JP2000319085A - Gas generating agent composition - Google Patents
Gas generating agent compositionInfo
- Publication number
- JP2000319085A JP2000319085A JP11125012A JP12501299A JP2000319085A JP 2000319085 A JP2000319085 A JP 2000319085A JP 11125012 A JP11125012 A JP 11125012A JP 12501299 A JP12501299 A JP 12501299A JP 2000319085 A JP2000319085 A JP 2000319085A
- Authority
- JP
- Japan
- Prior art keywords
- nitrate
- bitetrazole
- gas generating
- basic
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06D—MEANS FOR GENERATING SMOKE OR MIST; GAS-ATTACK COMPOSITIONS; GENERATION OF GAS FOR BLASTING OR PROPULSION (CHEMICAL PART)
- C06D5/00—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets
- C06D5/06—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets by reaction of two or more solids
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B31/00—Compositions containing an inorganic nitrogen-oxygen salt
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Air Bags (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、自動車等のエアバ
ック拘束システムに適したガス発生剤組成物、その成型
体及びそれらを用いたエアバック用インフレータに関す
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a gas generant composition suitable for an airbag restraint system of an automobile or the like, a molded product thereof, and an airbag inflator using the same.
【０００２】[0002]
【従来の技術】自動車における乗員保護装置としてのエ
アバッグ用ガス発生剤としては、従来からアジ化ナトリ
ウムを用いた組成物が多用されてきた。しかし、アジ化
ナトリウムの人体に対する毒性[ＬＤ50（oral−rat）＝
２７ｍｇ／ｋｇ]や取扱い時の危険性が問題視され、そ
れに替わるより安全ないわゆる非アジド系ガス発生剤組
成物として、各種の含窒素有機化合物を含むガス発生剤
組成物が開発されている。2. Description of the Related Art Compositions using sodium azide have been frequently used as gas generating agents for airbags as occupant protection devices in automobiles. However, the toxicity of sodium azide to the human body [LD 50 (oral-rat) =
27 mg / kg] and the danger at the time of handling are regarded as problems, and gas generator compositions containing various nitrogen-containing organic compounds have been developed as safer so-called non-azide gas generator compositions.
【０００３】例えば、米国特許４，９０９，５４９号に
は、水素を含むテトラゾール、トリアゾール化合物と酸
素含有酸化剤との組成物が開示されている。米国特許
４，３７０，１８１号には、水素を含まないビテトラゾ
ールの金属塩と酸素を含まない酸化剤とからなるガス発
生剤組成物が開示されている。米国特許４，３６９，０
７９号には、水素を含まないビテトラゾールの金属塩と
アルカリ金属硝酸塩、アルカリ金属亜硝酸塩、アルカリ
土類金属硝酸塩、アルカリ土類金属亜硝酸塩及びこれら
の混合物からなるガス発生剤組成物が開示されている。
米国特許５，５４２，９９９号には、ＧＺＴ，ＴＡＧ
Ｎ，ＮＧ（ニトログアニジン）、ＮＴＯ等の燃料、塩基
性硝酸銅、有毒ガスを低減する触媒とクーラント剤から
なるガス発生剤が開示されている。特開平１０−７２２
７３号には、ビテトラゾール金属塩、ビテトラゾールア
ンモニウム塩、アミノテトラゾールと硝酸アンモニウム
からなるガス発生剤が開示されている。[0003] For example, US Pat. No. 4,909,549 discloses a composition of a tetrazole or triazole compound containing hydrogen and an oxygen-containing oxidizing agent. U.S. Pat. No. 4,370,181 discloses a gas generant composition comprising a hydrogen-free metal salt of bitetrazole and an oxygen-free oxidizing agent. US Patent 4,369,0
No. 79 discloses a gas generating composition comprising a hydrogen-free metal salt of bitetrazole and an alkali metal nitrate, an alkali metal nitrite, an alkaline earth metal nitrate, an alkaline earth metal nitrite and a mixture thereof. ing.
U.S. Pat. No. 5,542,999 includes GZT, TAG
A gas generating agent comprising a fuel such as N, NG (nitroguanidine) or NTO, basic copper nitrate, a catalyst for reducing toxic gas, and a coolant is disclosed. JP-A-10-722
No. 73 discloses a gas generator comprising a bitetrazole metal salt, a bitetrazole ammonium salt, and an aminotetrazole and ammonium nitrate.
【０００４】[0004]
【発明が解決しようとする課題】しかしながら、上記の
非アジド系ガス発生剤組成物は、燃焼温度、燃焼速度、
相移転、一酸化炭素及び窒素酸化物の生成量、ガス発生
効率などに問題がある。例えば、前記の米国特許４，３
６９，０７９号のガス発生剤組成物は、燃焼温度が高
く、実際に使われると、大量のクーラントが必要とな
る。米国特許５，５４２，９９９号の組成物は、燃焼速
度が小さく、短時間で完全燃焼できない恐れがある。特
開平１０−７２２７３号のガス発生剤は、使用温度範囲
において硝酸アンモニウムの相転移による形状変化によ
って、ガス発生剤成型体が破損し、安定的に燃焼できな
くなる。However, the above-mentioned non-azide gas generant composition has a combustion temperature, a combustion speed,
There are problems with phase transfer, the production amount of carbon monoxide and nitrogen oxide, gas generation efficiency, and the like. For example, the above-mentioned U.S. Pat.
No. 69,079 has a high combustion temperature and requires a large amount of coolant when actually used. The composition of U.S. Pat. No. 5,542,999 has a low burning rate and may not be completely burned in a short time. In the gas generating agent disclosed in Japanese Patent Application Laid-Open No. H10-72273, the molded product of the gas generating agent breaks due to a change in shape due to the phase transition of ammonium nitrate in the operating temperature range, and cannot be stably burned.
【０００５】従って、本発明の課題は燃焼温度が低く、
燃焼速度が大きく、一酸化炭素及び窒素酸化物の生成量
が少なく、燃焼安定性の優れたガス発生剤組成物、その
成型体及びそれらを用いたエアバック用インフレータを
提供することにある。Accordingly, an object of the present invention is to reduce the combustion temperature,
An object of the present invention is to provide a gas generant composition having a high combustion rate, a small production amount of carbon monoxide and nitrogen oxides, and excellent combustion stability, a molded product thereof, and an airbag inflator using them.
【０００６】[0006]
【課題を解決するための手段】本発明は、（ａ）燃料で
あるビテトラゾール化合物及び（ｂ）酸化剤である塩基
性金属硝酸塩を含有するガス発生剤組成物を提供する。
また本発明は、（ａ）燃料であるビテトラゾール化合
物、（ｂ）酸化剤である塩基性金属硝酸塩及び（ｃ）バ
インダーを含有するガス発生剤組成物を提供する。ま
た、本発明は、上記のガス発生剤組成物から得られる単
孔円柱状、多孔円柱状又はペレット状の成型体を提供す
る。さらに、本発明は、上記のガス発生剤組成物及び成
型体を用いたエアバック用インフレータを提供する。SUMMARY OF THE INVENTION The present invention provides a gas generating composition containing (a) a bitetrazole compound as a fuel and (b) a basic metal nitrate as an oxidizing agent.
The present invention also provides a gas generating composition containing (a) a bitetrazole compound as a fuel, (b) a basic metal nitrate as an oxidizing agent, and (c) a binder. Further, the present invention provides a single-hole cylindrical, porous cylindrical or pellet-shaped molded article obtained from the above-mentioned gas generating composition. Further, the present invention provides an inflator for an air bag using the above-described gas generating composition and a molded article.
【０００７】[0007]
【発明の実施の形態】本発明で用いる（ａ）成分の燃料
であるビテトラゾール化合物は、一分子中の窒素原子の
含有量が高く、毒性も低く、さらに（ｂ）成分と組み合
わせた場合には燃焼速度が大きくなるので好ましい。ビ
テトラゾール化合物としては、ビテトラゾールカリウム
塩、ビテトラゾールナトリウム塩、ビテトラゾールマグ
ネシウム塩、ビテトラゾールカルシウム塩、ビテトラゾ
ール銅塩等のビテトラゾール金属塩、ビテトラゾールア
ンモニウム塩及びビテトラゾールメラミン塩から選ばれ
る１種以上が挙げられる。これらの中でも、窒素原子含
有量が８１．４重量％、ＬＤ50（oral−rat）が２００
０ｍｇ／ｋｇであり、燃焼効率が良いため、ビテトラゾ
ールアンモニウム塩が好ましい。ここでいうビテトラゾ
ール化合物には、２つのテトラゾール環の５−５’、１
−５’結合体を含み、価格と入手の容易さから５−５’
体が好ましい。BEST MODE FOR CARRYING OUT THE INVENTION The bitetrazole compound used as the fuel of the component (a) used in the present invention has a high content of nitrogen atoms in one molecule, low toxicity, and when combined with the component (b). Is preferred because the burning rate is increased. The bitetrazole compound is selected from bitetrazole potassium, bitetrazole sodium, bitetrazole magnesium, bitetrazole calcium, bitetrazole copper, and other bitetrazole metal salts, bitetrazole ammonium salts, and bitetrazole melamine salts. Species or more. Among these, the nitrogen atom content is 81.4% by weight, and the LD 50 (oral-rat) is 200%.
Because of 0 mg / kg and good combustion efficiency, a bitetrazol ammonium salt is preferable. The bitetrazole compound referred to herein includes 5-5 ′, 1
Includes -5 'conjugate, 5-5' for price and availability
The body is preferred.
【０００８】本発明で用いる（ｂ）成分の酸化剤である
塩基性金属硝酸塩としては、塩基性硝酸銅、塩基性硝酸
コバルト、塩基性硝酸亜鉛、塩基性硝酸マンガン、塩基
性硝酸鉄、塩基性硝酸モリブデン、塩基性硝酸ビスマス
及び塩基性硝酸セリウムから選ばれる１種以上が挙げら
れ、これらの中でも塩基性硝酸銅が好ましい。The basic metal nitrate which is the oxidizing agent of the component (b) used in the present invention includes basic copper nitrate, basic cobalt nitrate, basic zinc nitrate, basic manganese nitrate, basic iron nitrate, and basic iron nitrate. One or more selected from molybdenum nitrate, basic bismuth nitrate and basic cerium nitrate are mentioned, and among these, basic copper nitrate is preferable.
【０００９】塩基性硝酸銅は、酸化剤としての硝酸アン
モニウムに比べると、使用温度範囲において相転移がな
く、融点が高いので、熱安定性が優れている。さらに、
塩基性硝酸銅は、ガス発生剤の燃焼温度を低くするよう
に作用するので、窒素酸化物の生成量も少なくできる。[0009] Compared with ammonium nitrate as an oxidizing agent, basic copper nitrate has no phase transition in the operating temperature range and has a high melting point, and thus has excellent thermal stability. further,
Since basic copper nitrate acts to lower the combustion temperature of the gas generating agent, the amount of generated nitrogen oxides can be reduced.
【００１０】本発明のガス発生剤組成物を（ａ）成分及
び（ｂ）成分の２成分系にする場合の各成分の含有量は
下記のとおりである。（ａ）成分の含有量は５〜６０重
量％が好ましく、１５〜５５重量％がより好ましい。
（ｂ）成分の含有量は４０〜９５重量％が好ましく、４
５〜８５重量％がより好ましい。また、２成分系のガス
発生剤組成物の好ましい実施形態としては、（ａ）成分
としてビテトラゾールアンモニウム塩を１５〜３５重量
％及び（ｂ）成分として塩基性硝酸銅を６５〜８５重量
％含有するのものが挙げられる。When the gas generant composition of the present invention is made into a two-component system consisting of the component (a) and the component (b), the content of each component is as follows. The content of the component (a) is preferably 5 to 60% by weight, more preferably 15 to 55% by weight.
The content of the component (b) is preferably 40 to 95% by weight,
More preferably, it is 5 to 85% by weight. In a preferred embodiment of the two-component gas generating composition, the component (a) contains 15 to 35% by weight of a bitetrazol ammonium salt and the component (b) contains 65 to 85% by weight of a basic copper nitrate. To do.
【００１１】本発明で用いる（ｃ）成分のバインダーと
しては、カルボキシメチルセルロースナトリウム塩、カ
ルボキシメチルセルロースカリウム塩、酢酸セルロー
ス、カルボキシメチルセルロース、カルボキシメチルセ
ルロースアンモニウム塩、ポリアクリルアミド、ポリア
クリルアミドのアミノ化物、ポリアクリルヒドラジド、
アクリルアミド・アクリル酸金属塩共重合体、ポリアク
リルアミド・ポリアクリル酸エステル化合物の共重合
体、ポリビニルアルコール、グアガム及び水酸化アルミ
ニウムから選ばれる１種以上が挙げられる。The binder of component (c) used in the present invention includes carboxymethylcellulose sodium salt, carboxymethylcellulose potassium salt, cellulose acetate, carboxymethylcellulose, carboxymethylcellulose ammonium salt, polyacrylamide, aminated polyacrylamide, polyacrylhydrazide,
One or more selected from acrylamide / acrylic acid metal salt copolymer, polyacrylamide / polyacrylate compound copolymer, polyvinyl alcohol, guar gum, and aluminum hydroxide.
【００１２】ガス発生剤組成物の着火性を高める場合に
は、カルボキシメチルセルロースナトリウム塩及びカリ
ウム塩が好ましく、これらの中でもナトリウム塩がさら
に好ましい。In order to enhance the ignitability of the gas generating composition, sodium and potassium salts of carboxymethylcellulose are preferable, and among them, the sodium salt is more preferable.
【００１３】本発明のガス発生剤組成物を（ａ）〜
（ｃ）成分の３成分系にする場合の各成分の含有量は下
記のとおりである。（ａ）成分の含有量は５〜６０重量
％が好ましく、１５〜５５重量％がより好ましい。
（ｂ）成分の含有量は４０〜９５重量％が好ましく、４
５〜８５重量％がより好ましい。（ｃ）成分の含有量は
（ａ）及び（ｂ）成分の合計量１００重量部に対して
０．１〜１５重量部が好ましく、０．５〜１０重量部が
より好ましい。[0013] The gas generating composition of the present invention comprises (a)
The content of each component when the three-component system (c) is used is as follows. The content of the component (a) is preferably 5 to 60% by weight, more preferably 15 to 55% by weight.
The content of the component (b) is preferably 40 to 95% by weight,
More preferably, it is 5 to 85% by weight. The content of the component (c) is preferably 0.1 to 15 parts by weight, more preferably 0.5 to 10 parts by weight, based on 100 parts by weight of the total of the components (a) and (b).
【００１４】また、３成分系のガス発生剤組成物の好ま
しい実施形態としては、（ａ）成分としてビテトラゾー
ルアンモニウム塩を１５〜３５重量％、（ｂ）成分とし
て塩基性硝酸銅を６５〜８５重量％、（ｃ）成分として
カルボキシメチルセルロースナトリウム塩を（ａ）及び
（ｂ）成分の合計量１００重量部に対して０．５〜１０
重量部を含有するものが挙げられる。In a preferred embodiment of the three-component gas generant composition, 15 to 35% by weight of a bitetrazole ammonium salt is used as the component (a), and 65 to 85% of the basic copper nitrate is used as the component (b). Carboxymethylcellulose sodium salt as the component (c) in an amount of 0.5 to 10 based on 100 parts by weight of the total amount of the components (a) and (b).
Those containing parts by weight are exemplified.
【００１５】本発明のガス発生剤組成物には、さらに
（ｄ）成分として燃焼調節剤を配合することができ、こ
の燃焼調節剤としては、酸化銅、酸化鉄、酸化亜鉛、酸
化コバルト及び酸化マンガンから選ばれる１種以上が挙
げられる。The gas generating composition of the present invention may further contain a combustion regulator as component (d). Examples of the combustion regulator include copper oxide, iron oxide, zinc oxide, cobalt oxide and One or more kinds selected from manganese are mentioned.
【００１６】（ｄ）成分の含有量は、（ａ）及び（ｂ）
成分又は（ａ）、（ｂ）及び（ｃ）成分の合計量１００
重量部に対して１〜１０重量部が好ましく、１〜５重量
部がより好ましい。The content of the component (d) is defined as (a) and (b)
Component or total amount of components (a), (b) and (c) 100
The amount is preferably 1 to 10 parts by weight, more preferably 1 to 5 parts by weight based on parts by weight.
【００１７】本発明のガス発生剤組成物は所望の形状に
成型することができ、単孔円柱状、多孔円柱状又はペレ
ット状の成型体にすることができる。これらの成型体
は、ガス発生剤組成物に水又は有機溶媒を添加混合し、
押出成型する方法（単孔円柱状、多孔円柱状の成型体）
又は打錠機等を用いて圧縮成型する方法（ペレット状の
成型体）により製造することができる。The gas generating composition of the present invention can be molded into a desired shape, and can be formed into a single-hole cylindrical, porous cylindrical or pellet-shaped molded body. These molded bodies, water or organic solvent is added to the gas generating composition and mixed,
Extrusion molding method (single-hole cylindrical, porous cylindrical molded body)
Alternatively, it can be produced by a compression molding method (a pellet-shaped molded body) using a tableting machine or the like.
【００１８】本発明のガス発生剤組成物又はそれから得
られる成型体は、例えば、各種乗り物の運転席のエアバ
ック用インフレータ、助手席のエアバック用インフレー
タ及びサイドインフレータに適用できる。The gas generating composition of the present invention or a molded article obtained therefrom can be applied to, for example, an airbag inflator for a driver's seat, a passenger's seat airbag inflator, and a side inflator for various vehicles.
【００１９】[0019]
【実施例】以下、実施例により本発明をさらに詳しく説
明するが、本発明はこれらにより限定されるものではな
い。なお、下記の表１〜表４中、ＢＨＴＮＨ3はビテト
ラゾールアンモニウム塩、ＢＨＴＫはビテトラゾールカ
リウム塩、ＢＣＮは塩基性硝酸銅、ＣＭＣＮａはカルボ
キシメチルセルロースナトリウム塩を示す。EXAMPLES The present invention will be described in more detail with reference to the following Examples, but it should not be construed that the invention is limited thereto. In the following Tables 1 to 4, BHTNH 3 represents bitetrazole ammonium salt, BHTK represents bitetrazole potassium salt, BCN represents basic copper nitrate, and CMCNa represents sodium carboxymethylcellulose.
【００２０】実施例１〜７、比較例１〜２ 表１に示す組成を有するガス発生剤組成物を製造した。
これらの組成物の理論計算に基づく燃焼温度、発生ガス
効率（単位ｍｏｌ／１００ｇは組成物１００ｇ当たりの
発生ガスのモル数を表す）、ＣＯ及びＮＯ発生量を表１
に示す。Examples 1 to 7 and Comparative Examples 1 and 2 Gas generating compositions having the compositions shown in Table 1 were produced.
Table 1 shows the combustion temperature, generated gas efficiency (unit mol / 100 g represents the number of moles of generated gas per 100 g of the composition), CO and NO generation amounts based on theoretical calculations of these compositions.
Shown in
【００２１】[0021]
【表１】 [Table 1]
【００２２】実施例１〜７のいずれの燃焼温度も比較例
１〜２と比べて十分低く、１９００Ｋ以下であり、さら
にＮＯ発生量の低減に効果のあることを示している。ま
た、ＣＯ及びＮＯ発生量については、ＣＯ発生量２×１
０-3ｍｏｌ／１００ｇ以下及びＮＯ発生量２×１０-4ｍ
ｏｌ／１００ｇ以下が同時に達成されなければ実用上許
容されないが、実施例１〜７はこの条件を満足している
ことが分かる。The combustion temperature of each of Examples 1 to 7 was sufficiently lower than that of Comparative Examples 1 and 2, and was 1900 K or less, indicating that the combustion temperature was effective in reducing the amount of generated NO. Also, regarding the CO and NO generation amounts, the CO generation amount 2 × 1
0 -3 mol / 100g or less and NO emission amount 2 × 10 -4 m
Unless ol / 100 g or less is simultaneously achieved, it is practically unacceptable, but it can be seen that Examples 1 to 7 satisfy this condition.
【００２３】実施例８〜１０ 表２に示す組成を有するガス発生剤組成物を製造した。
これらの組成物のＪＩＳ Ｋ４８１０−１９７９の火薬
類性能試験法に基づく摩擦感度と落槌感度を試験した。
結果を表２に示す。Examples 8 to 10 Gas generating compositions having the compositions shown in Table 2 were produced.
These compositions were tested for friction sensitivity and hammer sensitivity based on the explosive performance test method of JIS K4810-1979.
Table 2 shows the results.
【００２４】[0024]
【表２】 [Table 2]
【００２５】実施例１１〜１２ 表３に示す組成を有するガス発生剤組成物を製造した。
これらの組成物について、理学（株）製のＴＡＳ型示差
熱分析装置による融解温度、発熱開始温度、ＴＧ重量減
少開始温度を測定した。測定時の昇温速度は２０℃／ｍ
ｉｎ、測定雰囲気は窒素ガス、測定時のサンプル量は１
〜２ｍｇであった。結果を表３に示す。Examples 11 to 12 Gas generating compositions having the compositions shown in Table 3 were produced.
For these compositions, the melting temperature, the exothermic onset temperature, and the TG weight loss onset temperature were measured by a TAS type differential thermal analyzer manufactured by Rigaku Corporation. Temperature rise rate during measurement is 20 ° C / m
in, measurement atmosphere is nitrogen gas, sample amount at measurement is 1
２2 mg. Table 3 shows the results.
【００２６】[0026]
【表３】 [Table 3]
【００２７】実施例１３〜１５ 表３に示す組成を有するガス発生剤組成物を製造した。
これらの組成物をストランドに成型して、５０、７０、
９０ｋｇ／ｃｍ2の圧力で、窒素雰囲気下で燃焼速度を
測定した。７０ｋｇ／ｃｍ2の燃焼速度と、５０〜９０
ｋｇ／ｃｍ2の間の圧力指数を表４に示す。Examples 13 to 15 Gas generating compositions having the compositions shown in Table 3 were produced.
These compositions are molded into strands and 50, 70,
The burning rate was measured under a nitrogen atmosphere at a pressure of 90 kg / cm 2 . A burning rate of 70 kg / cm 2 and 50-90
The pressure index between kg / cm 2 is shown in Table 4.
【００２８】[0028]
【表４】 [Table 4]
【００２９】以上のように実施例８〜１５に示されたそ
れぞれの数値は、インフレータガス用ガス発生剤組成物
としての実用上の条件を満足していることを示す。As described above, the respective numerical values shown in Examples 8 to 15 indicate that practical conditions as a gas generating composition for an inflator gas are satisfied.
【００３０】[0030]
【発明の効果】本発明のガス発生剤組成物及びその成型
体は、低毒性で危険性が小さいので取り扱いが容易であ
り、燃焼速度が大きく、燃焼温度が低く、さらに燃焼時
に一酸化炭素や窒素酸化物の生成量が少ない。The gas generating composition and the molded article of the present invention are easy to handle because of low toxicity and low danger, have a high burning rate, a low burning temperature, and have a low carbon monoxide and Low generation of nitrogen oxides.
Claims (11)
及び（ｂ）酸化剤である塩基性金属硝酸塩を含有するガ
ス発生剤組成物。1. A gas generating composition comprising (a) a bitetrazole compound as a fuel and (b) a basic metal nitrate as an oxidizing agent.
物、（ｂ）酸化剤である塩基性金属硝酸塩及び（ｃ）バ
インダーを含有するガス発生剤組成物。2. A gas generating composition comprising (a) a bitetrazole compound as a fuel, (b) a basic metal nitrate as an oxidizing agent, and (c) a binder.
リウム塩、ビテトラゾールナトリウム塩、ビテトラゾー
ルマグネシウム塩、ビテトラゾールカルシウム塩、ビテ
トラゾール銅塩、ビテトラゾールアンモニウム塩及びビ
テトラゾールメラミン塩から選ばれる１種以上である請
求項１又は２記載のガス発生剤組成物。3. The fuel of component (a) is selected from the following: bitetrazole potassium salt, bitetrazole sodium salt, bitetrazole magnesium salt, bitetrazole calcium salt, bitetrazole copper salt, bitetrazole ammonium salt and bitetrazole melamine salt. 3. The gas generating composition according to claim 1, which is at least one kind.
性硝酸銅、塩基性硝酸コバルト、塩基性硝酸亜鉛、塩基
性硝酸マンガン、塩基性硝酸鉄、塩基性硝酸モリブデ
ン、塩基性硝酸ビスマス及び塩基性硝酸セリウムから選
ばれる１種以上である請求項１、２又は３記載のガス発
生剤組成物。4. The basic metal nitrate of component (b) is basic copper nitrate, basic cobalt nitrate, basic zinc nitrate, basic manganese nitrate, basic iron nitrate, basic molybdenum nitrate, basic bismuth nitrate. 4. The gas generating composition according to claim 1, wherein the gas generating composition is at least one member selected from the group consisting of cerium nitrate and basic cerium nitrate.
ニウム塩を１５〜３５重量％及び（ｂ）成分として塩基
性硝酸銅を６５〜８５重量％含有する請求項１〜４のい
ずれか１記載のガス発生剤組成物。5. The gas according to claim 1, wherein the gas contains 15 to 35% by weight of a bitetrazole ammonium salt as the component (a) and 65 to 85% by weight of a basic copper nitrate as the component (b). Generator composition.
メチルセルロースナトリウム塩、カルボキシメチルセル
ロースカリウム塩、酢酸セルロース、カルボキシメチル
セルロース、カルボキシメチルセルロースアンモニウム
塩、ポリアクリルアミド、ポリアクリルアミドのアミノ
化物、ポリアクリルヒドラジド、アクリルアミド・アク
リル酸金属塩共重合体、ポリアクリルアミド・ポリアク
リル酸エステル化合物の共重合体、ポリビニルアルコー
ル、グアガム及び水酸化アルミニウムから選ばれる１種
以上である請求項２〜５のいずれか１記載のガス発生剤
組成物。6. The binder of component (c) is sodium carboxymethylcellulose, potassium carboxymethylcellulose, cellulose acetate, carboxymethylcellulose, ammonium carboxymethylcellulose, polyacrylamide, an aminated polyacrylamide, polyacrylhydrazide, acrylamide / acryl. The gas generating agent according to any one of claims 2 to 5, wherein the gas generating agent is at least one selected from an acid metal salt copolymer, a polyacrylamide / polyacrylate compound copolymer, polyvinyl alcohol, guar gum, and aluminum hydroxide. Composition.
含有する請求項１〜６のいずれか１記載のガス発生剤組
成物。7. The gas generating composition according to claim 1, further comprising a combustion regulator as component (d).
鉛、酸化コバルト及び酸化マンガンから選ばれる１種以
上である請求項７記載のガス発生剤組成物。8. The gas generating composition according to claim 7, wherein the combustion regulator is at least one selected from copper oxide, iron oxide, zinc oxide, cobalt oxide and manganese oxide.
生剤組成物から得られる単孔円柱状、多孔円柱状又はペ
レット状の成型体。9. A single-hole cylindrical, porous cylindrical or pellet-shaped molded product obtained from the gas generating composition according to claim 1. Description:
発生剤組成物を用いるエアバック用インフレータ。10. An airbag inflator using the gas generating composition according to claim 1. Description:
ック用インフレータ。11. An inflator for an air bag using the molded product according to claim 9.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11125012A JP2000319085A (en) | 1999-04-30 | 1999-04-30 | Gas generating agent composition |
| PCT/JP2000/002839 WO2000066518A1 (en) | 1999-04-30 | 2000-04-28 | Gas generator composition |
| EP00921099A EP1195367A4 (en) | 1999-04-30 | 2000-04-28 | Gas generator composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11125012A JP2000319085A (en) | 1999-04-30 | 1999-04-30 | Gas generating agent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2000319085A true JP2000319085A (en) | 2000-11-21 |
Family
ID=14899688
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11125012A Pending JP2000319085A (en) | 1999-04-30 | 1999-04-30 | Gas generating agent composition |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP1195367A4 (en) |
| JP (1) | JP2000319085A (en) |
| WO (1) | WO2000066518A1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001066494A1 (en) * | 2000-03-10 | 2001-09-13 | Nippon Kayaku Kabushiki-Kaisha | Gas-generating agent composition for use in air bag |
| JP2002012493A (en) * | 1999-10-08 | 2002-01-15 | Daicel Chem Ind Ltd | Gas generator composition |
| JP2005199867A (en) * | 2004-01-15 | 2005-07-28 | Daicel Chem Ind Ltd | Gas generator for air bag |
| JP2006517510A (en) * | 2003-01-21 | 2006-07-27 | オートリブ エーエスピー，インコーポレイティド | Gas generating agent |
| US7665764B2 (en) | 2004-01-15 | 2010-02-23 | Daicel Chemical Industries, Ltd. | Gas generator for air bag |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6712918B2 (en) * | 2001-11-30 | 2004-03-30 | Autoliv Asp, Inc. | Burn rate enhancement via a transition metal complex of diammonium bitetrazole |
| US6875295B2 (en) * | 2001-12-27 | 2005-04-05 | Trw Inc. | Cool burning gas generating material for a vehicle occupant protection apparatus |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4370181A (en) * | 1980-12-31 | 1983-01-25 | Thiokol Corporation | Pyrotechnic non-azide gas generants based on a non-hydrogen containing tetrazole compound |
| US4369079A (en) * | 1980-12-31 | 1983-01-18 | Thiokol Corporation | Solid non-azide nitrogen gas generant compositions |
| JP3468787B2 (en) * | 1992-11-27 | 2003-11-17 | 東洋化成工業株式会社 | Novel 5,5'-bi-1H-tetrazolamine salt |
| US5482579A (en) * | 1993-04-15 | 1996-01-09 | Nof Corporation | Gas generator compositions |
| US5682014A (en) * | 1993-08-02 | 1997-10-28 | Thiokol Corporation | Bitetrazoleamine gas generant compositions |
| DE4401213C1 (en) * | 1994-01-18 | 1995-03-02 | Fraunhofer Ges Forschung | Gas-generating mixture |
| KR100272955B1 (en) * | 1995-12-01 | 2000-11-15 | 구마모토 마사히로 | Gas generating agent and transfer charge for use in airbag gas generator, and gas generator comprising said gas generating agent and transfer charge |
| US5629494A (en) * | 1996-02-29 | 1997-05-13 | Morton International, Inc. | Hydrogen-less, non-azide gas generants |
| US5608183A (en) * | 1996-03-15 | 1997-03-04 | Morton International, Inc. | Gas generant compositions containing amine nitrates plus basic copper (II) nitrate and/or cobalt(III) triammine trinitrate |
| DE19643468A1 (en) * | 1996-10-22 | 1998-04-23 | Temic Bayern Chem Airbag Gmbh | Gas-generating, azide-free solid mixture |
| JPH10130086A (en) * | 1996-10-23 | 1998-05-19 | Nippon Kayaku Co Ltd | Gas generating agent for air bag |
| US5872329A (en) * | 1996-11-08 | 1999-02-16 | Automotive Systems Laboratory, Inc. | Nonazide gas generant compositions |
| JP4157176B2 (en) * | 1997-04-22 | 2008-09-24 | 東洋化成工業株式会社 | Novel 1,5'-bitetrazole compound, process for producing the same, and gas generating agent based on the 1,5'-bitetral compound |
| DE29821541U1 (en) * | 1998-12-02 | 1999-02-18 | TRW Airbag Systems GmbH & Co. KG, 84544 Aschau | Azide-free, gas generating composition |
-
1999
- 1999-04-30 JP JP11125012A patent/JP2000319085A/en active Pending
-
2000
- 2000-04-28 EP EP00921099A patent/EP1195367A4/en not_active Withdrawn
- 2000-04-28 WO PCT/JP2000/002839 patent/WO2000066518A1/en active Application Filing
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002012493A (en) * | 1999-10-08 | 2002-01-15 | Daicel Chem Ind Ltd | Gas generator composition |
| WO2001066494A1 (en) * | 2000-03-10 | 2001-09-13 | Nippon Kayaku Kabushiki-Kaisha | Gas-generating agent composition for use in air bag |
| JP2006517510A (en) * | 2003-01-21 | 2006-07-27 | オートリブ エーエスピー，インコーポレイティド | Gas generating agent |
| JP2005199867A (en) * | 2004-01-15 | 2005-07-28 | Daicel Chem Ind Ltd | Gas generator for air bag |
| US7665764B2 (en) | 2004-01-15 | 2010-02-23 | Daicel Chemical Industries, Ltd. | Gas generator for air bag |
| JP4494023B2 (en) * | 2004-01-15 | 2010-06-30 | ダイセル化学工業株式会社 | Gas generator for airbag |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1195367A1 (en) | 2002-04-10 |
| WO2000066518A1 (en) | 2000-11-09 |
| EP1195367A4 (en) | 2011-08-03 |
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