A kind of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass
Technical field
The utility model relates to a kind of imitative stone decorative material as ornament materials of building material field, particularly relates to a kind of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass.
Background technology
Now along with the raising of development of science and technology and people's living standard, as the ornament materials of ground and metope, people wish that it has the appearance of lithotome, and the pattern of artificial grantie, marble, jade for example is to increase the top grade sense of product.
Therefore, industry is just updated the dalle structure of natural-like stone, the design people is at glass, pottery, artificial stone, metal finishing sheet material field has multinomial China and Europe, beautiful, the developer of foreign patents such as day, as once proposing a kind of stereo ceramic granite, the patent of marble technology, its notification number is WO97/36840, on October 9th, 1997 is open, according to the made stone imitation material of this technology, its surface is formed with the pattern of clear boundary, and when standing Surface Machining, its pattern can not change basically, so can effectively promote its overall structure steadiness in the use.Yet the stone imitation material of this description of the Prior Art, boundary line between its pattern becomes vertical configuration, make colored pattern boundary transition equally hand over mixed nature,, still have a certain distance apart from people's demand so still seem not enough " natural " (natural) not as true stone material.
In order to satisfy people's practicality demand, back the design people also once proposed a kind of " porcelain imitation granite board and manufacture method thereof ", its notification number is WO99/28262, on June 10th, 1999 is open, above-mentioned porcelain imitation granite board and manufacture method thereof, though the imitative hilllock of the porcelain stone slab that can provide user one to have more practical effect, really has progressive, but when using, reality but finds also to have in its structure deficiency, goods according to this technology only have its surperficial pattern, there are not goods at three-dimensional pattern, and not as the mobile texture that forms pattern of natural lava, so product can not reflect natural granite pattern texture from inside to outside very truly, especially the middle and lower part of limit portion does not have pattern effect, if when the exposed edge of wall that is used for furniture table-board and construction and decoration or post must want opposite side portion to carry out the edging polishing, because wherein, the bottom is not the particle pattern of one with the top layer, so have untrue in practicality than lithotome, incomplete significant deficiency.
The design people yet once proposed ten multinomial category of glass patents, what have has just obtained patent right in 1987, as a kind of " decorating board with printed glass raster " patent wherein, its patent No. is ZL911084487, authorizing day is on October 17th, 1993, above-mentioned decorating board with printed glass raster and manufacture method thereof, though user one can be provided the new glass decoration sheet material that practical effect is arranged, has progressive, but when using, reality but finds also to have in its structure deficiency, goods according to this technology have just been handled one deck raster effects at the simple glass back side, though decorative effect is very magnificent, but because not at the three dimensions pattern Processing of goods, so more afterwards porcelain patent also has certain defective in practicality.
And in order to satisfy people's practicality demand, patent that back the design people once proposed again a kind of " the three-dimensional color pattern sheet material of porcelain powder sintering ", its publication number is CN 1339363A, on March 13rd, 2002 is open, the three-dimensional color pattern sheet material of above-mentioned porcelain powder sintering, though having proposed it is the powder that utilizes the porcelain colour raw material, repressed, and the porcelain product that is fired into, its goods have different color or same color but different color and luster weights of tool or the different porcelain that mixes the clear-cut that colour cell becomes burn till pattern area, pattern area all is even distribution the 70%--100% zone from the goods top layer to bottom thickness, and can be made into the three-dimensional stone imitation material as lithotome; Though very much progress is arranged on effect, can make powder specified distribution be arranged in not homochromy district, 3-D effect is arranged, this product is too late glass product on soil resistance.And existing glass product mostly is monochrome or the back adds pattern Processing.
Simultaneously, existing devitrified glass product does not all have three-D pattern, dull coloring, inflexible; And the utility model is used for devitrified glass, more can make the imitative jade of abundanter half penetrating effect, the imitative super pattern of stone material, can be used as the decorative panel of epoch-making top furniture, desk panel, top building, if adopting the upper strata is the devitrified glass of the utility model feature, make devitrified glass the three-D pattern effect occur, lower floor is the goods of ceramic sheet, then when reducing cost greatly, has improved class again.But if pattern is arranged just but the edge is very inflexible line of demarcation, and then can not clone the effect that two look district transition of natural jade and top stone material mix blending mutually truly, also there is defective.So, the product of the utility model technical pattern can be used at crystallizing glass sheet material, can solve the problem of existing crystallized glass article pattern dullness, imitative stone weak effect, can solve the transition of broken colour pattern color and the intersecting lens edge of each color chromatic color area again and mix a difficult problem of blending mutually, this.。It is a kind of circumscribed innovative technology of existing crystallized glass article that solved revolutionaryly.
The defective that exists for the microcrystalline glass decorative plate that solves existing natural-like stone pattern, relevant manufacturer there's no one who doesn't or isn't seeks solution painstakingly, but do not see always that for a long time suitable design finished by development, this obviously is the problem that the anxious desire of relevant dealer solves.
Because the defective that the microcrystalline glass decorative plate of above-mentioned existing natural-like stone pattern exists, the design people is based on being engaged in this type of product design manufacturing abundant for many years practical experience and professional knowledge, and the utilization of cooperation scientific principle, actively studied innovation, in the hope of founding a kind of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of new structure, can improve the microcrystalline glass decorative plate of general existing natural-like stone pattern, make it have more practicality.Through constantly research, design, and after studying sample and improvement repeatedly, create the utility model that has practical value finally.
Summary of the invention
The purpose of this utility model is, the defective that its microcrystalline glass decorative plate that not only can overcome existing natural-like stone pattern exists, technical problem to be solved is to make it can make the three-dimensional stone imitation material that has as lithotome, jade, or be called the microcrystal glass material of clone's stone natural marble, granite, jade, and form a kind of new board product, thereby be suitable for practicality more.Make the density and the position of colour devitrified glass material local distribution can be by the feature of lithotome pattern in goods interior three-dimensional space, the manufacturing of control can be arranged in the technology of pattern grid mould, and have the good effect that to copy lithotome truly.And the little pattern that contains the micro mist feature in the big pattern area of various colours can appear in the area of the pattern of clone's natural stone again, the edge transition that produces when not only flowing as natural lava is fine, the colourful polygon of form, many prism patterns, also have some in concave crescent shapes or many crescent shapes enrich fine pattern, and the fine pattern that also has has comprised the fritter pattern of other color, the edge of the meticulous fritter pattern that yet has is not to have a common boundary with a kind of look district, but have a common boundary with two or more more look district indentingly, the effect that generation is flowed as natural lava, especially in the processing of ceramic material micro mist, add and contain the tiny powder of 0.1mm-0.25mm to reach the effect of micro mist edge transition, and in microcrystal glass material processing, can use moisture content, low adhesive forms mobile difference, so can use diameter less than 0.1mm reach 2-5 doubly or diameter reach 2-5 powder doubly greater than 0.3mm, form the difference of flowability effect, reach the purpose of making imitative natural lava flow effect, thereby can copy more realistically such as the Arabescato in the marble, Drama White, Dark Green, Rossa Verona, Perlino Rosato, Sha Luo Hong, silver dried shrimps Huang, the gold of Rosso Norvegian and granite class is color to be bored, Giallo Veneziano, Baltic Brown, green brill, Multicolor Red, natural classical stone material such as Martiaca.
The purpose that the utility model is even more important; also be that topmost inventive point of the present utility model is: the utility model has been summed up pattern grid mould gone out to have at cloth to adopt on the critical process of pattern powder and has been sieved in the scope of 1mm-5mm; the vibration or rock; forming not, generation 1mm-5mm zone, intersecting lens edge two looks in homochromy district mix mutually; behind high heat burnout; appearance is as rock; process and effect when clone's lithotome that the crystal grain of the natural transiting color coloured silk of the two form and aspect blending that occurs when jade generates mixes mutually and jade produce; make the crystallized glass article technology obtain revolutionary lifting, this also is to the utility model people distillation and development of technology pattern grid mould process formerly.
A kind of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the utility model more can show compared to existing natural-like stone and advance the natural effect that one deck clone lithotome lava flows and forms when cloning big standard pattern.The utility model goods simultaneously than lithotome have also that water absorption rate is low, aberration is little, advantage such as highly polished, "dead" element pollution, be a kind of industrial circle wide popularization and application that is suitable for, quite have the new design of novelty, practicality and progressive.
Realize above-mentioned purpose, can realize by following measure:
The utility model three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass is characterized in that: its upper strata is to have by 2--10 kind different color or same color but different color and luster weights of tool or different 2-5000 the area that mixes the clear-cut of the microcrystal glass material that colour cell becomes reach 4cm
2-1m
2Pattern area; And wherein the rarest two kinds of not homochromy districts, each is in the area of the 50%-100% of its pattern area, and thickness reaches 1mm-60mm; And in the rarest 1 color lump pattern area edge 0.1mm-5mm scope, there are ten thousand granular devitrified glasses of 2-1000 of another adjacent look district color to blend in wherein; Its lower floor is the silicate material layer structure of monochrome or secondary colour.
Aforesaid three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass is characterized in that: its lower floor is the structure of ceramic material layer.
Aforesaid three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass, the pattern area of the area of 50%-100% separately of the devitrified glass of the rarest 2 kinds of different colors in the goods, its thickness reaches 10mm-60mm.
Aforesaid three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass, within the wherein said pattern colour district, a kind or 1-5 kind color are arranged, by 3-1000 area at 1cm
2-150cm
2, the indent crescent shape, the polygonal pattern block of being with micro mist material feature, the distance of the concave point of the straight line that two the most outstanding end points of concave crescent shape are linked to be in this and its inner fovea part is 1.5mm-10mm.
Aforesaid three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass, described by 2-10 kind different color or same color but the different color and luster weights of tool or different 2 or 2-50 pattern area of mixing the clear-cut of the microcrystal glass material that colour cell becomes, from the top layer or the top layer to the three dimensions of bottom thickness 70%-100%, also be provided with the piece bulk pattern that 1-5 kind diameter is formed at the colored powder material of 3mm-60mm.
Aforesaid three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass in the wherein said pattern area, contains the color grains material of 1-5 kind diameter at 1.5mm-30mm, and the volume of this particle accounts for the 2%-80% of pattern area area.
Aforesaid three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass, to be the single look of red, yellow, white, blue, black, green, purple, coffee look class or two kinds mix the color lump of composition or secondary colour and the single look common color lump of forming to multiple colorant grain to described color lump mutually.
Aforesaid three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass, the overall geometry of described goods are surface plate shape, cylindrical, cambered plate shape, partial circle cylindricality, sphere, hemispherical, awl circle shape hemispherical or the shape of justifying the moulding of shape combinatorial surface by plane and half cone.
A kind of a kind of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass that is applicable in the pattern followed rock sheet material that permanent ground, metope and furniture panel decorate that the utility model proposes.It is the powder that utilizes the colour devitrified glass raw material, fired or be bonded product, its goods upper strata are to have by 2--10 kind different color or same color but different color and luster weights of tool or different 2-5000 the area that mixes the clear-cut of the microcrystal glass material that colour cell becomes reach 4cm
2-1m
2Pattern area; And wherein the rarest two kinds of not homochromy districts, each is in the area of the 50%-100% of its pattern area, and thickness reaches 1mm-60mm; And in the rarest 1 color lump pattern area edge 0.1mm-5mm scope, there are ten thousand granular devitrified glasses of 2-1000 of another adjacent look district color to blend in wherein.The immitation stone plate of making therefrom as the lithotome effect more can be imitated out the product of three-D pattern effect compared to existing crystallized glass article.Adopt the imitative standard of the three-dimensional colour clocklike pattern of microcrystal glass material such as Arabescato, Snow Flower White, Dark Green, Iundra Brown, California Gilld, emerald, white jade, jasper, agate jadelike stone jade or the like top stone material, jade; Simultaneously the utility model goods than lithotome have also that water absorption rate is low, aberration is little, advantage such as highly polished, "dead" element pollution, and become a kind of new design that quite has practicality and progressive, be suitable for the industrial circle wide popularization and application.
By technique scheme, the utility model three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass has following advantage at least:
The utility model has carried out further improvement to imitating natural marble, granite, structure penetrating or half penetrating jade dalle, its structure simulation is splendid, and than natural stone have also that water absorption rate is low, aberration is little, the advantage of highly polished, "dead" element pollution, be suitable for practicality in the use more, and can be by the machining mass industrialized production, make manufacturing cost reduce relatively, meet economic benefit, and quite have the extensive value of industry.
In sum, the three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the utility model special construction, can make the three-dimensional stone imitation material that has as lithotome, or be called the microcrystal glass material of cloning stone natural marble, granite, jade, and form a kind of new board product.It has above-mentioned many advantages and practical value, and in like product, do not see have similar structural design to publish or use and really genus innovation, no matter it all has bigger improvement on product structure or function, have large improvement technically, and produced handy and practical effect, thereby being suitable for practicality more, and having the extensive value of industry, really is a new and innovative, progressive, practical new design.
Above-mentioned explanation only is the general introduction of technical solutions of the utility model, for can clearer understanding technological means of the present utility model, and can be implemented according to the content of specification, and for above-mentioned and other purposes, feature and advantage of the present utility model can be become apparent, below especially exemplified by preferred embodiment, and conjunction with figs., be described in detail as follows.
Description of drawings
Fig. 1 is the planar structure schematic diagram of goods first embodiment of a kind of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the utility model.
Fig. 2 is the structural representation of the local amplifier section in plane of look district boundary line of different color of goods first embodiment of a kind of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the utility model.
Fig. 3 is the structural representation of the local amplifier section of section of look district boundary line of different color of goods first embodiment of a kind of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the utility model.
Fig. 4 is the planar structure schematic diagram of the die orifice mould of the essential steel matter of goods first embodiment of a kind of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the utility model.
The specific embodiment
For further setting forth the utility model is to reach technological means and the effect that predetermined goal of the invention is taked, below in conjunction with accompanying drawing and preferred embodiment, to according to its specific embodiment of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass, structure, feature and the effect thereof that the utility model proposes, describe in detail as after.
Seeing also shown in Figure 1ly, is the planar structure schematic diagram that imitative Dark Green marble first embodiment of a kind of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the utility model is of a size of the goods of 600mm * 600mm.Pattern area 1 expression of big stain part is the blackish green district of microcrystal glass material; Pattern area 2 expressions of pore part are that the microcrystal glass material powder is green, the look district of two kinds of mixed sinterings of ash; Pattern area 3 expressions of oblique line part are the black chromatic color areas of microcrystal glass material.
Seeing also shown in Figure 2ly, is the structural representation of the local amplifier section in plane of look district boundary line of different color of goods first embodiment of a kind of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the utility model.Pattern area 1 expression of big stain part is the blackish green district of microcrystal glass material; Pattern area 2 expressions of pore part are that microcrystal glass material is green, the look district of two kinds of powder mixed sinterings of ash; Article two, the part between the dotted line represents that blackish green colorant and green, ash material nature hand over the powder that mixes and form to hand over mixed transition region 4 naturally, and the mixed ratio of the friendship of this transition region 4 reaches in 10: 50 to 30: 50.
Seeing also shown in Figure 3ly, is the structural representation of local amplifier section of look district boundary line of goods first embodiment and the different color perpendicular section in goods table plane of a kind of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the utility model.Upper strata 10 mainly comprises: the blackish green district of the microcrystal glass material of pattern area 1 expression of big stain part; The microcrystal glass material of pattern area 2 expressions of pore part is green, the look district of two kinds of powder mixed sinterings of ash; And the blackish green colorant represented of the part between two dotted lines and green, ash material nature hand over the powder that mixes and form to hand over mixed transition region 4 naturally, and the mixed ratio of the friendship of this transition region 4 reaches in 10: 50 to 30: 50.Lower floor 20 is the silicate material layer structure of monochrome or secondary colour, especially adopts the ceramic material layer.
Seeing also shown in Figure 4ly, is the planar structure schematic diagram of the die orifice mould of the essential steel matter of goods first embodiment of a kind of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the utility model.Big stain represents that partly the die orifice of blackish green colorant is by district 101; Pore is partly represented, and die orifices green, two kinds of compounds of ash pass through district 102; Oblique line partly represent be the black material die orifice by the district 103; Thick black line is partly represented the head-down position on steel die orifice plane 105.
Now preparation method and the manufacturing process thereof with a kind of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass first embodiment product of the utility model specifies as follows:
(1), in making enforcement, the glass ceramics frit pellet can be by following material composition and technological principle preparation, at first prepare a kind of contain the aftermentioned composition and by with the technology composite material that composition scope (parts by weight) mixes that is complementary, (contained composition has: SiO
255-65, AL
2O
35-10, KNaO 3-8, CaO 13-20, MgO 0-2, BaO 0-4, Ba
2O
30.5-1.5, ZnO 4-8 and an amount of fining agent and the required colouring agent of green, black, blackish green, grey isochrome); Second step was divided into composite material of all kinds, and one group of every look class is put in 1400 ℃ of-1560 ℃ of temperature and founded into glass metal; In the 3rd step, make the glass metal cooling become the glass ceramics frit grain of glass slag particle material and make its oven dry or air dry; The 4th step need be made into the required compound in goods district of all kinds with the glass ceramics frit grain by predetermined;
(2), it is first group with the blackish green colorant of microcrystal glass material; And each is 50% green, the grey compound is second group, and the black material is the 3rd group, and three groups of materials are respectively charged among three containers.
(3), the assembling die 10 of the die orifice of again a cover being made by product predetermined pattern shape with three big pattern colour districts is placed under the container: the raw material that make various looks are by the regulation gradation of Fig. 4 or with the pipeline mould grid areas separately that falls into simultaneously, injects, packs into.Wherein first group of die orifice that falls into blackish green colorant is by district's 101 big pattern area, and second group of die orifice that falls into compound is by district's 102 big pattern area, and the 3rd group of die orifice that falls into the black material is by district's 103 big pattern area.
(4), the operation of most critical is, with high speed machine action in the plane or preceding or back or a left side or right and determine that particularly parameter sieves, vibrates or rock steel matter mould 10 at 1mm-5mm with interior, forming not, the powder in homochromy zone has certain friendship naturally to mix shape at the 1mm-5mm intersection, form the three-dimensional structure of imitative Dark Green marble pattern very truly, make each colorant fall into the special use that is added with separating powder and burn till and reach 30mm thickness on the supporting plate, add fixative by the die orifice of pattern requirement by assembling die 10.
(5), send in the roller kilns then and burn till.Sintering process is a three phases, phase I is the temperature rise period, from 0 ℃ of-870 ℃ of particle bond, eliminate gradually in the space, begins crystallization from the interface to 980 ℃, particle is melted fully be integral body and abundant crystallization, second stage is finished from 1000 ℃ of-1240 ℃ of crystallizatioies, form the material that nucleus, crystalline phase are evenly distributed, the phase III begins progressively to lower the temperature and is cooled to room temperature, and whole firing period is 3-5 hour.
(6), through the demoulding from supporting plate, the polishing after, promptly obtain the marmorean goods of imitative Dark Green of the present utility model.
The above, only be for preferable preferred embodiment of the present utility model is described, yet it is not to be to restriction of the present utility model, any personnel that are familiar with this technology may utilize the technology contents of above-mentioned prompting to be changed or be modified to the equivalent embodiment of equivalent variations, every content that does not break away from technical solutions of the utility model, according to technical spirit of the present utility model to any simple modification that above embodiment did, equivalent variations and modification all still belong in the scope of technical solutions of the utility model.