CN1515155A - Bean cultures after-seedling weedicide multielement composition - Google Patents
Bean cultures after-seedling weedicide multielement composition Download PDFInfo
- Publication number
- CN1515155A CN1515155A CNA031376487A CN03137648A CN1515155A CN 1515155 A CN1515155 A CN 1515155A CN A031376487 A CNA031376487 A CN A031376487A CN 03137648 A CN03137648 A CN 03137648A CN 1515155 A CN1515155 A CN 1515155A
- Authority
- CN
- China
- Prior art keywords
- herbicide
- weed killer
- ethyl
- bentazon
- killer herbicide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 37
- 244000046052 Phaseolus vulgaris Species 0.000 title description 2
- 235000010627 Phaseolus vulgaris Nutrition 0.000 title description 2
- 230000002363 herbicidal effect Effects 0.000 claims abstract description 59
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims abstract description 42
- ZOMSMJKLGFBRBS-UHFFFAOYSA-N bentazone Chemical compound C1=CC=C2NS(=O)(=O)N(C(C)C)C(=O)C2=C1 ZOMSMJKLGFBRBS-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000004009 herbicide Substances 0.000 claims description 84
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 claims description 28
- 241000196324 Embryophyta Species 0.000 claims description 23
- ZWDFMOMBVDVEHE-UHFFFAOYSA-N 1,2-dicyclohexylethane-1,2-dione Chemical compound C1CCCCC1C(=O)C(=O)C1CCCCC1 ZWDFMOMBVDVEHE-UHFFFAOYSA-N 0.000 claims description 12
- IPPAUTOBDWNELX-UHFFFAOYSA-N (2-ethoxy-2-oxoethyl) 5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoate Chemical group C1=C([N+]([O-])=O)C(C(=O)OCC(=O)OCC)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 IPPAUTOBDWNELX-UHFFFAOYSA-N 0.000 claims description 10
- 239000005501 Cycloxydim Substances 0.000 claims description 3
- GGWHBJGBERXSLL-NBVRZTHBSA-N chembl113137 Chemical compound C1C(=O)C(C(=N/OCC)/CCC)=C(O)CC1C1CSCCC1 GGWHBJGBERXSLL-NBVRZTHBSA-N 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- SZXAJDQTPWYNBN-NWBUNABESA-M sodium;4-methoxycarbonyl-5,5-dimethyl-3-oxo-2-[(e)-n-prop-2-enoxy-c-propylcarbonimidoyl]cyclohexen-1-olate Chemical compound [Na+].C=CCO\N=C(/CCC)C1=C([O-])CC(C)(C)C(C(=O)OC)C1=O SZXAJDQTPWYNBN-NWBUNABESA-M 0.000 claims 1
- 239000000575 pesticide Substances 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 4
- 238000009333 weeding Methods 0.000 abstract description 4
- 239000005476 Bentazone Substances 0.000 abstract description 2
- 230000009471 action Effects 0.000 abstract description 2
- CNBGNNVCVSKAQZ-UHFFFAOYSA-N benzidamine Natural products C12=CC=CC=C2C(OCCCN(C)C)=NN1CC1=CC=CC=C1 CNBGNNVCVSKAQZ-UHFFFAOYSA-N 0.000 abstract description 2
- HJSLFCCWAKVHIW-UHFFFAOYSA-N cyclohexane-1,3-dione Chemical compound O=C1CCCC(=O)C1 HJSLFCCWAKVHIW-UHFFFAOYSA-N 0.000 abstract 1
- -1 aryloxy carboxylic acid Chemical class 0.000 description 31
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 22
- 239000003995 emulsifying agent Substances 0.000 description 18
- 239000003814 drug Substances 0.000 description 15
- 239000003795 chemical substances by application Substances 0.000 description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 9
- 235000021374 legumes Nutrition 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- VTNQPKFIQCLBDU-UHFFFAOYSA-N Acetochlor Chemical compound CCOCN(C(=O)CCl)C1=C(C)C=CC=C1CC VTNQPKFIQCLBDU-UHFFFAOYSA-N 0.000 description 8
- 244000068988 Glycine max Species 0.000 description 8
- 239000004480 active ingredient Substances 0.000 description 8
- 244000237956 Amaranthus retroflexus Species 0.000 description 7
- 235000013479 Amaranthus retroflexus Nutrition 0.000 description 7
- 244000025254 Cannabis sativa Species 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 235000010469 Glycine max Nutrition 0.000 description 7
- 238000009472 formulation Methods 0.000 description 7
- 239000004094 surface-active agent Substances 0.000 description 7
- 240000006995 Abutilon theophrasti Species 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 230000008485 antagonism Effects 0.000 description 6
- 239000012752 auxiliary agent Substances 0.000 description 6
- 150000002191 fatty alcohols Chemical class 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 231100000572 poisoning Toxicity 0.000 description 6
- 230000000607 poisoning effect Effects 0.000 description 6
- 229920000151 polyglycol Polymers 0.000 description 6
- 239000010695 polyglycol Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 230000003449 preventive effect Effects 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 210000000481 breast Anatomy 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 5
- 238000009313 farming Methods 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical compound CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- 241000209510 Liliopsida Species 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 239000003905 agrochemical Substances 0.000 description 4
- 239000004927 clay Substances 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 230000004083 survival effect Effects 0.000 description 4
- 239000000375 suspending agent Substances 0.000 description 4
- 238000009736 wetting Methods 0.000 description 4
- 244000105624 Arachis hypogaea Species 0.000 description 3
- 244000025670 Eleusine indica Species 0.000 description 3
- 235000014716 Eleusine indica Nutrition 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 230000003750 conditioning effect Effects 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 235000020232 peanut Nutrition 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- KKDONKAYVYTWGY-UHFFFAOYSA-M sodium;2-(methylamino)ethanesulfonate Chemical compound [Na+].CNCCS([O-])(=O)=O KKDONKAYVYTWGY-UHFFFAOYSA-M 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- 235000017060 Arachis glabrata Nutrition 0.000 description 2
- 235000010777 Arachis hypogaea Nutrition 0.000 description 2
- 235000018262 Arachis monticola Nutrition 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 244000058871 Echinochloa crus-galli Species 0.000 description 2
- 239000004258 Ethoxyquin Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000005600 Propaquizafop Substances 0.000 description 2
- 240000003461 Setaria viridis Species 0.000 description 2
- 235000002248 Setaria viridis Nutrition 0.000 description 2
- 235000010086 Setaria viridis var. viridis Nutrition 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 244000098338 Triticum aestivum Species 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- XCSGPAVHZFQHGE-UHFFFAOYSA-N alachlor Chemical compound CCC1=CC=CC(CC)=C1N(COC)C(=O)CCl XCSGPAVHZFQHGE-UHFFFAOYSA-N 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 230000002528 anti-freeze Effects 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
- 229940077388 benzenesulfonate Drugs 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- HKPHPIREJKHECO-UHFFFAOYSA-N butachlor Chemical compound CCCCOCN(C(=O)CCl)C1=C(CC)C=CC=C1CC HKPHPIREJKHECO-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 239000007957 coemulsifier Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 239000007884 disintegrant Substances 0.000 description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229940093500 ethoxyquin Drugs 0.000 description 2
- 235000019285 ethoxyquin Nutrition 0.000 description 2
- OSUHJPCHFDQAIT-UHFFFAOYSA-N ethyl 2-{4-[(6-chloroquinoxalin-2-yl)oxy]phenoxy}propanoate Chemical group C1=CC(OC(C)C(=O)OCC)=CC=C1OC1=CN=C(C=C(Cl)C=C2)C2=N1 OSUHJPCHFDQAIT-UHFFFAOYSA-N 0.000 description 2
- BYEVBITUADOIGY-UHFFFAOYSA-N ethyl nonanoate Chemical compound CCCCCCCCC(=O)OCC BYEVBITUADOIGY-UHFFFAOYSA-N 0.000 description 2
- VAIZTNZGPYBOGF-CYBMUJFWSA-N fluazifop-P-butyl Chemical group C1=CC(O[C@H](C)C(=O)OCCCC)=CC=C1OC1=CC=C(C(F)(F)F)C=N1 VAIZTNZGPYBOGF-CYBMUJFWSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- IXQGCWUGDFDQMF-UHFFFAOYSA-N o-Hydroxyethylbenzene Natural products CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 description 2
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- FROBCXTULYFHEJ-OAHLLOKOSA-N propaquizafop Chemical compound C1=CC(O[C@H](C)C(=O)OCCON=C(C)C)=CC=C1OC1=CN=C(C=C(Cl)C=C2)C2=N1 FROBCXTULYFHEJ-OAHLLOKOSA-N 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- SXERGJJQSKIUIC-UHFFFAOYSA-N 2-Phenoxypropionic acid Chemical class OC(=O)C(C)OC1=CC=CC=C1 SXERGJJQSKIUIC-UHFFFAOYSA-N 0.000 description 1
- OOLBCHYXZDXLDS-UHFFFAOYSA-N 2-[4-(2,4-dichlorophenoxy)phenoxy]propanoic acid Chemical compound C1=CC(OC(C)C(O)=O)=CC=C1OC1=CC=C(Cl)C=C1Cl OOLBCHYXZDXLDS-UHFFFAOYSA-N 0.000 description 1
- JLYFCTQDENRSOL-UHFFFAOYSA-N 2-chloro-N-(2,4-dimethylthiophen-3-yl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound COCC(C)N(C(=O)CCl)C=1C(C)=CSC=1C JLYFCTQDENRSOL-UHFFFAOYSA-N 0.000 description 1
- WVQBLGZPHOPPFO-UHFFFAOYSA-N 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound CCC1=CC=CC(C)=C1N(C(C)COC)C(=O)CCl WVQBLGZPHOPPFO-UHFFFAOYSA-N 0.000 description 1
- KZNDFYDURHAESM-UHFFFAOYSA-N 2-chloro-n-(2-ethyl-6-methylphenyl)-n-(propan-2-yloxymethyl)acetamide Chemical compound CCC1=CC=CC(C)=C1N(COC(C)C)C(=O)CCl KZNDFYDURHAESM-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 240000006122 Chenopodium album Species 0.000 description 1
- 235000009344 Chenopodium album Nutrition 0.000 description 1
- 239000005497 Clethodim Substances 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 239000005506 Diclofop Substances 0.000 description 1
- 229920005682 EO-PO block copolymer Polymers 0.000 description 1
- DHAHEVIQIYRFRG-UHFFFAOYSA-N Fluoroglycofen Chemical compound C1=C([N+]([O-])=O)C(C(=O)OCC(=O)O)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 DHAHEVIQIYRFRG-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 244000292697 Polygonum aviculare Species 0.000 description 1
- 235000006386 Polygonum aviculare Nutrition 0.000 description 1
- 239000005614 Quizalofop-P-ethyl Substances 0.000 description 1
- CSPPKDPQLUUTND-NBVRZTHBSA-N Sethoxydim Chemical compound CCO\N=C(/CCC)C1=C(O)CC(CC(C)SCC)CC1=O CSPPKDPQLUUTND-NBVRZTHBSA-N 0.000 description 1
- 235000002594 Solanum nigrum Nutrition 0.000 description 1
- 240000002307 Solanum ptychanthum Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- LUZZPGJQJKMMDM-JTQLQIEISA-N [(2s)-1-ethoxy-1-oxopropan-2-yl] 2-chloro-5-[2-chloro-4-(trifluoromethyl)phenoxy]benzoate Chemical group C1=C(Cl)C(C(=O)O[C@@H](C)C(=O)OCC)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 LUZZPGJQJKMMDM-JTQLQIEISA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- VAIZTNZGPYBOGF-UHFFFAOYSA-N butyl 2-(4-{[5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoate Chemical group C1=CC(OC(C)C(=O)OCCCC)=CC=C1OC1=CC=C(C(F)(F)F)C=N1 VAIZTNZGPYBOGF-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical class ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 1
- SILSDTWXNBZOGF-JWGBMQLESA-N clethodim Chemical compound CCSC(C)CC1CC(O)=C(C(CC)=NOC\C=C\Cl)C(=O)C1 SILSDTWXNBZOGF-JWGBMQLESA-N 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical class OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- PQKBPHSEKWERTG-LLVKDONJSA-N ethyl (2r)-2-[4-[(6-chloro-1,3-benzoxazol-2-yl)oxy]phenoxy]propanoate Chemical group C1=CC(O[C@H](C)C(=O)OCC)=CC=C1OC1=NC2=CC=C(Cl)C=C2O1 PQKBPHSEKWERTG-LLVKDONJSA-N 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- BGZZWXTVIYUUEY-UHFFFAOYSA-N fomesafen Chemical compound C1=C([N+]([O-])=O)C(C(=O)NS(=O)(=O)C)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 BGZZWXTVIYUUEY-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- MFSWTRQUCLNFOM-SECBINFHSA-N haloxyfop-P-methyl Chemical group C1=CC(O[C@H](C)C(=O)OC)=CC=C1OC1=NC=C(C(F)(F)F)C=C1Cl MFSWTRQUCLNFOM-SECBINFHSA-N 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- UWNADWZGEHDQAB-UHFFFAOYSA-N i-Pr2C2H4i-Pr2 Natural products CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- CONWAEURSVPLRM-UHFFFAOYSA-N lactofen Chemical compound C1=C([N+]([O-])=O)C(C(=O)OC(C)C(=O)OCC)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 CONWAEURSVPLRM-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- GAIFAPDHLCPUMF-IWIPYMOSSA-N methyl 2-[(e)-[1-[5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrophenyl]-2-methoxyethylidene]amino]oxyacetate Chemical compound C1=C([N+]([O-])=O)C(C(=N\OCC(=O)OC)/COC)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 GAIFAPDHLCPUMF-IWIPYMOSSA-N 0.000 description 1
- BACHBFVBHLGWSL-UHFFFAOYSA-N methyl 2-[4-(2,4-dichlorophenoxy)phenoxy]propanoate Chemical group C1=CC(OC(C)C(=O)OC)=CC=C1OC1=CC=C(Cl)C=C1Cl BACHBFVBHLGWSL-UHFFFAOYSA-N 0.000 description 1
- 229940095102 methyl benzoate Drugs 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229940087419 nonoxynol-9 Drugs 0.000 description 1
- 229920004918 nonoxynol-9 Polymers 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 230000026731 phosphorylation Effects 0.000 description 1
- 238000006366 phosphorylation reaction Methods 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 150000004804 polysaccharides Chemical class 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 239000006041 probiotic Substances 0.000 description 1
- 235000018291 probiotics Nutrition 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- OSUHJPCHFDQAIT-GFCCVEGCSA-N quizalofop-P-ethyl Chemical group C1=CC(O[C@H](C)C(=O)OCC)=CC=C1OC1=CN=C(C=C(Cl)C=C2)C2=N1 OSUHJPCHFDQAIT-GFCCVEGCSA-N 0.000 description 1
- BACHBFVBHLGWSL-JTQLQIEISA-N rac-diclofop methyl Natural products C1=CC(O[C@@H](C)C(=O)OC)=CC=C1OC1=CC=C(Cl)C=C1Cl BACHBFVBHLGWSL-JTQLQIEISA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000003516 soil conditioner Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- FBWNMEQMRUMQSO-UHFFFAOYSA-N tergitol NP-9 Chemical compound CCCCCCCCCC1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 FBWNMEQMRUMQSO-UHFFFAOYSA-N 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention belongs to the field of pesticide, the weedicide composition includes diphenyl ether weedicide, bentazone and hydroresorcinol herbicidal substance. The composition has strong weeding action and good safety for leguminous crops.
Description
The invention belongs to pesticide field, composition specifically of the present invention be diphenyl ether herbicide, Bentazon and at least the 1-2 kind be selected from the composition of aryloxy carboxylic acid, cyclohexyl diketone, acetamide-group herbicides respectively.
Herbicide spraying is missed in the legume field before emerging, spraying cauline leaf processing type weed killer herbicide behind seedling then is that a kind of saving of labor economizes this labour-saving weeding measure.It is little that the hat level of coverage is planted in legume field fertility in early days, grows multiple single, double cotyledon weeds easily, and often herbicidal effect is not good to use single weed killer herbicide.But it is single that existing in the market weed killer herbicide or mixture kind mostly are herbicidal effect, and what have can only prevent and kill off monocotyledon weed, and what have can only prevent and kill off broadleaf weed, therefore demands developing the double weed killer herbicide mixture kind of controlling of single, double cotyledon weeds urgently.
The object of the present invention is to provide a kind of herbicidal composition, it has the double effect of controlling of single, double cotyledon weeds.
The inventor discovers that diphenyl ether herbicide is under the recommended dose of producer, and the spray medicine very easily produces poisoning when summer high temperature, jeopardizes output.Moreover, longer as diphenyl ether herbicide longevities of residure such as prowers, easily late stubble sensitive crops such as rape and wheat are produced residual poisoning.Therefore, in using diphenyl ether herbicide, need further to reduce dosage.After reducing its dosage, in order to improve the broadleaf weed preventive effect, we adopt the method for adding Bentazon to solve.Bentazon is fool proof to legumes such as soybean and peanuts, even tangible poisoning can not take place under the 1-2 of recommended dose (effective dose 48-96 gram/mu) situation doubly, and there is not any residual poisoning in it to succession crop yet.Bentazon has good preventive effect to weeds such as piemarkers, but relatively poor to the preventive effect of weeds such as Amaranthus retroflexus.And diphenyl ether herbicide has good preventive effect to broadleaf weeds such as Amaranthus retroflexus and kitchen gardens.Therefore, Bentazon and diphenyl ether herbicide are used in combination and can remedy the defective that careless spectrum, safety and residual aspect are killed in each leisure.But only this still is not enough to prevent and kill off monocotyledon weed, also need add a kind of problem that solves monocotyledon weed of aryloxy carboxylic acid or cyclohexyl diketone weed killer herbicide in composition.
Under the high situation of legume planting density, diphenyl ether herbicide+Bentazon (bentazone)+at least a kind is selected from the composition of aryloxy carboxylic acid or cyclohexyl diketone weed killer herbicide can disposable solution legume field weed problem, but also need on the basis of above-mentioned triple combination, to add acetamide-group herbicides for the low legume field of planting density, to prolong the lasting period, the growth of control later stage weeds.
Herbicidal composition provided by the invention comprise diphenyl ether herbicide (I), Bentazon (H) and at least the 1-2 kind be selected from aryloxy carboxylic acid (III), cyclohexyl diketone (IV), amide-type (V) weed killer herbicide.Herbicidal composition can be by I+II+III; I+II+IV; I+II+III+V; Four kinds of modes of I+II+IV+V combine, and the weed killer herbicide of every kind gets that it is a kind of.Diphenyl ether herbicide of the present invention can be prowers (fomesafen), fluoroglycofen-ethyl (the fast grass that kills, fluoroglycofen), weeds burn (acifluoffen), restrain wealthy pleasure (lactofen), ethoxyfen-ethyl, AKH-7088, SUAM16476, MON12800 and other diphenyl ether herbicide; Fragrant phenoxy propionic acid class weed killer herbicide of the present invention can be Quizalotop-ethyl (quizalofop-p-ethyl), quizalofop-ethyl (quizalofop-ethyl), prestige despot (fenoxaprop-p-ethyl), fluazifop-p-butyl (fluazifop-p-butyl), surely kill (fluazifop-butyl), haloxyfop-r-methyl (haloxyfoxyfox-R-methyl), cover grass energy (haloxyfoxyfox), diclofop-methyl (diclofop), grass propaquizafop (propaquizafop) and other aryloxy carboxylic acid weed killer herbicide; Cyclohexyl diketone weed killer herbicide of the present invention can be to receive happy logical (clethodim), cycloxydim (cycloxydim), Sethoxydin (sethoxydim) and other cyclohexyl diketone weed killer herbicide.Acetamide-group herbicides of the present invention can be alachlor (alachlor), Acetochlor (acetochlor), butachlor (butachlor), isopropyl methoxalamine (metolachlor), Probiotics (propisochlor), dimethenamid, BayFOE5043, SSH-122, OK8901 and other weed killer herbicide.Above-mentioned known weed killer herbicide is in " newly organized agricultural chemicals handbook, 1989, agriculture publishing house; " newly organized agricultural chemicals handbook (sequel) ", 1998, Chinese agriculture publishing house; " external new varieties of pesticides handbook, 1992, Chemical Industry Press; " the sustainable improvement of Chinese farmland weed geared to the 21st century ", 1999, Guangxi Nationalities Press; Su Shaoquan, the classification of herbicide action target and use, agricultural chemicals, 1998,37 (11): narration is arranged among the 1-7.
Composite weedicide of the present invention can also be with other agricultural chemicals such as weed killer herbicide, insecticide, bactericide, plant growth regulator, have surfactant (synergist), plant nutrient agent, fertilizer, safener, soil conditioner, the colouring agent of synergistic effect to be mixed with into preparation or companion's formula packaged form.
The part by weight of each active ingredient can change in the scope of broad in the herbicidal composition of the present invention.In the formulation: the content range of diphenyl ether herbicides such as I. prowers, fluoroglycofen-ethyl is 0.1-99%, preferable range 0.1-80%; II. the content range of Bentazon is 0.1-99%, preferable range 0.1-90%; III. the content range of aryloxy carboxylic acid or IV. cyclohexyl diketone weed killer herbicide is 0.1-99%, preferable range 0.1-80%; V. the content range of acetamide-group herbicides is 0.1-99%, preferable range 0.1-90%; As prowers 0.1-80%+ Bentazon 0.1-90%+ Quizalotop-ethyl 0.1-80% prowers 0.1-80%+ Bentazon 0.1-90%+ Quizalotop-ethyl 0.1-80%+ Acetochlor 0.1-90%; Fluoroglycofen-ethyl 0.1-80%+ Bentazon 0.1-90%+ Quizalotop-ethyl 0.1-80%; Fluoroglycofen-ethyl 0.1-80%+ Bentazon 0.1-90%+ Quizalotop-ethyl 0.1-80%+ Acetochlor 0.1-90% etc.
Herbicidal composition of the present invention can be applied to legume fields such as soybean, peanut and prevent and kill off single, double cotyledon weeds, as lady's-grass, eleusine indica, barnyard grass grass, green foxtail, piemarker, Amaranthus retroflexus, black nightshade, knotweed, lamb's-quarters etc., but is not limited to above-mentioned weeds.The crop that is suitable for also is not limited to soybean and peanut, can be one or more of legume field.
Utilize the described weed killer herbicide of the invention described above, be equipped with the known auxiliary agent of those skilled in that art, can be made into the composite weedicide of the multiple formulation of the present invention.Herbicidal composition of the present invention can be made with arbitrary regular dosage form.The formulation that can process is: A, missible oil (EC); B, wetting powder (WP); C, dry suspending agent (DF, WG, WDF); D, pulvis (DP); E, aqueous suspension agent (SC); F, oil-suspending agent (OF); G, aqueous emulsion (EW), H, soluble powder I, aqua; J, companion's type preparation etc.
A, missible oil are by active ingredient is dissolved in the organic solvent, and add other auxiliary agent and be processed into.Being used for solvent of the present invention can be one or more compositions among pentane, ether, hydrocarbon alcohol (as ethanol, methyl alcohol), ethyl acetate, chloromethanes, acetone, dimethyl sulfoxide (DMSO), aromatic solvent (as dimethylbenzene, toluene) and the N-long chain hydrocarbon groups pyrroles hydrocarbon ketone etc.; The common consumption of one or more materials that is used for emulsifier of the present invention and is among No. 601, emulsifier, No. 500, emulsifier T-20～emulsifier T-85 series, agricultural newborn 0206-B, farming breast 2201,0201-B is 0.1-30%, preferable amount 1-15%.The present invention also includes synergist penetrant t, JFC, azone, neopelex (ABS), common consumption 0.01-20%, preferable amount 0.1-10%.
B, wetting powder are can homodisperse preparation in water.Wetting powder of the present invention except being added with thinners such as white carbon black, precipitated calcium carbonate, potter's clay, diatomite or inert substance; it also contains ionic or nonionic surface active agent (wetting agent; dispersant); for example: fatty alcohol polyglycol ether sulphate; fatty acid amide N methyl taurine sodium salt; fatty alcohol polyoxyethylene ether sulfate; alkylphenol polyoxyethylene; neopelex (calcium); sodium lignin sulfonate (calcium); among the anionic surfactant such as SOPA one or more, its consumption are 0.1-30%.Also include penetrant t, one or more materials among JFC, azone, neopelex (ABS), the emulsifier T-20～emulsifier T-85 series, content is 0.1-30%, makes wetting powder through grinding and processing.
C, dry suspending agent are with former the effective elements of the medicine, wetting agent, disintegrant, dispersant and adhesive, by forming with the water mixing granulation.Be used for wetting agent of the present invention and can be among the anionic surfactant such as sodium alkyl sulfate, sodium alkyl benzene sulfonate and benzene sulfonic acid sodium salt one or more, its consumption is 0.1-10%.Be used for disintegrant of the present invention and can be among starch and derivative, alginic acid and salt and the clay etc. one or more, consumption is 0.1-20%.Be used for formaldehyde condensation products that dispersant of the present invention and adhesive are lignosulfonates, alkylbenzenesulfonate, alkylnaphthalene sulfonate and one or more materials among the polycarboxylic acid surfactant.Common consumption 3-30%.
D, pulvis are by with active ingredient and finely divided property solid matter such as talcum, and natural clay such as kaolin, nation's soil, precipitated calcium carbonate and pyrophyllite or diatomite, white carbon black grind together to be made, and supplies 100%.
E, aqueous suspension agent are after active ingredient is passed through to add auxiliary agent and synergist, the preparation that process ball milling, sand milling are made.Auxiliary agent of the present invention can be one or more materials among fatty alcohol polyglycol ether sulphate, fatty acid amide N methyl taurine sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, alkylphenol polyoxyethylene sulphate, alkylphenol polyoxyethylene, triphen ethyl-phenol polyoxyethylene, farming breast 2201,0206-B, the emulsifier T-20～emulsifier T-85 series, consumption 0.1-30% usually; The present invention also contains penetrant t, JFC, azone, neopelex (ABS), common consumption 0.1-10%; Ethylene glycol, consumption 0.1-10% usually; CMC, consumption 0.1-10% usually; Xanthans, 0.1-10%; Tributyl phosphate, 0.1-20%.
F, oil-suspending agent are made by former medicine, surfactant adding mineral oil or vegetable oil.Surfactant of the present invention comprises the liquid ester class of dioctyl phthalate, alcohol, fatty acid, alicyclic ring alcohol, as repefral, and butyl ester, diisobutyl ester, two laruyl alcohol esters, two cyclic esters, two cyclohexanols and two ring monooctyl esters etc. also can be used C
6-C
10Carboxylic acid such as positive acetate, certain herbaceous plants with big flowers acid, n-nonanoic acid, benzoic acid and ester, as the benzylacetic acid ester, ethyl acetate, ethyl pelargonate, methyl benzoate or ethyl ester etc., consumption 0.1-30% usually.Can be as emulsifier: fatty alcohol polyglycol ether sulphate; fatty acid amide N methyl taurine sodium salt; sodium sulfate of polyethenoxy ether of fatty alcohol; alkylphenol polyoxyethylene sulphate; alkylphenol polyoxyethylene; sodium alkyl benzene sulfonate (calcium), sodium lignin sulfonate (calcium), consumption 0.1-30% usually.
G, aqueous emulsion (EW): contain active ingredient, solvent, emulsifier or dispersant, co-emulsifier, water, antifreeze, defoamer, antimicrobial, density adjuster, PH conditioning agent, thickener, colouring agent and smell conditioning agent usually.Wherein have plenty of necessaryly, what have is not essential.Wherein, solvent can be used on the solvent of mentioning in the above-mentioned missible oil; With the mixture (as Pluronic F108, L62, L72) of ethylene oxide-propylene oxide block copolymer, ethoxyquin alkyl phenylate, ethoxyquin alkyl ether, alkyl benzene calcium sulfonate, oxirane-fat primary amine contract and contain the triethanolamine salt of thing or its mixture, Nonoxynol-9, alkyl polyglycol ether, alkyl phenyl polyglycol ether, polyoxyethylene sorbitol acid anhydride ester, polyoxyethylene fatty acid, phenol polyglycol ether phosphate monoester or monoester and diester mixture emulsifier; Dispersant available polyethylene alcohol, gum Arabic; Co-emulsifier can use butanols, isobutanol, alkane alcohols; Antifreeze can make spent glycol, propane diols, glycerine, urea, sulfuric acid amine, Nacl, CaCl
2Deng; Defoamer can use silicone defoaming agent; The PH conditioning agent can be with general inorganic or organic acids and base, phosphorylation surfactant; Density adjuster can use Nacl, CaCl
2, mineral salt, urea; Thickener can use polyacrylate, natural polysaccharide, inorganic thickening agent, but also can use sometimes.
H, soluble powder: preparation is made up of former medicine, filler and auxiliary agent.Filler can be with water miscible mineral salt (as sodium sulphate, sulfuric acid amine etc.), and also available water-fast filler is (as clay, white carbon black, CaCO
3Deng); Auxiliary agent is anionic, nonionic surface active agent or both mixtures mostly, as alkylaryl polyoxyethylene groups ether, aliphatic alcohol polyethenoxy base ether, alkylbenzenesulfonate, lignosulfonates etc.
I, aqua: the former medicine of each weed killer herbicide is dissolved in organic solvent, adds suitable quantity of water then and emulsifier is made.Organic solvent can be the organic solvent mentioned in the missible oil of the present invention and dimethyl formamide etc.; Emulsifier can be that the emulsifier mentioned in the missible oil of the present invention is as No. 601, No. 500, emulsifier T-20 one or more materials among emulsifier T-85 series, agricultural newborn 0206-B, farming breast 2201,0201-B, usually consumption is 0.1-10%, preferable amount 1-5%.Also can contain penetrant t, JFC, azone, neopelex synergist such as (ABS) in the aqua, common consumption 0.1-15%, preferable amount 0.5-10%.
J, companion's type preparation: the 3-4 kind active ingredient that contains in the present composition can adopt the above-mentioned various formulations of pesticide of mentioning to be mixed with unitary agent respectively, makes companion's type packing then, now mixes existing using during use; Also can adopt the above-mentioned various formulations of pesticide of mentioning be mixed with binary mixture composition of the present invention two kinds of active ingredients wherein, and then with composition of the present invention in the unitary agent or the binary mixture of the other 1-2 kind active ingredient mentioned be combined into companion's type preparation.Make binary mixture as prowers (or fluoroglycofen-ethyl) and Bentazon, Quizalotop-ethyl is made unitary agent, and both are combined into companion's type preparation.
The present invention has compared following advantage than prior art:
1, broad weed-killing spectrum.Adopt Bentazon and diphenyl ether herbicide to prevent and kill off broadleaf weeds such as piemarker, kitchen garden, Amaranthus retroflexus; Unifacial leaf agent for preventing and eliminating (comprising aryloxy carboxylic acid and cyclohexyl diketone weed killer herbicide) such as employing Quizalotop-ethyl are prevented and kill off grassy weeds such as eleusine indica, lady's-grass, barnyard grass grass, green foxtail, have solved the monocotyledon weed and the broadleaf weed in legume field simultaneously.
2, improved safety.Bentazon is fool proof to soybean, even under the 1-2 of recommended dose (96g ai./mu) situation doubly, also can not produce the poisoning to soybean.Diphenyl ether herbicides such as it and prowers, fluoroglycofen-ethyl are used with, and the diphenyl ether herbicide medication is descended, and have improved the safety of soybean.
3, the longevity of residure is moderate.Diphenyl ether herbicide such as prowers, fluoroglycofen-ethyl still might produce poisoning to succession crops such as rape, wheats at recommended dose (as prowers 25-33g ai./mu).By using with, can reduce its dosage, safer to second stubble crop.In preparation, add acetamide-group herbicides such as Acetochlor and help prolonging the lasting period, be suitable for the soybean field piece that density is less, the envelope ridge is later and use.
4, mu weeding cost reduces.Diphenyl ether herbicide costs such as prowers are higher.Can reduce its dosage by rationally using with, help the reduction of weeding cost.
5, polynary synergistic effect (seeing biologicall test embodiment table 1-2) of using with to a certain degree.
Formulation Example:
Former medicine 1.25 1.25 2.5 2.5 acetochlor tc-10-10 dimethylbenzene of former medicine 15 15 20 20 Quizalotop-ethyls of embodiment 1 embodiment 2 embodiment former medicine 3.75 3.75 7.5 7.5 Bentazons of 3 embodiment, 4 prowers 50 40 40 30 acetone 20 18 20 16 farming breasts 2,201 5656 emulsifying agent T-80 4.8 53 4ABS 0.2 124
Former medicine 1.25 1.25 2.5 2.5 acetochlor tc-10-10 dimethylbenzene of former medicine 15 15 20 20 Quizalotop-ethyls of embodiment 1 embodiment 2 embodiment former medicine 0.75 0.75 1.5 1.5 Bentazon of 3 embodiment, 4 fluoroglycofen-ethyls 53 43 40 35 acetone 20 18 20 16 farming breasts 2,201 5567 emulsifying agent T-80 4.5 545 azones 0.5 263
Take by weighing each amount of substance according to the foregoing description,, can make different missible oil of the present invention with the method that those skilled in that art know.The embodiment of other formulation of the present invention does not enumerate one by one at this.
Biologicall test embodiment:
See Table 1-3.Analyze from table 2, the synergy percentage that adds up is 58.4, and the antagonism percentage that adds up is 23.4, both average synergy 35.0.The frequency that synergistic effect occurs is 66.7, and the frequency that antagonism occurs is 33.3.When low dosage, the frequency height of antagonism appears; When high dose, the frequency that antagonism occurs is low.And in actual applications, use high dose more.From field trial table 3 as seen, each medicament list with and binary use equal preventive effects of using with not as ternary or quaternary with.Therefore, prescription of the present invention is feasible in actual applications.
The weeds survival rate of table 1, different disposal (natural conditions, potted plant)
| Medicament | Dosage g ai./mu | Weeds survival rate (%) | ||||
| Piemarker | Amaranthus retroflexus | Kitchen garden | Eleusine indica | Add up to | ||
| Bentazon (B) | ?????6 | ????87.0 | ????60.5 | ????61.2 | ????100 | ????75.1 |
| Bentazon | ????12 | ????69.1 | ????45.0 | ????58.2 | ????82.9 | ????59.1 |
| Bentazon | ????18 | ????47.5 | ????39.2 | ????22.3 | ????90.9 | ????35.4 |
| Quizalotop-ethyl (Q) | ????0.5 | ????82.9 | ????83.1 | ????100 | ????25.9 | ????68.4 |
| Quizalotop-ethyl | ????1.0 | ????82.6 | ????82.3 | ????94.2 | ????22.1 | ????70.4 |
| Quizalotop-ethyl | ????1.5 | ????82.1 | ????82.8 | ????87.4 | ????2.9 | ????66.8 |
| Prowers (F) | ????1.5 | ????79.5 | ????30.4 | ????55.3 | ????76.2 | ????45.3 |
| Prowers | ????3.0 | ????69.8 | ????22.9 | ????58.3 | ????73.7 | ????47.8 |
| Prowers | ????4.5 | ????68.4 | ????19.5 | ????19.4 | ????61.2 | ????42.7 |
| ???B+Q+F | ????6+0.5+ ????1.5 | ????45.5 | ????26.1 | ????35.9 | ????18.7 | ????30.9 |
| ???B+Q+F | ????12+1.0+ ????3.0 | ????34.9 | ????10.9 | ????12.6 | ????8.7 | ????18.3 |
| ???B+Q+F | ????18+1.5+ ????4.5 | ????23.9 | ????1.6 | ????6.8 | ????3.7 | ????5.8 |
Table 2, Colby method result of calculation
| Medicament g ai./mu | Piemarker | Amaranthus retroflexus | Kitchen garden | Cowhells | Add up to | |||||
| ??E | ??E 0 | ??E | ??E 0 | ??E | ??E 0 | ??E | ??E 0 | ??E | ??E 0 | |
| ??B6+Q0.5+ ??F1.5 | ??65.9 | ??45.5+ | ??15.3 | ??26.1- | ??33.8 | ??35.9- | ??19.7 | ??18.7+ | ??23.3 | ??30.9- |
| ??B12+ ??Q1.0+F3.0 | ??39.8 | ??34.9+ | ??8.5 | ??10.9- | ??32.0 | ??12.6+ | ??13.5 | ??8.7+ | ??19.6 | ??18.3+ |
| ??B18+Q1.5 ??+F4.5 | ??26.7 | ??23.9+ | ??4.1 | ??1.6+ | ??9.4 | ??6.8+ | ??1.6 | ??3.7- | ??10.1 | ??5.8+ |
Annotate: the B=Bentazon; The Q=Quizalotop-ethyl; The F=prowers; The theoretical value of E=survival rate; E
0The observed value of survival rate; E＞E
0Be synergy, E＜E
0Be antagonism; E
0"+" expression synergy after the value, E
0"-" expression antagonism after the value.
Table 3, mixture are prevented and kill off soybean weeds effect (Shunyi, Beijing, 2000)
| The weed killer herbicide kind | Dosage (g ai./mu) | Preventive effect (%) | ||||
| Lady's-grass | Amaranthus retroflexus | Kitchen garden | Piemarker | Add up to | ||
| Quizalotop-ethyl | ????2.5 | ????96.5 | ????9.3 | ????44.0 | ????11.1 | ????40.2 |
| Bentazon | ????30 | ????0 | ????84.2 | ????100 | ????100 | ????71.1 |
| Prowers | ????8.5 | ????56.0 | ????89.5 | ????100 | ????7.5 | ????80.1 |
| ????B+Q | ????30+2.5 | ????96.9 | ????54.3 | ????98.3 | ????89.7 | ????84.8 |
| ????Q+F | ????1.5+7 | ????88 | ????84.2 | ????83.3 | ????100 | ????88.9 |
| ?F+B+Q (20％EC) | ????7.5+30+ ????2.5 | ????99.5 | ????99.3 | ????99.7 | ????99.7 | ????99.5 |
| ?F+B+Q+C (30％EC) | ????7.5+30+ ????2.5+20 | ????99.7 | ????99.5 | ????99.6 | ????99.7 | ????99.6 |
| The fast grass that kills | ????1.5 | ????36.3 | ????90.5 | ????99.9 | ????99.5 | ????83.9 |
| ?K+B+Q (17％EC) | ????1.5+30+ ????2.5 | ????98.2 | ????99.3 | ????100 | ????100 | ????99.4 |
| ?K+B+Q+C (27％EC) | ????1.5+30+ ????2.5+20 | ????99.1 | ????100 | ????100 | ????100 | ????99.8 |
Annotate: the B=Bentazon; The Q=Quizalotop-ethyl; The F=prowers; The C=Acetochlor; K=fluoroglycofen-ethyl (the fast grass that kills).
Claims (6)
1. herbicidal composition, said composition contains diphenyl ether herbicide, Bentazon and cyclohexyl diketone weed killer herbicide.
2. weed killer herbicide according to claim 1 is characterized in that diphenyl ether herbicide can be that wealthy pleasure and other diphenyl ether herbicide are burnt, restrained to prowers, fluoroglycofen-ethyl, weeds.
3. weed killer herbicide according to claim 1 is characterized in that the cyclohexyl diketone weed killer herbicide can be Sethoxydin, receive happy logical, cycloxydim, alloxydimsodium and other cyclohexyl diketone weed killer herbicide.
4. composite weedicide according to claim 1 is characterized in that containing: diphenyl ether herbicide 0.1-80% (percentage by weight, down together)+Bentazon 0.1-90%+ cyclohexyl diketone weed killer herbicide 0.1-80%.
5. weed killer herbicide according to claim 1 is characterized in that containing: prowers 0.1-80%+ Bentazon 0.1-90%+ Sethoxydin 0.1-80%.
6. weed killer herbicide according to claim 1 is characterized in that containing: fluoroglycofen-ethyl 0.1-80%+ Bentazon 0.1-90%+ Sethoxydin 0.1-80%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA031376487A CN1515155A (en) | 2001-01-11 | 2001-01-11 | Bean cultures after-seedling weedicide multielement composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA031376487A CN1515155A (en) | 2001-01-11 | 2001-01-11 | Bean cultures after-seedling weedicide multielement composition |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011005270A Division CN1164175C (en) | 2001-01-11 | 2001-01-11 | Multi-element composition as herbicide after seedling stage for bean crops |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1515155A true CN1515155A (en) | 2004-07-28 |
Family
ID=34240112
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA031376487A Pending CN1515155A (en) | 2001-01-11 | 2001-01-11 | Bean cultures after-seedling weedicide multielement composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1515155A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101822261A (en) * | 2010-05-12 | 2010-09-08 | 孟凡刚 | Herbicide for bean field and preparation method thereof |
| CN102265864A (en) * | 2010-06-03 | 2011-12-07 | 南京华洲药业有限公司 | Mixed herbicide containing bentazone, acifluorfen and sethoxydim and application thereof |
| CN103749448A (en) * | 2013-12-25 | 2014-04-30 | 山东滨农科技有限公司 | Weed killer composition containing clethodim and ethoxyfen |
-
2001
- 2001-01-11 CN CNA031376487A patent/CN1515155A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101822261A (en) * | 2010-05-12 | 2010-09-08 | 孟凡刚 | Herbicide for bean field and preparation method thereof |
| CN102265864A (en) * | 2010-06-03 | 2011-12-07 | 南京华洲药业有限公司 | Mixed herbicide containing bentazone, acifluorfen and sethoxydim and application thereof |
| CN103749448A (en) * | 2013-12-25 | 2014-04-30 | 山东滨农科技有限公司 | Weed killer composition containing clethodim and ethoxyfen |
| CN103749448B (en) * | 2013-12-25 | 2016-03-02 | 山东滨农科技有限公司 | Herbicidal composition containing clethodim and ethoxyfenethyl |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1317241A (en) | Composition of bensultap and herbicide for monocotyledonous weeds | |
| CN101861867A (en) | Pesticide compound containing penoxsulam and cyhalofop-butyl and application thereof | |
| CN1164175C (en) | Multi-element composition as herbicide after seedling stage for bean crops | |
| CN103338639B (en) | Insecticidal composition comprising sulphur, acaricide and agrochemical excipients | |
| CN106342853B (en) | Plant growth regulator composition with synergistic effect | |
| CN104068024B (en) | A kind of herbicidal composition and application thereof | |
| CN101773142A (en) | Herbicide composition containing glufosinate and oxadiazon and application thereof | |
| CN103783076B (en) | A kind of mixed herbicide containing glyphosate, two careless ether and methoxone and application thereof | |
| CN104430357A (en) | Bactericide composition containing coumoxystrobin with synergistic effect | |
| CN102669181A (en) | Sterilization composition containing captan and copper calcium sulfate and application of sterilization composition | |
| CN101617653B (en) | Compound herbicide composition | |
| CN104488914A (en) | Complex herbicide for rice field | |
| CN102150671A (en) | Bactericide composition and preparation and application thereof | |
| CN102150656A (en) | Bactericide composition, preparation and application thereof | |
| CN105265446B (en) | A kind of composition pesticide containing alkene oxime amine and tetraconazole | |
| CN101617654A (en) | Herbicide composition containing mesotrione and nicosulfuron | |
| CN103392715B (en) | A kind of bactericidal composition containing cyprodinil and captan | |
| CN1515155A (en) | Bean cultures after-seedling weedicide multielement composition | |
| CN102204530A (en) | Imidacloprid suspension | |
| CN100396181C (en) | Weeding composition, its application and method | |
| CN103348990B (en) | Bactericidal composition containing mandipropamid and captan | |
| KR101915411B1 (en) | Herbicide compositions for controlling pests of horticultural products comprising rare-earth elements as active ingredients | |
| CN102131391A (en) | Crop safeners | |
| CN100548125C (en) | Fluometuron and amide herbicide composition | |
| CN110250190A (en) | A kind of composition, preparation and its application, preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |