JP2008081843A - High-strength flame-resistant magnesium alloy - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a high-strength flame-resistant magnesium alloy having high tensile strength and high strength and producible at a low cost without using elements such as rare earths. <P>SOLUTION: A high-strength flame-resistant magnesium alloy is produced, as an additive(s), by adding at least one or more selected from molybdenum (Mo), niobium (Nb), tungsten (W), alumina (Al<SB>2</SB>O<SB>3</SB>), magnesium silicate (Mg<SB>2</SB>Si) and silicon carbide (SiC) to a small piece block of a flame-resistant magnesium alloy resulting from addition of 0.5 to 5.0 wt.% calcium to a magnesium alloy, and subjecting the resultant matter to crushing, molding, sintering and plastic working. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

  The present invention relates to a high-strength flame-retardant magnesium alloy in which the mechanical strength of the flame-retardant magnesium alloy is increased.

  Magnesium alloys are attracting attention as substitutes for aluminum and its alloys because they are extremely lightweight. Magnesium alloys belong to the lightest of all practical metals, and have a relatively high specific strength, specific elastic modulus, etc. obtained by dividing strength and elastic modulus by density. For this reason, the demand is expected to increase in the future in the industrial field where weight reduction is required. Although titanium and aluminum alloys have sufficient strength, they have the disadvantage that properties such as lightness and buffering properties are low as compared with magnesium alloys.

  Conventional magnesium alloys have been known to have the disadvantages of being easy to ignite because they have a relatively high specific strength, but have a lower absolute strength than titanium and aluminum alloys and a low ignition point. For this reason, in order to make it flame-retardant, a flame-retardant magnesium alloy has been developed in which calcium is added to the magnesium alloy to increase its ignition point, and it is made difficult to ignite by plastic working such as extrusion and rolling (patent) Reference 1).

  Various magnesium alloys that have been improved to obtain strength corresponding to titanium and aluminum alloys have also been proposed. For example, the strength and specific strength are high and the crystal grain size after plastic deformation is small. Mg, Ca, Zn, and X (where X is a rare earth element, Y, Ce, La, Nd, Pr, A magnesium alloy having a structure in which a predetermined amount of one or more elements selected from the group consisting of Sm and Mm) is added and these compounds are finely dispersed and a manufacturing technique thereof are disclosed (for example, see Patent Document 2). ). That is, a predetermined amount of rare earth element is added, and the structure is refined by a rapid solidification atomization method.

  In addition, as one that realizes high strength and high ductility at the same time, it is contained in the periodic table group 2, group 3, or lanthanoid system, and is one kind of solute atoms 0.03-0.54 atoms having a larger atomic radius than magnesium % And a magnesium alloy composed of the balance of magnesium is disclosed (for example, see Patent Document 3). This magnesium alloy has an average grain size of 1.5 μm or less, and solute atoms in the vicinity of grain boundaries are unevenly distributed at a concentration of 1.5 to 10.0 times the concentration of solute atoms in the grains. It has a grain structure.

Furthermore, as a magnesium alloy having high strength and high ductility, 1.0 to 4.0 atomic% Zn and 1.0 to 4.5 atomic% Y are contained in magnesium at a predetermined composition ratio, A structure in which an intermetallic compound Mg ₃ Y ₂ Zn and a long-period structure Mg ₁₂ YZn are simultaneously contained is disclosed (for example, see Patent Document 4). This is because the intermetallic compound Mg ₃ Y ₂ Zn and the long-period phase Mg ₁₂ YZn are present at the same time, thereby improving the yield strength, tensile strength, and elongation.

  Further, as described above, a flame retardant magnesium alloy in which calcium is contained in a magnesium alloy has a high ignition point, high mechanical strength, and easy handling characteristics. For this reason, a technique that uses this advantage to apply this magnesium alloy to a helmet as a product (for example, see Patent Document 5) and a technique that applies to a frame of glasses (for example, see Patent Document 6) have been proposed.

Japanese Unexamined Patent Publication No. 2000-109963 Japanese Patent Laid-Open No. 9-41065 JP 2006-16658 A JP 2006-97037 A JP 2005-350808 A Japanese Patent Laid-Open No. 2005-196094

  As described above, various improved techniques for improving the mechanical properties of magnesium alloys have been proposed. However, current magnesium alloys still have many problems, are not satisfactory, and are still insufficient for application to actual products. That is, Patent Document 2 requires the addition of an expensive rare earth element, and the resulting alloy is inevitably expensive. Furthermore, special and advanced techniques such as rapid solidification atomization must be used. Although the proof stress of the alloy according to Patent Document 2 is 510 to 635 MPa and high strength is achieved, the elongation at break is as extremely small as 1.0 to 4.0%, which is a very brittle material.

Moreover, although the technique of patent document 3 is illustrated as what improved the yield stress and elongation, since elements other than Ca of the designated solute atom are rare earth elements, cost is the same as that mentioned above. It becomes a high alloy. Furthermore, in the magnesium alloy described in Patent Document 4, only when the intermetallic compound Mg ₃ Y ₂ Zn and the long-period phase Mg ₁₂ YZn exist at the same time, the tensile strength of 390 to 520 MPa and 4.5 to 10. The elongation at break of 3% is obtained, and it has been shown that the presence of either one of the intermetallic compound and the long period phase cannot combine high strength and high ductility. Thus, advanced organization control is essential.

  As described above, the magnesium alloys described in Patent Documents 2, 3 and 4 have advantages, respectively, but are insufficient as properties required for machine materials. As a result, magnesium alloys produced using rare earth elements have a problem that they are expensive.

  The present invention has been made based on such a conventional technical background, and achieves the following object. An object of the present invention is to use a flame-retardant magnesium alloy having high tensile strength and high strength characteristics by adding a general-purpose element or compound without using an alloying element limited to rare earth elements. On offer.

The present invention takes the following means in order to achieve the object.
The high-strength flame-retardant magnesium alloy according to the first aspect of the present invention includes molybdenum (Mo), niobium (Nb), tungsten ( It is obtained by adding at least one additional additive selected from W), alumina (Al ₂ O ₃ ), magnesium silicide (Mg ₂ Si), and silicon carbide (SiC).

The high-strength flame-retardant magnesium alloy of the present invention 2 is characterized in that, in the present invention 1, the amount of molybdenum (Mo) as the additional additive is 1.0 to 12.0% by weight.
The high-strength flame-retardant magnesium alloy of the present invention 3 is characterized in that, in the present invention 1, the amount of niobium (Nb) as the additional additive is 0.5 to 5.0% by weight.

The high-strength flame-retardant magnesium alloy of the present invention 4 is characterized in that, in the present invention 1, the amount of tungsten (W) as the additional additive is 5.0 to 40.0% by weight.
The high-strength flame-retardant magnesium alloy of the present invention 5 is characterized in that, in the present invention 1, the amount of the additive additive alumina (Al ₂ O ₃ ) is 1.0 to 5.0 wt%. .

The high-strength flame-retardant magnesium alloy of the present invention 6 is characterized in that, in the present invention 1, the amount of the additional additive magnesium silicide (Mg ₂ Si) is 2.0 to 6.0% by weight.
The high-strength flame-retardant magnesium alloy of the present invention 7 is characterized in that, in the present invention 1, the amount of the additional additive silicon carbide (SiC) is 0.7 to 20.0% by weight.

The high-strength flame-retardant magnesium alloy of the present invention 8 is the present invention 1, wherein the magnesium alloy comprises 0 to 12.0 wt% aluminum, 0 to 5.0 wt% zinc, and 0.5 wt% or less. It is a magnesium alloy containing manganese.
The high-strength flame retardant magnesium alloy of the present invention 9 is selected from the AZ31 series, AZ61 series, AZ80 series, AZ91 series, AZ92 series, AM50 series, AM60 series, and AM100 series in the present invention 1. It is characterized by being one kind of magnesium alloy.

The high-strength flame-retardant magnesium alloy of the present invention 10 is characterized in that, in the present invention 1, the flame-retardant magnesium alloy comprises a pulverized product obtained from the flame-retardant magnesium alloy material.
The high-strength flame-retardant magnesium alloy of the present invention 11 is manufactured by the plastic processing according to the first aspect of the present invention, wherein the high-strength flame-retardant magnesium alloy is added with the additional additive and then subjected to external force to cause permanent deformation. It is the alloy which was made.

The high-strength flame-retardant magnesium alloy of the present invention 12 is characterized in that, in the present invention 10, the pulverized product is a cutting waste or a powder obtained by cutting.
The high-strength flame-retardant magnesium alloy of the present invention 13 is the present invention 12, wherein the plastic working is one type selected from extrusion processing, drawing processing, rotary forging processing and rolling processing, or a combination of two or more types. It is characterized by that.

  As described above, according to the high-strength flame-retardant magnesium alloy of the present invention, a pulverized product can be obtained without adding alloying elements limited to expensive rare earth elements, and by adding additives for general-purpose elements and compounds. By forming, sintering and plastic working, a low-cost flame-retardant magnesium alloy having high tensile strength and high strength and high strength characteristics was obtained.

[High-strength flame retardant magnesium alloy]
Hereinafter, embodiments of the flame-retardant magnesium alloy of the present invention will be described in detail. First, in order to facilitate understanding of the present invention, a magnesium alloy will be described. Magnesium alloys are standardized by the American Society for Testing Materials (hereinafter referred to as “ASTM”) or Japanese Industrial Standards (hereinafter referred to as “JIS”). Magnesium alloys are broadly classified into magnesium alloys for casting and magnesium alloys for drawing. For each, the range from the minimum value to the maximum value of the mechanical characteristics standardized by ASTM and JIS is as follows. Since the composition of the chemical components of these standardized alloys is standardized and is a known technique, the description thereof is omitted.

  The mechanical properties of the magnesium alloy for casting are as follows. Tensile strength: 140 MPa (AM100A-F material) to 270 MPa (ZK61A-T5, T6 treated material). Yield strength: 70 MPa (AM100A-F material) to 180 MPa (ZK61A-T5, T6 treated material). Elongation: Almost 0% (AM100A-F material) to 10% (AM50A-F material).

  The mechanical properties of the wrought magnesium alloy are as follows. Tensile strength: 190 MPa (AZ31C-O material) to 310 MPa (ZK60A-T5 treated material). Yield strength: 90 MPa (AZ31C-O material) to 230 MPa (ZK60A-T5 treated material). Elongation: 4% (AZ31C-H14 treated material) to 13% (AZ31C-O material).

  In general, in the case of a metal, the mechanical properties such as strength and ductility of the wrought alloy are greatly improved due to the effects of plastic working and thermomechanical processing as compared with the casting alloy. Although the magnesium alloy has also been improved as described above, there is little improvement in strength and ductility at present. For this reason, further technical development has been carried out, and the technology is disclosed as in the case of the aforementioned patented technology. The high-strength flame-retardant magnesium alloy according to the present embodiment is obtained by adding low-priced element and compound additives to a flame-retardant magnesium alloy that has been made flame-retardant by adding Ca. It improves the mechanical strength. This embodiment uses a pulverized product of a flame-retardant magnesium alloy, and is a high-strength flame retardant having mechanical properties of a tensile strength at room temperature of 419 MPa or more and a proof stress of 360 MPa or more by molding, sintering and plastic working. Promising magnesium alloy is proposed.

  Here, the reason why the tensile strength is set to 419 MPa or more and the proof stress is set to 360 MPa or more in the high-strength flame-retardant magnesium alloy of the present embodiment is as follows. Duralumin is known as a typical lightweight and high-strength aluminum alloy. Duralumin is an Al-Cu-Mg-based alloy. For example, the tensile strength of A2024-T3 or T4 heat-treated extruded material (bar diameter 6 mm or less), which is one of the alloys, is specified to be 390 MPa or more and proof stress 295 MPa or more. (JIS H4040-2006). In view of these numerical values, the alloy according to the present invention has a tensile strength of 419 MPa or more and a proof stress of 360 MPa or more. Next, the alloy and its manufacturing technique in the present invention will be described.

The magnesium alloy shown in the present embodiment is a magnesium alloy for casting represented by ASTM AM60B or the like . However, the alloy capable of carrying out the present invention is not necessarily limited to this magnesium alloy for casting [AM60B], and may be other magnesium alloys. 0.5-5.0 wt% Ca is added to this alloy. In this embodiment, 2% by weight of Ca is added.

  AM60B is an alloy for die casting, and is a high-purity magnesium alloy in which the contents of impurities Fe, Ni, and Cu are reduced in order to improve corrosion resistance. Its basic chemical composition consists of Al 5.5 to 6.5% by weight, Mn 0.24 to 0.60% by weight, and the balance magnesium. Calcium is added to this to make a flame retardant magnesium alloy. As described above, the amount of calcium added is preferably 0.5 to 5.0% by weight.

[Method for producing high-strength flame-retardant magnesium alloy]
Next, the manufacturing method of the high intensity | strength flame-retardant magnesium alloy of this invention is demonstrated. As the base magnesium alloy, a flame retardant magnesium alloy “AM60B + 2Ca alloy” to which 2% by weight of Ca was added was used in the present embodiment. AM60B is originally a magnesium alloy for casting (die casting), but it enables plastic working such as extrusion while hot. By adding 2% by weight of Ca to this AM60B, the ignition temperature of this flame retardant magnesium alloy “AM60B + 2Ca alloy” can be increased by 200 to 300 ° C.

  For this reason, the melting | dissolving operation | work in air | atmosphere can also be performed safely. From this flame retardant magnesium alloy “AM60B + 2Ca alloy”, a small block having a form suitable for pulverization in the next step is obtained. In the present embodiment, the cutting waste produced by cutting the flame retardant magnesium alloy “AM60B + 2Ca alloy” is used for convenience. Needless to say, the small blocks are not limited to cutting scraps by cutting, but also cutting scraps and grinding scraps discharged by various machining, press scraps such as cutting and punching, and crushing machines. It may be obtained by pulverizing crushed scraps, small blocks of castings and cast materials, and the like. A pulverized product is obtained from these small blocks, and a ball mill or the like is used for this.

In the case of the flame retardant magnesium alloy in the present embodiment, flame retardancy is achieved by the addition of Ca, so it is safe to leave it in the air at room temperature in the state of a pulverized product. For example, the explosion lower limit concentration value of the pulverized product of the flame-retardant magnesium alloy “AM60B + 2Ca alloy” having an average particle diameter of 146 μm is 100 mg / m ³ , which is larger than the aluminum powder (35 mg / m ³ ), <120 mg / m ³ ), the danger of explosion is greatly reduced, and handling is easy.

Next, when obtaining a pulverized product from the small block, a predetermined element or compound is added as an additional additive, which is a feature of the present embodiment. This additional additive is not limited to rare earth elements, and including its proportion, 0.1 to 0.3 wt% C, 1.0 to 12.0 wt% Mo, 0.5 to 5.0 wt% Nb, 0.5 to 6.0 wt% Si, 5.0 to 40.0 wt% W, 1.0 to 5.0 _wt% Al ₂ O 3, _{2.0~6.0 wt%} Mg 2 Si, which is the element or these predetermined compounds, of 0.7 to 20.0 wt% SiC.

  The types and addition amounts of these elements or compounds are limited because they indicate the range in which the flame-retardant magnesium alloy produced can achieve high strength. This is because it fades. One kind or a plurality of kinds selected from these are additionally added, and the pulverization of the small blocks and the compounding of the elements or compounds are simultaneously performed. That is, in this pulverization step, the flame-retardant magnesium alloy in small blocks is reformed to a fine homogeneous structure by breaking the solidified structure. At the same time, the additive is finely and homogeneously combined with the flame retardant magnesium alloy powder.

[Molding and sintering]
Next, the flame-retardant magnesium alloy of the pulverized product having such a fine and homogeneous structure is formed and sintered. This forming can be either cold forming or hot forming. However, in consideration of shortening of the process, hot forming which can simultaneously perform sintering is preferable. A pulse current sintering method is suitable for hot forming. The pulse electric current sintering method is a known processing method in which a graphite mold is filled with a target sample, and electric current is applied in a pulsed manner while being pressed to perform sintering. In this example, this sample is a pulverized product made of the flame-retardant magnesium alloy described above. This treatment method has an advantage that the pulverized product can be efficiently heated and sintered in a short time.

  Next, plastic forming is performed using the sintered body of the pulverized flame-retardant magnesium alloy formed and sintered as a billet. This plastic working has the effect of giving the sintered body shear deformation to make the crushed material more firmly fixed than the sintered body and also to refine the microstructure of the sintered body. There are various processing methods such as extrusion, rolling, drawing, forging, and rotary forging as means for performing plastic working. In this example, hot extrusion performed at a temperature higher than the recrystallization temperature of the material is used. This is because a large shear deformation can be imparted to the workpiece in the extrusion process. In addition, the extrusion ratio at this time increases the mechanical strength of the material that can be obtained to some extent, but if it is unnecessarily large, the life of the extrusion mold will be shortened or damaged, and the extrusion equipment will be enlarged. The maximum is preferably about 120.

  By this extrusion molding, the pulverized material in the sintered body is subjected to shear deformation and becomes more firmly bonded, and the particles of intermetallic compounds originally contained in the flame retardant magnesium alloy and additional additives are uniformly contained in the magnesium matrix. It becomes a distributed organization form. In addition, recrystallization occurs during hot extrusion, and the magnesium matrix crystal grains are refined. These improve the mechanical characteristics and increase the strength.

  The magnesium alloy to be used is magnesium containing 0 to 12.0% by weight of aluminum, 0 to 5.0% by weight of zinc, and 0.5% by weight or less of manganese other than those disclosed in the above-described embodiment. Effective results are possible with alloys. Further, the magnesium alloy uses any one selected from AZ31 series, AZ61 series, AZ80 series, AZ91 series, AZ92 series, AM50 series, AM60 series and AM100 series of American Standards for Materials Testing (ASTM) standard indication. Even valid results are possible. Although the embodiments have been described above, it is needless to say that the present invention is not limited to the embodiments.

The alloy of Example 1 was based on a flame retardant magnesium alloy “AM60B + 2Ca” to which 2.0 wt% Ca was added in order to impart flame retardancy to the AM60B alloy. As an additional additive, an element or compound of C, Mo, Nb, Si, W, Al ₂ O ₃ , Mg ₂ Si, and SiC was added so as to have a composition shown in Table 1. In Example 1, cutting scraps, which are turning chips, were used as small blocks of the alloy. The cutting waste was pulverized by a ball mill to obtain a pulverized product. At this time, an additional additive was also added at the same time, and the additive was uniformly dispersed and compounded.

  Next, the pulverized product of the flame retardant magnesium alloy prepared by this ball mill was solidified and formed in the atmosphere by a pulse current sintering method at a sintering temperature of 480 ° C. for 20 minutes. Next, hot extrusion was performed at an extrusion ratio of 110 and an extrusion temperature of 480 ° C. using this as a billet. Test pieces were collected in the longitudinal direction of the obtained extruded material and tested for tensile strength, yield strength, and elongation at break at room temperature. The test results are summarized in Table 2. According to this result, in any test piece, the tensile strength was 419 MPa or more and the proof stress was 380 MPa or more, and the effect of the present invention was confirmed.

The data for each element or compound as a result is shown in FIGS. Figure 1 is the case of adding C, if 2 is added with Mo, 3 the case of adding Nb, if 4 is added with Si, the case of FIG. 5 with the addition of W, 6 Al ₂ When O ₃ is added, FIG. 7 shows a case where Mg ₂ Si is added, and FIG. 8 shows a case where SiC is added. Each of the tensile strength, yield strength and elongation at break according to the amount added is a data diagram.
Incidentally, in each figure, the value when the addition amount is 0% indicates the result of Comparative Example 1.

Next, since the comparison corresponding to the present Example 1 was performed, the comparative examples 1-3 are shown. The result of this Example 1 exceeds all of Comparative Examples 1 to 3 shown below.
(Comparative Example 1)
In Comparative Example 1, cutting waste from a cast material of a flame retardant magnesium alloy “AM60B + 2Ca” having the same chemical composition as Example 1 was pulverized by a ball mill, and then under exactly the same conditions as Example 1. Then, this pulverized product was molded and sintered by the pulse current sintering method. This was used as a billet under the same conditions as in Example 1, hot extrusion was performed at an extrusion ratio R = 110 and extrusion temperature T = 480 ° C., and a tensile strength test was performed at room temperature in the longitudinal direction of the obtained extruded material. It was. The result of the tensile strength test is
Tensile strength = 415 MPa, yield strength = 364 MPa, elongation at break = 23%.
These values are shown at the left end where the amount of each additive is 0% in FIGS. 1 to 8 showing the results in Example 1.

(Comparative Example 2)
In Comparative Example 2, a cast material of a flame retardant magnesium alloy “AM60B + 2Ca” having exactly the same chemical composition as in Example 1 was extruded under the same conditions as in Example 1, with an extrusion ratio R = 110 and an extrusion temperature T = 480 ° C. The tensile strength test was performed at room temperature in the longitudinal direction of the extruded material. The result of the tensile strength test is
Tensile strength = 305 MPa, yield strength = 242 MPa, elongation at break = 18%.

(Comparative Example 3)
This comparative example 3 is a drawn material prepared by extruding a cast material of a flame retardant magnesium alloy “AM60B + 2Ca” having exactly the same chemical composition as in Example 1 and then subjecting it to hot drawing. The tensile strength test was conducted at room temperature in the longitudinal direction. The result of the tensile strength test is
Tensile strength = 286 MPa, yield strength = 198 MPa, elongation at break = 16%.

The alloy of Example 2 was based on a flame retardant magnesium alloy “AZ91D + 2Ca” to which 2.0 wt% Ca was added in order to impart flame retardancy to the AZ91D alloy. As an additional additive, elements such as Mo, Nb, W, Al ₂ O ₃ , Mg ₂ Si, SiC, or a compound were added so as to have the composition shown in Table 3. In Example 2, cutting scraps that are turning chips were used as small blocks of the alloy. The cutting waste was pulverized by a ball mill to obtain a pulverized product. At this time, an additional additive was also added at the same time, and the additive was uniformly dispersed and compounded.

  Next, the pulverized product of the flame retardant magnesium alloy prepared by this ball mill was solidified and formed in the atmosphere by a pulse current sintering method at a sintering temperature of 450 ° C. for a time of 20 minutes. Next, hot extrusion was performed at an extrusion ratio of 110 and an extrusion temperature of 400 ° C. using this as a billet. Test pieces were collected in the longitudinal direction of the obtained extruded material and tested for tensile strength, yield strength, and elongation at break at room temperature. The test results are summarized in Table 4. According to this result, in any test piece, the tensile strength was 419 MPa or more and the yield strength was 360 MPa or more, and the effect of the present invention was confirmed.

The data for each element or compound as a result is shown in FIG. 9 to FIG. 9 shows a case where Mo is added, FIG. 10 shows a case where Nb is added, FIG. 11 shows a case where W is added, FIG. 12 shows a case where Al ₂ O ₃ is added, FIG. 13 shows a case where Mg ₂ Si is added, FIG. 14 is a data diagram showing each tensile strength, yield strength, and elongation at break according to the addition amount when SiC is added. Incidentally, in each figure, the value when the addition amount is 0% indicates the result of Comparative Example 4. Next, since the comparison corresponding to the present Example 2 was performed, the comparative example is shown.

(Comparative Example 4)
In Comparative Example 4, the cutting waste from the cast material of the flame retardant magnesium alloy “AZ91D + 2Ca” having the same chemical composition as in Example 2 was pulverized by a ball mill, and then under exactly the same conditions as in Example 2. Then, this pulverized product was molded and sintered by the pulse current sintering method. This was used as a billet under the same conditions as in Example 2, hot extrusion was performed at an extrusion ratio R = 110 and extrusion temperature T = 400 ° C., and a tensile strength test was performed at room temperature in the longitudinal direction of the obtained extruded material. It was. The results of the tensile strength test were tensile strength = 461 MPa, proof stress = 451 MPa, and elongation at break = 8%. These values are shown at the left end where the amount of each additive is 0% in FIGS. 9 to 14 showing the results in Example 2.

(Comparative Example 5)
In Comparative Example 5, a cast material of a flame retardant magnesium alloy “AZ91D + 2Ca” having the same chemical composition as in Example 2 was extruded under the same conditions as in Example 2, with an extrusion ratio R = 110 and an extrusion temperature T = 400 ° C. The tensile strength test was performed at room temperature in the longitudinal direction of the extruded material. The results of the tensile strength test were tensile strength = 360 MPa, yield strength = 260 MPa, and elongation at break = 10%.

FIG. 1 is a data diagram of a tensile strength test result of a high-strength flame-retardant magnesium alloy when C is added to a pulverized product of the flame-retardant magnesium alloy “AM60B + 2Ca”. FIG. 2 is a data diagram of a tensile strength test result of a high-strength flame-retardant magnesium alloy when Mo is added to a pulverized product of the flame-retardant magnesium alloy “AM60B + 2Ca”. FIG. 3 is a data diagram of a tensile strength test result of a high-strength flame-retardant magnesium alloy when Nb is added to a pulverized product of the flame-retardant magnesium alloy “AM60B + 2Ca”. FIG. 4 is a data diagram of a tensile strength test result of a high-strength flame-retardant magnesium alloy when Si is added to a pulverized product of the flame-retardant magnesium alloy “AM60B + 2Ca”. FIG. 5 is a data diagram of a tensile strength test result of a high-strength flame-retardant magnesium alloy when W is added to a pulverized product of the flame-retardant magnesium alloy “AM60B + 2Ca”. FIG. 6 is a data diagram of a tensile strength test result of a high-strength flame-retardant magnesium alloy when Al ₂ O ₃ is added to a pulverized product of the flame-retardant magnesium alloy “AM60B + 2Ca”. FIG. 7 is a data diagram of a tensile strength test result of a high-strength flame-retardant magnesium alloy when Mg ₂ Si is added to a pulverized product of the flame-retardant magnesium alloy “AM60B + 2Ca”. FIG. 8 is a data diagram of a tensile strength test result of a high-strength flame-retardant magnesium alloy when SiC is added to a pulverized product of the flame-retardant magnesium alloy “AM60B + 2Ca”. FIG. 9 is a data diagram of a tensile strength test result of a high-strength flame-retardant magnesium alloy when Mo is added to a pulverized product of the flame-retardant magnesium alloy “AZ91D + 2Ca”. FIG. 10 is a data diagram of a tensile strength test result of a high-strength flame-retardant magnesium alloy when Nb is added to a pulverized product of the flame-retardant magnesium alloy “AZ91D + 2Ca”. FIG. 11 is a data diagram of a tensile strength test result of a high-strength flame-retardant magnesium alloy when W is added to a pulverized product of the flame-retardant magnesium alloy “AZ91D + 2Ca”. FIG. 12 is a data diagram of a tensile strength test result of a high-strength flame-retardant magnesium alloy when Al ₂ O ₃ is added to a pulverized product of the flame-retardant magnesium alloy “AZ91D + 2CaM60B + 2Ca”. FIG. 13 is a data diagram of a tensile strength test result of a high-strength flame-retardant magnesium alloy when Mg ₂ Si is added to a pulverized product of the flame-retardant magnesium alloy “AZ91D + 2Ca”. FIG. 14 is a data diagram of a tensile strength test result of a high-strength flame-retardant magnesium alloy when SiC is added to a pulverized product of the flame-retardant magnesium alloy “AZ91D + 2Ca”.

Claims (13)

A flame retardant magnesium alloy obtained by adding 0.5 to 5.0% by weight of calcium to a magnesium alloy, molybdenum (Mo), niobium (Nb), tungsten (W), alumina (Al ₂ O ₃ ), magnesium silicide A high-strength flame-retardant magnesium alloy obtained by adding at least one additional additive selected from (Mg ₂ Si) and silicon carbide (SiC). In the high-strength flame-retardant magnesium alloy according to claim 1,
The amount of molybdenum (Mo) as the additive is 1.0 to 12.0% by weight. In the high-strength flame-retardant magnesium alloy according to claim 1,
The amount of niobium (Nb) as the additional additive is 0.5 to 5.0% by weight. In the high-strength flame-retardant magnesium alloy according to claim 1,
The amount of tungsten (W) as the additional additive is 5.0 to 40.0% by weight. In the high-strength flame-retardant magnesium alloy according to claim 1,
A high-strength flame-retardant magnesium alloy characterized in that the amount of alumina (Al ₂ O ₃ ) as the additional additive is 1.0 to 5.0% by weight. In the high-strength flame-retardant magnesium alloy according to claim 1,
The amount of additional additives silicide magnesium _(Mg 2 Si) is a high strength, flame retardant magnesium alloy, which is a 2.0 to 6.0 wt%. In the high-strength flame-retardant magnesium alloy according to claim 1,
The amount of the additional additive silicon carbide (SiC) is 0.7 to 20.0 wt%, a high-strength flame-retardant magnesium alloy. In the high-strength flame-retardant magnesium alloy according to claim 1,
The magnesium alloy is a magnesium alloy containing 0 to 12.0% by weight of aluminum, 0 to 5.0% by weight of zinc, and 0.5% by weight or less of manganese. alloy. In the high-strength flame-retardant magnesium alloy according to claim 1,
The magnesium alloy is one type of magnesium alloy selected from AZ31 series, AZ61 series, AZ80 series, AZ91 series, AZ92 series, AM50 series, AM60 series, and AM100 series. Magnesium alloy. In the high-strength flame-retardant magnesium alloy according to claim 1,
The flame-retardant magnesium alloy is a high-strength flame-retardant magnesium alloy characterized by comprising a pulverized product obtained from the flame-retardant magnesium alloy material. In the high-strength flame-retardant magnesium alloy according to claim 1,
The high-strength flame-retardant magnesium alloy is an alloy manufactured by plastic working that causes external deformation to cause permanent deformation after the addition of the additional additive. In the high-strength flame-retardant magnesium alloy according to claim 10,
The high-strength flame-retardant magnesium alloy is characterized in that the pulverized material is cutting waste or powder obtained by cutting. In the high-strength flame-retardant magnesium alloy according to claim 12,
The high-strength flame-retardant magnesium alloy characterized in that the plastic working is one type selected from extrusion processing, drawing processing, rotary forging processing and rolling processing, or a combination of two or more types.

Images