EP1965869A1

EP1965869A1 - Cosmetic preparation with merocyanines in dissolved form

Info

Publication number: EP1965869A1
Application number: EP06830562A
Authority: EP
Inventors: Andreas Clausen; Claudia Mundt; Kerstin Skubsch; Christoph Smuda; Heike Lerg
Original assignee: Beiersdorf AG
Current assignee: Beiersdorf AG
Priority date: 2005-12-13
Filing date: 2006-12-12
Publication date: 2008-09-10
Also published as: WO2007068703A1; DE102005059740A1; WO2007068703A9

Abstract

The invention relates to a cosmetic preparation containing a) the compound (I) and b) one or more oily components with a surface tension of less than or equal to 37 mN/m (at 25 °C).

Description

Beiersdorf Aktiengesellschaft Hamburg

description

Cosmetic preparation with merocyanines in dissolved form

The present invention relates to a cosmetic preparation with merocyanines and oil components having a surface tension of less than or equal to 37 imN / m (at 25 ° C).

The trend away from sophisticated paleness to "healthy, sporty brown skin" has been unbroken for years, and people are exposing their skin to sunlight, as it causes pigmentation in the sense of melanin formation, which has ultraviolet radiation from sunlight In addition to the acute injury (sunburn), long-term damage such as an increased risk of developing skin cancer due to excessive exposure to light from the UVB range (wavelength: 280-320 nm) occurs UVB and UVA radiation (wavelength: 320-400 nm) also leads to a weakening of the elastic and collagen fibers of the connective tissue, which leads to numerous phototoxic and photoallergic reactions and leads to premature aging of the skin.

To protect the skin, therefore, a number of sunscreen filter substances have been developed which can be used in cosmetic preparations. These UVA and UVB filters are summarized in most industrialized countries in the form of positive lists such as Appendix 7 of the Cosmetics Regulation.

However, the large number of commercially available sunscreens must not disguise the fact that these prior art preparations contain a number of

Have disadvantages. So the expert knows the class of UV filters of merocyanines. These

Sunscreen filters are disclosed, for example, in WO 2004/006878. However, these sunscreen filters have the disadvantage that, according to the prior art, they have only low solubility or dispersibility in cosmetic formulations. A high UV light protection (especially UV-A light protection) has therefore not been achieved with these sunscreen filters. It was therefore the object of the present invention to eliminate the disadvantages of the prior art and a cosmetic preparation with a high content of merocyanines, in particular the compound a)

[Compound a)]. The merocyanine should be present in dissolved form.

Surprisingly, the objects are achieved by a cosmetic preparation containing a) the compound

such as

b) one or more oil components with a surface tension of less than or equal to 37 mN / m (at 25 ° C).

The objects are further achieved by a process for the preparation of a cosmetic preparation containing the compound

characterized in that this compound is dissolved in an oil phase of one or more oil components having a surface tension of less than or equal to 37 mN / m (at 25 ° C), combined with the other oil-soluble components (with the exception of the perfumes) and then mixed with the aqueous phase and homogenized.

Not least, the objects are achieved by the use of oil components with a surface tension of less than or equal to 37 imN / m (at 25 ° C) for the solution of merocyanines, in particular the compound

It is advantageous according to the invention if the cosmetic preparation, the process or the use is characterized in that the preparation contains the compound a) in a concentration of 0.1 to 20% by weight and preferably in a concentration of 0.5 to 10 % By weight, based on the total weight of the cosmetic preparation.

Embodiments of the present invention which are advantageous according to the invention are characterized in that the cosmetic preparation, the process or the use are characterized in that the oil components having a surface tension of less than or equal to 37 mN / m (at 25 ° C.) in the preparation in a total concentration from 1 to 50% by weight, and preferably in a total concentration of from 3 to 30% by weight, based on the total weight of the cosmetic preparation.

According to the invention, the oil components according to the invention are liquid at 20 ° C. and atmospheric pressure.

Embodiments of the present invention which are preferred according to the invention are characterized in that the cosmetic preparation, the process or the use as oil components having a surface tension of less than or equal to 37 mN / m (at 25 ° C.) comprises one or more compounds selected from the group of the compounds Ci ₂ -i ₅ -alkyl benzoate, butylene glycol dicaprylate / dicaprate, octyldodecanol, phenethyl benzoate, cocoglyceride, 2-ethylhexyl-2-cyano-3,3-diphenyl acrylate, homomenthyl salicylate, ethylhexyl salicylate, 4-methoxycinnamic acid isoamyl ester. It is advantageous according to the invention when the cosmetic preparation, process or use according to the invention is characterized in that the weight ratio of compound a) to the total amount of oil components having a surface tension of less than or equal to 37 imN / m (at 25 ° C.) of 1 : 40 to 40: 1 and preferably from 1:20 to 20: 1.

It is advantageous for the purposes of the present invention if the preparation according to the invention contains further UV light protection filters.

Embodiments of the present invention that are advantageous according to the invention are characterized in that the cosmetic preparation, the method or the use are characterized in that the preparation comprises one or more further UV filters selected from the group of the compounds phenylene-1,4-bis (2 benzimidazyl) -3,3'-5,5'-tetrasulfonic acid salts; 2-phenylbenzimidazole-5-sulfonic acid salts; 1,4-di (2-oxo-10-sulfo-3-bornylidenemethyl) benzene and its salts; 4- (2-oxo-3-bomylidenemethyl) benzene sulfonic acid salts; 2-methyl-5- (2-oxo-3-bornylidenemethyl) sulfonic acid salts; 2,2'-methylene-bis (6- (2H-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) -phenol); 2- (2H-Benzotriazol-2-yl) -4-methyl-6- [2-methyl-3- [1,3,3,3-tetramethyl-1 - [(trimethylsilyl) oxy] disiloxanyl] propyl] phenol ; 3- (4-

Methylbenzylidene) camphor; 3-benzylidenecamphor; ethylhexyl salicylate;

Terephthalidendicamphersulfonsäure; 4- (dimethylamino) benzoic acid (2-ethylhexyl) ester; 4- (dimethylamino) benzoic acid amyl ester; 4-Methoxybenzalmalon-säuredi (2-ethylhexyl) ester; 4-methoxycinnamic acid (2-ethylhexyl) ester; 4-methoxycinnamate; 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone; 2,2'-dihydroxy-4-methoxybenzophenone; Hexyl 2- (4'-diethylamino-2'-hydroxybenzoyl) benzoate 4- (tert-butyl) -4'-methoxydibenzoylmethane; homomenthyl; 2-ethylhexyl 2-hydroxybenzoate; 2-ethylhexyl-2-cyano-3,3-diphenylacrylate; dimethicodiethylbenzalmalonate; 3- (4- (2,2-bis

Ethoxycarbonylvinyl) phenoxy) propenyl) methoxysiloxane / dimethylsiloxane copolymer; 2,4-bis - {[4- (2-ethylhexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1, 3,5-triazine (INChBis

Ethylhexyloxyphenol methoxyphenyl triazine); Dioctylbutylamidotriazone (INCI: diethylhexylbutamidotriazone); 2,4-bis- [5-1 (dimethylpropyl) benzoxazol-2-yl- (4-phenyl) -imino] -6- (2-ethylhexyl) -imino-1,3,5-triazine having the (CAS No 288254-16-0); 4,4 ', 4 "- (1,3,5-triazine-2,4,6-triyltriimino) -tris-benzoic acid tris (2-ethylhexyl ester) (also: 2,4,6-tris [anilino] (p-carbo-2'-ethyl-1'-hexyloxy)] - 1, 3,5-triazine (INCI: ethylhexyl triazone); 2,4,6-tribiphenyl-4-yl-1,3,5-triazine Titanium dioxide, zinc oxide in a concentration of 0.01 to 40% by weight and preferably in a concentration of 1 to 20% by weight, based on the total weight of the preparation. O

According to the invention, the preparation according to the invention is free of p-methylbenzylidene camphor.

Advantageously in accordance with the invention, the preparation according to the invention is free from diethylhexyl naphthalate (Hallbrite TQ or Corapan TQ from Symrise).

The pigments (titanium dioxide, zinc oxide) can advantageously also be used in the form of commercially available oily or aqueous predispersions for the purposes of the present invention. Advantageously, dispersants and / or solubilizers can be added to these predispersions.

According to the invention, the pigments (titanium dioxide, zinc oxide) can advantageously be surface-treated ("coated"), in which case for example a hydrophilic, amphiphilic or hydrophobic character is to be formed or is to be retained.This surface treatment can consist in that the pigments are prepared by processes known per se be provided with a thin hydrophilic and / or hydrophobic inorganic and / or organic layer.The various surface coatings may also contain water for the purposes of the present invention.

Inorganic surface coatings for the purposes of the present invention may consist of aluminum oxide (Al ₂ O ₃ ), aluminum hydroxide Al (OH) ₃ or aluminum oxide hydrate (also: alumina, CAS No .: 1333-84-2), sodium hexametaphosphate (NaPO ₃ ) ₆ , Sodium metaphosphate (NaPOs) _n , silicon dioxide (SiO ₂ ) (also: silica, CAS No .: 7631-86-9), barium sulfate (BaSO ₄ ) or iron oxide (Fe ₂ O ₃ ). These inorganic surface coatings may be present alone, in combination and / or in combination with organic coating materials.

Organic surface coatings for the purposes of the present invention may consist of vegetable or animal aluminum stearate, vegetable or animal stearic acid, lauric acid, dimethylpolysiloxane (also: dimethicone), methylpolysiloxane (methicone), simethicone (a mixture of dimethylpolysiloxane with an average chain length of 200 to 350 Dimethylsiloxane units and silica gel) or alginic acid. These organic surface coatings may be present alone, in combination and / or in combination with inorganic coating materials. According to the invention, the preparation according to the invention is present in the form of an emulsion. The following two embodiments have proven to be preferred according to the invention:

On the one hand, it is advantageous according to the invention if the preparation is in the form of an O / W emulsion. In this case, it is particularly preferred according to the invention if the preparation comprises one or more O / W emulsifiers selected from the group of the compounds glyceryl stearate citrate, glyceryl stearate (self-emulsifying), stearic acid, stearate salts, polyglyceryl-3-methylglycose distearate, ceteareth-20, PEG-40 Stearate and sodium Cetearylsulfat contains.

According to the invention, these O / W emulsifiers according to the invention may advantageously be present in a concentration of from 0 to 10% by weight and preferably in a concentration of from 1 to 7% by weight, based on the total weight of the preparation.

On the other hand, it is advantageous according to the invention if the preparation is in the form of a W / O emulsion. In this case, it is particularly preferred according to the invention if the preparation contains one or more W / O emulsifiers selected from the group of the compounds polyglyceryl-2-dipolyhydroxystearate, PEG-30 dipolyhydroxystearate, cetyl dimethicone copolyol, polyglyceryl-3 diisostearate.

According to the invention, these W / O emulsifiers according to the invention may advantageously be present in a concentration of from 0.1 to 10% by weight and preferably in a concentration of from 0.2 to 7% by weight, based on the total weight of the preparation.

The preparations according to the invention may also advantageously contain self-tanning substances, for example dihydroxyactone and / or melanin derivatives in concentrations of 1% by weight up to 10% by weight, based on the total weight of the preparation.

Furthermore, the preparations according to the invention may also advantageously contain repellents for protection against mosquitoes, ticks and spiders and the like. Advantageous z. N, N-diethyl-3-methylbenzamide (trade name: Meta-delphene, "DEET"), dimethyl phthalate (trade name: Palatinol M, DMP), 1-piperidinecarboxylic acid 2- (2-hydroxyethyl) -1-methylpropyl ester, and especially 3- (Nn-butyl-N-acetyl-amino) -propionic acid ethyl ester (available commercially from Merck under the tradename Insekt Repellent® 3535.) The repellents can be used either singly or in combination. Moisturizers are substances or mixtures of substances which give cosmetic preparations the property, after application or spreading on the skin surface, to reduce the moisture release of the horny layer (also called transepidermal water joss (TEWL)) and / or hydration of the horny layer positively influence.

Advantageous humectants (moisturizers) for the purposes of the present invention are, for example, glycerol, lactic acid and / or lactates, in particular sodium lactate, butylene glycol, propylene glycol, biosaccharide gum-1, glycine soya, ethylhexyloxyglycerol, pyrrolidonecarboxylic acid and urea. Furthermore, it is particularly advantageous to use polymeric moisturizers from the group of water-soluble and / or water-swellable and / or water-gellable polysaccharides. Hyaluronic acid, chitosan and / or a fucose-rich polysaccharide, for example, which are filed in the Chemical Abstracts under the registry number 178463-23-5 and z. B. under the name Fucogel®1000 from the company SOLABIA S.A. is available. Moisturizers can also be used advantageously as anti-wrinkle active ingredients for protection against skin changes, as described, for example, in US Pat. B. occur during skin aging, can be used.

It is advantageous for the purposes of the present invention, when the inventive preparation one or more humectants in a total concentration of 0.1 to 20% by weight and preferably in a total concentration of 0.5 to 10% by weight, each based on the total weight of Preparation containing.

The cosmetic preparations according to the invention may also advantageously, although not necessarily, contain fillers which are e.g. B. further improve the sensory and cosmetic properties of the formulations and, for example, cause or enhance a velvety or silky feel on the skin. Advantageous fillers for the purposes of the present invention are starch and starch derivatives (such as, for example, tapioca starch, distarch phosphate, aluminum or sodium starch, octenylsuccinate and the like), pigments which have neither chiefly UV filter nor coloring action (such as, for example, US Pat. B. boron nitride etc.) and / or Aerosils ^® (CAS no. 7631-86-9).

The aqueous phase of the preparations according to the invention may advantageously contain customary cosmetic auxiliaries, such as, for example, alcohols, in particular those of low C number, preferably ethanol and / or isopropanol, diols or polyols of low C number and also their

Ether, preferably propylene glycol, glycerol, ethylene glycol, ethylene glycol monoethyl or -mo- nobutyl ether, propylene glycol monomethyl, monoethyl or monobutyl ether, diethylene glycol monomethyl or monoethyl ether and analogous products, polymers, foam stabilizers, electrolytes, self-tanning agents, and in particular one or more thickening agents, which may be advantageously selected from the group of silica, aluminum silicates, Polysaccharides or their derivatives, for. As hyaluronic acid, xanthan gum, hydroxypropylmethylcellulose, particularly advantageous from the group of polyacrylates, preferably a polyacrylate from the group of so-called carbopols, for example Carbopols types 980, 981, 1382, 2984, 5984, each individually or in combination. Further thickeners advantageous according to the invention are permuents TR 1, TR 2, Aristoflex AVC.

The preparations according to the invention can furthermore advantageously contain one or more substances from the following group of siloxane elastomers, for example in order to increase the water resistance and / or the sun protection factor of the products: (a) siloxane elastomers which contain the units R ₂ SiO and RSiOi ₅ and / or R ₃ SIOO ₅ and / or SiO ₂ contained, where the individual radicals R are each independently hydrogen, Ci _-24 alkyl (for example methyl, ethyl, propyl) or aryl (such as phenyl or tolyl), alkenyl (such as vinyl) and the weight ratio of the units R ₂ SiO to RSiOi _{5 is selected} from the range of 1: 1 to 30: 1; (b) Siloxane elastomers which are insoluble and swellable in silicone oil obtainable by the addition reaction of an organopolysiloxane (1) containing silicon-bonded hydrogen with an organopolysiloxane (2) containing unsaturated aliphatic groups, the proportions used being such be such that the amount of the hydrogen of the organopolysiloxane (1) or the unsaturated aliphatic groups of

Organopolysiloxane (2)

In the range of 1 to 20 mol%, if the organopolysiloxane is not cyclic and

In the range from 1 to 50 μmol%, when the organopolysiloxane is cyclic.

Advantageously in the context of the present invention, the siloxane elastomer (s) are in the form of spherical powders or in the form of gels.

Advantageously present in the form of spherical powders siloxane elastomers are those with the INCI name dimethicone / vinyl dimethicone crosspolymer, for example that available from DOW CORNING under the trade names DOW CORNING 9506 Powder available. It is particularly preferred if the siloxane elastomer is used in combination with oils of hydrocarbons of animal and / or vegetable origin, synthetic oils, synthetic esters, synthetic ethers or mixtures thereof.

Particularly advantageous preparations are also obtained when antioxidants are used as additives or active ingredients. According to the invention, the preparations advantageously contain one or more antioxidants. As favorable, but nevertheless optional to be used antioxidants all suitable or common for cosmetic applications antioxidants can be used.

Particularly advantageous for the purposes of the present invention, water-soluble antioxidants can be used, such as vitamins, eg. As ascorbic acid and its derivatives.

Further preferred antioxidants are vitamin E and its derivatives as well as vitamin A and its derivatives.

The amount of the antioxidants (one or more compounds) in the preparations is preferably 0.001 to 30 wt .-%, particularly preferably 0.05 to 20 wt .-%, in particular 0.1 to 10 wt .-%, based on the total weight the preparation.

If vitamin E and / or its derivatives represent the antioxidant (s), it is advantageous to choose their respective concentrations from the range from 0.001 to 10% by weight, based on the total weight of the formulation.

If vitamin A or vitamin A derivatives, or carotenes or derivatives thereof, are the antioxidant (s), it is advantageous if their respective concentrations are in the range from 0.001 to 10% by weight, based on the total weight of the formulation choose.

It is particularly advantageous if the cosmetic preparations according to the present invention contain cosmetic active ingredients, where preferred active ingredients are antioxidants which can protect the skin against oxidative stress.

Further advantageous active ingredients in the context of the present invention are natural active ingredients and / or derivatives thereof, such as. Alpha-lipoic acid, phytoene, D-biotin, coenzyme Q10, alpha-glucosylrutin, carnitine, carnosine, natural and / or synthetic isoflavonoids, creatine,

Creatinine, taurine and / or ß-alanine and 8-hexadecene-1, 16-dicarboxylic acid (dioic acid, CAS) Number 20701-68-2; provisional INCI name octadecenedioic acid) and / or licochalcone A.

Inventive formulations which z. B. known anti-wrinkle active ingredients such as flavone glycosides (especially α-glycosyl rutin), coenzyme Q10, vitamin E and / or derivatives and the like, are particularly advantageous for protection against aesthetically unattractive skin lesions, as described for. Skin aging (such as dryness, roughness, dryness wrinkles, itching, decreased refatting (eg, after washing), visible vascular dilation (telangiectasia, cuperosis), slackness and wrinkle and wrinkle formation, localized hypersensitivity). , Hypo and false pigmentation (eg, age spots), increased susceptibility to mechanical stress (eg, cracking), and the like). Furthermore, they are advantageously suitable against the appearance of dry or rough skin.

The cosmetic preparations according to the invention may contain cosmetic adjuvants, such as are commonly used in such preparations, for. Preservatives, preservatives, complexing agents, bactericides, perfumes, substances for preventing or increasing foaming, dyes, pigments which have a coloring effect, thickeners, moisturizing and / or moisturizing substances, fillers which improve the feel on the skin, fats, oils, Waxes or other common ingredients of a cosmetic or dermatological formulation such as alcohols, polyols, polymers, foam stabilizers, electrolyte, organic solvents or silicone derivatives.

In the method according to the invention, it is advantageous according to the invention to heat the oil phase, wherein an upper temperature limit of 85 ° C is advantageous.

The oil phase according to the invention can be combined with the aqueous phase according to the invention in the following ways:

^■ Mixing the heated oil phase with a heated aqueous phase, followed by cooling and subsequent addition of the perfume, possibly preservatives and other temperature-sensitive ingredients.

^■ Mixing the heated oil phase with an aqueous phase at room temperature, followed by cooling and subsequent addition of the perfume, possibly preservatives and other temperature-sensitive ingredients. ^■ Mixing the oil phase of the aqueous phase at room temperature and then adding the perfume, possibly preservatives and other temperature-sensitive ingredients. Advantageous in the context of the present invention are preparations for the care of the skin: they can serve the cosmetic sunscreen, as well as make-up product in decorative cosmetics.

According to their structure, cosmetic compositions according to the present invention, for example, be used as a skin protection cream, day or night cream, etc. It may be possible and advantageous to use the compositions of the invention as a basis for pharmaceutical formulations.

It is also advantageous in the context of the present invention to prepare cosmetic preparations whose main purpose is not the protection from sunlight, but which nevertheless contain a content of UV protective substances. So z. B. in day creams or makeup products usually incorporated UV-A or UV-B filter substances. Also UV protection substances, as well as antioxidants and, if desired, preservatives, an effective protection of the preparations themselves against spoilage. Also favorable are cosmetic preparations which are in the form of a sunscreen.

In particular, according to the invention, the use of the preparation according to the invention for protection against aging of the skin (in particular for protection against UV-related aging of the skin) and as a sunscreen agent.

According to the invention, the preparation according to the invention advantageously has a pH of 5 to 8. This can be adjusted by the conventional acids, bases and buffer systems.

For use, the cosmetic preparations according to the invention are applied to the skin and / or the hair in a sufficient amount in the manner customary for cosmetics.

The following examples are intended to illustrate the present invention without limiting it. Unless indicated otherwise, all amounts, proportions and percentages are based on the weight and the total amount or on the total weight of the preparations. Examples of O / W lotions

Examples of gels

Examples of sprays

Claims

claims

1. Cosmetic preparation containing a) the compound

and b) one or more oil components with a surface tension of less than or equal to 37 mN / m (at 25 "C).

2. A process for the preparation of a cosmetic preparation containing the compound

characterized in that this compound in an oil phase of one or more oil components having a surface tension of less than or equal to 37 mN / m

dissolved (at 25 ° C), combined with the other oil-soluble components (with the exception of the perfume) and then mixed with the aqueous phase and homogenized.

3. Use of oil components with a surface tension of less than or equal to 37 mN / m (at 25 ° C) for the solution of merocyanines, especially the compound

4. Cosmetic preparation, method or use according to one of the preceding claims, characterized in that the preparation contains the compound a) in a concentration of 0.1 to 20% by weight, based on the total weight of the cosmetic preparation.

5. Cosmetic preparation, process or use according to one of the preceding claims, characterized in that the oil components with a surface tension of less than or equal to 37 mN / m (at 25 ° C) in the preparation in a Total concentration of 1 to 50% by weight, based on the total weight of the cosmetic preparation contained in this.

6. Cosmetic preparation, method or use according to one of the preceding

Claims, characterized in that as oil components with a surface tension of less than or equal to 37 imN / m (at 25 ° C) one or more

Compounds selected from the group of compounds C _{_2-15} -alkyl, butylene glycol dicaprylate / dicaprate, octyldodecanol, phenethyl benzoate, cocoglyceride, 2-ethylhexyl-2-cyano-3,3-diphenylacrylate, are used homomenthyl salicylate, ethylhexyl salicylate, 4-methoxycinnamic acid isoamyl ester.

7. Cosmetic preparation, method or use according to one of the preceding

Claims, characterized in that the weight ratio of compound a) to the total amount of oil components having a surface tension of less than or equal to 37 mN / m (at 25 ° C) is from 1:40 to 40: 1.

8. Cosmetic preparation, method or use according to one of the preceding claims, characterized in that the preparation one or more further

UV filter selected from the group of the compounds phenylene-1,4-bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid salts; 2-phenylbenzimidazole-5-sulfonic acid salts; 1,4-di (2-oxo-10-sulfo-3-bomylidenemethyl) benzene and its salts; 4- (2-oxo-3-bomylidenemethyl) benzenesulfonic acid salts; 2-methyl-5- (2-oxo-3-bornylidenemethyl) sulfonic acid salts; 2,2'-methylenebis (6- (2H-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) -phenol); 2- (2H-benzotriazol-2-yl) -4-methyl-6- [2-methyl-3- [1,3,3,3-tetramethyl-1 - [(trimethylsilyl) oxy] disiloxanyl] propyl] -phenol; 3- (4-methylbenzylidene) camphor; 3-benzylidenecamphor; ethylhexyl salicylate; Terephthalidendicamphersulfonsäure; 2-ethylhexyl 4- (dimethylamino) benzoate; 4- (dimethylamino) benzoic acid amyl ester; Di (2-ethylhexyl) -4-methoxybenzalmalonate; 2-ethylhexyl 4-methoxycinnamate; Isoamyl 4-methoxycinnamate; 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone; 2,2'-dihydroxy-4-methoxybenzophenone; Hexyl 2- (4'-diethylamino-2'-hydroxybenzoyl) benzoate 4- (tert-butyl) -4'-methoxydibenzoylmethane; homomenthyl; 2-ethylhexyl 2-hydroxybenzoate; 2-ethylhexyl-2-cyano-3,3-diphenylacrylate; dimethicodiethylbenzalmalonate; 3- (4- (2,2-bis

Ethoxycarbonylvinyl) phenoxy) propenyl) methoxysiloxane / dimethylsiloxane copolymer; 2,4-Bis - {[4- (2-ethyl-hexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine) ; Dioctylbutylamidotriazone (INCI: diethylhexyl-butamidotriazone); 2,4-bis- [5-1 (dimethylpropyl) benzoxazol-2-yl- (4-phenyl) imino] -6- (2-ethylhexyl) -imino-1,3,5-triazine having the (CAS No 288254-16-0); 4,4 ', 4 "- (1, 3,5-

Triazine-2,4,6-triyltriimino) tris-benzoic acid tris (2-ethylhexyl ester) (also: 2,4,6-tris [anilino- (p-carbo-2'-ethyl-1'-hexyloxy) ] -1,3,5-triazine (INCI: ethylhexyl triazone); 2,4,6- Tribiphenyl-4-yl-1,3,5-triazine; titanium dioxide; Contains zinc oxide in a concentration of 0.01 to 30% by weight, based on the total weight of the preparation.

9. Cosmetic preparation, method or use according to one of the preceding claims, characterized in that the preparation is in the form of an O / W emulsion.

10. A cosmetic preparation, method or use according to claim 9, characterized in that the preparation one or more O / W emulsifiers selected from the group of compounds glyceryl stearate citrate, glyceryl stearate (self-emulsifying), stearic acid, stearate salts, polyglyceryl-3-methylglycosedistearat, ceteareth -20, PEG-40 stearate, sodium cetearyl sulfate.

1 1. A cosmetic preparation, method or use according to any one of the preceding claims, characterized in that the preparation is in the form of a W / O emulsion.

12. A cosmetic preparation, method or use according to claim 11, characterized in that the preparation one or more W / O emulsifiers selected from the group of compounds polyglyceryl-2-dipolyhydroxystearate, PEG-30 dipolyhydroxystearate, cetyl dimethicone copolyol, polyglyceryl-3 Contains diisostearate.