JP2001172167A - Cleanser composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a cleanser composition which improves the adhesivity of a skin-activating ingredient and gives a high skin-activating effect. SOLUTION: This cleanser composition characterized by containing (A) a surfactant, (B) a skin-activating ingredient and (C) an acrylic polymer and/or a cellulosic polymer.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

TECHNICAL FIELD The present invention relates to the prevention and improvement of spots and freckles, the prevention and improvement of wrinkle formation, the prevention and improvement of pores and acne caused by bacteria and abnormal keratinization, the moisturization of the skin, and rough skin. The present invention relates to a detergent composition having an effect of preventing and improving skin irritation, weakening of skin, declining elasticity, and dullness of complexion.

[0002]

2. Description of the Related Art In recent years, maintaining healthy and beautiful skin has become a serious concern for both young and old. However, the skin is delicately affected by aging, temperature, humidity, ultraviolet rays, cosmetics, disease, stress, eating habits, etc. Therefore, various functions of the skin (prevention of loss of moisture etc. from the living body, constant body temperature) Functions that control the maintenance of the body, physical and chemical stimulation from the outside world and the function of protecting the body from various bacteria, the function of maintaining the elasticity of the skin and determining the surface morphology, etc.), the aging of the skin, etc. Trouble occurs.

Further, as described above, skin troubles are caused by changes in the external environment (seasonal changes, ultraviolet rays, etc.), and changes in physiological functions due to aging and diseases, and the functions of skin tissues caused by factors inside and outside the body. In addition to abnormalities, they are caused by skin thickening, parakeratosis, and the like induced by these.

[0004] The main attempts to prevent and improve such skin troubles are to apply a synthetic or natural moisturizing component to prevent drying of the skin and to enhance the moisturizing ability of the skin, and to apply a blood circulation promoter to promote blood circulation. And other methods have been developed.

[0005] That is, a medicated skin external preparation or cosmetic containing moisturizers such as free amino acids, organic acids, urea, inorganic ions, polysaccharides such as hyaluronic acid, animal and plant extracts, vitamins and their derivatives, peptides, proteins and the like. Attempts have been made to prevent and ameliorate the above-mentioned skin problems by using ingredients.

[0006] In addition, skin spots and freckles are generally activated by melanocytes due to irritation caused by exposure to ultraviolet rays from sunlight, hormonal abnormalities, or genetic factors. It is thought to be caused by abnormal deposition.

Conventionally, to prevent such skin spots and freckles, L-ascorbic acid and its derivatives,
Hydroquinone, arbutin, kojic acid, cysteine,
BACKGROUND ART Cosmetics containing a melanin inhibitor such as glutathione or a placenta extract that acts on keratinocytes to produce a whitening effect are used.

[0008] Wrinkles, which are one of the skin problems, are also cited as one of the skin cosmetic problems, and are known to be worsened by drying of the skin and the influence of ultraviolet rays. The mechanism of the development of this wrinkle is still largely unknown, but at the epidermal level of the skin, dryness and a decrease in the moisturizing power of the stratum corneum,
At the dermis level, it is considered that long-term ultraviolet irradiation affects the aging of the skin, and the elastic fibers are degraded, that is, the elasticity is reduced due to the collapse of the elastin network.

Conventionally, various compositions and methods have been proposed for suppressing or treating wrinkles due to such aging effects (JP-A-50-31051, JP-A-62-31051). No. 185005, JP-A-62-5025
46, JP-A-2-72157, JP-A-2-72157
288822).

On the other hand, these cosmetics are generally used for the prevention and improvement of skin troubles occurring on the face and parts of the body, and are incorporated in ointments or creams, packs, emulsions, lotions and the like. Have been. However, skin troubles occur throughout the body, and it is practically difficult to apply them to the whole body. Therefore, the prevention and improvement of wrinkle formation on the face and the whole body by a simple method on a daily basis,
Prevention and improvement of spots and freckles, prevention and improvement of conspicuous pores and acne caused by bacteria and abnormal keratinization, moisturization of the skin, prevention and improvement of rough skin, skin peeling, loss of elasticity, dullness of complexion, etc. There have been proposed methods of using as a cleaning agent in order to obtain a preventive / improving effect (JP-A-1-275524, JP-A-2-14296, JP-A-6-279).
No. 789, Japanese Unexamined Patent Application Publication No. H8-73895,
No. 1-508613). However, all of these are difficult to effectively adhere to the skin, and have not exhibited satisfactory skin activating effects.

[0011]

Accordingly, the present invention overcomes such drawbacks that it is difficult to apply the composition to the face and the whole body and improves the adhesion of the skin active ingredient, thereby improving the skin active effect. It is an object of the present invention to provide a cleaning composition excellent in water resistance.

[0012]

Means for Solving the Problems and Embodiments of the Invention The present inventors have conducted intensive studies to develop a detergent having an excellent skin activating effect, and as a result, have found that a surfactant, a skin active component, an acrylic polymer and / or Alternatively, the present inventors have found that the use of a detergent composition comprising a combination with a cellulosic polymer at the time of washing a face, taking a bath, and the like has an extremely good skin activating effect, and have completed the present invention.

That is, the present invention provides (A) a surfactant,
(B) a skin active ingredient, (C) an acrylic polymer and / or
Another object of the present invention is to provide a detergent composition containing a cellulosic polymer.

Hereinafter, the present invention will be described in more detail.
As described above, the cleaning composition of the present invention contains (A) a surfactant, (B) a skin active ingredient, (C) an acrylic polymer and / or a cellulose polymer as essential components.

Component (A) As the component (A), those commonly used in detergents, such as anionic surfactants, nonionic surfactants, amphoteric surfactants and semipolar surfactants, can be used. Can be used.

[Anionic surfactant] As the anionic surfactant, a carboxylate, a sulfonate, a sulfate, an alkyl phosphate or the like can be used. Further, the above-mentioned anionic surfactants can be used alone or in combination of two or more.

As the carboxylate, in addition to C ₁₂ -C ₁₈ saturated and unsaturated fatty acids, a mixture thereof such as coconut oil fatty acid, hydrogenated coconut oil fatty acid, palm oil fatty acid, hydrogenated palm oil fatty acid, tallow fatty acid, and hydrogenated fatty acid Potassium salts such as tallow fatty acid, sodium salts, triethanolamine salts, fatty acid soaps such as ammonium salts, alkyl ether carboxylates, N-acyl sarcosine salts, N-acyl glutamates and the like, for example, potassium laurate, Sodium laurate, triethanolamine myristate, sodium N-lauroylsarcosine, sodium N-lauroylglutamate, N-lauroylmethyl-
β-alanine sodium, mono-N-lauryl tartaramide triethanolamine, potassium mono-N-lauryl malate, and the like. The fatty acid soap may be used as it is, or may be used after neutralizing the fatty acid and the alkali separately in the detergent composition.

Examples of the sulfonate include N-acylaminosulfonate, polyoxyethylene sulfosuccinate, and the like. N-cocoylmethyltaurine sodium, N-lauroylmethyltaurine sodium, N-myristoylmethyltaurine triethanolamine And sodium polyoxyethylene alkyl sulfosuccinate.

The sulfates include higher alkyl sulfates and polyoxyethylene alkyl ether sulfates.

Examples of the alkyl phosphate salt include triethanolamine monolauryl phosphate, sodium monolauryl phosphate and triethanolamine monomyristyl phosphate.

Among the above anionic surfactants, carboxylate and the like are preferable from the viewpoint of feeling of use. More preferably, sodium N-lauroylglutamate, sodium N-lauroylmethyl-β-alanine, mono-N-
It is potassium lauryl malate and potassium coconut oil.

[Nonionic surfactant] Examples of the nonionic surfactant include polyoxyalkylene addition type, polyoxypropylene / polyoxyethylene addition type, mono- or diethanolamide type, sorbitan fatty acid ester, glycerin fatty acid ester, and sucrose. Fatty acid esters, alkyl saccharides, N-polyhydroxyalkyl fatty acid amides and the like can be used.

Among the above-mentioned nonionic surfactants, polyoxyalkylene addition type, mono- or diethanolamide type, glycerin fatty acid ester, sucrose fatty acid ester and the like are preferable from the viewpoint of feeling of use and stability. More preferably, polyoxyalkylene addition type, diethanolamide type, and glycerin fatty acid ester are used. The above nonionic surfactants can be used alone or in combination of two or more.

[Amphoteric and semipolar surfactants] As the amphoteric surfactant and the semipolar surfactant, imidazoline type,
Amidoamino acid salts, carbobetaine type, alkylbetaine type, alkylamidobetaine type, alkylsulfobetaine type, alkylhydroxysulfobetaine type, acyl tertiary amine oxide, acyl tertiary phosphone oxide and the like can be used.

Among the amphoteric surfactants and semipolar surfactants described above, alkyl betaine type and acyl tertiary amine oxides are preferable from the viewpoint of foaming properties, and desalted from the viewpoint of stability. Is preferred. The amphoteric surfactants and semipolar surfactants described above can be used alone or in combination of two or more.

The surfactant (A) can be used alone or in combination of two or more.
It is preferable to mix 90 mass%. If the amount is less than 1% by mass, a sufficient cleansing effect on the skin cannot be obtained.
If the amount exceeds the mass%, the stability may be reduced. More preferably, it is 5 to 90% by weight.

(B) Component The skin active component used as the component (B) refers to any activity on the skin, for example, whitening effect, wrinkle prevention / improvement effect, skin softening effect, anti-inflammatory effect, antioxidant effect, blood circulation. It has a promoting effect, a sebum secretion suppressing effect, and the like. There is no particular limitation as long as it is used in ordinary cosmetics, and for example, components and plant extracts generally used as whitening agents, antibacterial agents, anti-inflammatory agents, sebum secretion inhibitors, cell activators, ultraviolet protective agents, and the like, Examples include amino acids and salts thereof.

Among the component (B) used in the present invention, examples of the whitening agent include ellagic acid compounds, L-ascorbic acid and its derivatives, hydroquinone derivatives, kojic acid and its derivatives, placental extracts and the like. .

Among these whitening agents, ellagic acid compounds and arbutin are preferred, and ellagic acid compounds are more preferred.

These whitening agents can be used alone or in combination of two or more. From the viewpoint of whitening effect and feeling of use, it is preferable to add 0.001 to 30% by mass in the whole composition. Preferably 0.01 to 10% by mass, particularly 0.01 to 5% by mass, not only obtains a sufficient whitening effect but is more excellent in use feeling and stability.

Among the component (B) used in the present invention, examples of the wrinkle preventive / ameliorating agent include coenzyme A [C ₂₁
H ₃₆ N ₇ O ₁₆ P ₃ S, coenzyme A, hereinafter simply referred to as “CoA”] and salts thereof (JP-A-50-31051), oxidized CoA and salts thereof (JP-A-2-49729). , Retinoic acid, α-hydroxy acid, retinol (vitamin A) and the like.

Of these agents for preventing and improving wrinkles, oxidized CoA and salts thereof and α-hydroxy acids are preferred, and oxidized CoA and salts thereof are more preferred.

These wrinkle preventing / ameliorating agents may be used alone or in combination.
More than one kind can be used in combination, and from the viewpoint of the effect of preventing and improving wrinkles and feeling of use, the amount is preferably 0.001 to 5% by mass, more preferably 0.01% by mass, based on the total amount of the detergent composition. If the content is less than 0.001% by mass, the effect of preventing skin aging that is the object of the present invention may not be exhibited. Is not exhibited.

Among the components (B) used in the present invention, antibacterial agents include, for example, pyrocton olamine, sulfur, triclosan, trichlorocarbanilide, chlorhexidine hydrochloride, benzalkonium chloride, benzethonium chloride,
Cetylpyridinium chloride, benzalkonium alkylphosphate, isopropylmethylphenol, benzoic acid, Photosensitizer No. 201, resorcin, and the like. Of these, pyrocton olamine, triclosan and isopropylmethylphenol are particularly preferred. When these antibacterial agents are blended, 0.0001 to 5% by mass in the total composition,
Especially 0.01 to 2% by mass, more preferably 0.05 to 2% by mass.
It is preferable that the compounding by mass is high in that a high antibacterial effect against bacteria existing in the skin and an effect of preventing and improving acne can be obtained.

Of the component (B) used in the present invention, examples of the anti-inflammatory agent include glycyrrhizic acid and salts thereof,
Glycyrrhetinic acid and its salts, alkyl glycyrrhetinate, isopropylaminocaproic acid and its salts, allantoin, lysozyme chloride, guaiazulene, methyl salicylate, γ-oryzanol and the like, among these, glycyrrhizic acid and its salts, stearyl glycyrrhetinate is preferred. .

These anti-inflammatory agents can be used alone or in combination of two or more.
It is preferable to mix 5 mass%, especially when 0.01 to 2 mass% is blended, a high anti-inflammatory effect is obtained, and it is preferable in terms of feeling of use and stability.

Among the components (B) used in the present invention, examples of the sebum secretion inhibitor include anti-male, which is described in “Fragrance Journal No. 10 (1994)” and is generally used as a sebum secretion inhibitor. Hormone preparations,
Crude drug extracts, astringents, and other components can be used.

These sebum secretion inhibitors are contained in the total composition in an amount of 0.0001 to 5% by mass, particularly 0.01 to 2% by mass, and more preferably 0.05 to 2% by mass. ) Is preferable because a high sebum secretion inhibitory effect can be obtained.

Among the component (B) used in the present invention, the ultraviolet ray protective agent is not particularly limited, and any of commonly used ultraviolet ray scattering agents, oil-soluble ultraviolet ray absorbents and water-soluble ultraviolet ray absorbents can be suitably used. Can be used. Among these, examples of the ultraviolet light scattering agent include titanium oxide, zinc oxide, iron oxide, cerium oxide, zirconium oxide and the like, which are those which have been surface-treated with silicone, metal soap, N-acylglutamic acid, etc. Is also good. Their shape, size and form are not particularly limited, and they may be used in the form of a sol or the like.

When these ultraviolet ray protective agents are blended, 0.1 to 40% by mass, preferably 0.1% by mass in the total composition.
-30% by mass, more preferably 0.2-20% by mass.

Among the component (B) used in the present invention, plant extracts include coleus, aerial parts of coleus, usbnia oi, abrico do para, derbilia, katsaba, filantas, carophilis, aloe ECW,
Mirabu Armor, Ginseng, Birch, Birch Sap, Bodaiju, Chimpi, Ginkgo, Oak, Rosemary, Melissa, Kumaseba, Ezocogi, Licorice Flavonoid, Inuengju, Yaeyamashitan, Clara, Juniper, Melon Root, Cakkon, Gigartina, Kukukuronori, Oka Extracts such as egis, mace, sage, eucalyptus, and buttons.

These plant extracts are dried or pulverized without drying at least one part of the whole plant of each plant or its leaves, bark, roots, branches, etc., and then dried at room temperature or under heating. ,
It can be obtained by extracting with a solvent or by using an extraction device such as a Soxhlet extractor. Here, the solvent used is not particularly limited.
Known solvents such as secondary alcohols, polyhydric alcohols, esters, hydrocarbons, ethers, and acetone,
These solvents can be used alone or in combination of two or more.

These plant extracts can be used alone or in combination of two or more. It is preferable that the plant extract is incorporated in the total composition in an amount of 0.0001 to 20% by mass in terms of dry solid content. 0.0001 to 10% by mass, further 0.00
When added in an amount of from 1 to 5% by mass, the moisturizing effect, the effect of preventing and improving the formation of wrinkles, the effect of preventing and improving the roughness of the skin, the effect of preventing and improving skin swelling, loss of elasticity, dullness of complexion, and the prevention of spots and freckles. It is preferable because an improving effect, an antibacterial effect, a cell activating effect, an astringent effect, an active oxygen removing effect, and the like can be obtained, and the feeling and stability are excellent.

Among the component (B) used in the present invention, examples of the amino acid or a salt thereof include tryptophan, lysine, arginine, histidine, glutamic acid,
Aspartic acid, alanine, glycine, proline, valine, methionine, cysteine, hydroxyproline,
Examples include phenylalanine, tyrosine, trimethylglycine, sodium glutamate, cysteine hydrochloride, histidine phosphate, lysine hydrochloride, ornithine acetate, tryptophan hydrochloride, arginine-glutamate, lysine-aspartate, and ε-aminocaproic acid. Of these, proline and trimethylglycine are preferred.

These amino acids or salts thereof can be used singly or in combination of two or more, and are preferably incorporated in the entire composition in an amount of 0.0001 to 15% by mass, particularly preferably 0.001 to 10% by mass. Mixing is preferable because it is excellent in moisturizing effect, prevention and improvement effect of wrinkle formation, prevention and improvement effect of rough skin, feeling of use and stability.

As the skin active ingredient (B), the above-mentioned various ingredients can be used alone or in combination of two or more, and the total amount is 0.0001 to 50% by mass in the total composition.
Is more preferable, and more preferably 0.01 to 40% by mass.

Component (C): acrylic polymer and / or
Is a carboxyvinyl polymer, polyacrylic acid, methacrylic acid.
Acrylic ester copolymers, methacrylic acid / acrylamide copolymers and the like can be mentioned.

Examples of the alkaline agent for neutralizing and gelling the acrylic acid polymer include inorganic bases such as sodium hydroxide, potassium hydroxide and ammonium hydroxide and organic acids such as triethanolamine and L-arginine. Salts. These alkaline agents are used in an amount of 0.1 to 3 parts by weight, especially 0.1 to 3 parts by weight, based on 1 part by weight of the acrylic acid polymer.
It is preferable to use 5 to 2 parts by weight.

Of the above acrylic polymers, methacrylic acid / acrylic acid ester copolymers are preferable from the viewpoint of liquidity, and in particular, a water-soluble vinyl polymer having a carboxylic acid group such as acrylic acid or methacrylic acid and a carbon chain having a carbon chain length. It is composed of two or more different acrylates or methacrylates and has an average molecular weight of 5,000 to 20.
Range of 10,000, the molar ratio of the hydrophilic group to the hydrophobic group is 1.5 to 0.2.
5 is desirable.

Examples of the cellulosic polymer include hydroxypropylmethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, cationized cellulose, carboxymethylcellulose and the like.

Among the above-mentioned cellulose polymers, hydroxypropylmethylcellulose, hydroxyethylcellulose and carboxymethylcellulose are preferable from the viewpoint of liquid properties.

The acrylic polymer and the cellulose polymer as the component (C) may be used alone or in combination of two or more. It is desirable to use one or more of each selected from an acrylic polymer and a cellulose polymer from the viewpoint of the effect of the skin active ingredient. The mixing ratio of the acrylic polymer and the cellulosic polymer is preferably 500: 1 to 1:50 as a mass ratio.
0, more preferably 100: 1 to 1: 100. The compounding amount is preferably 0.1 to the total amount of the composition.
The content is selected from the range of from 0.01 to 5% by mass, more preferably from 0.05 to 3% by mass. If it exceeds 300, it is not preferable from the viewpoint of feeling of use and stability.

The cleansing composition of the present invention can provide a good skin activating effect as a skin cleansing agent, and is prepared and applied as a body soap, a cleansing gel, a face wash cream, a liquid face wash, a soap, a cleansing milk, and the like. The dosage form can be appropriately selected from liquids, emulsions, creams, foams, solids, and the like. The cleaning composition of the present invention contains optional components according to the purpose, dosage form, and the like. It can be appropriately compounded as long as the effects of the invention are not hindered. Optional components include, for example, higher alcohols, oils such as silicone oil, lanolin derivatives, protein derivatives, vitamins, bactericides, preservatives, pH adjusters, antioxidants, pigments, fragrances,
Pigment, water-insoluble polymer powder such as nylon and polyethylene, and the like. The optional components are not limited to these, and the amount of these optional components can be a normal amount within a range that does not impair the effects of the present invention.

[0054]

The cleaning composition of the present invention improves the adhesiveness of the skin active ingredient and gives a high skin active effect.

[0055]

EXAMPLES The present invention will be described below in detail with reference to examples and comparative examples, but the present invention is not limited to the following examples. In the following examples,% indicates mass%.

[Examples 1 to 16, Comparative Examples 1 to 4]
A cleaning composition having the formulation shown in No. 3 was prepared, and its skin activity was evaluated by the following method. The results are shown in Tables 1 to 3.

<Whitening effect> Male panel 2 of 20-39 years old
Twice a day after UV-B irradiation by 0 people, continuous 4
After being separately used on the left and right back by the 0-day half body method, the degree of pigmentation was examined. The degree of pigmentation was scored according to the following criteria, and the average was determined to determine the effect of improving pigmentation. Pigmentation score 3 ... Little pigmentation observed 2 ... Slight pigmentation observed 1 ... Moderate pigmentation observed 0 ... Strong pigmentation observed Pigmentation improvement effect judgment ◎ ... Average 2 points or more ○ ... Average value of 1.5 points or more and less than 2 points △: Average value of 1 point or more and less than 1.5 points ×: Average value of less than 1 point

<Wrinkle-reducing effect> Twenty 35-55-year-old female panels were used on the left and right faces twice a day for three consecutive months by the half-face method, and the degree of fine wrinkle improvement was examined. The degree of improvement was scored according to the following criteria, and the average value was determined to determine the effect of improving wrinkles. Wrinkle improvement effect score 3: Improvement effect is significant 2 ... Improvement effect is effective 1 ... Improvement effect is slightly effective 0 ... Improvement effect is ineffective Judgment of wrinkle improvement effect ◎ ... Average value 2 points or more ○ ... Average value of 1.5 points or more and less than 2 points △: Average value of 1 point or more and less than 1.5 points ×: Average value of less than 1 point

<Effects of Acne Improvement> Twenty daily 20-39-year-old female panels were used on the left and right faces separately by the half-face method for 10 consecutive days, and the degree of acne improvement was examined. The degree of improvement was scored according to the following criteria, and the average value was determined to determine the effect of improving acne. Acne improvement effect score 3: Improvement effect is significant 2 ... Improvement effect is effective 1 ... Improvement effect is slightly effective 0 ... Improvement effect is ineffective Acne improvement effect judgment ◎ ... Average value 2 points or more ○ ... Average value of 1.5 points or more and less than 2 points △: Average value of 1 point or more and less than 1.5 points ×: Average value of less than 1 point

[0060]

[Table 1]

[0061]

[Table 2]

[0062]

[Table 3] * 1 Carbopol 941, manufactured by BF Goodrich * 2 Average molecular weight 1,000,000 * 3 Average molecular weight 1,000,000, molar ratio (hydrophilic group / hydrophobic group =
0.5) * 4 Average molecular weight 2,000,000, molar ratio (hydrophilic group / hydrophobic group =
0.5) * 5 MERQUAT PLUS 3330, manufactured by Calgon Co., Ltd. * 6 HEC Daicel SP550, manufactured by Daicel Chemical Industries, Ltd. * 7 Metros 60SH-4000, manufactured by Shin-Etsu Chemical Co., Ltd. * 8 CMC Daicel 1180, manufactured by Daicel Chemical Industries, Ltd. * 9 Leogard KGP, manufactured by Lion * 10 Nisso HPC, manufactured by Nippon Soda

The following cleaning compositions also provide good skin activating effects.

[0064]

[Table 4] * 2 Average molecular weight 1,000,000 * 6 HEC Daicel SP550, manufactured by Daicel Chemical Industries * 7 Metroze 60SH-4000, manufactured by Shin-Etsu Chemical Co., Ltd.

[0065]

[Table 5] * 3 Average molecular weight 1,000,000, molar ratio (hydrophilic group / hydrophobic group =
0.5) * 7 Metros 60SH-4000, manufactured by Shin-Etsu Chemical Co., Ltd.

[0066]

[Table 6] * 3 Average molecular weight 1,000,000, molar ratio (hydrophilic group / hydrophobic group =
0.5) * 5 MERQUAT PLUS 3330, manufactured by Calgon * 9 Leogard KGP, manufactured by Lion

[0067]

[Table 7] * 1 Carbopol 941, manufactured by BF Goodrich * 8 CMC Daicel 1180, manufactured by Daicel Chemical Industries * 10 Nisso HPC, manufactured by Nippon Soda

[0068]

[Table 8] * 7 Metros 60SH-4000, manufactured by Shin-Etsu Chemical Co., Ltd. * 8 CMC Daicel 1180, manufactured by Daicel Chemical Industries, Ltd.

[0069]

[Table 9] * 4 Average molecular weight 2,000,000, molar ratio (hydrophilic group / hydrophobic group =
0.5) * 7 Metros 60SH-4000, manufactured by Shin-Etsu Chemical Co., Ltd.

[0070]

[Table 10] * 1 Carbopol 941, manufactured by BF Goodrich

[0071]

[Table 11] * 3 Average molecular weight 1,000,000, molar ratio (hydrophilic group / hydrophobic group =
0.5) * 10 Nisso HPC, manufactured by Nippon Soda Co., Ltd.

[0072]

[Table 12] * 1 Carbopol 941, manufactured by BF Goodrich * 2 Average molecular weight 1,000,000 * 6 HEC Daicel SP550, manufactured by Daicel Chemical Industries

[0073]

[Table 13] * 9 Leogard KGP, manufactured by Lion

Continued on the front page F term (reference) 4C083 AA112 AA122 AB032 AB242 AB442 AC022 AC122 AC132 AC182 AC242 AC302 AC312 AC342 AC392 AC402 AC422 AC432 AC442 AC542 AC562 AC582 AC642 AC662 AC712 AC782 AC792 AC812 AC842 AC852 AC902 AC912 AD042 AD091 AD09AD2 AD532 AD642 BB01 BB51 CC23 DD08 DD21 DD23 DD31 DD41 EE12 EE14 4H003 AB05 AB06 AB08 AB09 AC03 AC08 AD04 BA12 DA02 EB11 EB30 EB42 EB43 EC03 ED02 FA33 FA34

Claims (1)

[Claims] 1. A cleaning composition comprising (A) a surfactant, (B) a skin active ingredient, (C) an acrylic polymer and / or a cellulosic polymer.