脂組成物 |
JPH09151294A (ja) * | 1995-09-29 | 1997-06-10 | Mitsubishi Chem Corp | タルク含有プロピレン系樹脂組成物 |
JP2009062526A (ja) * | 2007-08-10 | 2009-03-26 | Toyoda Gosei Co Ltd | 樹脂組成物及び樹脂製品 |
JP2010537039A (ja) * | 2007-09-26 | 2010-12-02 | 株式会社プライムポリマー | ポリプロピレン系樹脂組成物 |
WO2009060738A1 (ja) * | 2007-11-09 | 2009-05-14 | Prime Polymer Co., Ltd. | 自動車材用ポリプロピレン系樹脂組成物 |
JP2013159709A (ja) * | 2012-02-06 | 2013-08-19 | Japan Polypropylene Corp | 自動車外装部材用ポリプロピレン系樹脂組成物及び自動車外装部材 |
JP2014074102A (ja) * | 2012-10-03 | 2014-04-24 | Prime Polymer Co Ltd | ポリプロピレン系樹脂組成物 |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2020122102A (ja) * | 2019-01-31 | 2020-08-13 | 白石カルシウム株式会社 | 樹脂組成物及び射出成形品 |
JP7116423B2 (ja) | 2019-01-31 | 2022-08-10 | 白石カルシウム株式会社 | 樹脂組成物及び射出成形品 |
JP2020158554A (ja) * | 2019-03-25 | 2020-10-01 | 株式会社プライムポリマー | ポリプロピレン系樹脂組成物 |
JP7406922B2 (ja) | 2019-03-25 | 2023-12-28 | 株式会社プライムポリマー | ポリプロピレン系樹脂組成物 |
WO2022004551A1 (ja) * | 2020-06-30 | 2022-01-06 | 住友化学株式会社 | ポリプロピレン系樹脂組成物 |
WO2023112857A1 (ja) * | 2021-12-14 | 2023-06-22 | 株式会社プライムポリマー | ポリプロピレン系樹脂組成物およびその用途 |
WO2023112858A1 (ja) * | 2021-12-14 | 2023-06-22 | 株式会社プライムポリマー | 積層構造体およびその用途 |
JP7522521B2 (ja) | 2021-12-14 | 2024-07-25 | 株式会社プライムポリマー | 積層構造体およびその用途 |
JP7575635B2 (ja) | 2021-12-14 | 2024-10-29 | 株式会社プライムポリマー | 積層構造体およびその用途 |
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