JP2009073932A - Oligomer ester and composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide highly safe oligomer esters excellent in solubility and dispersibility to water and in lubricity, and aqueous or water-soluble compositions containing the oligomer esters and having excellent safety, lubricity and cooling properties, and cosmetic/skin external preparations containing the oligomer esters and reducing stickiness. <P>SOLUTION: The oligomer esters are composed of the following components (A) and (B): (A) one kind of or two or more kinds of bivalent carboxylic acid including a 2-36C normal/branched chain or a ring structure; (B) one or two or more polyglycerol having the average polymerization degree of 2-15 calculated from a hydroxyl value, and glycerin. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

The present invention relates to oligomer esters, water-based and water-soluble lubricating compositions having good safety, lubricity and cooling properties containing these oligomer esters, and cosmetics in which stickiness is suppressed by blending these oligomer esters. Or it relates to a skin external preparation. More specifically, an oligomer ester synthesized from the following components (A) and (B), and an aqueous / water-soluble solution having good safety, lubricity, and cooling properties characterized by containing these oligomer esters. The present invention relates to a cosmetic lubricant composition, and a cosmetic or a skin external preparation in which stickiness is suppressed by blending these oligomer esters.
(A) One or more divalent carboxylic acids containing a straight chain, branched chain, or cyclic structure having 2 to 36 carbon atoms.
(B) One or more polyglycerols having an average degree of polymerization calculated from the hydroxyl value of 2 to 15, and glycerol.

  In general, lubricants are roughly classified into liquid lubricants, semi-solid lubricants, and solid lubricants. Liquid lubricants among these are further classified into animal and vegetable oils / petroleum lubricants, synthetic lubricants, and water-based / water-soluble lubricants. being classified. For water-based and water-soluble lubricants, metal working fluids used in metal cutting, grinding, wire drawing, etc., hydraulic fluids that are pressure transmission media in hydraulic systems, etc., and lubrication of working parts such as machines and devices Fluids or hydraulic fluids, lubricants used in machining machinery / equipment, rust preventive lubricants used in cleaning systems, coolants used in metal cleaning / grinding / cutting / plastic processing, and quenching and tempering steel There are liquids. Examples of the form of the aqueous / water-soluble lubricant solution include a transparent type, an O / W emulsion type, a W / O emulsion type, a W / O / W emulsion type, and an emulsion type such as an O / W / O emulsion type. .

  In particular, water-based and water-soluble lubricants have been used in recent years because of high safety in the storage and transportation of fire-fighting laws and regulations, as well as the processing parts and processing tools during metal cutting, grinding, and wire drawing. Because it is extremely hot, non-flammable and cooling lubricants are required, and even if the lubricant splashes during metal cutting, grinding, and wire drawing, safety, contamination, and environmental impact are excellent. This is because there is a need for lubricating fluids, and hydraulic fluids for hydraulic equipment such as welding robots for steel equipment, die casting machines, and automobile assembly equipment are also required to have flame resistance to prevent accidents in the event of a fire. is there.

  In recent years, water-based and water-soluble lubricating components used for such purposes include propylene oxide-ethylene oxide-propylene oxide structure block type polyalkylene oxide (Patent Document 1), alcohol ethylene oxide addition type nonionic surface activity And polyalkylene glycol-based oils such as propylene oxide terminal addition type nonionic surfactants (Patent Documents 2 and 4) and polyalkylene glycols (Patent Document 3) are known. However, alcoholic ethylene oxide addition type nonionic surfactants have the problem that they are chemical substances that fall under the Chemical Substance Emission Control Management Promotion Act (PRTR method), and these polyalkylene glycol oils are safe. The lubricity is not enough. As substances that have improved the safety and lubricity of these polyalkylene glycol oils, the present inventors have proposed oligomer esters synthesized from divalent carboxylic acids and polyglycerin (Patent Documents 5 and 6, Non-patent literature 1) still has problems to be improved in terms of performance and economy, and further, a lubricating composition having high safety and lubricity and excellent economy has been desired.

On the other hand, in the field of cosmetics or skin external preparations, glycols, fats, polysaccharides, and the like have been conventionally used for the purpose of protecting skin, moisturizing, etc., but these components are used alone. Although the moisturizing effect and the like are excellent, cosmetics or skin external preparations containing these in a high concentration in order to have high moisturizing properties have a drawback that the touch is sticky. So far, substances that suppress the sticky feeling have been developed, but the suppression of the sticky feeling of cosmetics or external preparations for skin has not been satisfactory. From these backgrounds, a substance capable of suppressing stickiness has been desired in order to improve the feel of cosmetics or external preparations for skin.
JP-A-8-239683 Japanese Patent Application Laid-Open No. 2002-212584 JP 2006-83378 A JP 2006-96826 A JP 2007-137847 A Japanese Patent Application No. 2007-086442 Public Technical Publication No. 2006-505658

  The problem to be solved by the present invention is an oligomer ester having high safety, excellent solubility in water, dispersibility, good lubricity, and safety, lubricity, and cooling properties containing these oligomer esters. It is an object of the present invention to provide a good water-based / water-soluble lubricating composition and a cosmetic or external preparation for skin in which stickiness is suppressed by blending these oligomer esters.

As a result of intensive studies to solve the above problems, the present inventors have found that oligomer esters synthesized from the following components (A) and (B) have high safety, solubility in water, and dispersibility. It was found to be excellent in lubricity. Furthermore, the oligomeric ester has excellent lubricity when applied to the skin, that is, it has a smooth and good feel, and is added to cosmetics or skin external preparations to suppress the stickiness of cosmetics or skin external preparations. As a result, the present invention has been completed.
(A) One or more divalent carboxylic acids containing a straight chain, branched chain, or cyclic structure having 2 to 36 carbon atoms.
(B) One or more polyglycerols having an average degree of polymerization calculated from the hydroxyl value of 2 to 15, and glycerol.
That is, the present invention is an oligomer ester synthesized from components (A) and (B), and an aqueous / water-soluble lubricating composition having good safety, lubricity and cooling properties containing these oligomer esters, and It is intended to provide a cosmetic or skin external preparation in which the sticky feeling is suppressed by blending these oligomer esters.

  The oligomer ester of the present invention has high safety, excellent solubility in water, dispersibility, and good lubricity. The water-based and water-soluble lubricating composition containing these oligomer esters is safe and lubricious. The cosmetics and the external preparation for skin containing these oligomeric esters have a good feeling in which the sticky feeling is suppressed.

In the present invention, it is essential to use an oligomer ester synthesized from the following components (A) and (B).
(A) One or more divalent carboxylic acids containing a straight chain, branched chain, or cyclic structure having 2 to 36 carbon atoms.
(B) One or more polyglycerols having an average degree of polymerization calculated from the hydroxyl value of 2 to 15, and glycerol.

  The carboxylic acid that can be used in the production of the oligomer ester of the present invention is a divalent carboxylic acid containing a linear, branched, or cyclic structure having 2 to 36 carbon atoms, and substantially contains a monovalent carboxylic acid. This is a feature of the present invention. Specific examples of the divalent carboxylic acid that can be used include oxalic acid, malonic acid, succinic acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, 2,4-diethylpentanedioic acid, Polymerizes undecanedioic acid, dodecanedioic acid, tridecanedioic acid, tetradecanedioic acid, pentadecanedioic acid, hexadecanedioic acid, octadecanedioic acid, 8-ethyloctadecanedioic acid, eicosanedioic acid, dimethyleicosane diacid, unsaturated fatty acid Examples of the dimer acid, hydrogenated dimer acid, and cyclohexanedicarboxylic acid that are obtained in this manner. These divalent carboxylic acids may be used alone or in combination of two or more.

When the average number of carbon atoms of the divalent carboxylic acid (the number of carbon atoms when used alone) is low, the lubricity due to the hydrocarbon group of the divalent carboxylic acid is lowered. Therefore, the average number of carbon atoms is preferably 6 or more. On the other hand, if the average number of carbons is too large, compatibility with polyglycerin at the reaction temperature is lacking, so that a local reaction occurs at the interface, resulting in partial production of a high polymer. In order not to cause such a local reaction, the average number of carbon atoms of one or more divalent carboxylic acids is preferably 19 or less. Accordingly, as one or more divalent carboxylic acids used in the present invention, one or more divalent carboxylic acids containing a linear, branched or cyclic structure having 2 to 22 carbon atoms are used. And the average number of carbon atoms is 6-19. Specifically, oxalic acid, malonic acid, succinic acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, 2,4-diethylpentanedioic acid, undecanedioic acid, dodecanedioic acid, tridecanedioic acid, More preferably, it is selected from tetradecanedioic acid, pentadecanedioic acid, hexadecanedioic acid, octadecanedioic acid, 8-ethyloctadecanedioic acid, eicosanedioic acid, dimethyleicosanedioic acid, and cyclohexanedicarboxylic acid. Most preferably, at least one of the species or two or more species is sebacic acid. Here, the average carbon number is a numerical value obtained by the following equation.
(Formula 1)
Average carbon number = Σ [(carbon number of each divalent carboxylic acid) × (molar fraction of each divalent carboxylic acid)]

As polyglycerol used for manufacture of the oligomer ester of this invention, it is a polyglycerol with an average degree of polymerization computed from the hydroxyl value of 2-15. As such polyglycerin, for example, diglycerin S, polyglycerin # 310, ditto # 500, ditto # 750, etc. manufactured by Sakamoto Pharmaceutical Co., Ltd. are commercially available. If the average degree of polymerization is low, the number of unreacted hydroxyl groups is reduced and the hydrophilicity is poor, and if the average degree of polymerization is high, the lubricating performance tends to decrease. Therefore, the average degree of polymerization calculated from the hydroxyl value is more preferably 6 to 6. 12 polyglycerols. Here, the average degree of polymerization calculated from the hydroxyl value is a numerical value obtained by the following formula.
(Formula 2)
If A = 56.1 × 1000 / hydroxyl value, average polymerization degree = (2 × A-18.0) / (74.1-A)

  Although the manufacturing method of the oligomer ester of this invention is not specifically limited, It can obtain by carrying out esterification reaction of a component (A) and a component (B). In the production of the oligomer ester of the present invention, the polymerization degree of the resulting oligomer ester can be adjusted by changing the respective charging ratios of the component (A) and the component (B). If the component (A) is less than the component (B), sufficient lubricating performance cannot be obtained. Moreover, when there are many components (A) with respect to a component (B), a viscosity will become high corresponding to a polymerization degree, and manufacture will become difficult. Therefore, a preferable range of the charging ratio is 0.3 to 1.5 mol of component (A) with respect to 1.0 mol of component (B), and a more preferable range is 1.0 mol of component (B). On the other hand, the component (A) is 0.4 to 1.2 mol.

  In the production of the oligomer ester of the present invention, it is important for the component (B) to use polyglycerin and glycerin together, and by using glycerin together, the lubricity is superior to the case where polyglycerin is used alone. Oligomeric esters can be obtained. Moreover, using glycerin together is also advantageous from the economical aspect. In component (B), if the ratio of glycerin to polyglycerin is high, the hydrophilicity becomes poor. Conversely, if the ratio of glycerin to polyglycerin is low, sufficient lubricating performance cannot be obtained. Therefore, the preferable range of the charging ratio of each of the polyglycerol and glycerol as the component (B) is a molar ratio of glycerol and polyglycerol of 10: 1 to 1: 1, and a more preferable range is that of glycerol and polyglycerol. The molar ratio is 7: 1 to 1.5: 1, and the most preferable range is that the molar ratio of glycerin to polyglycerin is 4.5: 1 to 2: 1.

  The conditions for the esterification reaction are not particularly limited, and the reaction is performed by a commonly used method. For example, p-toluenesulfonic acid, sulfuric acid, hydrochloric acid, methanesulfonic acid, boron trifluoride diethyl ether complex or the like can be used as a catalyst, and a suitable solvent can be used at 50 to 260 ° C. Alternatively, the esterification can be carried out at 150 to 260 ° C. even without solvent and without catalyst. A more preferable method is a method of performing esterification at 150 to 260 ° C. without solvent and without catalyst. The oligomer ester thus obtained can be used as it is in an aqueous / water-soluble lubricating composition and cosmetics or a skin external preparation, but further purified by distillation, decolorization, deodorization and the like by a usual method as necessary. Can also be used.

  The oligomeric ester obtained as described above has a structure with high biodegradability and low environmental impact, high safety to humans, and high hydrophilicity and water content. Therefore, it is possible to provide a lubricating composition having good safety, lubricity and cooling properties. In addition, it is possible to provide a cosmetic or skin external preparation that can be easily blended into a cosmetic or skin external preparation containing water and that has a good feel with a reduced stickiness.

  On the other hand, the water-based and water-soluble lubricating composition containing the oligomer ester of the present invention may contain water, preservatives, and the like in addition to the oligomer ester as long as the preferable effects of the present invention are not impaired. Furthermore, additive components generally blended in lubricants such as extreme pressure agents, corrosion inhibitors, rust inhibitors, lubricant additives, pH adjusters, sequestering agents, surfactants, solvents, thickeners, An antioxidant, an antifoaming agent, a coloring agent, etc. can be mix | blended. The blending amount of the oligomer ester of the present invention in the aqueous / water-soluble lubricating composition is not particularly limited, but is preferably about 0.1 to 90% by weight, more preferably 1 to 60% by weight.

  Examples of these ingredients include hydroxybenzoic acid such as methylparaben, ethylparaben, propylparaben and butylparaben and salts or esters thereof; hexahydro-1,3,5-tris (2-hydroxyethyl) Triazines such as -1,3,5-triazine; 1,2-benzisothiazolin-3-one, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-methyl-4-isothiazoline-3- Isothiazolinone derivatives such as ON; phenols such as o-phenylphenol, sodium o-phenylphenol, 2,3,4,6-tetrachlorophenol, phenol, isopropylphenol, cresol, thymol, parachlorophenol; Halogenated bisphenols, acids Midos, quaternary ammonium salts; trichlorocarbanide, zinc pyrithione, benzalkonium chloride, benzethonium chloride, sorbic acid, chlorhexidine, chlorhexidine gluconate, halocarban, hexachlorophene, hinokitiol, salicylic acid; sodium benzoate; phenoxyethanol; Preferred are 1,2-diols such as pentanediol and 1,2-hexanediol; phenylethyl alcohol; imidazolinium urea; dehydroacetic acid and its salts.

  Examples of extreme pressure agents include sulfur compounds such as dibenzyl disulfide and sulfurized fatty esters, and phosphorus compounds such as tricresyl phosphate. Corrosion inhibitors include benzotriazole, mercaptobenzothiazole, sodium gluconate, and succinic acid. Examples of the antirust agent include carboxylic acids and salts thereof, sulfonic acids and salts thereof, amines and salts thereof, esters, ethers, and fats.

  Lubricating additives include hydrocarbon compounds such as alpha olefin oligomers, polybutenes, alkylbenzenes, cycloalkanes; 2-ethylhexanoic acid, caprylic acid, nonanoic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid , Fatty acids derived from isostearic acid, oleic acid, lanolin, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, 2,4-diethylpentanedioic acid, undecanedioic acid, dodecanedioic acid, tridecanedioic acid, tetradecanediic acid Aliphatic carboxylic acids such as acids and dimer acids; 2-ethylhexanol, octanol, nonanol, decanol, dodecanol, tetradecanol, hexadecanol, octadecanol, isostearyl alcohol, oleyl alcohol, dimer diol, Aliphatic alcohols such as limethylolpropane, pentaerythritol, dipentaerythritol, neopentyl glycol; ester compounds such as esters of the above aliphatic carboxylic acids and aliphatic alcohols, polyol esters, phosphate esters; polyalkylene glycols, poly Ether compounds such as alkylene glycol alkyl ethers and phenyl ethers; Silicone compounds such as polysiloxanes and silicate esters; Fluorocarbon compounds; Mineral oil, soybean oil, rapeseed oil, castor oil, palm oil, beef tallow and other animal and vegetable oils There is.

  pH adjusters include sodium hydroxide, potassium hydroxide, magnesium hydroxide, calcium hydroxide, lithium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate, sodium sesquicarbonate, potassium sesquicarbonate, boron oxide Inorganic alkali such as sodium metaborate, ethylamine, diisopropylamine, butylamine, monoethanolamine, diethanolamine, triethanolamine, N-methylmonoethanolamine, N-ethylmonoethanolamine, N-methyldiethanolamine, N-ethyldiethanolamine, Organic alkalis such as ethylenediamine, diethylenetriamine, pyridine, piperazine, and morpholine are listed.

  Examples of sequestering agents include edetates (ethylenediaminetetraacetate) such as EDTA, EDTA2Na, EDTA3Na, and EDTA4Na; hydroxyethylethylenediamine triacetate such as HEDTA3Na; pentetate (diethylenetriaminepentaacetate); phytic acid; Phosphonic acids such as acids and salts thereof such as sodium and potassium salts; sodium oxalate; polypolyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphoric acid; sodium citrate, citric acid, alanine , Dihydroxyethylglycine, gluconic acid, ascorbic acid, succinic acid, tartaric acid and the like.

  Surfactants include polyethylene glycol, polyethylene glycol alkyl ether, polyethylene glycol dialkyl ether, polypropylene glycol, polyethylene glycol propylene glycol, polyethylene glycol propylene glycol alkyl ether, ethylene oxide homopolymer, random or block copolymer of ethylene oxide and propylene oxide. Examples thereof include polymers, alkyl ether derivatives of ethylene oxide homopolymers, alkyl ether derivatives of random or block copolymers of ethylene oxide and propylene oxide, alkylbenzene sulfonates, petroleum sulfonate salts, and fatty acid salts.

  Examples of the solvent include acetone, methanol, ethanol, propanol, ethylene glycol monoalkyl ether, ethylene glycol dialkyl ether, methyl ethyl ketone, methyl isobutyl ketone, ethylene glycol, propylene glycol, glycerin and sorbitol.

  Examples of the thickener include polycarboxylic acids and salts thereof, polyvinyl alcohol, alcohol alkylene oxide adducts, polyamine alkylene oxide adducts, and cellulose derivatives.

  Antioxidants include phenolic compounds such as 2,4-dimethyl-6-tertbutylphenol and 2,6-ditertbutyl-4-methylphenol, N-phenyl-4-octylphenylamine, N-phenylalphanaphthylamine An amine compound such as phenothiazine, a zinc phosphate compound such as zinc diallyldithiophosphate, a silicon compound as an antifoaming agent, a polyether nonionic activator, and an organic dye as a coloring agent.

  In addition to these, components generally blended as water-based / water-soluble lubricating compositions, components described in Japanese and foreign patent gazettes and patent publications (including publications and republications), etc. are publicly known. It is possible to mix | blend by the combination of these, and a compounding ratio and compounding quantity.

  The water-based / water-soluble lubricating composition of the present invention is a metal working fluid used for metal cutting / grinding / drawing, etc., hydraulic fluid that is a pressure transmission medium in a hydraulic system, etc. Lubricant or hydraulic fluid for parts, lubricant used during machining of machinery / equipment, rust preventive lubricant used in cleaning system, metal cleaning / grinding / cutting / plastic processing, used for quenching and tempering of steel It can be used as a coolant liquid or the like.

  The water-based / water-soluble lubricating composition of the present invention is an oil-in-water (O / W) type, water-in-oil (W / O) type, emulsified type such as W / O / W type, O / W / O type, and the like. It can be used in a dosage form such as a solubilized type. The obtained water-based / water-soluble lubricating composition may be used as it is, but it may be diluted 1.1 to 100 times with water or a solvent as necessary.

  On the other hand, the cosmetic or skin external preparation containing the oligomer ester of the present invention is excellent in touch and safety due to the sticky feeling suppressing function of the oligomer ester of the present invention. Although the compounding quantity to the cosmetics or skin external preparation of the oligomer ester of this invention is not specifically limited, About 0.01 to 50 weight% is preferable as an oligomer ester, More preferably, it is 0.05 to 50 weight%. Further, in the cosmetic or skin external preparation of the present invention, if necessary, water and additive components generally blended into the cosmetic or skin external preparation, for example, an oily base, a moisturizer, a touch improver, a surfactant, Polymer, thickening / gelling agent, solvent, propellant, antioxidant, reducing agent, oxidizing agent, preservative, antibacterial agent, chelating agent, pH adjuster, acid, alkali, powder, inorganic salt, UV absorption Agent, whitening agent, vitamins and derivatives thereof, anti-inflammatory agent, anti-inflammatory agent, hair growth agent, blood circulation promoter, stimulant, hormones, anti-wrinkle agent, anti-aging agent, squeeze agent, cooling sensation agent, warm feeling Agents, wound healing promoters, stimulation relieving agents, analgesics, cell activators, plant / animal / microbe extracts, antipruritic agents, exfoliating / dissolving agents, antiperspirants, refreshing agents, astringents, enzymes, nucleic acids, fragrances, A pigment | dye, a coloring agent, dye, a pigment, water, etc. can be mix | blended.

  Examples of these additive components include cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, jojoba alcohol, chimyl alcohol, seraalkyl alcohol, batyl. Higher alcohols such as alcohol, hexyldecanol, isostearyl alcohol, 2-octyldodecanol, dimer diol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylen Acid, 12-hydroxystearic acid, palmitooleic acid, oleic acid, linoleic acid, linolenic acid, erucic acid, docosahexaenoic acid, ethyl Higher fatty acids such as cosapentaenoic acid, isohexadecanoic acid, anteisohenicosanoic acid, long-chain branched fatty acid, dimer acid, hydrogenated dimer acid, and their aluminum salts, calcium salts, magnesium salts, zinc salts, potassium, sodium salts, etc. Metal soaps, and nitrogen-containing derivatives such as amides; liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin, α-olefin oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalene , Hydrocarbons such as petroleum jelly and solid paraffin; candelilla wax, carnauba wax, rice wax, wax, beeswax, montan wax, ozokerite, ceresin, paraffin wax, microcrystalline wax , Petrolatum, Fischer-Tropsch wax, polyethylene wax, ethylene / propylene copolymer and other waxes; palm oil, palm oil, palm kernel oil, safflower oil, olive oil, castor oil, avocado oil, sesame oil, tea oil, evening primrose oil, Wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rosehip oil, meadow foam oil, persic oil, tea tree oil, mint oil, corn oil, rapeseed oil, sunflower oil, wheat germ oil, linseed oil, cottonseed oil, soybean oil Vegetable oils such as peanut oil, rice bran oil, cacao butter, shea butter, hydrogenated palm oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil; beef tallow, milk fat, horse fat, egg yolk oil, mink oil, turtle Animal fats and oils such as oil; animal oils such as whale wax, lanolin and orange luffy oil Liquid lanolin, reduced lanolin, adsorption purified lanolin, lanolin acetate, acetic acid liquid lanolin, hydroxy lanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin alcohol acetate, acetic acid (cetyl lanolyl) ester, etc. Lanolins: phospholipids such as lecithin, phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingomyelin, phosphatidic acid, lysolecithin, etc .; hydrogenated soybean phospholipid, partially hydrogenated soybean phospholipid , Phospholipid derivatives such as hydrogenated egg yolk phospholipid, partially hydrogenated egg yolk phospholipid; cholesterol, dihydrocholesterol, lanosterol, dihi Sterols such as loranosterol, phytosterol, cholic acid; sapogenins; saponins; cholesteryl acetate, cholesteryl nonanoate, cholesteryl stearate, cholesteryl isostearate, cholesteryl oleate, di-N-lauroyl-L-glutamate (cholesteryl / behenyl / Octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / octyldodecyl) Acyl sarcosine alkyl esters such as N-lauroyl sarcosine isopropyl, cholesteryl 12-hydroxystearate, macadamia nut oil fatty acid cholesteryl, Steroid esters such as macadamia nut oil fatty acid phytosteryl, isostearate phytosteryl, soft lanolin fatty acid cholesteryl, hard lanolin fatty acid cholesteryl, long chain branched fatty acid cholesteryl, long chain α-hydroxy fatty acid cholesteryl; phospholipid / cholesterol complex, phospholipid / phytosterol complex Lipid complexes such as octyldodecyl myristate, hexyldecyl myristate, octyldodecyl isostearate, cetyl palmitate, octyldodecyl palmitate, cetyl octanoate, hexyldecyl octanoate, isotridecyl isononanoate, isononanoyl isononanoate, isononanoic acid Octyl, isotridecyl isononanoate, isodecyl neopentanoate, isotridecyl neopentanoate, neopentanoic acid Stearyl, octyldodecyl neodecanoate, oleyl oleate, octyldodecyl oleate, octyldodecyl ricinoleate, lanolin fatty acid octyldodecyl, hexyldecyl dimethyloctanoate, octyldodecyl erucate, isostearic acid hydrogenated castor oil, ethyl oleate, avocado oil fatty acid Ethyl, isopropyl myristate, isopropyl palmitate, octyl palmitate, isopropyl isostearate, lanolin fatty acid isopropyl, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, diisopropyl adipate, dibutyloctyl sebacate, diisobutyl adipate, dioctyl succinate , Monoalcohol carboxylic acid esters such as triethyl citrate; cetyl lactate, dii malate Oxyacid esters such as sostearyl, monoisostearic acid hydrogenated castor oil; glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, glyceryl diisostearate, tri (caprylic acid / capric acid) glyceryl, tri (caprylic acid / caprin) Acid / myristic acid / stearic acid) glyceryl, hydrogenated rosin triglyceride (hydrogenated ester gum), rosin triglyceride (ester gum), glyceryl behenate, trimethylolpropane trioctanoate, trimethylolpropane triisostearate, dioctanoic acid Neopentyl glycol, neopentyl glycol dicaprate, 2-butyl-2-ethyl-1,3-propanediol dioctanoate, propylene glycol dioleate Pentaerythrityl tetraoctanoate, hydrogenated rosin pentaerythrityl, ditrimethylolpropane triethylhexanoate, ditrimethylolpropane (isostearic acid / sebacic acid), pentaerythrityl triethylhexanoate, (hydroxystearic acid / stearic acid / rosin acid) Dipentaerythrityl, diglyceryl diisostearate, polyglyceryl tetraisostearate, polyglyceryl-10 nonaisostearate, deca (erucic acid / isostearic acid / ricinoleic acid) polyglyceryl-8, (hexyldecanoic acid / sebacic acid) diglyceryl oligoester, glycol distearate ( Ethylene glycol distearate), 3-methyl-1,5-pentanediol dineopentanoate, 2, dineopentanoic acid 2, Polyhydric alcohol fatty acid esters such as diethyl-1,5-pentanediol; diisopropyl dimerlinoleate, diisostearyl dimerdilinoleate, dimerdilinoleate di (isostearyl / phytosteryl), dimerdilinoleic acid (phytosteryl) / Behenyl), dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl), dimer dilinoleic acid dimer dilinoleyl, diisostearic dimer dilinoleyl, dimer dilinoleyl hydrogenated rosin condensate, dimer dilinol Dimer acid or dimer diol derivative such as acid-hardened castor oil, hydroxyalkyl dimer linoleyl ether; coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanola Amide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (partamide MEA), palmitic acid diethanolamide ( Fatty acid alkanolamides such as partamide DEA), palm oil fatty acid methylethanolamide (cocamidomethyl MEA); dimethicone (dimethylpolysiloxane), highly polymerized dimethicone (highly polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopenta Siloxane), phenyltrimethicone, diphenyldimethicone, phenyldimethicone, stearoxypropyldimethylamine, (aminoethylamino) (Ropyrumethicone / dimethicone) copolymer, dimethiconol, dimethiconol crosspolymer, silicone resin, silicone rubber, amino-modified silicone such as aminopropyl dimethicone and amodimethicone, cation-modified silicone, polyether-modified silicone such as dimethicone copolyol, polyglycerin-modified silicone, sugar Modified silicone, carboxylic acid modified silicone, phosphoric acid modified silicone, sulfuric acid modified silicone, alkyl modified silicone, fatty acid modified silicone, alkyl ether modified silicone, amino acid modified silicone, peptide modified silicone, fluorine modified silicone, cation modified and polyether modified silicone, Amino- and polyether-modified silicones, alkyl- and polyether-modified silicones, Silicones such as hexane-polyoxyalkylene copolymer; perfluorodecane, perfluorooctane, fluorine-based oils such as perfluoropolyether may be mentioned as preferred.

  As the humectant / feel improver, glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, Polyols such as trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol / propylene glycol copolymer and polymers thereof; diethylene glycol monoethyl ether (Ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether, etc. (Eicosandioic acid / tetradecandioic acid) water-soluble esters such as polyglyceryl-10 and tetradecandioic acid polyglyceryl-10; sugar alcohols such as sorbitol, xylitol, erythritol, mannitol, maltitol; glucose, fructose, galactose Mannose, threose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins (α-, β-, γ-cyclodextrin, and maltosylation, Modified cyclodextrins such as hydroxyalkylation), β-glucan, chitin, chitosan, heparin and derivatives, pectin, arabinogalactan, dextrin, dextran, glycogen Sugars such as ethyl glucoside, glucosyl ethyl methacrylate polymer or copolymer, and derivatives thereof; hyaluronic acid, sodium hyaluronate; chondroitin sulfate sodium; mucoitin sulfate, caroline sulfate, kerato sulfate, dermatan sulfate; white jellyfish extract, white jellyfish Polysaccharides; Fucoidan; Tuberose polysaccharides, naturally derived polysaccharides; Organic acids such as citric acid, tartaric acid and lactic acid and salts thereof; Urea; 2-pyrrolidone-5-carboxylic acid and salts thereof such as sodium; Betaine (trimethylglycine) , Proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threonine, glutamic acid, glutamine, asparagine, aspartic acid, cysteine, cystine, methio , Leucine, isoleucine, valine, tryptophan, histidine, taurine and other amino acids and salts thereof; collagen, fish-derived collagen, atelocollagen, gelatin, elastin, collagen-degrading peptide, hydrolyzed collagen, hydroxypropylammonium chloride-hydrolyzed collagen, elastin Degraded peptide, keratin degrading peptide, hydrolyzed keratin, conchiolin degrading peptide, hydrolyzed conchiolin, silk proteolytic peptide, hydrolyzed silk, lauroyl hydrolyzed silk sodium, soybean proteolytic peptide, wheat proteolytic peptide, hydrolyzed wheat protein, casein Protein peptides such as degraded peptides and acylated peptides and their derivatives; palmitoyl oligopeptide, palmitoyl pentapeptide, palmitoyl tetrapep Acylated peptides such as tide; silylated peptides; lactic acid bacteria culture solution, yeast extract, eggshell membrane protein, bovine submandibular gland mucin, hypotaurine, sesame lignan glycoside, glutathione, albumin, whey; choline chloride, phosphorylcholine; Animal and plant extract components such as placenta extract, aerostin, collagen, aloe extract, hamamelis water, loofah water, chamomile extract, licorice extract, comfrey extract, silk extract, Izayoi rose extract, yarrow extract, eucalyptus extract, and melilot extract Preferred are ceramides such as natural ceramides (types 1, 2, 3, 4, 5, 6), hydroxyceramide, pseudoceramide, glycosphingolipid, ceramide, and sugar-ceramide-containing extract.

Preferred examples of the surfactant include an anionic surfactant, a nonionic surfactant, a cationic surfactant, an amphoteric surfactant, and a polymer surfactant. There is no restriction | limiting in particular in HLB of surfactant, It can use from about 1 low thing to about 20 high thing, It is also preferable to combine a low thing and a high thing of HLB. Examples of preferable surfactants include fatty acid salts such as potassium laurate and potassium myristate; alkyl sulfates such as sodium lauryl sulfate, triethanolamine lauryl sulfate, and ammonium lauryl sulfate; laureth Polyoxyethylene alkyl sulfates such as sodium sulfate and laureth sulfate triethanolamine; cocoyl methyl taurine sodium, cocoyl methyl taurine potassium, lauroyl methyl taurine sodium, myristoyl methyl taurine sodium, lauroyl methyl alanine sodium, lauroyl sarcosine sodium, lauroyl sarcosine triethanol Acyl N-methyl amino acid salts such as amines and sodium methylalanine lauroylglutamate; Cocoyl Glue Acyl amino acid salts such as sodium minate, triethanolamine cocoyl glutamate, sodium lauroyl glutamate, sodium myristoyl glutamate, sodium stearoyl glutamate, ditriethanolamine palmitoyl aspartate, cocoylalanine triethanolamine; polyoxyethylene alkyl ethers such as sodium laureth acetate Acetic acid salt; Succinic acid ester salt such as sodium lauroyl monoethanolamide succinate; Fatty acid alkanolamide ether carboxylate; Acyl lactate; Polyoxyethylene fatty amine sulfate; Fatty acid alkanolamide sulfate; Hardened coconut oil fatty acid sodium glyceryl sulfate Fatty acid glyceride sulfate such as alkylbenzene polyoxyethylene sulfate; α-olefin Olefin sulfonates such as sodium sulfonate; alkylsulfosuccinates such as disodium lauryl sulfosuccinate and dioctyl sodium sulfosuccinate; disodium laureth sulfosuccinate, monolauroyl monoethanolamide polyoxyethylene sodium sodium sulfosuccinate, lauryl polypropylene glycol sulfosuccinic acid Alkyl ether sulfosuccinates such as sodium; alkylbenzene sulfonates such as sodium tetradecylbenzenesulfonate and tetraethanolamine tetraethanol; alkylnaphthalenesulfonates; alkanesulfonates; α-sulfo fatty acid methyl ester salts; Acyl isethionate; alkyl glycidyl ether sulfonate; alkyl sulfoacetate; laurethrin Alkyl ether phosphates such as sodium, sodium dilaureth phosphate, sodium trilaureth phosphate, sodium monooles phosphate; alkyl phosphate salts such as potassium lauryl phosphate; sodium caseinate; alkyl aryl ether phosphate; fatty acid amide ether phosphorus Phospholipids such as phosphatidylglycerol, phosphatidylinositol, and phosphatidic acid; silicone anionic surfactants such as carboxylic acid-modified silicone, phosphate-modified silicone, and sulfate-modified silicone; and nonionic surfactants, laureth (Polyoxyethylene lauryl ether), ceteth (polyoxyethylene cetyl ether), steareth (polyoxyethylene stearyl ether), behenez (polyoxyethylene) Nbehenyl ethers), isosteares (polyoxyethylene isostearyl ethers), octyldecesses (polyoxyethylene octyldodecyl ethers) and other polyoxyethylene alkyl ethers with various polyoxyethylene addition numbers; polyoxyethylene alkylphenyl ethers; Polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, polyoxyethylene hydrogenated castor oil monopyroglutamic acid monoisostearate diester, poly Castor oil such as oxyethylene hydrogenated castor oil maleic acid and hydrogenated castor oil derivatives; polyoxyethylene phytosterol; polyoxyethylene cholesterol; polyoxy Polyoxyethylene lanolin; polyoxyethylene reduced lanolin; polyoxyethylene polyoxypropylene cetyl ether, polyoxyethylene polyoxypropylene 2-decyltetradecyl ether, polyoxyethylene polyoxypropylene monobutyl ether, polyoxyethylene lanolin; Oxyethylene / polyoxypropylene hydrogenated lanolin, polyoxyethylene / polyoxypropylene alkyl ethers such as polyoxyethylene / polyoxypropylene glycerin ether; polyoxyethylene / polyoxypropylene glycol; (poly) such as PPG-9 diglyceryl Glycerin polyoxypropylene glycol; glyceryl stearate, glyceryl isostearate, glyceryl palmitate, myristate group Glyceryl fatty acid partial esters such as ceryl, glyceryl oleate, glyceryl coconut fatty acid, mono-cotton oil fatty acid glycerin, glyceryl monoerucate, glyceryl sesquioleate, α, α'-oleic acid pyroglutamic acid glycerin, monostearic acid glycerin malic acid; Polyglyceryl stearate-2, 3, 4, 5, 6, 8, 10, polyglyceryl distearate-6, 10, polyglyceryl tristearate, polyglyceryl decastearate-10, polyglyceryl isostearate -2, 3, 4, 5, 6, 8, 10, diglycostyl diisostearate (diglyceryl diisostearate), 3, 10, polyglyceryl-2 triisostearate, polyglyceryl tetraisostearate Ril-2, polyglyceryl-10 decaisostearate, polyglyceryl-2 oleate, 3,4, 5,6, 8,8, dioleate polyglyceryl-6, trioleate polyglyceryl-2, dekaoleic acid Polyglyceryl fatty acid esters such as polyglyceryl-10; ethylene glycol monofatty acid esters such as ethylene glycol monostearate; propylene glycol monofatty acid esters such as propylene glycol monostearate; pentaerythritol partial fatty acid esters; sorbitol partial fatty acid esters; maltitol moieties Fatty acid ester; maltitol ether; sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monos Sorbitan fatty acid esters such as allate, sorbitan sesquioleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate; sucrose fatty acid ester, methyl glucoside fatty acid ester, trehalose undecylenate, etc. Partial derivatives of sugar derivatives; alkyl glucosides such as caprylyl glucoside; alkyl polyglycosides; lanolin alcohols; reduced lanolin; polyoxyethylene distearate, polyethylene glycol diisostearate, polyoxyethylene monooleate, polyoxyethylene di- Polyoxyethylene fatty acid mono- and diesters such as oleate; polyoxyethylene propylene glycol fatty acid ester; polyoxyethylene Polyoxyethylene glycerin fatty acid esters such as polyoxyethylene monooleate such as polyglycerin monostearate, polyoxyethylene glycerin monoisostearate, polyoxyethylene glycerin triisostearate; polyoxyethylene sorbitan monooleate, polyoxy Polyoxyethylene sorbitan fatty acid esters such as ethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan tetraoleate; polyoxyethylene sorbitol monolaurate, polyoxyethylene sorbitol monooleate, polyoxyethylene sorbitol penta Polyoxyethylene sorbitol fatty acid esters such as oleate and polyoxyethylene sorbitol monostearate Polyoxyethylene methyl glucoside fatty acid ester; Polyoxyethylene alkyl ether fatty acid ester; Polyoxyethylene animal and vegetable oils such as polyoxyethylene sorbitol beeswax; Alkyl such as isostearyl glyceryl ether, chimyl alcohol, ceralkyl alcohol, batyl alcohol Glyceryl ethers; polyhydric alcohol alkyl ethers; polyoxyethylene alkylamines; tetrapolyoxyethylene / tetrapolyoxypropylene-ethylenediamine condensates; natural surfactants such as saponins and sophorolipids; polyoxyethylene fatty acid amides; coconut oil Fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (laura) De-MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (partamid MEA), palmitic acid diethanolamide (partamide DEA), palm oil fatty acid methylethanolamide (cocamidomethyl) Fatty acid alkanolamides such as MEA); alkyldimethylamine oxides such as lauramine oxide, cocamamine oxide, stearamine oxide, and behenamine oxide; alkylethoxydimethylamine oxide; polyoxyethylene alkyl mercaptan; poly such as dimethicone copolyol Silicone such as ether-modified silicone, polysiloxane-oxyalkylene copolymer, polyglycerin-modified silicone, sugar-modified silicone Nonionic surfactants, etc .; for cationic surfactants, alkyltrimethylammonium chlorides such as behentrimonium chloride, steartrimonium chloride, cetrimonium chloride, lauryltrimonium chloride; alkyls such as stearyltrimonium bromide Trialkylammonium bromide; dialkyldimethylammonium chloride such as distearyldimonium chloride and dicocodimonium chloride; fatty acid amidoamines and salts thereof such as stearamidepropyldimethylamine and stearamideethyldiethylamine; alkyl ether amines such as stearoxypropyldimethylamine; Salt or quaternary salt thereof; ethyl sulfate long chain branched fatty acid (12-31) aminopropylethyldimethylammonium, ethyl lanolin sulfate Fatty acid amide-type quaternary ammonium salts such as aminopropylethyldimethylammonium fatty acid; polyoxyethylene alkylamine and its salts or quaternary salts; alkylamine salts; fatty acid amidoguanidinium salts; alkyl etheraminemonium salts; Benzalkonium salt; Pyridinium salt such as cetylpyridinium chloride; Imidazolinium salt; Alkylisoquinolinium salt; Dialkyl morpholinium salt; Polyamine fatty acid derivatives; Aminopropyl dimethicone and amodimethicone Silicone-based cationic surfactants such as amino-modified silicone, cation-modified silicone, cation-modified and polyether-modified silicone, amino-modified and polyether-modified silicone;
In amphoteric surfactants, N-alkyl-N, N-dimethylamino acid betaines such as laurylbetaine (lauryldimethylaminoacetic acid betaine); fatty acid amidoalkyl-N, N-dimethylamino acids such as cocamidopropylbetaine and lauramidopropylbetaine Betaines; imidazoline-type betaines such as sodium cocoamphoacetate and sodium lauroamphoacetate; alkylsulfobetaines such as alkyldimethyltaurine; sulfate-type betaines such as alkyldimethylaminoethanol sulfate; phosphate-type betaines such as alkyldimethylaminoethanol phosphate; Sphingophospholipids such as phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, sphingomyelin, lysolecithin, hydrogenated soybean phospholipid, partially hydrogenated Phospholipids such as soybean phospholipid, hydrogenated egg yolk phospholipid, partially hydrogenated egg yolk phospholipid, and hydroxylated lecithin; silicone-based amphoteric surfactants; polymer surfactants such as polyvinyl alcohol, sodium alginate, starch derivatives, Preferred are tragacanth gum, acrylic acid / alkyl methacrylate copolymer; and various silicone surfactants.

  Polymers, thickeners and gelling agents include guar gum, locust bean gum, queens seed, carrageenan, galactan, arabic gum, tara gum, tamarind, far selelain, karaya gum, troarooi, cara gum, tragacanth gum, pectin, pectic acid and sodium Salt such as salt, salt such as alginic acid and sodium salt, mannan; starch such as rice, corn, potato, wheat; xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid and its salt, xanthan gum, pullulan, gellan gum, chitin , Chitosan, agar, gypsum extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropi Cellulose, carboxymethylcellulose and its salts such as sodium, methylhydroxypropylcellulose, sodium cellulose sulfate, cellulose dialkyldimethylammonium sulfate, crystalline cellulose, cellulose powder such as cellulose powder; soluble starch, carboxymethyl starch, methylhydroxypropyl starch, Starch-based polymers such as methyl starch, starch derivatives such as hydroxypropyltrimonium chloride, octenyl succinate corn starch and aluminum; alginic acid derivatives such as sodium alginate and propylene glycol alginate; polyvinylpyridone (PVP), polyvinyl alcohol (PVA), Vinyl pydridone-vinyl alcohol copolymer, polyvinyl methyl ether Polyethylene glycol, polypropylene glycol, polyoxyethylene / polyoxypropylene copolymer; amphoteric methacrylic acid such as (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer, (acrylates / stearyl acrylate / ethylamine methacrylate oxide) copolymer, etc. Ester copolymer; (Dimethicone / vinyl dimethicone) crosspolymer, (alkyl acrylate / diacetone acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer AMP; Polyvinyl acetate partial saponification product, maleic acid copolymer; Vinylpyrrolidone / dialkylaminoalkyl methacrylate copolymer; acrylic resin alkanolamine; polyester, water-dispersible polyester; Kurylamide; Polyacrylic acid ester copolymer such as polyethyl acrylate, carboxyvinyl polymer, polyacrylic acid and its sodium salt, acrylic acid / methacrylic acid ester copolymer; acrylic acid / alkyl methacrylate Polymer: Cationic cellulose such as polyquaternium-10, diallyldimethylammonium chloride / acrylamide copolymer such as polyquaternium-7, acrylic acid / diallyldimethylammonium chloride copolymer such as polyquaternium-22, and acrylic acid such as polyquaternium-39・ Diallyldimethylammonium chloride / acrylamide copolymer, acrylic acid / cationized methacrylic acid ester copolymer, acrylic acid / cationized methacrylic acid amide copolymer, polyquaternium Acrylic acid / methyl acrylate / methacrylamidopropyltrimethylammonium chloride copolymer such as 47, methacrylic acid choline ester polymer; cationized polysaccharides such as cationized oligosaccharide, cationized dextran, guar hydroxypropyltrimonium chloride; Polyethyleneimine; Cationic polymer; Polymer of 2-methacryloyloxyethyl phosphorylcholine such as polyquaternium-51 and copolymer with butyl methacrylate copolymer; Acrylic resin emulsion, polyethyl acrylate emulsion, polyacrylalkyl ester emulsion, Polymer emulsions such as polyvinyl acetate resin emulsion, natural rubber latex, synthetic latex; nitrocellulose; polyurethanes and various copolymers; various silicones Various silicone-based copolymers such as acrylic-silicone graft copolymers; various fluoropolymers; 12-hydroxystearic acid and its salts; dextrin fatty acid esters such as dextrin palmitate and dextrin myristate; silicic anhydride, Smoke-like silica (ultrafine silicic anhydride), aluminum magnesium silicate, magnesium magnesium silicate, metal soap, dialkyl phosphate metal salt, bentonite, hectorite, organically modified clay mineral, sucrose fatty acid ester, fructooligosaccharide fatty acid ester It is mentioned as preferable.

  Solvents and propellants include ethanol, 2-propanol (isopropyl alcohol), butanol, isobutyl alcohol and other lower alcohols; propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, isopentyl diol and other glycols Diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether Glycol ethers such as ethylene glycol monoethyl ether Glycol ether esters such as acetate, diethylene glycol monoethyl ether acetate, propylene glycol monoethyl ether acetate; Glycol esters such as diethoxyethyl succinate, ethylene glycol disuccinate; benzyl alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate , Acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbon, next-generation flon; propellants such as LPG, dimethyl ether, carbon dioxide, and the like are preferable.

  Antioxidants include tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; gallic acid derivatives such as propyl gallate; vitamin C (ascorbic acid) and / or derivatives thereof; erythorbic acid and derivatives thereof; Preferred are sulfites such as sodium sulfite; bisulfites such as sodium bisulfite; thiosulfates such as sodium thiosulfate; metabisulfites; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, cysteine hydrochloride As mentioned. Preferred examples of the reducing agent include thioglycolic acid, cysteine, cysteamine and the like. Preferred examples of the oxidizing agent include aqueous hydrogen peroxide, ammonium persulfate, sodium bromate, and percarbonate.

  Preservatives and antibacterial agents include hydroxybenzoic acid such as methylparaben, ethylparaben, propylparaben, and butylparaben and salts or esters thereof; salicylic acid; sodium benzoate; phenoxyethanol; 1,2-pentanediol, 1,2-hexane 1,2-diols such as diols; isothiazolinone derivatives such as methylchloroisothiazolinone and methylisothiazolinone; imidazolinium urea; dehydroacetic acid and its salts; phenols; halogenated bisphenols such as triclosan, acid amides , Quaternary ammonium salts; trichlorocarbanide, zinc pyrithione, benzalkonium chloride, benzethonium chloride, sorbic acid, chlorhexidine, chlorhexidine gluconate, halocarban, hexachlorophene, Kichioru; phenol, isopropyl phenol, cresol, thymol, p-chlorophenol, phenylphenol, other phenols such as phenylphenol sodium; phenylethyl alcohol, photosensitive Motorui, be mentioned as antibacterial zeolite, silver ion. Examples of chelating agents include edetate (ethylenediaminetetraacetate) such as EDTA, EDTA2Na, EDTA3Na, and EDTA4Na; hydroxyethylethylenediaminetriacetate such as HEDTA3Na; pentetate (diethylenetriaminepentaacetate); phytic acid; Phosphonic acid and its sodium salt; sodium oxalate; polypolyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphoric acid; sodium citrate, citric acid, alanine, dihydroxyethylglycine Gluconic acid, ascorbic acid, succinic acid, and tartaric acid are preferable. pH adjusters / acids / alkalis include citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, monoethanol Amine, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, hydroxylation Sodium, potassium hydroxide, aqueous ammonia, guanidine carbonate, and ammonium carbonate are preferable.

  Examples of powders include mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, muscovite, phlogopite, synthetic mica, red mica, biotite, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, silica Barium acid, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluorine apatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, Metal soap (e.g., zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, bengara, yellow iron oxide, black iron oxide, ultramarine, bitumen, carbon black, titanium oxide, fine particles and ultrafine Titanium oxide, zinc oxide, fine and ultrafine zinc oxide, alumina, silica, fumed silica (ultrafine silica), titanium mica, fish scale foil, boron nitride, photochromic pigment, synthetic fluorophlogopite, fine particle composite powder Body, gold, aluminum, etc., various sizes and shapes of inorganic powders, and these are treated with various surface treatment agents such as hydrogen silicone, cyclic hydrogen silicone, or other silane or titanium coupling agents Inorganic powders such as hydrophobized or hydrophilized powders; starch, cellulose, nylon powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, copolymer resin powder of styrene and acrylic acid, polyester powder, Benzoguanamine resin powder, polyethylene terephthalate, polymethyl Organic powders and surface-treated powders of various sizes and shapes, such as methacrylate powder, polyethylene terephthalate / aluminum / epoxy powder, urethane powder, silicone powder, Teflon (registered trademark) powder, organic-inorganic composite powder Is preferable. Inorganic salts include sodium chloride-containing salts such as salt, common salt, rock salt, sea salt, natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, bittern, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, Aluminum sulfate / potassium sulfate (alum), aluminum sulfate / ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, copper sulfate; sodium phosphates such as 1Na, 2Na and 3Na phosphates, phosphoric acid Potassium, calcium phosphates and magnesium phosphates are preferred.

Examples of ultraviolet absorbers include paraaminobenzoic acid, paraaminobenzoic acid monoglycerin ester, N, N-dipropoxyparaaminobenzoic acid ethyl ester, N, N-diethoxyparaaminobenzoic acid ethyl ester, and N, N-dimethylparaaminobenzoic acid ethyl ester. Benzoic acid-based ultraviolet absorbers such as esters, N, N-dimethylparaaminobenzoic acid butyl ester, N, N-dimethylparaaminobenzoic acid ethyl ester; Anthranilic acid-based ultraviolet absorbers such as homomenthyl-N-acetylanthranilate; Salicylic acid And salicylic acid-based purple such as sodium salt, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate Line absorber: Octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl-p- Methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, 2-ethylhexyl p-methoxycinnamate (octyl paramethoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate (sinoxate), Cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl α-cyano-β-phenylcinnamate (octocrine), glyceryl mono-2-ethylhexanoyl-diparamethoxy Nameto, cinnamic acid UV absorbers such as ferulic acid and its derivatives; 2,4-dihydroxybenzophenone, 2,2'-
Dihydroxy-4-methoxybenzophenone, 2,2′-dihydroxy-4,4′-dimethoxybenzophenone, 2,2 ′, 4,4′-tetrahydroxybenzophenone, 2-hydroxy-4-
Methoxybenzophenone (oxybenzone-3), 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4'-phenyl -Benzophenone ultraviolet absorbers such as benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone; 3- (4'-methylbenzylidene) -d, l- Camphor, 3-benzylidene-d, l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5-methylphenylbenzotriazole; 2- (2'-hydroxy-5'-t- Octylphenyl) benzotriazole; 2- (2′-H Dioxy-5'-methylphenylbenzotriazole;dibenzalazine;dianisoylmethane; 5- (3,3-dimethyl-2-norbornylidene) -3-pentan-2-one; di- such as 4-t-butylmethoxydibenzoylmethane Benzoylmethane derivatives; octyl triazone; urocanic acid derivatives such as urocanic acid and ethyl urocanate; 2- (2′-hydroxy-5′-methylphenyl) benzotriazole, 1- (3,4-dimethoxyphenyl) -4, Hydantoin derivatives such as 4-dimethyl-1,3-pentanedione, dimethoxybenzylidenedioxoimidazolidinepropionate 2-ethylhexyl, phenylbenzimidazolazole sulfonic acid, terephthalylidene dicamphulsulfonic acid, drometrizol trisiloxane, anthranyl Methyl, rutin and its derivatives, oryzanol and derivatives thereof as preferred.

  Examples of whitening agents include hydroquinone glycosides such as arbutin and α-arbutin and esters thereof; ascorbic acid phosphate salts such as ascorbic acid, sodium ascorbate phosphate and magnesium ascorbate phosphate, ascorbic acid Ascorbic acid fatty acid esters such as tetraisopalmitic acid ester, ascorbic acid alkyl ethers such as ascorbic acid ethyl ether, ascorbic acid glucosides such as ascorbic acid-2-glucoside and fatty acid esters thereof, ascorbic acid sulfate ester, tocopheryl ascorbyl phosphate Ascorbic acid derivatives such as kojic acid, ellagic acid, tranexamic acid and its derivatives, ferulic acid and its derivatives, placenta extract, glutathione, oryzanol, butylreso Shinoru, oil soluble Kamomiraekisu oil soluble licorice extract, Nishikawa willow extract, be mentioned as saxifrage extract, and the like plant extracts are preferred.

  Vitamins and their derivatives include vitamin A such as retinol, retinol acetate, retinol palmitate; thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine dipalmitate, Flavin adenine dinucleotide, cyanocobalamin, folic acid, nicotinic acid such as nicotinic acid amide / benzyl nicotinate, vitamin B group such as choline; vitamin C such as ascorbic acid and its sodium salt; vitamin D; α, Vitamin Es such as β, γ, δ-tocopherol; other vitamins such as pantothenic acid and biotin; ascorbic acid phosphates such as ascorbic acid phosphate sodium salt and ascorbic acid phosphate magnesium salt; Ascorbic acid fatty acid esters such as corobic acid tetraisopalmitic acid ester, ascorbyl stearate, ascorbyl palmitate and ascorbyl dipalmitate, ascorbic acid alkyl ether such as ascorbic acid ethyl ether, ascorbic acid glucoside such as ascorbic acid-2-glucoside and Ascorbic acid derivatives such as fatty acid esters and tocopheryl phosphate ascorbyl; vitamin derivatives such as tocopherol nicotinate, tocopherol acetate, tocopherol acetate, tocopherol linoleate, tocopherol phosphate, tocopherol phosphate etc., tocotrienol, and other various vitamin derivatives Is preferable.

  Anti-inflammatory and anti-inflammatory agents include glycyrrhizic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, guaiazulene, allantoin, indomethacin, zinc oxide, hydrocortisone acetate, prednisone, diphedramine hydrochloride, chlorpheniramine maleate; peach leaf extract A plant extract such as a koji leaf extract is preferable. Plant growth and tinctures such as assembly extract, red pepper tincture, ginger tincture, ginger extract, cantalis tincture; capsaicin, nonyl acid valenylamide, gingeron, ictamol, tannic acid Borneol, cyclandelate, cinnarizine, trazoline, acetylcholine, verapamil, cephalanthin, γ-oryzanol, cephalanthin, vitamin E and nicotinic acid tocopherol, acetic acid tocopherol and other derivatives, γ-oryzanol, nicotinic acid, nicotinic acid amide, nicotinic acid benzyl Derivatives such as ester, inositol hexanicotinate, nicotine alcohol, allantoin, photosensitizer 301, photosensitizer 401, capronium chloride, pentadecanoic acid monoglyceride, Preferable examples include flavonol derivatives, stigmasterol or stigmasteranol, its glycosides, and minoxidil. Preferred hormones include estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone and the like. Other remedies such as anti-wrinkle agents, anti-aging agents, squeeze agents, cooling sensations, warming sensation agents, wound healing promoters, irritation relievers, analgesics, cell activators include retinols, retinoic acids, retinoin Acid tocopheryl; derivatives such as lactic acid, glycolic acid, gluconic acid, fruit acid, salicylic acid and glycosides / esterified products thereof, α- or such as hydroxycapric acid, long chain α-hydroxy fatty acid, long chain α-hydroxy fatty acid cholesteryl β-hydroxy acids and derivatives thereof; γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid; carnitine; carnosine; creatine; ceramides, sphingosines; caffeine, xanthine and the like; and coenzyme Q10, carotene, lycopene , Astaxanthin, lutein, α-lipoic acid, platinum nanocolloid, fullerenes, etc. Antioxidant / active oxygen scavengers; catechins; flavones such as quercetin; isoflavones; gallic acid and ester sugar derivatives; polyphenols such as tannin, sesamin, protoanthocyanidin, chlorogenic acid, apple polyphenol; rutin and glycosides, etc. Derivatives of hesperidin and glycosides; lignan glycosides; licorice extract-related substances such as grabrizine, glabrene, liquiritin, and isoliquiritin; lactoferrin; shogaol, gingerol; fragrance substances such as menthol, camphor, cedrol, and derivatives thereof Preferred examples include capsaicin, vanillin and the like and derivatives; insect repellents such as diethyltoluamide; and complexes of physiologically active substances and cyclodextrins.

  Plant / animal / microbe extracts include iris extract, ashitaba extract, asunalo extract, asparagus extract, avocado extract, achacha extract, almond extract, altea extract, arnica extract, aloe extract, apricot extract, apricot kernel extract, ginkgo biloba extract , Incheon extract, Fennel extract, Turmeric extract, Oolong tea extract, Peony extract, Ages extract, Echinacea leaf extract, Enmeo extract, Ogon extract, Oat extract, Auren extract, Barley extract, Panax ginseng extract, Hypericum extract, Odori extract , Dutch mustard extract, orange extract, dried sea water, seaweed extract, oyster leaf extract, oyster extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolysis Luc, Cascon extract, Chamomile extract, Oil-soluble chamomile extract, Carrot extract, Kawara mugi extract, Oat extract, Calcade extract, Licorice extract, Oil-soluble Licorice extract, Kiwi extract, Kiou extract, Cyprid extract, Quina extract, Cucumber extract, Kiri leaf extract, Guanosine, guava extract, cucumber extract, gardenia extract, kumazasa extract, clara extract, walnut extract, chestnut extract, grapefruit extract, clematis extract, black rice extract, brown sugar extract, black vinegar, chlorella extract, mulberry extract, gentian extract, Gentian pepper extract, tea Extract, yeast extract, kokuboku extract, coffee extract, burdock extract, rice extract, rice fermented extract, rice bran fermented extract, rice germ oil, comfrey extract, Lagen, Cowberry extract, Saishin extract, Psycho extract, Saitai extract, Saffron extract, Salvia extract, Salmon extract, Sasa extract, Hawthorn extract, Sansha extract, Salamander extract, Shiitake extract, Giant extract, Shikon extract, Perilla extract, Linden extract, Shimosukeso Extract, jatoba extract, peonies extract, ginger cucumber extract, ginger root extract, white birch extract, white jellyfish extract, horsetail extract, stevia extract, stevia fermented product, west river willow extract, horse chestnut extract, hawthorn extract, elderberry extract, yarrow extract , Mint extract, sage extract, mallow extract, nematode extract, essence extract, Sakuhakuhi extract, Diou extract, Dai Extract, peanut extract, thyme extract, dandelion extract, lichen extract, tea extract, clove extract, chigaya extract, chimpi extract, tea tree oil, tea tea extract, red pepper extract, red snapper extract, red snapper extract, red spruce extract, red spruce extract, tomato Extract, natto extract, carrot extract, garlic extract, wild rose extract, hibiscus extract, bacmond extract, lotus extract, parsley extract, birch extract, honey, hamamelis extract, parietalia extract, hyacinth extract, bisabolol, cypress extract, bifidobacteria extract, Loquat extract, dandelion extract, burdock extract, bukkuri extract, butcher bloom extract, grape extract, grape seed extract, propolis, loofah extract, Safflower extract, peppermint extract, body extract, button extract, hop extract, squid extract, pine extract, maroonnier extract, mizubasho extract, mukuroji extract, melissa extract, mozuku extract, peach extract, cornflower extract, eucalyptus extract, yukinoshita extract, yuzu extract, lily extract, Yokuinin extract, mugwort extract, lavender extract, green tea extract, eggshell membrane extract, apple extract, rooibos tea extract, litchi extract, lettuce extract, lemon extract, forsythia extract, forsythia extract, rose extract, rosemary extract, roman chamomile extract, royal jelly Extracts such as an extract and a bitumen extract are preferred.

  Examples of the antipruritic agent include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, substance-P inhibitor, and the like. Examples of the exfoliating / dissolving agent include salicylic acid, sulfur, resorcin, selenium sulfide, pyridoxine and the like. Examples of the antiperspirant include chlorohydroxyaluminum, aluminum chloride, zinc oxide, and zinc paraphenol sulfonate. Examples of the refreshing agent include menthol and methyl salicylate. Examples of the astringent include citric acid, tartaric acid, lactic acid, aluminum sulfate / potassium sulfate, and tannic acid. Examples of enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, protease, and the like. Preferred nucleic acids include ribonucleic acid and salts thereof, deoxyribonucleic acid and salts thereof, and adenosine triphosphate disodium.

  As perfumes, acetyl cedrene, amylcinnamaldehyde, allyl amyl glycolate, β-ionone, iso-Esuper, isobutyl quinoline, Iris oil, Iron, indole, ylang ylang oil, undecanal, undecenal, γ-undecalactone, Estragole, eugenol, oak moss, opoponax resinoid, orange oil, eugenol, auranthiol, galac solid, carvacrol, L-carvone, camphor, cannon, carrot seed oil, clove oil, methyl cinnamate, geraniol, geranyl nitrile , Isobornyl acetate, geranyl acetate, dimethylbenzyl carvinyl acetate, styrylyl acetate, cedolyl acetate, terpinel acetate, pt-butylcyclohexyl acetate, vetiberyl acetate, benzyl acetate, vinegar Linalyl, isopentyl salicylate, benzyl salicylate, sandalwood oil, santalol, cyclamenaldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromilsenol, jasmine absolute, jasmine lactone, cis-jasmon, citral, citronenol, citronellal, Cinnamon bark oil, 1,8-cineole, cinnamaldehyde, stylax resinoid, cedarwood oil, cedrene, cedrol, celery seed oil, thyme oil, damascon, damacenone, thymol, tuberose absolute, decanal, decalactone, terpineol, γ-terpinene, Tripral, Nellore, Nonanal, 2,6-Nonadienol, Nonalactone, Patchouli alcohol, Vanilla absolute , Vanillin, basil oil, patchouli oil, hydroxycitronellal, α-pinene, piperitone, phenethyl alcohol, phenylacetaldehyde, petitglen oil, hexylcinnamaldehyde, cis-3-hexenol, peruvian valam, vetiver oil, vetiverol, peppermint oil, Pepper oil, heliotropin, bergamot oil, benzylbenzoate, borneol, milresinoid, musk ketone, methylnonylacetaldehyde, γ-methylyonone, menthol, L-menthol, L-menthol, eucalyptus oil, β-yonone, lime oil, lavender oil, Synthetic and natural fragrances such as D-limonene, linalool, rillar, rigliall, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, various essential oils, and various blended fragrances It can be mentioned as preferred.

As pigments / colorants / dyes / pigments, brown 201, black 401, purple 201, purple 401, blue 1, blue 2, blue 201, blue 202, blue 203, blue 204 , Blue 205, Blue 403, Blue 404, Green 201, Green 202, Green 204, Green 205, Green 3, Green 401, Green 402, Red 102, Red 104-1 , Red 105-1, Red 106, Red 2, Red 201, Red 202, Red 203, Red 204, Red 205, Red 206, Red 207, Red 208, Red 213 Red 214, Red 215, Red 218, Red 219, Red 220, Red 221, Red 223, Red 225, Red 226, Red 227, Red 228, Red 230 No. 1, Red 230-2, Red 231, Red 232, Red 3, Red 401, Red 404, Red 405, Red 501, Red 502, Red 503, Red 504, Red 505, red 506, orange 201, orange 203, orange 204, orange 205, orange 206, orange 207, orange 401, orange 402, orange 403, yellow 201, yellow 202- No. 1, yellow 202-2, yellow 203, yellow 204, yellow 205, yellow 4, yellow 401, yellow 402, yellow 403-1, yellow 404, yellow 405, yellow 406 , Yellow 407, Yellow 5 and other legal dyes; Acid Red 14 and other acidic dyes; Arianor Sienna Brown, Arianor Madder Red, Arianor
Basic dyes such as Steel Blue and Arianor Straw Yellow; HC Yellow 2, HC Yellow 5, HC Red 3, 4-hydoxypropylamino-3-nitrophenol, N, N'-bis (2-hydroxyethyl) -2-nitro-p-
Nitro dyes such as phenylenediamine, HC Blue 2 and Basic Blue 26; disperse dyes; inorganic white pigments such as titanium dioxide and zinc oxide; inorganic red pigments such as iron oxide (bengala) and iron titanate; γ-iron oxide Inorganic brown pigments; inorganic yellow pigments such as yellow iron oxide and ocher; inorganic black pigments such as black iron oxide and low-order titanium oxide; inorganic purple pigments such as mango violet and cobalt violet; chromium oxide and chromium hydroxide Inorganic green pigments such as cobalt titanate; inorganic blue pigments such as ultramarine and bitumen; titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil Pearl powder such as aluminum powder, copper powder, metal powder pigment such as gold; surface treatment inorganic and metal powder pigment; Color 201, Red 202, Red 204, Red 205, Red 220, Red 226, Red 228, Red 405, Orange 203, Orange 204, Yellow 205, Yellow 401, Blue 404 No. 3, Red No. 3, Red No. 104, Red No. 106, Red No. 227, Red No. 230, Red No. 401, Red No. 505, Orange No. 205, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203, Organic pigments such as Zirconium, Barium or Aluminum Lake such as Green No. 3 and Blue No. 1; Surface-treated organic pigments; Anthraquinones such as astaxanthin and alizarin, anthocyanidins, β-carotene, catenal, capsanthin, chalcone, calsamine, quercetin, crocin , Naphthoquinones such as chlorophyll, curcumin, cochineal, shikonin, bixin, Natural pigments and dyes such as lavones, betacyanidine, henna, hemoglobin, lycopene, riboflavin, rutin; p-phenylenediamine, toluene-2,5-diamine, o-, m-, or p-aminophenol, m-phenylene Oxidative dye intermediates and couplers such as diamine, 5-amino-2-methylphenol, resorcin, 1-naphthol, 2,6-diaminopyridine and their salts; auto-oxidizing dyes such as indoline; Can be mentioned.

  Preferred examples of water include normal water, purified water, hard water, soft water, natural water, deep sea water, electrolytic alkaline ionized water, electrolytic acidic ionized water, ionic water, and clustered water.

  In addition to these, cosmetic raw material standards, blending ingredient standard by cosmetic varieties, Japan Cosmetic Industry Association ingredient display name list, INCI dictionary (The International Cosmetic Ingredient Dictionary and Handbook), quasi-drug raw material standards, Japanese pharmacopoeia, pharmaceutical additives Ingredients listed in standards, official food additives, etc., and Japanese and foreign patent publications and patent publications (including publications and republications) in which the international patent classification IPC belongs to the classification of A61K7 and A61K8 It is possible to contain known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc., such as the ingredients described, in known combinations, blending ratios and blending amounts.

  Examples of the cosmetic / skin external preparation of the present invention include skin external preparations such as hair cosmetics, basic cosmetics, makeup cosmetics, aromatic cosmetics, body cosmetics, and ointments. The cosmetic / skin external preparation of the present invention can be produced according to a usual method.

  The types of cosmetics and external preparations for skin according to the present invention will be described in more detail. Examples of hair cosmetics include oil shampoos, cream shampoos, conditioning shampoos, dandruff shampoos, hair color shampoos, rinse-integrated shampoos and the like. Rinsing, treatment, hair pack, hair foam, hair mousse, hair spray, hair mist, hair wax, hair gel, water grease, set lotion, color lotion, hair tonic, hair liquid, pomade, tic, hair cream, hair blow, split hair coat , Hair oil, permanent wave agent, straight permanent agent, oxidative hair dye, hair bleach, hair color pre-treatment, hair color after treatment, perm pre-treatment, perm after Treatments, hair manicure, and as hair growth agents are preferred.

  Basic cosmetics include soft lotion, astringent lotion, cleansing lotion, multi-layer lotion, etc .; emollient lotion, moisture lotion, milky lotion, nourishing lotion, nourishing milk, skin moisture, moisturizer -Emulsions such as emulsion, massage lotion, cleansing lotion, protect emulsion, sun protect, sun protector, UV care milk, sunscreen, makeup lotion, horny smoother, elbow lotion, hand lotion, body lotion; emollient cream, nutritional cream, nari Thing cream, burnishing cream, moisture cream, night cream, massage cream, cleansing cream, makeup cream, base cream Cream, sun makeup cream, suntan cream, hair removal cream, deodorant cream, shaving cream, keratin softening cream, etc .; gel such as moisture gel; essence such as moisturizing essence, whitening essence, UV protection essence; liposome Liposome cosmetics such as beauty essence and liposome lotion; Peel-off packs, powder packs, washing packs, oil packs, cleansing masks and other packs and masks; cleansing foams, cleansing creams, cleansing milks, cleansing lotions, cleansing gels, cleansing oils , Cleansing mask, washing powder, face washing powder, etc .; cosmetic soap, transparent soap, medicated soap, liquid soap, shaving soap, synthetic cosmetic soap Soap can be mentioned as preferred.

  Examples of makeup cosmetics that may be preferably used include white powder, dusts, foundations, lipsticks, lip gloss, blushers, eyeliner, mascara, eye shadow, eyebrow, eyebrow, nail enamel, enamel remover, and nail treatment.

  Preferred examples of the aromatic cosmetics include perfume, perfume, parfum, eau de parfum, eau de toilette, eau de cologne, perfumes, fragrance powder, perfume soap, body lotion and bath oil.

  Body cosmetics such as body shampoos; deodorant lotions, deodorant powders, deodorant sprays, deodorant sticks and other deodorant cosmetics; decoloring agents, hair removal / hair removal agents; bathing agents; insect repellents A repeller is preferred.

  Moreover, as a skin external preparation, it can be used with dosage forms, such as an ointment, a patch, a lotion agent, a liniment agent, and a liquid coating agent. It can also be used as an oral cosmetic such as toothpaste and mouthwash.

  As the dosage form of the cosmetic or external preparation for skin of the present invention, emulsification such as oil-in-water (O / W) type, water-in-oil (W / O) type, W / O / W type, O / W / O type, etc. Type cosmetics, oily cosmetics, solid cosmetics, liquid cosmetics, paste cosmetics, stick cosmetics, volatile oil cosmetics, powder cosmetics, jelly cosmetics, gel cosmetics, pastes Preferred examples include cosmetics, emulsified polymer cosmetics, sheet cosmetics, mist cosmetics, and spray cosmetics.

  Hereinafter, although this technique is demonstrated in detail using an Example, this technique is not limited to these Examples.

Example 1
In a 500 mL reactor equipped with a stirrer, a thermometer, and a gas introduction tube, 75 g (0.37 mol) of sebacic acid (Ogura Gosei Kogyo, Sebacic acid) and 47.8 g (0. 52 mol), charged with 167.1 g (0.23 mol) of polyglycerin (Aoki Yushi Kogyo Co., Ltd., Glysurf 10) having an average degree of polymerization calculated from a hydroxyl value of 10 and heated to 210 ° C. to 220 ° C. in a nitrogen stream. The esterification reaction was carried out for 10 hours while distilling off the water to obtain 258.4 g of a viscous liquid oligomer ester at room temperature. The acid value of the obtained oligomer ester was 0.5. 100 g of Example Composition 1 was obtained by adding 39.8 g of water and 0.2 g of methyl p-hydroxybenzoate to 60 g of the obtained oligomer ester, and stirring and mixing. Moreover, 40g of glycerol was added to 60g of obtained oligomer ester, and 100g of Example composition 2 was obtained by stirring and mixing.

Example 2
In a 500 mL reactor equipped with a stirrer, a thermometer, and a gas introduction tube, 90 g (0.37 mol) of sebacic acid (Ogura Synthesis, Sebacic acid), 65.6 g (0.71) (glycolin, Ogura synthesis) Mol), 133.7 g (0.17 mol) of polyglycerin (Aoki Yushi Kogyo Co., Ltd., Glysurf 10) having an average degree of polymerization calculated from the hydroxyl value of 10 is charged and heated to 210 ° C. to 220 ° C. in a nitrogen stream. While distilling off, esterification was carried out for 10 hours to obtain 249.6 g of a viscous liquid oligomer ester at room temperature. The acid value of the obtained oligomer ester was 0.6.

Comparative Example 1
Polyglycerin (Aoki Oils and Fats) with an average polymerization degree calculated from 70 g (0.21 mol) of sebacic acid (Ogura Gosei Co., Ltd., sebacic acid) in a 500 mL reactor equipped with a stirrer, thermometer and gas introduction tube Industrial, Glysurf 10) 225 g (0.3 mol) was charged, heated to 210 ° C. to 220 ° C. in a nitrogen stream, and subjected to an esterification reaction for 10 hours while distilling off water. 0.7 g was obtained. The acid value of the obtained oligomer ester was 0.6.

Comparative Example 2
292 g (0.35) of polyglycerin 90% aqueous solution (polyglycerin # 750, manufactured by Sakamoto Pharmaceutical Co., Ltd.) having an average degree of polymerization calculated from the hydroxyl value of 10 in a 1 L reactor equipped with a stirrer, a thermometer and a gas introduction tube. Mole), and after dehydration under reduced pressure, 71.8 g (0.21 mol) of eicosan diacid (manufactured by Okamura Oil Co., Ltd., SL-20), 36.1 g (0.14 mol) of tetradecanedioic acid (manufactured by Cognis, EMEROX 114) And heated to 210-220 ° C. in a nitrogen stream, and the esterification reaction was carried out for 24 hours while distilling off the produced water, to obtain 341 g of solid oligomer ester at room temperature. The acid value of the obtained oligomer ester was 0.2.

表１の結果からわかるように、本発明の化合物は比較例に示された化合物よりも摩擦係数及びトルクが小さく、潤滑性能に優れることが見出された。 Example 3
The lubrication performance of the obtained oligomer ester was evaluated by the following method.
(Lubrication performance evaluation method)
Test method for wear resistance of lubricating oil of the Japan Petroleum Institute (shell four-ball type) In accordance with JPI-5S-32-90, the test is performed under the following conditions, the friction coefficient and torque are measured, and the average value is calculated. did.
Equipment: Shell four-ball friction tester (Takachiho Seiki Co., Ltd.)
Load: 30kgf
Rotation speed: 1,000rpm
Total number of revolutions: 10,000 revolutions Temperature: room temperature Measurement concentration: 3% aqueous solution The results obtained are shown in Table 1.

As can be seen from the results in Table 1, it was found that the compound of the present invention has a smaller coefficient of friction and torque than the compounds shown in the comparative examples and is excellent in lubricating performance.

  Furthermore, the example of the lubricating composition which mix | blended the oligomer ester of this invention and cosmetics or a skin external preparation was shown next.

Example 4 Metalworking Lubricant Component Blending amount (% by weight)
1 Oligomer ester of Example 1 30.0
2 Isononanoic acid 5.0
3 Triethanolamine 10.0
4 Preservative 0.1
5 Water Total amount to be 100 (Preparation method)
No. 1-2 were heated to about 80 ° C. and dissolved uniformly (part A). Next, no. 3 to 5 were heated to about 80 ° C. and dissolved uniformly (part B). A part A was added to part B with stirring, and the mixture was made uniform and then cooled.

Example 5 Water-soluble coolant liquid Component Blending amount (% by weight)
1 Oligomer ester of Example 1 15.0
2 Caprylic acid 5.0
3 Sodium carbonate 10.0
4 Sodium metaborate 1.0
5 Preservative 0.1
6 Water Total amount to be 100 (Preparation method)
No. 1-2 were heated to about 80 ° C. and dissolved uniformly (part A). Next, no. 3 to 6 were heated to about 80 ° C. and dissolved uniformly (part B). A part A was added to part B with stirring, and the mixture was made uniform and then cooled.

Example 6 Hydraulic fluid component Component amount (% by weight)
1 Oligomer ester of Example 2 40.0
2 Polyethylene glycol 10.0
3 Ethylene glycol 10.0
4 Glycerin 10.0
5 Rust inhibitor 1.0
6 Preservative 0.1
7 Silicon antifoam 0.1
8 Water Amount that makes a total of 100 (Preparation method)
No. 1 to 8 were heated to about 70 ° C., dissolved uniformly, and then cooled.

Example 7 Hydraulic fluid component Component amount (% by weight)
1 Example Composition 1 of Example 1 40.0
2 Random copolymer of ethylene oxide and propylene oxide (EO / PO = 30/70) 20.0
3 Glycerin 10.0
4 Rust inhibitor 1.0
5 Preservative 0.1
6 Silicon antifoam 0.1
7 Water Total amount of 100 (preparation method)
No. 1 to 7 were heated to about 70 ° C., dissolved uniformly, and then cooled.

Example 8 Water-soluble lubricating liquid Component Compounding amount (% by weight)
1 Example Composition 1 of Example 1 30.0
2 Oleic acid 5.0
3 Oleic acid amide 1.0
4 Triethanolamine 1.0
5 Potassium hydroxide 1.0
6 Preservative 0.1
7 Water Total amount of 100 (preparation method)
No. 1-3 were heated to about 80 ° C. and dissolved uniformly (part A). Next, no. 4 to 7 were heated to about 80 ° C. and dissolved uniformly (part B). A part A was added to part B with stirring, and the mixture was made uniform and then cooled.

Example 9 Water-soluble lubricating liquid Component Blending amount (% by weight)
1 Example Composition 1 of Example 1 30.0
2 Random copolymer of ethylene oxide and propylene oxide (EO / PO = 75/25) 15.0
3 Oleic acid 5.0
4 Triethanolamine 5.0
5 Preservative 0.1
6 Water Total amount to be 100 (Preparation method)
No. 1-3 were heated to about 80 ° C. and dissolved uniformly (part A). Next, no. 4 to 6 were heated to about 80 ° C. and dissolved uniformly (part B). A part A was added to part B with stirring, and the mixture was made uniform and then cooled.

Example 10 Anticorrosive Lubricant Component Compounding amount (wt%)
1 Example composition of Example 1 2 20.0
2 Oleic acid 5.0
3 Diethanolamine 5.0
4 Glyceryl triisostearate 1.0
5 Preservative 0.1
6 EDTA4Na 2.0
7 Water Total amount of 100 (preparation method)
No. 1-2, 4 was heated to about 80 ° C. and dissolved uniformly (part A). Next, no. 3, 5-7 were heated to about 80 ° C. and dissolved uniformly (part B). A part A was added to part B with stirring, and the mixture was made uniform and then cooled.

Example 11 Antirust Lubricating Liquid for Tableware, Medical Device / Equipment
1 Oligomer ester of Example 1 20.0
2 Propylene glycol 40.0
3 Glycerin 10.0
4 Ethanol 5.0
5 Water Total amount to be 100 (Preparation method)
No. 1 to 5 were heated to about 70 ° C., dissolved uniformly, and then cooled.

Example 12 Heat Treatment Liquid Component Compounding amount (% by weight)
1 Oligomer ester of Example 2 25.0
2 Polyethylene glycol 10.0
3 Glycerin 10.0
4 Preservative 0.1
5 Water Total amount to be 100 (Preparation method)
No. 1 to 5 were heated to about 70 ° C., dissolved uniformly, and then cooled.
All of these lubricating compositions were excellent in safety, lubricity, and cooling properties.

（結果）
結果を表２に示した。なお、表中◎は１０名中８名以上が良好と回答、○は１０名中６〜７名が良好と回答、△は１０名中４〜５名が良好と回答、×は１０名中３名以下が良好と回答したことを示す。結果より、本発明品を配合した化粧水は比較例１のオリゴマーエステルを配合したもの、未配合のものよりもべたつきが無く、優れた感触であることがわかった。 Examples 13 and 14 Lotion Toner lotions having the composition shown in Table 2 were prepared using the oligomer ester obtained in Examples 1 and 2 of the present invention and the oligomer ester obtained in Comparative Example 1, and applied to the skin. The panelists evaluated the absence of stickiness.
(Preparation method)
No. Ingredients 1-9 are No. Add to 10 with stirring to make uniform.

(result)
The results are shown in Table 2. In the table, ◎ indicates that 8 or more out of 10 are good, ○ indicates that 6 to 7 out of 10 are good, △ indicates that 4 to 5 out of 10 are good, and × indicates 10 out of 10 It shows that 3 or less responded as good. From the results, it was found that the lotion containing the product of the present invention was less sticky than the one containing the oligomer ester of Comparative Example 1 and the one not blended, and had an excellent feel.

（結果）
結果を表３に示した。なお、表中◎は１０名中８名以上が良好と回答、○は１０名中６〜７名が良好と回答、△は１０名中４〜５名が良好と回答、×は１０名中３名以下が良好と回答したことを示す。結果より、本発明品を配合した化粧水は比較例１のオリゴマーエステルを配合したもの、未配合のものよりもべたつきが無く、優れた感触であることがわかった。 Examples 15 and 16 Skin Care Cream A cream having the composition shown in Table 3 was prepared using the oligomer ester obtained in Examples 1 and 2 of the present invention and the oligomer ester obtained in Comparative Example 1, and applied to the skin. Ten panelists evaluated the absence of stickiness.
(Preparation method)
No. 1-3, no. 12 to 17 were heated to about 80 ° C. and dissolved uniformly (part A). Next, no. 4 to 11 were heated to about 80 ° C. and dissolved uniformly (part B). A part A was added to part B with stirring, and the mixture was made uniform and then cooled.

(result)
The results are shown in Table 3. In the table, ◎ indicates that 8 or more out of 10 are good, ○ indicates that 6 to 7 out of 10 are good, △ indicates that 4 to 5 out of 10 are good, and × indicates 10 out of 10 It shows that 3 or less responded as good. From the results, it was found that the lotion containing the product of the present invention was less sticky than the one containing the oligomer ester of Comparative Example 1 and the one not blended, and had an excellent feel.

Example 17 Lotion Toner lotion having the following formulation was prepared. This skin lotion was not sticky, gave a moist feeling, and was excellent in familiarity with the skin.

Component Blending amount (% by weight)
--------------------------------
1 Oligomer ester of Example 2 2.00
2 BG 1.00
3 Glycerin 2.00
4 Citric acid 0.01
5 Na citrate 0.10
6 Arginine 0.10
7 Glycyrrhizic acid 2K 0.05
8 Ethanol 7.00
9 Preservative Appropriate amount 10 Perfume Small amount 11 Purified water Amount to be 100 in total --------------------------------
(Preparation method)
No. 1-6 are No. 11 and stirred and mixed uniformly (part A). Next, no. 9 to 10 are No. No. 8 after dissolution in No. 8 7 was added and dispersed (part B). A part was added to part B with stirring to make it uniform.

Example 18 Cosmetic liquid A cosmetic liquid having the following formulation was prepared. This essence had a smooth feel while softening the skin and keeping the skin fresh and smooth.

Component Blending amount (% by weight)
----------------------------------
Part A oligomer oligomer of Example 1 2.00
Preservative Suitable amount PEG-40 hydrogenated castor oil 0.20
Purified water 5.00
Part B xanthan gum 0.40
Carbomer 0.10
BG 10.00
White jellyfish polysaccharide (Nippon Seika) 0.10
Purified water Amount to be 100 in total C part hydroxylated K (1% aqueous solution)
Purified water 10.00
Part D glycyrrhizic acid 2K 0.20
Purified water 5.00
----------------------------------
(Production method)
Each of parts A to D was dissolved at room temperature. C. Part C was gradually added to part B while stirring to obtain a viscous liquid, and then parts A and D were added and stirred to make uniform.

Example 19 Shampoo A shampoo having the following formulation was prepared. This shampoo was able to give moist and smooth fingering to the hair.

Component Blending amount (% by weight)
--------------------------------
1 Oligomer ester of Example 2 2.00
2 Cocamidopropyl betaine (40%) 40.00
3 Cocoa glutamate TEA (27%) 10.00
4 Tetradecenesulfonic acid Na (36%) 2.00
5 PEG120-methylglucose dioleate 3.00
6 Triethanolamine 0.20
7 Methylisothiazolineone 0.01
8 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1 to 5 were heated to about 80 ° C. and dissolved uniformly (part A). Next, no. 6-8 were heated to about 80 ° C. and dissolved uniformly (part B). Part B was added to part A and mixed with stirring at about 80 ° C. until uniform, and then cooled.

Example 20 Shampoo A shampoo having the following formulation was prepared. This shampoo was able to give moist and smooth fingering to the hair.

Component Blending amount (% by weight)
--------------------------------
1 Oligomer ester of Example 1 1.00
2 Cocamidopropyl betaine (30%)
30.00
3 Laureth sulfate Na (25%)
14.00
4 Lauryl sulfate Na
1.00
5 Cocamide DEA 1.00
6 Methylparaben 0.20
7 Phenoxyethanol 0.80
8 Polyquaternium-10 0.60
9 Citric acid 0.05
10 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1 to 7 were heated to about 70 ° C. and dissolved uniformly (part A). Next, no. 8, no. 10 was heated to about 70 ° C. and dissolved uniformly (part B). Part B was added to part A and mixed uniformly, and then cooled. Furthermore, no. 9 was added and mixed uniformly.

Example 21 Treatment A treatment having the following formulation was prepared. This treatment was able to give the hair a moist feeling and smooth fingering.

Component Blending amount (% by weight)
--------------------------------
1 Cetanol 8.00
2 Oleyl alcohol 1.00
3 Dimethicone (100cs) 1.00
4 Glyceryl stearate 1.00
5 Plandool-H (Nippon Seika) 1.00
6 Methylparaben 0.20
7 Oligomer ester of Example 1 1.00
8 Behentrimonium chloride 2.40
9 Hydroxyethyl cellulose 0.40
10 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1 to 8 were heated to about 70 ° C. and dissolved uniformly (part A). Next, no. 9 to 10 were heated to about 70 ° C. and dissolved uniformly (part B). Part B was added to part A and stirred and mixed uniformly, and then cooled to room temperature.

Example 22 Styling Gel A styling gel having the following formulation was prepared. When applied to hair, this styling gel was not sticky, did not move even when it was applied, and had high hair adhesion due to its high adhesion, and had excellent hairstyle durability.

Component Blending amount (% by weight)
-------------------------------------
1 STRUCTURE 2001 (made by NSC Japan) 5.00
2 TEA (50%) 3.50
3 AMPHOMER SH30 (made by NSC Japan) 3.00
4 Ethanol (95%) 3.00
5 Methylisothiazolineone 0.01
6 Oligomer ester of Example 1 2.00
7 Glycolic acid Appropriate amount 8 TEA Appropriate amount 9 Purified water Amount to be 100 in total --------------------------------- -----
(Preparation method)
No. No. 9 no. 6 was dissolved by heating. 2, no. 5 is dissolved (part A). No. in part A 1 is gradually added and mixed uniformly (part B). No. No. 3 4 and dissolved in part B cooled to 40 ° C. while mixing and dissolved uniformly. No. 7 or No. 8 adjust the pH to 7.0-7.5.

Example 23 Emollient cream An emollient cream having the following formulation was prepared. This emollient cream was a cream excellent in the effect of imparting a moist feeling.

Component Blending amount (% by weight)
--------------------------------
1 Oligomer ester of Example 1 2.00
2 Hydrogenated palm oil 2.50
3 Behenyl alcohol 2.00
4 Dimethicone (10cs) 1.50
5 Glyceryl stearate 1.50
6 Stearyl alcohol 1.20
7 Stearic acid PG (SE) 1.00
8 PEG-60 glyceryl isostearate 1.00
9 Octyl methoxycinnamate 0.20
10 Ethylparaben 0.10
11 BG 6.00
12 Glycerin 1.00
13 Phenoxyethanol 0.20
14 Methylparaben 0.15
15 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1-10 were added, and it heated and melt | dissolved at about 80 degreeC (A part). No. in a separate container. 11 to 15 were taken, heated to about 80 ° C., and dissolved uniformly (part B). Part B was added to part A, emulsified with a homomixer, and then cooled to 40 ° C.

Example 24 Sunscreen Agent A sunscreen agent having the following formulation was prepared. This sunscreen agent was a cream that suppressed breakage due to sweat and had a moist feeling.

Component Blending amount (% by weight)
--------------------------------
1 Oligomer ester of Example 1
11.70
2 Squalane 22.50
3 LUSPLAN PI-DA (Nippon Seika) 2.70
4 Microcrystalline wax 2.70
5 Al distearate 1.60
6 Mg stearate 1.60
7 BG 5.00
8 Behenyl alcohol 4.80
9 Composite-PC (Nippon Seika) 1.00
10 Cholesterol 0.80
11 Propylparaben 0.20
12 Methylparaben 0.20
13 Titanium oxide 9.00
14 Mg sulfate 0.50
15 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. No. 13 Nos. 1 and 2 3 was added and kneaded with a mill (part A). No. in a separate container. No. 2 4-6 were added and it heated and dissolved at about 150 degreeC (part B). No. in a separate container. No. 1 No. 7-12 were added, and it heated and dissolved at about 80 degreeC (part C). No. in a separate container. 14, 15 was added, and the mixture was heated to about 80 ° C. and dissolved (part D). Part C was added to part B, mixed, and then added to part A and mixed uniformly. Subsequently, D part was added, it stirred, and it cooled to 40 degreeC after emulsification.

Example 25 Base Cream A base cream having the following formulation was prepared. This base cream was a base cream that had a good elongation, had a foundation, had a good feel, and was able to impart a light touch.

Component Blending amount (% by weight)
--------------------------------
1 Oligomer ester of Example 2 5.00
2 Cyclomethicone 15.00
3 Trimethylsiloxysilicic acid 3.00
4 Glyceryl stearate (SE) 2.00
5 PG stearate (SE) 2.00
6 Macadamia nut fatty acid phytosteryl 2.00
7 Stearic acid 0.50
8 Palmitic acid 0.50
9 Octyl methoxycinnamate 0.50
10 Tocopherol 0.20
11 BG 10.00
12 Mica 8.00
13 Talc 7.00
14 Phenoxyethanol 0.80
15 Titanate (Li / Cobalt) 0.20
16 Xanthan gum (10%) 2.00
17 Cellulose gum (10%) 2.00
18 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 16 and 17 are No. A part of 18 was dissolved to obtain a viscous liquid (part A). No. in a separate container. 1-10 was added, and it heated and dissolved at about 80 degreeC (B part). No. in a separate container. 11-15, no. The remainder of 18 was added and heated to about 80 ° C. and dissolved (part C). After adding part C to part B and emulsifying, part A was added and mixed uniformly. It cooled to 40 degreeC after stirring.

Example 26 Foundation A foundation having the following formulation was prepared. This foundation had excellent color development and a moist feel.

Component Blending amount (% by weight)
--------------------------------
1 Oligomer ester of Example 1 6.00
2 Cyclomethicone 3.50
3 Dimethicone (5cs) 2.00
4 Trimethylsiloxysilicic acid 1.50
5 Octyl methoxycinnamate 1.00
6 Phenoxyethanol 0.40
7 Tocopherol 0.10
8 Mica 39.60
9 Talc 24.00
10 Titanium oxide
20.00
11 Iron oxide 1.90
--------------------------------
(Preparation method)
Each component was stirred at high speed and mixed uniformly.

Example 27 Lipstick A lipstick having the following formulation was prepared. This lipstick was fresh and highly adhesive.

Component Blending amount (% by weight)
--------------------------------
1 Oligomer ester of Example 1 1.00
2 Cetyl octanoate
22.50
3 Trioctanoin
28.50
4 Cyclomethicone
16:00
5 Ceresin 9.00
6 Candelilla Row 5.00
7 LUSPLAN PI-DA (Nippon Seika) 5.00
8 Sorbitan sesquiisostearate 4.00
9 Macadamia nut oil 1.00
10 Tocopherol 0.50
11 Iron oxide 2.25
12 Titanium oxide 2.25
13 Mica 1.50
14 Red 202 1.50
--------------------------------
(Preparation method)
No. Nos. 11-14 are No. 1 and 2 were kneaded (part A). No. in a separate container. 3 to 10 were added, and the mixture was heated to about 80 ° C. and dissolved (Part B). At about 80 ° C., part A was added to part B, dissolved, and then rapidly cooled.

Example 28 Lip Gloss A lip gloss having the following formulation was prepared. The lip gloss was fresh and had high adhesion.

Component Blending amount (% by weight)
--------------------------------
1 Oligomer ester of Example 1 2.00
2 Dextrin palmitate
10.00
3 Macadamia nut oil fatty acid phytosteryl 43.00
4 Methylphenylpolysiloxane
30.00
5 Trioctanoin
10.00
6 Liquid paraffin 5.00
--------------------------------
(Preparation method)
No. 1 and 2 were heated to 100-110 degreeC, and were dissolved uniformly. Next, no. 3-6 were added and it was made to melt | dissolve uniformly at about 80 degreeC.

Example 29 Cleansing oil A cleansing oil having the following formulation was prepared. This cleansing oil had a refreshing feel and was well-familiar with foundations, makeup, etc., and could be quickly removed.

Component Blending amount (% by weight)
--------------------------------
1 Oligomer ester of Example 1 1.00
2 Laureth-4 7.00
3 Tocopherol Appropriate amount 4 Propylparaben Appropriate amount 5 Cetyl octanoate Total amount of 100 6 Mineral oil 10.00
--------------------------------
(Preparation method)
All ingredients were heated and dissolved and mixed.

Example 30 Mascara A mascara having the following formulation was produced. This mascara had good adhesion, good usability, and good stability.

Component Blending amount (% by weight)
------------------------------
1 Iron oxide (black)
10.00
2 Light isoparaffin
30.00
3 Polyacrylate emulsion
30.00
4 Solid paraffin 8.00
5 Oligomer ester of Example 2 1.20
6 Sorbitan sesquioleate 4.00
7 Preservative Appropriate amount 8 Perfume Appropriate amount 9 Purified water Amount to be 100 in total --------------------------
(Preparation method)
No. No. 9 no. No. 1 was added and dispersed with a homomixer. 3 was added and heated to 70 ° C (aqueous phase). The other ingredients were mixed and heated to 70 ° C. (oil phase). The aqueous phase was added to the oil phase, and the mixture was uniformly emulsified and dispersed with a homomixer to obtain the desired mascara.

Example 31 Eyeshadow An eye shadow having the following formulation was produced. This eye shadow had good adhesion, good usability, and good emulsification stability.

Component Blending amount (% by weight)
------------------------------
1 Talc
10.00
2 Kaolin 2.00
3 facial medicine 5.00
4 Oligomer ester of Example 1 3.00
5 Stearic acid 3.00
6 Isopropyl myristate 5.00
7 Liquid paraffin 5.00
8 Propylene glycol monolaurate 3.00
9 Antioxidant appropriate amount 10 fragrance proper amount 11 BG
12 Glycerin 1.00
13 Preservative Appropriate amount 14 Triethanolamine 1.20
15 Metal ion sequestering agent Appropriate amount 16 Purified water Amount to be 100 in total --------------------------------
(Preparation method)
No. 1-3 were mixed with a blender and then processed with a pulverizer (powder part). No. 11 to 16 were heated and dissolved at 70 to 75 ° C. (aqueous phase part). No. 4 to 10 were dissolved by heating at 70 to 80 ° C. (oil phase part). The powder part was added to the aqueous phase part and mixed with stirring. The oil phase was added to this while stirring, dispersed with a homomixer, and stirred and cooled to room temperature to obtain the desired eye shadow.

Example 32 Straight Perm Agent (Cation Type)
One part and two parts of a straight perm agent (cation type) having the following formulation were prepared. This straight perm solution is a straight perm solution that can be applied firmly to the straight perm because of its high adhesiveness to the hair and setting power.

(1 liquid)
Component Blending amount (% by weight)
------------------------------------
1 Oligomer ester of Example 1 0.50
2 Cetanol 5.00
3 Steartrimonium chloride (63%) 2.40
4 Seths-20 2.40
5 TRIBEHENIN PEG-20 ESTERS 2.00
6 Seth-6 0.80
7 Lauramide MIPA 0.80
8 PEG-60 hydrogenated castor oil 0.40
9 Ammonium thioglycolate solution (50%) 13.50
10 Monoethanolamine 1.70
11 Polyquaternium-6 1.30
12 Hydrolyzed soy protein 1.00
13 EDTA-4Na 0.10
14 Ammonia water (28%) 1.10
15 Purified water Total amount of 100 ------------------------------------
(Preparation method)
No. Most of 15 were heated to about 80 ° C. (Part A). No. in a separate container. 1-8 were added and it heated and dissolved (part B). No. in a separate container. No.15, no. 9 to 13 were added and dissolved uniformly (part C). Part B was added to part A, mixed and stirred, and part C was added at about 45 ° C. and mixed uniformly. After cooling to room temperature, no. 14 was added.

(2 liquids)
Component Blending amount (% by weight)
------------------------------------
1 Oligomer ester of Example 1 2.00
2 Cetanol 5.00
3 Emmacol VT-20 (Sanei Chemical) 5.00
4 Dimethicone (200cs) 2.00
5 Trioctanoin 2.00
6 Octyldodecanol 0.60
7 SETES-20 0.50
8 Diammonium phosphate 0.20
9 Sodium benzoate 0.15
10 Na bromate 8.00
11 Purified water Total amount of 100 ------------------------------------
(Preparation method)
No. 1-7 were added, it heated at about 70 degreeC, and it was made to melt | dissolve (A part). No. in a separate container. No. 11 was taken and heated to about 70 ° C. 8 and 9 were added and dissolved (part B). No. in a separate container. No. 11 was taken and heated to about 60 ° C. 10 was added and dissolved (part C). At about 70 ° C., part B was added to part A and stirred until the viscosity increased. The mixture was cooled to 60 ° C., and part C was added with stirring and mixed uniformly. After the temperature dropped to about 50 ° C., it was rapidly cooled.

Example 33 Hair Depigmenting Agent (2 agent type)
Using the compound D obtained in Example 4, a hair bleaching agent (two-agent formula) having the following formulation was prepared. This depigmenting agent (two-component type) is a depigmenting agent that reduces the feeling of hair damage after depigmentation and gives the hair a good feel such as softness, moistness, and slipping. there were.

(1 agent)
Component Blending amount (% by weight)
--------------------------------
1 Oligomer ester of Example 2 0.50
2 Polyoxyethylene oleyl ether
52.00
3 Ammonia water (25%)
25.50
4 Cetrimonium chloride (30%)
10.00
5 Ethanol
10.00
6 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was stirred and mixed uniformly.

(2 agents)
Component Blending amount (% by weight)
--------------------------------
1 Hydrogen peroxide solution 17.00
2 Cetrimonium chloride (30%) 10.00
3 Cetanol 3.00
4 Seth-2 1.00
5 Seths-20 1.00
6 Na pyrophosphate 0.10
7 Diethylenetriaminepentaacetic acid 0.10
8 Citric acid (50%) Appropriate amount 9 Purified water Amount to be 100 in total --------------------------------
(Preparation method)
Each component was mixed uniformly, and the pH was adjusted to 3.5 to 4.0 with citric acid.
(Mixing ratio)
1 agent: 2 agents = 1: 7

Example 34 Oxidative hair dye An oxidative hair dye having the following formulation was prepared. This oxidative hair dye is an oxidative hair dye that reduces the feeling of hair damage after hair dyeing and gives the hair a good feel such as flexibility, moist feeling, and slipperiness. It was.

(1 agent)
Component Blending amount (% by weight)
--------------------------------
1 Oligomer ester of Example 1 0.50
2 Cetrinium chloride (25%)
24.00
3 Cetanol 9.00
4 Octild Decanol 9.00
5 Monoethanolamine 3.80
6 Ammonia water 2.00
7 Myristyl sulfate Na 1.50
8 Ores-20 1.40
9 Toluene hydrochloride, 2,5-diamine 1.00
10 Resorcinol 1.00
11 Metaaminophenol 0.50
12 Paraaminophenol 0.20
13 Orthoaminophenol 0.10
14 Ascorbic acid 0.20
15 Fragrance 0.10
16 Purified water Total amount to be 100 --------------------------------
(Preparation method)
Each component was mixed uniformly.

(2 agents)
Component Blending amount (% by weight)
--------------------------------
1 Hydrogen peroxide solution 17.00
2 Cetrinium chloride (30%) 10.00
3 Cetanol 3.00
4 Seth-2 1.00
5 Seths-20 1.00
6 Na pyrophosphate 0.10
7 Diethylenetriaminepentaacetic acid 0.10
8 Citric acid (50%) Appropriate amount 9 Purified water Amount to be 100 in total --------------------------------
(Preparation method)
Each component was mixed uniformly, and the pH was adjusted to 3.5 to 4.0 with citric acid.
(Mixing ratio)
1 agent: 2 agents = 1: 1

Example 35 Curling Agent A curling agent having the following formulation was produced. By using the curl agent 1 and 2 produced in this way for the hair, it was possible to curl with good flexibility, slipperiness, moist texture, and good finish.

(1 liquid)
Component Blending amount (% by weight)
------------------------------
1 Cysteamine hydrochloride 2.00
2 DL cysteine 0.40
3 Monoethanolamine 0.90
4 Ammonia water (28%) 0.50
5 POE20 palm oil fatty acid sorbitan 0.50
6 Perfume 0.10
7 Diallylammonium chloride / acrylic acid copolymer 1.00
8 Emmacol VT-20 (Sanei Chemical) 3.00
9 Ores-20 0.50
10 Ores-50 0.20
11 Oligomer ester of Example 1 0.50
12 Lanolin fatty acid octyldodecyl (Nippon Seika) 0.30
13 Sorbitan monostearate 0.20
14 tetrasodium edetate tetrahydrate 0.10
15 Ammonium phosphate 0.50
16 Purified water Total amount of 100 ---------------------------------
(Preparation method)
No. No. 16 in part (20%) 1 to 3 was added and dissolved, and No. 1 was previously stored in a separate container. No. 16 in part (10%) What was melt | dissolved by adding 14 and 15 was added at about 40 degreeC, and it was made to melt | dissolve uniformly (part A). In another container, no. The remainder of 16 was warmed to about 75 ° C. (Part B). In another container 8-13 were taken and heated to about 75 ° C. to dissolve (Part C). After adding part B to part C and emulsifying and stirring and mixing well, it was cooled to 40 ° C. and part A was added and stirred uniformly. Next, no. No. 7 was added and stirred. Nos. 5 and 6 were added. 4 was added, and the mixture was stirred and mixed uniformly to adjust the pH to 9.0 to 9.5, thereby obtaining the target curling agent 1 solution.

(2 liquids)
Component Blending amount (% by weight)
----------------------------------
1 EDTA-2Na 0.10
2 Na bromate 4.00
3 Ammonium phosphate 0.50
4 Cationic NH (Nippon Seika) 2.00
5 Cetrinium chloride (30%) 1.00
6 Ores-50 0.20
7 Dimethicone Copolyol 0.50
8 Sodium benzoate 0.15
9 Purified water Total amount of 100 ----------------------------------
(Preparation method)
No. 4-7 were heated to about 80 ° C. and dissolved (part A). In another container 9 (70%) and No. 9 1 and 8 were added and heated to about 80 ° C. to dissolve (Part B). In another container, no. No. 9 and No. 9 A few were added and heated to about 50 ° C. to dissolve (Part C). Add part B to part A and mix and stir uniformly to emulsify, then add part C when the temperature reaches 40 ° C., mix well, and adjust the pH to 6.5 to 6.8 at room temperature. Curl agent 2 liquid was obtained.

Example 36 Hair Cream A hair cream having the following formulation was prepared. This hair cream was glossy, non-sticky, kept the moisture of the hair, and was able to give a smooth feel.

Component Blending amount (% by weight)
--------------------------------
1 Oligomer ester of Example 2 2.00
2 Cetanol 4.00
3 Dimethicone (500cs)
13:00
4 Glyceryl stearate 2.80
5 Ores-10 phosphoric acid 0.80
6 Glyceryl stearate (SE) 1.60
7 Phenoxyethanol 0.40
8 Methylparaben 0.20
9 10% NaOH 0.60
10 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1 to 6 were heated to about 80 ° C. and dissolved (part A). No. in a separate container. 7-10 were added, and it heated and melt | dissolved at about 80 degreeC (B part). Part B was added to part A and mixed with stirring.

Example 37 Emollient cream An emollient cream having the following formulation was prepared. This emollient cream was a cream excellent in the effect of imparting a moist feeling.

Component Blending amount (% by weight)
--------------------------------
1 Oligomer ester of Example 1. 1.20
2 Cetyl octanoate 6.60
3 Hydrogenated palm oil 4.20
4 Glyceryl stearate (SE) 2.20
5 PEG-60 glyceryl isostearate 1.90
6 PG stearate (SE) 0.60
7 Stearyl alcohol 0.60
8 Dimethicone (10cs) 1.80
9 Ethylparaben 0.10
10 BG 3.00
11 Glycerin 1.00
12 Phenoxyethanol 0.20
13 Methylparaben 0.15
14 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1 to 9 were heated to about 70 ° C. and dissolved uniformly (part A). Next, no. 10-14 were heated to about 70 ° C. and dissolved uniformly (part B). To Part A, Part B was added with stirring and emulsified, and then cooled.

Example 38 Massage cream A massage cream having the following formulation was prepared. This massage cream was a cream having a high massage effect and excellent moisturizing effect.

Component Blending amount (% by weight)
--------------------------------
1 Oligomer ester of Example 1 4.00
2 Macadamia nut fatty acid phytosteryl 8.00
3 Glyceryl stearate (SE) 2.00
4 Polysorbate 60 1.80
5 sorbitan stearate 1.00
6 Polyglyceryl stearate-10 0.50
7 Cholesterol 0.20
8 Dimethicone (10cs) 1.00
9 Myristyl alcohol 1.00
10 Stearic acid 1.00
11 Stearyl alcohol 0.50
12 Behenyl alcohol 0.50
13 Hydrogenated palm oil 9.00
14 Tocopherol 0.10
15 Isostearyl palmitate 2.00
16 Cetyl octanoate 15.00
17 Ethylparaben 0.20
18 Phenoxyethanol 0.20
19 Methylparaben 0.10
20 BG
10.00
21 Glycerin 3.00
22 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1 to 17 were heated to about 70 ° C. and dissolved uniformly (part A). Next, no. 18-22 was heated to about 70 ° C. and dissolved uniformly (part B). To Part A, Part B was added with stirring and emulsified, and then cooled.

Example 39 Lip Gloss A lip gloss having the following formulation was prepared. This lip gloss was glossy, fresh and had high adhesion.

Component Blending amount (% by weight)
--------------------------------
1 Oligomer ester of Example 1. 7.70
2 LUSPLAN DD-DA7 (Nippon Seika)
17:00
3 Cetyl octanoate
33.00
4 Dextrin palmitate 7.00
5 Mica 9.00
6 Sulfuric acid Ba 25.00
7 Red 104 (1) 0.50
8 Yellow 203 0.80
--------------------------------
(Preparation method)
No. No. 4 In addition to a part of 3, it was heated to about 100-110 ° C. and dissolved uniformly (part A). Next, no. 1, 2 and the remaining No. 3, no. 5-8 were added and it mixed by the roll mill (B part). Part A and part B were added, heated to about 60 ° C., stirred and mixed uniformly, then filled into a mold and rapidly cooled.

Example 40 Liquid Foundation A liquid foundation having the following formulation was prepared. This liquid foundation was excellent in usability and adhesion to the skin.

Component Blending amount (% by weight)
--------------------------------
1 Oligomer ester of Example 1 5.00
2 Glyceryl stearate (SE) 1.00
3 Stearic acid PG (SE) 1.00
4 Cetyl octanoate 6.00
5 Tocopherol 0.10
6 Propylparaben 0.10
7 Titanium oxide / iron oxide mixture
18.00
(Toyo Pigment Co., Ltd. FDP-W-007)
8 Mica 7.00
9 Trimethylsiloxysilicate 3.00
10 Cyclomethicone 7.00
11 Phenylmethicone 5.00
12 Cellulose gum 0.10
13 Xanthan gum 0.20
14 BG 5.00
15 Methylparaben 0.20
16 Purified water Total amount to be 100 --------------------------------
(Preparation method)
No. 12 is a part of No. 12. 16 and stirred to give a viscous liquid (Part A). No. 13 for some No. 13 16 and stirred to give a viscous liquid (Part B). Next, no. 1 to 6 and 9 to 11 were added, and the mixture was heated to about 70 ° C. and dissolved (part C). No. 7, 8, 14, 15 and the remaining No. 16 was heated to about 70 ° C. and dissolved (part D). Part D was added to part C with stirring and emulsified, then cooled to about 50 ° C., part A and part B were added and stirred until uniform.

Example 41 Anti-aging cream An anti-aging cream having the following formulation was prepared. This cream had good elongation and was excellent in the effect of imparting a moist feeling.

Component Blending amount (% by weight)
----------------------------------
A
Oligomer ester of Example 1
10.00
Cetyl octoate 7.00
Batyl isostearate 2.00
PEG-60 glyceryl isostearate 1.50
Hydrogenated palm oil 3.70
Ceramide 2 0.10
Retinol 0.10
Oil-soluble chamomile extract 0.10
Ethylparaben 0.20
Stearyl alcohol 3.50
Glyceryl stearate (SE) 1.00
Steareth-6 1.50
Distearic acid PEG-8 1.00
Cetanol 1.00
Dimethicone 1.00
Cetyl dimethicone copolyol 0.50
Tocopherol 0.20
B
Saiheyanagi Extract 0.05
C
Arbutin 0.50
Ascorbic acid 2-O-glucoside 0.50
EDTA-3Na 0.10
Polyglutamic acid (Ichimaru Falcos, Bio PGA solution) 0.10
(Eicosanedioic acid / Tetradecanedioic acid) Polyglyceryl-10 Esters 1.00
Glycerin 4.00
Bisulfite Na 0.05
Methylparaben 0.10
Phenoxyethanol 0.10
BG 6.00
Hydroxide K Appropriate amount of purified water Amount to be 100 in total
(Production method)
A was heated to about 80 ° C. and dissolved uniformly (part A). C was heated to about 80 ° C. and dissolved (part C). While stirring with a homomixer at about 80 ° C., part C was gradually added to part A, mixed uniformly after emulsification, cooled to about 40 ° C., B was added and mixed uniformly.

Example 42 Hair Growth Agent A hair growth agent having the following formulation was prepared. This hair restorer was able to prevent hair loss, dandruff and itching.

Component Blending amount (% by weight)
----------------------------------
Example 1 Oligomer Ester 0.05
Diethyl sebacate 0.45
Menthol 0.10
Pepper tincture 0.50
Assembly extract 2.00
Ethanol 30.00
Preservative Appropriate amount of perfume Appropriate amount PPG-6 decyltetradeceth-30 0.30
Purified water Total amount of 100 ----------------------------------
(Production method)
Each component was stirred and mixed uniformly.

Example 43 Bath agent (bubble bath)
A bath preparation having the following formulation was prepared. This bath preparation has effects such as moisturizing skin and improving skin gloss.

Component Blending amount (% by weight)
--------------------------------
A
(C12, 13) Palace-3 sulfate Na 5.00
Cocamide DEA 2.00
Sulfosuccinic acid (C12-14) Palace-2Na 2.00
BG 2.00
The oligomeric ester of Example 2 1.00
PEG-20 glyceryl triisostearate 1.00
B
Citric acid 0.05
Sodium benzoate 0.20
Blue No.1 Trace yellow No.4 Trace C
Purified water Total amount of 100 --------------------------------
(Production method)
A is dissolved in a part of C to make it uniform. Add the remaining C and B and knead well.

Example 44 Hair Wax A hair wax having the following formulation was prepared. When applied to the hair, this hair wax is glossy, non-sticky, does not disperse even if it moves, has high adhesion, has a feeling of hair bundle, and has excellent hair style durability.

Component Blending amount (% by weight)
--------------------------------
1 Oligomer ester of Example 2 4.00
2 Candelilla Row 2.00
3 Cetanol 8.00
4 mineral oil
18.00
5 Trioctanoin 4.00
6 Microcrystalline wax 2.00
7 Diethyl sebacate 2.00
8 Dimethicone (100cs) 2.00
9 Laureth-2 2.00
10 Glyceryl stearate 3.00
11 PEG-40 hydrogenated castor oil 2.00
12 Polyglyceryl-3 diisostearate-3.00
13 Glycerin 6.00
14 BG 4.00
15 Phenoxyethanol 0.60
16 Methylparaben 0.20
17 Alcox E-240 (Meisei Chemical Industry) 0.20
18 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1 to 14 were heated to about 80 ° C. and dissolved (part A). Next, no. 15-18 was heated to about 80 ° C. and dissolved (part B). While stirring Part B into Part A, it was gradually added and dissolved uniformly.

Example 45 Liquid Facial Cleanser A liquid facial cleanser having the following formulation was prepared. This liquid cleanser was able to give the skin a moist and smooth slipperiness.

Component Blending amount (% by weight)
--------------------------------
1 Lauroyl sarcosine Na
12.00
2 Myristoyl methyl taurine Na 2.00
3 Isethionate Na 1.00
4 Polyglyceryl-6 laurate 2.00
5 Cocamide DEA 2.00
6 Sorbitol 8.00
7 PEG-30 4.00
8 BG 8.00
9 Oligomer ester of Example 1 2.00
10 Glycerin 5.00
11 Phenoxyethanol 0.80
12 (HEMA glucoside / ethyltrimonium methacrylate methacrylate)
Copolymer (10%) (Nippon Seika) 1.00
13 Purified water Total amount of 100 --------------------------------
(Production method)
No. 3 and 10 were heated to about 80 ° C. and dissolved (part A). No. in part A 1, 2, 4-9, 11-13 were added, heated to about 80 ° C. and uniformly dissolved, and then cooled.

Example 46 Body Shampoo A body shampoo having the following formulation was prepared. This body shampoo was able to give the skin a moist and smooth slipperiness.

Component Blending amount (% by weight)
--------------------------------
1 (HEMA glucoside / ethyltrimonium methacrylate methacrylate)
Copolymer (10%) (Nippon Seika) 2.00
2 Cocoyl Methyl Taurine Na 10.00
3 Lauroyl hydrolyzed silk Na 6.00
4 Lauroylmethylalanine Na 10.00
5 Cocoamphoacetate Na (30%) 4.00
6 Cocamidopropyl betaine (30%)
10.00
7 Cocamide DEA 3.00
8 Oligomer ester of Example 1 3.00
9 BG 5.00
10 Methylparaben 0.20
11 Purified water Total amount of 100 --------------------------------
(Production method)
No. 1 and a part of No. 11 were heated at about 80 ° C. and mixed uniformly (part A). No. 2-No. 10. The remaining 11 was heated at about 80 ° C. and mixed uniformly (Part B). While stirring, part A was gradually added to part B and mixed uniformly.

Example 47 Soap A soap having the following formulation was prepared. This soap was able to give the skin a moist feeling and a smooth slipperiness.

Component Blending amount (% by weight)
--------------------------------
Soken base Amount of total lauric acid 5.00
BG 3.00
Oligomer ester of Example 1 5.00
Plandool-H (Nippon Seika) 0.05
Titanium oxide 1.00
Etidronic acid 0.10
Edetate 0.10
Yellow No. 205 Trace --------------------------------
(Production method)
All components are dissolved by heating to 80 ° C., cooled with stirring, poured into molds and left to stand.

Example 48 Face Wash A face wash having the following formulation was prepared. This facial cleanser was able to give the skin a moist feeling and a smooth slipperiness.

Component Blending amount (% by weight)
--------------------------------
A
Oligomer ester of Example 1 0.50
Plandool-H (Nippon Seika) 0.20
Jojoba oil 0.10
Squalane 0.10
Cocamide DEA 2.00
Lauramide DEA 3.00
Tocopherol 0.20
Propylparaben 0.10
B
Glycol distearate 1.00
Lauroylmethylalanine Na (30%) 10.00
Coconut fatty acid K, myristic acid K (40%)
40.00
BG 3.50
1,5-pentanediol 0.50
1,2-hexanediol 0.30
PEG-20 5.00
PEG-400 5.00
Citric acid 0.50
Methylparaben 0.20
CETEARETH-60 myristyl glycol 2.00
Purified water Total amount of 100 --------------------------------
(Production method)
A was heated to about 80 ° C. and dissolved. B was heated to about 80 ° C. and dissolved. B was added to A with stirring and emulsified, and then cooled to about 40 ° C.

Example 49 Hair Foam A hair foam having the following formulation was prepared. This hair foam has a good feeling of use and a light natural setability, and provides an improved feel such as imparting gloss and moisture to the hair.

Component Blending amount (% by weight)
--------------------------------
(Stock solution formulation)
A
Oligomeric ester of Example 1 1.00
Plandool-H (Nippon Seika) 1.00
LUSPLAN DD-IS (Nippon Seika) 1.00
Hydrogenated polybutene 0.20
Cetanol 1.50
Beeswax 1.00
Octenyl succinate corn starch 0.20
Dimethicone 0.10
Dimethicone polyol 0.30
Myristic acid 2.00
Triethanolamine appropriate amount PEG-hydrogenated castor oil 0.20
PEG-sorbitan cocoate 0.20
Behentrimonium chloride 0.20
PEG 3.00
ethanol
15.00
Phenoxyethanol Appropriate amount of propylparaben Appropriate amount of methylparaben Appropriate amount of purified water Amount B totaling 100 in total
Fragrance 0.10
(Filling prescription)
Undiluted solution
50.00
LPG
50.00
--------------------------------
(Preparation method)
A was mixed according to a conventional method, and B was added. After filling this stock solution into a can, it was filled with gas.

Example 50 Pre-shave lotion A pre-shave lotion having the following formulation was prepared. This pre-shave lotion has the effect of making the skin smooth.

Component Blending amount (% by weight)
--------------------------------
A
The oligomeric ester of Example 1 0.10
Citric acid 0.05
Zinc phenol sulfonate 0.20
PEG-60 hydrogenated castor oil 0.10
Glycyrrhizic acid 2K 0.05
Purified water Amount B totaling 100
ethanol
30.00
Tocopherol 0.01
Methylparaben 0.15
--------------------------------
(Preparation method)
Both A and B are dissolved at room temperature, and B is gradually added to A with stirring to make it uniform.

Example 51 Deodorant (Antiperspirant)
A deodorant (antiperspirant) having the following formulation was prepared. This deodorant has the effect of making the skin smooth.

Component Blending amount (% by weight)
--------------------------------
A
The oligomeric ester of Example 1 0.20
Purified water Amount to be 100 in total Methylparaben 0.10
Na chloride 0.01
Citric acid 0.05
Na citrate 0.05
Laureth-21 0.10
Benzalkonium chloride 0.05
Chlorhydroxyaluminum 0.20
B
Denatured alcohol 40.00
Propylparaben 0.50
Isopropyl methylphenol 0.50
--------------------------------
(Preparation method)
Both A and B are dissolved at room temperature, and B is gradually added to A with stirring to make it uniform.

Example 52 Moisture Pack A moisture pack having the following formulation was prepared. This moist chair pack enhances the moisturizing effect, softens the skin, gives a moist feeling, and provides an excellent cleaning action.

Component Blending amount (% by weight)
--------------------------------
A
Polyvinyl alcohol
13:00
BG 3.00
Alginic acid K 0.50
(Styrene / Vinylpyrrolidone) Copolymer 1.50
B
Plandool-G (Nippon Seika) 0.30
The oligomeric ester of Example 1 0.20
PCA Glyceres-25 Isostearate-25 1.50
Denatured alcohol 8.00
PEG / PPG-5 / 30 copolymer 1.00
Ores-10 phosphate DEA 1.00
Glycyrrhizic acid 2K 0.05
Tocopherol 0.10
Methylparaben 0.20
Hyaluronic acid Na 0.05
Na chloride 0.30
Purified water Total amount of 100 --------------------------------
(Preparation method)
A is warmed and swollen at 50 ° C. Slowly add B to A with stirring and mix uniformly. Cool with stirring, stop stirring at 30-25 ° C. and let stand.

Example 53 Cleansing milk A cleansing milk having the following formulation was prepared. Since this cleansing milk is excellent in solubility, it has a good foundation and make-up, and has an effect of giving a refreshing feel.

Component Blending amount (% by weight)
--------------------------------
1 Oligomer ester of Example 1 3.00
2 Neosolute-DE (Nippon Seika) 5.00
3 Stearic acid 0.50
4 Mineral oil 32.00
5 Seths-20 2.40
6 Triceteth-5 phosphoric acid 3.60
7 Stearic acid PG (SE) 3.00
8 Propylparaben 0.10
9 Dimethicone 10.0
10 Carbomer 0.10
11 Hydroxide K 0.04
12 EDTA-2Na 0.05
13 Phenoxyethanol 0.20
14 Methylparaben 0.10
15 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 15 is a part of No. 15. No. 10 was added and stirred well. 11 was added to obtain a viscous liquid (Part A). No. 12-14, the remaining No. 15 was heated to about 70 ° C. and dissolved (Part B). No. 1 to 9 were heated to about 70 ° C. and dissolved (part C). After stirring and emulsifying part B while stirring part C, part A was added and cooled with stirring.

According to the present invention, an oligomer ester having high safety, excellent solubility in water, dispersibility, and good lubricity, and water-based and water-soluble lubrication having good safety, lubricity and cooling properties containing these oligomer esters. The composition and the cosmetics or the external preparation for skin containing the oligomer ester in which the sticky feeling was suppressed can be provided.

Claims (7)

Oligomer ester synthesized from the following components (A) and (B).
(A) One or more divalent carboxylic acids containing a straight chain, branched chain, or cyclic structure having 2 to 36 carbon atoms.
(B) One or more polyglycerols having an average degree of polymerization calculated from the hydroxyl value of 2 to 15, and glycerol.   The oligomer ester according to claim 1, wherein the polyglycerin of the component (B) is a polyglycerin having an average degree of polymerization calculated from the hydroxyl value of 6 to 12.   The oligomer (1) according to claim 1 or 2, wherein the component (A) is one or more divalent carboxylic acids containing a linear, branched or cyclic structure having 2 to 22 carbon atoms.   The oligomer (1) according to claims 1 to 3, wherein the component (A) is at least one sebacic acid among one or more divalent carboxylic acids.   The molar ratio of glycerin and polyglycerin which is an oligomer ester synthesized using 0.3 to 1.5 mol of component (A) with respect to 1.0 mol of component (B) and which constitutes component (B) The oligomer ester according to claim 1, wherein is 10: 1 to 1: 1.   An aqueous and water-soluble lubricating composition containing the oligomer ester according to any one of claims 1 to 5. A cosmetic or external preparation for skin containing the oligomer ester according to any one of claims 1 to 5.