GB1501682A - Non-vitreous ceramic metal oxide microcapsules - Google Patents
Non-vitreous ceramic metal oxide microcapsulesInfo
- Publication number
- GB1501682A GB1501682A GB41385/77A GB4138577A GB1501682A GB 1501682 A GB1501682 A GB 1501682A GB 41385/77 A GB41385/77 A GB 41385/77A GB 4138577 A GB4138577 A GB 4138577A GB 1501682 A GB1501682 A GB 1501682A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methyl
- microcapsules
- pentanol
- metal oxide
- butanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003094 microcapsule Substances 0.000 title abstract 7
- 239000000919 ceramic Substances 0.000 title abstract 5
- 229910044991 metal oxide Inorganic materials 0.000 title abstract 5
- 150000004706 metal oxides Chemical class 0.000 title abstract 5
- 239000007788 liquid Substances 0.000 abstract 5
- 239000000463 material Substances 0.000 abstract 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 abstract 3
- MSXVEPNJUHWQHW-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O MSXVEPNJUHWQHW-UHFFFAOYSA-N 0.000 abstract 3
- 239000002243 precursor Substances 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- WFRBDWRZVBPBDO-UHFFFAOYSA-N 2-methyl-2-pentanol Chemical compound CCCC(C)(C)O WFRBDWRZVBPBDO-UHFFFAOYSA-N 0.000 abstract 2
- MXLMTQWGSQIYOW-UHFFFAOYSA-N 3-methyl-2-butanol Chemical compound CC(C)C(C)O MXLMTQWGSQIYOW-UHFFFAOYSA-N 0.000 abstract 2
- FRDAATYAJDYRNW-UHFFFAOYSA-N 3-methyl-3-pentanol Chemical compound CCC(C)(O)CC FRDAATYAJDYRNW-UHFFFAOYSA-N 0.000 abstract 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 abstract 2
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 abstract 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 abstract 2
- JYVLIDXNZAXMDK-UHFFFAOYSA-N pentan-2-ol Chemical compound CCCC(C)O JYVLIDXNZAXMDK-UHFFFAOYSA-N 0.000 abstract 2
- IKECULIHBUCAKR-UHFFFAOYSA-N 2,3-dimethylbutan-2-ol Chemical compound CC(C)C(C)(C)O IKECULIHBUCAKR-UHFFFAOYSA-N 0.000 abstract 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 abstract 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 abstract 1
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 238000010304 firing Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 239000005300 metallic glass Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- -1 methylacetate) Chemical class 0.000 abstract 1
- 229940032007 methylethyl ketone Drugs 0.000 abstract 1
- 238000005065 mining Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000008279 sol Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/04—Making microcapsules or microballoons by physical processes, e.g. drying, spraying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/20—After-treatment of capsule walls, e.g. hardening
- B01J13/203—Exchange of core-forming material by diffusion through the capsule wall
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/51—Spheres
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/30—Oxides other than silica
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B30/00—Compositions for artificial stone, not containing binders
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/009—Porous or hollow ceramic granular materials, e.g. microballoons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/32—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/16—Solid spheres
- C08K7/18—Solid spheres inorganic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Civil Engineering (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
1501682 Microcapsules MINNESOTA MINING & MFG CO 6 Jan 1975 [7 Jan 1974]41385/77 Divided out of 1501681 Heading C1A Microcapsules are made by adding a precursor material comprising an aqueous solution, dispersion or sol of one or more ceramic metal oxides (or compounds calcinable to form a ceramic metal oxide agitated to an organic dehydrating liquid, so that the dehydrating liquid is maintained in contact with droplets of the precursor material to extract rapidly at 20 to 40 C. the major amount of water from the droplets; drying the resulting spherical, gelled, porous, microcapsules to remove liquid from within, and firing the dried product to produce spherical ceramic microcapsules the wall or shell of which encloses a single hollow, is homogeneous and is made of non-vitreous ceramic comprising polycrystalline metal oxide or amorphous metal oxide convertible to the polycrystalline form upon further heating. In particular a process is described in which the precursor material is added to a swirling organic dehydrating liquid having a limited solubility of 3 to 50 wt. per cent for water at about 23 C., and wherein the major amount of water is extracted from the droplets within 30 secs. at 20 to 40 C. which are subsequently dried and fired to yield a product, the predominant amount (e.g., 85-95%) of which is in microcapsule form. Suitable organic dehydrating liquids are alcohols with 3-6 C atoms (e.g., nbutanol, sec-butanol, 1-pentanol, 2-pentanol, 3 - methyl - 2 - butanol, 2 - methyl - 2 - butanol, 3 - methyl - 3 - pentanol, 2 - methyl - 1 - propanol, 2,3 - dimethyl - 2 - butanol and 2-methyl-2-pentanol and cyclohexanol); ketones (e.g. methyl-ethyl ketone); amines (e.g. dipropylamine); and esters (e.g., methylacetate), and mixtures thereof. Various non-vitreous materials (defined as those which are not derived from melts) which may comprise the microcapsule walls form the subject-matter of parent Specification.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US43134374A | 1974-01-07 | 1974-01-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1501682A true GB1501682A (en) | 1978-02-22 |
Family
ID=23711507
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB41385/77A Expired GB1501682A (en) | 1974-01-07 | 1975-01-06 | Non-vitreous ceramic metal oxide microcapsules |
| GB453/75A Expired GB1501681A (en) | 1974-01-07 | 1975-01-06 | Non-vitreous ceramic metal oxide microcapsules |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB453/75A Expired GB1501681A (en) | 1974-01-07 | 1975-01-06 | Non-vitreous ceramic metal oxide microcapsules |
Country Status (13)
| Country | Link |
|---|---|
| JP (1) | JPS603856B2 (en) |
| BE (1) | BE824119A (en) |
| BR (1) | BR7500085A (en) |
| CA (1) | CA1061366A (en) |
| CH (1) | CH626269A5 (en) |
| DE (1) | DE2500153A1 (en) |
| ES (1) | ES433416A1 (en) |
| FR (1) | FR2256779B1 (en) |
| GB (2) | GB1501682A (en) |
| IT (1) | IT1026234B (en) |
| NL (1) | NL181335C (en) |
| SE (1) | SE437771B (en) |
| ZA (1) | ZA75104B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4399226A (en) | 1978-09-28 | 1983-08-16 | Minnesota Mining And Manufacturing Company | Tagging with microcapsules containing perfluoroalkyl pentafluorosulfide |
| GB2189780A (en) * | 1986-04-22 | 1987-11-04 | Shell Int Research | A process for the preparation of alumina spheres |
| EP0371343A1 (en) * | 1988-11-29 | 1990-06-06 | Bayer Ag | Titanium dioxide, process for its preparation and use thereof |
| CN107973522A (en) * | 2017-12-16 | 2018-05-01 | 李炫颖 | A kind of preparation method of resistance to compression hollow glass micropearl |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2960516D1 (en) * | 1978-01-31 | 1981-10-29 | Atomic Energy Authority Uk | Thermally insulating, fire resistant material and its production |
| GB8333794D0 (en) * | 1983-12-19 | 1984-01-25 | Atomic Energy Authority Uk | Materials |
| JPH0524926Y2 (en) * | 1986-08-23 | 1993-06-24 | ||
| JPS63113165U (en) * | 1987-01-16 | 1988-07-21 | ||
| DE19950479A1 (en) * | 1999-10-20 | 2001-05-23 | Henkel Kgaa | Microcapsules |
| DE10013406B4 (en) * | 2000-03-17 | 2007-01-04 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Process for the production of moldings from a composite material and use of the moldings |
| NO320969B1 (en) * | 2004-05-03 | 2006-02-20 | Yara Int Asa | Oven and catalyst production process |
| JP6957776B1 (en) * | 2020-05-01 | 2021-11-02 | 積水化学工業株式会社 | Thermally expandable microcapsules |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR91342E (en) * | 1965-04-21 | 1968-05-24 | Grace W R & Co | Process for manufacturing cores for microspheres and microspheres obtained by this process |
| GB1231385A (en) * | 1967-08-04 | 1971-05-12 | ||
| US3709706A (en) * | 1969-05-16 | 1973-01-09 | Minnesota Mining & Mfg | Refractory fibers and other articles of zirconia and silica mixtures |
| US3748274A (en) * | 1969-08-29 | 1973-07-24 | Atomic Energy Commission | Method of making particles from an aqueous sol |
| NL7111738A (en) * | 1971-08-26 | 1973-02-28 | ||
| CA947192A (en) * | 1971-09-14 | 1974-05-14 | Thomas J. Miller | Method of forming particulate material from salt solutions |
| US3855172A (en) * | 1972-04-07 | 1974-12-17 | Du Pont | Uniform oxide microspheres and a process for their manufacture |
| JPS5426142B2 (en) * | 1973-08-09 | 1979-09-01 | ||
| JPS5121954A (en) * | 1974-08-16 | 1976-02-21 | Hitachi Ltd | HEADORAIYAA |
-
1974
- 1974-12-11 CA CA215,704A patent/CA1061366A/en not_active Expired
- 1974-12-27 NL NLAANVRAGE7416904,A patent/NL181335C/en not_active IP Right Cessation
- 1974-12-27 SE SE7416307A patent/SE437771B/en not_active IP Right Cessation
- 1974-12-28 ES ES433416A patent/ES433416A1/en not_active Expired
-
1975
- 1975-01-03 IT IT47524/75A patent/IT1026234B/en active
- 1975-01-03 DE DE19752500153 patent/DE2500153A1/en active Granted
- 1975-01-06 JP JP50004359A patent/JPS603856B2/en not_active Expired
- 1975-01-06 ZA ZA00750104A patent/ZA75104B/en unknown
- 1975-01-06 FR FR7500235A patent/FR2256779B1/fr not_active Expired
- 1975-01-06 GB GB41385/77A patent/GB1501682A/en not_active Expired
- 1975-01-06 BR BR85/75A patent/BR7500085A/en unknown
- 1975-01-06 GB GB453/75A patent/GB1501681A/en not_active Expired
- 1975-01-06 BE BE152158A patent/BE824119A/en not_active IP Right Cessation
- 1975-01-07 CH CH10175A patent/CH626269A5/en not_active IP Right Cessation
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4399226A (en) | 1978-09-28 | 1983-08-16 | Minnesota Mining And Manufacturing Company | Tagging with microcapsules containing perfluoroalkyl pentafluorosulfide |
| GB2189780A (en) * | 1986-04-22 | 1987-11-04 | Shell Int Research | A process for the preparation of alumina spheres |
| EP0371343A1 (en) * | 1988-11-29 | 1990-06-06 | Bayer Ag | Titanium dioxide, process for its preparation and use thereof |
| US5009879A (en) * | 1988-11-29 | 1991-04-23 | Bayer Aktiengesellschaft | Titanium dioxide, a process for its production and its use |
| CN107973522A (en) * | 2017-12-16 | 2018-05-01 | 李炫颖 | A kind of preparation method of resistance to compression hollow glass micropearl |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1061366A (en) | 1979-08-28 |
| BR7500085A (en) | 1975-11-04 |
| DE2500153A1 (en) | 1975-07-31 |
| JPS50100107A (en) | 1975-08-08 |
| AU7689574A (en) | 1976-07-01 |
| IT1026234B (en) | 1978-09-20 |
| CH626269A5 (en) | 1981-11-13 |
| NL181335B (en) | 1987-03-02 |
| NL7416904A (en) | 1975-07-09 |
| NL181335C (en) | 1987-08-03 |
| SE437771B (en) | 1985-03-18 |
| SE7416307L (en) | 1975-07-08 |
| FR2256779B1 (en) | 1978-10-13 |
| DE2500153C2 (en) | 1989-12-07 |
| JPS603856B2 (en) | 1985-01-31 |
| ES433416A1 (en) | 1976-11-16 |
| GB1501681A (en) | 1978-02-22 |
| BE824119A (en) | 1975-07-07 |
| FR2256779A1 (en) | 1975-08-01 |
| ZA75104B (en) | 1976-01-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| 732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
| PE20 | Patent expired after termination of 20 years |
Effective date: 19950105 |