EP0305426A1 - Installation de coulee de metal liquide et procede pour sa mise en oeuvre. - Google Patents
Installation de coulee de metal liquide et procede pour sa mise en oeuvre.Info
- Publication number
- EP0305426A1 EP0305426A1 EP88901871A EP88901871A EP0305426A1 EP 0305426 A1 EP0305426 A1 EP 0305426A1 EP 88901871 A EP88901871 A EP 88901871A EP 88901871 A EP88901871 A EP 88901871A EP 0305426 A1 EP0305426 A1 EP 0305426A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- orifice
- pouring orifice
- liquid metal
- pouring
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910001338 liquidmetal Inorganic materials 0.000 title claims abstract description 48
- 238000009434 installation Methods 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims description 9
- 239000011810 insulating material Substances 0.000 claims abstract description 14
- 238000005058 metal casting Methods 0.000 claims abstract description 6
- 229910052751 metal Inorganic materials 0.000 claims description 30
- 239000002184 metal Substances 0.000 claims description 30
- 239000007789 gas Substances 0.000 claims description 21
- 238000005266 casting Methods 0.000 claims description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- 238000005245 sintering Methods 0.000 claims description 11
- 238000007789 sealing Methods 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 230000001590 oxidative effect Effects 0.000 claims description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 230000005587 bubbling Effects 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 230000004927 fusion Effects 0.000 claims description 2
- 239000010954 inorganic particle Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 description 22
- 229910000831 Steel Inorganic materials 0.000 description 12
- 239000010959 steel Substances 0.000 description 12
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000002893 slag Substances 0.000 description 5
- 241000233948 Typha Species 0.000 description 4
- 238000009749 continuous casting Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 3
- 239000011819 refractory material Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000009865 steel metallurgy Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/14—Closures
- B22D41/16—Closures stopper-rod type, i.e. a stopper-rod being positioned downwardly through the vessel and the metal therein, for selective registry with the pouring opening
- B22D41/18—Stopper-rods therefor
- B22D41/186—Stopper-rods therefor with means for injecting a fluid into the melt
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D3/00—Charging; Discharging; Manipulation of charge
- F27D3/15—Tapping equipment; Equipment for removing or retaining slag
- F27D3/1509—Tapping equipment
Definitions
- the present invention relates to a liquid metal casting installation comprising a metallurgical container intended to contain liquid metal, provided with a pouring orifice and comprising under this orifice a main device for closing and opening said orifice.
- the invention also relates to the method for implementing this installation.
- any metallurgical container such as a ladle or a continuous pouring distributor, mainly with slab or bloom, comprises a device for closing the pouring orifice to allow it to be closed, before and during the start of the pouring of the liquid metal into this container, then the release of this orifice to allow the pouring of the liquid metal into a second metallurgical container, for example in a continuous casting mold.
- Such a device must also allow partial or total closure of this orifice if it is necessary to limit the flow rate or interrupt the pouring of the liquid metal.
- the most well-known sealing devices are the stopper rods fitted with a conventional refractory lining requiring heating before the metal is poured to avoid any risk of solidification of the metal in contact with its surface. These cattails are heavier and difficult to handle.
- the closure devices currently used are the drawer nozzles. These give full satisfaction with regard to the sealing function before and during casting and at the end of it. On the other hand, it may happen that, despite the care taken in preparing the pouring container before a pouring, a plug of various debris r of slag and / or solidified metal prevents the pouring of the metal in the pouring orifice. liquid or severely limiting it.
- the solution generally consists in trying to burn with oxygen the incandescent magma forming the plug which obstructs the pouring orifice.
- a metal tube is introduced into this orifice through the lower part of the metallurgical vessel, into which a jet of oxygen is supplied.
- a flame is formed on contact with the magma, the heat of which melts the latter.
- This operation is always very delicate. In fact, it often happens that by melting the magma, the pouring orifice and / or the drawer device are damaged. In addition, this operation is dangerous for the personnel who perform it.
- the object of the present invention is to remedy the aforementioned drawbacks by providing a molten metal casting apparatus of simple and effective aforementioned type, for preheating, closing and unplugging d r a discharge opening of the metallurgical vessel, that allows in particular, for a low cost, the rapid and effective removal of a plug obstructing the pouring orifice.
- the installation is characterized in that it also comprises an auxiliary device for pre-heating, sealing and unblocking the pouring orifice, placed above said orifice, and comprising an elongated element intended to be partially immersed in the liquid metal and made of a refractory and / or refractory insulating material which can be sintered on contact liquid metal, means for holding the elongated element on the pouring orifice so as to close it before and during the start of the pouring of the molten metal into the container and for lifting this element above the orifice casting, this element comprising at least one longitudinal duct opening at right and / or in the vicinity of the pouring orifice and which is connected to at least one source of pressurized gas allowing the preheating and / or unclogging of said orifice.
- an auxiliary device for pre-heating, sealing and unblocking the pouring orifice placed above said orifice, and comprising an elongated element intended to be partially immersed in the liquid metal and made of a
- This device which is only used as an auxiliary for preheating and / or closing the pouring orifice at the start of casting, can be simple and therefore light and economical.
- This device by its mere presence on the pouring orifice before the arrival of the liquid metal, also considerably limits the risk of debris of any kind falling into the pouring orifice to obstruct it.
- this device which is placed on the pouring orifice and then lifted slightly above it, allows, in the event of the presence of a possible plug, to send directly to this plug at very short distance, therefore with great precision, an oxidizing gas, such as for example oxygen or any other gas enriched with oxygen, oxidizing and / or reducing, to melt this plug.
- the elongated element is preferably made of a material capable of sintering on contact with the liquid metal allows the latter to maintain its mechanical cohesion throughout the duration of its stay in this liquid metal.
- the refractory insulating material, sinterable in contact with the liquid metal is composed of refractory inorganic particles, such as silica and / or alumina and / or magnesia, and optionally organic and / or refractory fibers, agglomerated using an organic and / or inorganic binder, capable of sintering on contact with the liquid metal.
- this material Since this material has a density and a thermal conductivity significantly lower than that of conventional refractories, this material does not require any preheating and does not risk causing solidification of the liquid metal in contact with it.
- this material remains slightly malleable after sintering, which is favorable for good sealing of the pouring orifice.
- the duct is constituted at least by a metal tube disposed longitudinally inside the elongated element and opening at the end of this element located above the orifice of pouring, the end of this tube opposite the pouring orifice being connected at least by a pipe to a source of oxygen and / or similar oxidizing gas and / or reducing gas under pressure, bubbling gas, to a powder feed mechanism, grains, metallic wire.
- a metal tube arranged longitudinally inside the elongated element allows a very simple construction of this element to which the tube serves as a frame.
- the jet of oxygen or enriched gas emerging at the end of the tube and of the elongated element situated above the pouring orifice forms a flame in contact with the liquid metal and attacks at very low distance and therefore with great precision the magma obstructing the pouring orifice without damaging the walls of this orifice or the elements of the slide or rotary shutter.
- the elongated element is preferably made being both refractory and insulating, the thickness of this material around the metal tube can be reduced and this elongated element can thus be very light compared to a traditional distaff.
- the method for implementing an installation comprises the following steps: a) the elongated element of the auxiliary device is placed on the pouring orifice, or main preheating, sealing and uncorking, b) the container is started to fill with liquid metal, c) when the liquid metal reaches the desired level in the container, the main closure device is opened, then d) the elongated element of the auxiliary device is slightly raised above the pouring orifice, e) if the liquid metal does not flow normally through the pouring orifice, control the arrival of the oxidizing gas in the conduit of the element to eliminate by fusion the plug formed in the pouring orifice, f) as soon as the metal flows normally through the pouring orifice, the elongated element is completely raised.
- FIG. 1 is a cross-sectional view of an installation according to an embodiment of one invention
- FIG. 2 is a sectional view similar to Figure 1, the elongated element of the installation according to the invention being raised above the pouring orifice, and being different from that shown in Figure 1;
- FIG. 3 is an axial sectional view longitudinal of the elongated element of an installation according to the invention.
- a metallurgical container constituted by a distributor 1 of a continuous casting installation.
- This distributor 1 containing liquid metal 2 such as molten steel comprises an outer steel casing 3, internally lined with a permanent refractory lining 4 which is itself preferably protected by a refractory insulating coating 5.
- the casting distributor 1 comprises a pouring orifice 6 formed in a pouring nozzle 7 usually made of refractory material.
- a main shutter device 8 with drawer 9 Under the pouring orifice 6 of the distributor 1 is installed a main shutter device 8 with drawer 9.
- the main shutter device with drawer 8 may include a tube 10 allowing the blowing of argon in the nozzle 7 which in this case is made of porous refractory material.
- a pouring tube 11 Under the drawer closure device 8 is mounted a pouring tube 11.
- the pouring orifice 6 of the distributor 1 is equipped with an auxiliary preheating and / or sealing and uncapping device 12, which mainly comprises an elongated element 13 disposed substantially vertically on the casting orifice 6 so as to 1 '' seal.
- Element 13 is axially traversed by a tube 23 which serves as a frame.
- the elongate element 13 can be lifted above the pouring orifice 6 by any known system, manual or remote-controlled.
- this control device comprises a lever 14 articulated at 16 on a stand 17 carried by the casing 3 of the distributor 1.
- the lever 14 is articulated on the one hand to a collar 15 which encloses the upper part of the tube 23 above the element 13 and on the other hand to a link 18 guided by a sheath 20.
- the link 18 is controlled in translation by a lever, operating 21 articulated at 22 on the envelope
- this element has inside its metallic tube 23, generally made of ordinary steel, for example a standardized tube of nominal diameter 1 "(25,4
- the tube 23 is externally threaded at its lower end and screwed into a threaded sleeve 24.
- the end of the sleeve 24 opposite the tube 23 is for example welded to a washer 25 provided at its center with a circular orifice 26 in which is welded along the axis of the tube 23 a tubular element 27 of diameter smaller than that of the tube 23.
- a layer of insulating material covering the surface of the bath of liquid steel.
- the elongated element 13 is composed of several annular parts 13a, 13b, 13c fitted one on top of the other around the metal tube 23. These parts 13a, 13b, 13c can be joined to each other for example by means of a refractory adhesive. It is possible to interpose between the annular parts 13 ⁇ one or more parts 13e of a larger diameter, in particular in the region of the slag and / or of the layer of insulating material 35 covering the surface of the bath of liquid steel (FIG. 1).
- the part 13a adjacent to the pouring orifice 6 has a spherical surface 13d determined to be able to be applied in a sealed manner on the frustoconical edge 31a of the seat brick 31 and on the edge of the nozzle 7 housed in that -this.
- the end 28 of the tube 23 opposite the pouring orifice 6 is connected to a source of oxygen 30 under pressure by means of a flexible tube 29.
- the elongate element 13 can be produced in several ways.
- the tube 23 and the sleeve 24, to which the washer 25 and the section of tube 27 have been previously assembled, are assembled, to which a porous plug allowing the gases to pass is added, and the insulating coating is produced in a single operation.
- the material 34 constituting the different parts 13a, 13b, 13c of the element 13 is a refractory and / or refractory thermal insulating material composed of particles refractory inorganics, such as silica and / or alumina, and / or magnesia, ... and optionally organic and / or refractory fibers, the whole being agglomerated using organic binders and / or inorganic, liable to sinter on contact with liquid metal 2.
- composition of the refractory thermal insulating material and the particle size of its constituents are adjusted so that sintering occurs, in the case of steel metallurgy, between 800 ° C and 1500 ° C.
- addition of a mineral binder frees the composition from the sintering constraints.
- the specific mass of this material can vary between 0.5 and 2.9 kg / dm 3 depending on the composition and the particle size of its constituents.
- the outer walls of the tube 23, of the sleeve 24, of the washer 25 and of the tube section 27 can be coated beforehand with an adhesive facilitating the adhesion of the material 34 to the metal.
- Another way of making the element 23 consists in separately preparing the end part 13a having substantially the shape of a hemisphere extended by a cylinder, then screwing the tube 23 into the sleeve 24 and then threading onto the tube 23 the various prefabricated tubular parts 13b, 13c.
- the lower part 13a intended to close the pouring orifice 6, which supports the pressure hydrostatic of the liquid metal and rests on the periphery of the pouring orifice 6 has the maximum thickness of refractory and / or refractory insulating material 34. It has for example an outside diameter of 132 mm and a total height of 100 mm which includes the height of one frustoconical recess allowing the nesting, either for example 15 mm and the height of the threaded sleeve 24, or for example 52 mm, the upper part of the sleeve flush with the level of the refractory and / or refractory insulating material.
- the upper tubular parts 13b, 13c which support less effort, can have a thinner thickness of material 34 and have for example an outside diameter of around 75 mm for an inside diameter of the order of 35 to 40 mm, and a height 150 mm unit.
- the parts 13a, 13b, 13c can be produced for example by press or by accelerated filtration under pressure or by suction. They can be refractory and / or insulating refractory. They can have a larger diameter in the slag area than the elements 13b and 13c.
- the container is a continuous casting distributor.
- the distributor 1 comprising an auxiliary device 12 and a main device 8
- the elongated element 13 is fixed to the arm 14.
- the element 13 rests by its own weight on the bottom of the distributor 1 and care is taken to center the lower spherical part 13a on the pouring orifice 6.
- the element 13 being in place, the device is placed at drawer 8 in closed position. The mere presence of the element 13 on the pouring orifice 6 will therefore prevent the introduction of undesirable foreign matter into this orifice.
- the refractory insulating material 34 surrounding the element 13 begins to sinter.
- This sintering continues inside the material, as the temperature inside the parts 13a, 13b, 13c increases. Thanks to this sintering, the cohesion of the material is maintained, despite the decomposition of the binder.
- the liquid metal does not wet the surface of the material of the element 13, so that the behavior of this element is not likely to be disturbed by undesirable metal adhesions.
- the material of the element 13 being insulating, there is no solidification of metal against its surface.
- the material 34 of the element 13 remains slightly malleable even after sintering, which further improves the sealing conditions of the pouring orifice 6.
- the surface of the bath of liquid steel is covered with an insulating material 35 then the main valve closure device 8 is opened then, using the levers 21 and 14, the element 13 is slightly raised above the pouring orifice 6, as shown in FIG. 2. If the metal flows normally, element 13 can be lifted to its upper release position and kept there by any blocking device (not shown).
- the element 13 is lowered again on this orifice 6 and oxygen is blown through the tube 23 and the tube section 26 which forms a nozzle. Upon contact with the liquid metal, a flame 32 is immediately formed which will melt and disappear any magma 33 of metal and foreign matter obstructing the pouring orifice 6.
- the element 13 is raised to its upper release position and held there. Then it is possible, when a blowing of argon is planned, to open the arrival of argon through the pipe 10 in the nozzle 7 to expel from the vicinity of the orifice 6 any impurities.
- the element 13 is dismantled and replaced by a new element.
- the invention is not limited to the metallurgy of steel and can be used for all liquid metals, in particular aluminum, copper and their alloys, provided that the composition and the particle size of the materials constituting the material of the element 13, the parts 13a or 13b or 13c or 13e of which are refractory insulators, are adapted to allow sintering of this material in contact with the liquid metal.
- This refractory insulating material can at will be acidic, basic or neutral depending on the composition chosen according to the intended use.
- the total charge of the refractory component (s) of this material can reach 99.5%, the percentage of fibers being able to reach 20%.
- the refractory insulating parts not subjected to sintering contain an inorganic binder.
- the installation according to the invention can be adapted for example to a ladle and / or to each pouring orifice of a distributor, the length of the element 13 being adapted to the conditions of use.
- the drawer nozzle can be replaced by a barrel nozzle.
- the tube 23, the sleeve 24, the washer 25, the section of the tube 27 can be replaced by equivalent elements assembled by any known means.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Continuous Casting (AREA)
- Furnace Charging Or Discharging (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT88901871T ATE61532T1 (de) | 1987-02-20 | 1988-02-19 | Verfahren und vorrichtung zum giessen von fluessigem metall. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8702225A FR2611151B1 (fr) | 1987-02-20 | 1987-02-20 | Dispositif de prechauffage et/ou d'obturation et de debouchage d'un orifice de coulee et procede pour sa mise en oeuvre |
FR8702225 | 1987-02-20 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0305426A1 true EP0305426A1 (fr) | 1989-03-08 |
EP0305426B1 EP0305426B1 (fr) | 1991-03-13 |
Family
ID=9348133
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88901871A Expired - Lifetime EP0305426B1 (fr) | 1987-02-20 | 1988-02-19 | Installation de coulee de metal liquide et procede pour sa mise en oeuvre |
Country Status (5)
Country | Link |
---|---|
US (1) | US4909421A (fr) |
EP (1) | EP0305426B1 (fr) |
CA (1) | CA1329977C (fr) |
FR (1) | FR2611151B1 (fr) |
WO (1) | WO1988006068A1 (fr) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE1004282A6 (fr) * | 1989-06-27 | 1992-10-27 | Centre Rech Metallurgique | Dispositif de prechauffage d'une busette de coulee d'un metal en fusion et installation de coulee d'un metal equipee de ce dispositif. |
US5203909A (en) * | 1991-10-15 | 1993-04-20 | Ltv Steel Company, Inc. | Method and apparatus for slag free casting |
GB9316270D0 (en) * | 1993-08-05 | 1993-09-22 | Foseco Int | Improvements in molten metal handling vessels |
DE19543058C2 (de) * | 1995-11-10 | 2001-01-04 | Sms Demag Ag | Verfahren und Vorrichtung zum Verschließen einer Abstichöffnung |
DE10111273A1 (de) * | 2001-03-09 | 2002-09-12 | Sms Demag Ag | Verfahren und Einrichtung zum Auswechseln einer Schieberbaugruppe an einem metallurgischen Gefäß, insbesondere an einem Elektroschmelzofen |
GB2407287A (en) * | 2003-10-24 | 2005-04-27 | Pyrotek Engineering Materials | Stopper rod made from reinforced ceramic |
JP5805030B2 (ja) * | 2012-08-09 | 2015-11-04 | 株式会社神戸製鋼所 | ストッパ |
CN103008636B (zh) * | 2013-01-21 | 2015-01-07 | 河北联合大学 | 插枪式塞棒装置以及用其在水口处吸附夹杂物的方法 |
CN106521282B (zh) * | 2016-11-16 | 2018-05-01 | 攀钢集团攀枝花钢铁研究院有限公司 | 阶梯环塞棒 |
CN112449546B (zh) * | 2019-08-27 | 2024-07-19 | 华硕电脑股份有限公司 | 液态金属散热膏涂布方法及散热模块 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3200457A (en) * | 1964-03-09 | 1965-08-17 | United States Steel Corp | Method of regulating the discharge of molten metal from ladles |
LU56046A1 (fr) * | 1968-05-09 | 1970-01-14 | ||
EP0084416B1 (fr) * | 1982-01-18 | 1986-09-03 | Stephen David Mills | Support de quenouille pour poches de coulée |
JPS6036386A (ja) * | 1983-08-05 | 1985-02-25 | 東芝セラミツクス株式会社 | スラデイングノズル用充填材 |
JPS6082256A (ja) * | 1983-10-07 | 1985-05-10 | Toshiba Ceramics Co Ltd | 溶融金属用ストツパ− |
US4791978A (en) * | 1987-11-25 | 1988-12-20 | Vesuvius Crucible Company | Gas permeable stopper rod |
-
1987
- 1987-02-20 FR FR8702225A patent/FR2611151B1/fr not_active Expired - Fee Related
-
1988
- 1988-02-19 EP EP88901871A patent/EP0305426B1/fr not_active Expired - Lifetime
- 1988-02-19 US US07/276,505 patent/US4909421A/en not_active Expired - Fee Related
- 1988-02-19 CA CA000559291A patent/CA1329977C/fr not_active Expired - Fee Related
- 1988-02-19 WO PCT/FR1988/000095 patent/WO1988006068A1/fr active IP Right Grant
Non-Patent Citations (1)
Title |
---|
See references of WO8806068A1 * |
Also Published As
Publication number | Publication date |
---|---|
FR2611151A1 (fr) | 1988-08-26 |
FR2611151B1 (fr) | 1991-06-14 |
CA1329977C (fr) | 1994-06-07 |
US4909421A (en) | 1990-03-20 |
EP0305426B1 (fr) | 1991-03-13 |
WO1988006068A1 (fr) | 1988-08-25 |
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