ES2128786T3 - Polimeros ramificados de cadena larga y su produccion. - Google Patents
Polimeros ramificados de cadena larga y su produccion.Info
- Publication number
- ES2128786T3 ES2128786T3 ES95938287T ES95938287T ES2128786T3 ES 2128786 T3 ES2128786 T3 ES 2128786T3 ES 95938287 T ES95938287 T ES 95938287T ES 95938287 T ES95938287 T ES 95938287T ES 2128786 T3 ES2128786 T3 ES 2128786T3
- Authority
- ES
- Spain
- Prior art keywords
- matta
- ziegler
- polymerizable
- approx
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
SE PROPORCIONAN COPOLIMEROS, Y PROCEDIMIENTOS DE FABRICACION DE LOS MISMOS, QUE DERIVAN DE MONOMEROS, LOS CUALES COMPRENDEN: A) UNA MONO-OLEFINA, QUE TIENE UN SOLO ENLACE POLIMERIZABLE DE ZIEGLER-MATTA; B) UN SEGUNDO MONOMERO, QUE TIENE AL MENOS UN ENLACE POLIMERIZABLE DE ZIEGLER-MATTA; C) UN TERCER MONOMERO, QUE TIENE AL MENOS DOS ENLACES POLIMERIZABLES DE ZIEGLER-MATTA, SIENDO DICHO MONOMERO: I) DE CADENA LINEAL Y DE MENOS DE SEIS O AL MENOS SIETE ATOMOS DE CARBONO; II) DE CADENA NO LINEAL; O III) UNA COMBINACION DE LOS MISMOS; COMPRENDIENDO DICHO COPOLIMERO: D) AL MENOS APROX. UN ENLACE INSATURADO CARBONO-CARBONO POR MOLECULA MEDIA EN NUMERO; E) UNA ENERGIA VISCOSA DE ACTIVACION (E{SUB,A}), AL MENOS 1 KCAL/MOL MAYOR, QUE LA DE UN COPOLIMERO CON UN ESQUELETO LINEAL, DERIVADO DE LOS MISMOS MONOMEROS, PERO EXCLUYENDO AQUELLOS QUE POSEEN AL MENOS DOS ENLACES POLIMERIZABLES DE ZIEGLER-MATTA; F) NIVEL DE CRISTALINIDAD, APROX. DEL 10 AL 50%; Y G) M{SUB,Z}/M{SUB,W} AL MENOS APROX. DE 1''7. DICHOSCOPOLIMEROS, MUESTRAN UNA CAPACIDAD MEJORADA DE TRATAMIENTO EN ESTADO FUNDIDO, Y OTRAS PROPIEDADES, DURANTE LA FABRICACION DEL PRODUCTO FINAL.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/328,187 US6300451B1 (en) | 1994-10-24 | 1994-10-24 | Long-chain branched polymers and their production |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2128786T3 true ES2128786T3 (es) | 1999-05-16 |
Family
ID=23279893
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES95938287T Expired - Lifetime ES2128786T3 (es) | 1994-10-24 | 1995-10-24 | Polimeros ramificados de cadena larga y su produccion. |
Country Status (13)
Country | Link |
---|---|
US (1) | US6300451B1 (es) |
EP (1) | EP0788521B1 (es) |
JP (1) | JPH10512600A (es) |
KR (1) | KR100358857B1 (es) |
CN (2) | CN1091774C (es) |
AU (1) | AU694812B2 (es) |
BR (1) | BR9509427A (es) |
CA (1) | CA2202402C (es) |
DE (1) | DE69506906T2 (es) |
ES (1) | ES2128786T3 (es) |
RU (1) | RU2165437C2 (es) |
TW (1) | TW422857B (es) |
WO (1) | WO1996012744A1 (es) |
Families Citing this family (92)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5773106A (en) * | 1994-10-21 | 1998-06-30 | The Dow Chemical Company | Polyolefin compositions exhibiting heat resistivity, low hexane-extractives and controlled modulus |
WO1997001586A1 (en) * | 1995-06-29 | 1997-01-16 | Dsm N.V. | Elastomeric copolymer |
CA2190678A1 (en) | 1995-11-22 | 1997-05-23 | Robert Joseph Noel Bernier | Process for preparing elastomeric compounds from granular elastomers and polymers and articles manufactured therefrom |
US5814714A (en) * | 1995-11-30 | 1998-09-29 | The Dow Chemical Company | Mono-olefin/polyene interpolymers, method of preparation, compositions containing the same, and articles made thereof |
AR005066A1 (es) * | 1995-12-15 | 1999-04-07 | Union Carbide Chem Plastic | Un procedimiento para hacer un homopolimero, copolimero o terpolimero de polietileno con ramificacion de cadena larga, una composicion de polietilenoasi obtenida y un articulo de pelicula o moldeado por inyeccion que comprende dicha composicion. |
NL1006421C2 (nl) * | 1997-06-27 | 1998-12-29 | Dsm Nv | Elastomeer copolymeer. |
EP0994906B1 (en) * | 1997-06-27 | 2002-05-29 | Dsm N.V. | Elastomeric copolymer and process for the preparation thereof |
KR100564506B1 (ko) * | 1998-02-17 | 2006-03-29 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 에틸렌 공중합 방법 |
US6294631B1 (en) * | 1998-12-15 | 2001-09-25 | Exxonmobil Chemical Patents Inc. | Hyperbranched polymers by coordination polymerization |
US6281316B1 (en) | 1999-03-22 | 2001-08-28 | Union Carbide Chemicals & Plastics Technology Corporation | Enhanced crosslinking terpolymer |
EP1183286A1 (en) * | 1999-05-14 | 2002-03-06 | Dupont Dow Elastomers L.L.C. | Highly crystalline eaodm interpolymers |
US7041617B2 (en) * | 2004-01-09 | 2006-05-09 | Chevron Phillips Chemical Company, L.P. | Catalyst compositions and polyolefins for extrusion coating applications |
US6509431B1 (en) * | 2000-01-18 | 2003-01-21 | Exxonmobil Oil Corporation | Terpolymers |
JP4945080B2 (ja) * | 2002-06-19 | 2012-06-06 | エクソンモービル・ケミカル・パテンツ・インク | エチレン、より高級なα−オレフィンコモノマー及びジエン、特にビニルノルボルネン、並びにそのような方法を用いて製造されるポリマー |
CN1681858A (zh) * | 2002-09-20 | 2005-10-12 | 埃克森美孚化学专利公司 | 超临界聚合方法和由其生产的聚合物 |
US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
US7807769B2 (en) | 2002-09-20 | 2010-10-05 | Exxonmobil Chemical Patents Inc. | Isotactic polypropylene produced from supercritical polymerization process |
AU2003302033A1 (en) | 2002-10-15 | 2004-06-15 | Exxonmobil Chemical Patents Inc. | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
EP1586591A4 (en) * | 2003-01-23 | 2006-06-14 | Mitsui Chemicals Inc | PROCESS FOR PRODUCING NON-CONJUGATED ETHYLENE / α-OLEFIN / POLYENE COPOLYMER AND NON-CONJUGATED ETHYLENE / α-OLEFIN / POLYENE COPOLYMER THUS OBTAINED |
US7906586B2 (en) * | 2003-12-09 | 2011-03-15 | Dow Global Technologies Llc | Thermoplastic olefinic compositions |
US20050209403A1 (en) * | 2003-12-09 | 2005-09-22 | Walton Kim L | Thermoplastic olefinic compositions |
US7119153B2 (en) | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
US7601666B2 (en) * | 2004-07-08 | 2009-10-13 | Exxonmobil Chemical Patents Inc. | Olefin polymerization catalyst system and process for use thereof |
WO2006019494A1 (en) | 2004-07-14 | 2006-02-23 | Exxonmobil Chemical Patents Inc. | Polymer production at supercritical conditions |
US8101697B2 (en) * | 2005-02-01 | 2012-01-24 | Bridgestone Corporation | Multi-functionalized high-trans elastomeric polymers |
ATE425217T1 (de) * | 2005-05-12 | 2009-03-15 | Dow Global Technologies Inc | Thermogeformte und extrudierte folie mit reduziertem glanz |
JP5210860B2 (ja) * | 2005-05-20 | 2013-06-12 | 株式会社ブリヂストン | 低分子量ポリマーの調製方法 |
US8288480B2 (en) | 2005-06-22 | 2012-10-16 | Exxonmobil Chemical Patents Inc. | In-reactor polymer blends |
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US8557938B2 (en) | 2005-11-10 | 2013-10-15 | Arkema Inc. | Branched fluoropolymers |
US7517939B2 (en) | 2006-02-02 | 2009-04-14 | Chevron Phillips Chemical Company, Lp | Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching |
US7619047B2 (en) * | 2006-02-22 | 2009-11-17 | Chevron Phillips Chemical Company, Lp | Dual metallocene catalysts for polymerization of bimodal polymers |
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US8143352B2 (en) * | 2006-12-20 | 2012-03-27 | Exxonmobil Research And Engineering Company | Process for fluid phase in-line blending of polymers |
CN104927184B (zh) * | 2006-12-21 | 2019-06-14 | 陶氏环球技术有限责任公司 | 填充的热塑性聚烯烃组合物、制备其的方法和由其制得的制品 |
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CN101855249B (zh) * | 2007-09-13 | 2013-02-13 | 埃克森美孚研究工程公司 | 在线生产增塑聚合物和增塑聚合物共混物的方法 |
EP2201042B1 (en) * | 2007-09-13 | 2012-06-27 | ExxonMobil Research and Engineering Company | In-line blending of plasticizers with a base polymer |
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WO2009082463A1 (en) * | 2007-12-20 | 2009-07-02 | Exxonmobil Research And Engineering Company | In-line process to produce pellet-stable polyolefins |
US7910679B2 (en) * | 2007-12-20 | 2011-03-22 | Exxonmobil Research And Engineering Company | Bulk homogeneous polymerization process for ethylene propylene copolymers |
EP2450403A1 (en) * | 2007-12-20 | 2012-05-09 | ExxonMobil Research and Engineering Company | Polypropylene ethylene-propylene copolymer blends and in-line process to produce them |
US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
CN102066477A (zh) | 2008-06-18 | 2011-05-18 | 陶氏环球技术公司 | 聚合物组合物、其制备方法和由其制备的制品 |
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KR101762461B1 (ko) | 2009-10-14 | 2017-07-27 | 가부시키가이샤 브리지스톤 | 환식 비환식 디엔 공중합체의 제조 방법 및 고무 조성물 |
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CN104812828B (zh) | 2012-12-05 | 2016-10-12 | 埃克森美孚化学专利公司 | 具有优异的膜泡稳定性的hdpe 改性聚乙烯吹塑膜组合物 |
US8877672B2 (en) | 2013-01-29 | 2014-11-04 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
US9034991B2 (en) | 2013-01-29 | 2015-05-19 | Chevron Phillips Chemical Company Lp | Polymer compositions and methods of making and using same |
CN103304743B (zh) * | 2013-06-24 | 2015-04-29 | 苏州新区佳合塑胶有限公司 | 一种含有4-甲基-1-戊烯的阻燃耐热塑胶 |
CN103304742B (zh) * | 2013-06-24 | 2015-04-15 | 苏州新区佳合塑胶有限公司 | 一种含有1,3-环己二烯的阻燃耐热塑胶 |
JP6439280B2 (ja) * | 2013-08-09 | 2018-12-19 | 三菱ケミカル株式会社 | 熱可塑性エラストマー組成物の製造方法 |
US10184045B2 (en) | 2014-02-24 | 2019-01-22 | Dow Global Technologies Llc | Thermoplastic polyolefin with reduced gloss for non-carpeted flooring |
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CN106414568B (zh) | 2014-05-29 | 2019-08-06 | 埃克森美孚化学专利公司 | 聚乙烯薄膜及其生产 |
US10125247B2 (en) | 2014-05-29 | 2018-11-13 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions |
CN109153750B (zh) | 2016-05-20 | 2022-04-26 | 切弗朗菲利浦化学公司 | 制备低密度聚乙烯的低压方法 |
US9574035B1 (en) | 2016-08-12 | 2017-02-21 | Lion Copolymer Geismar, Llc | Process for making high molecular weight tetrapolymer and articles produced therefrom |
US9574034B1 (en) | 2016-08-12 | 2017-02-21 | Lion Copolymer Geismar, Llc | Process for making high molecular weight tetrapolymer and articles produced therefrom |
US9574033B1 (en) | 2016-08-12 | 2017-02-21 | Lion Copolymer Geismar, Llc | Process for continuously making high molecular weight tetrapolymer for use in anti-vibration applications |
BR112019002474B1 (pt) | 2016-08-12 | 2022-09-13 | Dow Global Technologies Llc | Composição |
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US10550252B2 (en) | 2017-04-20 | 2020-02-04 | Chevron Phillips Chemical Company Lp | Bimodal PE resins with improved melt strength |
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US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
US5096743A (en) | 1990-11-09 | 1992-03-17 | E. I. Du Pont De Nemours And Company | Process for making roofing membrane of epdm elastomer and ethylene-containing polymer |
GB9103527D0 (en) | 1991-02-20 | 1991-04-10 | Exxon Chemical Patents Inc | Hp catalyst killer |
NL9101536A (nl) | 1991-09-11 | 1993-04-01 | Dsm Nv | Katalysator en werkwijze voor de bereiding van een amorf copolymeer van etheen. |
US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
IT1252069B (it) | 1991-11-25 | 1995-05-29 | Enichem Elastomers | Processo per la preparazione di copolimeri elastomerici dell'etilene |
DE69309726T2 (de) | 1992-01-23 | 1997-08-21 | Mitsui Petrochemical Ind | Ethylen/Alpha-Olefin/7-Methyl-1,6-Octadien Copolymerisat-Kautschuk und Zusammensetzungen desselben |
ATE164169T1 (de) | 1992-06-18 | 1998-04-15 | Montell Technology Company Bv | Verfahren zur herstellung eines ethylenischen copolymerisats |
WO1994000500A1 (en) | 1992-06-26 | 1994-01-06 | Exxon Chemical Patents Inc. | Solution phase polymerization process utilizing metallocene catalyst with production of olefin polymers |
JPH08502303A (ja) | 1992-09-29 | 1996-03-12 | エクソン・ケミカル・パテンツ・インク | 長鎖分岐ポリマー及び長鎖分岐ポリマーを製造する方法 |
WO1994013175A1 (en) * | 1992-12-16 | 1994-06-23 | Paul Solomon | Door comprising recessed cabinet |
CA2110654C (en) | 1992-12-17 | 2006-03-21 | Albert Rossi | Dilute process for the polymerization of ethylene/alpha-olefin copolymer using metallocene catalyst systems |
US5410003A (en) * | 1994-03-31 | 1995-04-25 | Union Carbide Chemicals & Plastics Technology Corporation | Process for production of homogeneous polyethylenes |
US5552489A (en) * | 1994-07-22 | 1996-09-03 | Exxon Chemical Patents Inc. | Tackifiers and a process to obtain tackifiers |
JPH1054010A (ja) | 1997-06-06 | 1998-02-24 | Ohbayashi Corp | 鋼管・コンクリート複合構造橋脚 |
-
1994
- 1994-10-24 US US08/328,187 patent/US6300451B1/en not_active Expired - Fee Related
-
1995
- 1995-10-24 EP EP95938287A patent/EP0788521B1/en not_active Revoked
- 1995-10-24 JP JP8514092A patent/JPH10512600A/ja active Pending
- 1995-10-24 WO PCT/US1995/013643 patent/WO1996012744A1/en not_active Application Discontinuation
- 1995-10-24 ES ES95938287T patent/ES2128786T3/es not_active Expired - Lifetime
- 1995-10-24 AU AU38970/95A patent/AU694812B2/en not_active Ceased
- 1995-10-24 KR KR1019970702672A patent/KR100358857B1/ko not_active IP Right Cessation
- 1995-10-24 CA CA002202402A patent/CA2202402C/en not_active Expired - Fee Related
- 1995-10-24 BR BR9509427A patent/BR9509427A/pt not_active IP Right Cessation
- 1995-10-24 RU RU97108600/04A patent/RU2165437C2/ru not_active IP Right Cessation
- 1995-10-24 DE DE69506906T patent/DE69506906T2/de not_active Revoked
- 1995-10-24 CN CN95195850A patent/CN1091774C/zh not_active Expired - Fee Related
-
1996
- 1996-04-26 TW TW085105107A patent/TW422857B/zh not_active IP Right Cessation
-
2001
- 2001-09-06 CN CNB011328118A patent/CN1204157C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US6300451B1 (en) | 2001-10-09 |
AU694812B2 (en) | 1998-07-30 |
EP0788521A1 (en) | 1997-08-13 |
CN1204157C (zh) | 2005-06-01 |
TW422857B (en) | 2001-02-21 |
CN1091774C (zh) | 2002-10-02 |
AU3897095A (en) | 1996-05-15 |
KR100358857B1 (ko) | 2003-02-07 |
BR9509427A (pt) | 1998-01-06 |
KR970707184A (ko) | 1997-12-01 |
DE69506906D1 (de) | 1999-02-04 |
JPH10512600A (ja) | 1998-12-02 |
CA2202402C (en) | 2006-10-17 |
MX9702954A (es) | 1998-07-31 |
CN1341672A (zh) | 2002-03-27 |
DE69506906T2 (de) | 1999-05-27 |
EP0788521B1 (en) | 1998-12-23 |
WO1996012744A1 (en) | 1996-05-02 |
RU2165437C2 (ru) | 2001-04-20 |
CA2202402A1 (en) | 1996-05-02 |
CN1161700A (zh) | 1997-10-08 |
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