JP2013231166A - Shock absorbing material - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a shock absorbing material, which has excellent thermal conductivity and shock-absorbing properties, and is disposed between a heat-generating member and a casing covering the heat-generating member and radiating the heat of the member.SOLUTION: There is provided a shock absorbing material 4 which is disposed between a heat-generating member 2 and a casing covering the member 2 and radiating heat of the member 2. The shock absorbing material 4 is formed by foaming a resin composition including a resin (A) including an elastomer and thermally conductive filler (B) having a thermal conductivity, and has a shock absorbing layer 41 having a 25% compressive strength of ≤200 kPa.

Description

  The present invention relates to a cushioning material obtained by subjecting a resin containing an elastomer to a foaming treatment.

  2. Description of the Related Art In recent years, along with higher performance and smaller size of electronic devices, electronic components that make up electronic devices have been increasing in density and functionality. As a result, the electronic component itself generates a large amount of heat, and the heat generation causes deterioration of the quality of the electronic component, efficiency reduction, malfunction, damage, etc., so a means for appropriately dissipating heat is provided. It has been. As an example of the heat radiating means, there is a method of attaching a metal housing such as a heat sink to an electronic component that is a heat source. Further, there is a method in which a casing covering the electronic component is used as a part of the heat radiating means.

  In order to efficiently dissipate heat, it is desirable that a member such as an electronic component that is a heat generation source and a heat dissipating unit that radiates heat from the member are in reliable contact. Therefore, a heat dissipation material has been proposed that has a heat dissipation function by mixing a heat conductive filler with a cushioning material made of an elastomer or rubber material that is highly flexible and has good followability to the shape of an electronic component (Patent Literature). 1). However, if the amount of the thermally conductive filler is increased in order to increase the thermal conductivity, the heat dissipation material becomes harder, and when it is formed so as to have a thickness required for a small electronic device, it is sufficiently flexible. However, there is a problem that the shock absorption at the time of dropping or the like is lowered.

  In addition, heat radiation grease made of liquid silicone, heat radiation sheet made of gel-like silicone, and the like have been proposed (see Patent Document 2). Although the heat dissipation sheet made of gel silicone has good adhesion and followability, it has been difficult to mold it to a thickness required for a small electronic device. Further, in the electronic equipment field, since a silicone compound causes a contact failure, it is desired that the silicone compound does not contain a siloxane compound, and some of the above-described heat dissipation sheets and heat dissipation grease are incompatible. In addition, urethane foam is known as a general-purpose cushioning material. Urethane foam has also been difficult to mold with high precision so as to have a thickness required in the field of electronic equipment due to its manufacturing characteristics.

  As a device having a member that generates heat and a housing, a measure for increasing heat dissipation from the member is also demanded in a secondary battery represented by a lithium ion battery or the like. There is also a need for a measure that increases the cushioning between the member and the housing.

JP 2005-097440 A Japanese Patent Laid-Open No. 05-065347

  The present invention is a cushioning material having thermal conductivity disposed between a member that generates heat and a casing that covers the member that generates heat and radiates heat of the member, and has excellent thermal conductivity and buffering properties. It aims at providing the shock absorbing material which has.

As a result of intensive studies, the present inventors have made foaming so that the 25% compressive strength of a resin composition containing a resin (A) containing an elastomer and a thermally conductive filler (B) having thermal conductivity becomes a specific value. As a result, the present inventors have found that the above-mentioned problems can be solved and completed the present invention.
The present invention includes the following contents.
[1] A heat-conductive cushioning material disposed between a member that generates heat and a casing that covers the member that generates heat and radiates the heat of the member, and includes a resin (A) containing elastomer and heat A buffer material comprising a buffer layer having a 25% compressive strength of 200 kPa or less obtained by foaming a resin composition containing a thermally conductive filler (B) having conductivity.

  According to the present invention, a shock-absorbing material having thermal conductivity disposed between a member that generates heat and a casing that covers the member that generates heat and radiates heat of the member, and has excellent thermal conductivity and A cushioning material having cushioning properties can be provided.

It is sectional drawing explaining the structure of the battery which has arrange | positioned the shock absorbing material which concerns on embodiment of this invention.

Hereinafter, the present invention will be described in detail.
[Buffer material]
A cushioning material according to the present invention is a cushioning material having thermal conductivity and disposed between a member that generates heat and a casing that covers the member that generates heat and radiates heat of the member, and includes a resin containing an elastomer The resin composition containing (A) and a thermally conductive filler (B) having thermal conductivity is foamed, and has a buffer layer having a 25% compressive strength of 200 kPa or less.
When the range of the 25% compressive stress exceeds 200 kPa, the flexibility becomes insufficient, and the cushioning material cannot sufficiently follow the shape of the member or the case that generates heat, and sufficient sealing performance cannot be obtained. Also, if the 25% compressive strength exceeds 200 kPa, the repulsive force will not match the strength of the housing when it is placed between the heat generating member and the housing, and the housing may be deformed or Troubles such as inability to closely contact occur.

It is preferable that a buffer material contains 40-800 mass parts of heat conductive fillers (B) with respect to 100 mass parts of resin (A) containing an elastomer. If the content of the heat conductive filler is 40 parts by mass or more with respect to the resin (A) containing the elastomer, the thermal conductivity at 25% compression of the buffer layer may be 1 to 20 W / m · K. Can contribute to the heat dissipation of the heat generating member. If content of a heat conductive filler is 800 mass parts or less, 25% compressive strength can be 200 kPa or less.
The thermal conductivity of the buffer layer at 25% compression is preferably 1 to 20 W / m · K. When the thermal conductivity of the buffer layer at 25% compression is 1 to 20 W / m · K, heat generated from a member that generates heat can be easily transmitted to a radiator such as a housing.
The thickness of the entire cushioning material is 0.5 to 10 mm. If the thickness of the entire cushioning material is 0.5 to 10 mm, it can be placed between the electronic component and the housing.
If the thickness of the buffer layer is 0.5 mm or more, it is possible to follow the irregularities on the surface of the member that generates heat. If the thickness of the buffer layer is 3 mm or less, the heat generated from the member that generates heat can be easily transmitted to a radiator such as a casing. From this viewpoint, the thickness of the buffer layer is more preferably 0.5 to 3 mm.
The expansion ratio of the buffer layer can be 1.1-4. When the expansion ratio is in the above range, an appropriate compressive strength can be obtained. For example, when used as a sealing material or a cushioning material, a member or casing that needs to be protected from gas or liquid is not deformed. The predetermined compressive strength can be maintained over the usable period of the applied product. Thereby, sealing performance can be maintained. Moreover, the function as a buffer material can be maintained over a usable period.

<Resin containing elastomer (A)>
As the elastomer forming the buffer layer constituting the buffer material according to the present invention, a thermoplastic elastomer is suitable, and a compound not containing a siloxane compound is preferable.
Examples of the thermoplastic elastomer include ethylene-propylene-diene rubber (EPDM), liquid ethylene-propylene-diene rubber, ethylene-propylene rubber (EPM), liquid ethylene-propylene rubber, acrylonitrile butadiene rubber (NBR), liquid acrylonitrile butadiene rubber, natural Rubber (NR), liquid natural rubber, polybutadiene rubber (BR), liquid polybutadiene rubber, polyisoprene rubber (IR), liquid polyisoprene rubber, styrene-butadiene block copolymer (SBR), liquid styrene-butadiene block copolymer , Hydrogenated styrene-butadiene block copolymer (SEB), liquid hydrogenated styrene-butadiene block copolymer, hydrogenated styrene-butadiene-styrene block copolymer (SEBS), liquid Hydrogenated styrene-butadiene-styrene block copolymer, hydrogenated styrene-isoprene block copolymer (SEP), liquid hydrogenated styrene-isoprene block copolymer, hydrogenated styrene-isoprene-styrene block copolymer (SEPS) And at least one selected from liquid hydrogenated styrene-isoprene-styrene block copolymers and the like.
Among them, it is preferable to use acrylonitrile butadiene rubber (NBR) from the advantage that it is easily subjected to electron beam crosslinking or chemical crosslinking and does not require a monomer as a crosslinking accelerator. Nitrile rubber is preferable because it has a small compression set and is less likely to deteriorate in airtightness due to the passage of the period of use.
Since the thermoplastic elastomer described above generally has a glass transition temperature of room temperature or lower (for example, 20 ° C. or lower), the flexibility and shape following property of the buffer layer can be increased. Thereby, it can deform | transform so that a buffer layer may follow the shape of the member which heat | fever-generates, and a contact area with this member increases. Therefore, the efficiency of heat conduction to the housing can be increased.

<Thermal conductive filler (B)>
The thermally conductive filler is preferably an insulating material, and includes at least one selected from aluminum oxide, magnesium oxide, boron nitride, talc, and aluminum nitride. Among these, it is preferable to use aluminum oxide.
In addition, carbonaceous materials such as graphite, graphene, carbon black, carbon fiber, carbon nanotube, and carbon nanohorn have high thermal conductivity and are useful as a thermally conductive filler.

<Bulk layer>
The buffer material may have a bulk layer bonded to the buffer layer. In the present embodiment, the bulk layer is preferably a layer that has lower flexibility and higher heat dissipation than the buffer layer. The method for joining the bulk layer and the buffer layer is not particularly limited. For example, there are thermal lamination, double-sided tape, adhesive material coating, and the like.
The bulk layer is preferably rubber or elastomer. The bulk layer may be formed of the same resin as the elastomer that forms the buffer layer described above. You may use resin containing the elastomer mentioned above without foaming. When the resin containing the elastomer described above is used as a bulk layer by foaming, it is preferable to set the expansion ratio lower than the expansion ratio of the buffer layer. The bulk layer may be formed by stacking a plurality of layers formed using at least one selected from rubber, an elastomer that forms a buffer layer, and other elastomers.
When the buffer material has a bulk layer and a buffer layer, the buffer layer is disposed so as to be in contact with the member that generates heat, and the bulk layer is disposed so as to be in contact with the casing.
Thereby, since the buffer layer is deformed so as to follow the shape of the member that generates heat, the contact area with the member that generates heat increases. Moreover, the heat conduction efficiency to a housing | casing can be improved by arrange | positioning a bulk layer with high heat conductivity so that a housing | casing may be contact | connected. Therefore, the heat dissipation efficiency of the heat generated from the member that generates heat can be increased.

<Other additives>
Various additives can be blended with the resin forming the buffer layer as needed, as long as the object of the present invention is not impaired. The kind of additive is not particularly limited, and various additives that are usually used for forming a buffer layer can be used.
Examples of such additives include lubricants, shrinkage inhibitors, fillers, flame retardants, cell nucleating agents, crystal nucleating agents, plasticizers, pigments, dyes, ultraviolet absorbers, antioxidants, anti-aging agents, and shrinkage. Examples thereof include an inhibitor, a reinforcing agent, an antistatic agent, a surfactant, a vulcanizing agent, and a surface treatment agent.
The addition amount of these additives can be appropriately selected within a range not impairing the formation of bubbles and the like, and the addition amount used for foam molding of ordinary resins can be adopted. In addition, an additive can be used individually or in combination of 2 or more types.

[Method of manufacturing cushioning material]
<Manufacturing method 1>
The manufacturing method of the buffer material of this invention should just be a method which can form a bubble in resin (A) containing an elastomer, and what is called a batch system, a continuous system, etc. can be applied.
By extruding a resin composition (referred to as a raw material composition) containing a resin (A) containing an elastomer and a heat conductive filler (B) using an extruder such as a single screw extruder or a twin screw extruder, a raw material composition Objects can be processed into sheets. Alternatively, the raw material composition is kneaded with a kneader such as a Banbury mixer or a pressure kneader, and then continuously conveyed while kneading using a calendar, an extruder, a conveyor belt casting, etc. It is processed into a sheet having a predetermined thickness.
The processed raw material composition is put in a high-pressure vessel, and a gas composed of carbon dioxide, nitrogen, air, or the like is injected at a high pressure to impregnate the raw material composition with the gas. When the high-pressure gas is sufficiently impregnated, the pressure is released (usually up to atmospheric pressure), and bubble nuclei are generated in the raw material composition. Bubble nuclei may be grown at room temperature, but may be grown by heating.
After the bubbles are grown, the raw material composition is cooled with cold water or the like to fix the shape of the bubbles formed in the raw material composition. Thereby, a buffer layer can be obtained.
In addition, a raw material composition can use a thing of various shapes according to a use. Moreover, the molded object used for foaming can also be produced by other molding methods such as injection molding in addition to extrusion molding and press molding.

(Foaming agent used in production method 1)
In the manufacturing method described above, it is preferable to use a high-pressure inert gas as the foaming agent. The inert gas that can be used is not particularly limited as long as it is inert to the resin containing the elastomer and can be injected into the raw material composition. For example, carbon dioxide, nitrogen gas, air and the like can be mentioned. You may mix and use these inert gas. Of these inert gases, carbon dioxide having a large amount of impregnation into the raw material composition and a high impregnation rate is preferable.
When impregnating the raw material composition with an inert gas, the inert gas is preferably in a supercritical state. In the supercritical state, since the solubility of the inert gas in the raw material composition increases, the concentration of the inert gas mixed into the raw material composition can be increased. When a high-concentration inert gas is mixed in the raw material composition, more bubble nuclei are generated when the pressure is dropped rapidly after the raw material composition is impregnated with the inert gas. For this reason, the density of bubbles formed by the growth of bubble nuclei is increased, and fine bubbles can be obtained with respect to the porosity.
Carbon dioxide has a critical temperature of 31 ° C. and a critical pressure of 7.4 MPa.

(Foaming treatment in production method 1)
In the production method 1, the pressure condition for impregnating the raw material composition with the inert gas can be appropriately selected in consideration of the kind of the inert gas, the operability in production, etc., but it is 6 MPa or more (for example, 6 to 100 MPa) Degree), preferably 8 MPa or more (for example, about 8 to 100 MPa). When the pressure is 6 MPa or more, a bubble diameter and a bubble density suitable for the buffer layer of the present invention can be obtained.
When carbon dioxide is used as the inert gas, the pressure condition is preferably about 5 to 100 MPa (preferably about 7.4 to 100 MPa).
The lower the pressure when impregnating the raw material composition with the inert gas, the smaller the amount of impregnation of the gas, so the rate at which bubble nuclei are formed decreases and the number of bubble nuclei decreases. In this case, the amount of gas per bubble increases, and the bubble diameter easily grows when the pressure is released.
For this reason, when the pressure is lower than 6 MPa, the bubble diameter tends to grow large, which is not suitable for obtaining bubbles having an average cell diameter (average bubble diameter) of about 200 μm or less.

The temperature condition for impregnating the raw material composition with the inert gas can be appropriately selected depending on the inert gas and the raw material composition to be used, but considering the operability in production, for example, about 10 to 350 ° C. It is preferable. In a continuous method in which the raw material composition impregnated with an inert gas is extruded and foamed simultaneously with molding, the temperature is preferably 60 to 350 ° C.
In addition, when using a carbon dioxide as an inert gas, in order to hold | maintain the supercritical state mentioned above, it is preferable to set to 32 degreeC or more, especially 40 degreeC or more.
The mixing amount of the inert gas is not particularly limited, but is preferably 1 to 15% by mass, more preferably 2 to 12% with respect to the total amount of the raw material composition from the viewpoint of foamability and the average cell size. It is mass%, More preferably, it is 3-10 mass%.

<Manufacturing method 2>
The buffer layer of the present invention can also be produced by using a thermally decomposable foaming agent that decomposes by heating to generate foaming gas.
In the production method 2, a composition in which a pyrolytic foaming agent is further added to a raw material composition containing a resin containing an elastomer and a heat conductive filler (referred to as a foamable raw material composition) is used. You may mix | blend a crosslinking agent, a filler, etc. with a foaming raw material composition as needed.
In production method 2, a foamable raw material composition is prepared, and the foamable raw material composition is kneaded by a kneader such as a Banbury mixer or a pressure kneader. Thereafter, the foamable raw material composition is processed into a sheet by continuously conveying it while kneading using a calendar, an extruder, a conveyor belt casting or the like. After processing, the foamable raw material composition is heated to foam the pyrolytic foaming agent.
When it is necessary to crosslink the foamable raw material composition, the pyrolytic foaming agent is foamed after the foamable raw material composition is crosslinked. Alternatively, the foamable raw material composition may be crosslinked after foaming the pyrolytic foaming agent.

(Foaming agent used in production method 2)
The foaming agent is not particularly limited as long as it is a thermal decomposition type foaming agent that decomposes by heating to generate a foaming gas. For example, azodicarbonamide, benzenesulfonylhydrazide, dinitrosopentamethylenetetramine, toluene Examples include sulfonyl hydrazide and 4,4′-oxybis (benzenesulfonyl hydrazide). These thermal decomposition type foaming agents may be used independently and 2 or more types may be used together.
The amount of the pyrolyzable foaming agent in the foamable raw material composition is preferably 3 to 35 parts by mass, more preferably 6 to 33 parts by mass with respect to 100 parts by mass in total with the resin containing the elastomer. More preferably, it is 12 to 32 parts by mass. If a compounding quantity is the said range, the foaming ratio of a buffer layer can be 1.1-4.
Moreover, the foaming processing method can use a well-known method including the method described in the plastic foam handbook (Makihiro, Atsushi Kosaka edit Nikkan Kogyo Shimbun 1973).

(Crosslinking treatment in production method 2)
In the production method 2, the cross-linking treatment performed as necessary may be a physical cross-linking treatment using ionizing radiation or a chemical cross-linking treatment using an organic peroxide or a sulfur compound.

(Chemical cross-linking treatment)
Examples of the crosslinking agent that can be used for the chemical crosslinking treatment include organic peroxides, sulfur, and sulfur compounds. Of these, organic peroxides are preferable. Examples of the organic peroxide include diisopropylbenzene hydroperoxide, 2,4-dichlorobenzoyl peroxide, benzoyl peroxide, t-butyl perbenzoate, cumyl hydroperoxide, t-butyl hydroperoxide, 1,1. -Di (t-butylperoxy) -3,3,5-trimethylhexane, n-butyl-4,4-di (t-butylperoxy) valerate, α, α'-bis (t-butylperoxyisopropyl) ) Benzene, 2,5-dimethyl-2,5-di (t-butylperoxy) hexyne-3, t-butylperoxycumene and the like.
Examples of the sulfur compound include tetramethylthiuram disulfide, tetramethylthiuram monosulfide, zinc dimethyldithiocarbamate, 2-mercaptobenzothiazole, dibenzothiazyl disulfide, N-cyclohexyl-2-benzothiazolesulfenamide, Nt- Examples include butyl-2-benzothiazole sulfenamide, sulfur monochloride, sulfur dichloride and the like.

  The one minute half-life temperature of the crosslinking agent used in the chemical crosslinking treatment is preferably higher than the decomposition temperature of the thermally decomposable foaming agent. By using such a pyrolytic foaming agent and a crosslinking agent, crosslinking can be performed after foam molding. In addition, a buffer layer having high dimensional stability and high magnification and a high degree of crosslinking can be obtained. Here, the decomposition temperature of the pyrolytic foaming agent refers to a temperature at which the pyrolytic foaming agent starts to decompose rapidly, and specifically, a condition of a heating rate of 1 ° C./min by thermogravimetric analysis (TG). It is the temperature at which the mass is reduced by 50% when measured below.

  Although the compounding quantity of the crosslinking agent in a foamable raw material composition can be adjusted suitably, it is preferable that it is 0.1-7 mass parts with respect to 100 mass parts of elastomers, and 0.5-4 mass parts It is more preferable that When the blending amount of the crosslinking agent is within this range, the foaming agent foams well and closed cells can be formed.

(Physical crosslinking treatment)
Examples of the ionizing radiation used in the physical cross-linking treatment include ultraviolet rays, γ rays, and electron beams, and it is preferable to use electron beams. The amount of irradiation in the case of an electron beam can be appropriately adjusted depending on the characteristics of the elastomer and the use of the buffer layer. For example, 0.5 to 10 Mrad is preferable, and 0.7 to 5.0 Mrad is more preferable. There are no restrictions on the electron beam source, but for example, various electron beam accelerators such as Cockloft Walton type, Bandegraft type, resonant transformer type, insulated core transformer type, linear type, dynamitron type, and high frequency type may be used. it can.
When ultraviolet rays are used as the ionizing radiation, ultraviolet rays having a wavelength of 190 to 380 nm are preferably included. Although there is no restriction | limiting in an ultraviolet-ray source, For example, a high pressure mercury lamp, a low pressure mercury lamp, a metal halide lamp, a carbon arc lamp, etc. are used.
When selecting a physical cross-linking treatment using ionizing radiation, it is preferable that the foamable raw material composition contains a conventionally known photopolymerization initiator in an appropriate amount.

[Battery configuration]
FIG. 1 is a longitudinal sectional view schematically showing a configuration of a battery 1 to which a cushioning material according to an embodiment of the present invention is applied.
The battery 1 includes a cell 2, an outer case 3 that covers the cell, and a buffer material 4 that is disposed between the cell 2 and the outer case 3. In the battery 1 shown in FIG. 1, the cell 2 corresponds to a member that generates heat. The outer case 3 corresponds to a housing that covers a member that generates heat and radiates the heat of the member.
The cell 2 includes a cell main body portion 21 and an electrode portion 22 drawn from the cell main body portion 21. Although not shown in the figure, the cell main body 21 includes a positive electrode composed of a positive electrode current collector and a positive electrode active material layer, a negative electrode composed of a negative electrode current collector and a negative electrode active material layer, a separator, etc. for functioning as a battery. It is. The electrode part 22 is drawn out from the cell body part 21. Although not shown, a lead portion is connected to each electrode portion 22. The lead portion is electrically connected to a connection terminal formed on the outer surface of the outer case 3.
The buffer material 4 is disposed between the battery 1 and the outer case 3. The buffer material 4 includes a buffer layer 41 disposed so as to be in contact with the electrode portion 22 and a bulk layer 42 disposed so as to be in contact with the exterior case 3. Note that the bulk layer 42 is not necessarily arranged.
Between the cell main body 21 and the outer case 3, a buffer material 4 having thermal conductivity is disposed. By disposing the buffer material 4 having thermal conductivity, heat generated from the cell main body 21 of the battery 1 is quickly transmitted to the exterior case 3 via the buffer material 4. The outer case 3 is preferably formed of a metal material in order to enhance the heat dissipation effect. Further, since the buffer material 4 having thermal conductivity has a 25% compressive strength of 200 kPa or less, it has flexibility to buffer the twist of the outer case 3 and vibration transmitted to the outer case 3.
FIG. 1 shows a state in which the buffer material 4 is arranged around the electrode portion 22 constituting the cell 2. The place where the buffer material 4 is disposed is not limited to the periphery of the electrode portion 22. For example, you may arrange | position between the cells 2 and between the cell 2 and the exterior case 3.
The thickness of the entire cushioning material can be 0.5 to 10 mm. If the thickness of the entire cushioning material is 0.5 to 10 mm, it can be placed between the electronic component and the housing.

The present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples. [Measurement Method]
<25% compressive strength>
It measured by the method based on JISK6767 using the test piece of the buffer material of an Example and a comparative example.

<Thermal conductivity>
Thermal conductivity was measured as follows. An acrylic plate with a length of 50 mm × width 100 mm × thickness 1 mm and a heater (length 25 mm × width 25 mm × thickness 2 mm) (Sakaguchi Electric Heating Co., Ltd., Micro Ceramic Heater MS5) are placed on the heat insulating material. 25 mm wide sample pieces were stacked. An aluminum plate having a length of 50 mm, a width of 100 mm, and a thickness of 2 mm was placed on the sample piece, and the acrylic plate and the aluminum plate were fastened with bolts to transfer the heat of the sample piece to the aluminum plate. The acrylic plate and the aluminum plate were clamped so that the sample piece was in a state compressed by 25%. In this state, 1 W of electric power was applied to the heater, and the heater temperature after 15 minutes was measured. In the case of only the heater, when the electric power of 1 W is applied for 15 minutes, the temperature of the heater surface becomes 60 ° C. That is, when a measurement structure is manufactured and the same power is applied, if the temperature of the heater surface is lower than in the case of only the heater, it means that the heat is removed from the surface. The results are shown in Table 1.

[Examples 1 to 3, Comparative Examples 1 and 2]
<Example 1>
Acrylonitrile-butadiene rubber (NBR, manufactured by Nippon Zeon Co., Ltd., trade name “Nipol 1041”, density: 1.00 g / cm ³ , acrylonitrile component: 40.5% by mass) 100 parts by mass, azodicarbonamide (Otsuka Chemical Co., Ltd.) Manufactured, trade name "SO-L") 15 parts by mass, aluminum oxide (Micron Corporation, spherical alumina, trade name "AX3-32",
400 parts by weight of an average particle size of 3 μm) 0.1 parts by weight of a phenolic antioxidant (manufactured by Ciba Specialty Chemicals, trade name “Irganox 1010”) was melted in an extruder, kneaded, and then pressed. A resin sheet having a thickness of 1.6 mm was obtained.
Both surfaces of this resin sheet were irradiated with 1.2 Mrad of an electron beam having an acceleration voltage of 1000 kev to crosslink the resin sheet. The crosslinked resin sheet was foamed by heating to 250 ° C. to obtain a buffer layer A having an apparent density of 0.99 g · cm ³ and a thickness of 2.0 mm.
The buffer material formed using the manufactured buffer layer A was evaluated by the above evaluation method. The results are shown in Table 1.

<Example 2>
The formulation was the same as in Example 1, and the thickness of the resin sheet after pressing was 0.85 mm. The resin sheet was foamed to obtain a buffer layer B having an apparent density of 0.99 g · cm ³ and a thickness of 1.0 mm. Next, a composition having the same formulation as that of the buffer layer B was pressed to obtain a bulk layer having a thickness of 1.0 mm. The buffer layer B and the bulk layer were bonded together with a double-sided tape (double tack tape 3801 10 μm manufactured by Sekisui Chemical Co., Ltd.) to obtain a buffer material having a total thickness of 2.0 mm.

<Example 3>
70 parts by mass of ethylene-propylene-diene rubber (manufactured by JSR Corporation, trade name “EP21”, trade name “EP21”, density: 0.86 g / cm ³ , propylene content: 34% by mass), liquid ethylene-propylene-diene rubber (Mitsui Chemicals, trade name “PX-068”, density: 0.9 g / cm ³ , propylene content: 39% by weight) 30 parts by mass, azodicarbonamide (made by Otsuka Chemical Co., Ltd., trade name “SO -L ") 15 parts by mass, aluminum oxide (Micron Corporation, spherical alumina, trade name" AX3-32 ", average particle size 3 µm) 400 parts by mass, phenolic antioxidant (Ciba Specialty Chemicals, Inc., product) Name “Irganox 1010”) 0.1 parts by mass was melted in an extruder, kneaded, and then pressed to obtain a resin sheet having a thickness of 0.4 mm. .
Both surfaces of this resin sheet were irradiated with 2.0 Mrad of an electron beam with an acceleration voltage of 500 kev to crosslink the resin sheet. The crosslinked resin sheet was foamed by heating to 250 ° C. to obtain a buffer layer C having an apparent density of 0.56 g / cm ³ and a thickness of 0.5 mm.
Next, a composition having the same formulation as that of the buffer layer C was pressed to obtain a bulk layer having a thickness of 1.5 mm. The buffer layer B and the bulk layer were bonded together with a double-sided tape (double tack tape 3801 10 μm manufactured by Sekisui Chemical Co., Ltd.) to obtain a buffer material having a total thickness of 2.0 mm.

<Reference Example 1>
As a comparative buffer layer A, a silicone gel having a thermal conductivity processed into a sheet (trade name “λ gel COH-4000” manufactured by Taika Co., Ltd., thickness 2.0 mm, thermal conductivity 6.5 W / m ·
K) was evaluated by the above evaluation method. The results are shown in Table 1.

<Comparative Example 1>
As the comparative buffer layer B, a heat conductive sheet (manufactured by 3M, trade name “Hypersoft heat dissipation material 5590H”, thickness 2.0 mm, heat conductivity 3.0 W / m · K) was evaluated by the above evaluation method. The results are shown in Table 1.

  As is apparent from Table 1, Examples 1 and 2 did not contain a siloxane compound, but were found to have thermal conductivity comparable to that of Conventional Reference Example 1. Therefore, the cushioning material of Examples 1 and 2 can be used in the electronic equipment field. Although Comparative Example 1 did not contain a siloxane compound, it was found that it was not suitable for practical use because it had a high 25% compressive strength and a desired buffer property could not be obtained. That is, it was found that the samples of Examples 1 and 2 were excellent in both thermal conductivity and buffering properties.

  DESCRIPTION OF SYMBOLS 1 ... Battery, 2 ... Cell, 3 ... Exterior case, 4 ... Buffer material, 21 ... Cell main-body part, 22 ... Electrode part, 41 ... Buffer layer, 42 ... Bulk layer

Claims (9)

A buffer material having thermal conductivity disposed between a member that generates heat and a casing that covers the member that generates heat and radiates heat of the member,
A buffer material having a buffer layer having a 25% compressive strength of 200 kPa or less obtained by foaming a resin composition containing a resin (A) containing an elastomer and a thermally conductive filler (B) having thermal conductivity.   The buffer material according to claim 1, wherein the buffer layer has a thermal conductivity of 1 to 20 W / m · K at 25% compression.   The buffer material according to claim 1, further comprising a bulk layer bonded to the buffer layer, wherein the thermal conductivity of the bulk layer is higher than the thermal conductivity of the buffer layer at 25% compression.   The buffer material in any one of Claims 1-3 containing 40-800 mass parts of heat conductive fillers (B) with respect to 100 mass parts of resin (A) containing the said elastomer.   The cushioning material according to any one of claims 1 to 4, wherein the expansion ratio of the buffer layer is 1.1 to 4.   The buffer material according to claim 1, wherein the thermally conductive filler is at least one selected from aluminum oxide, magnesium oxide, and boron nitride.   The cushioning material according to claim 1, wherein the resin does not contain a siloxane compound.   The buffer material according to any one of claims 1 to 7, wherein the entire buffer material has a thickness of 0.5 to 10 mm.   The buffer material according to claim 8, wherein the buffer layer has a thickness of 0.5 to 3 mm.