GB1107005A - New organosilicon compounds and compositions containing them - Google Patents
New organosilicon compounds and compositions containing themInfo
- Publication number
- GB1107005A GB1107005A GB6031/66A GB603166A GB1107005A GB 1107005 A GB1107005 A GB 1107005A GB 6031/66 A GB6031/66 A GB 6031/66A GB 603166 A GB603166 A GB 603166A GB 1107005 A GB1107005 A GB 1107005A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formula
- compositions
- defined above
- compounds
- integer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 4
- 150000003961 organosilicon compounds Chemical class 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- FZENGILVLUJGJX-NSCUHMNNSA-N (E)-acetaldehyde oxime Chemical compound C\C=N\O FZENGILVLUJGJX-NSCUHMNNSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- VFURVLVRHAMJKG-UHFFFAOYSA-N dichloro-[2-[dichloro(methyl)silyl]ethyl]-methylsilane Chemical compound C[Si](Cl)(Cl)CC[Si](C)(Cl)Cl VFURVLVRHAMJKG-UHFFFAOYSA-N 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 229910000039 hydrogen halide Inorganic materials 0.000 abstract 1
- 239000012433 hydrogen halide Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000005055 methyl trichlorosilane Substances 0.000 abstract 1
- JLUFWMXJHAVVNN-UHFFFAOYSA-N methyltrichlorosilane Chemical compound C[Si](Cl)(Cl)Cl JLUFWMXJHAVVNN-UHFFFAOYSA-N 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 150000002923 oximes Chemical class 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
- 238000004073 vulcanization Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
- C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
- C08G77/388—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0892—Compounds with a Si-O-N linkage
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
Abstract
Novel compounds of the formula <FORM:1107005/C3/1> or <FORM:1107005/C3/2> wherein m and q are integers, p is 0 or an integer, a is 3 or 4, and each R individually is a monovalent hydrocarbon radical, unsubstituted or substituted by groups or atoms that do not interfere with vulcanization of compositions comprising the above compounds and a ,o - dihydroxydiorganopolysiloxanes, e.g. chlorine, nitro or alkyl substituents, may be prepared by condensing an aldoxime of formula R-CH = NOH, where R is as defined above, with the appropriate Si compound containing Si-halogen bonds, whereby hydrogen halide is eliminated. Specified Si compounds are 1,3-dimethyl 1,1,3,3 - tetrachlorosiloxane, methyltrichlorosilane, 1,2 - bis - (methyldichlorosilyl) ethane and 1,3,5,7 - tetramethyl - 1,3,5,7-tetrachlorocyclotetrasiloxane. An exemplified oxime is that of acetaldehyde; others are mentioned. Reaction is suitably effected in an inert organic solvent, e.g. diethyl ether, under anhydrous conditions and in the presence of an acid acceptor, e.g. a tertiary amine. Compositions vulcanizable by the action of liquid or vaporous water comprise at least one novel compound as defined above, and at least one a ,o -dihydroxydiorganopolysiloxane of the formula <FORM:1107005/C3/3> wherein R is as defined above, and n is an integer from 10-10,000. Fillers, e.g. silica, diluents, pigments and catalyst are optional additives. Films may be cast from such compositions.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR5396A FR1432799A (en) | 1965-02-12 | 1965-02-12 | Aldiminoxysilanes and siloxanes and compositions containing them |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1107005A true GB1107005A (en) | 1968-03-20 |
Family
ID=8570850
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB6031/66A Expired GB1107005A (en) | 1965-02-12 | 1966-02-11 | New organosilicon compounds and compositions containing them |
Country Status (2)
| Country | Link |
|---|---|
| FR (1) | FR1432799A (en) |
| GB (1) | GB1107005A (en) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2345457A1 (en) * | 1976-03-26 | 1977-10-21 | Gen Electric | Organofunctional (ketoximino) silanes - useful as crosslinkers, chain-extenders and -terminators for curable polydioganosiloxane compsns. |
| EP3385304B1 (en) | 2007-12-20 | 2020-07-15 | ELKEM SILICONES France SAS | Organopolysiloxane composition which can be vulcanised at ambient temperature in elastomer |
| FR2946656A1 (en) | 2009-06-12 | 2010-12-17 | Bluestar Silicones France | METHOD FOR SEALING AND ASSEMBLING COMPONENTS OF A MOTOR-PROPELLER GROUP |
| FR2946657A1 (en) | 2009-06-12 | 2010-12-17 | Bluestar Silicones France | METHOD FOR SEALING AND ASSEMBLING COMPONENTS OF A MOTOR-PROPELLER GROUP |
| FR2946654A1 (en) | 2009-06-15 | 2010-12-17 | Bluestar Silicones France | PROCESS FOR COATING A SILICONE COMPOSITION CONTAINING NO TIN ON A FLEXIBLE SUPPORT |
| FR2946655A1 (en) | 2009-06-15 | 2010-12-17 | Bluestar Silicones France | PROCESS FOR COATING A SILICONE COMPOSITION CONTAINING NO TIN ON A FLEXIBLE SUPPORT |
| WO2011114021A1 (en) | 2010-03-16 | 2011-09-22 | Bluestar Silicones France | Method and compositions for the sealing and assembly of power train components |
| EP2729533B1 (en) | 2011-07-07 | 2020-10-14 | ELKEM SILICONES France SAS | Uses of carbenes in solution as organopolysiloxane polycondensation catalysts |
| HUE045094T2 (en) | 2011-09-16 | 2019-12-30 | Elkem Silicones France Sas | Method and composition for sealing and assembling components of a power train |
| KR101779681B1 (en) | 2012-12-20 | 2017-09-18 | 블루스타 실리콘즈 프랑스 에스에이에스 | Article with antifouling properties, intended for aquatic uses and, in particular, for marine uses |
| CN104981524B (en) | 2012-12-20 | 2020-03-13 | 埃肯有机硅法国简易股份公司 | Organopolysiloxane compositions vulcanizable at ambient temperature into elastomers and novel organopolysiloxane polycondensation catalysts |
| FR3000090A1 (en) | 2012-12-20 | 2014-06-27 | Bluestar Silicones France | METHOD AND COMPOSITIONS USEFUL FOR SEALING AND ASSEMBLING COMPONENTS OF A MOTOR-PROPELLER GROUP |
| WO2014096567A1 (en) | 2012-12-20 | 2014-06-26 | Bluestar Silicones France Sas | Organopolysiloxane composition suitable for vulcanisation into an elastomer at room temperature and new organopolysiloxane polycondensation catalysts |
| FR2999980A1 (en) | 2012-12-20 | 2014-06-27 | Bluestar Silicones France | ARTICLE HAVING ANTIFOULING PROPERTIES AND INTENDED FOR USE IN AQUATIC APPLICATIONS, IN PARTICULAR MARINE |
| FR3014106B1 (en) | 2013-12-03 | 2017-03-10 | Bluestar Silicones France | CURABLE SILICONE COMPOSITION IN THE PRESENCE OF WATER OR HUMIDITY IN THE AIR |
| FR3014107A1 (en) | 2013-12-03 | 2015-06-05 | Bluestar Silicones France | ARTICLE HAVING ANTIFOULING PROPERTIES AND INTENDED FOR USE IN AQUATIC APPLICATIONS, IN PARTICULAR MARINE |
| WO2019002705A1 (en) | 2017-06-29 | 2019-01-03 | Elkem Silicones France Sas | Method for producing silicone elastomer moulds |
-
1965
- 1965-02-12 FR FR5396A patent/FR1432799A/en not_active Expired
-
1966
- 1966-02-11 GB GB6031/66A patent/GB1107005A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR1432799A (en) | 1966-03-25 |
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