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EP1264561B1 - Matériau non-tissé et procédé de fabrication - Google Patents

Matériau non-tissé et procédé de fabrication Download PDF

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Publication number
EP1264561B1
EP1264561B1 EP02011653A EP02011653A EP1264561B1 EP 1264561 B1 EP1264561 B1 EP 1264561B1 EP 02011653 A EP02011653 A EP 02011653A EP 02011653 A EP02011653 A EP 02011653A EP 1264561 B1 EP1264561 B1 EP 1264561B1
Authority
EP
European Patent Office
Prior art keywords
layer
fibres
nonwoven fabric
fabric material
material according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP02011653A
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German (de)
English (en)
Other versions
EP1264561B9 (fr
EP1264561B2 (fr
EP1264561A1 (fr
Inventor
Rainer Dr. Mangold
Maximilian Pütz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Paul Hartmann AG
Original Assignee
Paul Hartmann AG
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Publication date
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Application filed by Paul Hartmann AG filed Critical Paul Hartmann AG
Publication of EP1264561A1 publication Critical patent/EP1264561A1/fr
Application granted granted Critical
Publication of EP1264561B1 publication Critical patent/EP1264561B1/fr
Publication of EP1264561B2 publication Critical patent/EP1264561B2/fr
Publication of EP1264561B9 publication Critical patent/EP1264561B9/fr
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    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
    • D04H1/5412—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres sheath-core
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425—Cellulose series
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/02—Cotton wool; Wadding
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4266—Natural fibres not provided for in group D04H1/425
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282—Addition polymers
    • D04H1/4291—Olefin series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326—Condensation or reaction polymers
    • D04H1/435—Polyesters
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4374—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece using different kinds of webs, e.g. by layering webs
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/492—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
    • D04H1/5418—Mixed fibres, e.g. at least two chemically different fibres or fibre blends
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/542—Adhesive fibres
    • D04H1/544—Olefin series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/542—Adhesive fibres
    • D04H1/55—Polyesters
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/559—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00—Other non-woven fabrics

Definitions

  • the invention relates to a composite nonwoven material for skin care and cleansing and for cosmetic purposes, comprising at least two layers of nonwoven fabric.
  • EP 0 826 811 A2 discloses a composite nonwoven material having a first soft-feeling surface and a second surface facing away from the first and rough-feeling the first.
  • the layer which forms the rough-feeling surface comprises at least partially thermoplastic fibers, preferably from the class of polyolefins.
  • the other layer has natural and / or synthetic fibers having a lower fiber strength than those of the other layer and forming the soft feeling surface.
  • the document teaches to connect the layers by water jet needling together. In a subsequent heat treatment, only the free ends of the thermoplastic fibers projecting from the rough-feeling surface layer are melted to enhance the impression of a rough surface.
  • EP 0 405 043 A1 discloses a composite nonwoven material for cosmetic use which has two outer layers forming the first and the second surface and an inner layer arranged between them.
  • the layers may be formed of cotton, viscose, synthetic fibers or a mixture thereof.
  • the cohesion of the layers is created by bonding the outer layers to their peripheral edge regions by means of suitable adhesives or by compression.
  • US-A-5,480,699 shows a bi-layer composite nonwoven material for cosmetic use having at least two layers. At least the outer layers are compacted to the same or different extent by embossing. As materials cotton, viscose, synthetic fibers or mixtures thereof are indicated. Also the possibility of producing embossed patterns on the Outer layers is mentioned.
  • FR-A-2,052,089 also discloses a cotton two-layer composite nonwoven fabric for cosmetic purposes, the layers of which are joined together by punctiform or linear embossing
  • EP-A-0 441 667 discloses an at least three-layered cotton pad, wherein an absorbent nonwoven fabric layer is provided on both sides of a thin barrier layer.
  • the present invention has for its object to provide a composite nonwoven material for skin care and cleaning and cosmetic purposes with at least two nonwoven fabric layers, which can be easily and inexpensively manufactured and has different trained surfaces, which can be preferably distinguished by tactile perception, wherein the nonwoven material should prove at least equivalent in terms of a pleasant feel on materials known to a user's skin.
  • the cellulosic fibers of the first layer which are preferably cotton fibers; especially cotton noils, form a first soft-feeling surface of the composite nonwoven material.
  • the second surface facing away from this first surface which is formed by the second nonwoven fabric layer, feels rougher. This rough feel is due to the melt-set thermoplastic fibers of the second layer and the embossing pattern on the surface of the second layer.
  • Nonwoven fabric layers during the manufacture of the composite nonwoven material, a very intimate connection of the fibers within the second layer but also a connection of the two layers with each other can be achieved.
  • the first layer may also have a thermoplastic form.
  • first layer has been subjected to a water-jet needling before it is joined to the second nonwoven layer in order to increase the cohesion of the fibers of this first layer, especially if few or no thermoplastic fibers are present in this first layer.
  • thermoplastic fibers are present in the first layer, these are preferably polyester fibers.
  • the thermoplastic fibers of the second layer are at least partially, but especially 100% polyester fibers.
  • PET fibers polyester fibers
  • the use of polyester fibers (PES) as the first thermoplastic fiber in the top layer proves to be particularly advantageous because of its lofty resiliency, as this can easily and effectively prevent it from being deposited on the opposite surface the second layer provided embossing pattern transmits to the first layer or pushed through to the first layer.
  • the melting point of the first thermoplastic fibers provided in the first layer is higher than the melting point of the second thermoplastic fibers, these first thermoplastic fibers themselves are not melted and the surface of the first layer remains soft and gives a soft, pleasant feel Feeling of what is attributable to the cellulosic fibers, which preferably form 90 to 98% by weight of the first layer.
  • the polyester bicomponent fibers of the second layer may comprise a low-melting component of polyethylene (PE) and a higher-melting component of polyester (PES).
  • the polyester bicomponent fibers have a polyester core (PES) and a polyethylene (PE) shell.
  • the fiber thickness of the bicomponent fibers is advantageously 1.0 to 6.5 dtex, in particular 1.2 to 4.0 dtex, and preferably 1.5 to 3.0 dtex.
  • the fiber length is advantageously selected from 10 to 80 mm, in particular from 20 to 70 mm and preferably from 40 to 50 mm.
  • the second layer in addition to the thermoplastic fibers and cellulosic fibers in particular from 50 to 95 wt .-%, and preferably comprises from 70 to 95 wt .-%.
  • the proportion of the thermoplastic fibers preferably formed from polyester bicomponent fibers is from 5 to 50% by weight, and preferably from 5 to 30% by weight, of the particular layer considered.
  • the weight per unit area of the first and the second layer is in each case 100 to 150 g / m 2 .
  • the first layer is water jet-needled before the layers are arranged one above the other and joined together by heating the layer arrangement.
  • the heating of the layer arrangement can be achieved in any way ansich, advantageously, a hot gas flow is used for this purpose.
  • the invention further relates to a two-layered cotton pad for skin care and cleansing and for cosmetic purposes, formed from a composite nonwoven fabric material according to the invention.
  • Figure 1 shows a schematic representation of a first embodiment of a composite nonwoven fabric material 2 according to the invention with a first Nonwoven fabric layer 4, which forms a first soft-feeling surface 6, and with a second nonwoven fabric layer 8, which forms a surface 10 which is rough relative to the first surface 6.
  • the first layer 4 consists of 100% cotton seedlings. It was water jet needled before being placed over and bonded to the second layer 8.
  • the second layer 8 comprises 87% by weight of cotton combing and 13% by weight of polyester bicomponent fibers.
  • the polyester (PES) bicomponent fibers comprise, as a low-melting component, co-polyesters having a melting point of 160 ° C and, as a higher-melting component, polyesters having a melting point of 260 ° C.
  • the length of the fibers is 51 mm.
  • the fiber thickness is 2.5 dtex.
  • the first surface provides a very soft feel and is suitable for applying lotions, creams or the like.
  • the second surface 10, which has an embossed pattern, is suitable for make-up removal.
  • FIG. 2 shows a second exemplary embodiment of a composite nonwoven material 12 having a first layer 14 consisting of 95% by weight of cotton seedlings and 5% PES bicomponent fibers of the type explained in connection with FIG. 1.
  • the second nonwoven fabric layer 16 is formed by 85 % By weight of cotton combing rings and 15% by weight of polyethylene / polyester (PE / PES) bicomponent fibers, where polyester (PE) is the low melting component having a melting point of 120 ° C and polyester (PES) is the core of the bicomponent fiber forms higher melting component having a melting point of 260 ° C.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Nonwoven Fabrics (AREA)
  • Laminated Bodies (AREA)

Claims (27)

  1. Matériau non tissé pour les soins et le nettoyage de la peau et pour des applications cosmétiques comportant au moins deux couches de non-tissé, la première couche de non-tissé comprenant des fibres cellulosiques et la deuxième couche de non-tissé comprenant des fibres thermoplastiques, et les au moins deux couches de non-tissé étant reliées entre elles par l'intermédiaire de liaisons obtenues par fusion entre les fibres de la première couche et les fibres de la deuxième couche, et la deuxième couche présentant, sur sa surface dont l'orientation est à l'opposé à la première couche, un modèle gaufré.
  2. Matériau non tissé selon la revendication 1, caractérisé en ce que la première couche de non-tissé comprend des premières fibres thermoplastiques et la deuxième couche de non-tissé comprend des deuxièmes fibres thermoplastiques, dont la température de fusion est inférieure à celle des premières fibres thermoplastiques prévues dans la première couche de non-tissé.
  3. Matériau non tissé selon la revendication 1 ou 2, caractérisé en ce que les fibres cellulosiques sont des fibres de coton.
  4. Matériau non tissé selon la revendication 1, 2 ou 3, caractérisé en ce que la première couche comprend 90 à 98 % en poids de fibres cellulosiques.
  5. Matériau non tissé selon l'une des revendications 1 à 4, caractérisé en ce que la première couche est aiguilletée par jet d'eau.
  6. Matériau non tissé selon l'une des revendications 2 à 5, caractérisé en ce que les fibres thermoplastiques prévues dans la première couche sont des fibres de polyester.
  7. Matériau non tissé selon l'une des revendications précédentes, caractérisé en ce que les fibres thermoplastiques de la deuxième couche sont au moins en partie des fibres de polyester.
  8. Matériau non tissé selon la revendication 7, caractérisé en ce que les fibres de polyester de la deuxième couche sont au moins en partie des fibres à deux composants.
  9. Matériau non tissé selon la revendication 8, caractérisé en ce que les fibres, à deux composants de polyester de la deuxième couche, présentent un composant en polyéthylène (PE) à point de fusion bas et un composant en polyester (PES) à point de fusion élevé.
  10. Matériau non tissé selon la revendication 9, caractérisé en ce que les fibres à deux composants de polyester de la deuxième couche présentent un noyau en polyester (PES) et une enveloppe à base de polyéthylène (PE).
  11. Matériau non tissé selon l'une des revendications 8 à 10, caractérisé en ce que les fibres à deux composants présentent une épaisseur de fibres comprise entre 1,0 et 6,5 dtex.
  12. Matériau non tissé selon la revendication 11, caractérisé en ce que les fibres à deux composants présentent une épaisseur de fibres comprise entre 1,2 et 4,0 dtex.
  13. Matériau non tissé selon la revendication 12, caractérisé en ce que les fibres à deux composants présentent une épaisseur de fibres comprise entre 1,5 et 3,0 dtex.
  14. Matériau non tissé selon l'une des revendications 8 à 13, caractérisé en ce que les fibres à deux composants présentent une longueur de fibres comprise entre 10 et 80 mm.
  15. Matériau non tissé selon la revendication 14, caractérisé en ce que les fibres à deux composants présentent une longueur de fibres comprise entre 20 et 70 mm.
  16. Matériau non tissé selon la revendication 15, caractérisé en ce que les fibres à deux composants présentent une longueur de fibres comprise entre 40 et 50 mm.
  17. Matériau non tissé selon l'une des revendications précédentes, caractérisé en ce que la deuxième couche comprend, en plus des fibres thermoplastiques, 50 à 95 % en poids de fibres cellulosiques.
  18. Matériau non tissé selon la revendication 17, caractérisé en ce que la deuxième couche comprend, en plus des fibres thermoplastiques, 70 à 95 % en poids de fibres cellulosiques.
  19. Matériau non tissé selon la revendication 17 ou 18, caractérisé en ce que les fibres cellulosiques sont des fibres de coton.
  20. Matériau non tissé selon l'une des revendications précédentes, caractérisé en ce que le poids par unité de surface des différentes couches est de 100 à 150 g/m2.
  21. Procédé de fabrication d'un matériau non tissé selon l'une des revendications précédentes comprenant les étapes consistant à :
    - former une première couche avec des fibres cellulosiques,
    - former une deuxième couche avec des fibres thermoplastiques,
    - agencer les couches l'une au-dessus de l'autre,
    - exercer une pression sur l'agencement de couches et chauffer l'agencement de couches, de telle sorte que les deuxièmes fibres thermoplastiques fondent au moins à leur surface et qu'il se forme ainsi des liaisons par fusion entre les fibres de la première couche et les fibres de la deuxième couche, lesquelles liaisons relient les couches entre elles, et qu'il se forme, en plus, des liaisons par fusion entre les fibres de la deuxième couche, lesquelles liaisons consolident la deuxième couche en elle-même.
  22. Procédé selon la revendication 21, caractérisé en ce que la première couche est aiguilletée par jet d'eau avant que les couches soient agencées l'une au-dessus de l'autre.
  23. Procédé selon la revendication 22, caractérisé en ce que la première couche aiguilletée par jet d'eau est séchée avant que les couches soient agencées l'une au-dessus de l'autre.
  24. Procédé selon l'une des revendications 21 à 23, caractérisé en ce que le chauffage de l'agencement des couches est obtenu au moyen d'un flux de gaz chaud.
  25. Procédé selon l'une des revendications 21 à 24, caractérisé en ce que la pression exercée sur l'agencement de couches et le chauffage de l'agencement de couches sont réalisés par calandrage.
  26. Procédé selon l'une des revendications 21 à 25, caractérisé en ce qu'il est produit, par calandrage, un modèle gaufré sur la surface de la deuxième couche orientée à l'opposé de la première couche.
  27. Tampon d'ouate à deux couches pour les soins et le nettoyage de la peau et pour applications cosmétiques, réalisé à partir d'un matériau non tissé selon l'une ou plusieurs des revendications 1 à 20.
EP02011653A 2001-06-06 2002-05-31 Matériau non-tissé et procédé de fabrication Expired - Lifetime EP1264561B9 (fr)

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DE10127514 2001-06-06
DE10127514A DE10127514A1 (de) 2001-06-06 2001-06-06 Verbundvliesstoffmaterial und Verfahren zu seiner Herstellung

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EP1264561B1 true EP1264561B1 (fr) 2006-06-21
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8906275B2 (en) 2012-05-29 2014-12-09 Nike, Inc. Textured elements incorporating non-woven textile materials and methods for manufacturing the textured elements
US9227363B2 (en) 2009-02-06 2016-01-05 Nike, Inc. Thermoplastic non-woven textile elements
CN106192200A (zh) * 2016-08-16 2016-12-07 南通纺织丝绸产业技术研究院 一种功能性保暖复合絮片的制备方法

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE20118890U1 (de) * 2001-11-20 2002-01-24 Rauscher Consumer Products Gmbh, Wien Flächiges Produkt
JP4118640B2 (ja) * 2002-09-17 2008-07-16 ユニ・チャーム株式会社 吸収性複合シートおよびこれを用いた吸収性物品
DE20305717U1 (de) * 2003-04-09 2004-08-19 W. Pelz Gmbh & Co. Wattepad
US7514071B2 (en) 2004-03-08 2009-04-07 L'oreal S.A. Single-use cosmetic article
FR2867067B1 (fr) * 2004-03-08 2007-09-07 Oreal Article cosmetique a usage unique
DE102005022577A1 (de) * 2005-05-09 2006-11-16 Paul Hartmann Ag Mehrfach auf sich selbst gefaltetes Watteband
DE102006020590A1 (de) * 2006-05-02 2007-11-08 Sandler Ag Tampon mit verbesserter Haftung zwischen Hülle & Kern
DE102007022368B4 (de) * 2007-05-07 2015-11-19 Thüringisches Institut für Textil- und Kunststoff-Forschung e.V. Mehrlagiges Faserverbundhalbzeug aus kurzen Verstärkungsfasern mit optimierter Drapierbarkeit
US9682512B2 (en) 2009-02-06 2017-06-20 Nike, Inc. Methods of joining textiles and other elements incorporating a thermoplastic polymer material
US8850719B2 (en) * 2009-02-06 2014-10-07 Nike, Inc. Layered thermoplastic non-woven textile elements
US20130255103A1 (en) 2012-04-03 2013-10-03 Nike, Inc. Apparel And Other Products Incorporating A Thermoplastic Polymer Material
CN111058188B (zh) * 2019-12-24 2022-02-15 福建恒安集团有限公司 天然纤维基无纺布

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2052089A5 (fr) * 1969-07-18 1971-04-09 Riethmann Eugene
US3837995A (en) * 1972-04-24 1974-09-24 Kimberly Clark Co Autogenously bonded composite web
GB1432978A (fr) † 1973-04-10 1976-04-22
US4075382A (en) † 1976-05-27 1978-02-21 The Procter & Gamble Company Disposable nonwoven surgical towel and method of making it
US4287251A (en) * 1978-06-16 1981-09-01 King Mary K Disposable absorbent nonwoven structure
US4196245A (en) † 1978-06-16 1980-04-01 Buckeye Cellulos Corporation Composite nonwoven fabric comprising adjacent microfine fibers in layers
NZ201073A (en) † 1981-07-10 1985-12-13 Chicopee An absorbent thermal bonded nonwoven fabric and its use in a catamenial device
CH672249A5 (en) * 1986-09-08 1989-11-15 Flawa Schweiz Verband Wattefab Liq. or paste handling plate - is in several layers, with one layer
EP0405043B1 (fr) * 1989-02-22 1994-05-25 Flawa Schweizer Verbandstoff- und Wattefabriken AG Tampon pour appliquer et/ou ôter des substances liquides ou semi-fluides
FR2656780B1 (fr) * 1990-01-10 1993-08-06 Coativy Rene Dispositif pour demaquillage comportant une couche d'arret.
CA2078678A1 (fr) * 1990-03-21 1991-09-22 David D. Newkirk Non-tisse pour couvre-couches et methode de fabrication
AU679189B2 (en) † 1992-08-27 1997-06-26 Procter & Gamble Company, The Tissue paper treated with nonionic softeners that are biodegradable
DE4305271C2 (de) † 1993-02-20 2000-06-08 Corovin Gmbh Verbundvlies sowie Verfahren zur Herstellung eines Verbundvlieses
FR2752248B1 (fr) * 1996-08-09 1998-09-25 Lystil Sa Materiau complexe non tisse absorbant comportant une face souple et une face rugueuse, et procede pour son obtention
JPH10113222A (ja) * 1996-10-15 1998-05-06 Toray Ind Inc 化粧綿
ES2216184T3 (es) * 1996-12-06 2004-10-16 Weyerhaeuser Company Material compuesto estratificado unitario.
JP3400702B2 (ja) † 1997-12-26 2003-04-28 ユニ・チャーム株式会社 不織布の製造方法

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9227363B2 (en) 2009-02-06 2016-01-05 Nike, Inc. Thermoplastic non-woven textile elements
US8906275B2 (en) 2012-05-29 2014-12-09 Nike, Inc. Textured elements incorporating non-woven textile materials and methods for manufacturing the textured elements
CN106192200A (zh) * 2016-08-16 2016-12-07 南通纺织丝绸产业技术研究院 一种功能性保暖复合絮片的制备方法
CN106192200B (zh) * 2016-08-16 2018-07-13 南通纺织丝绸产业技术研究院 一种功能性保暖复合絮片的制备方法

Also Published As

Publication number Publication date
DE50207253D1 (de) 2006-08-03
DE10127514A1 (de) 2003-01-30
EP1264561B9 (fr) 2009-11-18
EP1264561B2 (fr) 2009-08-19
EP1264561A1 (fr) 2002-12-11
ATE330505T1 (de) 2006-07-15

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