ES2272562T3 - HIGHLY RAMIFIED POLYMERS FOR FINISHING AGAINST WRINKLES OF CELLULOSE TEXTILES. - Google Patents

Abstract

A process for wrinkleproofing cellulosic textiles by treating the textiles with a finish and drying the treated textiles, which comprises using a finish comprising one or more highly branched polymers in dissolved or dispersed form.

Description

Highly branched polymers for finishing against wrinkles of textiles containing cellulose.

The invention relates to methods for finishing against wrinkles of textiles containing cellulose, to agents for finishing against wrinkles, which contain polymers highly branched, to the use of finishing agents and highly branched polymers, as well as agents for treatment of textiles, to solid and liquid formulations of washing agents and laundry care agents, containing highly branched polymers.

Textiles containing cellulose are subjected to an easy maintenance finish for example by treatment with condensation products consisting of urea, glyoxal and formaldehyde. The finishing is carried out in this case during the manufacture of textile materials. For the finishing they are used frequently other additives such as softening compounds. Textiles, ennobled in this way, have, against untreated cellulose textiles, after the procedure of washing, the advantage of having a smaller amount of wrinkles and of folds, they can be ironed more easily and are soft and smooth.

It is known from publication WO 92/01773 on use of microemulsified aminosiloxanes in rinses softeners to reduce wrinkle formation and folds during the washing process (finished to reduce the wrinkles) At the same time ironing would be facilitated by use of aminosiloxanes.

It is known from publication WO 98/4772 a procedure for the pretreatment of textile materials, applying a mixture consisting of a polycarboxylic acid and by a cationic softener on textile materials. Of this mode protection against wrinkle formation is achieved.

They are known by the publication EP-A 0 300 525 softener rinses based on cross-linkable, aminofunctionalized silicones that cause a protection against the formation of wrinkles on textiles treated with them.

They are known by publication WO 99/55953 formulations that cause an effect against wrinkle formation during the treatment of textiles. The formulations are constituted by sliding agents, polymers, which are responsible for the dimensional and geometric stability of textiles, salts of lithium and, optionally, other components such as softeners, ionic and non-ionic surfactants, odor binding substances and bactericides. The application of the formulation on the product Textile is preferably carried out by spraying.

EP-A publication 0 978 556 describes a mixture consisting of a plasticizer and a crosslinking component with cationic properties as an agent for provide textiles with protection against the formation of wrinkles and creases, as well as a procedure for finishing Against the wrinkles of textiles.

They are known by publication WO 01 / 25385A softening compositions, which cause an effect against wrinkles  in treated textiles. The compositions contain polyorganosiloxane and other additives such as for example polyurethane.

They are known by publication US3905929A polyurethanes that can be used for finishing against wrinkles

They are known by publication DE19904444A highly branched dendrimers or polyurethanes.

They are known by publication EP0779358A washing agent compositions containing surfactants, adjuvants and dendrimer macromolecules as inhibitors for Run of the colors.

The task of the invention is to put provision another procedure for finishing against wrinkles of textiles containing cellulose as well as other agents for the wrinkle finish of such textiles.

The task is solved by means of a procedure for finishing against textile wrinkles that they contain cellulose by treating textiles with a finishing and drying agent of treated textiles, characterized because the finishing agent contains one or more polymers highly branched in dissolved or dispersed form.

The task is solved, also, by a finishing agent against textile wrinkles containing cellulose, which contain these highly branched polymers.

Highly branched polymers are themselves. known. Star brush-shaped polymers and hyperbranched polymers are designations for structures polymers characterized by a branched structure and by High functionality

The dendrimers are constituted by unitary macromolecules from the molecular point of view and structural with a highly symmetric constitution. These will they form by synthesis with many stages and therefore they are very expensive.

On the contrary, hyperbranched polymers they are not unitary neither from the molecular point of view nor from the structural point of view. These have branches of lengths variables and ramifications. Highly branched polymers, used according to the invention, are preferably such polymers hyperbranched in the strict sense of the word. But nevertheless unit dendrimer polymers can also be used from the structural and molecular point of view. The expression "polymers highly branched "within the meaning of this invention encompasses, therefore, hyperbranched polymers and polymers dendrimers

The highly branched polymers, used according to the invention, they can also be specially manufactured to from the so-called monomers AB_ {x}. These present two different functional groups A and B, which can react with each other by forming a link. Functional group A is content in this case only once per molecule and group Functional B is contained two or several times. By reaction of the monomers AB x together form polymers not crosslinked with branching points ordered so homogeneous Polymers present at the ends of the chains almost exclusively groups B. More details have been described precise for example in the publication of J.M.S. - Rev. Macromol. Chem. Phys., C37 (3), 555-579 (1997).

The highly branched polymers, which they present functional groups, they can be synthesized, in principle, of shape and manner known with the use of AB_ {x} monomers, preferably of monomers AB2. AB 2 monomers they may be constituted in this case completely in the form of ramifications, may be incorporated as terminal groups, that is, they still have two free B groups, or they can incorporate as linear groups with a free group B. The highly branched polymers, obtained, present, according to the degree of polymerization, a greater or lesser number of groups B, either as terminal groups or as lateral groups. Other indications concerning hyperbranched polymers and their syntheses are found, for example, in J.M.S. - Rev. Macromol. Chem. Phys., C37 (3), 555-579 (1997) and in Literature cited there.

The choice of highly polymers branched for use in the process according to the invention for the finish against wrinkles is not limited, in principle, to a certain class of polymers. They come into consideration highly branched polyesters, highly branched polyethers, highly branched polyurethanes, highly polyureaurethanes branched, highly branched polyamines, highly polyamides branched, highly branched polysiloxanes, carbosilanes highly branched, highly branched polyetheramides as well as highly branched polyesteramides. However they have revealed as highly suitable polyurethanes highly branched, highly branched polyesters, polyethers highly branched, highly branched polyesteramides and highly branched polyamines. Among the polyamines Highly branched, especially the highly branched polyethyleneimines. They are very especially highly branched polyurethanes are preferred.

Highly branched polymers can be manufactured for example as follows:

-

the highly branched polyurethanes according to WO 97/02304 or according to publication DE 199 04 444

-

the highly branched polyesters according to publication SE 468771 or according to publication SE 503342

-

the highly branched polyethers according to DE 199 47 631

-

the highly branched polyesteramides according to the publication    WO 99/16810

-

the highly branched polyamines according to WO publication 93/14147.

Highly branched and highly polymers functional, obtained by polymerization of molecules of AB2 can be used, in principle, as such in the agents for finishing according to the invention, provided that during the corresponding embodiment of the synthesis, the groups obtained functionalities are suitable for the use of polymers in dissolved or dispersed form.

Groups B, originally present, can transfunctionalized by reaction similar to polymerization with compounds suitable for it.

Examples of suitable functional groups, which can be introduced by appropriate participants in the reaction especially include groups that have atoms of H, acidic or basic, as well as its derivatives, such as -COOH, -COOR, -CONHR, -CONH2, -OH, -SH, -NH2, -NHR, -NR2, -NR 3 +, -SO 3 H, -SO 3 R -NHCOOR, -NHCONH 2, -NHCONHR or its salts. R remains are constituted, as a rule general, by straight chain or chain alkyl moieties branched, which may be additionally substituted, by example may be alkyl radicals with 1 to 8 carbon atoms. By therefore, other functional groups can also be introduced such as -CN or -OR.

In a preferred embodiment, the highly branched polymers, used according to the invention, they present one or several functional groups, chosen from the group consisting of -COOH, -COOR, -CONHR, -CONH2, -OH, -SH, -NH 2, -NHR, -NR 2, -NR 3 +, -SO 3 H, -SO 3 R, -NHCOOR, -NHCONH2, -NHCONHR or its salts.

The compounds, used for transfunctionalization can include groups desired functional as well as a second group, which is capable of react with the B groups of the highly branched polymer, used as a starting material, with the formation of a link. A example is the reaction of an isocyanate group with an acid hydroxycarboxylic.

However, compounds may also be used. monofunctional, with which simply modify the groups present. As an example, halides of alkyl for quaternization of the amino groups present.

Transfunctionalization of polymers hyperbranched can be carried out, advantageously, immediately after the polymerization reaction or in a separate reaction

The functional groups, which have a sufficient number of acidic H atoms can be transformed into corresponding salts by treatment with suitable bases. In an analogous way they can be transformed into salts corresponding the basic groups with suitable acids. Of this so highly branched polymers soluble in Water.

In the same way polymers can be generated highly branched that present diverse functionalities. This it can be carried out by reaction with a mixture of various compounds for transfunctionalization or also if done react only part of the functional groups originally present.

According to the intended employment, they can the degree of polymerization chosen by the person skilled in the art, molecular weight as well as the type and number of groups functional.

The especially preferred functional groups are -COOH, -CONH2, -OH, - NH2, -NHR, -NR2, -NR 3 + and -SO 3 H and their salts

In a special embodiment, the highly branched polymers, used according to the invention, they present one or several functional groups, chosen from the group consisting of -COOH, -OH, -SO3H and their salts.

In another embodiment, especially, the highly branched polymers, used according to the invention, they have one or more functional groups chosen from the group consisting of -NH2, -NHR, -NR2, -NR3 + and their you go out.

The highly branched polymers, used according to the invention, they have, on average, at least 4 groups functional per molecule. In principle, it is not limited to above the number of functional groups. Of course, the products with too many functional groups present frequently undesirable properties, such as for example a poor solubility or a very high viscosity. Therefore, the highly branched polymers, used according to the invention, preferably, on average, no more than 200 groups functional. Preferably, highly branched polymers they present, on average, from 4 to 150 and, especially preferred, from 4 to 100 functional groups.

The molecular weights of polymers highly branched, used according to the invention, depend on the class corresponding polymer and will be chosen accordingly by the technician in the field. They have been credited, however, products with a weight average molecular weight M w from 1,000 up to 20,000 g / mol, preferably from 1,000 to 100,000 g / mol

Preferred highly branched polymers, which are used in the finishing agents according to the invention, are highly branched polyurethanes.

The expression "polyurethanes" in the sense of this invention encompasses, beyond what is understood by the same, usually, polymers that can be obtained by reaction of diisocyanates or polyisocyanates with compounds with active hydrogen and that can be linked through structures of urethane as well as, for example, by means of structures of urea, allophanate, biuret, carbodiimide, amide, uretonimine, uretodione, isocyanurate or oxazolidone.

For the synthesis of polyurethanes highly branched, used according to the invention, will be used preferably AB_ monomers, which have both groups isocyanate as well as groups that can react with the groups isocyanate with bond formation. In this case x is a number natural between 2 and 8, preferably means 2 or 3. In this case A is an isocyanate group and B is a reactive group with the same, or the reverse case is presented.

Reactive groups with isocyanate groups they are preferably constituted by OH-, NH2-, NHR- or groups SH-.

AB x monomers can be manufactured from known way and form. AB x monomers can synthesized, for example, according to the method described in the WO 97/02304 publication using group techniques protectors As an example this technique has been explained for manufacture of a monomer AB2 from 2,4-toluylenediisocyanate (TDI) and trimethylolpropane First one of the groups is masked TDI isocyanate in known manner and manner, for example by reaction with an oxime. The free, remaining NCO group is reacts with trimethylolpropane, reacting only one of the three OH groups with the isocyanate group, while two OH groups are blocked by acetalization. After dissociation of protective group a molecule with an isocyanate group is obtained and with 2 OH groups.

In an especially advantageous way they can AB x molecules are synthesized according to the method described in the publication DE-A 199 04 444, according to which no They require protective groups. In this method they are used diisocyanates or polyisocyanates and are reacted with compounds that have at least two reactive groups with the isocyanate groups. At least one of the participants in the reaction it presents, in this case, groups with a variable reactivity against to the other participant in the reaction. The conditions for reaction will be chosen in such a way that they can only react each other certain reactive groups.

How diisocyanates and polyisocyanates enter consideration of aliphatic, cycloaliphatic and isocyanates aromatics known from the state of the art. Diisocyanates or preferred polyisocyanates are the 4,4'-diphenylmethanediisocyanate, mixtures constituted by monomeric diphenylmethanediisocyanates and by oligomeric diphenylmethanediisocyanates (MDI polymer), the tetramethylene diisocyanate, hexamethylene diisocyanate, 4,4'-methylenebis (cyclohexyl) -diisocyanate,  xylylenediisocyanate, tetramethylxylenediisocyanate, dodecyldiisocyanate, the diisocyanate of alkyl esters of lysine, meaning alkyl, an alkyl with 1 to 10 atoms of carbon, 2,2,4- or 2,4,4-trimethyl-1,6-hexamethylene diisocyanate, 1,4-diisocyancyclohexane or 4-isocyanatomethyl-1,8-octamethylene diisocyanate.

Diisocyanates are especially preferred or polyisocyanates with NCO groups of different reactivity, such as 2,4-toluylenediisocyanate (2,4-TDI), the 2,4'-diphenylmethanediisocyanate (2,4'-MDI), the triisocyanatoluene, the isophorone diisocyanate (IPDI), the 2-Butyl-2-ethylpentamethylene diisocyanate, 2-isocyanatopropylcyclohexyl isocyanate, the 3 (4) -isocyanatomethyl-1-methylcyclohexylisocyanate, he 1,4-diisocyanate-4-methylpentane, he 2,4'-methylenebis (cyclohexyl) di-isocyanate  and the 4-methylcyclohexane-1,3-diisocyanate (H-TDI). Also especially preferred are isocyanates (b), whose NCO groups initially have the same reactivity but that a decrease can be induced in them of the reactivity of the second NCO group by adding ester of an alcohol or an amine on an NCO group. Examples to this with respect to isocyanates, whose NCO groups are coupled to through a delocalized electronic system, for example 1,3- and 1,4-phenylenediisocyanate, the 1,5-naphthylenediisocyanate, diphenyldiisocyanate, tolidindiisocyanate or 2,6-toluylenediisocyanate.

They can also be used, for example, oligoisocyanates or polyisocyanates, which can be obtained from  the diisocyanates or of the polyisocyanates mentioned, or of their mixtures, by bonding through urethane structures, of allophanate, urea, biuret, uretodione, amide, isocyanurate, carbodiimide, uretonimine, oxadiazintrione or of iminooxadiazindione.

As compounds with at least two groups reagents with isocyanates will preferably be used difunctional, trifunctional or tetrafunctional compounds, whose functional groups have a variable reactivity against NCO groups. Compounds with at least one group are preferred primary hydroxyl and at least one secondary hydroxyl group, with at least one hydroxyl group and with at least one mercapto group, of especially preferred form with at least one hydroxyl group and, at least, with an amino group in the molecule, especially amino alcohols, aminodiols and aminotrols, since the reactivity of the amino groups clearly increases in the reaction with isocyanate, against hydroxyl groups.

Examples of the compounds cited with, at less, two groups reactive with the isocyanates with the propylene glycol, glycerin, mercaptoethanol, ethanolamine, N-Methylethanolamine, diethanolamine, ethanolpropanolamine, dipropanolamine, diisopropanolamine, 2-amino-1,3-propanediol, he 2-amino-2-methyl-1,3-propanediol  or tris (hydroxymethyl) -aminomethane. further mixtures of the compounds mentioned can also be used.

Obtaining an AB2 molecule has been explained by way of example in the case of a diisocyanate with a Aminodiol In this case, one mole is reacted first of a diisocyanate with one mole of an aminodiol at low temperatures, preferably in the range between -10 to 30 ° C. In this temperature range is carried out repression, practically complete, of the reaction for urethane formation and the isocyanate NCO reactive groups react, so exclusive, with the amino groups of the aminodiol. Molecule AB_ {x} formed presents a free NCO group as well as two OH groups free and can be used for the synthesis of a polyurethane highly branched.

By heating and / or adding catalysts can react this molecule AB2 intramolecularly to give a highly branched polyurethane. The synthesis of highly branched polyurethane can lead to advantageously carried out without prior isolation of the molecule from AB_ in a subsequent reaction stage at elevated temperature, preferably in the range between 30 and 80 ° C. When the aforementioned AB2 molecule with two OH groups and with an NCO group forms a highly crosslinked polymer, which presents, per molecule, a free NCO group as well as - agree with the degree of polymerization - a greater or lesser number of groups OH The reaction can be carried out until a high conversion, whereby high molecular weight structures will be obtained. Without however it can also be interrupted by the addition of suitable monofunctional compounds or by adding one of the starting compounds for obtaining the molecule AB2 when the desired molecular weight has been reached. From agreement with the starting compound, used for the interruption, completely finished molecules will be formed in NCO or molecules completely terminated in OH.

Alternatively, it can be obtained for example, also, a molecule of AB2 from one mole of glycerin and of 2 moles of 2,4-TDI. At low temperatures the primary alcoholic groups react like this as the isocyanate group in position 4 and an adduct will form, which will present an OH group and two isocyanate groups, which can become a highly branched polyurethane as it has described, at elevated temperatures. First a highly branched polymer, which has such a free OH group as - according to the degree of polymerization - a number more or less large of NCO groups.

Obtaining highly polyurethanes branched can be carried out, at first, without solvent, preferably however it will be carried out with solvent. How solvents are suitable, in principle, all compounds liquids at the temperature of the reaction and inert against the monomers and polymers.

Other products are accessible by others synthesis variants. AB3 molecules can be obtained, by example, by reaction of diisocyanates with compounds with, at less, 4 reactive groups against isocyanates. By way of example the reaction of the 2,4-toluylenediisocyanate with the tris (hydroxymethyl) aminomethane.

For polymerization interruption they can also be used polyfunctional compounds, which can react with the corresponding groups A. This way and way several small, highly branched molecules can be linked, to give a large, highly branched molecule.

Highly branched polymers with branches chain extenders can be obtained, for example, if used for the polymerization reaction, in addition to the AB x molecules additionally, in the 1: 1 molar ratio, a diisocyanate and a compound that has two reactive groups with Isocyanate groups. These additional compounds AA or BB they may also have other functional groups, other than reagents against groups A or against groups B under the conditions chosen for the reaction. In this way and way they can incorporate other functionalities in the polymer highly branched.

Other variants for the synthesis of highly branched polyurethanes are found in applications with file numbers DE 100 13 187.5 and DE 100 30 869.4.

Highly branched polyurethanes and highly functional, obtained, can already be used as such in the finishing agents according to the invention, provided that the functional groups, obtained in the course of the synthesis are suitable for the use of polyurethanes in dissolved form or scattered

Functional groups can be hydrophobic, hydrophilize or transfunctionalize, as described previously. In this way and way polyurethanes are accessible highly branched especially suitable for use in form of solution or aqueous dispersion. For the transfunctionalization are suitable in a very special way preferred, due to its reactivity, those highly polyurethanes Branches presenting isocyanate groups. They can also transfunctionalize polyurethanes terminated in OH or terminated in NH2 by means of suitable reaction participants.

Preferred groups, which can be introduced into highly branched polyurethanes are -COOH,
-CONH 2, -OH, -NH 2, -NHR, -NR 2, -NR 3 +, -SO 3 H and its salts. Especially preferred are -NH 2, -NHR, -NR 2, and -NR 3 + according to an embodiment of the invention and -COOH, -OH and -SO 3 H according to another embodiment of the invention.

The groups, which have a number Enough of acidic H atoms, can be transformed into salts corresponding by treatment with appropriate bases. By way of analogously, the corresponding salts can be transformed basic groups with suitable acids. In this way they can be obtained Water soluble highly branched polyurethanes.

By reacting the finished products in NCO with alkanols and alkylamines, especially with alkanols and alkylamines with alkyl moieties with 8 to 40 carbon atoms, hydrophobic products can be obtained.

Hydrophilic products, but not ionic, can be obtained by reaction of the polymers terminated in NCO with polyether alcohols, such as diethylene glycol, triethylene glycol or tetraethylene glycol or polyethylene glycol.

The acid groups can be incorporated for example by reaction with hydroxycarboxylic acids, with acids hydroxysulfonic or with amino acids. As examples of participants suitable in the reaction can be cited the acid 2-hydroxyacetic acid 4-hydroxybenzoic acid 12-hydroxidedecanoic acid 2-hydroxyethanesulfonic acid, glycine or to the girl.

By reacting the compounds, which they include acrylate groups, with alcohols, which include acrylate groups,  such as 2-hydroxyethyl acrylate or the 2-hydroxyethyl methacrylate can be obtained highly branched polyurethanes that have olefinic groups polymerizable.

Highly branched, drying polyurethanes by oxidation they can be obtained if they are reacted, first instead, mono or polyunsaturated fatty acids, especially acids fatty with 8 to 40 carbon atoms with an aliphatic alcohol with at least two OH groups, without being able to be esterified at least one OH group. As an example, the linoleic acid, linolenic acid or elaeoestearic acid. He fatty acid ester, obtained, which still has OH groups, is it reacts next with the NCO groups.

Highly polyurethanes can also be obtained branched that present diverse functionalities. This can carried out, for example, by reaction with a mixture of different compounds or also if only one is reacted part of the functional groups, originally present, by example only part of the OH groups and / or the groups NCO

In addition, one or several functional groups of the highly branched molecule with fiber-related reagents, for example with polyamines, such such as polyethyleneimine or polyvinylamine. In this way you get a highly branched polymer that has a part of the related molecule with the fibers in the form of an anchor group with the fibers

The transfunctionalization of polyurethane highly branched can be carried out advantageously immediately after the polymerization reaction without the NCO-terminated polyurethane must be previously insulated. The functionalization can be carried out however, also, in a separate reaction

Highly branched polyurethanes, used according to the invention, as a rule, present average, at least, 4 and no more than 200 functional groups. Preferably highly branched polyurethanes have from 4 to 150 and, especially preferably, from 4 Up to 100 functional groups. Highly polyurethanes branched, preferably used have a weight molecular weight average M w from 1,000 to 200,000 g / mol, preferably from 1,000 to 100,000 g / mol.

The object of the invention is constituted, in addition, by the use of highly branched polymers, especially of highly branched polyurethanes in agents for the wrinkle finish of textiles containing cellulose. Finishing agents are liquid formulations of any type, containing the highly branched polymer, especially highly branched polyurethane, for application on the textile product in dissolved or dispersed form. The finishing agents, according to the invention, can be presented, by example, as agents for finishing in the strict sense of word in obtaining textiles or can be presented in form of aqueous baths for laundry or as liquid agents for The treatment of textiles. As solvents they are suitable, for example, water, alcohols such as methanol, ethanol and Propanol, THF or mixtures thereof. In this way it is possible, by For example, treating textiles with the finishing agent together with the textile manufacturing. Textiles, which have not been treated with finishing agents or have been so insufficient, may be treated for example, at home before or after laundry, for example at the time of ironing, with an agent for the treatment of textiles, containing highly branched polymers. However, it is also possible deal with highly branched polymers the textiles in the main wash program or after the main wash program during the machine treatment or smoothing program washing machine.

The object of the present invention is also constituted by the use of highly polymers branched, especially from highly polyurethanes branched, in obtaining textiles, during treatment  of textiles before or after laundry, in the program main for the laundry of textile products, in the program of smoothing by rinsing textile products or at the time of ironing. For this, formulations are required respectively. different.

In the case of treatment before or after laundry of textiles can be used as an agent for treatment of textiles in the form of a finishing agent that contain, in addition to a highly branched polymer in form dissolved or dispersed, a surfactant. In this treatment textiles containing cellulose will be pulverized for example with highly branched polymers, being able to assume the amount applied, in general, from 0.01 to 10% by weight, preferably from 0.1 to 7, especially preferably from 0.3 to 4% by weight, based on the weight of the dry textile product. The finishing agent can be applied without however also to the textile product by immersion of textiles in a bath, containing, in general, from 0.1 to 10% in weight, preferably from 0.3 to 5% by weight, based on dry textile product weight of a highly branched polymer dissolved or dispersed The textile product will submerge well only for a short time in the bathroom or you can stay also in it for a period of time, for example, from 1 to 30 minutes.

Textiles, which contain cellulose, which have been treated with the finishing agent well by spraying or by immersion, they are pressed, if necessary, and dried. Drying can be carried out in this case in the air or also in a dryer or hot ironing of the textile product treaty. By drying the finishing agent is fixed on the textile. The most favorable conditions, respectively, in this case can be determined with the help of trials. Temperature during drying, including ironing, is in general, between 40 and 150 ° C, preferably between 60 and 110 ° C. The program is especially suitable for ironing for ironing the iron of the iron. The textiles, which have been treated according to the procedure described above with the highly branched polymers in dissolved or dispersed form, they have excellent protection against wrinkle formation and of folds, which is maintained for several washings. Frequently textile ironing is no longer required. Textiles treated in this way also have a protection with respect to The fibers and colors.

The object of the invention is constituted, also, by agents for the treatment of textiles, which they contain

to)

since 0.1 to 40% by weight, preferably 0.5 to 25% by weight of at least one highly branched polymer, especially at least a highly polyurethane branched,

b)

since 0 to 30% by weight of one or more silicones,

C)

since 0 to 30% by weight of one or more cationic surfactants and / or nonionic,

d)

since 0 to 60% by weight of other components such as others humectants, softeners, smoothing agents, polymers Water soluble, film and adhesive formers, products odorizers and dyes, stabilizers, additives for protection of fibers and colors, modifiers of the viscosity, dirt release additives (Soil-Release), protective additives against corrosion, bactericides, preservatives and agents spray aids, and

and)

since 0 to 99.9% by weight of water,

giving 100% by weight the sum of components a) up to and).

Preferred silicones are silicones that contain amino groups, which are preferably in the form microemulsified, alkoxylated silicones, especially ethoxylated, polyalkylene-polysiloxanes oxide, polyalkylene aminopolydimethylsiloxanes, silicones with quaternary ammonium groups (siliconquats) and surfactants of silicone. Suitable softeners or agents for smoothing are, for example, oxidized polyethylene or wax paraffin and oils. Water soluble polymers, formers of suitable film and adhesives are, for example, (co) acrylamide-based polymers of N-vinyl pyrrolidone, vinylformamide, N-vinylimidazole, of vinylamine, of (meth) acrylates of N, N'-dialkylaminoalkyl, from N, N'-dialkylaminoalkyl (meth) -acrylamides,  of (meth) acrylic acids, of (meth) acrylates of alkyl and / or vinyl sulphonate. The basic monomers, previously cited, can also be used in quaternized

When sprayed on the textile the formulation for the treatment of textiles, the formulation It may also contain an auxiliary agent for spraying. In some cases it may be advantageous, in addition, to add to the formulation alcohols such as ethanol, isopropanol, ethylene glycol or propylene glycol. Other usual additives are odorizing products and dyes, stabilizers, fiber and fiber protective additives the colors, viscosity modifiers, additives for the dirt release, additives for protection against corrosion, bactericides and preservatives in usual amounts for it.

The agent for the treatment of textiles can be applied at the time of ironing of the textile material after casting, in general, by spraying. In this way no only ironing is considerably facilitated but it is given a textile finish, in addition, with a protection against wrinkles and against the formation of long-lasting folds.

The use of highly branched polymers it can also be carried out during laundry of textiles in The main washing machine washing program.

The object of the invention is a formulation solid washing agent, which contains

to)

since 0.05 to 20% by weight of at least one highly polymer branched, especially at least one highly polymer branched,

b)

since 0 to 20% by weight silicone,

C)

since 0.1 to 40% by weight of at least one non-ionic surfactant and / or anionic,

d)

since 0 to 50% by weight of one or more adjuvants inorganic,

and)

since 0 to 10% by weight of one or more adjuvants organic,

F)

since 0 to 60% by weight of other usual components such as charges, enzymes, perfumes, complexing agents, inhibitors of corrosion, bleaching agents, bleaching activators, bleaching catalysts, cationic surfactants, inhibitors of the run of the colors, inhibitors of the gray, polyesters for the release of dirt, dyes, bactericides, dissolution improvers and / or disintegrating agents,

giving 100% by weight the sum of components a) up to F).

Suitable anionic surfactants are, especially:

-

sulfates of (fatty) alcohols of alcohols (fatty) with 8 to 22, preferably with 10 to 18 carbon atoms, for example sulfates of alcohols with 9 to 11 carbon atoms, sulfates of alcohols with 12 to 14 atoms of carbon, sulfates of alcohols with 12 to 18 carbon atoms, lauryl sulfate, cetyl sulfate, myristyl sulfate, palmityl sulfate, stearyl sulfate and alcohol sulfate tallow fatty;

-

alcohols with 8 to 22 atoms of sulfated carbon, alkoxylated (alkyl ether sulfates). The compounds  of this type are prepared for example by first alkoxylation instead of an alcohol with 8 to 22 carbon atoms, preferably of an alcohol with 10 to 18 carbon atoms, for example a fatty alcohol and then sulfate the product of alkoxylation. For alkoxylation, preferably, the ethylene oxide;

-

linear alkylbenzenesulfonates with 8 up to 20 carbon atoms (LAS), preferably alkylbenzenesulfonates and alkyl toluenesulfonates with 9 to 13 carbon atoms;

-

alkanesulfonates such as alkanesulfonates with 8 to 24 carbon atoms, preferably with 10 to 18 carbon atoms;

-

soaps such as salts of Na and K of carboxylic acids with 8 to 24 atoms of carbon.

The anionic surfactants, cited, are they will add to the washing agent preferably in the form of salts.  Suitable cations in these salts are metal ions alkalis such as sodium, potassium and lithium and ions ammonium such as hydroxyethylammonium, the di (hydroxyethyl) ammonium and the tri (hydroxyethyl) ammonium.

Suitable nonionic surfactants are, especially:

-

alcohols with 8 to 22 atoms of alkoxylated carbon such as fatty alcohol alkoxylates or oxoalcohol alkoxylates. These may be alkoxylated with ethylene oxide, with propylene oxide and / or with butylene As surfactants, in this case, all alkoxylated alcohols containing at least two added molecules of one of the alkylene oxides mentioned above. In this case, oxide block polymers of ethylene, propylene oxide and / or butylene oxide or products of addition, containing the alkylene oxides mentioned in a statistical distribution Nonionic surfactants contain, per mole of alcohol, in general, from 2 to 50, preferably from 3 to 20 moles of at least one alkylene oxide. Preferably these contain as alkylene oxide the oxide of ethylene. The alcohols preferably have from 10 to 18 carbon atoms Depending on the type of catalyst for the alkoxylation, used during obtaining, alkoxylates will present a distribution of the oxide counterparts of wide or narrow alkylene;

-

alkylphenolalkoxylates such as alkylphenoxyloxylates with alkyl chains with 6 to 14 atoms of carbon and with 5 to 30 units of alkylene oxide;

-

alkyl polyglycosides with 8 to 22, preferably with 10 to 18 carbon atoms in the chain alkyl and, in general, with 1 to 20, preferably with 1.1 to 5 glycoside units;

-

N-alkylglucamides, fatty acid amidoalkoxylates, acid alkanolamidoalkoxylates fatty as well as block copolymers consisting of oxide of ethylene, propylene oxide and / or butylene oxide.

Suitable inorganic adjuvants are, especially:

-

the crystalline or amorphous aluminosilicates with properties ion exchangers such as zeolites. How zeolites are especially suitable zeolites A, X, B, P, MAP and HS in its Na form or in ways in which Na is partially exchanged for other cations such as Li, K, Ca, Mg or ammonium;

-

crystalline silicates such as, especially, disilicates or stratified silicates, for example the δ-Na_ {2} Si_ {2} O_ {5} or the β-Na 2 Si 2 O 5. Silicates they can be used in the form of their alkali metal salts, of alkaline earth or ammonium metals, preferably as silicates Na, Li or Mg;

-

amorphous silicates such as for example sodium metasilicate or amorphous disilicate;

-

carbonates and bicarbonates. These can be used in the form of its salts with alkali metals, with metals alkaline earth or with ammonium. Carbonates are preferred or Na, Li and Mg bicarbonates, especially carbonate sodium and / or sodium bicarbonate;

-

polyphosphates such as for example the pentasodium triphosphate.

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Suitable organic adjuvants are, especially carboxylic acids under molecular weight, oligomers or polymers

-

the Suitable low molecular weight carboxylic acids are, by example, citric acid, citric acid modified so hydrophobic such as for example agaricinic acid, acid Malic acid, tartaric acid, gluconic acid, glutaric acid, succinic acid, imidodisuccinic acid, acid oxydisuccinic, propanotricarboxylic acid, acid butanotetracarboxylic acid, cyclopentanotetracarboxylic acid, alkyl- and alkenyl succinic acids and acids aminopolycarboxylic acids such as, for example, acid nitrilotriacetic, β-alanindiacetic acid, ethylenediaminetetraacetic acid, serinadiacetic acid, isoserinedic acid, the acid N- (2-hydroxyethyl) iminodiacetic acid ethylenediamine disuccinic acid and methyl- and ethylglycinate acetic acid;

-

the Suitable oligomeric or polymeric carboxylic acids are, by example, homopolymers of acrylic acid, acids oligomaleics, the copolymers of maleic acid with acid acrylic, methacrylic acid, olefins with 2 to 22 atoms carbon such as isobutene or long chain α-olefins, the vinyl alkyl ethers with alkyl groups with 1 to 8 atoms of carbon, vinyl acetate, vinyl propionate, (meth) acrylates of alcohols with 1 to 8 carbon atoms and Styrene Preferably the homopolymers of the Acrylic acid as well as acrylic acid copolymers with the maleic acid In addition, polyaparaginic acids are suitable as organic adjuvants. Oligomeric carboxylic acids and polymers will be used in acid form or as salt of sodium.

-

the suitable bleaching agents are, for example, the adducts of hydrogen peroxide on inorganic salts such as for example sodium perborate monohydrate, perborate tetrahydrate of sodium and sodium carbonate pentahydrate and acids percarboxylic acids such as acid phthalimidopercapronic.

-

how bleach activators are suitable, for example, the N, N, N ', N'-tetraacetylethylenediamine (TAED), the sodium p-nonanoyloxybenzenesulfonate and the N-methylmorpholinoacetonitrile sulfate methyl.

-

the enzymes preferably used in washing agents are proteases, lipases, amylases, cellulases, oxidized and peroxidated.

-

the Run inhibitors of suitable colors are, for example, the homopolymers and copolymers of the 1-vinyl pyrrolidone, from 1-vinylimidazole or N-oxide 4-vinylpyridine and homopolymers and copolymers of acid-transformed 4-vinylpyridine chloroacetic

A solid formulation of agents for washing, according to the invention, is usually presented in the form of powder or granulate or in the form of extruded bodies or tablets

The object of the invention is constituted, in addition, by a liquid formulation of washing agent, which contains

to)

since 0.05 to 20% by weight, at least, of a highly polymer branched, especially at least one highly polyurethane branched,

b)

since 0 to 20% by weight of one or more silicones,

C)

since 0.1 to 40% by weight of at least one non-ionic surfactant and / or anionic,

d)

since 0 to 20% by weight of one or more adjuvants inorganic,

and)

since 0 to 10% by weight of one or more adjuvants organic,

F)

since 0 to 60% by weight of other usual components such as sodium carbonate, enzymes, perfume, complexing agents, corrosion inhibitors, bleaching agents, activators bleaching, bleaching catalysts, cationic surfactants, color run inhibitors, blackening inhibitors, polyesters that release dirt, dyes, bactericides, non-aqueous solvents, solubilizers, hydrotropes, thickeners and / or alkanolamines,

g)

since 0 to 99.85% by weight of water,

giving 100% by weight the sum of components a) up to g).

You can use silicones, nonionic and anionic surfactants, adjuvants and adjuvants mentioned above.

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A detailed description of the components cited for washing agents is found, for example, in Publications WO 99/06524 or WO 99/04313 and in the publication Liquid Detergents, Editor: Kuo-Yann Lai, Surfactant Sci. Ser., Vol. 67, Marcel Decker, New York, 1997, pages 272-304.

The concentration of polymers highly Branches in the bathroom for laundry is comprised for example between 10 and 5,000 ppm and preferably is included in the range from 50 to 1,000 ppm. Textiles treated with highly branched polymers in the main wash program of the washing machine not only wrinkle in a proportion clearly smaller than untreated textiles. These can ironing, also, more easily, are softer and smoother, they are dimensionally and geometrically stable and give a feeling of less "used" after several washes due to its protection for the fibers and for the colors, therefore they have a smaller proportion of fluffs and knots and a deterioration or a minor lightening of colors.

The use of highly branched polymers can be carried out in the program called softener or treatment after the main laundry program. The concentration of highly branched polymers in the bath for laundry it is comprised, for example, from 10 to 5,000 ppm and is preferably in the range from 50 up to 1,000 ppm Typical components for a rinse softener or treatment may be present in case given in the bathroom for rinsing. Also the treated textiles of This mode has, after drying on the rope or, preferably, in the drum for drying, a very good protection against wrinkle formation, which is related to the positive effects about the ironing described above. Protection against Wrinkle formation can be reinforced even more clearly by a single, brief ironing of textiles after drying. Treatment in the softener rinse program or treatment also has a favorable effect on stability dimensional of textiles. It also inhibits the formation of knots and of fluffs and the deterioration of colors is repressed.

The object of the invention is constituted, also, by an agent for rinsing for the treatment of laundry, which contains

to)

since 0.05 to 40% by weight, at least, of a highly polymer branched, especially at least one highly polyurethane branched,

b)

since 0 to 20% by weight of one or more silicones,

C)

since 0.1 to 40% by weight of at least one surfactant cationic,

d)

since 0 to 30% by weight of one or more non-ionic surfactants Y

and)

since 0 to 30% by weight of other usual components such as silicones, other smoothing agents, wetting agents, film-forming polymers, odorizing products and dyes, stabilizers, fiber and fiber protective additives the colors, viscosity modifiers, additives for the soil release, additive inhibitors of corrosion, bactericides and preservatives, and

F)

since 0 to 99.85% by weight of water,

giving 100% by weight the sum of components a) up to F).

Preferred cationic surfactants are they choose from the group of quaternary salts of diesteramonium, of the quaternary salts of tetraalkylammonium, of quaternary salts of diamidoammonium, amidoamine esters and salts of imidazolium These are preferably contained in an amount from 3 to 30% by weight in the agents for rinsing for the treatment of laundry. Examples are quaternary salts of diésteramonio, that present / display two rest alkylacarbonyloxy (mono- to pentamethylene) with 11 to 22 carbon atoms and two residues alkyloxyalkyl or alkylhydroxyalkyl with 1 to 3 atoms of carbon on the N quaternary atom and bearing as counterion, for example, chloride, bromide, methylsulfate or sulfate.

The quaternary salts of diesteramonium are also, especially, those that present a rest alkyl (en) ilcarbonyloxytrimethylene with 11 to 22 carbon atoms, bearing on the central carbon atom of the trimethylene clustering a rest alkyl (en) ilcarbonyloxy with 11 to 22 atoms of carbon, and three alkyloxyalkyl or alkylhydroxyalkyl moieties with 1 to 3 carbon atoms over the N quaternary atom and that bear, as counterion, for example chloride, bromide, methylsulfate or sulfate.

The quaternary tetraalkylammonium salts are, especially, those that present two alkyl residues with 1 up to 6 carbon atoms and two alkyl (en) ilo moieties with 8 to 24 carbon atoms over the quaternary N atom and that bear, as counterion, for example, chloride, bromide, methylsulfate or sulfate.

The quaternary diaminoammonium salts are, by example, those that present two remains alkyl (en) ilcarbonylaminoethylene with 8 to 24 atoms carbon, a substituent chosen from hydrogen, methyl, ethyl and polyoxyethylene with up to 5 units of ethylene oxide and as another remainder a methyl group on the N quaternary atom and that bear, as counterion, for example, chloride, bromide, methylsulfate or sulfate.

Amidoamine esters are, for example, tertiary amines, which carry as substituents on the atom of N an alkyl (en) ylcarbonylamino (mono- up to trimethylene) with 11 to 22 carbon atoms, a remainder alkyl (en) ilcarbonyloxy (mono- to trimethylene) with 11 to 22 carbon atoms and a methyl group.

Imidazolium salts are, for example, those that carry a residue in position 2 of the heterocycle alkyl (en) ilo with 14 to 18 carbon atoms, about the atom of neutral N a remainder alkyl (en) ilcarbonyl (oxy or amino) ethylene with 14 to 18 carbon and hydrogen atoms, methyl or ethyl on the atom of N, which carries the positive charge, in this case the counterions are, for example, chloride, bromide, methylsulfate or sulfate.

The invention will be explained in greater detail by middle of the following examples.

Examples

The indications in percentage in the examples they refer to% by weight, as long as nothing else is said to this respect.

The following agents of finish.

Finishing Agent A

A 1% alkaline solution by weight of highly branched polyurethane A, which was prepared in the manner next:

168 g of hexamethylene diisocyanate were disposed (HDI), dissolved in 386 g of dimethylacetamine (DMAc), under nitrogen coverage, at room temperature. Then you they added, under intense agitation, within 1 minute, 134 g of dimethylolpropionic acid, dissolved in 313 g of DMAc. After dosing 0.2 g of dibutyltin dilaurate, it was heated at 70 ° C the reaction mixture and volumetric monitoring was followed decrease in NCO content. When content was reached in 1.5% by weight NCO presented the reaction product a average functionality in relation to the NCO of 1, in relation to COOH of 3 and in relation to the OH of 1.

To this addition product 22 g of trimethylolpropane (TMP), dissolved in 50 g of DMAc and continued stirring for 3 hours at 70 ° C. During this time the NCO content of the mixture up to 0%. The product was released from solvent then in vacuo in the rotary evaporator a 80 ° C

The final solid product presented the parameters following:

Functionality average with respect to OH approximately 5 and with respect to COOH approximately 9.

Molecular weight Medium: 6.018 g / mol.

Finishing Agent B

A 1% alkaline solution by weight of highly branched polyurethane B, which was prepared in the manner next:

336 g of hexamethylene diisocyanate were disposed (HDI), dissolved in 336 g of dimethylacetamide (DMAc), under nitrogen coverage and cooled to 0 ° C. Then you they added, under intense agitation, within 20 minutes, 105 g of diethanolamine and stirring was continued for 30 minutes at 0 ° C Then 134 g of acid were added dimethylolpropionic, dissolved in 239 g of DMAc. Behind the dosage of 0.5 g of dibutyltin dilaurate was heated to 60 ° C the reaction mixture and volumetric monitoring was followed decrease in NCO content. When content was reached in 1.2% NCO was added an excess of methanol to convert the NCO groups still present. The product was released from the solvent under vacuum in the rotary evaporator at 80 ° C.

The reaction product presented the following parameters:

Functionality average with respect to COOH approximately 3 and with respect to OH approximately 4.

Molecular weight Medium: 1,757 g / mol.

Finishing Agent C

1% alkaline solution by weight of polyurethane highly branched C, which was prepared as follows:

222 g of isophorone diisocyanate were placed (IPDI) under nitrogen coverage. Then it was added, in the After 1 minute, a mixture consisting of 67 g of TMP and 67 g of dimethylolpropionic acid, dissolved in 356 g of DMAc, under intense agitation After dosing 0.4 g of dilaurate dibutyltin heated the reaction mixture at 60 ° C, stirred at this temperature and the decrease in volumetric volume was followed NCO content. When an NCO content of 1.0% was reached in weight, the reaction product presented a medium functionality in relation to the NCO of 1, in relation to the COOH of 3 and in relation to to the OH of 4.

Now they were added to this product of polyaddition 32 g of polytetrahydrofuran with an average molecular weight  250 g / mol and stirring was continued for 3 hours at 60 ° C. During this time decreased the NCO content of the mixture to 0%. The product was then released from the solvent in vacuo in the rotary evaporator at 80 ° C.

The final solid product presented the parameters following:

Functionality average with respect to OH approximately 20 and with respect to COOH approximately 15.

Molecular weight Medium: 22,610 g / mol.

Finishing Agent D

1% alkaline solution by weight of polyurethane highly branched D, which was prepared as follows:

168 g of hexamethylene diisocyanate were disposed (HDI), dissolved in 168 g of dimethylacetamide (DMAc), under nitrogen coverage and cooled to 0 ° C. Then you they added, under intense agitation, within 20 minutes, 52.5 g of diethanolamine, dissolved in 52.5 g of DMAc and followed stirring for 30 minutes at 0 ° C. 59.9 were added next g of N-methyldiethanolamine, dissolved in 59.5 g of DMAc. After dosing 0.2 g of dibutyltin dilaurate, the reaction mixture was heated to 40 ° C and followed by volumetry the decrease in NCO content. When it was reached an NCO content of 1.2% by weight was added an excess of methanol for the conversion of the NCO groups still present. The product it was then released from the solvent in vacuo in the evaporator rotary at 80 ° C.

The reaction product presented the following parameters:

Functionality mean with respect to NR2 approximately 3 and with respect to OH approximately 4.

Molecular weight Medium: 1,782 g / mol.

Finishing fabric samples

Flat cotton structures (BW) the size indicated respectively in table 1 with a surface weight of 160 g / m2 were sprayed on both sides with the agents finish A, B, C and D such that the amount applied was 2% in relation to the respective weight of the dry textile material and, to then hot ironed in a light state damp.

Fabric samples, treated in this way, are washed, for comparative purposes, with untreated fabric samples of the same size and in the presence of loading tissue with an agent for liquid washing, at 40 ° C, in a domestic washing machine automatic (load between 1.5 and 3.0 kg) and then They were dried in the drum for drying. A program of normalized washing or a normalized drying program (40 ° C color wash program or drying program in closet). After drying, a simple evaluation was carried out View of the flat fabric samples according to the method of AATCC 124 test, meaning note 1 that the fabric is very wrinkled and presenting many folds, while note 5 is gave the fabrics free of wrinkles and creases. The samples of fabric previously treated with finishing agents A, B and C they obtained grades between 2.5 and 3.5. On the contrary the untreated fabric samples respectively received the note one.

TABLE 1

BW (40 cm x 40 cm) BW (40 cm x 40 cm) BW (40 cm x 80 cm) 1.5 kg load load 3.0 kg 1.5 kg load no treaty one one one TO 3.5 3 3 B 3 2.5 3 C 2.5 2.5 2.5 D 3 2.5 3

Claims (15)

1. Procedure for finishing against wrinkles of textiles containing cellulose by treating the textiles with an agent for finishing and drying the treated textiles, characterized in that the finishing agent contains one or more dendrimeric or hyperbranched polymers in dissolved form or scattered 2. Method according to claim 1, characterized in that the dendrimer or hyperbranched polymers are dendrimeric or hyperbranched polyurethanes. 3. Method according to one of claims 1 or 2, characterized in that the dendrimer or hyperbranched polymers have one or more functional groups selected from the group consisting of -COOH, -COOR, -CONHR, -CONH2, -OH, - SH, -NH 2, -NHR, -NR 2, -NR 3 +, -SO 3 H, -SO 3 R, -NHCOOR, -NHCONH 2, -NHCONHR and its salts. Method according to claim 3, characterized in that the functional groups are chosen from the group consisting of -COOH, CONH2, -OH, -NH2, -NHR, -NR2, -NR3 +, -SO3H and their salts. 5. Method according to claim 4, characterized in that the functional groups are chosen from the group consisting of -COOH, -OH, -SO3H and their salts. Method according to claim 4, characterized in that the functional groups are chosen from the group consisting of -NH2, -NHR, -NR2, -NR3 + and their salts. Method according to one of claims 1 to 6, characterized in that the dendrimer or hyperbranched polymers have, on average, at least four functional groups. Method according to claim 7, characterized in that the dendrimer or hyperbranched polymers have, on average, from 4 to 100 functional groups. 9. Use of dendrimer polymers or hyperbranched, chosen from the group consisting of polyesters, polyethers, polyurethanes, polyureaurethanes, polyamides, polysiloxanes, carbosilanes, polyetheramides and dendrimer polyesteramides or hyperbranched in agents for the treatment of textiles, in formulations of agents for washing and in agents for rinsed for the treatment of textiles, solids and liquids 10. Use of finishing agents, which they contain dendrimeric or hyperbranched polymers, chosen from group consisting of polyesters, polyethers, polyurethanes, polyureaurethanes, polyamides, polysiloxanes, carbosilanes, polyetheramides and polyesteramides, dendrimers or hyperbranched, for manufacture of textiles, for the treatment of textiles, in the main program of washing of textiles, in the program of Softener rinse of textile laundry and ironing. 11. Use of dendrimer polymers or hyperbranched, such as those defined in one of the claims 1 to 8, for finishing against wrinkles of textiles that contain cellulose. 12. Agent for the treatment of textiles, containing

to)

since 0.1 to 40% by weight of at least one dendrimer polymer or hyperbranched, chosen from the group consisting of polyesters, polyethers, polyurethanes, polyureaurethanes, polyamides, polysiloxanes, carbosilanes, polyetheramides and polyesteramides dendrimers or hyperbranched,

b)

since 0 to 30% by weight of one or more silicones,

C)

since 0 to 30% by weight of one or more cationic surfactants and / or nonionic,

d)

since 0 to 60% by weight of other components such as others humectants, softeners, smoothing agents, polymers Water soluble, film and adhesive formers, products odorizers and dyes, stabilizers, protective additives fibers and colors, viscosity modifiers, additives for the release of dirt, additives corrosion protectors, bactericides, agents for conservation and auxiliary agents for spraying, and

and)

since 0 to 99.9% by weight of water,

giving 100% by weight the sum of components a) up to and). 13. Solid formulations of agents for the washing, which contain

to)

since 0.05 to 20% by weight of at least one dendrimer polymer or hyperbranched, chosen from the group consisting of polyesters, polyethers, polyurethanes, polyureaurethanes, polyamides, polysiloxanes, carbosilanes, polyetheramides and polyesteramides dendrimers or hyperbranched,

b)

since 0 to 20% by weight of one or more silicones,

C)

since 0.1 to 40% by weight of at least one non-ionic surfactant and / or anionic,

d)

since 0 to 50% by weight of one or more adjuvants inorganic,

and)

since 0 to 10% by weight of one or more adjuvants organic,

F)

since 0 to 60% by weight of other usual components such as charges, enzymes, perfumes, complexing agents, inhibitors of corrosion, bleaching agents, bleaching activators, cationic surfactants, bleach catalysts, inhibitors of the run of the colors, inhibitors of the gray, polyesters for the release of dirt, dyes, bactericides, dissolution improvers and / or disintegrating agents,

giving 100% by weight the sum of components a) up to F). 14. Liquid formulation for washing agent, containing

to)

since 0.05 to 20% by weight of at least one dendrimer polymer or hyperbranched, chosen from the group consisting of polyesters, polyethers, polyurethanes, polyureaurethanes, polyamides, polysiloxanes, carbosilanes, polyetheramides and polyesteramides dendrimers or hyperbranched,

b)

since 0 to 20% by weight of one or more silicones,

C)

since 0.1 to 40% by weight of at least one non-ionic surfactant and / or anionic,

d)

since 0 to 20% by weight of one or more adjuvants inorganic,

and)

since 0 to 10% by weight of one or more adjuvants organic,

F)

since 0 to 60% by weight of other usual components such as sodium carbonate, enzymes, perfumes, complexing agents, corrosion inhibitors, bleaching agents, activators bleaching, bleaching catalysts, cationic surfactants, color run inhibitors, blackening inhibitors, polyesters for the release of dirt, dyes, bactericides, non-aqueous solvents, solubilizers, hydrotropes, thickeners and / or alkanolamines,

g)

since 0 to 99.85% by weight of water,

giving 100% by weight the sum of components a) up to g). 15. Agents for the treatment of laundry, that contain

to)

since 0.05 to 40% by weight of at least one dendrimer polymer or hyperbranched, chosen from the group consisting of polyesters, polyethers, polyurethanes, polyureaurethanes, polyamides, polysiloxanes, carbosilanes, polyetheramides and dendrimeric polyesteramides or hyperbranched,

b)

since 0 to 20% by weight of one or more silicones,

C)

since 0.1 to 40% by weight of at least one surfactant cationic,

d)

since 0 to 30% by weight of one or more surfactants not ionic,

and)

since 0 to 30% by weight of other usual components such as silicones, other smoothing agents, wetting agents, film-forming polymers, odorizing products and dyes, stabilizers, fiber and fiber protective additives the colors, viscosity modifiers, additives for the dirt release, protective additives against corrosion, bactericides and preservatives, and

F)

since 0 to 99.85% by weight of water,

giving 100% by weight the sum of components a) up to F).