FR3053350B1 - Composition liquide ou sirop comprenant un polymere a phases multiples et un polymere (meth)acrylique, sirop pour procede d'impregnation, procede d'impregnation pour un substrat fibreux, procede depolymerisation et article structure obtenu de celui-ci - Google Patents
Composition liquide ou sirop comprenant un polymere a phases multiples et un polymere (meth)acrylique, sirop pour procede d'impregnation, procede d'impregnation pour un substrat fibreux, procede depolymerisation et article structure obtenu de celui-ci Download PDFInfo
- Publication number
- FR3053350B1 FR3053350B1 FR1656099A FR1656099A FR3053350B1 FR 3053350 B1 FR3053350 B1 FR 3053350B1 FR 1656099 A FR1656099 A FR 1656099A FR 1656099 A FR1656099 A FR 1656099A FR 3053350 B1 FR3053350 B1 FR 3053350B1
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- France
- Prior art keywords
- syrup
- meth
- impregnation process
- polymer
- relates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000006188 syrup Substances 0.000 title abstract 8
- 235000020357 syrup Nutrition 0.000 title abstract 8
- 239000007788 liquid Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 5
- 239000000203 mixture Substances 0.000 title abstract 4
- 229920000058 polyacrylate Polymers 0.000 title abstract 4
- 229920000642 polymer Polymers 0.000 title abstract 4
- 238000005470 impregnation Methods 0.000 title abstract 3
- 239000000758 substrate Substances 0.000 title abstract 3
- 239000000178 monomer Substances 0.000 abstract 3
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 238000002360 preparation method Methods 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000012815 thermoplastic material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/02—Low molecular weight, e.g. <100,000 Da.
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/17—Viscosity
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/21—Rubbery or elastomeric properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2333/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2347/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
La présente invention concerne une composition liquide comprenant un monomère, un polymère (méth) acrylique et un polymère à phases multiples. En particulier, la présente invention concerne une composition liquide comprenant un monomère, un polymère (méth) acrylique et un polymère à phases multiples qui peuvent être utilisés en tant que sirop et spécialement en tant que sirop pour imprégnation et pour la préparation de, ou pour renforcer la résistance aux chocs d'un matériau thermoplastique obtenu après polymérisation du sirop. L'invention concerne également un procédé de fabrication d'un tel sirop. L'invention concerne également un procédé d'imprégnation d'un substrat fibreux de fibres longues avec ledit sirop liquide visqueux. L'invention concerne également un substrat fibreux préimprégné avec ledit sirop qui est utile pour la fabrication de pièces composites. Plus particulièrement, la présente invention concerne également un procédé de préparation d'une composition liquide comprenant un monomère (méth) acrylique, un polymère (méth) acrylique et un polymère à phases multiples.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1656099A FR3053350B1 (fr) | 2016-06-29 | 2016-06-29 | Composition liquide ou sirop comprenant un polymere a phases multiples et un polymere (meth)acrylique, sirop pour procede d'impregnation, procede d'impregnation pour un substrat fibreux, procede depolymerisation et article structure obtenu de celui-ci |
CN201780053563.9A CN109689776A (zh) | 2016-06-29 | 2017-06-29 | 包含多级聚合物和(甲基)丙烯酸类聚合物的液体组合物或浆液、用于浸渍法的浆液、用于纤维质基材的浸渍法、聚合方法及其获得的结构化制品 |
US16/311,760 US11142619B2 (en) | 2016-06-29 | 2017-06-29 | Liquid composition or syrup comprising a multistage polymer and a (meth)acrylic polymer, syrup for impregnation process, impregnation process for a fibrous substrate, a method of polymerization and structured article obtained thereof |
EP17732953.9A EP3478763A1 (fr) | 2016-06-29 | 2017-06-29 | Composition ou sirop liquide comprenant un polymère à couches multiples et un polymère (méth)acrylique, sirop destiné à un procédé d'imprégnation, procédé d'imprégnation destiné à un substrat fibreux, procédé de polymérisation et article structuré obtenu à partir de ce dernier |
PCT/EP2017/066201 WO2018002260A1 (fr) | 2016-06-29 | 2017-06-29 | Composition ou sirop liquide comprenant un polymère à couches multiples et un polymère (méth)acrylique, sirop destiné à un procédé d'imprégnation, procédé d'imprégnation destiné à un substrat fibreux, procédé de polymérisation et article structuré obtenu à partir de ce dernier |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1656099A FR3053350B1 (fr) | 2016-06-29 | 2016-06-29 | Composition liquide ou sirop comprenant un polymere a phases multiples et un polymere (meth)acrylique, sirop pour procede d'impregnation, procede d'impregnation pour un substrat fibreux, procede depolymerisation et article structure obtenu de celui-ci |
FR1656099 | 2016-06-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3053350A1 FR3053350A1 (fr) | 2018-01-05 |
FR3053350B1 true FR3053350B1 (fr) | 2020-03-27 |
Family
ID=57796401
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR1656099A Active FR3053350B1 (fr) | 2016-06-29 | 2016-06-29 | Composition liquide ou sirop comprenant un polymere a phases multiples et un polymere (meth)acrylique, sirop pour procede d'impregnation, procede d'impregnation pour un substrat fibreux, procede depolymerisation et article structure obtenu de celui-ci |
Country Status (5)
Country | Link |
---|---|
US (1) | US11142619B2 (fr) |
EP (1) | EP3478763A1 (fr) |
CN (1) | CN109689776A (fr) |
FR (1) | FR3053350B1 (fr) |
WO (1) | WO2018002260A1 (fr) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3053045B1 (fr) * | 2016-06-23 | 2020-06-19 | Arkema France | Preforme, son procede de preparation, son utilisation et composite comprenant celle-ci |
FR3068979B1 (fr) * | 2017-07-12 | 2020-07-31 | Arkema France | Composition d'adhesif (meth)acrylique, son procede de preparation et son utilisation |
JP7393367B2 (ja) | 2018-06-26 | 2023-12-06 | アルケマ フランス | 多段ポリマーをベースとする硬化性組成物 |
GB2575056A (en) * | 2018-06-27 | 2020-01-01 | Hexcel Composites Ltd | Curable compositions comprising filled multistage polymers |
FR3086294A1 (fr) * | 2018-09-25 | 2020-03-27 | Arkema France | Composition polymere pour vehicules nautiques, son utilisation et vehicule nautique comprenant celui-ci |
EP4004059A1 (fr) | 2019-07-31 | 2022-06-01 | Arkema France | Vernis à ongles à base de compositions photodurcissables |
EP3838936A1 (fr) * | 2019-12-19 | 2021-06-23 | Arkema France | Compositions durcissables comprenant des polymères à plusieurs étages |
FR3114099B1 (fr) * | 2020-09-17 | 2023-05-26 | Ceva Sante Animale | Composition fluide pour revetement de surface pour absorption et diffusion de composes volatils |
FR3114100B1 (fr) * | 2020-09-17 | 2023-05-12 | Melchior Material & Life Science France | Composition fluide pour revetement de surface pour absorption et diffusion de composes volatils |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
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KR0185028B1 (ko) * | 1995-06-21 | 1999-05-15 | 아이다 겐지 | (메트)아크릴계 성형재료 및 그의 제조방법 |
DE19812123A1 (de) * | 1998-03-19 | 1999-09-30 | Blanco Gmbh & Co Kg | Gießmassen für die Herstellung von Sanitärformteilen mit mehr als einer Sichtseite |
AU771383B2 (en) * | 1998-12-08 | 2004-03-18 | Rohm And Haas Company | Dirt pickup resistant coating binder and coatings |
US7056984B2 (en) * | 2001-05-15 | 2006-06-06 | Mitsubishi Gas Chemical Co., Inc. | Acrylic syrup and method of producing same |
JP2004123897A (ja) * | 2002-10-02 | 2004-04-22 | Japan U-Pica Co Ltd | 耐衝撃性成形材料組成物 |
US7005225B2 (en) * | 2002-11-12 | 2006-02-28 | Samsung Electronics Company | Organosol including amphipathic copolymeric binder having crystalline material, and use of the organosol to make dry tones for electrographic applications |
JP2005048059A (ja) * | 2003-07-29 | 2005-02-24 | Kuraray Co Ltd | 炭素繊維強化複合材用メタクリル系重合体組成物 |
JP2009149864A (ja) * | 2007-11-29 | 2009-07-09 | Mitsubishi Rayon Co Ltd | 多段階重合体とその製造方法、それを含有する樹脂組成物 |
FR2964970B1 (fr) | 2010-09-22 | 2013-11-01 | Arkema France | Nouveaux modifiants chocs et compositions thermoplastiques renforcees choc |
RU2013147679A (ru) * | 2011-03-28 | 2015-05-10 | Эвоник Рем ГмбХ | Формованные изделия из пластика для использования в качестве стекол легковых или грузопассажирских автомобилей |
EP2702112B1 (fr) * | 2011-04-27 | 2020-05-13 | Henkel IP & Holding GmbH | Compositions d'élastomères durcissables ayant une capacité d'étanchéité à basse température |
FR2981652B1 (fr) | 2011-10-21 | 2015-03-27 | Arkema France | Composites via la polymerisation in-situ de resines thermoplastiques methacryliques |
FR2993581B1 (fr) | 2012-07-18 | 2016-01-22 | Arkema France | Procede d'impregnation pour un substrat fibreux, sirop (meth)acrylique liquide pour le procede d'impregnation, son procede de polymerisation et produit structure obtenu a partir de celui-ci |
EP2933279B1 (fr) | 2012-12-24 | 2018-10-31 | LG Chem, Ltd. | Copolymère |
FR3002941B1 (fr) * | 2013-03-08 | 2015-04-10 | Arkema France | Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne |
FR3002940B1 (fr) * | 2013-03-08 | 2016-01-22 | Arkema France | Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux et son procede de fabrication, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne. |
FR3005057B1 (fr) | 2013-04-25 | 2015-05-15 | Arkema France | Sirop liquide (meth)acrylique, son procede de polymerisation, son utilisation et objet moule obtenu a partir de celui-ci |
WO2015098775A1 (fr) * | 2013-12-25 | 2015-07-02 | 株式会社カネカ | Composition de résine optique et article moulé |
FR3028859B1 (fr) * | 2014-11-24 | 2018-02-16 | Arkema France | Procede de fabrication multietapes d'un polymere, sa composition, son utilisation et composition comprenant celui-ci |
FR3030547B1 (fr) | 2014-12-22 | 2018-08-17 | Arkema France | Sirop (meth)acrylique liquide, procede d'impregnation d'un substrat fibreux par ledit sirop, et materiau composite obtenu apres polymerisation dudit sirop d'impregnation |
FR3030546B1 (fr) * | 2014-12-22 | 2018-04-06 | Arkema France | Sirop (meth)acrylique liquide, procede d'impregnation d'un substrat fibreux par ledit sirop, et materiau composite obtenu apres polymerisation dudit sirop d'impregnation |
FR3030585B1 (fr) | 2014-12-22 | 2017-02-03 | Arkema France | Procede d'impregnation d'un substrat fibreux avec un melange (meth)acrylique, composition dudit melange, et materiau composite obtenu apres polymerisation dudit melange. |
FR3046605B1 (fr) * | 2016-01-11 | 2019-09-06 | Arkema France | Composition liquide comprenant un polymere a phases multiples, son procede de preparation et son utilisation |
FR3046606B1 (fr) | 2016-01-11 | 2019-09-06 | Arkema France | Composition (meth)acrylique liquide comprenant un polymere a phases multiples et un monomere (meth)acrylique, son procede de preparation et son utilisation |
-
2016
- 2016-06-29 FR FR1656099A patent/FR3053350B1/fr active Active
-
2017
- 2017-06-29 WO PCT/EP2017/066201 patent/WO2018002260A1/fr unknown
- 2017-06-29 CN CN201780053563.9A patent/CN109689776A/zh active Pending
- 2017-06-29 EP EP17732953.9A patent/EP3478763A1/fr active Pending
- 2017-06-29 US US16/311,760 patent/US11142619B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
US11142619B2 (en) | 2021-10-12 |
FR3053350A1 (fr) | 2018-01-05 |
CN109689776A (zh) | 2019-04-26 |
WO2018002260A1 (fr) | 2018-01-04 |
US20190233603A1 (en) | 2019-08-01 |
EP3478763A1 (fr) | 2019-05-08 |
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