JP2007302611A5 - - Google Patents
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- Publication number
- JP2007302611A5 JP2007302611A5 JP2006133169A JP2006133169A JP2007302611A5 JP 2007302611 A5 JP2007302611 A5 JP 2007302611A5 JP 2006133169 A JP2006133169 A JP 2006133169A JP 2006133169 A JP2006133169 A JP 2006133169A JP 2007302611 A5 JP2007302611 A5 JP 2007302611A5
- Authority
- JP
- Japan
- Prior art keywords
- soap
- fatty acid
- acid
- poe
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000344 soap Substances 0.000 description 40
- 235000014113 dietary fatty acids Nutrition 0.000 description 39
- 239000000194 fatty acid Substances 0.000 description 39
- 150000004665 fatty acids Chemical class 0.000 description 31
- -1 jojoba oil Substances 0.000 description 28
- QIQXTHQIDYTFRH-UHFFFAOYSA-N Stearic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 19
- IPCSVZSSVZVIGE-UHFFFAOYSA-N Palmitic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 18
- 239000000203 mixture Substances 0.000 description 15
- POULHZVOKOAJMA-UHFFFAOYSA-N Lauric acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 14
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 14
- 230000001815 facial Effects 0.000 description 12
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 11
- 239000011591 potassium Substances 0.000 description 11
- 229910052700 potassium Inorganic materials 0.000 description 11
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 11
- 239000011734 sodium Substances 0.000 description 11
- 229910052708 sodium Inorganic materials 0.000 description 11
- 235000021314 Palmitic acid Nutrition 0.000 description 9
- 235000021355 Stearic acid Nutrition 0.000 description 9
- 239000008117 stearic acid Substances 0.000 description 9
- 239000005639 Lauric acid Substances 0.000 description 7
- 239000004359 castor oil Substances 0.000 description 7
- 235000019438 castor oil Nutrition 0.000 description 7
- 229920001296 polysiloxane Polymers 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 229940015001 Glycerin Drugs 0.000 description 5
- 239000006096 absorbing agent Substances 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- 229960005150 glycerol Drugs 0.000 description 5
- 239000004166 Lanolin Substances 0.000 description 4
- 229940039717 Lanolin Drugs 0.000 description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N Trimethylglycine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 4
- 235000019388 lanolin Nutrition 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- GPLRAVKSCUXZTP-UHFFFAOYSA-N 3-(2,3-dihydroxypropoxy)propane-1,2-diol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 3
- 229940105990 DIGLYCERIN Drugs 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000010445 mica Substances 0.000 description 3
- 229910052618 mica group Inorganic materials 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Substances CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L Barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- UNXHWFMMPAWVPI-QWWZWVQMSA-N D-Threitol Natural products OC[C@@H](O)[C@H](O)CO UNXHWFMMPAWVPI-QWWZWVQMSA-N 0.000 description 2
- 239000004386 Erythritol Substances 0.000 description 2
- 229940009714 Erythritol Drugs 0.000 description 2
- UNXHWFMMPAWVPI-ZXZARUISSA-N Erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N Oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 229960004063 Propylene glycol Drugs 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N Salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 229930003270 Vitamin B Natural products 0.000 description 2
- RMRCNWBMXRMIRW-WYVZQNDMSA-L Vitamin B12 Chemical compound N([C@@H]([C@@]1(C)[C@@](C)(CC(N)=O)[C@H](CCC(N)=O)\C(N1[Co+]C#N)=C(/C)\C1=N\C([C@H]([C@@]1(CC(N)=O)C)CCC(N)=O)=C\C1=N\C([C@H](C1(C)C)CCC(N)=O)=C/1C)[C@@H]2CC(N)=O)=C\1[C@]2(C)CCC(=O)NCC(C)OP([O-])(=O)O[C@H]1[C@@H](O)[C@@H](N2C3=CC(C)=C(C)C=C3N=C2)O[C@@H]1CO RMRCNWBMXRMIRW-WYVZQNDMSA-L 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 235000013871 bee wax Nutrition 0.000 description 2
- 239000012166 beeswax Substances 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 230000005591 charge neutralization Effects 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000019414 erythritol Nutrition 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- QUEDXNHFTDJVIY-WENCSYSZSA-N gamma-Tocopherol Natural products OC1=C(C)C(C)=C2O[C@](CCC[C@@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-WENCSYSZSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 229940119170 jojoba wax Drugs 0.000 description 2
- 230000001264 neutralization Effects 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 235000013772 propylene glycol Nutrition 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 235000019156 vitamin B Nutrition 0.000 description 2
- 239000011720 vitamin B Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- WGVKWNUPNGFDFJ-DQCZWYHMSA-N β-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C WGVKWNUPNGFDFJ-DQCZWYHMSA-N 0.000 description 2
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2R,3R,4R,5S)-hexane-1,2,3,4,5,6-hexol;(Z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 description 1
- BJDAUCLANVMIOB-UHFFFAOYSA-N (3-decanoyloxy-2,2-dimethylpropyl) decanoate Chemical compound CCCCCCCCCC(=O)OCC(C)(C)COC(=O)CCCCCCCCC BJDAUCLANVMIOB-UHFFFAOYSA-N 0.000 description 1
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- 229940031723 1,2-octanediol Drugs 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N 1-Tetradecanol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 1
- ZONJATNKKGGVSU-UHFFFAOYSA-N 14-methylpentadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCC(O)=O ZONJATNKKGGVSU-UHFFFAOYSA-N 0.000 description 1
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 1
- RKJGFHYCZPZJPE-UHFFFAOYSA-N 2,2-bis(16-methylheptadecanoyloxymethyl)butyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(CC)(COC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C RKJGFHYCZPZJPE-UHFFFAOYSA-N 0.000 description 1
- NRANXTWANPHZAU-UHFFFAOYSA-N 2-(1H-quinolin-2-ylidene)indene-1,3-dione Chemical compound N1C2=CC=CC=C2C=CC1=C1C(=O)C2=CC=CC=C2C1=O NRANXTWANPHZAU-UHFFFAOYSA-N 0.000 description 1
- OZZQHCBFUVFZGT-UHFFFAOYSA-N 2-(2-hydroxypropanoyloxy)propanoic acid Chemical compound CC(O)C(=O)OC(C)C(O)=O OZZQHCBFUVFZGT-UHFFFAOYSA-N 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N 2-Imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- NCLNAHJFXIKYBY-UHFFFAOYSA-N 2-hexyldecyl 16-methylheptadecanoate Chemical compound CCCCCCCCC(CCCCCC)COC(=O)CCCCCCCCCCCCCCC(C)C NCLNAHJFXIKYBY-UHFFFAOYSA-N 0.000 description 1
- MUHFRORXWCGZGE-KTKRTIGZSA-N 2-hydroxyethyl (Z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCO MUHFRORXWCGZGE-KTKRTIGZSA-N 0.000 description 1
- FKOKUHFZNIUSLW-UHFFFAOYSA-N 2-hydroxypropyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(C)O FKOKUHFZNIUSLW-UHFFFAOYSA-N 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-Aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- PZZYQPZGQPZBDN-UHFFFAOYSA-N Aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 1
- RWZYAGGXGHYGMB-UHFFFAOYSA-N Anthranilic acid Chemical compound NC1=CC=CC=C1C(O)=O RWZYAGGXGHYGMB-UHFFFAOYSA-N 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- 229960000686 Benzalkonium Chloride Drugs 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N Benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- GLQBXSIPUULYOG-UHFFFAOYSA-M Bismuth oxychloride Chemical compound Cl[Bi]=O GLQBXSIPUULYOG-UHFFFAOYSA-M 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue FCF Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- XOJVVFBFDXDTEG-UHFFFAOYSA-N Bute hydrocarbon Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 1
- 229960003563 Calcium Carbonate Drugs 0.000 description 1
- 229940073532 Candelilla Wax Drugs 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N Cetyl alcohol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- LBFUKZWYPLNNJC-UHFFFAOYSA-N Cobalt(II,III) oxide Chemical compound [Co]=O.O=[Co]O[Co]=O LBFUKZWYPLNNJC-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-α-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 1
- ZDQWESQEGGJUCH-UHFFFAOYSA-N Diisopropyl adipate Chemical compound CC(C)OC(=O)CCCCC(=O)OC(C)C ZDQWESQEGGJUCH-UHFFFAOYSA-N 0.000 description 1
- VJHINFRRDQUWOJ-UHFFFAOYSA-N Dioctyl sebacate Chemical compound CCCCC(CC)COC(=O)CCCCCCCCC(=O)OCC(CC)CCCC VJHINFRRDQUWOJ-UHFFFAOYSA-N 0.000 description 1
- 229940113120 Dipropylene Glycol Drugs 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N Dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- NOPFSRXAKWQILS-UHFFFAOYSA-N Docosanol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N Hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- AXISYYRBXTVTFY-UHFFFAOYSA-N Isopropyl myristate Chemical compound CCCCCCCCCCCCCC(=O)OC(C)C AXISYYRBXTVTFY-UHFFFAOYSA-N 0.000 description 1
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 1
- 240000000912 Macadamia tetraphylla Species 0.000 description 1
- 235000003800 Macadamia tetraphylla Nutrition 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L Magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N Maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 229940116985 POTASSIUM LAURYL SULFATE Drugs 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 229940066842 Petrolatum Drugs 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N Phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- 229960005323 Phenoxyethanol Drugs 0.000 description 1
- 239000004698 Polyethylene (PE) Substances 0.000 description 1
- ONQDVAFWWYYXHM-UHFFFAOYSA-M Potassium lauryl sulfate Chemical compound [K+].CCCCCCCCCCCCOS([O-])(=O)=O ONQDVAFWWYYXHM-UHFFFAOYSA-M 0.000 description 1
- MMXZSJMASHPLLR-UHFFFAOYSA-N Pyrroloquinoline quinone Chemical compound C12=C(C(O)=O)C=C(C(O)=O)N=C2C(=O)C(=O)C2=C1NC(C(=O)O)=C2 MMXZSJMASHPLLR-UHFFFAOYSA-N 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N Rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N Silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N Simethicone Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- 229940005581 Sodium Lactate Drugs 0.000 description 1
- 229940045870 Sodium Palmitate Drugs 0.000 description 1
- 229940045920 Sodium Pyrrolidone Carboxylate Drugs 0.000 description 1
- NGSFWBMYFKHRBD-UHFFFAOYSA-M Sodium lactate Chemical compound [Na+].CC(O)C([O-])=O NGSFWBMYFKHRBD-UHFFFAOYSA-M 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 229960005078 Sorbitan sesquioleate Drugs 0.000 description 1
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N Squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 1
- GLDOVTGHNKAZLK-UHFFFAOYSA-N Stearyl alcohol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- CZMRCDWAGMRECN-GDQSFJPYSA-N Sucrose Natural products O([C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](CO)O1)[C@@]1(CO)[C@H](O)[C@@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-GDQSFJPYSA-N 0.000 description 1
- 229920002359 Tetronic® Polymers 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N TiO Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- AOBORMOPSGHCAX-DGHZZKTQSA-N Tocofersolan Chemical compound OCCOC(=O)CCC(=O)OC1=C(C)C(C)=C2O[C@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C AOBORMOPSGHCAX-DGHZZKTQSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Tris Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 229940029983 VITAMINS Drugs 0.000 description 1
- 229940045997 Vitamin A Drugs 0.000 description 1
- FPIPGXGPPPQFEQ-BOOMUCAASA-N Vitamin A Natural products OC/C=C(/C)\C=C\C=C(\C)/C=C/C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-BOOMUCAASA-N 0.000 description 1
- 229930003756 Vitamin B7 Natural products 0.000 description 1
- 229940046008 Vitamin D Drugs 0.000 description 1
- 229930003316 Vitamin D Natural products 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 229940046009 Vitamin E Drugs 0.000 description 1
- 229940021016 Vitamin IV solution additives Drugs 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N Xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 Xylitol Drugs 0.000 description 1
- NWGKJDSIEKMTRX-HSACVWGTSA-N [(2R)-2-[(2R,3R,4S)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] (E)-octadec-9-enoate Chemical compound CCCCCCCC\C=C\CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-HSACVWGTSA-N 0.000 description 1
- UDRYFKCHZFVZGJ-UHFFFAOYSA-N [5-hexadecanoyloxy-4-(hexadecanoyloxymethyl)-6-methylpyridin-3-yl]methyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC1=CN=C(C)C(OC(=O)CCCCCCCCCCCCCCC)=C1COC(=O)CCCCCCCCCCCCCCC UDRYFKCHZFVZGJ-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N al2o3 Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 1
- 150000004347 all-trans-retinol derivatives Chemical class 0.000 description 1
- 229940087168 alpha Tocopherol Drugs 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N alpha-Tocopherol Natural products OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
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Description
一方、１）脂肪酸石鹸を洗浄成分とする、クリーム状の洗顔料であって、２）脂肪酸石鹸を構成する脂肪酸の組成に於いて、パルミチン酸及びステアリン酸を５０〜７０質量％含有し、３）前記脂肪酸石鹸がカリウム石鹸とナトリウム石鹸の混合物であり、カリウム石鹸とナトリウム石鹸のモル比が、１０：２〜１００：５である洗顔料は全く知られていないし、この様な構成を採用することにより、前記高温保存条件での安定性を損なわずに、ラウリン酸をパルミチン酸乃至はステアリン酸に置換し、ラウリン酸量を減じる手段となることも、全く知られていない。
On the other hand, 1) a cream-type facial cleanser comprising fatty acid soap as a cleaning component, and 2) a composition of fatty acid constituting fatty acid soap, containing 50 to 70% by mass of palmitic acid and stearic acid. ) The fatty acid soap is a mixture of potassium soap and sodium soap, and no facial cleanser having a molar ratio of potassium soap to sodium soap of 10: 2 to 100: 5 is known at all, and such a constitution is adopted. Thus, it has not been known at all that the lauric acid can be replaced with palmitic acid or stearic acid to reduce the amount of lauric acid without impairing the stability under the high temperature storage conditions.
ジグリセリンを洗顔料に含有させる技術は既に知られている（例えば、特許文献２、特許文献３を参照）が、かかる成分を加えることにより、１）脂肪酸石鹸を洗浄成分とする、クリーム状の洗顔料であって、２）脂肪酸石鹸を構成する脂肪酸の組成に於いて、パルミチン酸及びステアリン酸を５０〜７０質量％含有し、３）前記脂肪酸石鹸がカリウム石鹸とナトリウム石鹸の混合物であり、カリウム石鹸とナトリウム石鹸のモル比が、１０：２〜１００：５である洗顔料について、刺激感の更なる低減ができることも全く知られていない。
Techniques for incorporating diglycerin into facial cleansers are already known (see, for example, Patent Document 2 and Patent Document 3), but by adding such components, 1) a creamy cream containing fatty acid soap as a cleaning component 2) In the composition of the fatty acid constituting the fatty acid soap, 2) containing 50 to 70 % by weight of palmitic acid and stearic acid, and 3) the fatty acid soap is a mixture of potassium soap and sodium soap, It is not known at all that it is possible to further reduce the feeling of irritation for a face wash having a molar ratio of potassium soap to sodium soap of 10: 2 to 100: 5.
この様な状況に鑑みて、本発明者らは、４０〜５０℃の高温保存での安定性を損なわずに、ラウリン酸をパルミチン酸乃至はステアリン酸に置換し、ラウリン酸量を減じる手段を求めて、鋭意研究努力を重ねた結果、１）脂肪酸石鹸を洗浄成分とする、クリーム状の
洗顔料であって、２）脂肪酸石鹸を構成する脂肪酸の組成に於いて、パルミチン酸及びステアリン酸を５０〜７０質量％含有し、３）前記脂肪酸石鹸がカリウム石鹸とナトリウム石鹸の混合物であり、カリウム石鹸とナトリウム石鹸のモル比が、１０：２〜１００：５である洗顔料がその様な特性を備えていることを見いだし、発明を完成させるに至った。即ち、本発明は以下に示すとおりである。
（１）１）脂肪酸石鹸を洗浄成分とする、クリーム状の洗顔料であって、２）脂肪酸石鹸を構成する脂肪酸の組成に於いて、パルミチン酸及びステアリン酸を５０〜７０質量％含有し、３）前記脂肪酸石鹸がカリウム石鹸とナトリウム石鹸の混合物であり、カリウム石鹸とナトリウム石鹸のモル比が、１０：２〜１００：５であることを特徴とする、洗顔料。
（２）更に、ジグリセリンを１０〜４０質量％含有することを特徴とする、（１）に記載の洗顔料。
（３）前記脂肪酸石鹸を構成する脂肪酸の組成に於いて、ラウリン酸の含有量が、１０〜３０質量％であることを特徴とする、（１）又は（２）に記載の洗顔料。
（４）中和率が８０〜９０％であることを特徴とする、（１）〜（３）の何れかに記載の洗顔料。
（５）脂肪酸石鹸の含有量が、洗顔料全量に対して、４０〜５０質量％であることを特徴とする、（１）〜（４）の何れかに記載の洗顔料。
In view of such a situation, the present inventors replaced lauric acid with palmitic acid or stearic acid without reducing the stability at high temperature storage at 40 to 50 ° C., and reduced the amount of lauric acid. As a result of earnest research efforts, 1) a cream facial cleanser comprising fatty acid soap as a cleaning component, and 2) in the composition of the fatty acid constituting the fatty acid soap, palmitic acid and stearic acid were added. 50) -70% by mass, 3) The above-mentioned fatty acid soap is a mixture of potassium soap and sodium soap, and the facial cleanser whose molar ratio of potassium soap to sodium soap is 10: 2 to 100: 5 has such characteristics. It was found that it was equipped with, and came to complete the invention. That is, the present invention is as follows.
(1) 1) A cream-type facial cleanser comprising fatty acid soap as a cleaning component, and 2) a composition of fatty acid constituting fatty acid soap, containing 50 to 70% by mass of palmitic acid and stearic acid, 3) The facial cleanser, wherein the fatty acid soap is a mixture of potassium soap and sodium soap, and the molar ratio of potassium soap to sodium soap is 10: 2 to 100: 5.
(2) The face wash according to (1), further comprising 10-40% by mass of diglycerin.
(3) The facial cleanser according to (1) or (2), wherein the content of lauric acid is 10 to 30% by mass in the composition of the fatty acid constituting the fatty acid soap.
(4) The face wash according to any one of (1) to (3) , wherein the neutralization rate is 80 to 90%.
(5) The facial cleanser according to any one of (1) to (4) , wherein the content of the fatty acid soap is 40 to 50% by mass relative to the total amount of the facial cleanser.
本発明の洗顔料は、１）脂肪酸石鹸を洗浄成分とする、クリーム状の洗顔料であって、２）脂肪酸石鹸を構成する脂肪酸の組成に於いて、パルミチン酸及びステアリン酸を５０〜７０質量％、より好ましくは５５〜６５質量％含有し、３）前記脂肪酸石鹸がカリウム石鹸とナトリウム石鹸の混合物であり、カリウム石鹸とナトリウム石鹸のモル比が、１０：２〜１００：５、より好ましくは１００：１５〜１００：６であることを特徴とする。前記クリーム状とは、Ｂ型粘度計４号ローターを用いて３ｒｐｍの条件で粘度を計測した場合、２００００ｍＰａ・ｓ以上であるか、粘度の測定閾値を外れて、硬度でその性状を特徴づける性質のものであって、不透明で白濁状の外観を呈し、時に真珠様光沢を有することあるものを意味する。脂肪酸としては、パルミチン酸及び／又はステアリン酸を必須で含み、脂肪酸の中では最も大きな含有率を占めることが好ましく、該パルミチン酸とステアリン酸の質量比は１：２〜２：１が好ましく、より好ましくは２：３〜３：２であり、それ以外の脂肪酸としては、ミリスチン酸、ラウリン酸、オレイン酸、イソステアリン酸、イソパルミチン酸などが好適に例示できる。この内、ラウリン酸は脂肪酸総量に対して３０質量％以下にすることが好ましい。好ましい含有量は、１０〜３０質量％であり、より好ましくは１２〜２７質量％である。これは一過性の刺激感を更に低減するためである。脂肪酸石鹸のアルカリ構成は、前記の如くにカリウムとナトリウムの組み合わせであることが好ましい。本発明の効果を損なわない範囲に於いて、アルギニンなどの塩基性アミノ酸やトリエタノールアミンなどの有機アミン類を更に加えて併用することもできるが、経時での着色の可能性が存するなどの短所も存するため、かかる他のアルカリは併用しない方が好ましい。前記のクリーム状の性状を呈するためには、脂肪酸石鹸の総量は洗顔料全量に対して、４０〜５０質量％であることが好ましく、より好ましくは４２〜４８質量％である。又、脂肪酸の中和率は、８０〜９０％が好ましい。
The facial cleanser of the present invention is 1) a cream facial cleanser comprising fatty acid soap as a cleaning component, and 2) 50-70 masses of palmitic acid and stearic acid in the composition of fatty acids constituting the fatty acid soap. 3) The fatty acid soap is a mixture of potassium soap and sodium soap, and the molar ratio of potassium soap to sodium soap is 10: 2 to 100: 5, more preferably It is characterized by being 100: 15-100: 6. The cream-like property is characterized in that, when the viscosity is measured under the condition of 3 rpm using a B-type viscometer No. 4 rotor, it is 20000 mPa · s or more, or deviates from the viscosity measurement threshold and characterizes its properties by hardness. Means an opaque, cloudy appearance and sometimes pearly luster. As the fatty acid, palmitic acid and / or stearic acid is essential, and preferably occupies the largest content in the fatty acid, and the mass ratio of the palmitic acid and stearic acid is preferably 1: 2 to 2: 1, more preferably 2: 3 to 3: 2, the other fatty acids, Mi Risuchin acid, lauric acid, oleic acid, isostearic acid, isopalmitic acid can be preferably exemplified. Among these, lauric acid is preferably 30% by mass or less based on the total amount of fatty acids. A preferable content is 10 to 30% by mass, and more preferably 12 to 27% by mass. This is to further reduce the transient irritation. The alkali composition of the fatty acid soap is preferably a combination of potassium and sodium as described above. As long as the effects of the present invention are not impaired, basic amino acids such as arginine and organic amines such as triethanolamine can be further used in combination, but there are disadvantages such as the possibility of coloring over time. Therefore, it is preferable not to use such other alkali in combination. In order to exhibit the creamy properties, the total amount of fatty acid soap is preferably 40 to 50% by mass, more preferably 42 to 48% by mass, based on the total amount of the face wash. The neutralization rate of the fatty acid is preferably 80 to 90%.
本発明の洗顔料に於いては、前記の成分に加えて、通常洗顔料で使用される任意成分を、本願発明の効果を損ねない範囲に於いて、含有することができる。この様な任意成分としては、例えば、マカデミアナッツ油、アボガド油、トウモロコシ油、オリーブ油、ナタネ油、ゴマ油、ヒマシ油、サフラワー油、綿実油、ホホバ油、ヤシ油、パーム油、液状ラノリン、硬化ヤシ油、硬化油、モクロウ、硬化ヒマシ油、ミツロウ、キャンデリラロウ、カルナウバロウ、イボタロウ、ラノリン、還元ラノリン、硬質ラノリン、ホホバロウ等のオイル、ワックス類；流動パラフィン、スクワラン、プリスタン、オゾケライト、パラフィン、セレシン、ワセリン、マイクロクリスタリンワックス等の炭化水素類；セチルアルコール、ステアリルアルコール、イソステアリルアルコール、ベヘニルアルコール、オクチルドデカノール、ミリスチルアルコール、セトステアリルアルコール等の高級アルコール等；イソオクタン酸セチル、ミリスチン酸イソプロピル、イソステアリン酸ヘキシルデシル、アジピン酸ジイソプロピル、セバチン酸ジ−２−エチルヘキシル、乳酸セチル、リンゴ酸ジイソステアリル、ジ−２−エチルヘキサン酸エチレングリコール、ジカプリン酸ネオペンチルグリコール、ジ−２−ヘプチルウンデカン酸グリセリン、トリ−２−エチルヘキサン酸グリセリン、トリ−２−エチルヘキサン酸トリメチロールプロパン、トリイソステアリン酸トリメチロールプロパン、テトラ−２−エチルヘキサン酸ペンタンエリトリット等の合成エステル油類；ジメチルポリシロキサン、メチルフェニルポリシロキサン、ジフェニルポリシロキサン等の鎖状ポリシロキサン；オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサンシロキサン等の環状ポリシロキサン；アミノ変性ポリシロキサン、ポリエーテル変性ポリシロキサン、アルキル変性ポリシロキサン、フッ素変性ポリシロキサン等の変性ポリシロキサン等のシリコーン油等の油剤類；脂肪酸セッケン（ラウリン酸ナトリウム、パルミチン酸ナトリウム等）、ラウリル硫酸カリウム、アルキル硫酸トリエタノールアミンエーテル等のアニオン界面活性剤類；塩化ステアリルトリメチルアンモニウム、塩化ベンザルコニウム、ラウリルアミンオキサイド等のカチオン界面活性剤類；イミダゾリン系両性界面活性剤（２−ココイル−２−イミダゾリニウムヒドロキサイド−１−カルボキシエチロキシ２ナトリウム塩等）、ベタイン系界面活性剤（アルキルベタイン、アミドベタイン、スルホベタイン等）、アシルメチルタウリン等の両性界面活性剤類；ソルビタン脂肪酸エステル類（ソルビタンモノステアレート、セスキオレイン酸ソルビタン等）、グリセリン脂肪酸類（モノステアリン酸グリセリン等）、プロピレングリコール脂肪酸エステル類（モノステアリン酸プロピレングリコール等）、硬化ヒマシ油誘導体、グリセリンアルキルエーテル、ＰＯＥソルビタン脂肪酸エステル類（ＰＯＥソルビタンモノオレエート、モノステアリン酸ポリオキエチレンソルビタン等）、ＰＯＥソルビット脂肪酸エステル類（ＰＯＥ−ソルビットモノラウレート等）、ＰＯＥグリセリン脂肪酸エステル類（ＰＯＥ−グリセリンモノイソステアレート等）、ＰＯＥ脂肪酸エステル類（ポリエチレングリコールモノオレート、ＰＯＥジステアレート等）、ＰＯＥアルキルエーテル類（ＰＯＥ２−オクチルドデシルエーテル等）、ＰＯＥアルキルフェニルエーテル類（ＰＯＥノニルフェニルエーテル等）、プルロニック型類、ＰＯＥ・ＰＯＰアルキルエーテル類（ＰＯＥ・ＰＯＰ２−デシルテトラデシルエーテル等）、テトロニック類、ＰＯＥヒマシ油・硬化ヒマシ油誘導体（ＰＯＥヒマシ油、ＰＯＥ硬化ヒマシ油等）、ショ糖脂肪酸エステル、アルキルグルコシド等の非イオン界面活性剤類；ポリエチレングリコール、グリセリン、１，３−ブチレングリコール、エリスリトール、ソルビトール、キシリトール、マルチトール、プロピレングリコール、ジプロピレングリコール、イソプレングリコール、１，２−ペンタンジオール、２，４−ヘキサンジオール、１，２−ヘキサンジオール、１，２−オクタンジオール等のジグリセリンを除く多価アルコール類；ピロリドンカルボン酸ナトリウム、乳酸、乳酸ナトリウム等の保湿成分類；表面を処理されていても良い、マイカ、タルク、カオリン、合成雲母、
炭酸カルシウム、炭酸マグネシウム、無水ケイ酸（シリカ）、酸化アルミニウム、硫酸バリウム等の粉体類、；表面を処理されていても良い、ベンガラ、黄酸化鉄、黒酸化鉄、酸化コバルト、群青、紺青、酸化チタン、酸化亜鉛の無機顔料類；表面を処理されていても良い、雲母チタン、魚燐箔、オキシ塩化ビスマス等のパール剤類；レーキ化されていても良い赤色２０２号、赤色２２８号、赤色２２６号、黄色４号、青色４０４号、黄色５号、赤色５０５号、赤色２３０号、赤色２２３号、橙色２０１号、赤色２１３号、黄色２０４号、黄色２０３号、青色１号、緑色２０１号、紫色２０１号、赤色２０４号等の有機色素類；ポリエチレン末、ポリメタクリル酸メチル、ナイロン粉末、オルガノポリシロキサンエラストマー等の有機粉体類；パラアミノ安息香酸系紫外線吸収剤；アントラニル酸系紫外線吸収剤；サリチル酸系紫外線吸収剤；桂皮酸系紫外線吸収剤；ベンゾフェノン系紫外線吸収剤；糖系紫外線吸収剤；２−（２’−ヒドロキシ−５’−ｔ−オクチルフェニル)ベンゾトリアゾール、４−メトキシ−４’−ｔ−ブチルジベンゾイルメタン等の紫外線吸収剤類；エタノール、イソプロパノール等の低級アルコール類；ビタミンＡ又はその誘導体、ビタミンＢ 6 塩酸塩、ビタミンＢ 6 トリパルミテート、ビタミンＢ 6 ジオクタノエート、ビタミンＢ 2 又はその誘導体、ビタミンＢ 12 、ビタミンＢ 15 又はその誘導体等のビタミンＢ類；α−トコフェロール、β−トコフェロール、γ−トコフェロール、ビタミンＥアセテート等のビタミンＥ類、ビタミンＤ類、ビタミンＨ、パントテン酸、パンテチン、ピロロキノリンキノン等のビタミン類等；フェノキシエタノール等の抗菌剤などが好ましく例示できる。本発明の洗顔料は、前記の成分を常法に従って処理することにより、製造することができる。
In the face wash of the present invention, in addition to the above-mentioned components, optional components usually used in the face wash can be contained within a range not impairing the effects of the present invention. Such optional ingredients include, for example, macadamia nut oil, avocado oil, corn oil, olive oil, rapeseed oil, sesame oil, castor oil, safflower oil, cottonseed oil, jojoba oil, coconut oil, palm oil, liquid lanolin, hydrogenated coconut oil Oil, wax, oils such as beeswax, owl, hydrogenated castor oil, beeswax, candelilla wax, carnauba wax, ibotarou, lanolin, reduced lanolin, hard lanolin, jojoba wax; liquid paraffin, squalane, pristane, ozokerite, paraffin, ceresin, petrolatum Hydrocarbons such as microcrystalline wax; higher alcohols such as cetyl alcohol, stearyl alcohol, isostearyl alcohol, behenyl alcohol, octyldodecanol, myristyl alcohol, cetostearyl alcohol; Cetyl octoate, isopropyl myristate, hexyl decyl isostearate, diisopropyl adipate, di-2-ethylhexyl sebacate, cetyl lactate, diisostearyl malate, ethylene glycol di-2-ethylhexanoate, neopentyl glycol dicaprate, Synthetic esters such as glycerin di-2-heptylundecanoate, glyceryl tri-2-ethylhexanoate, trimethylolpropane tri-2-ethylhexanoate, trimethylolpropane triisostearate, pentane erythritol tetra-2-ethylhexanoate Oils: Chain polysiloxanes such as dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane; octamethylcyclotetrasiloxane, decamethylcyclopentasiloxa , Cyclic polysiloxanes such as dodecamethylcyclohexanesiloxane; oils such as silicone oils such as amino-modified polysiloxane, polyether-modified polysiloxane, alkyl-modified polysiloxane, and fluorine-modified polysiloxane; and the like; fatty acid soap (lauric acid) Sodium, sodium palmitate, etc.), anionic surfactants such as potassium lauryl sulfate, alkyl sulfate triethanolamine ether; cationic surfactants such as stearyltrimethylammonium chloride, benzalkonium chloride, laurylamine oxide; imidazoline-based amphoteric Surfactants (2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy disodium salt, etc.), betaine surfactants (alkyl betaines, amide betaines, Amphoteric surfactants such as sulfobetaine, acylmethyltaurine, etc .; sorbitan fatty acid esters (sorbitan monostearate, sorbitan sesquioleate, etc.), glycerin fatty acids (eg glyceryl monostearate), propylene glycol fatty acid esters ( Propylene glycol monostearate), hardened castor oil derivative, glycerin alkyl ether, POE sorbitan fatty acid esters (POE sorbitan monooleate, polyoxyethylene sorbitan monostearate, etc.), POE sorbite fatty acid esters (POE-sorbit monolaur) POE glycerin fatty acid esters (POE-glycerin monoisostearate, etc.), POE fatty acid esters (polyethylene glycol monooleate, POE diste) Rate), POE alkyl ethers (POE2-octyldodecyl ether, etc.), POE alkylphenyl ethers (POE nonylphenyl ether, etc.), Pluronic types, POE / POP alkyl ethers (POE / POP2-decyltetradecyl ether, etc.) ), Tetronics, POE castor oil / hardened castor oil derivatives (POE castor oil, POE hardened castor oil, etc.), nonionic surfactants such as sucrose fatty acid ester, alkyl glucoside; polyethylene glycol, glycerin, 1, 3 -Butylene glycol, erythritol, sorbitol, xylitol, maltitol, propylene glycol, dipropylene glycol, isoprene glycol, 1,2-pentanediol, 2,4-hexanediol, 1,2-hexane Polyhydric alcohols excluding diglycerin such as all and 1,2-octanediol; moisturizing ingredients such as sodium pyrrolidonecarboxylate, lactic acid and sodium lactate; surface may be treated, mica, talc, kaolin, synthesis mica,
Powders such as calcium carbonate, magnesium carbonate, anhydrous silicic acid (silica), aluminum oxide, barium sulfate; surface may be treated, bengara, yellow iron oxide, black iron oxide, cobalt oxide, ultramarine, bitumen Inorganic pigments such as titanium oxide and zinc oxide; surface-treated pearlescent agents such as titanium mica, fish phosphorus foil, bismuth oxychloride; red 202 and red 228 which may be raked , Red No. 226, Yellow No. 4, Blue No. 404, Yellow No. 5, Red No. 505, Red No. 230, Red No. 223, Orange No. 201, Red No. 213, Yellow No. 204, Yellow No. 203, Blue No. 1, Green Organic pigments such as 201, purple 201 and red 204; organic powders such as polyethylene powder, polymethyl methacrylate, nylon powder, organopolysiloxane elastomer Para-aminobenzoic acid UV absorbers; anthranilic acid UV absorbers; salicylic acid type ultraviolet absorbers; cinnamic acid-based ultraviolet absorbents; benzophenone ultraviolet absorbers; sugar-based ultraviolet absorbent; 2- (2'-hydroxy-5 ' UV absorbers such as -t-octylphenyl) benzotriazole and 4-methoxy-4'-t-butyldibenzoylmethane; lower alcohols such as ethanol and isopropanol; vitamin A or a derivative thereof, vitamin B 6 hydrochloride, Vitamin B 6 tripalmitate, vitamin B 6 dioctanoate, vitamin B 2 or its derivative, vitamin B 12 such as vitamin B 12 , vitamin B 15 or its derivative; α-tocopherol, β-tocopherol, γ-tocopherol, vitamin E acetate Such as vitamin E, vitamin D, vitamin H, pantote Acid, pantethine, vitamins etc. pyrroloquinoline quinone and the like; anti-microbial agents such as phenoxyethanol can be preferably exemplified. The face wash of the present invention can be produced by treating the above components according to a conventional method.
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| JP2006133169A JP2007302611A (en) | 2006-05-12 | 2006-05-12 | Facial cleanser |
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| JP6317252B2 (en) * | 2011-09-22 | 2018-04-25 | ロレアル | Cosmetic composition |
| CN104069026A (en) * | 2014-07-17 | 2014-10-01 | 广州丹奇日用化工厂有限公司 | Facial cleanser and preparation method |
| JP6835385B2 (en) * | 2016-12-27 | 2021-02-24 | ポーラ化成工業株式会社 | Cleaning composition |
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| JP2001072574A (en) * | 1999-09-02 | 2001-03-21 | Pola Chem Ind Inc | Cosmetic for face cleansing |
| JP2002154946A (en) * | 2000-11-21 | 2002-05-28 | Lion Corp | Creamy detergent composition |
| JP4294892B2 (en) * | 2001-07-31 | 2009-07-15 | ポーラ化成工業株式会社 | Cleaning fee with reduced tension |
| JP4432345B2 (en) * | 2003-03-31 | 2010-03-17 | 日油株式会社 | Creamy detergent composition |
| JP3811168B2 (en) * | 2003-06-13 | 2006-08-16 | 花王株式会社 | Skin cleanser composition |
| JP5252768B2 (en) * | 2004-09-30 | 2013-07-31 | 日油株式会社 | Creamy detergent composition |
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