DE102007029882A1 - Process for cooling or liquefying a hydrocarbon-rich stream - Google Patents
Process for cooling or liquefying a hydrocarbon-rich stream Download PDFInfo
- Publication number
- DE102007029882A1 DE102007029882A1 DE102007029882A DE102007029882A DE102007029882A1 DE 102007029882 A1 DE102007029882 A1 DE 102007029882A1 DE 102007029882 A DE102007029882 A DE 102007029882A DE 102007029882 A DE102007029882 A DE 102007029882A DE 102007029882 A1 DE102007029882 A1 DE 102007029882A1
- Authority
- DE
- Germany
- Prior art keywords
- refrigerant
- hydrocarbon
- cooling
- rich stream
- bar
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 20
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 12
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 12
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 12
- 238000001816 cooling Methods 0.000 title claims abstract description 10
- 239000003507 refrigerant Substances 0.000 claims abstract description 35
- 239000000203 mixture Substances 0.000 claims abstract description 12
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000003345 natural gas Substances 0.000 claims abstract description 5
- 230000006835 compression Effects 0.000 claims description 3
- 238000007906 compression Methods 0.000 claims description 3
- 238000005056 compaction Methods 0.000 abstract description 2
- 238000012423 maintenance Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0022—Hydrocarbons, e.g. natural gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/006—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the refrigerant fluid used
- F25J1/008—Hydrocarbons
- F25J1/0092—Mixtures of hydrocarbons comprising possibly also minor amounts of nitrogen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0244—Operation; Control and regulation; Instrumentation
- F25J1/0254—Operation; Control and regulation; Instrumentation controlling particular process parameter, e.g. pressure, temperature
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
- F25J1/0275—Construction and layout of liquefaction equipments, e.g. valves, machines adapted for special use of the liquefaction unit, e.g. portable or transportable devices
- F25J1/0277—Offshore use, e.g. during shipping
- F25J1/0278—Unit being stationary, e.g. on floating barge or fixed platform
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2290/00—Other details not covered by groups F25J2200/00 - F25J2280/00
- F25J2290/12—Particular process parameters like pressure, temperature, ratios
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Ocean & Marine Engineering (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Lubricants (AREA)
- Compressor (AREA)
Abstract
Es wird ein Verfahren zum Abkühlen oder Verflüssigen eines Kohlenwasserstoff-reichen Stromes, beispielsweise eines Erdgasstromes, beschrieben, bei dem die Abkühlung oder Verflüssigung des Kohlenwasserstoff-reichen Stromes gegen wenigstens einen Kältemittelkreislauf, gegen wenigstens einen Kältemittelgemischkreislauf oder gegen eine beliebige KLombination aus wenigstens einem Kältemittelkreislauf und wenigstens einem Kältemittelgemischkreislauf erfolgt. Erfindungsgemäß liegen das oder wenigstens eines der Kältemittel und/oder Kältemittelgemische, das bzw. die einer Verdichtung unterworfen werden, innerhalb des Kältemittelkreislaufes und/oder Kältemittelgemischkreislaufes zumindest teilweise kondensiert vor und weisen bei allen Verfahrenszuständen, insbesondere an der oder den Verdichtersaugseiten eine molare Dichte von wenigstens 0,30 kmol/M<SUP>3</SUP>, vorzugsweise von wenigstens 0,35 kmol/m<SUP>3</SUP>, auf.A method for cooling or liquefying a hydrocarbon-rich stream, such as a natural gas stream is described in which the cooling or liquefaction of the hydrocarbon-rich stream against at least one refrigerant circuit, against at least one refrigerant mixture cycle or against any KLombination of at least one refrigerant circuit and at least one refrigerant mixture cycle takes place. According to the invention, the or at least one of the refrigerants and / or refrigerant mixtures subjected to compaction are at least partially condensed within the refrigerant circuit and / or refrigerant mixture circuit and have a molar density of at least at all process states, in particular at the compressor suction side or sides 0.30 kmol / M <SUP> 3 </ SUP>, preferably at least 0.35 kmol / m <SUP> 3 </ SUP>.
Description
Die Erfindung betrifft ein Verfahren zum Abkühlen oder Verflüssigen eines Kohlenwasserstoff-reichen Stromes, beispielsweise eines Erdgasstromes, wobei die Abkühlung oder Verflüssigung des Kohlenwasserstoff-reichen Stromes gegen wenigstens einen Kältemittelkreislauf, gegen wenigstens einen Kältemittelgemischkreislauf oder gegen eine beliebige Kombination aus wenigstens einem Kältemittelkreislauf und wenigstens einem Kältemittelgemischkreislauf erfolgt.The The invention relates to a method for cooling or liquefying a Hydrocarbon-rich stream, such as a natural gas stream, with the cooling or liquefaction of the Hydrocarbon-rich stream against at least one refrigerant circuit, against at least one refrigerant mixture cycle or against any combination of at least one refrigerant circuit and at least one mixed refrigerant cycle he follows.
Aus dem Stand der Technik sind eine Vielzahl gattungsgemäßer Verfahren zum Abkühlen oder Verflüssigen eines Kohlenwasserstoff-reichen Stromes bekannt, bei denen die Abkühlung oder Verflüssigung des Kohlenwasserstoff-reichen Stromes gegen unterschiedlichst ausgebildete Kältemittel(gemisch)kreisläufe oder gegen beliebige Kombinationen aus wenigstens einem Kältemittelkreislauf und wenigstens einem Kältemittelgemischkreislauf erfolgen.Out The prior art is a variety of generic methods to cool down or liquefying a hydrocarbon-rich stream known in which the cooling or liquefaction of the hydrocarbon-rich stream against most diverse trained Refrigerant (mixture) circuits or against any combinations of at least one refrigerant circuit and at least one mixed refrigerant cycle respectively.
Lediglich beispielhaft genannt seien sog. Single-Flow-Verflüssigungsprozesse, Dual-Flow-Verflüssigungsprozesse sowie der von der Anmelderin entwickelte Mixed-Fluid-Cascade-Verflüssigungsprozess. Sämtlichen, zum Stand der Technik zählenden Verflüssigungsprozessen ist gemein, dass das in ihnen zirkulierende Kältemittel und/oder Kältemittelgemisch verdichtet werden muss. Hierzu kommen üblicherweise Kolben-, Schrauben- oder Turbo-Verdichter zur Anwendung.Only Examples include so-called single-flow liquefaction processes, Dual-flow liquefaction processes and the Applicant's mixed fluid cascade liquefaction process. all, to the state of the art counting liquefaction processes is common that the circulating in them refrigerant and / or refrigerant mixture must be compressed. These usually come piston, screw or turbo-compressor for use.
In der jüngeren Vergangenheit sind bereits eine Vielzahl der vorgenannten gattungsgemäßen Verflüssigungsprozesse im Rahmen von schwimmenden LNG-Anlagen – sog. Floating-LNG-Anlagen – konzipiert worden. Insbesondere derartige Anlagen bzw. Prozesse erfordern Komponenten und Bauteile, die eine kompakte Bauweise aufweisen und darüber hinaus vergleichsweise einfach und kostengünstig gewartet werden können. Die bis dato in Betracht gezogenen, vorgenannten Verdichtertypen eignen sich für derartige schwimmende LNG-Anlagen nur bedingt, da sie zum einen vergleichsweise groß bauen und zum anderen einen hohen Wartungsbedarf aufweisen.In the younger ones The past are already a variety of the aforementioned generic liquefaction processes in the framework of floating LNG plants - so-called floating LNG plants - designed Service. In particular, such systems or processes require components and components that have a compact design and beyond can be maintained comparatively easy and inexpensive. The to date considered, aforementioned compressor types are suitable for such floating LNG plants only conditionally, as they are on the one hand build comparatively large and on the other hand have a high maintenance requirement.
Aufgabe der vorliegenden Erfindung ist es, ein gattungsgemäßes Verfahren zum Abkühlen oder Verflüssigen eines Kohlenwasserstoff-reichen Stromes, beispielsweise eines Erdgasstromes, anzugeben, das die vorbeschriebenen Nachteile vermeidet.task The present invention is a generic method to cool down or liquefying a hydrocarbon-rich stream, such as a natural gas stream, specify that avoids the disadvantages described above.
Zur Lösung dieser Aufgabe wird ein Verfahren zum Abkühlen oder Verflüssigen eines Kohlenwasserstoff-reichen Stromes, beispielsweise eines Erdgasstromes, vorgeschlagen, das dadurch gekennzeichnet ist, dass das oder wenigstens eines der Kältemittel und/oder Kältemittelgemische, das bzw. die einer Verdichtung unterworfen werden, innerhalb des Kältemittelkreislaufes und/oder Kältemittelgemischkreislaufes zumindest teilweise kondensiert vorliegen und bei allen Verfahrenszuständen, insbesondere an der oder den Verdichtersaugseiten eine molare Dichte von wenigstens 0,30 kmol/m3, vorzugsweise von wenigstens 0,35 kmol/m3, aufweisen.To solve this problem, a method for cooling or liquefying a hydrocarbon-rich stream, such as a natural gas stream, proposed, which is characterized in that the or at least one of the refrigerant and / or refrigerant mixtures, which are subjected to a compaction, within of the refrigerant circuit and / or mixed refrigerant cycle are present at least partially condensed and at all process states, in particular at the compressor suction side or sides, a molar density of at least 0.30 kmol / m 3 , preferably at least 0.35 kmol / m 3 .
Weitere vorteilhafte Ausgestaltungen des erfindungsgemäßen Verfahrens zum Abkühlen oder Verflüssigen eines Kohlenwasserstoff-reichen Stromes, die Gegenstände der abhängigen Patentansprüche darstellen, sind dadurch gekennzeichnet, dass
- – die Verdichtung des oder wenigstens eines der Kältemittel und/oder Kältemittelgemische mittels eines Einwellen-Zentrifugalverdichters mit vertikal geteiltem Gehäuse erfolgt,
- – der Verdichter-Saugdruck wenigstens 5 bis 10 bar, vorzugsweise wenigstens 8 bar beträgt und
- – der Verdichter-Enddruck wenigstens 30 bis 70 bar, vorzugsweise wenigstens 50 bar beträgt.
- The compression of the or at least one of the refrigerants and / or refrigerant mixtures takes place by means of a vertically split-housing single-shaft centrifugal compressor,
- - The compressor suction pressure is at least 5 to 10 bar, preferably at least 8 bar and
- - The compressor discharge pressure is at least 30 to 70 bar, preferably at least 50 bar.
Die vorgenannten Einwellen-Zentrifugalverdichter mit vertikal geteiltem Gehäuse werden auch als Topfverdichter oder "Barrel Type Compressor" bezeichnet.The aforesaid single-shaft centrifugal centrifugal compressors casing are also referred to as a pot compressor or "barrel type compressor".
Derartige Einwellen-Zentrifugalverdichter weisen im Gegensatz zu den o. g. Verdichterkonstruktionen eine kompakte Bauweise auf und erfordern zudem einen geringeren Wartungsaufwand als bekannte Verdichterkonstruktionen. Insbesondere für die vorbeschriebene Anwendung bei schwimmenden LNG-Anlagen sind sie daher besonders vorteilhaft geeignet.such Single-shaft centrifugal compressors, in contrast to the o. G. Compressor designs have a compact design and require In addition, a lower maintenance than known compressor designs. Especially for the they are the above-described application for floating LNG plants therefore particularly advantageous.
Da ihr Saugvolumen jedoch begrenzt ist, lassen sich attraktive Anlagengrößen und Verflüssigungsleistungen nur dann realisieren, wenn man eine Anhebung des Druckniveaus in dem oder den Kältemittel(gemisch)kreisläufen zulässt. Dies führt jedoch zwangsläufig zu höheren Dichten, die thermodynamisch von Nachteil und daher unerwünscht sind. Nachdem jedoch diese höheren Dichten die Verwendung derartiger Einwellen-Zentrifugalverdichter erst in vernünftiger Weise ermöglichen, muss dieser Nachteil in Kauf genommen werden.There However, their suction volume is limited, can be attractive system sizes and liquefaction services only realize, if one raises the pressure level in the refrigerant or (refrigerant) cycles allowed. This leads however inevitably to higher Densities that are thermodynamically disadvantageous and therefore undesirable. However, after these higher Dense the use of such single shaft centrifugal compressors only in reasonable Allow way This disadvantage must be accepted.
Claims (4)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102007029882A DE102007029882A1 (en) | 2007-06-28 | 2007-06-28 | Process for cooling or liquefying a hydrocarbon-rich stream |
PE2008000790A PE20090346A1 (en) | 2007-06-28 | 2008-05-06 | PROCESS TO COOL OR LIQUEFIED A FLUID CONTAINING HYDROCARBONS |
PCT/EP2008/004642 WO2009000415A2 (en) | 2007-06-28 | 2008-06-11 | Method for cooling or liquefying a hydocarbon-rich flow |
ARP080102687A AR067129A1 (en) | 2007-06-28 | 2008-06-23 | PROCEDURE TO COOL OR LIQUIDIFY A CURRENT RICH IN HYDROCARBONS |
CL2008001928A CL2008001928A1 (en) | 2007-06-28 | 2008-06-27 | Process to cool or liquefy a stream rich in hydrocarbon, in lng flotation plants, where the cooling proceeds against a mixed refrigerant cycle that is subject to compression, and has a molar density of at least 0.30 kmol / m3, preferably at least 0.35 kmol / m3. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102007029882A DE102007029882A1 (en) | 2007-06-28 | 2007-06-28 | Process for cooling or liquefying a hydrocarbon-rich stream |
Publications (1)
Publication Number | Publication Date |
---|---|
DE102007029882A1 true DE102007029882A1 (en) | 2009-01-02 |
Family
ID=40075939
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE102007029882A Withdrawn DE102007029882A1 (en) | 2007-06-28 | 2007-06-28 | Process for cooling or liquefying a hydrocarbon-rich stream |
Country Status (5)
Country | Link |
---|---|
AR (1) | AR067129A1 (en) |
CL (1) | CL2008001928A1 (en) |
DE (1) | DE102007029882A1 (en) |
PE (1) | PE20090346A1 (en) |
WO (1) | WO2009000415A2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102007047765A1 (en) | 2007-10-05 | 2009-04-09 | Linde Aktiengesellschaft | Liquifying a hydrocarbon-rich fraction, comprises e.g. removing unwanted components like acid gas, water and/or mercury from hydrocarbon-rich fraction and liquifying the pretreated hydrocarbon-rich fraction by using a mixture cycle |
IT201700007473A1 (en) * | 2017-01-24 | 2018-07-24 | Nuovo Pignone Tecnologie Srl | COMPRESSION TRAIN WITH A CENTRIFUGAL COMPRESSOR AND LNG PLANT |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2778232B1 (en) * | 1998-04-29 | 2000-06-02 | Inst Francais Du Petrole | METHOD AND DEVICE FOR LIQUEFACTION OF A NATURAL GAS WITHOUT SEPARATION OF PHASES ON THE REFRIGERANT MIXTURES |
DE19937623B4 (en) * | 1999-08-10 | 2009-08-27 | Linde Ag | Process for liquefying a hydrocarbon-rich stream |
DE102004011483A1 (en) * | 2004-03-09 | 2005-09-29 | Linde Ag | Process for liquefying a hydrocarbon-rich stream |
-
2007
- 2007-06-28 DE DE102007029882A patent/DE102007029882A1/en not_active Withdrawn
-
2008
- 2008-05-06 PE PE2008000790A patent/PE20090346A1/en not_active Application Discontinuation
- 2008-06-11 WO PCT/EP2008/004642 patent/WO2009000415A2/en active Application Filing
- 2008-06-23 AR ARP080102687A patent/AR067129A1/en not_active Application Discontinuation
- 2008-06-27 CL CL2008001928A patent/CL2008001928A1/en unknown
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102007047765A1 (en) | 2007-10-05 | 2009-04-09 | Linde Aktiengesellschaft | Liquifying a hydrocarbon-rich fraction, comprises e.g. removing unwanted components like acid gas, water and/or mercury from hydrocarbon-rich fraction and liquifying the pretreated hydrocarbon-rich fraction by using a mixture cycle |
IT201700007473A1 (en) * | 2017-01-24 | 2018-07-24 | Nuovo Pignone Tecnologie Srl | COMPRESSION TRAIN WITH A CENTRIFUGAL COMPRESSOR AND LNG PLANT |
EP3351882A1 (en) * | 2017-01-24 | 2018-07-25 | Nuovo Pignone Tecnologie SrL | Compression train including one centrifugal compressor and lng plant |
US10809000B2 (en) | 2017-01-24 | 2020-10-20 | Nuovo Pignone Tecnologie Srl | Compression train including one centrifugal compressor and LNG plant |
Also Published As
Publication number | Publication date |
---|---|
WO2009000415A3 (en) | 2012-03-08 |
CL2008001928A1 (en) | 2010-02-05 |
WO2009000415A2 (en) | 2008-12-31 |
AR067129A1 (en) | 2009-09-30 |
PE20090346A1 (en) | 2009-03-22 |
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