DE3229558A1 - Impregnating and encapsulating composition for electrical components - Google Patents
Impregnating and encapsulating composition for electrical componentsInfo
- Publication number
- DE3229558A1 DE3229558A1 DE19823229558 DE3229558A DE3229558A1 DE 3229558 A1 DE3229558 A1 DE 3229558A1 DE 19823229558 DE19823229558 DE 19823229558 DE 3229558 A DE3229558 A DE 3229558A DE 3229558 A1 DE3229558 A1 DE 3229558A1
- Authority
- DE
- Germany
- Prior art keywords
- filler
- composition
- accelerator
- resin
- electrical components
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/40—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/22—Di-epoxy compounds
- C08G59/226—Mixtures of di-epoxy compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
- C08G59/38—Epoxy compounds containing three or more epoxy groups together with di-epoxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
- C08G59/686—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
Abstract
Description
Imorägniervergußmasse für elektrische BauteileImpregnation casting compound for electrical components
Stand der Technik Die Erfindung geht aus von einer Vergußmasse nach der Gattung des Hauptanspruchs. Käufliche derartige Vergußmassen, mit denen elektrische Bauteile umgossen werden, um sie vor mechanischen Einwirkungen zu schützen, und die aus einem härtbaren Harz bestehen, zeigen bei einer Aushärtung zwei Stunden bei 80 OC und anschließend zwei Stunden bei 120 0 einen verhältnismaßig niedrigen Glasübergangspunkt von 30 OC, verhältnismäßig hohe lineare thermische Ausdehnungskoeffiienten zwischen 44 und 129.10-6 1/°C bei 50 bzw.PRIOR ART The invention is based on a casting compound the genre of the main claim. Such potting compounds for sale, with which electrical Components are cast around to protect them from mechanical effects, and made of a curable resin show two hours when cured at 80.degree. C. and then for two hours at 120.degree. a relatively low one Glass transition point of 30 OC, relatively high linear thermal expansion coefficient between 44 and 129.10-6 1 / ° C at 50 resp.
oberhalb 90 0 sowie einen Volumenschwund, der mit 2,2 % auch verhältnismäßig groß ist. Schließlich weisen diese rarze mit mehr als 10 000 mPas bei 25 °C eine verhältnismäßig hohe Viskosität auf, was zu Vergußmassenführt, mit der einwandfreie Imprägnierungen, beispielsweise von elektrischen Spulen, nur schwer möglich sind. Auch ist bei diesen käuflichen Vergußmassen die Temperaturwechselbeständigkeit, beispielsweise für eine Anwendung bei Hochspannungs-Zündspulen im Kraftfahrzeug, nicht ausreichend, was mit dem niedrigen Glasübergangspunkt, wie er oben genannt ist, zusammenhangt.above 90 0 as well as a decrease in volume, which at 2.2% is also proportionate is great. After all, these rare substances have a temperature of more than 10,000 mPas at 25 ° C relatively high viscosity, which leads to casting compounds, with the perfect Impregnation, for example of electrical coils, is difficult. The thermal shock resistance of these commercially available casting compounds is also important, for example for use in high-voltage ignition coils in motor vehicles, not sufficient, what with the low glass transition point, as mentioned above is related.
Vorteile der Erfindung Die erfindungsgemäße Imprägniervergußmasse mit den kennzeichnenden Merkmalen des Haupt anspruchs hat demgegenüber den Vorteil, daß sie eine niedrige Viskosität, einen kleinen thermischen Ausdehnungskoeffizienten, einen hohen Glasübergangspunkt sowie eine hohe Temperaturwechselbestandigkeit und Wärmebeständigkeit aufweist; so sind Hochspannungs-Zündspulen, die mit dieser erfindungsgemäßen ergußmasse impragniert und vergossen sind, zwischen mindestens -40 °C und mindestens 120 °C temperaturwechselbeständig und elektrisch funktionsfähig bei Temperaturen in der Wicklung von mehr als 100 °C. Durch die geringe Viskositat wird es ermöglicht, derartige elektrische Bauteile in eine: Arbeitsgang zu imprägnieren und zu umhüllen.Advantages of the Invention The impregnation potting compound according to the invention with the characteristic features of the main claim has the advantage that they have a low viscosity, a small coefficient of thermal expansion, a high glass transition point as well as a high thermal shock resistance and Has heat resistance; so are high-voltage ignition coils that work with this invention Casting compound is impregnated and potted, between at least -40 ° C and at least 120 ° C resistant to temperature changes and electrically functional at temperatures in the winding of more than 100 ° C. The low viscosity makes it possible such electrical components in one: to impregnate and encase.
Durch die in den Unteransprüchen aufgeführten Maßnahmen sind vorteilhafte Weiterbildungen und Verbesserungen der im Hauptanspruch angegebenen Imprägniervergußmasse möglich.The measures listed in the subclaims are advantageous Developments and improvements of the impregnation casting compound specified in the main claim possible.
Besonders vorteilhaft ist es, wenn der Füllstoff in einer Menge von mehr als 53 Gew.-%, bezogen auf die Gesamtmasse, in der Vergußmasse enthalten ist, da die oben angegebenen Vorteile dann besonders zutage treten.It when the filler is particularly advantageous in an amount of more than 53% by weight, based on the total mass, is contained in the potting compound, because the advantages indicated above then become particularly apparent.
Beschreibung eines Ausführungsbeispiels Verwendet wird ein Epoxidharz auf Basis Bisphenol A und einem Cycloolefin als Cycloaliphat im Verhältnis 70:30 Gev.-Teilen, das bei 25 C eine Viskosität kleiner als 5000 mPas hat. Dazu wird ein modifiziertes Dicarbonsäureanhydrid7 z. B. Phtalsäureanhydrid als Härter sowie ein Imidazol, z. B. Pyrazol als Beschleuniger und Kreide als Füllstoff zugegeben, wobei Harz, Härter und Beschleuniger im Verhältnis 100:100:0,5 Gew.-Teile eingesetzt erden und der Füllstoff in einer Menge von 55 Gew.-%, bezogen suf die Gesamtmischung, zugegeben wird. Das Ganze wird gut gemischt und stellt dann eine niedrigviskose Masse dar. Zum Imprägnieren und Vergießen einer Hochspannungs-Zündspule wird zunächst die Lagenwicklung getrocknet, die Scheibenwicklung auf eine Temperatur von etwa 100 ° temperiert, der Vorratsbehälter, in welchem sich die vergußmasse befindet, evakuiert, um die Vergußmasse zu entgasen und schließlich das Imprägnieren und Vergießen unter Vakuum vorgenommen. Nach dem Entformen wird die Vergußmasse schließlich gehärtet, und zwar zunächst 1 1/2 Stunden bei 90 °C und dann nochmals 2 Stunden bei 120 °C.Description of an exemplary embodiment An epoxy resin is used based on bisphenol A and a cycloolefin as cycloaliphatic in a ratio of 70:30 Parts that have a viscosity of less than 5000 mPas at 25 ° C. To do this, a modified dicarboxylic anhydride7 e.g. B. phthalic anhydride as a hardener and a Imidazole, e.g. B. Pyrazole added as an accelerator and chalk as a filler, with Ground resin, hardener and accelerator in a ratio of 100: 100: 0.5 parts by weight and the filler was added in an amount of 55% by weight, based on the total mixture will. The whole thing is mixed well and then represents a low-viscosity mass. In order to impregnate and cast a high-voltage ignition coil, the first step is the layer winding dried, the disc winding tempered to a temperature of about 100 °, the reservoir, in which the potting compound is located, evacuated to the To degas casting compound and finally the impregnation and potting under vacuum performed. After removal from the mold, the potting compound is finally hardened, namely first 1 1/2 hours at 90 ° C and then another 2 hours at 120 ° C.
Bei dieser beschriebenen Imprägnier-Vergußmasse ergeben sich die folgenden Eigenschaften: viskosität 25 °C (10 000 mPas 60 cc < 1 000 mPas Glasübergangspunkt ca. 140 cc olumenschwund 1,5 % Linearer therm. Ausdehnungskoeffizîent bis 110 C 38.10-6 1/°C 110 bis 130 °C 57.10-6 1/°C >130 °C 115.10-6 1/°C Die auf die beschriebene Weise imprägnierten und vergossenen Zündspulen weisen eine Temperaturwechselbeständigkeit von mindestens -40 cc bis mindestens 120 cc auf und sind elektisch funktionsfähig bei Temperaturen in der Wicklung von mehr als 100 OC.In the case of this impregnation casting compound described, the following result Properties: viscosity 25 ° C (10 000 mPas 60 cc <1 000 mPas glass transition point approx. 140 cc oil shrinkage 1.5% linear thermal expansion coefficient up to 110 C 38.10-6 1 / ° C 110 to 130 ° C 57.10-6 1 / ° C> 130 ° C 115.10-6 1 / ° C The on the described Ignition coils which are impregnated and potted in this way are resistant to temperature changes from at least -40 cc to at least 120 cc and are electrically functional at temperatures in the winding of more than 100 OC.
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19823229558 DE3229558C2 (en) | 1982-08-07 | 1982-08-07 | Impregnation casting compound for electrical components |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19823229558 DE3229558C2 (en) | 1982-08-07 | 1982-08-07 | Impregnation casting compound for electrical components |
Publications (2)
Publication Number | Publication Date |
---|---|
DE3229558A1 true DE3229558A1 (en) | 1984-02-09 |
DE3229558C2 DE3229558C2 (en) | 1984-11-08 |
Family
ID=6170398
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19823229558 Expired DE3229558C2 (en) | 1982-08-07 | 1982-08-07 | Impregnation casting compound for electrical components |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE3229558C2 (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0307665A2 (en) * | 1987-09-15 | 1989-03-22 | International Business Machines Corporation | Encapsulation composition and use thereof |
US5189080A (en) * | 1989-04-25 | 1993-02-23 | Robert Bosch Gmbh | Epoxy resin composition for encapsulating electric circuit components |
DE4138411A1 (en) * | 1991-11-22 | 1993-05-27 | Bosch Gmbh Robert | HARDENING POWERS |
DE19523897A1 (en) * | 1995-06-30 | 1997-01-02 | Bosch Gmbh Robert | Use of silicone-modified epoxy resins as casting compounds for electrotechnical or electronic components |
US6001902A (en) * | 1996-03-27 | 1999-12-14 | Ciba Specialty Chemicals Corp. | Wollastonite-containing curable epoxy resin mixture |
US6030713A (en) * | 1994-07-01 | 2000-02-29 | Ciba Specialty Chemicals Corp. | Electrical or electronic components encapsulated with liquid epoxy resins containing a mixture of wollastonite and calcite fillers |
EP0984463A1 (en) * | 1997-05-23 | 2000-03-08 | Hitachi, Ltd. | Ignition coil unit for engine and engine provided with plastic head cover |
-
1982
- 1982-08-07 DE DE19823229558 patent/DE3229558C2/en not_active Expired
Non-Patent Citations (1)
Title |
---|
NICHTS-ERMITTELT * |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0307665A3 (en) * | 1987-09-15 | 1989-09-13 | International Business Machines Corporation | Encapsulation composition and use thereof |
EP0307665A2 (en) * | 1987-09-15 | 1989-03-22 | International Business Machines Corporation | Encapsulation composition and use thereof |
US5189080A (en) * | 1989-04-25 | 1993-02-23 | Robert Bosch Gmbh | Epoxy resin composition for encapsulating electric circuit components |
DE4138411A1 (en) * | 1991-11-22 | 1993-05-27 | Bosch Gmbh Robert | HARDENING POWERS |
US6030713A (en) * | 1994-07-01 | 2000-02-29 | Ciba Specialty Chemicals Corp. | Electrical or electronic components encapsulated with liquid epoxy resins containing a mixture of wollastonite and calcite fillers |
DE19523897C2 (en) * | 1995-06-30 | 2002-10-24 | Bosch Gmbh Robert | Use of silicone-modified epoxy resins as casting compounds for electrotechnical or electronic components |
DE19523897A1 (en) * | 1995-06-30 | 1997-01-02 | Bosch Gmbh Robert | Use of silicone-modified epoxy resins as casting compounds for electrotechnical or electronic components |
US5965637A (en) * | 1995-06-30 | 1999-10-12 | Robert Bosch Gmbh | Use of silicone-modified epoxy resins as sealing compound |
US6001902A (en) * | 1996-03-27 | 1999-12-14 | Ciba Specialty Chemicals Corp. | Wollastonite-containing curable epoxy resin mixture |
EP0984463A4 (en) * | 1997-05-23 | 2001-03-07 | Hitachi Ltd | Ignition coil unit for engine and engine provided with plastic head cover |
EP1225605A2 (en) * | 1997-05-23 | 2002-07-24 | Hitachi, Ltd. | Ignition coil for use in engine and engine having plastic cylinder head cover |
EP1225605A3 (en) * | 1997-05-23 | 2002-08-28 | Hitachi, Ltd. | Ignition coil for use in engine and engine having plastic cylinder head cover |
EP0984463A1 (en) * | 1997-05-23 | 2000-03-08 | Hitachi, Ltd. | Ignition coil unit for engine and engine provided with plastic head cover |
US6571784B2 (en) | 1997-05-23 | 2003-06-03 | Hitachi, Ltd. | Ignition coil for use in engine and engine having plastic cylinder head cover |
Also Published As
Publication number | Publication date |
---|---|
DE3229558C2 (en) | 1984-11-08 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
OP8 | Request for examination as to paragraph 44 patent law | ||
D2 | Grant after examination | ||
8364 | No opposition during term of opposition | ||
8320 | Willingness to grant licences declared (paragraph 23) | ||
8339 | Ceased/non-payment of the annual fee |