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FR2717816B1 - Composante catalytique pour la polymérisation des oléfines obtenue par impregnation d'un prépolymère par une solution d'une composante catalytique. Prépolymère et polymère obtenus à partir de ladite composante catalytique. - Google Patents

Composante catalytique pour la polymérisation des oléfines obtenue par impregnation d'un prépolymère par une solution d'une composante catalytique. Prépolymère et polymère obtenus à partir de ladite composante catalytique.

Info

Publication number
FR2717816B1
FR2717816B1 FR9403420A FR9403420A FR2717816B1 FR 2717816 B1 FR2717816 B1 FR 2717816B1 FR 9403420 A FR9403420 A FR 9403420A FR 9403420 A FR9403420 A FR 9403420A FR 2717816 B1 FR2717816 B1 FR 2717816B1
Authority
FR
France
Prior art keywords
catalytic component
prepolymer
impregnating
compsn
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR9403420A
Other languages
English (en)
Other versions
FR2717816A1 (fr
Inventor
Jean Malinge
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Elf Atochem SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=9461352&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=FR2717816(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Elf Atochem SA filed Critical Elf Atochem SA
Priority to FR9403420A priority Critical patent/FR2717816B1/fr
Priority to ES95400524T priority patent/ES2112020T3/es
Priority to EP95400524A priority patent/EP0673950B1/fr
Priority to CA002144472A priority patent/CA2144472A1/fr
Priority to AT95400524T priority patent/ATE161551T1/de
Priority to DE69501277T priority patent/DE69501277T2/de
Priority to KR1019950006007A priority patent/KR100397861B1/ko
Priority to FI951347A priority patent/FI951347A/fi
Priority to NO951097A priority patent/NO951097L/no
Priority to CN95103087A priority patent/CN1068605C/zh
Priority to JP7090153A priority patent/JPH07268016A/ja
Publication of FR2717816A1 publication Critical patent/FR2717816A1/fr
Publication of FR2717816B1 publication Critical patent/FR2717816B1/fr
Application granted granted Critical
Priority to US08/953,296 priority patent/US6551956B1/en
Priority to US10/379,728 priority patent/US7019090B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/627—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/629—Catalysts containing a specific non-metal or metal-free compound organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
FR9403420A 1994-03-23 1994-03-23 Composante catalytique pour la polymérisation des oléfines obtenue par impregnation d'un prépolymère par une solution d'une composante catalytique. Prépolymère et polymère obtenus à partir de ladite composante catalytique. Expired - Fee Related FR2717816B1 (fr)

Priority Applications (13)

Application Number Priority Date Filing Date Title
FR9403420A FR2717816B1 (fr) 1994-03-23 1994-03-23 Composante catalytique pour la polymérisation des oléfines obtenue par impregnation d'un prépolymère par une solution d'une composante catalytique. Prépolymère et polymère obtenus à partir de ladite composante catalytique.
ES95400524T ES2112020T3 (es) 1994-03-23 1995-03-13 Componente catalitico para la polimerizacion de las olefinas, obtenido por impregnacion de un copolimero con una solucion de un componente catalitico y polimero obtenido a partir del citado componente catalitico.
EP95400524A EP0673950B1 (fr) 1994-03-23 1995-03-13 Composante catalytique pour la polymérisation des oléfines obtenue par imprégnation d'un prépolymère par une solution d'une composante catalytique et polymère obtenue à partir de ladite composante catalytique
CA002144472A CA2144472A1 (fr) 1994-03-23 1995-03-13 Composante catalytique pour la polymerisation des olefines obtenue par impregnation d'un prepolymere par une solution d'une composante catalytique. prepolymere obtenu a partir de ladite composante catalytique
AT95400524T ATE161551T1 (de) 1994-03-23 1995-03-13 Katalysatorkomponente zur olefinpolymerisation, erhalten durch impregnierung eines prepolymeren mit einer lösung einer katalysator komponente und unter verwendung dieser katalysatorkomponente erhaltenes polymer
DE69501277T DE69501277T2 (de) 1994-03-23 1995-03-13 Katalysatorkomponente zur Olefinpolymerisation, erhalten durch Impregnierung eines Prepolymeren mit einer Lösung einer Katalysator komponente und unter Verwendung dieser Katalysatorkomponente erhaltenes Polymer
KR1019950006007A KR100397861B1 (ko) 1994-03-23 1995-03-21 예비중합체를촉매성분용액에함침함으로써제조되는올레핀의중합용촉매성분및그촉매성분으로부터제조되는예비중합체
NO951097A NO951097L (no) 1994-03-23 1995-03-22 Katalytisk komponent for polymerisering av olefiner, oppnådd ved impregnering av en forpolymer med en opplösning av en katalytisk komponent samt den fra komponenten oppnådde forpolymer
FI951347A FI951347A (fi) 1994-03-23 1995-03-22 Katalyyttinen komponentti olefiinien polymeroimiseksi ja esipolymeeri, joka on saatu lähtien tästä katalyyttisestä komponentista
CN95103087A CN1068605C (zh) 1994-03-23 1995-03-23 烯烃聚合用催化组分及用于它的预聚物
JP7090153A JPH07268016A (ja) 1994-03-23 1995-03-23 触媒成分の溶液をプレポリマーに含浸して得られるオレフィン重合触媒成分と、この触媒成分から得られるプレポリマー
US08/953,296 US6551956B1 (en) 1994-03-23 1997-10-17 Catalytic component for the polymerization of olefins obtained by impregnation of a prepolymer with a solution of a catalytic component, and the prepolymer obtained from the catalytic component
US10/379,728 US7019090B2 (en) 1994-03-23 2003-03-06 Catalytic component for the polymerization of olefins obtained by impregnation of a prepolymer with a solution of a catalytic component, prepolymer obtained from the catalytic component and polymerization process using said catalytic component

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9403420A FR2717816B1 (fr) 1994-03-23 1994-03-23 Composante catalytique pour la polymérisation des oléfines obtenue par impregnation d'un prépolymère par une solution d'une composante catalytique. Prépolymère et polymère obtenus à partir de ladite composante catalytique.

Publications (2)

Publication Number Publication Date
FR2717816A1 FR2717816A1 (fr) 1995-09-29
FR2717816B1 true FR2717816B1 (fr) 1996-04-26

Family

ID=9461352

Family Applications (1)

Application Number Title Priority Date Filing Date
FR9403420A Expired - Fee Related FR2717816B1 (fr) 1994-03-23 1994-03-23 Composante catalytique pour la polymérisation des oléfines obtenue par impregnation d'un prépolymère par une solution d'une composante catalytique. Prépolymère et polymère obtenus à partir de ladite composante catalytique.

Country Status (12)

Country Link
US (2) US6551956B1 (fr)
EP (1) EP0673950B1 (fr)
JP (1) JPH07268016A (fr)
KR (1) KR100397861B1 (fr)
CN (1) CN1068605C (fr)
AT (1) ATE161551T1 (fr)
CA (1) CA2144472A1 (fr)
DE (1) DE69501277T2 (fr)
ES (1) ES2112020T3 (fr)
FI (1) FI951347A (fr)
FR (1) FR2717816B1 (fr)
NO (1) NO951097L (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1269931B (it) * 1994-03-29 1997-04-16 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
KR970015607A (ko) * 1995-09-14 1997-04-28 크리스탄 플뢰미히 다수의 고체 촉매성분을 결합시키는 올레핀 중합을 위한 초기중합체
FR2738829B1 (fr) * 1995-09-19 1997-10-17 Atochem Elf Sa Prepolymere pour la polymerisation des olefines, associant plusieurs composantes catalytiques solides
EP0816394B1 (fr) * 1996-06-26 2002-01-30 BP Chemicals S.N.C. Procédé de polymérisation de l'éthylène en phase gazeuse
ES2171640T3 (es) 1996-06-26 2002-09-16 Bp Chem Int Ltd Procedimiento para la polimerizacion de etileno en fase gaseosa.
ES2198098T3 (es) 1998-03-09 2004-01-16 Basell Poliolefine Italia S.P.A. Procedimiento multietapas para la polimerizacion de olefinas.
US6136747A (en) * 1998-06-19 2000-10-24 Union Carbide Chemicals & Plastics Technology Corporation Mixed catalyst composition for the production of olefin polymers
ITMI991552A1 (it) * 1999-07-14 2001-01-14 Licio Zambon Componenti di catalizzatori per la polimerizzazione di olefine
US7991291B2 (en) * 2007-02-08 2011-08-02 Finisar Corporation WDM PON based on DML
CN101274968B (zh) * 2007-03-28 2012-11-21 中国石油化工股份有限公司 一种用于生产宽分子量分布的聚乙烯的复合催化剂

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0745541B2 (ja) 1986-10-02 1995-05-17 チッソ株式会社 ポリオレフイン製造用固体触媒成分の製造法
US4921825A (en) 1986-12-30 1990-05-01 Mitsui Petrochemical Industries, Ltd. Solid catalyst for olefin polymerization and processes for its production
US5122583A (en) * 1987-02-02 1992-06-16 Fina Technology, Inc. Efficiency of a pre-polymerized catalyst
US5120696A (en) 1989-12-29 1992-06-09 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for the polymerization of olefins
US5266544A (en) 1989-12-29 1993-11-30 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for the polymerization of olefins
FR2659336B1 (fr) * 1990-03-12 1993-05-07 Bp Chemicals Snc Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
MY141000A (en) * 1990-04-18 2010-02-12 Mitsui Chemicals Inc Process for the preparation of an ethylene copolymer and an olefin polymer, and catalysts for olefin polymerization
DE4119343A1 (de) * 1991-06-12 1992-12-17 Basf Ag Isolierbares, getraegertes katalysatorsystem zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen
FI112233B (fi) * 1992-04-01 2003-11-14 Basell Polyolefine Gmbh Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö
US5804524A (en) * 1993-04-28 1998-09-08 Fina Technology, Inc. Process for a isotactic/syndiotactic polymer blend in a single reactor
BE1007040A3 (fr) 1993-05-25 1995-02-28 Solvay Support de catalyseur et catalyseur de polymerisation des alpha-olefines; procedes pour leur obtention et polymerisation des alpha-olefines en presence du catalyseur.
IT1269931B (it) * 1994-03-29 1997-04-16 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine

Also Published As

Publication number Publication date
FI951347A0 (fi) 1995-03-22
NO951097L (no) 1995-09-25
CN1068605C (zh) 2001-07-18
FI951347A (fi) 1995-09-24
ATE161551T1 (de) 1998-01-15
EP0673950B1 (fr) 1997-12-29
NO951097D0 (no) 1995-03-22
DE69501277D1 (de) 1998-02-05
CN1112131A (zh) 1995-11-22
CA2144472A1 (fr) 1995-09-24
JPH07268016A (ja) 1995-10-17
KR950032331A (ko) 1995-12-20
US6551956B1 (en) 2003-04-22
KR100397861B1 (ko) 2003-12-18
EP0673950A1 (fr) 1995-09-27
US7019090B2 (en) 2006-03-28
DE69501277T2 (de) 1998-07-16
ES2112020T3 (es) 1998-03-16
FR2717816A1 (fr) 1995-09-29
US20030171208A1 (en) 2003-09-11

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