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CN100567032C - Three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass - Google Patents

Three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass Download PDF

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Publication number
CN100567032C
CN100567032C CNB2005100806381A CN200510080638A CN100567032C CN 100567032 C CN100567032 C CN 100567032C CN B2005100806381 A CNB2005100806381 A CN B2005100806381A CN 200510080638 A CN200510080638 A CN 200510080638A CN 100567032 C CN100567032 C CN 100567032C
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pattern
color
area
micro crystal
cross state
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CN1891495A (en
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杨德宁
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Abstract

The invention relates to a kind of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass, it has by 2-10 kind different color or same color but different color and luster weights of tool or different 2-5000 the area that mixes the clear-cut of the microcrystal glass material that colour cell becomes reach 4cm 2-1m 2Pattern area; And wherein the rarest two kinds of not homochromy districts, each is in the area of the 50%-100% of its pattern area, and thickness reaches 1mm-60mm; And in the rarest 1 color lump pattern area edge 0.1mm-5mm scope, there are ten thousand granular devitrified glasses of 2-1000 of another adjacent look district color to blend in wherein.It can make the three-dimensional stone imitation material that has as lithotome, or is called the microcrystal glass material of clone's stone natural marble, granite, jade, and forms a kind of new board product, thereby is suitable for practicality more.

Description

Three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass
Technical field
The present invention relates to be used as in a kind of microcrystal glass area construction material the imitative stone decorative material of ornament materials, particularly relate to a kind of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass that is applicable in the pattern followed rock sheet material that permanent ground, metope and furniture panel decorate.
Background technology
Now along with the raising of development of science and technology and people's living standard, as the ornament materials of ground and metope, people wish that it has the appearance of lithotome, and the pattern of artificial grantie, marble, jade for example is to increase the top grade sense of product.
Therefore, industry is just updated the dalle structure of natural-like stone, the inventor is at glass, pottery, artificial stone, metal finishing sheet material field has multinomial China and Europe, beautiful, the developer of foreign patents such as day, a kind of stereo ceramic granite was once proposed, the patent of marble technology, its notification number is WO97/36840, on October 9th, 1997 is open, according to the made stone imitation material of this technology, its surface is formed with the pattern of clear boundary, and when standing Surface Machining, its pattern can not change basically, so can effectively promote its overall structure steadiness in the use.Yet the stone imitation material of this description of the Prior Art, boundary line between its pattern becomes vertical configuration, make colored pattern boundary transition equally hand over mixed nature,, still have a certain distance apart from people's demand so still seem not enough " natural " (natural) not as true stone material.
In order to satisfy people's practicality demand, the inventor also once proposed a kind of " porcelain imitation granite board and manufacture method thereof ", its notification number is WO99/28262, on June 10th, 1999 is open, above-mentioned porcelain imitation granite board and manufacture method thereof, though the imitative hilllock of the porcelain stone slab that can provide user one to have more practical effect, really has progressive, but when using, reality but finds also to have in its structure deficiency, goods according to this technology only have its surperficial pattern, there are not goods at three-dimensional pattern, and not as the mobile texture that forms pattern of natural lava, so product can not reflect natural granite pattern texture from inside to outside very truly, especially the middle and lower part of limit portion does not have pattern effect, if when the exposed edge of wall that is used for furniture table-board and construction and decoration or post must want opposite side portion to carry out the edging polishing, because wherein, the bottom is not the particle pattern of one with the top layer, so have untrue in practicality than lithotome, incomplete significant deficiency.
The inventor yet once proposed ten multinomial category of glass patents, what have has just obtained patent right in 1987, as a kind of " decorating board with printed glass raster " patent wherein, its patent No. is ZL91108448.7, authorizing day is on October 17th, 1993, above-mentioned decorating board with printed glass raster and manufacture method thereof, though user one can be provided the new glass decoration sheet material that practical effect is arranged, has progressive, but when using, reality but finds also to have in its structure deficiency, goods according to this technology have just been handled one deck raster effects at the simple glass back side, though decorative effect is very magnificent, but because not at the three dimensions pattern Processing of goods, so more afterwards porcelain patent also has certain defective in practicality.
And in order to satisfy people's practicality demand, patent that the back inventor once proposed again a kind of " the three-dimensional color pattern sheet material of porcelain powder sintering ", its publication number is CN 1339363A, on March 13rd, 2002 is open, the three-dimensional color pattern sheet material of above-mentioned porcelain powder sintering, though having proposed it is the powder that utilizes the porcelain colour raw material, repressed, and the porcelain product that is fired into, its goods have different color or same color but different color and luster weights of tool or the different porcelain that mixes the clear-cut that colour cell becomes burn till pattern area, pattern area all is even distribution the 70%-100% zone from the goods top layer to bottom thickness, and can be made into the three-dimensional stone imitation material as lithotome; Though very much progress is arranged on effect, can make powder specified distribution be arranged in not homochromy district, 3-D effect is arranged, this product is too late glass product on soil resistance.And existing glass product mostly is monochrome or the back adds pattern Processing.
Simultaneously, existing devitrified glass product does not all have three-D pattern, dull coloring, inflexible; And the present invention is used for devitrified glass, more can make the imitative jade of abundanter half penetrating effect, the imitative super pattern of stone material, can be used as the decorative panel of epoch-making top furniture, desk panel, top building, if adopt the devitrified glass of upper strata for feature of the present invention, make devitrified glass the three-D pattern effect occur, lower floor is the goods of ceramic sheet, then when reducing cost greatly, has improved class again.But if pattern is arranged just but the edge is very inflexible line of demarcation, and then can not clone the effect that two look district transition of natural jade and top stone material mix blending mutually truly, also there is defective.So, the technology of the present invention constructed products can be used at crystallizing glass sheet material, can solve the problem of existing crystallized glass article pattern dullness, imitative stone weak effect, can solve the transition of broken colour pattern color and the intersecting lens edge of each color chromatic color area again and mix a difficult problem of blending mutually.
Combine by above-mentioned, the dalle of various devitrified glass natural-like stones of the prior art all can not show the sort of pattern of being made up of diverse color grains of not homochromy or same color density and powder of lithotome, and has the defective that can not copy lithotome, jade truly.
Because the defective that the microcrystalline glass decorative plate of above-mentioned existing natural-like stone pattern exists, the inventor is based on being engaged in this type of product design manufacturing abundant for many years practical experience and professional knowledge, and the utilization of cooperation scientific principle, actively studied innovation, in the hope of founding a kind of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of new structure, can improve the microcrystalline glass decorative plate of general existing natural-like stone pattern, make it have more practicality.Through constantly research, design, and after studying sample and improvement repeatedly, create the present invention who has practical value finally.
Summary of the invention
The objective of the invention is to, overcome the defective of the microcrystalline glass decorative plate existence of existing natural-like stone pattern, and provide a kind of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of new structure, technical problem to be solved is to make it can make the three-dimensional stone imitation material that has as lithotome, or be called the microcrystal glass material of clone's stone natural marble, granite, jade, and form a kind of new board product, thereby be suitable for practicality more.
In order to achieve the above object; according to three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the present invention; pattern grid mould is gone out to have at cloth adopt on the critical process of pattern powder and in the scope of 1mm-5mm, sieve; the vibration or rock; forming not, generation 1mm-5mm zone, intersecting lens edge two looks in homochromy district mix mutually; behind high heat burnout; appearance is as rock; process and effect when clone's lithotome that the crystal grain of the natural transiting color coloured silk of the two form and aspect blending that occurs when jade generates mixes mutually and jade produce; the crystallized glass article technology is got a promotion, and this also is to inventor's improvement of technology pattern grid mould process formerly.Make the density and the position of colour devitrified glass material local distribution can be by the feature of lithotome pattern in goods interior three-dimensional space, can be in the technology of pattern grid mould, the manufacturing of control is arranged, and have the good effect that to copy lithotome truly.And the little pattern that contains the micro mist feature in the big pattern area of various colours can appear in the area of the pattern of clone's natural stone again, the edge transition that produces when not only flowing as natural lava is fine, the colourful polygon of form, many prism patterns, also have some in concave crescent shapes or many crescent shapes enrich fine pattern, and the fine pattern that also has has comprised the fritter pattern of other color, the edge of the meticulous fritter pattern that yet has is not to have a common boundary with a kind of look district, but have a common boundary with two or more more look district indentingly, the effect that generation is flowed as natural lava, especially in the processing of ceramic material micro mist, add and contain the tiny powder of 0.1mm-0.25mm to reach the effect of micro mist edge transition, and in microcrystal glass material processing, can use moisture content, low adhesive forms mobile difference, so can use diameter less than 0.1mm reach 2-5 doubly or diameter reach 2-5 powder doubly greater than 0.3mm, form the difference of flowability effect, reach the purpose of making imitative natural lava flow effect, thereby can copy more realistically such as the Arabescato in the marble, Drama White, Dark Green, Rossa Verona, Perlino Rosato, Sha Luo Hong, silver dried shrimps Huang, the gold of Rosso Norvegian and granite class is color to be bored, Giallo Veneziano, Baltic Brown, green brill, Multicolor Red, natural classical stone material such as Martiaca.
Three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the present invention, its goods have by 2-10 kind different color or same color but different color and luster weights of tool or different 2-5000 the area that mixes the clear-cut of the microcrystal glass material that colour cell becomes reach 4cm 2-1m 2Pattern area; And wherein the rarest two kinds of not homochromy districts, each is in the area of the 50%-100% of its pattern area, and thickness reaches 1mm-60mm; And in the rarest 1 color lump pattern area edge 0.1mm-5mm scope, there are ten thousand granular devitrified glasses of 2-1000 of another adjacent look district color to blend in wherein.
Aforesaid three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass, the pattern area of the area of 50%-100% separately of the devitrified glass of the rarest wherein said 2 kinds of different colors, its thickness reaches 10mm-60mm.
Aforesaid three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass, within the wherein said pattern colour district, 1-5 kind color is arranged, by 3-1000 area at 1cm 2-150cm 2, the indent crescent shape, the polygonal pattern of being with micro mist material feature, the distance of the concave point of the straight line that two the most outstanding end points of concave crescent shape are linked to be in this and its inner fovea part is 1.5mm-10mm.
Aforesaid three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass, wherein said by 2-10 kind different color or same color but different color and luster weights of tool or different 2-50 pattern area of mixing the clear-cut of the microcrystal glass material that colour cell becomes, to the three dimensions of bottom 70%-100% thickness, also be provided with the piece bulk pattern that 1-5 kind diameter is formed at the colored powder material of 3mm-60mm from the top layer.
Aforesaid three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass in the wherein said pattern area, contains the color grains material of 1-5 kind diameter at 1.5mm-30mm, and the volume of this particle accounts for the 2%-80% of pattern area area.
Aforesaid three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass, to be the single look of red, yellow, white, blue, black, green, purple, coffee look class or two kinds mix the color lump of composition or secondary colour and the single look common color lump of forming to multiple colorant grain to wherein said color lump mutually.
Aforesaid three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass contains mica shape secondary crystallization pattern in the wherein said pattern area material.
Aforesaid three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass, its overall geometry are surface plate shape, cylindrical, cambered plate shape, partial circle cylindricality, hemispherical, awl circle shape hemispherical or the shape of justifying the moulding of shape combinatorial surface by plane and half cone.
Aforesaid three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass, its upper strata are the devitrified glass with feature of the present invention, and lower floor is the structure of porcelain plate.
The present invention is the powder that utilizes the colour devitrified glass raw material, fired or be bonded product, its goods have by 2-10 kind different color or same color but different color and luster weights of tool or different 2-5000 the area that mixes the clear-cut of the microcrystal glass material that colour cell becomes reach 4cm 2-1m 2Pattern area; And wherein the rarest two kinds of not homochromy districts, each is in the area of the 50%-100% of its pattern area, and thickness reaches 1mm-60mm; And in the rarest 1 color lump pattern area edge 0.1mm-5mm scope, there are ten thousand granular devitrified glasses of 2-1000 of another adjacent look district color to blend in wherein.
By technique scheme, the immitation stone plate of making therefrom as the lithotome effect more can be imitated out the product of three-D pattern effect compared to existing crystallized glass article.Adopt the imitative standard of the three-dimensional colour clocklike pattern of microcrystal glass material such as Arabescato, Snow Flower White, Dark Green, Iundra Brown, California Gilld, emerald, white jade, jasper, agate jadelike stone jade or the like top stone material, jade; Simultaneously goods of the present invention than lithotome have also that water absorption rate is low, aberration is little, advantage such as highly polished, "dead" element pollution, be suitable for practicality in the use more, and can be by the machining mass industrialized production, make manufacturing cost reduce relatively, meet economic benefit, and become a kind of new design that quite has practicality and progressive, be suitable for the industrial circle wide popularization and application.
In sum, the three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of special construction of the present invention, it can make the three-dimensional stone imitation material that has as lithotome, or be called the microcrystal glass material of cloning stone natural marble, granite, jade, and form a kind of new board product.It has above-mentioned many advantages and practical value, and in like product, do not see have similar structural design to publish or use and really genus innovation, no matter it all has bigger improvement on product structure or function, have large improvement technically, and produced handy and practical effect, and the microcrystalline glass decorative plate of more existing natural-like stone pattern has the multinomial effect of enhancement, thereby be suitable for practicality more, and have the extensive value of industry, really be a new and innovative, progressive, practical new design.
Above-mentioned explanation only is the general introduction of technical solution of the present invention, for can clearer understanding technological means of the present invention, and can be implemented according to the content of specification, and for above-mentioned and other purposes, feature and advantage of the present invention can be become apparent, below especially exemplified by preferred embodiment, and conjunction with figs., be described in detail as follows.
Description of drawings
Fig. 1 is the planar structure schematic diagram of goods first embodiment of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the present invention.
Fig. 2 is the structural representation of the local amplifier section in plane of look district boundary line of different color of goods first embodiment of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the present invention.
Fig. 3 is the structural representation of the local amplifier section of section of look district boundary line of different color of goods first embodiment of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the present invention.
Fig. 4 is the planar structure schematic diagram of the die orifice mould of the essential steel matter of goods first embodiment of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the present invention.
The specific embodiment
Reach technological means and the effect that predetermined goal of the invention is taked for further setting forth the present invention, below in conjunction with accompanying drawing and preferred embodiment, to its specific embodiment of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass, structure, feature and the effect thereof that foundation the present invention proposes, describe in detail as after.
Seeing also shown in Figure 1ly, is the planar structure schematic diagram that imitative Dark Green marble first embodiment of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the present invention is of a size of the goods of 600mm * 600mm.Pattern area 1 expression of big stain part is the blackish green district of microcrystal glass material; Pattern area 2 expressions of pore part are that the microcrystal glass material powder is green, the look district of two kinds of mixed sinterings of ash; Pattern area 3 expressions of oblique line part are the black chromatic color areas of microcrystal glass material.
Seeing also shown in Figure 2ly, is the structural representation of the local amplifier section in plane of look district boundary line of different color of goods first embodiment of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the present invention.Pattern area 1 expression of big stain part is the blackish green district of microcrystal glass material; Pattern area 2 expressions of pore part are that microcrystal glass material is green, the look district of two kinds of powder mixed sinterings of ash; Article two, the part between the dotted line represents that blackish green colorant and green, ash material nature hand over the powder that mixes and form to hand over mixed transition region 4 naturally, and the mixed ratio of the friendship of this transition region 4 reaches in 10: 50 to 30: 50.
Seeing also shown in Figure 3ly, is the structural representation of local amplifier section of look district boundary line of goods first embodiment and the different color perpendicular section in goods table plane of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the present invention.Its upper strata 5 is a glass-ceramic layer, and lower floor 6 is the porcelain plate.Pattern area 1 expression of big stain part is the blackish green district of microcrystal glass material; Pattern area 2 expressions of pore part are that microcrystal glass material is green, the look district of two kinds of powder mixed sinterings of ash; Article two, the part between the dotted line represents that blackish green colorant 1 and green, ash material 2 hand over the powder that mixes and form to hand over mixed transition region 4 naturally naturally, and the mixed ratio of the friendship of this transition region 4 reaches in 10: 50 to 30: 50.
Seeing also shown in Figure 4ly, is the planar structure schematic diagram of the die orifice mould of the essential steel matter of goods first embodiment of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass of the present invention.Big stain represents that partly the die orifice of blackish green colorant is by district 101; Pore is partly represented, and die orifices green, two kinds of compounds of ash pass through district 102; Oblique line partly represent be the black material die orifice by the district 103; Thick black line is partly represented the head-down position on steel die orifice plane 105.
Now preparation method and the manufacturing process thereof with the three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass first embodiment product of the present invention specifies as follows:
(1), in making enforcement, the glass ceramics frit pellet can be by following material composition and technological principle preparation, at first prepare a kind of contain the aftermentioned composition and by with the technology composite material that composition scope (percentage by weight) mixes that is complementary, (synthesize and part have: SiO 255-65, AL 2O 35-10, KNaO3-8, CaO 13-20, MgO 0-2, BaO 0-4, Ba 2O 30.5-1.5, ZnO 4-8 and an amount of fining agent and the required colouring agent of green, black, blackish green, grey isochrome); Second step was divided into composite material of all kinds, and one group of every look class is put in 1400 ℃ of-1560 ℃ of temperature and founded into glass metal; In the 3rd step, make the glass metal cooling become the glass ceramics frit grain of glass slag particle material and make its oven dry or air dry; The 4th step need be made into the required compound in goods district of all kinds with the glass ceramics frit grain by predetermined;
(2), it is first group with the blackish green colorant of microcrystal glass material; And each is 50% green, the grey compound is second group, and the black material is the 3rd group, and three groups of materials are respectively charged among three containers.
(3), the assembling die 10 of the die orifice of again a cover being made by product predetermined pattern shape with three big pattern colour districts is placed under the container: the raw material that make various looks are by the regulation gradation of Fig. 4 or with the pipeline mould grid areas separately that falls into simultaneously, injects, packs into.Wherein first group falls into 101, the second groups of big pattern area and falls into big pattern area and fall into big pattern area 103 for 102, the three groups.
(4), the operation of most critical is, with high speed machine action in the plane or preceding or back or a left side or right and determine that particularly parameter sieves, vibrates or rock steel matter mould 10 at 1mm-5mm with interior, forming not, the powder in homochromy zone has certain friendship naturally to mix shape at the 1mm-5mm intersection, form the three-dimensional structure of imitative Dark Green marble pattern very truly, make each colorant fall into the special use that is added with separating powder and burn till and reach 30mm thickness on the supporting plate, add fixative by the die orifice of pattern requirement by assembling die 10.
(5), send in the roller kilns then and burn till.Sintering process is a three phases, phase I is the temperature rise period, from 0 ℃ of-870 ℃ of particle bond, eliminate gradually in the space, begins crystallization from the interface to 980 ℃, particle is melted fully be integral body and abundant crystallization, second stage is finished from 1000 ℃ of-1240 ℃ of crystallizatioies, form the material that nucleus, crystalline phase are evenly distributed, the phase III begins progressively to lower the temperature and is cooled to room temperature, and whole firing period is 3-5 hour.
(6), through the demoulding from supporting plate, the polishing after, promptly obtain the marmorean goods of imitative Dark Green of the present invention.
The above, it only is preferred embodiment of the present invention, be not that the present invention is done any pro forma restriction, though the present invention discloses as above with preferred embodiment, yet be not in order to limit the present invention, any those skilled in the art, in not breaking away from the technical solution of the present invention scope, when the technology contents that can utilize above-mentioned announcement is made a little change or is modified to the equivalent embodiment of equivalent variations, in every case be the content that does not break away from technical solution of the present invention, according to technical spirit of the present invention to any simple modification that above embodiment did, equivalent variations and modification all still belong in the scope of technical solution of the present invention.

Claims (9)

1, a kind of three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass is characterized in that: it has by 2-10 kind different color or same color but different color and luster weights of tool or different 2-5000 the area that mixes the clear-cut of the microcrystal glass material that colour cell becomes reach 4cm 2-1m 2Pattern area; And wherein the rarest two kinds of not homochromy districts, each is in the area of the 50%-100% of its pattern area, and thickness reaches 1mm-60mm; And in the rarest 1 color lump pattern area edge 0.1mm-5mm scope, there are ten thousand granular devitrified glasses of 2-1000 of another adjacent look district color to blend in wherein.
2, three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass according to claim 1 is characterized in that: the pattern area of the area of 50%-100% separately of the devitrified glass of the rarest 2 kinds of different colors wherein, its thickness reaches 10mm-60mm.
3, three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass according to claim 1 is characterized in that: within the wherein said pattern colour district, 1-5 kind color is arranged, by 3-1000 area at 1cm 2-150cm 2, the indent crescent shape, the polygonal pattern of being with micro mist material feature, the distance of the concave point of the straight line that two the most outstanding end points of concave crescent shape are linked to be in this and its inner fovea part is 1.5mm-10mm.
4, three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass according to claim 1, it is characterized in that described by 2-10 kind different color or same color but different color and luster weights of tool or different 2-50 pattern area of mixing the clear-cut of the microcrystal glass material that colour cell becomes, to the three dimensions of bottom 70%-100% thickness, also be provided with the piece bulk pattern that 1-5 kind diameter is formed at the colored powder material of 3mm-60mm from the top layer.
5, three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass according to claim 1, it is characterized in that: in the described pattern area, contain the color grains material of 1-5 kind diameter at 1.5mm-30mm, this particle accounts for the 2%-80% of pattern area area.
6, three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass according to claim 1, it is characterized in that: to be the single look of red, yellow, white, blue, black, green, purple, coffee-like class or two kinds mix the color lump of composition or secondary colour and the single look common color lump of forming to multiple colorant grain to described color lump mutually.
7, three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass according to claim 1 is characterized in that: contain mica shape secondary crystallization pattern in the described pattern area material.
8, three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass according to claim 1 is characterized in that: its overall geometry is surface plate shape, cylindrical, cambered plate shape, partial circle cylindricality, hemispherical, awl circle shape hemispherical or the shape of justifying the moulding of shape combinatorial surface by plane and half cone.
9, three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass according to claim 1 is characterized in that its upper strata is a glass-ceramic layer, and lower floor is the structure of porcelain plate.
CNB2005100806381A 2005-07-04 2005-07-04 Three dimension pattern decoration plate for simulating flow rock cross state color micro crystal glass Expired - Fee Related CN100567032C (en)

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CN100567032C true CN100567032C (en) 2009-12-09

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Granted publication date: 20091209

Termination date: 20110704