GB1488659A - Gas and non-polar liquid purification - Google Patents
Gas and non-polar liquid purificationInfo
- Publication number
- GB1488659A GB1488659A GB254774A GB254774A GB1488659A GB 1488659 A GB1488659 A GB 1488659A GB 254774 A GB254774 A GB 254774A GB 254774 A GB254774 A GB 254774A GB 1488659 A GB1488659 A GB 1488659A
- Authority
- GB
- United Kingdom
- Prior art keywords
- component
- water
- gas
- soluble
- stretford
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Treating Waste Gases (AREA)
Abstract
1488659 H 2 S-removal; Stretford liquors BRITISH GAS CORP 15 Jan 1975 [16 Oct 1973 18 Jan 1974] 48084/73 and 02547/74 Heading ClA H 2 S is removed from gases or non-polar liquids by oxidation to elemental sulphur, by contacting the gas or liquid with an aqueous alkaline redox liquor containing (a) at least one water-soluble salt of an anthraquinone disulphonic acid, (b) at least one water-soluble compound of a metal, e.g. Fe, alkali metal or ammonium vanadates, which is capable of existing in at least two oxidation states, and (c) at least one water-soluble aromatic polyhydroxy compound. The redox liquor may also contain (d) a monohydric phenol. In the examples, Stretford liquors were used which contained NaHCO 3 and Na 2 CO 3 , and as component (a) the sodium salt of an anthraquinone disulphonic acid; as component (b) sodium metavanadate, as component (c) hydroquinone, and as component (d), phenol and ortho-, meta- and para-cresols. The solutions were used to remove H 2 S from "sour gases", using air to regenerate their oxidizing potential.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB254774A GB1488659A (en) | 1974-01-18 | 1974-01-18 | Gas and non-polar liquid purification |
JP50008296A JPS50104172A (en) | 1974-01-18 | 1975-01-18 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB254774A GB1488659A (en) | 1974-01-18 | 1974-01-18 | Gas and non-polar liquid purification |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1488659A true GB1488659A (en) | 1977-10-12 |
Family
ID=9741515
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB254774A Expired GB1488659A (en) | 1974-01-18 | 1974-01-18 | Gas and non-polar liquid purification |
Country Status (2)
Country | Link |
---|---|
JP (1) | JPS50104172A (en) |
GB (1) | GB1488659A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3216158A1 (en) * | 1982-04-30 | 1983-11-03 | Linde Ag, 6200 Wiesbaden | METHOD FOR REMOVING SULFUR HYDROGEN FROM GAS MIXTURES |
DE3239602A1 (en) * | 1982-10-26 | 1984-04-26 | Linde Ag, 6200 Wiesbaden | METHOD FOR REMOVING SULFUR HYDROGEN FROM GAS MIXTURES |
US4541998A (en) * | 1982-05-26 | 1985-09-17 | Linde Aktiengesellschaft | Thiocyanate to prevent the formation of thiosulfate in the oxidation of hydrogen sulfide |
US4687496A (en) * | 1985-04-17 | 1987-08-18 | Linde Aktiengesellschaft | Process for cleaning a packed column |
DE4130132A1 (en) * | 1991-09-07 | 1993-03-11 | Michael Wolter | Hydrogen sulphide absorption from gas with high carbon di:oxide content - in ferric amino-carboxylate soln. stabilised with alkali hydrogen carbonate to avoid oxidative decomposition of amino-carboxylate |
GB2436327A (en) * | 2006-03-24 | 2007-09-26 | Riverside Speciality Chemicals | A method of oxidation of vanadium (IV) ions |
EP2745914A3 (en) * | 2012-12-24 | 2015-03-25 | Université de Mons | Process for desulphurization of gases |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5479170A (en) * | 1977-12-08 | 1979-06-23 | Mitsubishi Rayon Co Ltd | Removing method for hydrogen sulfide |
-
1974
- 1974-01-18 GB GB254774A patent/GB1488659A/en not_active Expired
-
1975
- 1975-01-18 JP JP50008296A patent/JPS50104172A/ja active Pending
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3216158A1 (en) * | 1982-04-30 | 1983-11-03 | Linde Ag, 6200 Wiesbaden | METHOD FOR REMOVING SULFUR HYDROGEN FROM GAS MIXTURES |
US4541998A (en) * | 1982-05-26 | 1985-09-17 | Linde Aktiengesellschaft | Thiocyanate to prevent the formation of thiosulfate in the oxidation of hydrogen sulfide |
DE3239602A1 (en) * | 1982-10-26 | 1984-04-26 | Linde Ag, 6200 Wiesbaden | METHOD FOR REMOVING SULFUR HYDROGEN FROM GAS MIXTURES |
US4537752A (en) * | 1982-10-26 | 1985-08-27 | Linde Aktiengesellschaft | Method for removing hydrogen sulfide from gas streams |
US4687496A (en) * | 1985-04-17 | 1987-08-18 | Linde Aktiengesellschaft | Process for cleaning a packed column |
DE4130132A1 (en) * | 1991-09-07 | 1993-03-11 | Michael Wolter | Hydrogen sulphide absorption from gas with high carbon di:oxide content - in ferric amino-carboxylate soln. stabilised with alkali hydrogen carbonate to avoid oxidative decomposition of amino-carboxylate |
GB2436327A (en) * | 2006-03-24 | 2007-09-26 | Riverside Speciality Chemicals | A method of oxidation of vanadium (IV) ions |
GB2436327B (en) * | 2006-03-24 | 2011-06-29 | Riverside Speciality Chemicals Inc | Improvements relating to the oxidation of vanadium |
EP2745914A3 (en) * | 2012-12-24 | 2015-03-25 | Université de Mons | Process for desulphurization of gases |
Also Published As
Publication number | Publication date |
---|---|
JPS50104172A (en) | 1975-08-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |