IE57654B1 - Concentrated stable non-aqueous fabric softener composition - Google Patents

Abstract

Hexylene glycol alone or in combination with a lower alkanol or another glycol or glycol ether, or mixtures thereof provides a non-aqueous liquid carrier for cationic fabric softeners, especially the quaternary ammonium and imidazolinium cationic compounds, for preparing stable concentrated fabric softener compositions. The compositions may contain up to 60% by weight of the cationic compound and may additionally include up to 15% by weight of a nonionic surfactant. The concentrated compositions disperse easily in cold water and are easily dispensed from automatic dispensers.

Description

The present invention relates to fabric softener compositions adapted for use in the rinse cycle of a laundering process and in particular to highly concentrated fabric softener compositions which are easily dispersed in water when used, particularly in laundry machines having automatic dispensing mechanisms.

Compositions containing quaternary ammonium salts having at least one long chain hydrocarbyl group are commonly used to provide fabric softening benefits when employed in a laundry rinse operation; for example, see U.S. Patents 3,349,033; 3,644,203; 3,946,115; 3.997,453; 4,073,735 and 4,119,545.

For most aqueous softener compositions IS containing cationic quaternary ammonium compounds as active ingredients, the concentration of such cationics has, in general, been limited to the range of about 3 to 6% by weight (see U.S. Patent 3,904,533 and U.S. Patent 3,920,565). Such a low concentration is generally necessitated by the fact that cationics form gels in water systems at concentrations at above about 3%, and while the use of electrolytes to lower the viscosity of such compositions is known (see in particular U.S. Patent 4,199,545), such electrolytes are far from satisfactory. From a functional point of view, the electrolytes often do not perform as required particularly at concentrations of the cationics in the neighbourhood of about 12-15%.

Further, while the performance of the electrolytes may mitigate some of the gelling problem, their use is far from satisfactory in providing a highly concentra ted aqueous system of cationics which does not gel or severely change in viscosity within the usual range of temperatures encountered in the handling thereof, for example 0°F (about -18°C) up to about 14OJF (about 60"C) or in the dispensing from washing mach i nes.

In the ordinary use of European household auto mat ic washing machines, the user places the rinse cycle fabric softener in a dispensing unit (e.g. a dispensing drawer) of the machine. Then, in the operation of the machine, during the rinse cycle, the softener composition is subjected to a stream of cold water to transfer it to the drum. In winter, when the softener composition and the water fed to the dispenser may be especially cold, there can be problems in that some of the composition is not flushed completely off the dispenser during opera20 tion o£ the machine, and a deposit. oC the composition may build up with repeated wash cycles, so that. it. may become necessary for the user to flush the dispenser with hot water. This problem can be particularly severe for highly concentrated softener formulations because of the aforementioned gelling problem and also when a nonionic surfactant is present with the cationic softener since there is a tendency for the viscosity of the nonionic to. increase when mixed with cold water forming a gel.

In British Application 2053249A published 4th February, 1981, there are disclosed cationic fabric softening compositions containing 15 to 60% by «eight of cationic scftenec, 25 to 75% by weight of an aqueous medium and 0.5 to 40% by weight of a specified water soluble polymer.

In U.S. Patent 4,351,737 concentrated fabric softeners are described containing both cationic and non-ionic softeners and a non-ionic dispersin') agent along with a solvent mixture of a to Cj alkanol and a liquid glycol, polyglycoi or an alkyl ether thereof. Hexylene glycol is not disclosed.

It has now been found that the dispersibility in cold water and the flow from automatic dispensers, even in highly concentrated, nonionic surfactantcontaining liquid fabric softener compositions can be improved considerably by replacing part or all of the conventional liquid carrier of the non-aqueous liquid softener composition by hexylene glycol.

The present invention provides substantially nonaqueous stable, concentrated softener compositions based upon quaternary ammonium softening compounds and a carrier liquid comprising hexylene glycol and optionally a nonionic surfactant. The present invention also provides a method by which highly concentrated fabric softening compositions are produced and used.

Thus according to the present invention a stable substantially non-aqueous, concentrated fabric softening composition comprises (A) a water dispersible quaternary ammonium compound cationic softener; (B) a non-aqueous carrier liquid comprising a mixture containing at least 25% by weight of hexylene glycol and the balance being a to C3 alkanol, a C2 to Cg glycol, a C3 to Cg mono- or dialkyl ether of the said glycol, or mixtures thereof, and (C) a non-ionic surfactant.

The invention also extends to a composition comprising (A) water dispersible quaternary ammonium compound cationic softener; (B) a non-aqueous carrier liquid comprising a mixture containing at least 25% by weight of hexylene glycol and the balance being a C3 to C3 alkanol, a C2 to Cg glycol, a C3 to Cg monoor di- alkyl ether of the said glycol, or mixtures thereof, and (C) a nonionic surfactant which is a condensate of a Cg-f^o aliphatic alcohol, or a mono-, di-, or tri-alkyl phenol, with ethylene oxide or propylene oxide or a mixture thereof, each of the said alkyl groups in the alkyl phenol containing from 4 to 12 carbon atoms. Preferably A and B together constitute at least 91.9% of the composition.

The compositions of the present invention are stable substantially non-aqueous compositions which contain a high concentration of the cationic fabric softener which is a water dispersible quaternary ammonium compound an hereinafter described, and hexylene glycol as the, or as part of the, liquid carrier. Preferred compositions may also include non--ionic surfactant and electrolyte.

The compositions of the present invention contain at least about 20% cationic softener and up to about 80% thereof, preferably up to about 70% and more preferably up to about 60% said cationic softener having the general formula: R + I (i> R-N-R Υ I _ R __ wherein R represents a to C30 aliphatic group, preferably alkyl or alkenyl, or an aryl group (e.g. phenyl, tolyl or cumyl); or an aralkyl group (e.g. benzyl or phenethyl); or a halo, amido, hydroxy, or carboxy substituted version thereof; with.the proviso ’that at least one R represents a C^4 to C3Q and preferably a to group, and the other R's are lower alkyl groups, and more preferably at least two R's are Cj^ to C^g and the others are lower alkyl of C4 to C4 (and most preferably methyl or ethyl), or hydroxyalkyl (i.e. (CH2~CH-O)XH where x is 1 to 10, R1 preferably 1 to 5, moot preferably 1 or 2 and R^· represents a hydrogen atom or a C| to ¢4 alkyl group, and Y represents a water-solubilizing anion such as chloride, bromide, iodide, fluoride, sulphate, metho5 sulphate, nitrite, nitrate, phosphate er carboxylate (e.g. acetate, adipate, propionate, phthalate, benzoate or oleate). Typical cationic compounds of Formula 1 include the following: dietearyl dimethyl ammonium chloride; ditallow dimethyl ammonium chloride; dihexadecyl dimethyl ammonium chloride; dietearyl dimethyl ammonium bromide; di(hydrogenated tallow) dimethyl emmonium bromide; ditallow isopropyl methyl ammoniuft chloride; dietearyl di(isopropyl) ammonium chloride; dietearyl dimethyl ammonium methosulphate.

A highly preferred class of cationics is of Formula 1 wherein two of the R groups are 0^4 to C^g, one ft is methyl, or ethyl and one R is methyl, ethyl, isopropyl n-propyl, hydroxyethyl or hydroxypropyl.

Other quaternary softeners which may be used include theImidazolinium compounds of ths formula; (II) wherein r2 represents a Cg to C30, preferably Cg to v Cjg alkyl or alkenyl group; r3 and R4 each independently represent a hydrogen atom or a C^ to C4 alkyl group; R5 represents a Cy to C4 alkyl group; r6 represents a hydrogen atom or a C^ to C4 alkyl group; R7 represents a Cg to C30, preferably Cg to C^g, alkyl group; n is 2 or 3; and m is 2 or 3.

It will be appreciated that when n=2 the heterocyclic ring is five membered and when n=3 it is six membered.

Illustrative compounds of Formula II include: l-methyl-l-((tallowylamido-) ethyl) -2-tallowyl 4,5 dihydro imidazolinium methyl sulphate; and l-methyl-l-((palmitoylamido) ethyl)-2-octadecyl4,5 dihydroimidazolinium chloride.

Specifically preferred cationics are: ditallow monomethyl monohydroxypropyl ammonium chloride; distearyl dimethylammonium chloride; ditallow dimethylammonium chloride; and ditallow isopropyl methyl ammonium chloride.

The non-aqueous carrier may comprise from about % to about 80%, preferably from about 25% to about 60%, by weight of the composition.

The non-aqueous carrier of the composition of the present invention comprises at least about 25% and preferably at least 30% or 35% of hexylene glycol and the balance a Ci to C3 alkanol, preferably ethanol or propanol, a C2 to Cg glycol, preferably diethylene glycol or propylene glycol, or a Cj to Cg mono- or di alkyl ether of such glycols or mixtures thereof. The entire carrier may consist of hexylene glycol to the exclusion of the alcohols and/or glycols (and/or glycoL ethers). Hexylene glycol is the commercial name for 2-methylpentane-2,4-diol which will be referred to as hexylene glycol herein.

Typical carriers may comprise (a) 25% hexylene glycol and 75% propylene glycol; (b) 31% hexylene glycol and 69% propylene glycol; (c) 31% isopropanol and 69% hexylene glycol; (d) 100% hexylene glycol.

The total amount by weight of the cationic fabric softener and the non-aqueous liquid carrier in the composition will preferably be at least about 80 and up to 100%, preferably from about 85% to 99% by weight, the balance including nonionic surfactant, optional electrolyte and/or optional conventional additives.

The optional non-ionic component of the present composition comprises from about 0 to about ‘5.5%, by weight of the composition and generally may vary with the cationic softener in a weight ratio of cationic to nonionic of from about 25:1 to about 3:1, preferably from about 12:1 to 6:1 and especially preferably about 10:1. Suitable non-ionic compounds include ethylene oxide and propylene oxide (and mixtures thereof) condensates of Cg to C20 aliphatic alcohols and mono-, di- and tri-alkyl (each C4 to C12) phenols. Generally, the non-ionics preferred herein are moderately hydro-philic in nature with a moderate hydrophilic group.

In the present invention, this group is preferably an oxyethyl chain generally of at least about 2 terminal oxyethyl groups (i.e. the oxyethyl groups are contiguous and terminate in an hydroxyl group) with no more than about 20 such groups, although there may be as many as 200 moles oxyethylene per mole of the hydrophobic group.

Particularly suitable non-ionic surfactants incLude a Cg_n aliphatic alcohol containing 8 moles of condensed ethylene oxide, an ethoxylated nonyl phenol with 6 moles of ethylene oxide, an ethoxylated octyl phenol with 4.5 moles of ethylene oxide and a Cg aliphatic alcohol with 7.5 moles ethylene oxide.

In addition to the foregoing components of the softening compositions of the present invention, there may also be included numerous conventional, supplemental, and optional ingredients which do not adversely affect the stability and/or functional characteristics of the compositions of the present invention. Thus, for example, there may be present the ubiquitous perfumes, dyes, pigments, opacifiers, germicides, optical brighteners, anti corrosion agents (e.g. sodium siLicate), poLymers, ant.i--st.atic agents and the like. Where used, each may comprise, for example, from 0.01% to about 5% by weight of the composition.

It is, of course, recognized and understood that most available chemical materials and particularly (, those containing an hydrocarbyl moiety are generally mixtures of closely related moieties. Thus, the long j chain alkyl substituents (R) in the cationics used in the present invention may not only be a single length i carbon chain but are more likely a mixture. In this regard, a particularly useful quaternary salt, wherein the alkyl groups are derived from tallow, may contain about 35% C^g and 60% C^g and minor amounts of C[4 and even others. Similarly, the aliphatic alcohol percursors for the non-ionics used herein may be of a single carbon chain length but more likely, again, they will and can be a mixture in any proportion of the operable chain length compounds.

The fabric softening compositions of the present invention should have viscosities in the range of about 10 to 250 centipoises and preferably 25 to 150 centipoises in addition to their essential waterdispersibility in the rinse cycle (or any other form of dilution prior to use).

The manner of combining the hexylene glycol, other optional carriers, cationic softener and optional nonionic surfactant, electrolyte, and other optional conventional additives is not. particularly critical, nor is the order of addition. However, some degree of care should be taken to avoid excessive heating in order to limit solvent evapora25 tion and, more importantly, to stay below the flash point temperature of the carrier and any other low. boiling liquids that may be present or brought in as components of the softener and the like. For example, the flash point for hexylene glycol is 3Q 93°C. Generally, however, it is preferred to combine Ir all of the ingredients at room temperature, e.g. from about 15’C to 25 °C, or lower.

A suitable procedure for preparing the compositions of the present invention involves dissolving any nonionic and other additives (e.g. brightener, colour, perfume, etc.) in the carrier and then mixing this mixture with the cationic e.g. by adding the mixture to the cationic which preferably is in liquid form, e.g. as a dispersion in the carrier or any component thereof (for example, as a dispersion in isopropanol), or adding the cationic to the mixture.

The invention extends to a method of imparting softness to fabrics which comprises adding a composition in accordance with the present invention to an acqueous medium containing the fabrics in an amount to provide a concentration of the cationic compound of from about 0.005% to 0.5% based on the weight of the fabrics. The invention also extends to a method which involves diluting the composition with from about 4 to 15 times as much water by volume as the volume of the said composition and then adding the diluted composition to the clothes.

The invention may be put into practice in various ways and a number of specific embodiments will be described to illustrate the invention with L reference to the accompanying examples. Parts are by weight unless otherwise indicated.

EXAMPLE 1 Following the procedure described above, 2 parts of an ethoxylated nonyl phenol (containing 6 moles of ethylene oxide) are dissolved in about 75 parts of hexylene glycol at a temperature of about 20'C. To this solution are slowly added 20 parts of distearyl dimethyl ammonium chloride (75% active in isopropanol) with stirring. A stable product results with a viscosity of about 100 cps.

EXAMPLES 2A to 2D The procedure of Example 1 is repeated utilizing the following parts of (A) cationic (active), (B) surfactant; and (C) hexylene glycol given in Table 1 below: TABLE 1 Example 2A 2B 2C 2D Ingredients A 22 34 46 58 B 2.0 3.5 4.8 5.5 C 76.0 62.51 49.2 36.5 Notes on Table 1 1 Hexylene glycol/ethylene glycol at 3:1 weight ratio Examples EXAMPLES 3A to 3F 1 and 2 are repeated utilizing in place of distearyl dimethyl ammonium chloride the following: Example 3A - ditallow dimethyl ammonium chloride; Example 3B - distearyl dimethyl ammonium methosulphate; Example 3C - di(hydrogenated tallow) dimethyl ammonium bromide; Example 3D - di-hexadecyl dimethyl ammonium chloride; Example 3E - distearyl diethyl ammonium chloride; Example 3F - l-methyl-l-((tallowylamido)ethyl)-2tallowyl-4,d-dihydroimidazolinium methyl sulphate.

EXAMPLE 4 In order to demonstrate the improved dispensability of the hexylene glycol based liquid carrier for the concentrated softening compositions the following formulations Examples 4A to E are prepared having the proportions set out in Table 2 below: TABLE 2 Weight % Solvent (A-E) 31.9 Cationic fabric softener^· 60.0 Nonionic^ 5.0 Perfume, dye, minors 3.1 Notes on Table 2 75% active ingredient in isopropanol.

Nonyl phenol ethoxylated with an average of 6 moles ethylene oxide (C-9 phenol E06:l).

The following are used as solvent: Example 4A - 10% isopropyl alcohol and 21.9% diethylene glycol (comparison); Example 4B - 10% hexylene glycol and 21.9% propylene glycol; Example 4C - 10% isopropyl alcohol and 21.9% hexylene glycol; Example 4D - 31.9% hexylene glycol; Example 4E - 31.9% propylene glycol (comparison).

Each of the above softener formulations are added to the dispenser of a typical European washing machine, AEG-802, and after 3 cumulative up-to-boil cycles, (the dispenser being refilled for each cycle), the amount of the formulation remaining in the dispenser is measured. The results are shown in the following Table 3 as a percent of the total amount used (i.e. a triple dose): TABLE 3 — 1 τ— Example Solvent. Quan 1. i t.y Rema ini ng ( % ) 4A 10% isopropanol 21.9% diethylene glycol 15 4B 10% hexylene glycol 21.9% propylene glycol 6.7 4C 10% isopropanol 21.9% hexylene glycol 3.6 4D 31.9% hexylene glycol 2.8 4E 31.9% propylene glycol 19 From the above results it can be easily appreciated that the use of hexylene glycol in place of all or part of the conventional non-aqueous liquid carriers for rinse cycle added fabric softener formulations greatly improves the cold water dispersibility and flow (dispensibility), even of concentrated formulations containing nonionic surfactants.

Moreover, the concentrated liquid fabric softener compositions of the present invention are stable for long periods of time at both low, e.g. 4JC and high, e.g. 25°C, storage temperatures, including freeze-thaw cycles, over periods of 6 weeks and longer.

The compositions of the present invention have the further advantage that hexylene glycol is nontoxic and, therefore, the formulations are safe to use.

While the compositions of the present invention are intended primarily for direct use in the rinse cycle of automatic washing machines they can also be used in diluted form and for manual treatment, both in and out of the washing machine.

Still further, it should be understood that as used herein, the term non-aqueous means that no water is intentionally added to the system, although minor amounts of water, e.g. up to about 5%, can be present, based on addition of specific ingredients, e.g. dyes, as aqueous solutions, and the water contained in the softener, etc.

Claims (17)

1. A stable substantially non-aqueous, concentrated fabric softening composition comprising (A) a water dispersiblp quaternary ammonium compound cationic softener; (B) a non-aqueous carrier liquid comprising a mixture containing at least 25% by weight of hexylene glycol and the balance being a C^ to C3 alkanol, a C2 to Cg glycol, a C^ to Cg mono- or di- alkyl ether of the said glycol, or mixtures thereof; and (C) a non-ionic surfactant.

2. A stable substantially non-aqueous, concentrated fabric softening composition comprising (A) water dispersible quaternary ammonium compound cationic softener; (B) a non-aqueous carrier liquid comprising a mixture containing at least 25% by weight of hexylene glycol and the balance being a C^ to C3 alkanol, a C2 to Cg glycol, a C^ to Cg mono- or di- alkyl ether of the said glycol, or mixtures thereof, and (C) a nonionic surfactant which is a condensate of a CQ-C20 aliphatic alcohol or a mono-, di-, or tri-alkyl phenol, with ethylene oxide or propylene oxide or a mixture thereof, each of the said alkyl groups in the alkyl phenol containing from 4 to 12 carbon atoms.

3. A composition as claimed in Claim 1 or Claim 2 in which A and B together constitute at least 91.9% of the composition.

4. A composition as claimed in Claim 1, 2 or 3 which comprises 20 to 80% by weight of (A) and 20 to by weight of (B).

5. A composition as claimed in Claim 1, 2, 3 or 4 which comprises from.1 to 5.5% by weight of (C) nonionic surfactant.

6. A composition as claimed in anyone of Claims 1 to 5 in which the weight ratio of cationic fabric softener to nonionic surfactant is from about 25:1 to about 3:1.

7. A composition as claimed in Claim 6 in which the non-aqueous carrier (B) comprises at least 30% by weight of hexylene glycol.

8. A composition as claimed in Claim 7 in which the non-aqueous carrier consists of hexylene glycol.

9. A composition as claimed in any one of Claims-1 to in which the said non-aqueous carrier comprises (a) 25% hexylene glycol and 75% propylene glycol; (b) 31% hexylene glycol and 69% propylene glycol; (c) 31% isopropanol and 69% hexylene glycol; or (d) 100% hexylene glycol. 1 . A composition as claimed in any one of Claims 1 to in which the cationic softener is selected from the group consisting of compounds of the formula (I) or (II): . Y- (II) wherein R represents a aliphatic group, or an aryl group or an aralkyl group or a halo, amido, hydroxy or carboxy substituted version thereof with the proviso that at least one R represents a C^4 to c 30 group, and the other R’s represent lower alkyl or (CH2-CHR 1 -O) X H groups where x is 1 to

10. , and R* represents a hydrogen atom or a to C4 alkyl group, Y represents a water-solubilizing anion; R 2 represents a Cg to C3Q alkyl or alkenyl group; R 3 and r4 each, independently, represent a hydrogen atom or a to C 4 alkyl group; R 5 represents a Οχ to C 4 alkyl group; represents a hydrogen atom or a Οχ to C 4 alkyl group; R? represents a Cg to C^q alkyl group; ni is 2 oc 3; and n - 2 or 3.

11. A composition as claimed in Claim 10 in which the said condensate comprises from about 2 to about 20 moles of ethylene oxide per mole of alcohol or phenol.

12. A composition as claimed in Claim 1 substantially as specifically described herein with reference to the accompanying examples.

13. A method of forming a stable, concentrated non-aqueous fabric softening composition which comprises combining a water dispersible quaternary ammonium compound cationic fabric softening compound with a substantially non-aqueous liquid carrier comprising a mixture containing at least 25% by weight of hexylene glycol and the balance being a Cx to Cj alkanol, a C 2 to Cg mono- or di- alkyl ether of the said glycol, or mixtures thereof, and a nonionic surfactant, at about room temperature, the amount of the cationic compound being at least about 20% by weight of the composition.

14. A method for imparting softness to fabrics which comprises adding a composition as claimed in any one of Claims 1 to 12 to an aqueous medium >1 containing the fabrics in an amount to provide a 1 concentration of the cationic compound of from about 0.005% to 0.5% based on the weight of the fabrics.

15. A method as claimed in Claim 14 in which the composition is added during the rinse cycle of an automatic washing machine.

16. A method as claimed in Claim 15 in which the composition is added to the aqueous medium flowing a stream of cold water onto the composition whereby the composition is dispersed in the flowing stream and then transferred to the aqueous medium.

17. A method for imparting softeners to clothes which combines diluting the composition as claimed in any one of Claims 1 to 12 with from about 4 to 15 times as much water by volume as the volume of the said composition and then adding the diluted composition to the clothes.