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GB1489335A - Catalyst for the production of ethylene oxide - Google Patents

Catalyst for the production of ethylene oxide

Info

Publication number
GB1489335A
GB1489335A GB49962/73A GB4996273A GB1489335A GB 1489335 A GB1489335 A GB 1489335A GB 49962/73 A GB49962/73 A GB 49962/73A GB 4996273 A GB4996273 A GB 4996273A GB 1489335 A GB1489335 A GB 1489335A
Authority
GB
United Kingdom
Prior art keywords
catalyst
support
compound
ethylene oxide
oct
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB49962/73A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Priority to GB49962/73A priority Critical patent/GB1489335A/en
Priority to SE7412461A priority patent/SE407156B/en
Priority to CA210,866A priority patent/CA1048010A/en
Priority to DE2448449A priority patent/DE2448449C2/en
Priority to NL7413748A priority patent/NL7413748A/en
Priority to IN2330/CAL/74A priority patent/IN143192B/en
Priority to ES431308A priority patent/ES431308A1/en
Priority to FR7435691A priority patent/FR2249087B1/fr
Priority to IT28761/74A priority patent/IT1025175B/en
Priority to BE149849A priority patent/BE821439A/en
Priority to JP49122005A priority patent/JPS581629B2/en
Priority to RO80324A priority patent/RO84369B/en
Priority to DD181925A priority patent/DD114407A5/xx
Priority to PL1974175085A priority patent/PL99702B1/en
Priority to CS747326A priority patent/CS219313B2/en
Priority to US05/675,034 priority patent/US4207210A/en
Priority to ES447632A priority patent/ES447632A1/en
Priority to IN407/CAL/1977A priority patent/IN143563B/en
Publication of GB1489335A publication Critical patent/GB1489335A/en
Priority to SE7808959A priority patent/SE434837B/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1489335 Ethylene oxide preparation SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ BV 24 Oct 1974 [26 Oct 1973] 49962/73 Heading C2C [Also in Division B1] Ethylene oxide is made by the vapour phase oxidation of ethylene with O 2 in the presence of a silver catalyst which has been prepared by (a) impregnating a porous refractory support of surface area 0À03-10 m.<SP>2</SP>/g. with a solution of a compound of K, Rb or Cs in such a concentration, having regard to any leachable alkali metal in the support prior to impregnation, as to produce-optionally after extraction with a solvent after either step (b) or step (c)-in the final catalyst a content of 0À25-16 mg. e.w. of alkali metal per kilogram total catalyst for each square metre of surface area per gram of support, (b) at least partly drying the impregnated support, (c) contacting the at least partly dried product with a liquid phase containing a dissolved compound of Ag or a slurry of particles of Ag or Ag compound in an amount sufficient to deposit 1-25 wt. per cent Ag, based on the total catalyst, on the support surface, and (d) thermally treating the product of (c), optionally in the presence of a reducing agent, to convert the Ag compound to Ag metal. Preferably the oxidation is performed at 210-285‹ C. in the presence of a fixed bed of catalyst, an inert diluent gas and a chlorine-containing moderator.
GB49962/73A 1973-10-26 1973-10-26 Catalyst for the production of ethylene oxide Expired GB1489335A (en)

Priority Applications (19)

Application Number Priority Date Filing Date Title
GB49962/73A GB1489335A (en) 1973-10-26 1973-10-26 Catalyst for the production of ethylene oxide
SE7412461A SE407156B (en) 1973-10-26 1974-10-03 PROCEDURE FOR MAKING A SILVER CATALYST
CA210,866A CA1048010A (en) 1973-10-26 1974-10-07 Catalyst for the production of ethylene oxide
DE2448449A DE2448449C2 (en) 1973-10-26 1974-10-10 Silver catalyst for the production of ethylene oxide and its use
NL7413748A NL7413748A (en) 1973-10-26 1974-10-21 CATALYST FOR THE PREPARATION OF ETHYLENE OXIDE.
IN2330/CAL/74A IN143192B (en) 1973-10-26 1974-10-22
BE149849A BE821439A (en) 1973-10-26 1974-10-24 CATALYST FOR THE PRODUCTION OF ETHYLENE OXIDE
FR7435691A FR2249087B1 (en) 1973-10-26 1974-10-24
IT28761/74A IT1025175B (en) 1973-10-26 1974-10-24 CATALYST FOR THE PRODUCTION OF ETHYLENOXIDE
ES431308A ES431308A1 (en) 1973-10-26 1974-10-24 Catalyst for the production of ethylene oxide
JP49122005A JPS581629B2 (en) 1973-10-26 1974-10-24 Ethylene oxide sagebrush
PL1974175085A PL99702B1 (en) 1973-10-26 1974-10-25 CATALYST FOR OBTAINING ETHYLENE OXIDE AND METHOD OF MANUFACTURING A CATALYST FOR OBTAINING ETHYLENE OXIDE
DD181925A DD114407A5 (en) 1973-10-26 1974-10-25
RO80324A RO84369B (en) 1973-10-26 1974-10-25 Process for obtaining a catalyst used for producing ethylene oxide
CS747326A CS219313B2 (en) 1973-10-26 1974-10-25 Method of making the silver catalysers
US05/675,034 US4207210A (en) 1973-10-26 1976-04-08 Process for preparing an ethylene oxide catalyst
ES447632A ES447632A1 (en) 1973-10-26 1976-05-06 Catalyst for the production of ethylene oxide
IN407/CAL/1977A IN143563B (en) 1973-10-26 1977-03-21
SE7808959A SE434837B (en) 1973-10-26 1978-08-24 PROCEDURE FOR THE PREPARATION OF ETHYLENOXIDE BY DIRECT OXIDATION OF ETHEN IN ANGASE PHASE WITH MOLECULATED ACID IN THE PRESENT OF A SILVER CATALYST

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB49962/73A GB1489335A (en) 1973-10-26 1973-10-26 Catalyst for the production of ethylene oxide

Publications (1)

Publication Number Publication Date
GB1489335A true GB1489335A (en) 1977-10-19

Family

ID=10454139

Family Applications (1)

Application Number Title Priority Date Filing Date
GB49962/73A Expired GB1489335A (en) 1973-10-26 1973-10-26 Catalyst for the production of ethylene oxide

Country Status (15)

Country Link
JP (1) JPS581629B2 (en)
BE (1) BE821439A (en)
CA (1) CA1048010A (en)
CS (1) CS219313B2 (en)
DD (1) DD114407A5 (en)
DE (1) DE2448449C2 (en)
ES (2) ES431308A1 (en)
FR (1) FR2249087B1 (en)
GB (1) GB1489335A (en)
IN (1) IN143192B (en)
IT (1) IT1025175B (en)
NL (1) NL7413748A (en)
PL (1) PL99702B1 (en)
RO (1) RO84369B (en)
SE (2) SE407156B (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4419276A (en) 1981-09-30 1983-12-06 Union Carbide Corporation Silver catalyst for the manufacture of ethylene oxide and a process for preparing the catalyst
US4455392A (en) * 1981-10-05 1984-06-19 Union Carbide Corporation Process for preparing a supported silver catalyst
WO2004002954A3 (en) * 2002-06-28 2004-08-19 Shell Oil Co A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
WO2004101144A1 (en) * 2003-05-07 2004-11-25 Shell Internationale Research Maatschappij B.V., Silver-containing catalysts, the manufacture of such silver­ containing catalysts, and the use thereof
EP1622709A2 (en) * 2003-04-23 2006-02-08 SD Lizenzverwertungsgesellschaft mbH & Co. KG Ethylene oxide catalyst
US7102022B2 (en) 2002-06-28 2006-09-05 Shell Oil Company Method for the start-up of an epoxidation process and a process for the epoxidation of an olefin
US7348444B2 (en) 2003-04-07 2008-03-25 Shell Oil Company Process for the production of an olefin oxide
US7835868B2 (en) 2004-09-24 2010-11-16 Shell Oil Company Process for selecting shaped particles for use in a packed bed
US8043575B2 (en) 2003-05-07 2011-10-25 Shell Oil Company Reactor system and process for the manufacture of ethylene oxide
US8148555B2 (en) 2003-06-26 2012-04-03 Shell Oil Company Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
US8921586B2 (en) 2008-05-07 2014-12-30 Shell Oil Company Process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
US9346774B2 (en) 2008-05-07 2016-05-24 Shell Oil Company Process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
US10532989B2 (en) 2007-05-09 2020-01-14 Shell Oil Company Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
US11801493B2 (en) 2016-12-02 2023-10-31 Shell Usa, Inc. Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2640540C3 (en) * 1976-09-09 1988-07-28 Basf Ag, 6700 Ludwigshafen Catalyst for the production of ethylene oxide
US4066575A (en) * 1976-07-26 1978-01-03 Halcon International, Inc. Process for the preparation of a supported silver catalyst
DE2819595A1 (en) * 1977-05-12 1978-12-07 Basf Ag CATALYST FOR THE PRODUCTION OF ETHYLENE OXIDE
JPS5689843A (en) * 1979-12-25 1981-07-21 Nippon Shokubai Kagaku Kogyo Co Ltd Silver catalyst for production of ethylene oxide
BG37835A3 (en) * 1982-06-30 1985-08-15 Hoechst Aktiengesellschaft Method for preparing silver catalyst
US4575494A (en) * 1984-02-08 1986-03-11 The Dow Chemical Company Alumina compositions useful as catalyst supports for ethylene oxidation
JPS60216844A (en) * 1984-04-13 1985-10-30 Nippon Shokubai Kagaku Kogyo Co Ltd Silver catalyst for producing ethylene oxide
WO2019245859A1 (en) 2018-06-21 2019-12-26 The J. David Gladstone Institutes Generation of a population of hindbrain cells and hindbrain-like organoids from pluripotent stem cells
US11772082B1 (en) 2018-06-21 2023-10-03 Avn Corporation Catalyst supports—composition and process of manufacture

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE793658A (en) * 1972-01-07 1973-07-04 Shell Int Research CATALYST USED FOR THE PRODUCTION OF ETHYLENE OXIDE

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4419276A (en) 1981-09-30 1983-12-06 Union Carbide Corporation Silver catalyst for the manufacture of ethylene oxide and a process for preparing the catalyst
US4455392A (en) * 1981-10-05 1984-06-19 Union Carbide Corporation Process for preparing a supported silver catalyst
WO2004002954A3 (en) * 2002-06-28 2004-08-19 Shell Oil Co A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
US7485597B2 (en) 2002-06-28 2009-02-03 Shell Oil Company Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
US7102022B2 (en) 2002-06-28 2006-09-05 Shell Oil Company Method for the start-up of an epoxidation process and a process for the epoxidation of an olefin
US7348444B2 (en) 2003-04-07 2008-03-25 Shell Oil Company Process for the production of an olefin oxide
EP1622709A2 (en) * 2003-04-23 2006-02-08 SD Lizenzverwertungsgesellschaft mbH & Co. KG Ethylene oxide catalyst
EP1622709A4 (en) * 2003-04-23 2007-09-05 Sd Lizenzverwertungsgesell Mbh Ethylene oxide catalyst
AU2004232807B2 (en) * 2003-04-23 2009-10-29 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Ethylene oxide catalyst
WO2004101144A1 (en) * 2003-05-07 2004-11-25 Shell Internationale Research Maatschappij B.V., Silver-containing catalysts, the manufacture of such silver­ containing catalysts, and the use thereof
US8043575B2 (en) 2003-05-07 2011-10-25 Shell Oil Company Reactor system and process for the manufacture of ethylene oxide
US8148555B2 (en) 2003-06-26 2012-04-03 Shell Oil Company Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
US7835868B2 (en) 2004-09-24 2010-11-16 Shell Oil Company Process for selecting shaped particles for use in a packed bed
US10532989B2 (en) 2007-05-09 2020-01-14 Shell Oil Company Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
US8921586B2 (en) 2008-05-07 2014-12-30 Shell Oil Company Process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
US9346774B2 (en) 2008-05-07 2016-05-24 Shell Oil Company Process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
US11801493B2 (en) 2016-12-02 2023-10-31 Shell Usa, Inc. Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide

Also Published As

Publication number Publication date
NL7413748A (en) 1975-04-29
PL99702B1 (en) 1978-08-31
JPS581629B2 (en) 1983-01-12
SE7412461L (en) 1975-04-28
FR2249087B1 (en) 1976-10-22
SE434837B (en) 1984-08-20
CA1048010A (en) 1979-02-06
ES431308A1 (en) 1976-11-16
DD114407A5 (en) 1975-08-05
FR2249087A1 (en) 1975-05-23
RO84369A (en) 1984-06-21
SE407156B (en) 1979-03-19
ES447632A1 (en) 1977-06-16
SE7808959L (en) 1978-08-24
RO84369B (en) 1984-08-30
JPS5074589A (en) 1975-06-19
IT1025175B (en) 1978-08-10
CS219313B2 (en) 1983-03-25
DE2448449C2 (en) 1986-03-06
DE2448449A1 (en) 1975-04-30
BE821439A (en) 1975-04-24
IN143192B (en) 1977-10-15

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19921024