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FR3053350B1 - Composition liquide ou sirop comprenant un polymere a phases multiples et un polymere (meth)acrylique, sirop pour procede d'impregnation, procede d'impregnation pour un substrat fibreux, procede depolymerisation et article structure obtenu de celui-ci - Google Patents

Composition liquide ou sirop comprenant un polymere a phases multiples et un polymere (meth)acrylique, sirop pour procede d'impregnation, procede d'impregnation pour un substrat fibreux, procede depolymerisation et article structure obtenu de celui-ci Download PDF

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Publication number
FR3053350B1
FR3053350B1 FR1656099A FR1656099A FR3053350B1 FR 3053350 B1 FR3053350 B1 FR 3053350B1 FR 1656099 A FR1656099 A FR 1656099A FR 1656099 A FR1656099 A FR 1656099A FR 3053350 B1 FR3053350 B1 FR 3053350B1
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France
Prior art keywords
syrup
meth
impregnation process
polymer
relates
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FR1656099A
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FR3053350A1 (fr
Inventor
Pierre ESCALE
Pierre Gerard
Aline COUFFIN
Raber Inoubli
Philippe Hajji
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Arkema France SA
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Arkema France SA
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Application filed by Arkema France SA filed Critical Arkema France SA
Priority to FR1656099A priority Critical patent/FR3053350B1/fr
Priority to CN201780053563.9A priority patent/CN109689776A/zh
Priority to US16/311,760 priority patent/US11142619B2/en
Priority to EP17732953.9A priority patent/EP3478763A1/fr
Priority to PCT/EP2017/066201 priority patent/WO2018002260A1/fr
Publication of FR3053350A1 publication Critical patent/FR3053350A1/fr
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Publication of FR3053350B1 publication Critical patent/FR3053350B1/fr
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10Homopolymers or copolymers of methacrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/02Low molecular weight, e.g. <100,000 Da.
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/17Viscosity
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/21Rubbery or elastomeric properties
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/10Homopolymers or copolymers of methacrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2347/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Derivatives of such polymers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

La présente invention concerne une composition liquide comprenant un monomère, un polymère (méth) acrylique et un polymère à phases multiples. En particulier, la présente invention concerne une composition liquide comprenant un monomère, un polymère (méth) acrylique et un polymère à phases multiples qui peuvent être utilisés en tant que sirop et spécialement en tant que sirop pour imprégnation et pour la préparation de, ou pour renforcer la résistance aux chocs d'un matériau thermoplastique obtenu après polymérisation du sirop. L'invention concerne également un procédé de fabrication d'un tel sirop. L'invention concerne également un procédé d'imprégnation d'un substrat fibreux de fibres longues avec ledit sirop liquide visqueux. L'invention concerne également un substrat fibreux préimprégné avec ledit sirop qui est utile pour la fabrication de pièces composites. Plus particulièrement, la présente invention concerne également un procédé de préparation d'une composition liquide comprenant un monomère (méth) acrylique, un polymère (méth) acrylique et un polymère à phases multiples.
FR1656099A 2016-06-29 2016-06-29 Composition liquide ou sirop comprenant un polymere a phases multiples et un polymere (meth)acrylique, sirop pour procede d'impregnation, procede d'impregnation pour un substrat fibreux, procede depolymerisation et article structure obtenu de celui-ci Active FR3053350B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1656099A FR3053350B1 (fr) 2016-06-29 2016-06-29 Composition liquide ou sirop comprenant un polymere a phases multiples et un polymere (meth)acrylique, sirop pour procede d'impregnation, procede d'impregnation pour un substrat fibreux, procede depolymerisation et article structure obtenu de celui-ci
CN201780053563.9A CN109689776A (zh) 2016-06-29 2017-06-29 包含多级聚合物和(甲基)丙烯酸类聚合物的液体组合物或浆液、用于浸渍法的浆液、用于纤维质基材的浸渍法、聚合方法及其获得的结构化制品
US16/311,760 US11142619B2 (en) 2016-06-29 2017-06-29 Liquid composition or syrup comprising a multistage polymer and a (meth)acrylic polymer, syrup for impregnation process, impregnation process for a fibrous substrate, a method of polymerization and structured article obtained thereof
EP17732953.9A EP3478763A1 (fr) 2016-06-29 2017-06-29 Composition ou sirop liquide comprenant un polymère à couches multiples et un polymère (méth)acrylique, sirop destiné à un procédé d'imprégnation, procédé d'imprégnation destiné à un substrat fibreux, procédé de polymérisation et article structuré obtenu à partir de ce dernier
PCT/EP2017/066201 WO2018002260A1 (fr) 2016-06-29 2017-06-29 Composition ou sirop liquide comprenant un polymère à couches multiples et un polymère (méth)acrylique, sirop destiné à un procédé d'imprégnation, procédé d'imprégnation destiné à un substrat fibreux, procédé de polymérisation et article structuré obtenu à partir de ce dernier

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1656099A FR3053350B1 (fr) 2016-06-29 2016-06-29 Composition liquide ou sirop comprenant un polymere a phases multiples et un polymere (meth)acrylique, sirop pour procede d'impregnation, procede d'impregnation pour un substrat fibreux, procede depolymerisation et article structure obtenu de celui-ci
FR1656099 2016-06-29

Publications (2)

Publication Number Publication Date
FR3053350A1 FR3053350A1 (fr) 2018-01-05
FR3053350B1 true FR3053350B1 (fr) 2020-03-27

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FR1656099A Active FR3053350B1 (fr) 2016-06-29 2016-06-29 Composition liquide ou sirop comprenant un polymere a phases multiples et un polymere (meth)acrylique, sirop pour procede d'impregnation, procede d'impregnation pour un substrat fibreux, procede depolymerisation et article structure obtenu de celui-ci

Country Status (5)

Country Link
US (1) US11142619B2 (fr)
EP (1) EP3478763A1 (fr)
CN (1) CN109689776A (fr)
FR (1) FR3053350B1 (fr)
WO (1) WO2018002260A1 (fr)

Families Citing this family (9)

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FR3053045B1 (fr) * 2016-06-23 2020-06-19 Arkema France Preforme, son procede de preparation, son utilisation et composite comprenant celle-ci
FR3068979B1 (fr) * 2017-07-12 2020-07-31 Arkema France Composition d'adhesif (meth)acrylique, son procede de preparation et son utilisation
JP7393367B2 (ja) 2018-06-26 2023-12-06 アルケマ フランス 多段ポリマーをベースとする硬化性組成物
GB2575056A (en) * 2018-06-27 2020-01-01 Hexcel Composites Ltd Curable compositions comprising filled multistage polymers
FR3086294A1 (fr) * 2018-09-25 2020-03-27 Arkema France Composition polymere pour vehicules nautiques, son utilisation et vehicule nautique comprenant celui-ci
EP4004059A1 (fr) 2019-07-31 2022-06-01 Arkema France Vernis à ongles à base de compositions photodurcissables
EP3838936A1 (fr) * 2019-12-19 2021-06-23 Arkema France Compositions durcissables comprenant des polymères à plusieurs étages
FR3114099B1 (fr) * 2020-09-17 2023-05-26 Ceva Sante Animale Composition fluide pour revetement de surface pour absorption et diffusion de composes volatils
FR3114100B1 (fr) * 2020-09-17 2023-05-12 Melchior Material & Life Science France Composition fluide pour revetement de surface pour absorption et diffusion de composes volatils

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FR3030546B1 (fr) * 2014-12-22 2018-04-06 Arkema France Sirop (meth)acrylique liquide, procede d'impregnation d'un substrat fibreux par ledit sirop, et materiau composite obtenu apres polymerisation dudit sirop d'impregnation
FR3030585B1 (fr) 2014-12-22 2017-02-03 Arkema France Procede d'impregnation d'un substrat fibreux avec un melange (meth)acrylique, composition dudit melange, et materiau composite obtenu apres polymerisation dudit melange.
FR3046605B1 (fr) * 2016-01-11 2019-09-06 Arkema France Composition liquide comprenant un polymere a phases multiples, son procede de preparation et son utilisation
FR3046606B1 (fr) 2016-01-11 2019-09-06 Arkema France Composition (meth)acrylique liquide comprenant un polymere a phases multiples et un monomere (meth)acrylique, son procede de preparation et son utilisation

Also Published As

Publication number Publication date
US11142619B2 (en) 2021-10-12
FR3053350A1 (fr) 2018-01-05
CN109689776A (zh) 2019-04-26
WO2018002260A1 (fr) 2018-01-04
US20190233603A1 (en) 2019-08-01
EP3478763A1 (fr) 2019-05-08

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