EP2173974B1 - Heat shield segment for a stator of a gas turbine - Google Patents
Heat shield segment for a stator of a gas turbine Download PDFInfo
- Publication number
- EP2173974B1 EP2173974B1 EP08761301A EP08761301A EP2173974B1 EP 2173974 B1 EP2173974 B1 EP 2173974B1 EP 08761301 A EP08761301 A EP 08761301A EP 08761301 A EP08761301 A EP 08761301A EP 2173974 B1 EP2173974 B1 EP 2173974B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- heat shield
- turbine
- shield segment
- gas turbine
- elevation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 11
- 230000035882 stress Effects 0.000 description 4
- 238000010276 construction Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 230000008646 thermal stress Effects 0.000 description 2
- 239000000567 combustion gas Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D9/00—Stators
- F01D9/06—Fluid supply conduits to nozzles or the like
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2240/00—Components
- F05D2240/10—Stators
- F05D2240/11—Shroud seal segments
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2260/00—Function
- F05D2260/20—Heat transfer, e.g. cooling
- F05D2260/231—Preventing heat transfer
Definitions
- the invention relates to gas turbines according to the preamble of claim 1.
- the EP 1 225 305 B1 shows "textbook" on how the heat shield high stress concentrations that can be caused in operation due to high temperature and pressure, can be reduced or safely absorbed by the component.
- the known heat shield segment is amplified along critical lines.
- the transverse reinforcing ribs (10a, 10b) extend both in the circumferential direction and in the longitudinal direction.
- the US 5,380,150 shows as another example in Fig. 3 a high thermal stress heat shield segment with closed fin collar and adjacent reinforcing bumps at the end portions in the circumferential direction of the segments.
- the ribbed ring extends in the interior and not in the end of the heat shield.
- constructions are known in which, for reasons of weight, the ribs are dimensioned as short as possible, for example in the form of rib projections or elevations, so that a rib passing through between the end regions of the segment is dispensed with.
- the ribs are dimensioned as short as possible, for example in the form of rib projections or elevations, so that a rib passing through between the end regions of the segment is dispensed with.
- the heat shield segment of the gas turbine has a curved section in at least one region of the profile in the longitudinal direction of the gas turbine, wherein a radially outer surface of the heat shield segment in the region of the curved section in a first end region in the circumferential direction of the turbine with a is provided in the circumferential direction of the turbine extending increase.
- the stresses in the heat shield segment are reduced in the region of the curved portion. This leads to a considerable extension of the service life.
- the length of the increase in the circumferential direction is less than a quarter of the total length of the heat shield segment in the circumferential direction.
- the heat shield segment is sufficiently strengthened without having to provide a fin extending between the end ribs, which avoids additional metal consumption, so that the weight of the heat shield can be kept low.
- FIG. 4 is a heat shield segment 1 according to the prior art known from preliminary experiments.
- a heat shield may include a number of such heat shield segments 1 that define an outer boundary of a hot gas flow along the turbine blades 2 (see, eg, FIG FIG. 3 ) form.
- the profile of the heat shield segment 1 adapts to the basically conical guidance of a turbine rotor (not shown), and has a stepped cross section, as shown in FIG FIG. 3 can be seen.
- Halterseiementen 3 On the radially outer side of the heat shield segment 1 are Halterseiementen 3, 4 are arranged, which serve for positioning of the heat shield segment 1 in the radial direction and in the circumferential direction.
- FIG. 3 is a cross section through a turbine section with a heat shield segment according to said prior art shown.
- the turbine blades 2 of the turbine rotor have a circumferential, on the Radial outside of the turbine rotor arranged and cylindrically extending shroud 5 on.
- the shroud 5 has on its radial outer side two radially outwardly extending ribs 6.
- the two ribs 6 in the radial direction opposite to the heat shield segment 1 each honeycomb structures 7 are fixedly connected, which serve to seal the distance between the rib tip 6 and the heat shield segment 1.
- the inner mold 8 of the heat shield extends in a first section 9 substantially parallel to the longitudinal axis of the turbine.
- the inner mold 8 of the heat shield segment 1 in a second portion 11 extend obliquely to the longitudinal axis of the turbine, wherein the flow direction of the hot gas through the turbine is indicated by arrow 10. Since the heat shield segment 1 is exposed to the high temperature of the hot gas flow and the high pressure loss in the flow direction, it can in the curved portion 12 of the heat shield segment 1 between the first portion 9 and the second portion 11 and in particular in the end portions 13 of the heat shield segment 1 in the circumferential direction of the turbine lead to high voltages that can significantly limit the life of the heat shield segment 1.
- FIG. 1 a heat shield segment 1 according to a preferred embodiment of the invention is shown. Identical components are provided with the same reference numerals.
- a radially outer side 15 of the heat shield segment 1 is provided in the region of the curved section 12 and in at least one end region 13 of the heat shield segment 1 in the circumferential direction with an elevation 14 or shoulder extending in the circumferential direction of the turbine. This increase or decrease reduces the stress concentration in this area of the heat shield segment 1.
- An elevation or projection may be provided at each end 13 of the heat shield segment 1, respectively.
- the elevation or neck in the longitudinal direction of the turbine is located at a location where the first portion 9 and the second portion 11 meet.
- the length of the elevation 14 in the circumferential direction is less than one quarter of the total length of the heat shield segment 1 in the circumferential direction.
- the additional metal consumption can be kept low because no running between the ends of the heat shield segment 1 rib must be provided. Thereby, the weight of the heat shield segment 1 can be kept low.
- the radially outer surface 15 of the heat shield segment 1 is provided with two ribs 16 which extend at least partially at the ends of the heat shield segment 1 in the circumferential direction of the turbine in the longitudinal direction of the turbine.
- the elevation 14 or projection protrudes from the respective rib 16 in the circumferential direction.
- the profile of the heat shield segment 1 in the circumferential direction of the turbine and in the region of the elevation 14 have a two-stage shape, as shown in FIG. 2 is apparent.
- the length of the increase in the circumferential direction of the turbine to the width of the increase in the longitudinal direction of the turbine in the ratio of 1: 2 to 3: 1 behaves.
- the heat shield segment 1 has a curved section in at least two locations of the heat shield segment profile in the longitudinal direction of the turbine, that is to say that the heat shield cross section is formed essentially in two stages.
- the radial outside of the heat shield segment is in each case in the regions of the curved sections and in a first and / or a second end region each provided in the circumferential direction of the heat shield segment with a 14 extending in the circumferential direction of the turbine elevation.
- a heat shield may be equipped with a number of heat shield segments 1 according to the invention which have an outer boundary of a hot gas flow along the turbine blades 2 (cf. FIG. 3 ) form.
- the heat shield segments 1 are provided with a running in the longitudinal direction of the turbine groove 17 respectively in the end sides, as shown in FIG. 2 is apparent.
- the grooves 17 of two adjacent heat shield segments 1 serve to receive a seal plate (not shown) which prevents the penetration of hot combustion gases into the cooling air filled cavity 18 between the heat shield and the turbine housing 19.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
Abstract
Description
Die Erfindung betrifft Gasturbinen gemäß dem Oberbegriff des Anspruchs 1.The invention relates to gas turbines according to the preamble of
Es ist allgemein bekannt und üblich, in Gasturbinen segmentierte Hitzeschilde vorzusehen, um die thermische Beanspruchung des Gasturbinengehäuses zu begrenzen.It is well known and common to provide segmented heat shields in gas turbines to limit the thermal stress on the gas turbine casing.
Die
Mittels einer verstärkten Leichtbaukonstruktion mit spezieller Rippengestaltung am Außenrand sowie in den Querrichtungen, wie sie zum Beispiel in
Die
Im Übrigen sind Konstruktionen bekannt, bei denen aus Gewichtsgründen die Rippen möglichst kurz bemessen werden, z.B. in Form von Rippenansätzen oder Erhöhungen, so dass eine zwischen den Endbereichen des Segmentes durchlaufende Rippe erübrigt wird. Jedoch ist aus dem Stand der Technik keinerlei Hinweis darauf zu entnehmen, dass speziell in einem gekrümmten Längsabschnitt des Hitzeschildsegmentes, wie es beispielsweise aus der
Hier setzt die Erfindung an. Dabei liegt der vorliegenden Erfindung die Aufgabe zugrunde, eine Gasturbine mit Hitzeschildsegmenten für den Stator der Gasturbine mit verbesserter Konstruktion bereit zu stellen, wobei die Spannungen im gekrümmten Bereich des Hitzeschildsegmentes deutlich vermindert werden sollen.This is where the invention starts. It is the object of the present invention to provide a gas turbine with heat shield segments for the stator of the gas turbine with improved design, wherein the stresses in the curved portion of the heat shield segment should be significantly reduced.
Erfindungsgemäß wird dies durch die kennzeichnenden Merkmale des Anspruches 1 gelöst.This is achieved by the characterizing features of
Bei der Erfindung ist besonders bemerkenswert, dass das Hitzeschildsegment der Gasturbine in mindestens einem Bereich des Profils in Längsrichtung der Gasturbine einen gekrümmten Abschnitt aufweist, wobei eine radial äußere Fläche des Hitzeschildsegmentes im Bereich des gekrümmten Abschnitts in einem ersten Endbereich in Umfangsrichtung der Turbine mit einer sich in Umfangsrichtung der Turbine erstreckenden Erhöhung versehen ist. Dadurch werden die Spannungen im Hitzeschildsegment im Bereich des gekrümmten Abschnittes vermindert. Dies führt zu einer erheblichen Verlängerung der Lebensdauer.It is particularly noteworthy in the invention that the heat shield segment of the gas turbine has a curved section in at least one region of the profile in the longitudinal direction of the gas turbine, wherein a radially outer surface of the heat shield segment in the region of the curved section in a first end region in the circumferential direction of the turbine with a is provided in the circumferential direction of the turbine extending increase. As a result, the stresses in the heat shield segment are reduced in the region of the curved portion. This leads to a considerable extension of the service life.
In vorteilhafter Ausgestaltung der Erfindung beträgt die Länge der Erhöhung in Umfangsrichtung weniger als ein Viertel der Gesamtlänge des Hitzeschildsegmentes in Umfangsrichtung. Gleichwohl wird das Hitzeschildsegment genügend verstärkt, ohne dass eine zwischen den Endbereichen verlaufende Rippe vorgesehen werden muss, was zusätzlichen Metallverbrauch vermeidet, so dass das Gewicht des Hitzeschildes gering gehalten werden kann.In an advantageous embodiment of the invention, the length of the increase in the circumferential direction is less than a quarter of the total length of the heat shield segment in the circumferential direction. However, the heat shield segment is sufficiently strengthened without having to provide a fin extending between the end ribs, which avoids additional metal consumption, so that the weight of the heat shield can be kept low.
Weitere Vorteile und Ausgestaltungen der Erfindung ergeben sich aus der nachfolgenden Beschreibung und den beiliegenden Zeichnungen.Further advantages and embodiments of the invention will become apparent from the following description and the accompanying drawings.
Die Erfindung wird anhand eines Ausführungsbeispiels in den Zeichnungen schematisch dargestellt und im Folgenden unter Bezugnahme auf die Zeichnungen ausführlich beschrieben.The invention will be described schematically with reference to an embodiment in the drawings and described in detail below with reference to the drawings.
Es zeigen, jeweils schematisch,
Figur 1- in perspektivischer Ansicht ein Hitzeschildsegment gemäß einer Ausführungsform der Erfindung,
Figur 2- einen Schnitt durch das Hitzeschildsegment in
im Bereich der Erhöhung entlang der Linie A-A,Figur 1 Figur 3- einen Querschnitt durch einen Turbinenabschnitt mit einem Hitzeschildsegment gemäß einem Vorversuch der Patentinhaberin, bzw. -anmelderin,
Figur 4- in perspektivischer Ansicht ein Hitzeschildsegment gemäß dem Vorversuch der Patentinhaberin, bzw. -anmelderin.
- FIG. 1
- a perspective view of a heat shield segment according to an embodiment of the invention,
- FIG. 2
- a section through the heat shield segment in
FIG. 1 in the area of the increase along the line AA, - FIG. 3
- a cross section through a turbine section with a heat shield segment according to a preliminary test of the patent owner,
- FIG. 4
- in perspective view of a heat shield segment according to the preliminary test of the patent owner, or -anmelderin.
In
In
In
Vorzugsweise ist die Erhöhung oder der Ansatz in Längsrichtung der Turbine an einer Stelle, an der der erste Abschnitt 9 und der zweite Abschnitt 11 sich treffen, angeordnet.Preferably, the elevation or neck in the longitudinal direction of the turbine is located at a location where the
Vorzugsweise beträgt die Länge der Erhöhung 14 in Umfangsrichtung weniger als ein viertel der Gesamtlänge des Hitzeschildsegments 1 in Umfangsrichtung. Hierbei kann der zusätzliche Metallverbrauch gering gehalten werden, weil keine zwischen den Enden des Hitzeschildsegments 1 verlaufende Rippe vorgesehen werden muss. Dadurch kann das Gewicht des Hitzeschildsegments 1 gering gehalten werden.Preferably, the length of the
In der bevorzugten Ausführungsform in
In einer weitern Ausführungsform (nicht gezeigt) weist das Hitzeschildsegment 1 an mindestens zwei Stellen des Hitzeschildsegmentprofils in Längsrichtung der Turbine einen gekrümmten Abschnitt auf, dass heißt, dass der Hitzeschildquerschnitt im Wesentlichen zweistufig ausgebildet ist. In diesem Fall ist die radiale Außenseite des Hitzeschildsegments jeweils in den Bereichen der gekrümmten Abschnitte und in einem ersten und/oder einem zweiten Endbereich in Umfangsrichtung des Hitzeschildsegments jeweils mit einer sich in Umfangsrichtung der Turbine erstreckenden Erhöhung 14 versehen.In a further embodiment (not shown), the
Ein Hitzeschild kann mit einer Anzahl von erfindungsgemäßen Hitzeschildsegmenten 1 ausgestattet sein, die eine äußere Begrenzung einer heißen Gasströmung entlang den Turbinenlaufschaufeln 2 (vgl. z.B.
Die vorhergehende Beschreibung der Ausführungsbeispiele gemäß der vorliegenden Erfindung dient nur zu illustrativen Zwecken und nicht zum Zwecke der Beschränkung der Erfindung.The foregoing description of the embodiments according to the present invention is for illustrative purposes only, and not for the purpose of limiting the invention.
- 11
- HitzeschildsegmentHeat shield segment
- 22
- TurbinenlaufschaufelTurbine blade
- 33
- Halterungselementsupporting member
- 44
- Halterungselementsupporting member
- 55
- Deckbandshroud
- 66
- Ripperib
- 77
- HonigwabenstrukturHoneycomb structure
- 88th
- Innenforminterior shape
- 99
- erster Abschnittfirst section
- 1010
- Strömungsrichtungflow direction
- 1111
- zweiter Abschnittsecond part
- 1212
- gekrümmter Bereichcurved area
- 1313
- Endbereichend
- 1414
- Erhöhungincrease
- 1515
- radiale Außenseiteradial outside
- 1616
- Ripperib
- 1717
- Nutgroove
- 1818
- Hohlraumcavity
- 1919
- Turbinengehäuseturbine housing
Claims (7)
- Gas turbine, which has a rotatably mounted turbine rotor with turbine blades (2) and at least one stator-side heat shield segment (1), the respective heat shield segment (1) being arranged radially between the turbine rotor and a turbine casing (19) and fastened to the turbine casing (19) and having a profile which has a curved portion (12) in at least one region of the profile in the longitudinal direction of the turbine, characterized- in that, in the region of the curved portion (12) and in a first end region in the circumferential direction of the gas turbine, a radial outer side (15) of the heat shield segment (1) is provided with at least one elevation (14) extending in the circumferential direction of the gas turbine,- in that the radially outer face (15) of the heat shield segment (1) is provided with a rib (16), which, located at the end of the heat shield segment (1) in the circumferential direction of the gas turbine, at least partially extends in the longitudinal direction of the gas turbine, the elevation (14) protruding from the rib (16) in the circumferential direction,- in that, in the region of the curved portion (12) and in a second end region that is opposite from the first end region, the radially outer face (15) of the heat shield segment (1) is provided with a second elevation (14) extending in the circumferential direction of the turbine,- in that the profile of the heat shield segment (1) has in the region of the respective elevation (14) in the circumferential direction of the gas turbine a two-staged shape, a first stage leading from the radially outer face (15) of the heat shield segment (1) to the respective elevation (14), while a second stage leads from the respective elevation (14) to the rib (16).
- Gas turbine according to Claim 1, characterized in that the length of the elevation (14) in the circumferential direction of the gas turbine is less than one quarter of the total length of the heat shield segment (1) in the circumferential direction.
- Gas turbine according to one of the preceding claims, characterized in that the length of the elevation (14) in the circumferential direction of the turbine is in a ratio of 1:2 to 3:1 to the width of the elevation (14) in the longitudinal direction of the turbine.
- Gas turbine according to one of the preceding claims, characterized in that the heat shield segment (1) has at at least two points of the heat shield segment profile in the longitudinal direction of the turbine a curved portion (12), the radially outer face of the heat shield segment (1) being respectively provided in the region of the curved portions (12) and in a first and/or second end region in the circumferential direction of the heat shield segment (1) in each case with an elevation (14) extending in the circumferential direction of the turbine.
- Gas turbine according to one of the preceding claims, characterized in that the inner shape of the heat shield segment (1) has a first portion (9), running substantially parallel to the longitudinal direction of the turbine, and a second portion (11), adjacent to the first portion (9) in the upstream direction and running obliquely in relation to the longitudinal direction, the elevation (14) in the longitudinal direction of the turbine being arranged at a point at which the first and second portions (9, 11) meet.
- Gas turbine according to one of the preceding claims, characterized in that a groove (17) running in the longitudinal direction of the turbine is provided in a radially extending outer side of the heat shield segment (1), at least in the region of the elevation (14).
- Gas turbine according to one of the preceding claims, characterized in that a number of heat shield segments (1) form a heat shield, which forms an outer delimitation of a hot gas flow along the turbine blades (2).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH10432007 | 2007-06-28 | ||
PCT/EP2008/057946 WO2009000801A1 (en) | 2007-06-28 | 2008-06-23 | Heat shield segment for a stator of a gas turbine |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2173974A1 EP2173974A1 (en) | 2010-04-14 |
EP2173974B1 true EP2173974B1 (en) | 2011-10-26 |
Family
ID=38508786
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08761301A Active EP2173974B1 (en) | 2007-06-28 | 2008-06-23 | Heat shield segment for a stator of a gas turbine |
Country Status (7)
Country | Link |
---|---|
US (1) | US8182210B2 (en) |
EP (1) | EP2173974B1 (en) |
AT (1) | ATE530736T1 (en) |
CA (1) | CA2690705C (en) |
SI (1) | SI2173974T1 (en) |
TW (1) | TWI475152B (en) |
WO (1) | WO2009000801A1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8926269B2 (en) * | 2011-09-06 | 2015-01-06 | General Electric Company | Stepped, conical honeycomb seal carrier |
WO2014105512A1 (en) * | 2012-12-29 | 2014-07-03 | United Technologies Corporation | Mechanical linkage for segmented heat shield |
US10233844B2 (en) | 2015-05-11 | 2019-03-19 | General Electric Company | System for thermally shielding a portion of a gas turbine shroud assembly |
DE102016213810A1 (en) | 2016-07-27 | 2018-02-01 | MTU Aero Engines AG | Cladding element for a turbine intermediate housing |
US10358922B2 (en) * | 2016-11-10 | 2019-07-23 | Rolls-Royce Corporation | Turbine wheel with circumferentially-installed inter-blade heat shields |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3365173A (en) * | 1966-02-28 | 1968-01-23 | Gen Electric | Stator structure |
US4987736A (en) * | 1988-12-14 | 1991-01-29 | General Electric Company | Lightweight gas turbine engine frame with free-floating heat shield |
US5380150A (en) * | 1993-11-08 | 1995-01-10 | United Technologies Corporation | Turbine shroud segment |
DE19915049A1 (en) * | 1999-04-01 | 2000-10-05 | Abb Alstom Power Ch Ag | Heat shield for a gas turbine |
US6290459B1 (en) * | 1999-11-01 | 2001-09-18 | General Electric Company | Stationary flowpath components for gas turbine engines |
US6502622B2 (en) * | 2001-05-24 | 2003-01-07 | General Electric Company | Casting having an enhanced heat transfer, surface, and mold and pattern for forming same |
JP3632003B2 (en) * | 2000-03-07 | 2005-03-23 | 三菱重工業株式会社 | Gas turbine split ring |
JP4698847B2 (en) * | 2001-01-19 | 2011-06-08 | 三菱重工業株式会社 | Gas turbine split ring |
US6779597B2 (en) * | 2002-01-16 | 2004-08-24 | General Electric Company | Multiple impingement cooled structure |
DE102005013798A1 (en) * | 2005-03-24 | 2006-09-28 | Alstom Technology Ltd. | Heat release segment for sealing a flow channel of a flow rotary machine |
US8528339B2 (en) * | 2007-04-05 | 2013-09-10 | Siemens Energy, Inc. | Stacked laminate gas turbine component |
-
2008
- 2008-06-23 AT AT08761301T patent/ATE530736T1/en active
- 2008-06-23 CA CA2690705A patent/CA2690705C/en not_active Expired - Fee Related
- 2008-06-23 SI SI200830526T patent/SI2173974T1/en unknown
- 2008-06-23 EP EP08761301A patent/EP2173974B1/en active Active
- 2008-06-23 WO PCT/EP2008/057946 patent/WO2009000801A1/en active Application Filing
- 2008-06-27 TW TW097124440A patent/TWI475152B/en not_active IP Right Cessation
-
2009
- 2009-12-23 US US12/645,880 patent/US8182210B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US20100150712A1 (en) | 2010-06-17 |
CA2690705A1 (en) | 2008-12-31 |
SI2173974T1 (en) | 2012-03-30 |
CA2690705C (en) | 2015-08-04 |
EP2173974A1 (en) | 2010-04-14 |
US8182210B2 (en) | 2012-05-22 |
WO2009000801A1 (en) | 2008-12-31 |
TWI475152B (en) | 2015-03-01 |
ATE530736T1 (en) | 2011-11-15 |
TW200925389A (en) | 2009-06-16 |
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