EP2123826A2 - Method and device for producing a laminar product and the laminar product itself - Google Patents
Method and device for producing a laminar product and the laminar product itself Download PDFInfo
- Publication number
- EP2123826A2 EP2123826A2 EP09006429A EP09006429A EP2123826A2 EP 2123826 A2 EP2123826 A2 EP 2123826A2 EP 09006429 A EP09006429 A EP 09006429A EP 09006429 A EP09006429 A EP 09006429A EP 2123826 A2 EP2123826 A2 EP 2123826A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- mold
- mold elements
- diameter
- elements
- surface product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 claims abstract description 23
- 239000000725 suspension Substances 0.000 claims abstract description 23
- 238000001035 drying Methods 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims description 58
- 239000004033 plastic Substances 0.000 claims description 13
- 229920003023 plastic Polymers 0.000 claims description 13
- 239000001913 cellulose Substances 0.000 claims description 11
- 229920002678 cellulose Polymers 0.000 claims description 11
- 239000011111 cardboard Substances 0.000 claims description 7
- 239000011087 paperboard Substances 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 229920001187 thermosetting polymer Polymers 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 claims description 3
- 230000007704 transition Effects 0.000 claims description 3
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- 239000000470 constituent Substances 0.000 claims 1
- 238000007711 solidification Methods 0.000 abstract description 2
- 230000008023 solidification Effects 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 43
- 239000000123 paper Substances 0.000 description 23
- 239000000853 adhesive Substances 0.000 description 7
- 230000001070 adhesive effect Effects 0.000 description 7
- 239000000835 fiber Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 235000019289 ammonium phosphates Nutrition 0.000 description 4
- 238000003490 calendering Methods 0.000 description 4
- 230000002349 favourable effect Effects 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- 230000002393 scratching effect Effects 0.000 description 4
- 238000007493 shaping process Methods 0.000 description 4
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 4
- 239000004254 Ammonium phosphate Substances 0.000 description 3
- 239000004114 Ammonium polyphosphate Substances 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 3
- 239000002250 absorbent Substances 0.000 description 3
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 3
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 3
- 229920001276 ammonium polyphosphate Polymers 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 3
- 238000003780 insertion Methods 0.000 description 3
- 230000037431 insertion Effects 0.000 description 3
- 239000002861 polymer material Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- 244000273618 Sphenoclea zeylanica Species 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 241000218657 Picea Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 TeflonĀ® Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical compound [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012757 flame retardant agent Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000011089 mechanical engineering Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 238000012536 packaging technology Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000012858 resilient material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000011090 solid board Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000003351 stiffener Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
- D21F11/006—Making patterned paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
- D21F11/14—Making cellulose wadding, filter or blotting paper
Definitions
- the invention relates to a method and a device for producing a surface product as well as the surface product itself.
- a method for producing a surface product known as a fastener part comprising a plurality of integrally connected to a carrier and symmetrically constructed form elements in the form of hooking means in the manner of each one provided with a head stem, wherein a moldable material in a forming zone between a pressure tool and a mold is supplied.
- the opposing boundary walls are at least in a longitudinal section of the respective mold cavity continuously equipped with a convex trajectory, so that a smooth transition between the cross-sectional shapes of the stem and head part is achieved for a Verhakungsstoff the support member, so that it insofar comes to a non-inhibiting EntformungsprozeĆ for the surface product from the manufacturing device.
- this document discloses a web as a surface product solution, which is produced by this process.
- at least one of the two material layers is produced by coextrusion of the plastic material, wherein the stem ends are calendered with a further shaping roller in a further method step be so as to obtain a mushroom-shaped hook and loop closure material as the final product.
- the present invention seeks to provide a method for producing a surface product available, with which can increase the application possibilities for pertinent surface products in an advantageous, process-reliable and cost-effective manner.
- the invention is also based on the object to provide a device with which the manufacturing process can be reliably realized process technology, as well as to offer a surface product to the market, which is cost-effective and takes into account increased environmental requirements.
- the pertinent objects solves a method according to the feature configuration of claim 1, a device with the feature configuration of claim 7 and a surface product according to the feature design of claim 9.
- the inventive method is used to produce a surface product having at least partially cellulosic components, in particular made of paper or paperboard and having a support member, wherein by means of at least one forming tool individual mushroom-like form elements are formed, which are integral or separate part of the assignable support member and on this at least partially formed above.
- the support member may be constructed of cellulosic components, for example, entirely made of paper, which should be highly absorbent and by means of the shaping tool can be individual mushroom-like form elements as integral part of the support member on this above put on.
- the individual form elements in the form of mushroom-like projections are likewise formed from cellulosic material, in particular from paper material.
- the carrier part of the mentioned area product is constructed in several layers, with some of the layers may prove to be particularly absorbent and the other part serves mainly the stability of the overall product.
- the scratching effect can be improved even further if the carrier part is again made of paper;
- the mold elements as a separate component for example, consists of cellulose material with plastic parts, applied to the support member made of paper.
- the cellulose-plastic molded elements can be sprayed on the carrier part, for example, in the manner of enlarged drops with widened head diameters, wherein the Spraying device insofar then forms the forming tool.
- the sprayed or otherwise applied droplets retain their droplet shape due to the surface tension of the plastic material in spite of the cellulose base and can be appropriately cured and dried on the support member, for example using a heat source.
- the paper-like, possibly multi-layered support part then remains absorbent and the applied, on the support part solidified mushroom-like droplets, in turn, increase the scratching effect for improved cleaning of surfaces of any kind.
- the individual form elements are formed as mushroom-shaped closure elements, so that can be produced using the method according to the invention, a fastener closure part made of paper or cardboard.
- the adhesive fastener elements can be attached directly to paper or cardboard products such as boxes, optionally in one piece, so that the boxes can be reliably closed for receiving a packaged goods, without additional closure systems would be necessary, such as tapes, strapping, package cords and the like.
- it is preferably provided to offset the cellulosic suspension from which the mold elements can be produced with a plastics material, for example with a predeterminable percentage of conventional polymer material.
- the surface fastener mainly built from paper material so far proves to be particularly easy to recycle and biodegradable. Moreover, it can be produced on an industrial scale, which has a cost effect on its production price. It is surprising to one of ordinary skill in the art that he uses surface-mount fasteners such as Velcro Ā® fasteners using cellulosic material can build, that are reliable in use and long lasting usable.
- the mushroom-shaped closure elements of an adhesive closure part can be combined with mushroom-shaped closure elements of another adhesive closure part to form a repeatedly openable and closable adhesive closure with each other; but it is also conceivable to connect a conventional loop or loop material of a closure part with the closure part with the hook or mushroom-shaped form elements made of paper.
- a thermosetting curable molding compound is applied to the free head side of the respective mold element, which stiffen the paper head in order to ensure a safe Unterhakungsdorfkeit.
- the individual mold elements can also be obtained as a hollow element, d. H. the interior of the stem of the mold element forms a cavity, which in turn can be filled if necessary, for example with flame-retardant or flame-resistant materials, so as to be able to ensure increased fire safety in safety-relevant areas.
- the extinguishing agent can be introduced directly into the surface fastener.
- cellulose-containing suspensions are used which are very hydrous;
- 1% solids can come to 99% water content
- this fact takes into account the manufacturing device insofar as the forming tool consists of a forming wire.
- the sieve structure used in each case can also be multi-layered, so that a part of the sieve structure mainly serves the shaping of the form elements and the respective other sieve element primarily complies with the drainage task. If preferred stainless steel screens are used, the corrosion has been effectively countered, even if, if appropriate, by further additives of the suspension this should have a certain acid content.
- the surface product produced by the method and the device can be used for a variety of applications, the list is not complete.
- Other applications are conceivable in the field of clothing; but there are also technical applications conceivable, for example in the field of aerospace engineering, rail technology, mechanical engineering, motor vehicle construction etc ..
- the manufacturing device according to the Fig. 1 shows their basic structure in horizontal manufacturing orientation. Between two roller-shaped guide bodies 10, of which at least one is drivable, extends a band-shaped forming wire 12, which is part of a designated as a whole by 14 forming tool.
- the forming wire 12 has a plurality of individual mold cavities 16, which pass completely through the forming wire 12 and the respective cavity 16 has seen from the side according to the sectional view of the Fig. 1 the shape of a hyperboloid of revolution.
- the manufacturing device according to the Fig. 1 also has an additional circulating dewatering belt 18 which is arranged in a flat surface with the forming wire 12 between this and the two guide bodies 10.
- the dewatering belt 18 is provided with a continuous perforation 20, wherein the openings formed in the manner of a fine perforation form far more passages with a smaller cross-sectional area than those formed by the mold cavities 16 of the forming wire 12.
- the subdivided in the manner of upper run and lower run bands 12 and 18 have in the plane of a certain width and in the Fig. 1 Cavities 16, which are shown in only one plane, extend as well as the perforation 20 into the plane of the drawing over a predeterminable distance.
- the thus formed screen belts 12 and 18 may each have several 100 or 1000 through holes on 1cm 2 strip material surface. The better understanding because but are in the presentation after the Fig. 1 the proportions so far not correctly reproduced. In any case, the perforation 20 is such stated that the pulp material remains substantially in the mold cavities 16 and can not escape unintentionally.
- the drive direction of the guide body 10 is in the Fig. 1 reproduced with arrows, so that in the selected drive direction, the two bands 12 and 18, in the direction of the Fig. 1 seen, move relative to the upper run position from left to right, both bands with the same axial travel speed.
- the device according to the Fig. 1 an applicator 22, which provided on its underside with individual nozzles, the spray application, allows an even closer presented suspension.
- a drying device 24 is arranged in the direction of travel of the two belts 12 and 14 behind the application device 22, which by means of hot air or other heat radiation (UV, IR, ultrasound) over a certain drying zone, the drying of the suspension material.
- a collecting device 26 is arranged, which captures excess water of the suspension and removes it from the manufacturing device.
- cooling devices may be present which cool the finished surface product, which may also facilitate demolding to that extent.
- a blower 28 may be provided on the top of the lower run, which helps in demolding the product to be produced, the pertinent demolding process can be supported by a removal roller 30, the finished fabric produced the manufacturing device of the same for removal and further processing or shipping takes.
- the production device can still have a calendering roller 32 for a post-forming operation, which will be explained in more detail below.
- a cellulose-containing suspension is applied via the applicator 22 to the top of the upper run of the forming wire 12 and the aqueous suspension or Zelluslosebrei penetrates into the mold cavities 16 of the forming wire 12 a.
- a belt-like support member 34 with which the individual mold elements 36 are integrally connected In order to facilitate the entry of the suspension, preferably in the form of cellulose pulp in the mold cavities 16, an entry auxiliary device 38, for example, consisting of two oppositely disposed spinning rollers, which support the described entry with a corresponding contact force and the density of the support member 34 with pretending.
- the auxiliary recording device 38 may also have an air knife arrangement (not shown in more detail) with which the entry is supported to the extent described in the manner of an air curtain and under overpressure.
- the molding process is driven at such a speed that in any case excess water escape from the suspension and can penetrate the perforation 20 of the dewatering belt 18 in order to be able to be discharged from the trough-like collecting device 26 from the production device can.
- the already indicated drying device 24 also serves from the other side to the drying of the pulp to be solidified, which forms the paper structure for the surface product.
- the pulp in particular in the region of the lower run of the production device dried to the extent that the band-shaped support member 34 can be deducted from the top of the forming wire 12, preferably using the removal roller 30 and the finished mold elements 36 are made pulled out the assignable mold cavities 16, which can be supported by the indicated blowing device 28 with by this compressed air blows through the perforation 20 of the dewatering belt 18, and through the mold cavities 16 of the forming wire 12 from the rear region forth.
- the thus shaped mold elements 36 together with the carrier part 34 have a basically geometric structure, as in Fig. 3 as well as in the Fig. 4 shown.
- head tops as in the Fig. 5 shown presses the calendering roller 32 from above on the head-side projections of the front end of each mold element 36, with the result that a flattened head geometry according to the idealized representation of the Fig. 5 established.
- the formation of the surface product is a cellulosic suspension in which about 1% solids to 99% water content falls.
- fibers are preferably used having a diameter between 1 .mu.m and 100 .mu.m, preferably of the order of 10 .mu.m, and the length of the respective pulp fiber should be in the range of 10 .mu.m to 2 mm, preferably about 100 .mu.m. It has proven to be particularly favorable to obtain pulp fibers from vegetable raw materials, wherein preferably pine and spruce as the feedstock result in a long-fiber pulp which can be used particularly well within the framework of the described production device.
- a pure pulp suspension depending on the application for the finished surface product as a paper product may prove to be too stable, so that the use of plastic materials, such as polymer blends, makes sense, and it has proved to be particularly favorable 10 to 15.5% polymer material in the suspension to use.
- additives may be added to the cellulosic suspension, such as wet strength agent in the form of melamine resin or in the form of epichlorohydrin resin.
- an anti-sticking agent for example in the form of talcum powder, may be applied to the forming wire 12 with its cavities 16 by suitable means (not shown).
- Other additives may be provided to cleave formaldehyde from the pulp suspension or to remove impurities that could hinder the process.
- an active extinguishing medium may preferably be provided an extinguishing gas such as nitrogen, wherein as a nitrogen carrier, in particular melamine comes into question but also magnesium hydroxide (MDH).
- an extinguishing gas such as nitrogen
- a nitrogen carrier in particular melamine comes into question but also magnesium hydroxide (MDH).
- MDH magnesium hydroxide
- a vacuum device not shown, which, for example, arranged in the catcher 26, the dewatering of the fiber suspension favors, and pulp material as long as from the individual mold cavities 16 sucks with until a hollow stem cross-section (not shown) is created for the single mold element 36, which rests in the other with its edge-side material on the respectively assignable mold cavity 16.
- the hollow stem part produced so far can then be provided with a flame-retardant agent or else serve to introduce another stiffening agent, for example in the form of a polymer-plastic material to be injected.
- aqueous pulp suspension temperature around 60 Ā° C have proven to be favorable, and a residence time of 10 to 15 minutes at a temperature of 70 Ā° C for the drying zone by means of the drying device 24.
- a Teflon coating for the calendering roll 32 is preferably provided.
- unspecified, Binder and crosslinking materials are used to promote solidification of the pulp material.
- a calender roll 32 as shown in the Fig. 1 can be flat head sides for the mold elements 36 reach as in the Fig. 5 demonstrated. These can then be provided as a starting material from the free head side with a thermosetting molding compound as the respective head part 40, which forms a kind of protection or Verhakungskappe in hemispherical shape.
- thermosetting molding composition to this effect can be applied to the free end faces of the mold elements 36 via a conventional applicator, such as spray or doctor device and in the cured state, the head part 40 configured in this way is configured together with the underlying mold element 36 as a mushroom-shaped hooking element, so that in this respect a hookable Adhesive closure part is created, which forms with corresponding elements of another adhesive closure part (not shown) a repeatedly openable and closable adhesive closure.
- a structure is maintained, as in the Fig. 3 and 4 is shown as an example, the pertinent solution of a surface product is particularly suitable for use in the fields of tissue paper, toilet paper and wipes. Since the pulp material for the support member 34 may be very thin, is in a preferred embodiment of the surface product according to the representations of the 4 to 6 below the support member 34 to form a multi-layer system, a support layer 42 is present, for example, formed from a thin-walled polymer material or the like.
- the pertinent support layer 42 may also be elastic, so that when stretched the contrast rigid paper support member 34 can tear between the mold elements 36, with the result that depending on the applied strain the mold elements 36 move away from each other and in a starting position according to the representations after the 4 to 6 via the support member 34 in turn reach their initial position shown.
- a roller-shaped drive body 10 is used, which is to rotate in the direction of the arrow shown.
- a forming wire 12 is arranged, which corresponds to the forming wire 12 according to the solution of the manufacturing device according to the Fig. 1 equivalent.
- the forming wire 12 can be easily worn in case of wear against a new exchange, without having to change the guide body 12.
- preferably made of stainless steel forming wires 12 are cleaned off from time to time, so it is advantageous if you can remove them from the guide body 12 without problems.
- the guide body 10 shown is provided along its upper side with a perforation, not shown, over which the dehydration can take place, so that parallels exist in this respect to the perforation 20 of the dewatering belt 18 according to the solution Fig. 1 ,
- the solution after the Fig. 2 has a collecting device 26 for water, which is preferably formed in the present case as a vacuum device.
- the drying device 24 is arranged, to which in turn the blowing device 28 is connected.
- the devices 24, 26 and 28 are arranged stationary and the guide body roller 10 rotates together with the forming wire 12 about the pivot axis 44 of the overall device.
- the solution after the Fig. 2 again has the peel-off or removal roller 30 and the insertion aid 38 is this time of a circumferential, one-piece band formed around Deflection rollers 56 is guided around and otherwise has a drive direction according to the arrow, which corresponds to the drive direction of the forming screen roller 10, 12.
- the band of the insertion aid 38 may preferably be made of a flexible, resilient material; but here is also the use of metal foil materials, such as an aluminum foil or the like possible.
- the band of the recording auxiliary device 38 can be driven independently or preferably be taken by the friction during the rotational movement of the guide body 10.
- the solution according to the Fig. 2 a doctor device 48, with which the pulp-containing suspension can be applied to the forming wire 12.
- the band-shaped insertion auxiliary device 38 then in turn helps to introduce the pulp suspension into the mold cavities 16 of the forming wire 12 while forming the band-shaped carrier part 34.
- the finished surface product, the representation of the Fig. 3 corresponds, is then discharged on the bottom of the manufacturing device.
Landscapes
- Paper (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
Abstract
Description
Die Erfindung betrifft ein Verfahren und eine Vorrichtung zum Herstellen eines FlƤchenproduktes sowie das FlƤchenprodukt selbst.The invention relates to a method and a device for producing a surface product as well as the surface product itself.
Im Stand der Technik sind eine Vielzahl von dahingehenden Lƶsungen betreffend FlƤchenprodukte bekannt.In the prior art, a variety of pertinent solutions concerning surface products are known.
So ist beispielsweise durch die
Bei dem bekannten Verfahren werden zumindest in einem LƤngsschnitt des jeweiligen Formhohlraumes gesehen die einander gegenĆ¼berliegenden BegrenzungswƤnde durchgehend mit einem konvexen Bahnverlauf ausgestattet, so dass ein stetig verlaufender Ćbergang zwischen den Querschnittsformen von Stiel- und Kopfteil fĆ¼r ein Verhakungsmittel des TrƤgerteils erreicht ist, so dass es insoweit zu einem hemmfreien EntformungsprozeĆ fĆ¼r das FlƤchenprodukt aus der Herstellvorrichtung kommt.In the known method, the opposing boundary walls are at least in a longitudinal section of the respective mold cavity continuously equipped with a convex trajectory, so that a smooth transition between the cross-sectional shapes of the stem and head part is achieved for a Verhakungsmittel the support member, so that it insofar comes to a non-inhibiting EntformungsprozeĆ for the surface product from the manufacturing device.
Durch die
- AuswƤhlen mindestens eines ersten Materials fĆ¼r eine erste Materialschicht,
- AuswƤhlen mindestens eines zweiten Materials fĆ¼r eine zweite Materialschicht,
- Schmelzformen der ersten Schicht mit einer ersten OberflƤche und einer zweiten OberflƤche aus dem ersten Material,
- Schmelzformen der zweiten Schicht mit einer ersten OberflƤche und einer zweiten OberflƤche aus dem zweiten Material,
- Verbinden der ersten OberflƤchen der ersten und zweiten Materialschicht, wƤhrend sich die Schichten im geschmolzenen Zustand befinden, zur Ausbildung einer mehrlagigen Folie als TrƤgerteil und
- Ausbilden mehrere Stiele auf mindestens der zweiten OberflƤche der zweiten Materialschicht,
- wobei dieser Formschritt das Formen der mehreren Stiele aus mindestens dem ersten Material und/oder dem zweiten Material und das Verfahren weiterhin den Schritt des Steuerns der Verarbeitungsbedingungen und der Dicke, ViskositƤt und relativer GrƶĆen des ersten und zweiten Materials umfaĆt, derart, dass das erste Material, das die erste Schicht bildet, in oder durch die auf der zweiten OberflƤche der zweiten Schicht ausgebildeten Stiele hindurch ragt und Teil der Stiele bildet.
- Selecting at least one first material for a first material layer,
- Selecting at least one second material for a second material layer,
- Melting the first layer having a first surface and a second surface of the first material,
- Melting the second layer with a first surface and a second surface of the second material,
- Bonding the first surfaces of the first and second material layers while the layers are in the molten state to form a multilayer film as a support member and
- Forming a plurality of stems on at least the second surface of the second material layer,
- wherein said forming step comprises forming the plurality of stems from at least one of the first material and the second material, and the method further comprises the step of controlling the processing conditions and the thickness, viscosity, and relative sizes of the first and second materials such that the first material forming the first layer, protruding into or through the stems formed on the second surface of the second layer, and forming part of the stems.
Ferner ist durch diese EuropƤische Schrift eine Bahn als FlƤchenproduktlƶsung bekannt, die nach diesem Verfahren hergestellt ist. Mit dieser bekannten Lƶsung wird mindestens eine der beiden Materialschichten durch Coextrusion des Kunststoffmaterials hergestellt, wobei in einem weiteren Verfahrensschritt die Stielenden mit einer weiteren Formgebungswalze kalandriert werden, um dergestalt ein pilzfƶrmiges HakenverschluĆmaterial als Endprodukt zu erhalten.Furthermore, this document discloses a web as a surface product solution, which is produced by this process. With this known solution, at least one of the two material layers is produced by coextrusion of the plastic material, wherein the stem ends are calendered with a further shaping roller in a further method step be so as to obtain a mushroom-shaped hook and loop closure material as the final product.
Mit den bekannten Verfahren lassen sich eine Vielzahl von verschiedenen AusfĆ¼hrungsformen eines HaftverschluĆteiles als FlƤchenprodukt mit vorzugsweise pilzfƶrmigen HaftverschluĆteilen als Formelementen auf einem bandfƶrmigen TrƤgerteil erhalten, die dadurch charakterisiert sind, dass das jeweilige Form- oder VerschluĆelement (Stiel und Kopf) massiv ausgebildet aus einem Kunststoffmaterial besteht. Obwohl die hier zum Einsatz kommenden Kunststoffmaterialien recycelbar und sogar zumindest teilweise biologisch abbaubar sind, lƤĆt der Einsatz dahingehender Materialien, insbesondere betreffend die Verpackungstechnik und unter Einbezug einer erhƶhten UmweltvertrƤglichkeit noch WĆ¼nsche offen. Auch kommt es zusehends auf den MƤrkten zu einer Rohstoffverknappung, was die Kunststoffpreise in die Hƶhe schnellen lƤĆt, so dass die hieraus erstellten Endprodukte entsprechend teuer werden.With the known methods can be a variety of different embodiments of a fastener part obtained as surface product with preferably mushroom-shaped fastener parts as mold elements on a band-shaped support member, which are characterized in that the respective form or closure element (stem and head) made of a solid plastic material , Although the plastic materials used here are recyclable and even at least partially biodegradable, the use of pertinent materials, especially with regard to packaging technology and with regard to increased environmental compatibility, still leaves something to be desired. There is also a growing shortage of raw materials on the markets, which is causing plastic prices to soar so that the end products produced from them are becoming expensive.
Des weiteren sind im Stand der Technik als FlƤchenprodukte eine Vielzahl von Papier- oder Papp-Schachtelerzeugnissen bekannt, die auch als sogenannte Display-Verpackungen eingesetzt der modernen KonsumgĆ¼terindustrie die Mƶglichkeit erƶffnen, eine Vielzahl von Produkten am Ort des Verkaufs direkt zu plazieren und aufzustƤndern. In der Regel wird die dahingehende Display-Verpackung in der Art einer Display-Palette ausgebildet und dergestalt, wie bei sonstigen Palettensystemen auch Ć¼blich, transportiert, wobei dann aber regelmƤĆig am Ort der Aufstellung und des Verkaufs fĆ¼r die jeweilige Aufstell- oder Verkaufsmannschaft eine Vielzahl von Handhabungsschritten notwendig ist, um den Inhalt der Display-Paletten verkaufsfƤhig zu machen.Furthermore, in the prior art as surface products a variety of paper or cardboard box products are known, which also used as so-called display packaging the modern consumer goods industry open the possibility to place a variety of products at the point of sale directly and aufzustƤndern. In general, the pertinent display packaging is formed in the manner of a display pallet and the like, as usual in other pallet systems transported, but then regularly at the place of installation and sale for the respective installation or sales team a variety of Handling steps is necessary to make the content of the display pallets salable.
Um diesem Nachteil zu begegnen ist in der
Des weiteren kennt der Verbraucher aus dem tƤglichen Leben auch FlƤchenprodukte aus Papier, wie Toilettenpapier, TaschentĆ¼cher, HandtĆ¼cher, WischtĆ¼cher etc., die teilweise mehrlagig aufgebaut, modernen Produktanforderungen GenĆ¼ge tun.Furthermore, the consumer from everyday life also knows surface products made of paper, such as toilet paper, handkerchiefs, towels, wipes, etc., some of which are multi-layered, meet modern product requirements.
Ausgehend von diesem Stand der Technik liegt der Erfindung die Aufgabe zugrunde, ein Verfahren zum Herstellen eines FlƤchenproduktes zur VerfĆ¼gung zu stellen, mit dem sich in vorteilhafter, prozesssicherer und kostengĆ¼nstiger Weise die Einsatzmƶglichkeiten fĆ¼r dahingehende FlƤchenprodukte erhƶhen lassen. Der Erfindung liegt ferner die Aufgabe zugrunde, eine Vorrichtung zu schaffen, mit der sich das Herstellverfahren prozeĆtechnisch sicher verwirklichen lƤĆt, sowie eine FlƤchenprodukt dem Markt anzubieten, das kostengĆ¼nstig ist sowie erhƶhten Umweltanforderungen Rechnung trƤgt. Die dahingehenden Aufgabenstellungen lƶst ein Verfahren gemĆ¤Ć der Merkmalsausgestaltung des Patentanspruches 1, eine Vorrichtung mit der Merkmalsausgestaltung des Anspruches 7 sowie ein FlƤchenprodukt gemĆ¤Ć der Merkmalsausgestaltung des Anspruches 9.Based on this prior art, the present invention seeks to provide a method for producing a surface product available, with which can increase the application possibilities for pertinent surface products in an advantageous, process-reliable and cost-effective manner. The invention is also based on the object to provide a device with which the manufacturing process can be reliably realized process technology, as well as to offer a surface product to the market, which is cost-effective and takes into account increased environmental requirements. The pertinent objects solves a method according to the feature configuration of claim 1, a device with the feature configuration of claim 7 and a surface product according to the feature design of claim 9.
Das erfindungsgemƤĆe Verfahren dient dem Herstellen eines FlƤchenproduktes, das zumindest teilweise zellulosehaltige Bestandteile aufweist, insbesondere aus Papier oder Pappe besteht und ein TrƤgerteil aufweist, wobei mittels mindestens eines Formgebungswerkzeuges einzelne pilzartige Formelemente gebildet werden, die einstĆ¼ckig oder separat Bestandteil des zuordenbaren TrƤgerteils sind und Ć¼ber dieses zumindest teilweise vorstehend ausgebildet werden.The inventive method is used to produce a surface product having at least partially cellulosic components, in particular made of paper or paperboard and having a support member, wherein by means of at least one forming tool individual mushroom-like form elements are formed, which are integral or separate part of the assignable support member and on this at least partially formed above.
So kann beispielsweise das TrƤgerteil aus zellulosehaltigen Bestandteilen aufgebaut sein, beispielsweise ganz aus Papier bestehen, das in hohem MaĆe saugfƤhig sein soll und mittels des Formgebungswerkzeuges lassen sich einzelne pilzartige Formelemente als einstĆ¼ckiger Bestandteil des TrƤgerteils auf dieses vorstehend aufsetzen. Insoweit sind die einzelnen Formelemente in der Art von pilzartigen VorsprĆ¼ngen gleichfalls aus zellulosehaltigem Material, insbesondere aus Papiermaterial, gebildet. Durch die einzelnen Formelemente, insbesondere im Hinblick auf die im Durchmesser vergrƶĆerten Kopfteile, tritt nun zum einen eine OberflƤchenvergrƶĆerung fĆ¼r das TrƤgerteil auf und zum anderen erlauben die Formelemente eine Art Kratzeffekt, was das Abreinigungsergebnis verbessert, insbesondere wenn das dahingehend aufgebaute FlƤchenprodukt als Wischtuch im Haushalt eingesetzt wird oder als Toilettenpapier seinen Bestimmungszweck erfƤhrt.Thus, for example, the support member may be constructed of cellulosic components, for example, entirely made of paper, which should be highly absorbent and by means of the shaping tool can be individual mushroom-like form elements as integral part of the support member on this above put on. In that regard, the individual form elements in the form of mushroom-like projections are likewise formed from cellulosic material, in particular from paper material. By the individual form elements, in particular with regard to the enlarged diameter head parts, now on the one hand, an increase in surface area for the support member and on the other allow the mold elements a kind of scratching effect, which improves the Abreinigungsergebnis, especially if the thus constructed surface product as a wipe in the home is used or as toilet paper its intended purpose.
Um die SaugfƤhigkeit noch weiter zu verbessern, ist insofern das TrƤgerteil des angesprochenen FlƤchenproduktes mehrlagig aufgebaut, wobei ein Teil der Lagen sich als besonders saugfƤhig erweisen kann und der andere Teil dient Ć¼berwiegend der StabilitƤt des Gesamtproduktes. Zwar ist bei dahingehenden Haushaltsprodukten auch Ć¼blich, durch EinprƤgen einer reliefartigen Struktur in das Papiermaterial die angesprochene OberflƤchenvergrƶĆerung mit Kratzeffekt zu erreichen; allein die angeformten, einzeln vorstehenden Formelemente, die ansonsten die OberflƤche des TrƤgerteils unberĆ¼hrt lassen, erweisen sich als die bessere Lƶsung.In order to improve the absorbency even further, so far, the carrier part of the mentioned area product is constructed in several layers, with some of the layers may prove to be particularly absorbent and the other part serves mainly the stability of the overall product. Although it is also common in domestic household products to achieve the mentioned surface enlargement with scratching effect by impressing a relief-like structure in the paper material; but the molded, individually protruding mold elements, which otherwise leave the surface of the support member untouched, prove to be the better solution.
Der Kratzeffekt lƤĆt sich noch verbessern, wenn man das TrƤgerteil wiederum aus Papier aufbaut; die Formelemente jedoch als separaten Bestandteil, beispielsweise aus Zellulosematerial mit Kunststoffanteilen bestehend, auf das TrƤgerteil aus Papier aufbringt. Die Zellulose-Kunststoff-Formelemente lassen sich beispielsweise in der Art von vergrƶĆerten Tropfen mit verbreiterten Kopfdurchmessern auf das TrƤgerteil aufsprĆ¼hen, wobei die SprĆ¼heinrichtung insoweit dann das Formgebungswerkzeug bildet. Die aufgesprĆ¼hten oder sonst aufgetragenen Trƶpfchen behalten aufgrund der OberflƤchenspannung des Kunststoffmaterials trotz der Zellulosebasis ihre Trƶpfenchenform bei und kƶnnen auf dem TrƤgerteil entsprechend ausgehƤrtet und getrocknet werden, beispielsweise unter Einsatz einer WƤrmequelle. Das papierfƶrmige, gegebenenfalls mehrlagige TrƤgerteil bleibt dann nach wie vor saugfƤhig und die aufgebrachten, auf dem TrƤgerteil verfestigten pilzartigen Trƶpfchen, erhƶhen wiederum den Kratzeffekt zum verbesserten Abreinigen von FlƤchen jedweder Art.The scratching effect can be improved even further if the carrier part is again made of paper; However, the mold elements as a separate component, for example, consists of cellulose material with plastic parts, applied to the support member made of paper. The cellulose-plastic molded elements can be sprayed on the carrier part, for example, in the manner of enlarged drops with widened head diameters, wherein the Spraying device insofar then forms the forming tool. The sprayed or otherwise applied droplets retain their droplet shape due to the surface tension of the plastic material in spite of the cellulose base and can be appropriately cured and dried on the support member, for example using a heat source. The paper-like, possibly multi-layered support part then remains absorbent and the applied, on the support part solidified mushroom-like droplets, in turn, increase the scratching effect for improved cleaning of surfaces of any kind.
Bei einer besonders bevorzugten AusfĆ¼hrungsform des erfindungsgemƤĆen Verfahrens werden jedoch die einzelnen Formelemente als pilzfƶrmige Verschlusselemente ausgebildet, so dass sich unter Einsatz des erfindungsgemƤĆen Verfahrens ein Haftverschlussteil aus Papier oder Pappe erzeugen lƤĆt. Die HaftverschluĆelemente lassen sich unmittelbar an Papier- oder Papperzeugnissen wie Schachteln, gegebenenfalls einstĆ¼ckig anbringen, so dass sich die Schachteln zur Aufnahme eines Packgutes verlƤĆlich schlieĆen lassen, ohne dass zusƤtzliche VerschluĆsysteme notwendig wƤren, wie KlebebƤnder, UmreifungsbƤnder, PaketschnĆ¼re und dergleichen mehr. Um den Formelementen eine erhƶhte Steifigkeit zu verleihen, ist es bevorzugt vorgesehen, die zellulosehaltige Suspension, aus der die Form- elemente erzeugbar sind, mit einem Kunststoffmaterial zu versetzen, beispielsweise mit einem vorgebbaren prozentualen Anteil an Ć¼blichem Polymermaterial.In a particularly preferred embodiment of the method according to the invention, however, the individual form elements are formed as mushroom-shaped closure elements, so that can be produced using the method according to the invention, a fastener closure part made of paper or cardboard. The adhesive fastener elements can be attached directly to paper or cardboard products such as boxes, optionally in one piece, so that the boxes can be reliably closed for receiving a packaged goods, without additional closure systems would be necessary, such as tapes, strapping, package cords and the like. In order to give the molded elements increased rigidity, it is preferably provided to offset the cellulosic suspension from which the mold elements can be produced with a plastics material, for example with a predeterminable percentage of conventional polymer material.
Der insoweit Ć¼berwiegend aus Papiermaterial aufgebaute FlƤchenhaftverschluĆ erweist sich als besonders gut recycelbar und biologisch abbaubar. Im Ć¼brigen lƤĆt er sich in groĆtechnischem MaĆstab herstellen, was sich kostengĆ¼nstig auf seinen Herstellpreis auswirkt. Es ist fĆ¼r einen Durchschnittsfachmann Ć¼berraschend, dass er unter Einsatz von zellulosehaltigem Material FlƤchenhaftverschlĆ¼sse in der Art von KlettenĀ®-HaftverschlĆ¼ssen aufbauen kann, die funktionssicher im Gebrauch sind und lang andauernd verwendbar sind.The surface fastener mainly built from paper material so far proves to be particularly easy to recycle and biodegradable. Moreover, it can be produced on an industrial scale, which has a cost effect on its production price. It is surprising to one of ordinary skill in the art that he uses surface-mount fasteners such as Velcro Ā® fasteners using cellulosic material can build, that are reliable in use and long lasting usable.
Die pilzfƶrmigen VerschluĆelemente eines HaftverschluĆteils lassen sich mit pilzfƶrmigen VerschluĆelementen eines anderen HaftverschluĆteils unter Bildung eines wiederholt ƶffenbaren und schlieĆbaren Haftverschlusses miteinander kombinieren; es ist aber auch denkbar ein Ć¼bliches Schlingen- oder Schlaufenmaterial des einen VerschluĆteiles mit dem VerschluĆteil mit den haken- oder pilzfƶrmigen Formelementen aus Papier zu verbinden. Um hier eine besondere Sicherheit in der VerschluĆgeometrie zu erreichen, ist vorzugsweise vorgesehen, dass auf die freie Kopfseite des jeweiligen Formelementes eine duroplastische aushƤrtbare Formmasse aufgebracht wird, die dergestalt den Papierkopf aussteift, um eine sichere Unterhakungsmƶglichkeit gewƤhrleisten zu kƶnnen. Der derart hergestellte VerschluĆ aus Papierformelementen nebst PapiertrƤgerteil baut besonders leicht auf und das eingesetzte Zellulosematerial lƤĆt sich kostengĆ¼nstig in sehr groĆen Mengen auf dem Weltmarkt erhalten, was bei manchen Kunststoffsorten schon heute nicht mehr der Fall ist.The mushroom-shaped closure elements of an adhesive closure part can be combined with mushroom-shaped closure elements of another adhesive closure part to form a repeatedly openable and closable adhesive closure with each other; but it is also conceivable to connect a conventional loop or loop material of a closure part with the closure part with the hook or mushroom-shaped form elements made of paper. In order to achieve a special security in the closure geometry, it is preferably provided that a thermosetting curable molding compound is applied to the free head side of the respective mold element, which stiffen the paper head in order to ensure a safe Unterhakungsmƶglichkeit. The thus produced closure of paper forming elements together with paper carrier part builds particularly easy and the cellulose material used can be obtained inexpensively in very large quantities on the world market, which is already no longer the case with some types of plastic.
Sofern es auf eine weitere Gewichtsreduzierung ankommt, lassen sich die einzelnen Formelemente auch als Hohlelement erhalten, d. h. das Stielinnere des Formelementes bildet einen Hohlraum aus, der bei Bedarf wiederum befĆ¼llt werden kann, beispielsweise mit flammhemmende oder flammresistenten Materialien, um derart auch in sicherheitsrelevanten Bereichen eine erhƶhte Feuersicherheit gewƤhrleisten zu kƶnnen. Insoweit kann das Lƶschmittel direkt in den FlƤchenhaftverschluĆ eingebracht sein.If it depends on a further reduction in weight, the individual mold elements can also be obtained as a hollow element, d. H. the interior of the stem of the mold element forms a cavity, which in turn can be filled if necessary, for example with flame-retardant or flame-resistant materials, so as to be able to ensure increased fire safety in safety-relevant areas. In that regard, the extinguishing agent can be introduced directly into the surface fastener.
Da bei der Anwendung des erfindungsgemƤĆen Verfahrens zellulosehaltige Suspensionen eingesetzt werden, die sehr wasserhaltig sind; so kann beispielsweise 1 % Feststoff auf 99% Wasseranteil kommen, trƤgt diesem Umstand die Herstellvorrichtung insoweit Rechnung, als das Formgebungswerkzeug aus einem Formsieb besteht. Dabei kann die jeweils eingesetzte Siebstruktur auch mehrlagig sein, so dass ein Teil der Siebstruktur Ć¼berwiegend der Formgebung der Formelemente dient und das jeweils andere Siebelement vorrangig der EntwƤsserungsaufgabe nachkommt. Sofern bevorzugt Edelstahlsiebe zur Anwendung kommen, ist der Korrosion wirksam begegnet, auch wenn gegebenenfalls durch weitere Additive der Suspension diese einen gewissen SƤureanteil aufweisen sollte.Since in the application of the method according to the invention cellulose-containing suspensions are used which are very hydrous; Thus, for example, 1% solids can come to 99% water content, this fact takes into account the manufacturing device insofar as the forming tool consists of a forming wire. In this case, the sieve structure used in each case can also be multi-layered, so that a part of the sieve structure mainly serves the shaping of the form elements and the respective other sieve element primarily complies with the drainage task. If preferred stainless steel screens are used, the corrosion has been effectively countered, even if, if appropriate, by further additives of the suspension this should have a certain acid content.
Das mit dem Verfahren und der Vorrichtung hergestellte FlƤchenprodukt lƤĆt sich, wie vorstehend dargelegt, fĆ¼r eine Vielzahl von AnwendungsfƤllen zum Einsatz bringen, wobei die dahingehende Auflistung nicht vollstƤndig ist. Weitere AnwendungsfƤlle sind denkbar im Bereich der Bekleidung; es sind aber auch technische Anwendungen vorstellbar, beispielsweise im Bereich der Luft- und Raumfahrttechnik, Schienentechnik, Maschinenwesen, Kraftfahrzeugbau etc..The surface product produced by the method and the device, as stated above, can be used for a variety of applications, the list is not complete. Other applications are conceivable in the field of clothing; but there are also technical applications conceivable, for example in the field of aerospace engineering, rail technology, mechanical engineering, motor vehicle construction etc ..
Im Folgenden wird die erfindungsgemƤĆe Lƶsung anhand verschiedener AusfĆ¼hrungsformen nach der Zeichnung nƤher erlƤutert. Dabei zeigen in prinzipieller und nicht maĆstƤblicher Darstellung die
- Fig.1
- eine schematische Darstellung einer Herstellvorrichtung zum DurchfĆ¼hren des erfindungsgemƤĆen Verfahrens;
- Fig.2
- eine gegenĆ¼ber der
Fig. 1 geƤnderte AusfĆ¼hrungsform der Herstellvorrichtung; - Fig. 3
- in stark vergrƶĆertem MaĆstab einzelne Formelemente eines FlƤchenproduktes, hergestellt mit einer Herstellvorrichtung nach den
Fig. 1 und2 ; - Fig. 4 bis 6
- einen Teilausschnitt betreffend verschiedene FlƤchenprodukte auf der Grundlage des FlƤchenproduktes nach der
Fig. 3 .
- Fig.1
- a schematic representation of a manufacturing apparatus for performing the method according to the invention;
- Fig.2
- one opposite the
Fig. 1 modified embodiment of the manufacturing device; - Fig. 3
- on a greatly enlarged scale individual form elements of a surface product, manufactured with a manufacturing device according to the
Fig. 1 and2 ; - 4 to 6
- a partial section concerning different surface products on the basis of the surface product after the
Fig. 3 ,
Die Herstellvorrichtung nach der
Die in der Art von Obertrum und Untertrum unterteilten BƤnder 12 und 18 weisen in die Zeichenebene hineinragend eine gewisse Breite auf und die in der
Die Antriebsrichtung der FĆ¼hrungskƶrper 10 ist in der
Ferner kƶnnen KĆ¼hleinrichtungen (nicht dargestellt) vorhanden sein, die das fertige FlƤchenprodukt abkĆ¼hlen, was insoweit auch die Entformung erleichtern kann. ZusƤtzlich kann noch auf der Oberseite des Untertrums eine Blaseinrichtung 28 vorgesehen sein, die beim Entformen des herzustellenden FlƤchenproduktes hilft, wobei der dahingehende EntformungsprozeĆ noch durch eine Entnahmewalze 30 unterstĆ¼tzt werden kann, die das fertig erzeugte FlƤchenprodukt der Herstellvorrichtung aus derselben zum Abtransport und zur weiteren Bearbeitung oder Versand entnimmt. Des weiteren kann die Herstellvorrichtung noch Ć¼ber eine Kalandrierwalze 32 verfĆ¼gen fĆ¼r einen Nachformungsvorgang, was im Folgenden noch nƤher erlƤutert werden wird.Furthermore, cooling devices (not shown) may be present which cool the finished surface product, which may also facilitate demolding to that extent. In addition, a
FĆ¼r den Erhalt des gewĆ¼nschten FlƤchenproduktes wird eine zellulosehaltige Suspension Ć¼ber die Auftrageinrichtung 22 auf die Oberseite des Obertrums des Formsiebes 12 aufgebracht und die wƤssrige Suspension oder Zelluslosebrei dringt in die FormkavitƤten 16 des Formsiebes 12 ein. Bei dem dahingehenden Formgebungsvorgang verbleibt auf der Oberseite des Obertrums des Formsiebes 12 ein bandartiges TrƤgerteil 34 mit dem die einzelnen Formelemente 36 einstĆ¼ckig verbunden sind. Um den Eintrag der Suspension, vorzugsweise in Form des Zellulosebreis in die FormkavitƤten 16 zu erleichtern, dient eine Eintraghilfseinrichtung 38, beispielsweise bestehend aus zwei gegenĆ¼berliegend angeordneten DrĆ¼ckwalzen, die mit einer entsprechenden Anpresskraft den beschriebenen Eintrag unterstĆ¼tzen und die Dichte des TrƤgerteils 34 mit vorgeben.To obtain the desired surface product, a cellulose-containing suspension is applied via the
Es kƶnnen hier mehrere DrĆ¼ckwalzen vorgesehen sein, die der Einfachheit halber in der Darstellung weggelassen sind. Alternativ oder zusƤtzlich zu den angesprochenen DrĆ¼ckwalzen kann die Eintraghilfseinrichtung 38 auch eine nicht nƤher dargestellte Luftrakelanordnung aufweisen, mit der in der Art eines Luftvorhanges und unter Ćberdruck der Eintrag im beschriebenen Umfang unterstĆ¼tzt wird. Der FormprozeĆ wird derart mit einer Geschwindigkeit gefahren, dass jedenfalls Ć¼berschĆ¼ssiges Wasser aus der Suspension austreten und die Perforation 20 des EntwƤsserungsbandes 18 durchdringen kann, um dann von der wannenartigen Auffangeinrichtung 26 gesammelt aus der Herstellvorrichtung abgefĆ¼hrt werden zu kƶnnen. Die bereits aufgezeigte Trockeneinrichtung 24 dient darĆ¼ber hinaus von der anderen Seite her dem Abtrocknen des zu verfestigenden Zellstoffs, der die Papierstruktur fĆ¼r das FlƤchenprodukt bildet.It can be provided here several pressure rollers, which are omitted for simplicity in the illustration. As an alternative or in addition to the mentioned spinning rollers, the
Ist der Zellstoffbrei, insbesondere im Bereich des Untertrums der Herstellvorrichtung soweit abgetrocknet, lƤĆt sich das bandfƶrmige TrƤgerteil 34 von der Oberseite des Formsiebes 12, vorzugsweise unter Einsatz der Entnahmewalze 30 abziehen und die fertigen Formelemente 36 werden aus den zuordenbaren FormkavitƤten 16 herausgezogen, was durch die aufgezeigte Blaseinrichtung 28 noch mit unterstĆ¼tzt werden kann, indem diese Druckluft durch die Perforation 20 des EntwƤsserungsbandes 18 blƤst, sowie durch die FormkavitƤten 16 des Formsiebes 12 von dessen rĆ¼ckwƤrtigem Bereich her. Die derart ausgeformten Formelemente 36 nebst dem TrƤgerteil 34 haben einen grundsƤtzlich geometrischen Aufbau, wie in der
Wie bereits aufgezeigt, eignet sich zur Bildung des FlƤchenproduktes eine zellulosehaltige Suspension, bei der etwa 1 % Feststoff auf 99% Wasseranteil fƤllt. Zur Bildung der Zellulosesuspension werden vorzugsweise Fasern eingesetzt mit einem Durchmesser zwischen 1Āµm und 100Āµm, vorzugsweise in der GrƶĆenordnung von 10Āµm und die LƤnge der jeweiligen Zellstofffaser soll im Bereich von 10Āµm bis 2mm liegen, vorzugsweise etwa 100Āµm betragen. Als besonders gĆ¼nstig hat sich erwiesen Zellstofffasern aus pflanzlichen Rohmaterialien zu gewinnen, wobei vorzugsweise Kiefer und Fichte als Einsatzmaterial einen langfaserigen Zellstoff ergeben, der besonders gut im Rahmen der beschriebenen Herstellvorrichtung einsetzbar ist.As already indicated, the formation of the surface product is a cellulosic suspension in which about 1% solids to 99% water content falls. To form the cellulosic suspension, fibers are preferably used having a diameter between 1 .mu.m and 100 .mu.m, preferably of the order of 10 .mu.m, and the length of the respective pulp fiber should be in the range of 10 .mu.m to 2 mm, preferably about 100 .mu.m. It has proven to be particularly favorable to obtain pulp fibers from vegetable raw materials, wherein preferably pine and spruce as the feedstock result in a long-fiber pulp which can be used particularly well within the framework of the described production device.
Es hat sich jedoch in der Praxis gezeigt, dass eine reine Zellstoffsuspension je nach Anwendungsfall fĆ¼r das fertige FlƤchenerzeugniss als Papierprodukt sich als zuwenig stabil erweisen kann, so dass der Einsatz von Kunststoffmaterialien, wie Polymermischungen, Sinn macht, wobei es sich als besonders gĆ¼nstig erwiesen hat 10 bis 15,5% Polymermaterial in der Suspension zum Einsatz zu bringen. Ferner kƶnnen Additive der zellulosehaltigen Suspension zugesetzt werden, wie beispielsweise Nassfestmittel in Form von Melaminharz oder in Form von Epichlorhydrinharz. Um ein verstƤrktes Anhaften des Zellulosebreis auf dem Formsieb 12 verhindern zu helfen, kann ein Antihaftmittel, beispielsweise in Form von Talkumpuder Ć¼ber eine geeignete Einrichtung (nicht dargestellt) auf das Formsieb 12 mit seinen KavitƤten 16 aufgetragen werden. Weitere ZusƤtze kƶnnen dazu vorgesehen sein, aus der Zellstoffsuspension Formaldehyd abzuspalten oder Verunreinigungen, die den ProzeĆ behindern kƶnnten, zu beseitigen.However, it has been shown in practice that a pure pulp suspension depending on the application for the finished surface product as a paper product may prove to be too stable, so that the use of plastic materials, such as polymer blends, makes sense, and it has proved to be particularly favorable 10 to 15.5% polymer material in the suspension to use. Further, additives may be added to the cellulosic suspension, such as wet strength agent in the form of melamine resin or in the form of epichlorohydrin resin. To an increased attachment To prevent the cellulose pulp on the forming
Als besonders vorteilhaft hat es sich erwiesen als Zelluloseeinsatzmaterial auf gleichlange Stapelfasern zurĆ¼ckzugreifen, wobei auch sogenannte Bikomponentenfasern zum Einsatz kommen kƶnnen, die jeweils einen Zellulosekern aufweisen, der von einer PolymerhĆ¼lle umfasst ist. Das dahingehende Zelluloseeintragmaterial ist auf dem Markt frei erhƤltlich, so dass hier nicht mehr nƤher auf Einzelheiten eingegangen wird. Da das Papier-FlƤchenprodukt erfahrungsgemĆ¤Ć leicht brennbar ist, kƶnnen Zusatzmaterialien eingesetzt werden, um flammhemmend oder als aktives Lƶschmedium zu wirken. HierfĆ¼r geeignet sind insbesondere folgende Stoffgruppen:
- Ammonium Phosphat (AP)
- Ammonium Polyphosphat (APP)
- Resorcinol bis-Diphenylphosphat (PDP)
- Roter Phosphor (RP)
- Tri-n-butyl Phosphat (TBP)
- Tricresyl Phosphat (TCP)
- Triphenyl Phosphat (TPP).
- Ammonium phosphate (AP)
- Ammonium polyphosphate (APP)
- Resorcinol bis-diphenyl phosphate (PDP)
- Red phosphorus (RP)
- Tri-n-butyl phosphate (TBP)
- Tricresyl phosphate (TCP)
- Triphenyl phosphate (TPP).
Als aktives Lƶschmedium kann bevorzugt ein Lƶschgas wie Stickstoff vorgesehen sein, wobei als StickstofftrƤger insbesondere Melamin in Frage kommt aber auch Magnesium Hydroxid (MDH). Vorzugsweise kann ferner vorgesehen sein, dass zumindest in das TrƤgerteil 34 Nano-Partikel wie Silicate oder Graphit eingebracht oder aufgetragen werden, die gleichfalls sehr gute Lƶscheigenschaften besitzen und darĆ¼ber hinaus das papierne TrƤgerteil 34 bei Bedarf aussteifen kƶnnen.As an active extinguishing medium may preferably be provided an extinguishing gas such as nitrogen, wherein as a nitrogen carrier, in particular melamine comes into question but also magnesium hydroxide (MDH). Preferably, it may further be provided that at least in the
Besonders vorteilhaft ist es jedoch auf die Unterseite des Obertrums der BƤnder 12 und 18 eine nicht nƤher dargestellte Vakuumeinrichtung zu setzen, die beispielsweise im Bereich der Auffangeinrichtung 26 angeordnet, die EntwƤsserung der Fasersuspension begĆ¼nstigt, und Zellstoffmaterial solange aus den einzelnen FormkavitƤten 16 mit absaugt, bis ein hohler Stielquerschnitt (nicht dargestellt) fĆ¼r das einzelne Formelement 36 geschaffen ist, das sich im Ć¼brigen mit seinem randseitigen Material an der jeweils zuordenbaren FormkavitƤt 16 anlegt. Der insoweit hergestellte hohle Stielteil kann dann mit einem flammhemmenden Mittel versehen werden oder aber dem Eintrag eines sonstigen Aussteifungsmittels dienen, beispielsweise in Form eines einzuspritzenden Polymer-Kunststoffmateriales. Vorzugsweise wird jedoch daran festgehalten, im wesentlichen ein als Ganzes aus Papier- oder Pappmaterial bestehendes FlƤchenprodukt als Enderzeugniss zu erhalten, das von der Gewichtsseite her betrachtet sehr leicht aufbaut und insoweit dort immer Verwendung finden kann, wo es auf eine Gewichtsreduktion ankommt, beispielsweise im technischen Bereich des Flugzeugbaus, wo der Einsatz solcher flexiblen FlƤchenprodukte auch als Kabelbinder oder dergleichen mƶglich wƤre. Auch lieĆen sich Polsterbezugstoffe, Wandverkleidungen oder dergleichen mit dem aufgezeigten PapierverschluĆmaterial in Leichtbauweise sicher festlegen.It is particularly advantageous, however, to put on the underside of the upper strand of the
Als Verarbeitungstemperaturen fĆ¼r die aufzutragende wƤssrige Zellstoffsuspension haben sich Temperaturen um die 60Ā°C als gĆ¼nstig erwiesen, sowie eine Verweilzeit von 10 bis 15 Min bei einer Temperatur von 70Ā°C fĆ¼r die Trockungszone mittels der Trockeneinrichtung 24. Um das fertige FlƤchenprodukt mƶglichst wenig zu schƤdigen, ist bevorzugt eine Teflonauflage fĆ¼r die Kalandrierwalze 32 vorgesehen. Ferner kƶnnen, nicht nƤher aufgezeigte, Binder- und Vernetzermaterialien zum Einsatz kommen, um eine Verfestigung des Zellstoffmaterials zu begĆ¼nstigen.As processing temperatures for the applied aqueous pulp suspension temperatures around 60 Ā° C have proven to be favorable, and a residence time of 10 to 15 minutes at a temperature of 70 Ā° C for the drying zone by means of the drying
Sofern eine Kalandrierwalze 32 gemĆ¤Ć der Darstellung nach der
Wird hingegen eine Struktur beibehalten, wie sie in den
Nachfolgend wird noch eine modifizierte Herstellvorrichtung nach der
Auch die Lƶsung nach der
Das Band der Eintraghilfseinrichtung 38 kann vorzugsweise aus einem flexiblen, elastisch nachgiebigen Material bestehen; es ist hier aber auch der Einsatz von Metallfolienwerkstoffen, wie einer Aluminiumfolie oder dergleichen mƶglich. Das Band der Eintraghilfseinrichtung 38 kann selbstƤndig angetrieben werden oder aber bevorzugt durch die Reibung bei der Rotationsbewegung des FĆ¼hrungskƶrpers 10 mitgenommen werden. Ferner weist die Lƶsung nach der
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EP2123826A3 EP2123826A3 (en) | 2013-06-19 |
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Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102021005940A1 (en) | 2021-12-01 | 2023-06-01 | Gottlieb Binder Gmbh & Co. Kg | Method of making a fastener tape |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002013647A2 (en) | 2000-08-16 | 2002-02-21 | Gottlieb Binder Gmbh & Co | Method for producing an adhesive closing element |
EP1028639B1 (en) | 1997-10-03 | 2004-06-16 | Minnesota Mining And Manufacturing Company | Coextruded mechanical fastener constructions |
WO2007059862A1 (en) | 2005-11-22 | 2007-05-31 | Seyfert Gmbh | Stand part |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6660366B1 (en) * | 1998-07-31 | 2003-12-09 | Eugene D. Simpson | Interlocking fastening and packing material |
US6660362B1 (en) * | 2000-11-03 | 2003-12-09 | Kimberly-Clark Worldwide, Inc. | Deflection members for tissue production |
US8877316B2 (en) * | 2002-12-20 | 2014-11-04 | The Procter & Gamble Company | Cloth-like personal care articles |
DE102006054770B4 (en) * | 2006-11-17 | 2015-12-10 | Cvp Clean Value Plastics Gmbh | Process for the recycling of waste plastic, in particular mixed plastic |
-
2008
- 2008-05-21 DE DE102008024528A patent/DE102008024528A1/en not_active Withdrawn
-
2009
- 2009-05-13 EP EP09006429.6A patent/EP2123826B1/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1028639B1 (en) | 1997-10-03 | 2004-06-16 | Minnesota Mining And Manufacturing Company | Coextruded mechanical fastener constructions |
WO2002013647A2 (en) | 2000-08-16 | 2002-02-21 | Gottlieb Binder Gmbh & Co | Method for producing an adhesive closing element |
WO2007059862A1 (en) | 2005-11-22 | 2007-05-31 | Seyfert Gmbh | Stand part |
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US11486092B2 (en) | 2016-10-27 | 2022-11-01 | The Procter & Gamble Company | Deflecting member for making fibrous structures |
US10815618B2 (en) | 2016-10-27 | 2020-10-27 | The Procter & Gamble Company | Deflecting member for making fibrous structures |
US11583489B2 (en) | 2016-11-18 | 2023-02-21 | First Quality Tissue, Llc | Flushable wipe and method of forming the same |
US10619309B2 (en) | 2017-08-23 | 2020-04-14 | Structured I, Llc | Tissue product made using laser engraved structuring belt |
US11286622B2 (en) | 2017-08-23 | 2022-03-29 | Structured I, Llc | Tissue product made using laser engraved structuring belt |
US11396725B2 (en) | 2017-10-27 | 2022-07-26 | The Procter & Gamble Company | Deflecting member for making fibrous structures |
US11732413B2 (en) | 2017-10-27 | 2023-08-22 | The Procter & Gamble Company | Deflecting member for making fibrous structures |
US12097654B1 (en) | 2017-10-27 | 2024-09-24 | The Procter & Gamble Company | Deflecting member for making fibrous structures |
US11505898B2 (en) | 2018-06-20 | 2022-11-22 | First Quality Tissue Se, Llc | Laminated paper machine clothing |
US11738927B2 (en) | 2018-06-21 | 2023-08-29 | First Quality Tissue, Llc | Bundled product and system and method for forming the same |
US11697538B2 (en) | 2018-06-21 | 2023-07-11 | First Quality Tissue, Llc | Bundled product and system and method for forming the same |
Also Published As
Publication number | Publication date |
---|---|
EP2123826B1 (en) | 2015-09-23 |
EP2123826A3 (en) | 2013-06-19 |
DE102008024528A1 (en) | 2009-11-26 |
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