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JP2008159352A - Method and device for manufacturing cylindrical cell - Google Patents

Method and device for manufacturing cylindrical cell Download PDF

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JP2008159352A
JP2008159352A JP2006345498A JP2006345498A JP2008159352A JP 2008159352 A JP2008159352 A JP 2008159352A JP 2006345498 A JP2006345498 A JP 2006345498A JP 2006345498 A JP2006345498 A JP 2006345498A JP 2008159352 A JP2008159352 A JP 2008159352A
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separator
cylindrical
bottom separator
winding
electrode material
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JP5070833B2 (en
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Yoshihiro Sawada
伊弘 澤田
Kengo Osaki
健吾 大崎
Masahisa Yamashita
真央 山下
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Panasonic Holdings Corp
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Matsushita Electric Industrial Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method of manufacturing a cylindrical cell with a housing volume of an anode material restrained from decreasing, by arranging an overlapping part of a cylindrical separator made up by being wound around in a cylindrical shape and a folded overlapping part of a folded corner part of a square-shaped bottom-part separator so as not to overlap each other, and suppressing reaction shortage of both electrodes by narrowing an interval between an anode material and a cathode material, in one housing the cylindrical separator and the bottom-part separator in a cell case of a bottomed cylindrical shape. <P>SOLUTION: In the manufacturing method of the cylindrical cell, a cathode material 2, an anode material 4, alkaline solution and a cylindrical separator 3 intercalated between the cathode material 2 and the anode material 4 as well as the bottom-part separator 5 are housed in the bottomed cylindrical-shape cell case 1, and it is so arranged that an overlapping part 3a of the cylindrical separator 3 made up by being wound around in a cylindrical shape and a corner part 5a of the square-shaped bottom-part separator 5 shall not overlap each other. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、アルカリマンガン乾電池に代表される円筒形電池の正極材と負極材との間に介在されるセパレータの位置を改良した円筒形電池の製造方法およびその製造装置に関するものである。   The present invention relates to a manufacturing method and an apparatus for manufacturing a cylindrical battery in which the position of a separator interposed between a positive electrode material and a negative electrode material of a cylindrical battery typified by an alkaline manganese dry battery is improved.

近年、強負荷の放電性能を必要とされる携帯型情報機器やデジタルカメラなどでは大電流放電する電子機器が多く市場に普及している。これらの電子機器の電源として求められているアルカリマンガン乾電池に代表される円筒形電池の需要が急速に高まっている。それに伴い、アルカリマンガン乾電池の生産効率の向上および高品質で信頼性のある大容量でハイパワーな円筒形電池の生産が求められている。   In recent years, there are many electronic devices that discharge large currents in portable information devices and digital cameras that require high load discharge performance. Demand for cylindrical batteries typified by alkaline manganese dry batteries, which are required as power sources for these electronic devices, is rapidly increasing. Accordingly, there is a demand for improvement in production efficiency of alkaline manganese batteries and production of high-quality, reliable, large-capacity, high-power cylindrical batteries.

図9に従来技術に係るアルカリマンガン乾電池の構成を示す。アルカリマンガン乾電池は、円筒状外形の底部に正極凸部85が形成された電池ケース103内に、円筒状の正極材104、円筒状の筒状セパレータ101および正方形の底部セパレータ102、ゲル状の負極材106を収納し電池ケース103の開口端を絶縁ガスケット87を介して封口板88で封口すると共に、ゲル状の負極材106中に挿入された負極集電棒89に封口板88を接続して構成されている。この電池ケース103の底部には底部セパレータ102が配設され、ゲル状の負極材106と正極端子となる電池ケース103との間が内部短絡しないように隔離する方法が提案されている(例えば、特許文献1参照)。   FIG. 9 shows the configuration of an alkaline manganese dry battery according to the prior art. An alkaline manganese battery has a cylindrical positive electrode material 104, a cylindrical cylindrical separator 101 and a square bottom separator 102, a gel negative electrode in a battery case 103 having a positive electrode convex portion 85 formed at the bottom of a cylindrical outer shape. The material 106 is accommodated, and the opening end of the battery case 103 is sealed with a sealing plate 88 through an insulating gasket 87, and the sealing plate 88 is connected to a negative electrode current collector rod 89 inserted into the gelled negative electrode material 106. Has been. A bottom separator 102 is provided at the bottom of the battery case 103, and a method of isolating the gel-like negative electrode material 106 and the battery case 103 serving as a positive electrode terminal so as not to be internally short-circuited has been proposed (for example, Patent Document 1).

また、従来電池の構成に係る製造装置の工程手順を示す状態図を図10(a)〜(c)に示す。図10(a)で示すように前工程で正極材104を挿入された電池ケース103を電池搬送治具110で筒状セパレータ101が通過できる円形のガイド穴114とガイド穴114の上部に正方形の底部セパレータ102を保持する保持部111からなるセパレータ装填治具112の中心軸が同一軸線上になるように搬送する。   Moreover, the state diagram which shows the process procedure of the manufacturing apparatus which concerns on the structure of a conventional battery is shown to Fig.10 (a)-(c). As shown in FIG. 10A, a circular guide hole 114 through which the cylindrical separator 101 can be passed by the battery transport jig 110 through the battery case 103 in which the positive electrode material 104 has been inserted in the previous process, and a square shape above the guide hole 114. The separator loading jig 112 including the holding unit 111 that holds the bottom separator 102 is conveyed so that the central axis is on the same axis.

次に図10(b)で示すように、電池ケース103内の正極材104の内周面に接するように円筒状に2回巻かれた筒状セパレータ101とセパレータ装填治具112の保持部111に保持された底部セパレータ102を巻芯113を用いてセパレータ装填治具112と巻芯113と電池ケース103とをそれぞれの中心軸が同一軸線上に一致した状態で、筒状セパレータ101の先端部を底部セパレータ102に当接させて両セパレータを同時にガイド穴114を通過させて電池ケース103に挿入される。   Next, as shown in FIG. 10B, the cylindrical separator 101 wound twice in a cylindrical shape so as to be in contact with the inner peripheral surface of the positive electrode material 104 in the battery case 103 and the holding portion 111 of the separator loading jig 112. The bottom separator 102 held on the tip of the cylindrical separator 101 with the core 113 aligned with the separator loading jig 112, the core 113, and the battery case 103 using the core 113 is aligned on the same axis. Are brought into contact with the bottom separator 102, and both separators are simultaneously inserted into the battery case 103 through the guide hole 114.

その後、図10(c)で示すように挿入された両セパレータ101,102は電池ケース103内において配設されたまま巻芯113は上昇し、電池搬送治具110は次工程(図示せず)へと搬送される。その後、次工程において両セパレータ101,102で囲まれた中央空間にゲル状の負極材を投入し、電解液を注液後に電池ケース103の開口部を封口板で封口して円筒形電池を製造する方法が提案されている(例えば、特許文献2参照)。
特許第3552911号公報 特許第3655469号公報
Thereafter, as shown in FIG. 10 (c), both the separators 101 and 102 are disposed in the battery case 103 while the core 113 is raised, and the battery transfer jig 110 is moved to the next step (not shown). It is conveyed to. Thereafter, in the next step, a gelled negative electrode material is introduced into the central space surrounded by both separators 101, 102, and after pouring the electrolyte, the opening of the battery case 103 is sealed with a sealing plate to produce a cylindrical battery. A method has been proposed (see, for example, Patent Document 2).
Japanese Patent No. 3555211 Japanese Patent No. 3655469

しかしながら、上述した特許文献に示される従来技術では、図9に示すように底部セパレータ102の角部と筒状セパレータ101の巻初めと巻終わりからなる重なり部が重な
り合い、負極材106と正極材104との極間距離が増大し両極の反応不足を引き起こしたり、負極材106の収容量が減少したりすることで所要の放電性能が得られないなどの課題があった。
However, in the prior art disclosed in the above-mentioned patent document, as shown in FIG. 9, the corners of the bottom separator 102 overlap the overlapping portions formed from the beginning and end of winding of the cylindrical separator 101, and the negative electrode material 106 and the positive electrode material 104 are overlapped. As a result, there is a problem that the required discharge performance cannot be obtained due to an increase in the distance between the electrodes and a shortage of reaction between the two electrodes, or a decrease in the capacity of the negative electrode material 106.

図11で示す筒状セパレータ101と底部セパレータ102の組付ける状態を示した斜視図のように、筒状セパレータ101の一部分を底部セパレータ102で包み込んだ際に筒状セパレータ101の巻始めと巻終わりが重なった重なり部101aと底部セパレータ102の折り曲げられた角部102aとが重なり合って厚くなり、図9に示す負極材106と正極材104とが筒状セパレータ101を介して対面する反応面の極間距離が増大して隙間が生じ、負極材106と正極材104との極間反応が悪くなる。その上、筒状セパレータ101の重なり部101aと底部セパレータ102の折り曲げられた角部102aによって両セパレータが幾重にもなるため負極材106の収容量が減少することになり、所要の放電性能が得られないという問題が生じていた。   As shown in the perspective view of the assembled state of the cylindrical separator 101 and the bottom separator 102 shown in FIG. 11, when the cylindrical separator 101 is partially wrapped with the bottom separator 102, the start and end of winding of the cylindrical separator 101 are performed. The overlapping portion 101 a where the two overlap each other and the bent corner portion 102 a of the bottom separator 102 overlap and become thick, and the negative electrode material 106 and the positive electrode material 104 shown in FIG. The gap between the gaps increases and a gap between the negative electrode material 106 and the positive electrode material 104 deteriorates. In addition, since the separators are overlapped by the overlapped portion 101a of the cylindrical separator 101 and the bent corner portion 102a of the bottom separator 102, the capacity of the negative electrode material 106 is reduced, and the required discharge performance is obtained. There was a problem that it was not possible.

本発明は上記従来の課題を鑑みてなされたもので、円筒状に巻回してなる筒状セパレータの重なり部と方形状の底部セパレータの角部とを重ならないように配置することにより、負極材の容量の減少を抑制することができ、また両セパレータを介しての正極材と負極材との極間距離が近くなるので内部抵抗のバラツキを抑えられ、放電特性のバラツキを抑制でき、放電特性の向上が可能となる信頼性の高い大容量でハイパワーな円筒形電池の製造方法およびその製造装置を提供することを目的としている。   The present invention has been made in view of the above-described conventional problems. By disposing the overlapping portion of the cylindrical separator wound in a cylindrical shape and the corner portion of the rectangular bottom separator so as not to overlap, the negative electrode material In addition, since the distance between the positive electrode material and the negative electrode material through both separators is reduced, the variation in internal resistance can be suppressed, and the variation in discharge characteristics can be suppressed. It is an object of the present invention to provide a method for manufacturing a highly reliable, large capacity, high power cylindrical battery and its manufacturing apparatus.

上記目的を達成するために本発明の円筒形電池の製造方法は、有底円筒状の電池ケース内に円筒状に成形した正極材を収納し、方形状の底部セパレータと円筒状の筒状セパレータを挿入後に電解液とゲル状の負極材を挿入したのち、電池ケースの開口部を負極集電棒を具備した封口板で封口する円筒形電池の製造方法において、底部セパレータと筒状セパレータを同時に挿入する際、底部セパレータの角部を位置決めし円筒状に成形した筒状セパレータの巻始めと巻終わりからなる重なり部が底部セパレータの角部と重ならない位置となるように位置決めした後に挿入することを特徴としている。   In order to achieve the above object, a method for manufacturing a cylindrical battery according to the present invention includes a positive electrode material formed in a cylindrical shape in a bottomed cylindrical battery case, and a rectangular bottom separator and a cylindrical cylindrical separator. In the method of manufacturing a cylindrical battery in which the electrolytic solution and the gelled negative electrode material are inserted, and then the opening of the battery case is sealed with a sealing plate equipped with a negative electrode current collector rod, the bottom separator and the cylindrical separator are simultaneously inserted. When positioning, the corner of the bottom separator is positioned and inserted after positioning so that the overlapping part consisting of the beginning and end of winding of the cylindrical separator formed into a cylindrical shape does not overlap the corner of the bottom separator. It is a feature.

本発明によれば、円筒状に巻回してなる前記筒状セパレータの重なり部と方形の底部セパレータの角部とを重ならないように配置することにより、筒状セパレータの重なり部と底部セパレータの角部が折れ曲がった折り重なり部とが重ならないことで負極材の容量の減少を抑制でき、かつ正極材と負極材との極間距離が近くなり、内部抵抗のバラツキおよび放電特性が向上され大容量で高い信頼性を得ることが可能となる。   According to the present invention, the overlapping part of the cylindrical separator and the corner of the bottom separator are arranged so as not to overlap the overlapping part of the cylindrical separator and the corner of the rectangular bottom separator. Since the folded part does not overlap with the bent part, it is possible to suppress the decrease in capacity of the negative electrode material, and the distance between the positive electrode material and the negative electrode material is reduced, so that variation in internal resistance and discharge characteristics are improved, resulting in high capacity. High reliability can be obtained.

本発明の第1の発明においては、有底円筒状の電池ケース内に円筒状に成形した正極材を収納し、方形状の底部セパレータと円筒状の筒状セパレータを挿入後に電解液とゲル状の負極材を挿入したのち、電池ケースの開口部を負極集電棒を具備した封口板で封口する円筒形電池の製造方法において、底部セパレータと筒状セパレータを同時に挿入する際に底部セパレータの角部を位置決めし、円筒状に成形した筒状セパレータの巻始めと巻終わりからなる重なり部が底部セパレータの角部と重ならない位置となるように位置決めした後に挿入することにより、筒状セパレータの重なり部と底部セパレータの折り曲げた角部とが重ならず、負極材の容量の減少が抑制され、かつ正極材と負極材との極間距離が近くなり内部抵抗のバラツキが抑えられ、放電特性を向上させることが可能となる。   In the first invention of the present invention, the positive electrode material formed in a cylindrical shape is housed in a cylindrical battery case with a bottom, and after inserting a rectangular bottom separator and a cylindrical cylindrical separator into an electrolyte and a gel In the method of manufacturing a cylindrical battery in which the negative electrode material is inserted and then the opening of the battery case is sealed with a sealing plate having a negative electrode current collector rod, the corner of the bottom separator is inserted when the bottom separator and the cylindrical separator are simultaneously inserted. The cylindrical separator overlaps the cylindrical separator by inserting it after positioning it so that the overlapping part consisting of the beginning and end of winding of the cylindrical separator formed in a cylindrical shape does not overlap the corner of the bottom separator. And the bent corners of the bottom separator do not overlap, reducing the capacity of the negative electrode material, and reducing the distance between the positive electrode material and the negative electrode material, reducing variations in internal resistance Is, it is possible to improve the discharge characteristics.

本発明の第2の発明においては、底部セパレータの周縁の立上り部が円筒状に成形した正極材の内周面に接するように挿入すると同時に筒状セパレータの先端部を底部セパレー
タの周縁の立上り部で外側より包むように装着することにより、衝撃や振動等による底部セパレータの位置がズレて負極材と電池ケースとの接触による内部短絡を抑え、負極材の底面側は底部セパレータのみで電池ケースとの間を絶縁されるので負極材の収容量の減少を抑制し、効率よい放電が可能となる。
In the second invention of the present invention, the leading edge of the cylindrical separator is inserted into the peripheral edge of the bottom separator at the same time as the rising edge of the peripheral edge of the bottom separator is in contact with the inner peripheral surface of the positive electrode material formed into a cylindrical shape. By mounting it so that it wraps from the outside, the position of the bottom separator is shifted due to impact, vibration, etc., and internal short circuit due to contact between the negative electrode material and the battery case is suppressed, and the bottom surface side of the negative electrode material is the bottom separator only with the battery case. Since the gap is insulated, it is possible to suppress a decrease in the capacity of the negative electrode material and to discharge efficiently.

本発明の第3の発明においては、底部セパレータとして、帯状セパレータを4辺の長さが同一寸法になるように切断して成形することにより、底部セパレータの切り出しのロスをなくして原材料の歩留まり向上が可能となる。   In the third aspect of the present invention, as the bottom separator, the strip separator is cut and molded so that the lengths of the four sides have the same dimension, thereby eliminating the loss of cutting out of the bottom separator and improving the raw material yield. Is possible.

本発明の第4の発明においては、有底円筒状の電池ケース内に円筒状に成形した正極材を収納し、方形状の底部セパレータと円筒状の筒状セパレータを挿入後に電解液とゲル状の負極材を挿入し、電池ケースの開口部を負極集電棒を具備した封口板で封口する円筒形電池の製造装置において、底部セパレータの供給部と底部セパレータの角部を位置決めする位置決め部を有し、筒状セパレータ供給部と筒状セパレータの巻始めと巻終わりからなる重なり部を底部セパレータの角部と重ならないように位置決めする位置決め部と位置決めされた筒状セパレータと底部セパレータとを正極材を収納した電池ケース内に同時に挿入する挿入部と、正極材を収納した電池ケースを搬入する搬送部と搬出する搬出部から構成したことにより、筒状セパレータの重なり部を位置決めした底部セパレータの角部と重ならない位置に配置し装着することが可能となる。   In the fourth invention of the present invention, the positive electrode material formed into a cylindrical shape is housed in a cylindrical battery case with a bottom, and after inserting a rectangular bottom separator and a cylindrical cylindrical separator into an electrolyte and a gel In a cylindrical battery manufacturing apparatus in which the negative electrode material is inserted and the opening of the battery case is sealed with a sealing plate provided with a negative electrode current collector rod, a positioning part for positioning the supply part of the bottom separator and the corner part of the bottom separator is provided. The cylindrical separator supply section and the cylindrical separator and the bottom separator are positioned as a positive electrode material, positioning the cylindrical separator supply section and the cylindrical separator and the bottom separator so as not to overlap the corners of the bottom separator. The cylindrical separator is configured by an insertion portion that is simultaneously inserted into a battery case that houses the battery case, a transport portion that carries in the battery case that houses the positive electrode material, and a carry-out portion that carries out the battery case. Placed in a position that does not overlap with the corner portion of the positioning and bottom separator overlapping portion of the data it is possible to mount.

本発明の第5の発明においては、底部セパレータの供給部として、帯状セパレータを送り出す送りローラと帯状セパレータから正方形に切断する切断刃ローラと、切断した底部セパレータを真空吸着して搬送する真空吸着ローラと真空吸着レバーを有する送転盤と、真空を発生する真空部と駆動源である駆動部から構成したことにより、帯状セパレータから正方形である底部セパレータを切り出すことが可能となり底部セパレータの取り扱いが簡素化でき、生産能力の向上が可能となる。   In a fifth aspect of the present invention, as a supply unit for the bottom separator, a feeding roller for feeding the strip separator, a cutting blade roller for cutting the strip separator into a square, and a vacuum suction roller for sucking and transporting the cut bottom separator And a vacuum disk that has a vacuum suction lever, a vacuum unit that generates vacuum, and a drive unit that is a drive source, it is possible to cut out a square bottom separator from a strip separator, and the handling of the bottom separator is simple And production capacity can be improved.

本発明の第6の発明においては、底部セパレータの位置決め部として、底部セパレータ保持回転盤内に設けられた底部セパレータ保持部と電池ケースを位置決めするガイドから構成したことにより、底部セパレータの角部の位置決めをし、その位置決めした状態を維持しながら筒状セパレータの重なり部と重ならないように配置することができ確実な位置決めが可能となる。   In the sixth aspect of the present invention, the bottom separator positioning portion includes a bottom separator holding portion provided in the bottom separator holding rotating disk and a guide for positioning the battery case. Positioning can be performed so as not to overlap the overlapping portion of the cylindrical separator while maintaining the positioned state, and reliable positioning is possible.

本発明の第7の発明においては、筒状セパレータの供給部として、帯状セパレータを供給する巻出し部と帯状セパレータを所定の寸法に切断する切断部からなる構成にしたことにより、巻回時に筒状セパレータの巻終わりが巻始めの位置になる寸法で切断し、ズレることなく確実な筒状セパレータの重なり部を成形することが可能となる。   In the seventh aspect of the present invention, the cylindrical separator supply section includes an unwinding section that supplies the strip separator and a cutting section that cuts the strip separator into a predetermined size. It is possible to cut a dimension at which the winding end of the cylindrical separator becomes the winding start position, and to form a reliable overlapping portion of the cylindrical separator without deviation.

本発明の第8の発明においては、筒状セパレータの位置決め部として、切断した帯状セパレータを巻初め位置に導く巻付けガイドと巻芯と巻芯に巻き付ける巻付けローラと挿入ヘッド回転盤と駆動部からなる構成にしたことにより、巻回時に筒状セパレータの巻終わりが巻始めの位置になる寸法で切断された筒状セパレータを巻回し所定の位置で筒状セパレータの重なり部の位置決めをすることが可能となる。   In the eighth aspect of the present invention, as a positioning portion of the cylindrical separator, a winding guide for guiding the cut strip separator to a winding start position, a winding core, a winding roller for winding the winding core, an insertion head rotating disk, and a driving unit By winding the cylindrical separator that has been cut in such a dimension that the end of winding of the cylindrical separator becomes the starting position when winding, the overlapping portion of the cylindrical separator is positioned at a predetermined position. Is possible.

以下、本発明の一実施の形態について図を参照にしながら詳細に説明する。まず、本発明の一実施の形態の円筒形電池であるアルカリマンガン乾電池の構成について、図1を参照して説明する。   Hereinafter, an embodiment of the present invention will be described in detail with reference to the drawings. First, the configuration of an alkaline manganese battery that is a cylindrical battery according to an embodiment of the present invention will be described with reference to FIG.

図1に示すように底面に正極端子とする外方に向けて突出形成した正極凸部6を設け、有底円筒形に形成された正極端子一体型の電池ケース1に電池ケース1の内周面に接して
いる円筒形状に成形された正極材2が収容され、この正極材2の内径方向に底部セパレータ5と筒状セパレータ3で隔てられた電解液(図示せず)とゲル状の負極材4が収容されている。電池ケース1の開口端は絶縁ガスケット7を介して、封口板8によって封口されると共にゲル状の負極材4に挿入した負極集電棒9を接続し負極端子である封口板8が取り付けられて円筒形のアルカリマンガン乾電池10を構成している。
As shown in FIG. 1, a positive electrode convex portion 6 is formed on the bottom surface so as to protrude outward as a positive electrode terminal. A positive electrode material 2 formed in a cylindrical shape in contact with the surface is accommodated, and an electrolyte solution (not shown) and a gel-like negative electrode separated by a bottom separator 5 and a cylindrical separator 3 in the inner diameter direction of the positive electrode material 2 The material 4 is accommodated. The open end of the battery case 1 is sealed by a sealing plate 8 via an insulating gasket 7 and connected to a negative electrode current collector rod 9 inserted into a gelled negative electrode material 4 and attached to a sealing plate 8 serving as a negative electrode terminal. The alkaline manganese dry battery 10 is formed.

以下、本発明の一実施の形態に関わるアルカリマンガン乾電池の製造方法について図を参照しながら詳細に説明するが、本発明は、これらのみに限定されない。まず、図1に示すように有底円筒形に形成し底面には正極端子となる外方に向けて突出形成した正極凸部6が設けられた電池ケース1内に、粉末状の正極合剤を円筒形状に圧縮成形した正極材2を電池ケース1の内周面に接した状態で挿入し収納する。アルカリマンガン乾電池の品種により収納する円筒形状した正極材2を複数個収納し、本発明の一実施の形態においては電池ケース1内に2個の正極材2を収納する。   Hereinafter, although the manufacturing method of the alkaline manganese battery in connection with one embodiment of this invention is demonstrated in detail, referring a figure, this invention is not limited only to these. First, as shown in FIG. 1, a powdered positive electrode mixture is formed in a battery case 1 formed with a bottomed cylindrical shape and provided with a positive electrode convex portion 6 formed on the bottom surface so as to protrude outward as a positive electrode terminal. Is inserted and housed in a state where it is in contact with the inner peripheral surface of the battery case 1. A plurality of cylindrical positive electrode materials 2 to be stored depending on the type of alkaline manganese dry battery are stored. In one embodiment of the present invention, two positive electrode materials 2 are stored in the battery case 1.

なお、正極材2は二酸化マンガンと黒鉛とを90:10の重量比で混合した混合物とアルカリ電解液とを100:3の重量比で混合し、十分に攪拌した後、フレーク状に圧縮成形した。また、アルカリ電解液には、40重量%の水酸化ナトリウム水溶液を用い、フレーク状の正極合剤を粉砕して粉末状にしてふるいによって分級し、10〜100メッシュのものを中空円筒形に圧縮成形してペレット状の正極材2を得た。この正極材2を電池ケース1内に2個挿入した。   The positive electrode material 2 was prepared by mixing a mixture of manganese dioxide and graphite in a weight ratio of 90:10 and an alkaline electrolyte in a weight ratio of 100: 3, sufficiently stirring, and then compression-molding into a flake shape. . In addition, 40% by weight sodium hydroxide aqueous solution is used as the alkaline electrolyte, and the flaky positive electrode mixture is pulverized and powdered and classified by sieving. The pelletized positive electrode material 2 was obtained by molding. Two of the positive electrode materials 2 were inserted into the battery case 1.

次に筒状セパレータ3の直径より大きい幅をもつ帯状のセパレータを幅の寸法と同じ長さの寸法に切断し、即ち正方形に成形した底部セパレータ5を電池ケース1の中心と底部セパレータ5の中心が同一になる位置に配置する。ここで正方形に切断された底部セパレータ5の角部5aは切断時に位置決めされて、その位置決めされた状態を保持しながら電池ケース1の上に配置する。なお、底部セパレータ5はイオンのみを透過する微孔性フィルムとして再生セルロースを用い、その両面に化学繊維からなる不織布をラミネートしており、厚みは0.02mmから0.3mmが好ましい。   Next, a strip-shaped separator having a width larger than the diameter of the cylindrical separator 3 is cut into a length having the same length as the width, that is, the bottom separator 5 formed into a square is formed at the center of the battery case 1 and the center of the bottom separator 5. Placed at the same position. Here, the corner 5a of the bottom separator 5 cut into a square is positioned at the time of cutting, and is placed on the battery case 1 while maintaining the positioned state. The bottom separator 5 uses regenerated cellulose as a microporous film that allows only ions to pass through, and laminates a nonwoven fabric made of chemical fibers on both sides, and the thickness is preferably 0.02 mm to 0.3 mm.

また、筒状セパレータ3の高さ方向の寸法と同じ寸法の幅を持つ帯状のセパレータを所定の長さに切断し、巻芯を用いて円筒状に巻回して筒状セパレータ3を作製する。ここで、筒状セパレータ3の巻回する回数はアルカリマンガン乾電池の品種により決定され、本発明の一実施の形態においては3巻きの巻回回数を有した筒状セパレータ3とした。   In addition, a strip-shaped separator having a width that is the same as the dimension in the height direction of the cylindrical separator 3 is cut into a predetermined length, and is wound into a cylindrical shape using a winding core to produce the cylindrical separator 3. Here, the number of windings of the cylindrical separator 3 is determined by the type of alkaline manganese dry battery, and in the embodiment of the present invention, the cylindrical separator 3 having three windings is used.

さらに切断する長さは3巻きすることで巻始めと巻終わりが同一位置になる長さで切断した。なお、必要回数巻いた後に切断しても構わない。また、この筒状セパレータ3も底部セパレータ5と同様にイオンのみを透過する微孔性フィルムとして再生セルロースを用い、その両面に化学繊維からなる不織布をラミネートしている。   Furthermore, the length to cut | disconnect was cut | disconnected by the length which the winding start and winding end become the same position by winding 3 times. In addition, you may cut | disconnect after winding required number of times. In addition, similar to the bottom separator 5, the tubular separator 3 uses regenerated cellulose as a microporous film that transmits only ions, and a nonwoven fabric made of chemical fibers is laminated on both sides thereof.

次に筒状セパレータ3の中心と電池ケース1および底部セパレータ5の中心が同一になる位置に配置する。ここで、筒状セパレータ3の中心と底部セパレータ5の中心を合致させ、筒状セパレータ3の巻始めと巻終わりの重なり部を底部セパレータ5の角部5aと重ならない位置に底部セパレータ5の上に配置する。   Next, it arrange | positions in the position where the center of the cylindrical separator 3 and the center of the battery case 1 and the bottom part separator 5 become the same. Here, the center of the cylindrical separator 3 and the center of the bottom separator 5 are made to coincide with each other, and the overlapping portion of the cylindrical separator 3 at the beginning and end of the winding is positioned so as not to overlap the corner 5a of the bottom separator 5. To place.

さらに、筒状セパレータ3を巻いた巻芯を電池ケース1の開口部の方向に挿入することで、図3に示すように筒状セパレータ3の下部を底部セパレータ5の周縁を折り曲げた立上り部5dで包み込んだ状態となり、電池ケース1に収納した円筒状の正極材2の内径に沿わせて装着することができる。底部セパレータ5の角部5aを寄せて折り曲げた重なり部5bが筒状セパレータ3の重なり部3aと重ならない状態で装着していることで、従来技術で課題となっていた筒状セパレータ3の重なり部3aと底部セパレータ5の重なり部
5bとが重なって負極材4の容量の減少する現象を抑制することができ、両セパレータを介しての正極材2と負極材4との極間距離が近くなり電池の内部抵抗のバラツキを抑えられる。
Further, by inserting the core around which the cylindrical separator 3 is wound in the direction of the opening of the battery case 1, as shown in FIG. 3, the rising portion 5d is formed by bending the lower portion of the cylindrical separator 3 at the periphery of the bottom separator 5. It can be mounted along the inner diameter of the cylindrical positive electrode material 2 housed in the battery case 1. The overlapping portion 5b of the bottom separator 5 that has been bent by approaching the corner portion 5a is mounted so that it does not overlap with the overlapping portion 3a of the tubular separator 3, thereby overlapping the tubular separator 3 that has been a problem in the prior art. It is possible to suppress the phenomenon in which the capacity of the negative electrode material 4 decreases due to the overlap of the portion 3a and the overlapping portion 5b of the bottom separator 5, and the distance between the positive electrode material 2 and the negative electrode material 4 through both separators is close. The variation in the internal resistance of the battery can be suppressed.

また、底部セパレータ5と筒状セパレータ3の中心のズレがなく挿入し装着しているため、底部セパレータ5は中心を対称にして絞られ、電池ケース1の底部を底部セパレータ5で覆う形となり、後の工程においてゲル状の負極材4を充填した時の正極材2との短絡を防ぐ。   In addition, since the center of the bottom separator 5 and the cylindrical separator 3 is inserted and attached without being displaced, the bottom separator 5 is squeezed with the center symmetrical, and the bottom of the battery case 1 is covered with the bottom separator 5. A short circuit with the positive electrode material 2 when the gelled negative electrode material 4 is filled in a later step is prevented.

その後、電解液(図示せず)を注液し、ゲル状になった負極材4を挿入した後、周縁に絶縁ガスケット7が装着され負極端子である封口板8の中央部の負極集電棒9を負極材4に挿入しながら、電池ケース1の開口部に装着して、電池ケース1の開口部を内側方向に折り曲げてかしめ封口し密閉したアルカリマンガン乾電池10を作製する。   Thereafter, an electrolyte solution (not shown) is injected, and after the gelled negative electrode material 4 is inserted, an insulating gasket 7 is attached to the periphery, and a negative electrode current collecting rod 9 at the center of a sealing plate 8 serving as a negative electrode terminal. Is inserted into the negative electrode material 4 and attached to the opening of the battery case 1, the opening of the battery case 1 is bent inward, caulked, sealed, and sealed to produce an alkaline manganese dry battery 10.

なお、ゲル状の負極材4はゲル化剤としてポリアクリル酸ナトリウムと、アルカリ電解液として40重量%の水酸化ナトリウム水溶液と、負極活物質として亜鉛粉末とを1:33:66の重量比で混合している。   Note that the gelled negative electrode material 4 comprises sodium polyacrylate as a gelling agent, a 40 wt% aqueous sodium hydroxide solution as an alkaline electrolyte, and zinc powder as a negative electrode active material in a weight ratio of 1:33:66. Mixed.

以下に本発明における円筒形電池の製造装置の模式図を図2に示す。以下に示される構成については、本発明を説明するために掲げた製造装置の一例を示すものであって、本発明は円筒形電池の構造および製造装置を下記のものに特定するものではない。   FIG. 2 shows a schematic diagram of a cylindrical battery manufacturing apparatus according to the present invention. About the structure shown below, an example of the manufacturing apparatus hung up in order to demonstrate this invention is shown, Comprising: This invention does not specify the structure and manufacturing apparatus of a cylindrical battery to the following.

例えば、図2は本発明に係る直径14mm、高さ50mmmの円筒形電池であるアルカリマンガン乾電池LR6の筒状セパレータと底部セパレータを供給挿入する製造装置を示すものである。図2において、本発明に係るアルカリマンガン乾電池の製造装置の底部セパレータ5を供給する工程と筒状セパレータ3を供給し電池ケース1に底部セパレータ5とを同時に挿入する工程に分けて説明する。   For example, FIG. 2 shows a manufacturing apparatus for supplying and inserting a cylindrical separator and a bottom separator of an alkaline manganese dry battery LR6 which is a cylindrical battery having a diameter of 14 mm and a height of 50 mm according to the present invention. In FIG. 2, the process of supplying the bottom separator 5 of the alkaline manganese dry battery manufacturing apparatus according to the present invention and the process of supplying the cylindrical separator 3 and simultaneously inserting the bottom separator 5 into the battery case 1 will be described.

まず、底部セパレータ5を供給する工程では底部セパレータ5の供給部52として、帯状セパレータ18を送り出す送りローラ27と帯状セパレータ18を切断する切断ローラ11と切断した底部セパレータ5を吸着保持する真空吸着ローラ12から構成する。   First, in the step of supplying the bottom separator 5, as the supply unit 52 of the bottom separator 5, a feed roller 27 that feeds the strip separator 18, a cutting roller 11 that cuts the strip separator 18, and a vacuum suction roller that holds the cut bottom separator 5 by suction. It consists of twelve.

切断刃ローラ11は円盤形状で円周面に等間隔に割り付けられた複数の切断刃11aを備え、円盤形状の真空吸着ローラ12の円周面には底部セパレータ5を真空吸着する複数の真空孔が備わる。また、真空吸着ローラ12に接続した真空を発生させる真空部40と切断刃ローラ11と真空吸着ローラ12を同期して回転駆動を与える駆動部41を備え、切断刃ローラ11の切断刃11aに真空吸着ローラ12の円周面が接触した状態で垂直に並列配置した。   The cutting blade roller 11 has a disk shape and includes a plurality of cutting blades 11a allocated at equal intervals on the circumferential surface, and a plurality of vacuum holes for vacuum-sucking the bottom separator 5 on the circumferential surface of the disk-shaped vacuum suction roller 12 Is provided. A vacuum unit 40 that generates a vacuum connected to the vacuum suction roller 12, a cutting blade roller 11, and a drive unit 41 that synchronously drives the vacuum suction roller 12 to rotate are provided, and a vacuum is applied to the cutting blade 11 a of the cutting blade roller 11. The suction roller 12 was arranged vertically in parallel with the circumferential surface of the suction roller 12 in contact.

また、送転盤14に具備した底部セパレータ5を搬送するU字形状の真空吸着レバー13と垂直に配置した真空吸着ローラ12の円周面に底部セパレータ5が入る隙間を空けて、送転盤14を水平に配置し、送転盤14に接続した真空を発生させる真空部42と送転盤14を回転駆動させる駆動部43を設けた。   Further, a clearance for entering the bottom separator 5 is provided on the circumferential surface of the vacuum suction roller 12 arranged perpendicularly to the U-shaped vacuum suction lever 13 for transporting the bottom separator 5 provided in the paper feed plate 14. 14 is disposed horizontally, and a vacuum unit 42 that generates a vacuum connected to the turntable 14 and a drive unit 43 that rotationally drives the turntable 14 are provided.

また、送転盤14に具備した真空吸着レバ13の中心と底部セパレータ保持回転盤28に内蔵した底部セパレータ5の位置決め部17の中心が重なる位置で送転盤14と平行に底部セパレータ保持回転盤28を平行に配置した。さらに、図4に示すように真空吸着レバ13の下面に吸着した底部セパレータ5を後述詳細に述べる巻芯16で位置決め部17に挿入する際に、真空吸着レバ13は巻芯16と同じ方向(図中の矢印方向)にお互いが回動するため干渉しないようにU字形状をしている。また、位置決め部17は後述詳細に
述べるが図6に示すように挿入穴23と保持部22とガイド穴37と突起ガイド21とから構成した。
Further, the bottom separator holding rotary disk is parallel to the rotary disk 14 at a position where the center of the vacuum suction lever 13 provided in the rotary disk 14 and the center of the positioning part 17 of the bottom separator 5 built in the bottom separator holding rotary disk 28 overlap. 28 were arranged in parallel. Furthermore, as shown in FIG. 4, when the bottom separator 5 adsorbed on the lower surface of the vacuum suction lever 13 is inserted into the positioning portion 17 with the core 16 described in detail later, the vacuum suction lever 13 is in the same direction as the core 16 ( Since they rotate in the direction of the arrow in the figure, they are U-shaped so as not to interfere with each other. Further, as will be described later in detail, the positioning portion 17 is composed of an insertion hole 23, a holding portion 22, a guide hole 37, and a projection guide 21, as shown in FIG.

次に、図2に示すように筒状セパレータ3を供給し電池ケース1に底部セパレータ5とを同時に挿入する工程では、筒状セパレータ3を成形する巻芯16や筒状セパレータ3の位置決め部25を複数具備した円盤形状の挿入ヘッド回転盤15を上段に備え、中段には底部セパレータ5の位置を決めて保持する位置決め部17を複数具備した円盤形状の底部セパレータ保持回転盤28と下段に電池ケース1を収納した電池搬送治具24を搬送する送転盤51を同軸上に配置し、同じ回転数で回転駆動を与える駆動部46からなる構成にした。   Next, as shown in FIG. 2, in the step of supplying the cylindrical separator 3 and simultaneously inserting the bottom separator 5 into the battery case 1, the core 16 for forming the cylindrical separator 3 and the positioning portion 25 of the cylindrical separator 3. The disc-shaped insertion head rotating disc 15 having a plurality of discs is provided in the upper stage, and the disc-shaped bottom separator holding rotating disc 28 having a plurality of positioning portions 17 for determining and holding the position of the bottom separator 5 is provided in the middle level and the battery in the lower level. A turntable 51 for transporting the battery transport jig 24 in which the case 1 is housed is arranged on the same axis, and is configured by a drive unit 46 that applies rotational drive at the same rotational speed.

また、挿入ヘッド回転盤15の巻芯16の中心と底部セパレータ保持回転盤28にある底部セパレータ5の位置決め部17の中心と送転盤51の電池搬送治具24に収納した電池ケース1の中心とは合致しており、さらに送転盤14の真空吸着レバ13の中心とも合致している。   Further, the center of the winding core 16 of the insertion head rotating disk 15, the center of the positioning part 17 of the bottom separator 5 in the bottom separator holding rotating disk 28, and the center of the battery case 1 housed in the battery transport jig 24 of the rotating disk 51. And also match the center of the vacuum suction lever 13 of the feeding disk 14.

挿入ヘッド回転盤15の筒状セパレータ3の位置決め部25に筒状セパレータ3を供給する供給部53として、帯状セパレータ36を供給する巻出し部48と帯状セパレータ36を送り出す送りローラ29を備え、帯状セパレータ36を所定の寸法で切断する切断部49を備えた。   As a supply unit 53 that supplies the cylindrical separator 3 to the positioning unit 25 of the cylindrical separator 3 of the insertion head rotating disk 15, a feed unit 29 that supplies the strip separator 36 and a feed roller 29 that feeds the strip separator 36 are provided. A cutting portion 49 for cutting the separator 36 with a predetermined dimension was provided.

また、挿入ヘッド回転盤15に備えた筒状セパレータ3の位置決め部25は、図5に示すように自転する巻芯16と帯状セパレータ36の巻初め位置を決め案内する巻付けガイド19と巻き付けるための巻付けローラ20が2個からなる構成をし、巻芯16は筒状セパレータ3の巻き厚みに相当する大きさだけ大きくした段部26を有する構成になっている。   Further, the positioning portion 25 of the cylindrical separator 3 provided in the insertion head rotating disk 15 is used for winding with the winding guide 19 for determining and guiding the winding start position of the winding core 16 and the strip separator 36 as shown in FIG. The winding roller 20 is composed of two pieces, and the winding core 16 has a step portion 26 that is enlarged by a size corresponding to the winding thickness of the cylindrical separator 3.

また、底部セパレータ保持回転盤28に備えた底部セパレータ5の位置決め部17は、図6に示すように底部セパレータ5の外形より小さい直径の挿入穴23と挿入穴23の下部に底部セパレータ5を位置決めしたまま平面状態で収容する底部セパレータ5の対角線の長さと相等しい直径の真円である保持部22と保持部22に通じるガイド穴37と電池ケース1の位置を決める突起ガイド21によって構成され、先端の突起ガイド21は電池ケース1の開口端に挿入することで電池ケース1の位置を決められる構成になっている。   Further, the positioning part 17 of the bottom separator 5 provided in the bottom separator holding rotary disk 28 positions the bottom separator 5 in the insertion hole 23 having a diameter smaller than the outer shape of the bottom separator 5 and the lower part of the insertion hole 23 as shown in FIG. The bottom part 5 accommodated in a flat state as it is is constituted by a holding part 22 which is a perfect circle having the same diameter as the diagonal line, a guide hole 37 leading to the holding part 22 and a protrusion guide 21 which determines the position of the battery case 1. The protrusion guide 21 at the tip is configured to be able to determine the position of the battery case 1 by being inserted into the opening end of the battery case 1.

さらに、図2に示す底部セパレータ保持回転盤28の下方に電池ケース1を収納した電池搬送治具24を搬送する送転盤51を備え、送転盤51に電池ケース1を収納した電池搬送治具24を搬入する搬入部である搬入コンベア45と送転盤51から電池ケース1を収納した電池搬送治具24を次の工程に搬出する搬出部である搬出コンベア47を接続した。   2 is provided below the bottom separator holding turntable 28 shown in FIG. 2, and includes a turntable 51 for carrying the battery carrying jig 24 containing the battery case 1. The carrying-in conveyor 45 which is a carrying-in part which carries in the battery transport jig | tool 24 which accommodated the battery case 1 which accommodated the battery case 1 in the carrying-in part 45 which carries in the tool 24 from the turntable 51 to the next process was connected.

(実施の形態1)
次に、本発明の実施の形態1に係る製造装置についてさらに詳しく説明する。底部セパレータ5を供給し保持する工程では、まず図2に示す厚みが0.2mm、幅が15mmの不織布を極薄の厚みに加工した帯状セパレータ18を送りローラ27を回転させ、切断刃ローラ11と真空吸着ローラ12との間に搬送した。
(Embodiment 1)
Next, the manufacturing apparatus according to Embodiment 1 of the present invention will be described in more detail. In the step of supplying and holding the bottom separator 5, first, the belt-like separator 18 obtained by processing a non-woven fabric having a thickness of 0.2 mm and a width of 15 mm shown in FIG. And the vacuum suction roller 12.

駆動部41を駆動させて切断ローラ11と真空吸着ローラ12を回転させ、切断刃ローラ11に具備した等間隔に割り付けられた切断刃11aと真空吸着ローラ12との間で挟み込み、幅寸法と同じ15mmの長さで切断し、正方形の底部セパレータ5を形成した。帯状セパレータ18の幅は正方形に形成した底部セパレータ5の幅寸法にし、幅寸法と同
じ長さ寸法に切り出すことにより正方形となり、材料ロスがなく、切り屑が発生しないので屑処理の作業工程も省略することができる。
The drive unit 41 is driven to rotate the cutting roller 11 and the vacuum suction roller 12 so as to be sandwiched between the cutting blades 11a and the vacuum suction roller 12 provided in the cutting blade roller 11 at equal intervals. Cut to a length of 15 mm to form a square bottom separator 5. The width of the strip separator 18 is the same as the width of the bottom separator 5 formed in a square shape, and is cut into the same length as the width dimension so that it becomes a square shape. There is no material loss and no chips are generated. can do.

また、切断刃ローラ11の切断刃11aで切断した底部セパレータ5は、真空部40を作動させ真空吸着ローラ12の表面に真空吸着した。その際、帯状セパレータ18を送り出す送り速度より真空吸着ローラ12の回転速度を早くし、切断した底部セパレータ5が繋がることなく等間隔に間を空けて搬送され、切断した底部セパレータ5を1枚ずつ搬送することができる。   Further, the bottom separator 5 cut by the cutting blade 11 a of the cutting blade roller 11 was vacuum-sucked on the surface of the vacuum suction roller 12 by operating the vacuum unit 40. At that time, the rotational speed of the vacuum suction roller 12 is made faster than the feeding speed for feeding the belt-like separator 18, and the cut bottom separators 5 are transported at equal intervals without being connected. Can be transported.

次に、真空吸着ローラ12で真空吸着した底部セパレータ5は、真空吸着ローラ12により送転盤14の真空吸着レバ13の受け渡し位置まで搬送する。その後、真空部42を作動させて真空吸着レバ13の下面に搬送されてきた状態を保持したまま真空吸着して受け渡した後、送転盤14に接続した駆動部43を作動させて、底部セパレータ保持回転盤28に内蔵された底部セパレータ5の位置決め部17の位置まで底部セパレータ5を搬送した。   Next, the bottom separator 5 vacuum-sucked by the vacuum suction roller 12 is transported by the vacuum suction roller 12 to the delivery position of the vacuum suction lever 13 of the turntable 14. Thereafter, the vacuum unit 42 is operated and vacuum suction is performed while the state conveyed to the lower surface of the vacuum suction lever 13 is held, and then the driving unit 43 connected to the turntable 14 is operated to operate the bottom separator. The bottom separator 5 was conveyed to the position of the positioning portion 17 of the bottom separator 5 incorporated in the holding turntable 28.

また、位置決め部17では図7(a)に示すように真空吸着レバ13の下面に真空吸着している底部セパレータ5に向かって、巻芯16を下降させ底部セパレータ5を位置決め部17の保持部22へ挿入し保持する。その際、筒状セパレータ3を挿入する工程で後述詳細に述べる電池ケース1を収納した電池搬送治具24が底部セパレータ保持回転盤28の下方に待機している。   Further, in the positioning portion 17, as shown in FIG. 7A, the core 16 is lowered toward the bottom separator 5 that is vacuum-sucked on the lower surface of the vacuum suction lever 13, and the bottom separator 5 is held by the holding portion of the positioning portion 17. Insert into 22 and hold. At that time, in the step of inserting the cylindrical separator 3, the battery transport jig 24 that houses the battery case 1, which will be described in detail later, is waiting below the bottom separator holding rotary plate 28.

さらに、図7(b)に示すように底部セパレータ5が巻芯16により押され、底部セパレータ5の角部5aは底部セパレータ5よりも小さい径の挿入穴23の縁にあたり上向きに変形して絞られながら挿入され、底部セパレータ5の対角線の長さと相等しい直径21mmの保持部22内に挿入される。   Further, as shown in FIG. 7B, the bottom separator 5 is pushed by the winding core 16, and the corner 5 a of the bottom separator 5 is deformed upward by hitting the edge of the insertion hole 23 having a diameter smaller than that of the bottom separator 5. And inserted into the holding portion 22 having a diameter of 21 mm which is equal to the diagonal length of the bottom separator 5.

その後、図7(c)に示すように保持部22の収容空間の高さが底部セパレータ5の変形した角部5aを復元できる寸法に構成しているため保持部22の空間内に挿入穴23を塞ぐ元の平らな状態で、底部セパレータ5を保持部22に保持した。また、底部セパレータ保持回転盤28の下方に待機している電池ケース1を収納した電池搬送治具24を上昇させ、突起ガイド21に電池ケース1の開口部を挿入して電池ケース1の位置決めをした後、巻芯16を元の位置に上昇した。   After that, as shown in FIG. 7C, the height of the storage space of the holding portion 22 is configured such that the deformed corner portion 5 a of the bottom separator 5 can be restored, so that the insertion hole 23 is inserted into the space of the holding portion 22. The bottom separator 5 was held by the holding unit 22 in the original flat state. In addition, the battery transport jig 24 storing the battery case 1 waiting under the bottom separator holding rotating disk 28 is raised, and the opening of the battery case 1 is inserted into the protrusion guide 21 to position the battery case 1. After that, the core 16 was raised to the original position.

また、図7(d)に示すように底部セパレータ5の角部5aが保持部22の内壁をガイドとして位置決め部17の中心と底部セパレータ5の中心とが自動的に一致するように保持した。   Further, as shown in FIG. 7D, the corner 5a of the bottom separator 5 is held so that the center of the positioning portion 17 and the center of the bottom separator 5 automatically coincide with each other using the inner wall of the holding portion 22 as a guide.

挿入穴23が保持部22の内径より小さく形成していることにより、小さくて軽い底部セパレータ5が振動や風によって保持部22内から飛び出すことや保持部22の内壁で底部セパレータ5の角部5aをガイドして位置ズレを抑制するため、保持部22に収容した底部セパレータ5が回動移動する状況においても位置決めした状態が保持される。また、底部セパレータ5は水平方向で搬送されたままの状態を保持し、巻芯16で挿入するため底部セパレータ5を位置がズレることなく位置決め部17の保持部22に確実に挿入し保持ができる。   Since the insertion hole 23 is formed to be smaller than the inner diameter of the holding portion 22, the small and light bottom separator 5 jumps out of the holding portion 22 due to vibration or wind, and the corner 5 a of the bottom separator 5 on the inner wall of the holding portion 22. In order to suppress misalignment by guiding the position, the positioned state is maintained even in the situation where the bottom separator 5 accommodated in the holding part 22 is rotated. Further, since the bottom separator 5 is kept conveyed in the horizontal direction and is inserted by the winding core 16, the bottom separator 5 can be reliably inserted and held in the holding portion 22 of the positioning portion 17 without being displaced. .

次に、図2に示す筒状セパレータ3を供給し電池ケース1に底部セパレータ5とを同時に挿入する工程では、別工程(図示せず)で中空円筒形に圧縮成形したペレット状の正極材2を2個挿入した電池ケース1を収納した電池搬送治具24を搬入コンベア45にて回転盤51まで搬送した。   Next, in the step of supplying the cylindrical separator 3 shown in FIG. 2 and simultaneously inserting the bottom separator 5 into the battery case 1, the pellet-shaped positive electrode material 2 compression-molded into a hollow cylindrical shape in a separate step (not shown). The battery carrying jig 24 containing the battery case 1 with two inserted therein was carried to the turntable 51 by the carry-in conveyor 45.

また、筒状セパレータ3の供給部53として、巻出し部48より厚みが0.2mm、幅が44mmの帯状セパレータ36を送りローラ29により送り出し、挿入ヘッド回転盤15の位置決め部25に帯状セパレータ36を挿入して切断部49で85mmの長さに切断し、その帯状セパレータ36の先端を挿入ヘッド回転盤15の位置決め部25に挿入した。   Further, as the supply unit 53 of the cylindrical separator 3, a strip separator 36 having a thickness of 0.2 mm and a width of 44 mm is fed by the feed roller 29 from the unwinding unit 48, and the strip separator 36 is fed to the positioning unit 25 of the insertion head rotating disk 15. Was cut into a length of 85 mm by the cutting part 49, and the tip of the strip separator 36 was inserted into the positioning part 25 of the insertion head rotating disk 15.

次に、図8(a)に示すように位置決め部25にある巻芯16と巻付けガイド19との間に帯状セパレータ36の厚さに相当する間隙を設け、その隙間に帯状セパレータ36の先端を挿入した。その後、底部セパレータ5の角部5aの位置と重ならない位置に設定された巻初め位置に帯状セパレータ36の端面を案内し、自由に自転する巻付けローラ20を巻芯16の方向に接近させ巻初め位置の帯状セパレータ36の端面を巻付けガイド19内にある巻付けローラ20と巻芯16で挟み、巻芯16を3回転自転させて巻芯16の段部26の下方に帯状セパレータ36を巻き付けた後、巻芯16を停止して3巻きからなる筒状セパレータ3を成形した。   Next, as shown in FIG. 8A, a gap corresponding to the thickness of the strip separator 36 is provided between the winding core 16 and the winding guide 19 in the positioning portion 25, and the tip of the strip separator 36 is formed in the gap. Inserted. Thereafter, the end face of the strip separator 36 is guided to the winding start position set at a position not overlapping the corner 5a of the bottom separator 5, and the winding roller 20 that rotates freely approaches the direction of the core 16 and winds. The end face of the strip-shaped separator 36 at the initial position is sandwiched between the winding roller 20 and the core 16 in the winding guide 19, the core 16 is rotated three times, and the strip-shaped separator 36 is placed below the step portion 26 of the core 16. After winding, the core 16 was stopped and the cylindrical separator 3 consisting of 3 rolls was formed.

また、筒状セパレータ3の巻始めと巻終わりからなる重なり部は、巻終わりが巻初めの位置で巻終わる寸法で切断部49にて帯状セパレータ36を切断しており、巻初めの位置が決まることで巻終わる位置もおのずと決定する。なお、必要巻数を巻き終えた後に、センサーで検知して帯状セパレータ36を切断部49で切断し筒状セパレータ3を成形しても構わない。   Further, the overlapping portion formed by the winding start and the winding end of the cylindrical separator 3 cuts the strip separator 36 at the cutting portion 49 so that the winding end is finished at the winding start position, and the winding start position is determined. The position where the winding ends is decided naturally. Note that after the necessary number of windings have been completed, the tubular separator 3 may be formed by detecting with a sensor and cutting the strip separator 36 with the cutting part 49.

筒状セパレータ3を成形した後、巻付けローラ20を離して筒状セパレータ3を巻き付けた巻芯16を下降させ、保持部22に平面状態で保持されている底部セパレータ5を電池ケース1の底面に底部セパレータ5が当接するまで挿入した。   After forming the cylindrical separator 3, the winding roller 20 is released to lower the winding core 16 around which the cylindrical separator 3 is wound, and the bottom separator 5 held in a flat state on the holding portion 22 is used as the bottom surface of the battery case 1. Until the bottom separator 5 comes into contact.

この時、筒状セパレータ3は底部セパレータ5で包んだ状態で電池ケース1内に挿入され、巻芯16の段部26に押されて電池ケース1の底面に底部セパレータ5が当接するまで挿入される。また、巻芯16に巻回された筒状セパレータ3は、巻付けガイド19により巻緩みが生じないように保持され、巻芯16の下降に伴って図6に示した挿入穴23、保持部22、ガイド穴37からなる位置決め部17に進入し、位置決めされた電池ケース1内に挿入されるため巻緩みは生じない。   At this time, the cylindrical separator 3 is inserted into the battery case 1 in a state of being wrapped by the bottom separator 5, and inserted until the bottom separator 5 comes into contact with the bottom surface of the battery case 1 by being pushed by the step portion 26 of the winding core 16. The Further, the cylindrical separator 3 wound around the winding core 16 is held by the winding guide 19 so as not to loosen the winding, and the insertion hole 23 shown in FIG. 22, since it enters the positioning portion 17 including the guide hole 37 and is inserted into the positioned battery case 1, no loosening of the winding occurs.

さらに、底部セパレータ5と巻芯16の中心のズレが生じないことで底部セパレータ5は中心を対称にして絞られ電池ケース1の底部を覆うように装着されことにより、後の工程においてゲル状の負極材4を充填した時に電池ケース1や正極材2と短絡することを高い精度で抑制できる。   Further, since there is no deviation between the center of the bottom separator 5 and the core 16, the bottom separator 5 is squeezed symmetrically about the center and attached so as to cover the bottom of the battery case 1, so that a gel-like shape is formed in a later step. Short circuit with the battery case 1 and the positive electrode material 2 when the negative electrode material 4 is filled can be suppressed with high accuracy.

筒状セパレータ3と底部セパレータ5を同時に挿入後、図8(b)に示すように巻芯16を元の位置に上昇させ、電池ケース1を電池搬送治具24とともに下降し、図2に示す搬出コンベア47で筒状セパレータ3および底部セパレータ5が装着された電池ケース1を収納した電池搬送治具24を次工程に搬送する。   After inserting the cylindrical separator 3 and the bottom separator 5 at the same time, the core 16 is raised to the original position as shown in FIG. 8B, and the battery case 1 is lowered together with the battery transport jig 24, as shown in FIG. The battery transport jig 24 storing the battery case 1 with the cylindrical separator 3 and the bottom separator 5 mounted thereon is transported to the next process by the carry-out conveyor 47.

次工程で、図1で示したように電池ケース1内に電解液を注液しゲル状の負極材4を挿入して、電池ケース1の開口部に封口板8を装着後、電池ケース1の開口部を内側方向に折り曲げてかしめ封口し密閉したLR6のアルカリマンガン乾電池10を作製した。   In the next step, as shown in FIG. 1, the electrolytic solution is injected into the battery case 1, the gel-like negative electrode material 4 is inserted, and the sealing plate 8 is attached to the opening of the battery case 1. The LR6 alkaline manganese dry battery 10 was produced by bending the opening of the inner side of the battery inward and crimping and sealing.

この際の筒状セパレータ3と底部セパレータ5は、図3に示すように筒状セパレータ3の下部を底部セパレータ5の周縁を折り曲げた立上り部5dで包み込み、図1に示す電池ケース1内でゲル状の負極材4と電池ケース1の底面とを内部短絡しないように隔離絶縁
している。
As shown in FIG. 3, the cylindrical separator 3 and the bottom separator 5 at this time wrap the lower part of the cylindrical separator 3 with a rising portion 5d obtained by bending the periphery of the bottom separator 5, and the gel is contained in the battery case 1 shown in FIG. The negative electrode material 4 and the bottom surface of the battery case 1 are isolated and insulated so as not to be internally short-circuited.

さらに図3に示すように、底部セパレータ5の角部5aを寄せて折り曲げた重なり部5bが筒状セパレータ3の重なり部3aと重ならない状態で装着していることで、筒状セパレータ3の重なり部3aと底部セパレータ5の重なり部5bとが重ならず、負極材4の容量が減少する課題を抑制することができ、両セパレータを介しての正極材2と負極材4との極間距離が近くなり電池の内部抵抗のバラツキを抑えられる。   Further, as shown in FIG. 3, the overlapping portion 5 b that is bent with the corner portion 5 a of the bottom separator 5 being bent is attached so as not to overlap the overlapping portion 3 a of the cylindrical separator 3. The overlapping part 5b of the part 3a and the bottom separator 5 does not overlap, and the problem that the capacity of the negative electrode material 4 is reduced can be suppressed, and the distance between the positive electrode material 2 and the negative electrode material 4 through both separators This reduces the variation in the internal resistance of the battery.

以上のように本発明は、筒状セパレータの巻始めと巻終わりからなる重なり部と正方形の底部セパレータの角部とが重ならない位置に位置決めして、底部セパレータで筒状セパレータを包み込む構成にすることで、底部セパレータの角部からなる折れ曲がった折り重なり部が筒状セパレータの巻始めと巻終わりからなる重なり部と重ならないと共に高い精度で底部セパレータの挿入を実現ができ、漏液や内部短絡を発生させずに大容量で信頼性の高い円筒形電池の供給安定化、安全性の安定化を実現する。   As described above, the present invention is configured such that the overlapping portion formed by the beginning and end of winding of the cylindrical separator and the corner portion of the square bottom separator are positioned so as not to overlap, and the cylindrical separator is wrapped with the bottom separator. As a result, the folded overlap part consisting of the corners of the bottom separator does not overlap with the overlap part consisting of the start and end of winding of the cylindrical separator, and the bottom separator can be inserted with high accuracy, resulting in liquid leakage and internal short circuit. The stable supply of high-capacity and highly reliable cylindrical batteries and the stability of safety can be achieved without generating any problems.

本発明によれば、円筒状に巻回してなる筒状セパレータの重なり部と方形の底部セパレータの角部とを重ならないように構成することにより、筒状セパレータの重なり部と底部セパレータの角部が折れ曲がった折り重なり部とが重ならず、負極材の容量の減少を抑制でき、かつ正極材と負極材との極間距離が近くなり、内部抵抗のバラツキおよび放電特性が向上され、大容量で高品質な信頼性の高い円筒形電池を得ることが可能となり、強負荷放電性能を必要とされる携帯型情報機器やデジタルカメラなどの大電流放電機器の電源として有用である。   According to the present invention, the overlapping portion of the cylindrical separator and the corner portion of the bottom separator are configured so as not to overlap the overlapping portion of the cylindrical separator and the corner portion of the rectangular bottom separator. Can be prevented from decreasing the capacity of the negative electrode material, the distance between the positive electrode material and the negative electrode material is close, variation in internal resistance and discharge characteristics are improved, large capacity Thus, it is possible to obtain a high-quality and reliable cylindrical battery, which is useful as a power source for a large-current discharge device such as a portable information device or a digital camera that requires a high load discharge performance.

本発明の一実施の形態における円筒形電池の半部分切欠断面図Half-cutaway sectional view of a cylindrical battery in an embodiment of the present invention 本発明の一実施の形態における製造装置の模式図The schematic diagram of the manufacturing apparatus in one embodiment of this invention 本発明の実施の形態における底部セパレータで筒状セパレータを包み込んだ状態を示す模式図The schematic diagram which shows the state which wrapped the cylindrical separator with the bottom part separator in embodiment of this invention. 本発明の一実施の形態における底部セパレータを位置決め部に挿入する状態を示す斜視図The perspective view which shows the state which inserts the bottom part separator in one embodiment of this invention in a positioning part. 本発明の一実施の形態における筒状セパレータの位置決め部の模式図The schematic diagram of the positioning part of the cylindrical separator in one embodiment of this invention 本発明の一実施の形態における底部セパレータの位置決め部の模式図The schematic diagram of the positioning part of the bottom part separator in one embodiment of this invention (a)本発明の一実施の形態における底部セパレータの挿入状態を示す模式図、(b)同位置決め部における底部セパレータ挿入時の状態を示す模式図、(c)同位置決め部における底部セパレータ保持の状態を示す模式図、(d)同位置決め部の平面図(A) Schematic diagram showing the insertion state of the bottom separator in one embodiment of the present invention, (b) Schematic diagram showing the state when the bottom separator is inserted in the positioning part, (c) Holding the bottom separator in the positioning part Schematic diagram showing the state, (d) Plan view of the positioning part (a)本発明の一実施の形態における筒状セパレータ巻回時の状態を示す模式図、(b)同底部セパレータと筒状セパレータの挿入後の状態を示す模式図(A) The schematic diagram which shows the state at the time of cylindrical separator winding in one embodiment of this invention, (b) The schematic diagram which shows the state after insertion of the bottom part separator and a cylindrical separator 従来例における円筒形電池の半部分切欠断面図Half cutaway cross-sectional view of a cylindrical battery in a conventional example (a)従来例における筒状セパレータの巻付け状態を示す模式図、(b)同底部セパレータと筒状セパレータの挿入時の状態を示す模式図、(c)同底部セパレータと筒状セパレータの装着時の模式図(A) Schematic diagram showing the winding state of the cylindrical separator in the conventional example, (b) Schematic diagram showing the state when the bottom separator and the cylindrical separator are inserted, (c) Mounting of the bottom separator and the cylindrical separator Schematic diagram of time 従来例における底部セパレータで筒状セパレータを包み込んだ状態を示す模式図The schematic diagram which shows the state which wrapped the cylindrical separator with the bottom part separator in a prior art example

符号の説明Explanation of symbols

1 電池ケース
2 正極材
3 筒状セパレータ
3a 重なり部
4 負極材
5 底部セパレータ
5a 角部
5b 重なり部
5d 立上り部
6 正極凸部
7 絶縁ガスケット
8 封口板
9 負極集電棒
10 アルカリマンガン乾電池
11 切断刃ローラ
11a 切断刃
12 真空吸着ローラ
13 真空吸着レバ
14 送転盤
15 挿入ヘッド回転盤
16 巻芯
17 位置決め部
18 帯状セパレータ
19 巻付けガイド
20 巻付けローラ
21 突起ガイド
22 保持部
23 挿入穴
24 電池搬送治具
25 位置決め部
26 段部
27 送りローラ
28 底部セパレータ保持回転盤
29 送りローラ
36 帯状セパレータ
40 真空部
41 駆動部
42 真空部
43 駆動部
45 搬入コンベア
46 駆動部
47 搬出コンベア
48 巻出し部
49 切断部
51 送転盤
52 供給部
53 供給部
DESCRIPTION OF SYMBOLS 1 Battery case 2 Positive electrode material 3 Cylindrical separator 3a Overlapping part 4 Negative electrode material 5 Bottom part separator 5a Corner | angular part 5b Overlapping part 5d Rising part 6 Positive electrode convex part 7 Insulation gasket 8 Sealing plate 9 Negative electrode current collector 10 Alkaline manganese dry cell 11 Cutting blade roller DESCRIPTION OF SYMBOLS 11a Cutting blade 12 Vacuum suction roller 13 Vacuum suction lever 14 Feeding board 15 Insertion head rotary board 16 Core 17 Positioning part 18 Strip separator 19 Winding guide 20 Winding roller 21 Projection guide 22 Holding part 23 Insertion hole 24 Battery conveyance control Tool 25 Positioning part 26 Step part 27 Feeding roller 28 Bottom separator holding rotating disk 29 Feeding roller 36 Strip separator 40 Vacuum part 41 Driving part 42 Vacuum part 43 Driving part 45 Loading conveyor 46 Driving part 47 Unloading conveyor 48 Unwinding part 49 Cutting part 51 Turning machine 52 Supply unit 53 Supply unit

Claims (8)

有底円筒状の電池ケース内に円筒状に成形した正極材を収納し、方形状の底部セパレータと円筒状の筒状セパレータを挿入後に電解液とゲル状の負極材を挿入したのち、前記電池ケースの開口部を負極集電棒を具備した封口板で封口する円筒形電池の製造方法において、前記底部セパレータと筒状セパレータを同時に挿入する際に、前記底部セパレータの角部を位置決めし円筒状に成形した筒状セパレータの巻始めと巻終わりからなる重なり部が前記底部セパレータの角部と重ならない位置となるように位置決めた後に挿入することを特徴とする円筒形電池の製造方法。   The positive electrode material formed into a cylindrical shape is housed in a bottomed cylindrical battery case, and after inserting the square bottom separator and the cylindrical tubular separator, the electrolyte and the gel negative electrode material are inserted, and then the battery In the method of manufacturing a cylindrical battery in which the opening of the case is sealed with a sealing plate having a negative electrode current collector rod, when the bottom separator and the cylindrical separator are inserted simultaneously, the corners of the bottom separator are positioned and cylindrical. A cylindrical battery manufacturing method, wherein the cylindrical battery is inserted after being positioned so that an overlapping portion formed of a winding start and a winding end of the formed cylindrical separator does not overlap with a corner portion of the bottom separator. 底部セパレータの周縁の立上り部が円筒状に成形した正極材の内周面に接するように挿入すると同時に筒状セパレータの先端部を前記底部セパレータの周縁の立上り部で外側より包むように装着することを特徴とする請求項1に記載の円筒形電池の製造方法。   Inserting so that the rising edge of the peripheral edge of the bottom separator is in contact with the inner peripheral surface of the positive electrode material formed into a cylindrical shape, and simultaneously mounting the tip of the cylindrical separator so as to be wrapped from the outside by the rising edge of the peripheral edge of the bottom separator The method for manufacturing a cylindrical battery according to claim 1, wherein: 底部セパレータとして、帯状のセパレータを4辺の長さが同一寸法になるように切断して成形することを特徴とする請求項1に記載の円筒形電池の製造方法。   2. The method for manufacturing a cylindrical battery according to claim 1, wherein the bottom separator is formed by cutting a strip-shaped separator so that the lengths of the four sides have the same dimension. 有底円筒状の電池ケース内に円筒状に成形した正極材を収納し、方形状の底部セパレータと円筒状の筒状セパレータを挿入後に電解液とゲル状の負極材を挿入し、前記電池ケースの開口部を負極集電棒が具備された封口板で封口する円筒形電池の製造装置において、前記底部セパレータの供給部と、前記底部セパレータの角部を位置決めする位置決め部を有し、前記筒状セパレータの供給部と、前記筒状セパレータの巻始めと巻終わりからなる重なり部を底部セパレータの角部と重ならないように位置決めする位置決め部と、位置決めされた前記筒状セパレータと底部セパレータとを正極材を収納した電池ケース内に同時に挿入する挿入部と、前記正極材を収納した電池ケースを搬入する搬送部と搬出する搬出部から構成したことを特徴とする円筒形電池の製造装置。   A positive electrode material formed into a cylindrical shape is stored in a bottomed cylindrical battery case, and after inserting a square bottom separator and a cylindrical tubular separator, an electrolyte and a gel negative electrode material are inserted, and the battery case In the cylindrical battery manufacturing apparatus that seals the opening of the bottom separator with a sealing plate provided with a negative electrode current collector rod, the cylindrical separator has a supply part for positioning the bottom separator and a positioning part for positioning a corner of the bottom separator, A separator supply unit, a positioning unit that positions an overlapping portion formed by starting and ending winding of the cylindrical separator so as not to overlap a corner of the bottom separator, and the positioned cylindrical separator and the bottom separator are positive electrodes. It is characterized by comprising an insertion part for simultaneously inserting into a battery case containing a material, a transport part for carrying in the battery case containing the positive electrode material, and a carry-out part for carrying it out. A cylindrical battery manufacturing apparatus. 底部セパレータの供給部として、帯状セパレータを送り出す送りローラと帯状セパレータを正方形に切断する切断刃ローラと、切断した前記底部セパレータを真空吸着して搬送する真空吸着ローラと真空吸着レバーを有する送転盤と、真空を発生する真空部と駆動源である駆動部から構成したことを特徴とする請求項4に記載の円筒形電池の製造装置。   A feed roller having a feed roller for feeding the strip separator, a cutting blade roller for cutting the strip separator into a square, a vacuum suction roller for vacuum-sucking and transporting the cut bottom separator, and a vacuum suction lever as a supply unit for the bottom separator The apparatus for manufacturing a cylindrical battery according to claim 4, comprising: a vacuum unit that generates a vacuum; and a drive unit that is a drive source. 底部セパレータの位置決め部として、底部セパレータ保持回転盤内に設けられた前記底部セパレータの保持部と電池ケースを位置決めするガイドから構成にしたことを特徴とする請求項4に記載の円筒形電池の製造装置。   5. The cylindrical battery manufacturing method according to claim 4, wherein the bottom separator positioning portion includes a bottom separator holding portion provided in a bottom separator holding turntable and a guide for positioning the battery case. apparatus. 筒状セパレータの供給部として、帯状セパレータを供給する巻出し部と帯状セパレータを所定の寸法に切断する切断部からなる構成にしたことを特徴とする請求項4に記載の円筒形電池の製造装置。   5. The cylindrical battery manufacturing apparatus according to claim 4, wherein the cylindrical separator supply unit includes an unwinding unit that supplies the strip separator and a cutting unit that cuts the strip separator into a predetermined size. . 筒状セパレータの位置決め部として、切断した帯状セパレータを巻初め位置に導く巻付けガイドと巻芯と巻芯に巻き付ける巻付けローラと挿入ヘッド回転盤と駆動部からなる構成にしたことを特徴とする請求項4に記載の円筒形電池の製造装置。   The cylindrical separator positioning portion is composed of a winding guide for guiding the cut strip separator to a winding start position, a winding core, a winding roller for winding the winding core, an insertion head rotating disk, and a driving portion. The manufacturing apparatus of the cylindrical battery of Claim 4.
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JP2008251196A (en) * 2007-03-29 2008-10-16 Matsushita Electric Ind Co Ltd Cylindrical battery
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