HK1127619A1 - Dual metallocene catalysts for polymerization of bimodal polymers - Google Patents
Dual metallocene catalysts for polymerization of bimodal polymersInfo
- Publication number
- HK1127619A1 HK1127619A1 HK09105058.9A HK09105058A HK1127619A1 HK 1127619 A1 HK1127619 A1 HK 1127619A1 HK 09105058 A HK09105058 A HK 09105058A HK 1127619 A1 HK1127619 A1 HK 1127619A1
- Authority
- HK
- Hong Kong
- Prior art keywords
- polymerization
- metallocene catalysts
- bimodal polymers
- dual metallocene
- dual
- Prior art date
Links
- 230000002902 bimodal effect Effects 0.000 title 1
- 230000009977 dual effect Effects 0.000 title 1
- 239000012968 metallocene catalyst Substances 0.000 title 1
- 229920000642 polymer Polymers 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/07—Catalyst support treated by an anion, e.g. Cl-, F-, SO42-
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/359,972 US7619047B2 (en) | 2006-02-22 | 2006-02-22 | Dual metallocene catalysts for polymerization of bimodal polymers |
| PCT/US2007/062555 WO2007101053A1 (en) | 2006-02-22 | 2007-02-22 | Dual metallocene catalysts for polymerization of bimodal polymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HK1127619A1 true HK1127619A1 (en) | 2009-10-02 |
Family
ID=38265127
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HK09105058.9A HK1127619A1 (en) | 2006-02-22 | 2009-06-05 | Dual metallocene catalysts for polymerization of bimodal polymers |
Country Status (16)
| Country | Link |
|---|---|
| US (4) | US7619047B2 (xx) |
| EP (1) | EP1989238A1 (xx) |
| JP (1) | JP5639744B2 (xx) |
| KR (1) | KR101401851B1 (xx) |
| CN (1) | CN101389668B (xx) |
| AR (1) | AR059670A1 (xx) |
| AU (1) | AU2007220861B2 (xx) |
| BR (1) | BRPI0707405B1 (xx) |
| CA (1) | CA2641515C (xx) |
| EG (1) | EG26233A (xx) |
| HK (1) | HK1127619A1 (xx) |
| MX (1) | MX2008009969A (xx) |
| MY (2) | MY153961A (xx) |
| RU (1) | RU2433143C2 (xx) |
| SG (1) | SG169350A1 (xx) |
| WO (1) | WO2007101053A1 (xx) |
Families Citing this family (229)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7226886B2 (en) * | 2005-09-15 | 2007-06-05 | Chevron Phillips Chemical Company, L.P. | Polymerization catalysts and process for producing bimodal polymers in a single reactor |
| US7517939B2 (en) | 2006-02-02 | 2009-04-14 | Chevron Phillips Chemical Company, Lp | Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching |
| US7589162B2 (en) * | 2006-02-22 | 2009-09-15 | Chevron Philips Chemical Company Lp | Polyethylene compositions and pipe made from same |
| US7619047B2 (en) | 2006-02-22 | 2009-11-17 | Chevron Phillips Chemical Company, Lp | Dual metallocene catalysts for polymerization of bimodal polymers |
| US7943711B2 (en) * | 2007-05-14 | 2011-05-17 | Exxonmobil Chemical Patents Inc. | Ethylene elastomer compositions |
| US8119553B2 (en) * | 2007-09-28 | 2012-02-21 | Chevron Phillips Chemical Company Lp | Polymerization catalysts for producing polymers with low melt elasticity |
| US7799721B2 (en) | 2007-09-28 | 2010-09-21 | Chevron Phillips Chemical Company Lp | Polymerization catalysts for producing polymers with high comonomer incorporation |
| US7468452B1 (en) | 2007-12-12 | 2008-12-23 | Chevron Phillips Chemical Company Lp | Process for one-pot synthesis of 1,1-diphenyl-1-(3-substituted-cyclopentadienyl)-1-(2,7-di-t-butyl-fluoren-9-yl)methane type ligands |
| US8080681B2 (en) | 2007-12-28 | 2011-12-20 | Chevron Phillips Chemical Company Lp | Nano-linked metallocene catalyst compositions and their polymer products |
| US7863210B2 (en) * | 2007-12-28 | 2011-01-04 | Chevron Phillips Chemical Company Lp | Nano-linked metallocene catalyst compositions and their polymer products |
| US8012900B2 (en) * | 2007-12-28 | 2011-09-06 | Chevron Phillips Chemical Company, L.P. | Nano-linked metallocene catalyst compositions and their polymer products |
| US11208514B2 (en) | 2008-03-20 | 2021-12-28 | Chevron Phillips Chemical Company Lp | Silica-coated alumina activator-supports for metallocene catalyst compositions |
| US7884163B2 (en) | 2008-03-20 | 2011-02-08 | Chevron Phillips Chemical Company Lp | Silica-coated alumina activator-supports for metallocene catalyst compositions |
| US8802797B2 (en) | 2008-06-20 | 2014-08-12 | Exxonmobil Chemical Patents Inc. | Vinyl-terminated macromonomer oligomerization |
| US8372930B2 (en) | 2008-06-20 | 2013-02-12 | Exxonmobil Chemical Patents Inc. | High vinyl terminated propylene based oligomers |
| US8283419B2 (en) | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Olefin functionalization by metathesis reaction |
| US8399725B2 (en) | 2008-06-20 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Functionalized high vinyl terminated propylene based oligomers |
| US8283428B2 (en) | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Polymacromonomer and process for production thereof |
| JP5754940B2 (ja) * | 2008-08-19 | 2015-07-29 | 三井化学株式会社 | 混合触媒によるプロピレン重合体の製造方法 |
| KR101249995B1 (ko) * | 2008-12-11 | 2013-04-03 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매, 이의 제조방법 및 이를 이용한 올레핀계 중합체의 제조방법 |
| US8114946B2 (en) * | 2008-12-18 | 2012-02-14 | Chevron Phillips Chemical Company Lp | Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches |
| KR101132180B1 (ko) * | 2009-01-23 | 2012-04-05 | 대림산업 주식회사 | 멀티모달 폴리올레핀 제조를 위한 촉매 및 이를 이용한 올레핀의 중합방법 |
| US8536391B2 (en) | 2009-06-16 | 2013-09-17 | Chevron Phillips Chemical Company Lp | Oligomerization of alpha olefins using metallocene-SSA catalyst systems and use of the resultant polyalphaolefins to prepare lubricant blends |
| US7919639B2 (en) * | 2009-06-23 | 2011-04-05 | Chevron Phillips Chemical Company Lp | Nano-linked heteronuclear metallocene catalyst compositions and their polymer products |
| SG177344A1 (en) | 2009-06-29 | 2012-02-28 | Chevron Phillips Chemical Co | The use of hydrogen scavenging catalysts to control polymer molecular weight and hydrogen levels in a polymerization reactor |
| EP2448978B1 (en) | 2009-06-29 | 2016-05-18 | Chevron Phillips Chemical Company LP | Dual metallocene catalyst systems for decreasing melt index and increasing polymer production rates |
| WO2011012245A1 (en) | 2009-07-27 | 2011-02-03 | Basell Polyolefine Gmbh | Organometallic transition metal compound, catalyst system and preparation of polyolefins |
| EP2485839A1 (en) * | 2009-10-06 | 2012-08-15 | Chevron Phillips Chemical Company LP | Oligomerization of olefin waxes using metallocene-based catalyst systems |
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| US8669326B2 (en) | 2011-03-25 | 2014-03-11 | Exxonmobil Chemical Patents Inc. | Amine functionalized polyolefin and methods for preparation thereof |
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| US8399724B2 (en) | 2011-03-25 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin copolymers and methods to produce thereof |
| WO2012134720A2 (en) * | 2011-03-25 | 2012-10-04 | Exxonmobil Chemical Patents Inc. | Enhanced catalyst performance for production of vinyl terminated propylene and ethylene/propylene macromers |
| US8426659B2 (en) | 2011-03-25 | 2013-04-23 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin polymers and methods to produce thereof |
| US8841397B2 (en) | 2011-03-25 | 2014-09-23 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin polymers and methods to produce thereof |
| US8669330B2 (en) | 2011-03-25 | 2014-03-11 | Exxonmobil Chemical Patents Inc. | Olefin triblock polymers via ring-opening metathesis polymerization |
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| US8362161B2 (en) | 2011-04-12 | 2013-01-29 | Chevron Phillips Chemical Company Lp | System and method for processing reactor polymerization effluent |
| WO2012170384A1 (en) | 2011-06-06 | 2012-12-13 | Chevron Phillips Chemical Company Lp | Use of metallocene compounds for cancer treatment |
| US8318883B1 (en) * | 2011-06-08 | 2012-11-27 | Chevron Phillips Chemical Company Lp | Polymer compositions for blow molding applications |
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| US8895679B2 (en) | 2012-10-25 | 2014-11-25 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| US9238698B2 (en) | 2012-10-31 | 2016-01-19 | Chevron Phillips Chemical Company Lp | Pressure management for slurry polymerization |
| US8921498B2 (en) | 2012-10-31 | 2014-12-30 | Chevron Phillips Chemical Company Lp | Pressure management for slurry polymerization |
| ES2606684T3 (es) | 2012-11-07 | 2017-03-27 | Chevron Phillips Chemical Company Lp | Resinas de poliolefina de baja densidad y películas preparadas a partir de éstas |
| KR101394943B1 (ko) * | 2012-11-19 | 2014-05-14 | 대림산업 주식회사 | 에틸렌과 알파-올레핀의 공중합체 및 그 제조방법 |
| KR101437509B1 (ko) * | 2012-12-03 | 2014-09-03 | 대림산업 주식회사 | 성형성 및 기계적 물성이 우수한 멀티모달 폴리올레핀 수지 제조를 위한 촉매 조성물 및 이를 이용한 중합 방법 |
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- 2007-02-22 AU AU2007220861A patent/AU2007220861B2/en active Active
- 2007-02-22 JP JP2008556539A patent/JP5639744B2/ja active Active
- 2007-02-22 AR ARP070100762A patent/AR059670A1/es not_active Application Discontinuation
- 2007-02-22 MY MYPI20116099 patent/MY152947A/en unknown
- 2007-02-22 WO PCT/US2007/062555 patent/WO2007101053A1/en active Application Filing
- 2007-02-22 EP EP07757312A patent/EP1989238A1/en not_active Ceased
- 2007-02-22 BR BRPI0707405-0A patent/BRPI0707405B1/pt active IP Right Grant
- 2007-02-22 KR KR1020087023125A patent/KR101401851B1/ko active IP Right Grant
- 2007-02-22 SG SG201100551-9A patent/SG169350A1/en unknown
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2008
- 2008-07-27 EG EG2008071257A patent/EG26233A/en active
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2009
- 2009-06-05 HK HK09105058.9A patent/HK1127619A1/xx not_active IP Right Cessation
- 2009-10-01 US US12/571,824 patent/US7960487B2/en active Active
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2011
- 2011-04-26 US US13/094,174 patent/US8138113B2/en active Active
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2012
- 2012-02-15 US US13/397,286 patent/US8268944B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| SG169350A1 (en) | 2011-03-30 |
| AU2007220861B2 (en) | 2013-01-31 |
| BRPI0707405A2 (pt) | 2011-05-03 |
| US20110201770A1 (en) | 2011-08-18 |
| CA2641515C (en) | 2015-06-02 |
| EG26233A (en) | 2013-05-05 |
| MY153961A (en) | 2015-04-30 |
| CN101389668B (zh) | 2011-11-30 |
| RU2008137652A (ru) | 2010-03-27 |
| CA2641515A1 (en) | 2007-09-07 |
| US8268944B2 (en) | 2012-09-18 |
| JP2009527636A (ja) | 2009-07-30 |
| KR101401851B1 (ko) | 2014-05-29 |
| US7960487B2 (en) | 2011-06-14 |
| WO2007101053A1 (en) | 2007-09-07 |
| US7619047B2 (en) | 2009-11-17 |
| CN101389668A (zh) | 2009-03-18 |
| US20100041842A1 (en) | 2010-02-18 |
| KR20080104331A (ko) | 2008-12-02 |
| US20120190804A1 (en) | 2012-07-26 |
| MX2008009969A (es) | 2008-11-06 |
| BRPI0707405B1 (pt) | 2018-07-24 |
| EP1989238A1 (en) | 2008-11-12 |
| JP5639744B2 (ja) | 2014-12-10 |
| US8138113B2 (en) | 2012-03-20 |
| US20070197374A1 (en) | 2007-08-23 |
| MY152947A (en) | 2014-12-15 |
| RU2433143C2 (ru) | 2011-11-10 |
| AR059670A1 (es) | 2008-04-23 |
| AU2007220861A1 (en) | 2007-09-07 |
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| Date | Code | Title | Description |
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| PC | Patent ceased (i.e. patent has lapsed due to the failure to pay the renewal fee) |
Effective date: 20170222 |