CN112519416B - Ink jet recording apparatus and ink jet recording method - Google Patents
Ink jet recording apparatus and ink jet recording method Download PDFInfo
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- CN112519416B CN112519416B CN202010983607.1A CN202010983607A CN112519416B CN 112519416 B CN112519416 B CN 112519416B CN 202010983607 A CN202010983607 A CN 202010983607A CN 112519416 B CN112519416 B CN 112519416B
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- water
- ink composition
- printing ink
- recording apparatus
- dye
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- IHVXOVVDYSKGMH-UHFFFAOYSA-K trisodium 2-[[6-[(4-amino-6-chloro-1,3,5-triazin-2-yl)-methylamino]-1-hydroxy-3-sulfonatonaphthalen-2-yl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].CN(c1ccc2c(O)c(N=Nc3ccc4c(cccc4c3S([O-])(=O)=O)S([O-])(=O)=O)c(cc2c1)S([O-])(=O)=O)c1nc(N)nc(Cl)n1 IHVXOVVDYSKGMH-UHFFFAOYSA-K 0.000 description 1
- VRVDFJOCCWSFLI-UHFFFAOYSA-K trisodium 3-[[4-[(6-anilino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-5-methoxy-2-methylphenyl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].COc1cc(N=Nc2cc(c3cccc(c3c2)S([O-])(=O)=O)S([O-])(=O)=O)c(C)cc1N=Nc1c(O)c2ccc(Nc3ccccc3)cc2cc1S([O-])(=O)=O VRVDFJOCCWSFLI-UHFFFAOYSA-K 0.000 description 1
- WDWBPYFNRWQKNZ-UHFFFAOYSA-K trisodium 5-[(4-anilino-6-chloro-1,3,5-triazin-2-yl)amino]-4-hydroxy-3-[(2-sulfonatophenyl)diazenyl]naphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=CC(NC=3N=C(NC=4C=CC=CC=4)N=C(Cl)N=3)=C2C(O)=C1N=NC1=CC=CC=C1S([O-])(=O)=O WDWBPYFNRWQKNZ-UHFFFAOYSA-K 0.000 description 1
- ZUCXUTRTSQLRCV-UHFFFAOYSA-K trisodium;1-amino-4-[3-[[4-chloro-6-(3-sulfonatoanilino)-1,3,5-triazin-2-yl]amino]-2,4,6-trimethyl-5-sulfonatoanilino]-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].CC1=C(S([O-])(=O)=O)C(C)=C(NC=2C=3C(=O)C4=CC=CC=C4C(=O)C=3C(N)=C(C=2)S([O-])(=O)=O)C(C)=C1NC(N=1)=NC(Cl)=NC=1NC1=CC=CC(S([O-])(=O)=O)=C1 ZUCXUTRTSQLRCV-UHFFFAOYSA-K 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000007601 warm air drying Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0023—Digital printing methods characterised by the inks used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J3/00—Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed
- B41J3/407—Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed for marking on special material
- B41J3/4078—Printing on textile
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/328—Inkjet printing inks characterised by colouring agents characterised by dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
- D06P1/6491—(Thio)urea or (cyclic) derivatives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/90—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Ink Jet (AREA)
- Coloring (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Treatment Of Fiber Materials (AREA)
Abstract
An object of the present invention is to provide an ink jet recording apparatus and an ink jet recording method, which are excellent in clogging recovery and capable of forming a high-density image with less blurring. An inkjet recording apparatus includes a textile printing ink composition containing a water-soluble dye, a water-soluble organic solvent, and water, and a liquid ejecting head having nozzles for ejecting the textile printing ink composition, wherein the content of the water-soluble dye is 10% by mass or more relative to the total amount of the textile printing ink composition, and the liquid ejecting head has the nozzles for ejecting the textile printing ink composition, a pressure chamber to which the textile printing ink composition is supplied, and a circulation flow path through which the textile printing ink composition in the pressure chamber can circulate.
Description
Technical Field
The present invention relates to an ink jet recording apparatus and an ink jet recording method.
Background
The ink jet recording method enables high-definition image recording with a relatively simple apparatus, and is rapidly developed in various aspects. Among them, various studies have been made on image quality and the like. For example, patent document 1 discloses an ink containing an acid dye, two types of nonionic surfactants, and water, for the purpose of providing an acid dye ink having a high dyeing concentration and causing no uneven dyeing, and a method for printing fibers using the same.
Patent document 1: japanese patent laid-open publication No. 2017-110096
However, when the dye concentration is increased for the purpose of increasing the dyeing concentration as described in patent document 1, the content of the solvent in the ink is relatively decreased. Therefore, it was found that the ink was liable to solidify and the clogging recovery was poor.
Disclosure of Invention
The present invention is an inkjet recording apparatus including a textile printing ink composition and a liquid ejecting head, the liquid ejecting head having nozzles for ejecting the textile printing ink composition, the textile printing ink composition containing a water-soluble dye, a water-soluble organic solvent, and water, the water-soluble dye being contained in an amount of 10 mass% or more relative to the total amount of the textile printing ink composition, the liquid ejecting head having the nozzles for ejecting the textile printing ink composition, a pressure chamber to which the textile printing ink composition is supplied, and a circulation flow path through which the textile printing ink composition in the pressure chamber can circulate.
Preferably, in the inkjet recording apparatus, the water-soluble dye is an acid dye, a reactive dye, or a direct dye.
Preferably, in the inkjet recording apparatus, a content of the water-soluble dye is 20% by mass or more with respect to a total amount of the printing ink composition.
Preferably, in the inkjet recording apparatus, the water-soluble organic solvent includes a first water-soluble organic solvent having a vapor pressure of 1Pa or more at 20 ℃ and a second water-soluble organic solvent having a vapor pressure of less than 1Pa at 20 ℃.
Preferably, in the inkjet recording apparatus, a content ratio of the second water-soluble organic solvent to the first water-soluble organic solvent is 0.02 to 2 on a mass basis.
Preferably, in the inkjet recording apparatus, the textile printing ink composition contains urea.
Preferably, in the inkjet recording apparatus, a content ratio of the urea to the water-soluble dye is 0.1 to 0.3 on a mass basis.
Preferably, in the inkjet recording apparatus, the dye is at least one of acid blue 138, acid blue 290, acid violet 54, acid orange 116, reactive yellow 15, reactive red 123, or reactive blue 222.
The ink jet method of the present invention is an ink jet method including: the ink jet recording apparatus includes an ejection step of ejecting a textile printing ink composition containing a water-soluble dye, a water-soluble organic solvent, and water, the water-soluble dye being contained in an amount of 10% by mass or more relative to the total amount of the textile printing ink composition, by using a liquid ejection head having the nozzles for ejecting the textile printing ink composition, a pressure chamber to which the textile printing ink composition is supplied, and a circulation flow path through which the textile printing ink composition in the pressure chamber can be circulated.
Drawings
Fig. 1 is a schematic diagram for explaining a structure of a liquid ejection head that can be used in the present embodiment.
Fig. 2 is a perspective view showing a serial type inkjet recording apparatus of the present embodiment.
Description of the symbols
1. A nozzle; 2. a pressure chamber; 3. a circulation flow path; 4. a communication path; 10. a liquid ejection head; 20. a serial printer; 220. a conveying section; 230. a recording unit; 231. an ink jet head; 234. a carriage; 235. a carriage moving mechanism; F. a recording medium; s1, S2, main scanning direction; t1, T2, sub scanning direction.
Detailed Description
Hereinafter, an embodiment of the present invention (hereinafter, referred to as "the present embodiment") will be described in detail with reference to the drawings as necessary, but the present invention is not limited thereto and various modifications can be made without departing from the gist thereof. In the drawings, the same elements are denoted by the same reference numerals, and redundant description thereof is omitted. In addition, positional relationships such as up, down, left, and right are based on the positional relationships shown in the drawings unless otherwise specified. The dimensional ratio of the drawings is not limited to the illustrated scale.
1. Ink jet recording apparatus
The inkjet recording apparatus of the present embodiment includes a textile printing ink composition and a liquid ejecting head that ejects the textile printing ink composition. The liquid ejecting head has nozzles for ejecting the printing ink composition, pressure chambers to which the printing ink composition is supplied, and a circulation flow path through which the printing ink composition in the pressure chambers can circulate.
The ink jet recording apparatus of the present embodiment is a recording apparatus that ejects a textile printing ink composition containing a large amount of water-soluble dye, and may have an ink container that contains the textile printing ink composition, and an ink flow path that connects the ink container and a liquid ejecting head. The ink jet recording apparatus of the present embodiment includes a predetermined liquid ejecting head, and thus can suppress clogging and maintain clogging recovery even in a printing ink composition containing a large amount of a water-soluble dye. Therefore, a recorded matter having high color developability can be produced from the printing ink composition containing a large amount of the water-soluble dye.
1.1. Liquid ejection head
As shown in fig. 1, the liquid ejecting head includes a nozzle 1, a pressure chamber 2 to which a printing ink composition is supplied, and a circulation flow path 3 through which the composition in the pressure chamber 2 can circulate. This enables the printing ink composition to be circulated in the head, and the ink composition in the vicinity of the nozzles to be prevented from being cured, thereby obtaining a recorded matter having a high color development.
The liquid ejecting head may have a heating portion for heating the printing ink composition in the head. The position of the heating unit is not particularly limited as long as the heating unit can heat the composition in the circulation path including the pressure chamber 2 and the circulation flow path 3, and the heating unit can be provided in, for example, the liquid ejecting head and/or the ink flow path. When the liquid ejecting head is provided with the heating portion, the heating portion may be provided in either the pressure chamber or the circulation flow path. In the ink jet recording apparatus of the present embodiment, the printing ink composition is preferably filled in the ink flow path or the ink tank.
Fig. 2 is a perspective view of a serial printer as an example of an inkjet recording apparatus. As shown in fig. 2, the serial printer 20 includes a conveying unit 220 and a recording unit 230. The transport unit 220 transports the recording medium F supplied to the serial printer to the recording unit 230, and discharges the recorded recording medium to the outside of the serial printer. Specifically, the conveying unit 220 includes conveying rollers and conveys the recording medium F conveyed thereto in the sub-scanning direction T2. The conveying unit may be an endless belt, or may include a winding roller on the downstream side in the sub-scanning direction.
The recording unit 230 includes an inkjet head 231 for ejecting a composition onto the recording medium F sent from the transport unit 220, a carriage 234 on which the inkjet head is mounted, and a carriage moving mechanism 235 for moving the carriage 234 in the main scanning directions S1 and S2 of the recording medium F.
In the case of a serial printer, a head having a length smaller than the width of a recording medium is provided as the inkjet head 231, and the head moves to perform recording in a plurality of paths (multi-path). In addition, in the serial printer, a head 231 is mounted on a carriage 234 that moves in a predetermined direction, and the composition is discharged onto a recording medium by the head moving in accordance with the movement of the carriage. Thereby, recording is performed in 2 or more paths (multipath). Further, the path is also referred to as main scanning. The sub-scanning for conveying the recording medium is performed from path to path. That is, the main scanning and the sub-scanning are alternately performed.
The inkjet recording apparatus according to the present embodiment is not limited to the serial printer described above, and may be a line printer described above.
1.2. Printing ink composition
The printing ink composition contains a water-soluble dye, a water-soluble organic solvent and water, and may contain urea, a surfactant, a pH adjuster, and other additives as required.
1.2.1. Water-soluble dyes
The water-soluble dye is not particularly limited, and examples thereof include an acid dye, a reactive dye, and a direct dye. One dye may be used alone, or two or more dyes may be used in combination.
The acid dye is not particularly limited, and examples thereof include c.i. acid yellow, c.i. acid red, c.i. acid blue, c.i. acid orange, c.i. acid violet, and c.i. acid black.
The direct dye is not particularly limited, and examples thereof include c.i. direct yellow, c.i. direct red, c.i. direct blue, c.i. direct orange, c.i. direct violet, and c.i. direct black.
The reactive dye is not particularly limited, and examples thereof include c.i. reactive yellow, c.i. reactive red, c.i. reactive blue, c.i. reactive orange, c.i. reactive violet, and c.i. reactive black.
Among them, as the water-soluble dye, at least one of acid blue 138, acid blue 290, acid violet 54, acid orange 116, reactive yellow 15, reactive red 123, and reactive blue 222 is preferably used. Such a water-soluble dye tends to be easily deteriorated in clogging recovery property because of high wet fastness and low solubility in water. Therefore, the present invention is particularly effective.
The content of the water-soluble dye is 10% by mass or more, more preferably 12% by mass or more, still more preferably 15% by mass or more, and particularly preferably 20% by mass or more, based on the total amount of the printing ink composition. The preferable lower limit of the content of the water-soluble dye may vary depending on the kind of the water-soluble dye. The coloring material penetrates into the middle and back of the fiber during printing. Therefore, by setting the content of the water-soluble dye to 10% by mass or more, a recorded matter having high color developability can be produced. In particular, for black dyes, there is a tendency that a higher concentration of water-soluble dyes is required.
When the content of the water-soluble dye is increased, the amount of the water-soluble organic solvent and water contained in the printing ink composition is relatively decreased, and the ink composition tends to be easily solidified, thereby reducing the clogging recovery property. In contrast, in the present embodiment, by using the liquid ejecting head having the above-described configuration, the clogging recovery property can be maintained by circulating the printing ink composition in the liquid ejecting head.
The upper limit of the content of the water-soluble dye is not particularly limited, and is preferably 35% by mass or less, more preferably 30% by mass or less, and still more preferably 25% by mass or less, relative to the total amount of the printing ink composition. The preferable upper limit of the content of the water-soluble dye may vary depending on the kind of the water-soluble dye. When the content of the water-soluble dye is 35% by mass or less, the clogging recovery property tends to be further improved.
1.2.2. Water soluble organic solvent
The water-soluble organic solvent is not particularly limited, and examples thereof include glycerin; lower alcohols such as methanol, ethanol, 1-propanol, isopropanol, 1-butanol, 2-butanol, isobutanol, 2-methyl-2-propanol, 1, 3-butanediol, 2-methyl-1, 3-propanediol, 3-methyl-1, 5-pentanediol, and 1, 2-hexanediol; glycols such as ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, pentaethylene glycol, propylene glycol, dipropylene glycol, and tripropylene glycol; glycol derivatives such as diethylene glycol monobutyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, triethylene glycol monopropyl ether, triethylene glycol monobutyl ether, tetraethylene glycol monomethyl ether, tetraethylene glycol monoethyl ether, tetraethylene glycol dimethyl ether and tetraethylene glycol diethyl ether; cyclic amide compounds such as 2-pyrrolidone, N-methyl-2-pyrrolidone, and N-ethyl-2-pyrrolidone. The water-soluble organic solvent may be used alone in 1 kind, or may be used in combination in 2 or more kinds.
The content of the water-soluble organic solvent is preferably 15 to 60% by mass, more preferably 20 to 55% by mass, and still more preferably 25 to 50% by mass, based on the total amount of the printing ink composition. When the content of the water-soluble organic solvent is 15% by mass or more, the water-soluble dye having low solubility in water can be dissolved, and a printing ink composition containing the dye at a high concentration tends to be obtained. Further, when the content of the water-soluble organic solvent is 60% by mass or less, a rapid increase in viscosity due to water volatilization can be suppressed, and clogging recovery tends to be further improved.
Among them, the water-soluble organic solvent preferably contains a first water-soluble organic solvent having a vapor pressure at 20 ℃ of 1Pa or more and a second water-soluble organic solvent having a vapor pressure at 20 ℃ of less than 1 Pa. Since the viscosity of the first water-soluble organic solvent is low, the use of the first water-soluble organic solvent tends to further improve the fluidity of the printing ink composition and further improve the clogging recovery property. Further, since the second water-soluble organic solvent has low volatility, the use of the second water-soluble organic solvent tends to further improve the fluidity of the printing ink composition and further improve the clogging recovery property.
Examples of the first water-soluble organic solvent include, but are not particularly limited to, propylene glycol, diethylene glycol, 1, 2-hexanediol, 1, 3-butanediol, diethylene glycol monobutyl ether, 2-methyl-1, 3-propanediol, and 2-pyrrolidone. The first water-soluble organic solvent may be used alone in 1 kind, or may be used in combination in 2 or more kinds.
The content of the first water-soluble organic solvent is preferably 7 to 45% by mass, more preferably 10 to 40% by mass, and still more preferably 10 to 30% by mass, based on the total amount of the printing ink composition. When the content of the first water-soluble organic solvent is in the above range, the clogging recovery property tends to be further improved.
The second water-soluble organic solvent is not particularly limited, and examples thereof include glycerin, triethylene glycol, 3-methyl-1, 5-pentanediol, and triethylene glycol monobutyl ether. The second water-soluble organic solvent may be used alone in 1 kind, or may be used in combination in 2 or more kinds.
The content of the second water-soluble organic solvent is preferably 0.1 to 40% by mass, more preferably 5 to 35% by mass, and still more preferably 10 to 30% by mass, based on the total amount of the printing ink composition. When the content of the second water-soluble organic solvent is in the above range, the clogging recovery property tends to be further improved.
The content ratio of the second water-soluble organic solvent to the first water-soluble organic solvent is preferably 0.01 to 2.5, more preferably 0.02 to 2, and still more preferably 0.5 to 2 on a mass basis. The viscosity of the printing ink composition may increase rapidly due to the circulation of the ink in which a small amount of water evaporates from the nozzle portion, and the clogging recovery property may be impaired. However, when the content ratio of the second water-soluble organic solvent to the first water-soluble organic solvent is in the above range, such a viscosity increase can be suppressed, and the clogging recovery property tends to be further improved.
1.2.3. Water (W)
The content of water is preferably 15 to 75% by mass, and more preferably 20 to 70% by mass, based on the total amount of the printing ink composition. When the water content is within the above range, the clogging recovery property tends to be further improved.
1.2.4. Urea
The printing ink composition preferably contains urea. By containing urea, the wettability of the printing ink composition is improved, and the clogging recovery property tends to be further improved.
The content of urea is preferably 0.5 to 15% by mass, and more preferably 1 to 12.5% by mass, based on the total amount of the printing ink composition. When the urea content is within the above range, the clogging recovery property tends to be further improved.
The content ratio of urea to the water-soluble dye is preferably 0.05 to 1.0, more preferably 0.1 to 0.5, and further preferably 0.1 to 0.3 on a mass basis. When the content ratio of urea to the water-soluble dye is within the above range, the wettability of the printing ink composition tends to be further improved, and the clogging recovery tends to be further improved.
1.2.5. Surface active agent
The surfactant is not particularly limited, and examples thereof include acetylene glycol surfactants, fluorine surfactants, and silicone surfactants.
The acetylene glycol-based surfactant is not particularly limited, and examples thereof include an alkylene oxide adduct of 2,4,7, 9-tetramethyl-5-decyne-4, 7-diol and 2,4,7, 9-tetramethyl-5-decyne-4, 7-diol, and an alkylene oxide adduct of 2, 4-dimethyl-5-decyne-4-ol and 2, 4-dimethyl-5-decyne-4-ol.
The fluorine-based surfactant is not particularly limited, and examples thereof include perfluoroalkyl sulfonate, perfluoroalkyl carboxylate, perfluoroalkyl phosphate, perfluoroalkyl ethylene oxide adduct, perfluoroalkyl betaine, and perfluoroalkyl amine oxide compound.
Examples of the silicone surfactant include a silicone compound, a polyester-modified silicone, and a polyether-modified organosiloxane. Examples of the polyester-modified silicone include BYK-347, 348, BYK-UV3500, 3510 and 3530 (BYK Additives & Instruments Co., Ltd.), and examples of the polyether-modified silicone include BYK-3570(BYK Additives & Instruments Co., Ltd.).
Among them, acetylene glycol surfactants are preferable. By using such a surfactant, clogging recovery tends to be further improved.
The content of the surfactant is preferably 0.1 to 1% by mass, and more preferably 0.2 to 0.8% by mass, based on the total mass of the printing ink composition. When the content of the surfactant is within the above range, the clogging recovery property tends to be further improved.
pH regulators
The pH adjuster is not particularly limited, and examples thereof include hydroxides of alkali metals such as lithium hydroxide, potassium hydroxide, and sodium hydroxide; amines such as ammonia, triethanolamine, tripropanolamine, diethanolamine, and monoethanolamine; and carboxylic acids such as adipic acid and citric acid. These pH regulators can be used alone in 1, or more than 2 combination.
The content of the pH adjuster is preferably 0.1 to 1% by mass, and more preferably 0.2 to 0.8% by mass, based on the total mass of the printing ink composition.
2. Ink jet method
The ink jet method of the present embodiment is an ink jet method using the ink jet recording apparatus, and includes an ejection step of ejecting the textile printing ink composition by a liquid ejecting head and attaching the composition to a recording medium.
2.1. Discharge step
In the discharge step, the textile printing ink composition is discharged from the liquid discharge head and is attached to the recording medium. More specifically, the pressure generation unit is driven to eject the composition filled in the pressure generation chamber of the liquid ejecting head from the nozzle. Such an ejection method is also called an ink jet method.
The liquid ejecting head used in this embodiment will be described. Fig. 1 shows a schematic diagram for explaining the configuration of a liquid ejection head 10. Fig. 1 shows an outline of one nozzle 1 for discharging a printing ink composition, a pressure chamber 2 to which the composition is supplied, and a circulation flow path 3 through which the composition in the pressure chamber 2 can be circulated. In the example of fig. 1, the nozzle 1 and the pressure chamber 2 communicate with each other through a communication passage 4.
The nozzle 1 is a through hole for ejecting the printing ink composition. More specifically, the nozzle 1 is a through hole formed in the nozzle plate. A plurality of nozzles are formed in the nozzle plate, and a pressure chamber 2 is provided in each of the nozzles. The pressure chamber 2 is formed separately for each nozzle 1. The printing ink composition is supplied to the pressure chamber 2. When the pressure in the pressure chamber 2 is changed by a pressure generating means (not shown), a part of the composition flowing through the communication passage 4 is ejected from the nozzle 1 to the outside, and the remaining part flows into the circulation passage 3.
The path of the circulation flow path 3 is not particularly limited, and the flow path may be configured such that the composition flowing into the circulation flow path 3 is supplied to the pressure chamber 2. The composition flowing into the circulation flow path 3 does not necessarily have to be supplied to the same pressure chamber again, and may be supplied to a pressure chamber corresponding to another nozzle. In addition, the circulation flow path 3 does not have to have all flow paths located inside the liquid jet head 10, and some flow paths may be located outside the liquid jet head 10 as long as the composition flowing out of the pressure chamber 2 is supplied to the pressure chamber 2 again.
As described above, according to the liquid jet head 10 of the present embodiment, the composition in the pressure chamber 2, more specifically, the composition in the vicinity of the nozzle 1 can be efficiently circulated in the head. This makes it possible to suppress clogging of each nozzle due to the composition even if the usage rate and the nozzle position are different for each nozzle.
Examples of the liquid ejecting head 10 used in the ejection step include a line head for performing line recording and a serial head for performing serial recording.
In a line type using a line head, for example, a liquid ejecting head having a width equal to or larger than a recording width of a recording medium is fixed to an ink jet recording apparatus. Then, the recording medium is moved in a sub-scanning direction (longitudinal direction of the recording medium, conveyance direction), and ink droplets are ejected from the nozzles of the liquid ejecting head in conjunction with the movement, thereby recording an image on the recording medium.
In the serial type using a serial head, for example, a liquid ejecting head is mounted on a carriage movable in the width direction of a recording medium. Then, the carriage is moved in the main scanning direction (the lateral direction of the recording medium, the width direction), and ink droplets are ejected from the nozzle openings of the head in conjunction with the movement, whereby an image can be recorded on the recording medium.
2.2. First heating step
The ink jet method of the present embodiment may have a first heating step of heating the composition in the liquid ejecting head. More specifically, a heating step of heating the composition in the circulation path constituted by the pressure chamber 2, the circulation flow path 3, and the communication path 4 may be provided. The heating means may be provided in the pressure chamber 2, the circulation flow path 3, or the communication path 4, for example, and is not particularly limited. In addition, a heating means for heating the nozzle plate may be provided, and when the circulation path 3 passes through the outside of the liquid ejecting head 10, the heating means may be provided in the circulation path 3 existing outside the liquid ejecting head 10. Further, a heating unit may be provided in the ink flow path upstream of the pressure chamber. Here, the ink flow path refers to a flow path for flowing ink. The ink flow path also includes, for example, an ink supply path for supplying ink from an ink storage container storing ink to the ink jet recording head.
In the heating step, the composition is preferably heated to 40 ℃ or higher. The heating temperature of the composition is more preferably 40 to 60 ℃, and still more preferably 40 to 50 ℃. By combining such a heating step with a liquid ejecting head for circulating the composition, clogging of the printing ink composition can be suppressed.
2.3. Second heating step
The ink jet method of the present embodiment may further include a second heating step of heating the recording medium to which the textile printing ink composition is attached after the ejection step. By heating, the moisture and solvent components of the attached printing ink composition can be evaporated, and defects such as transfer of the attached printing ink composition to the back surface or non-attached portion of the recording medium when the recording medium is wound or stacked can be prevented.
2.4. Fixing and attaching process
In the ink jet method of the present embodiment, in order to fix the dye attached to the recording medium, it is preferable to perform a fixing step (vapor step) by exposing the recording medium to water vapor in a high-temperature environment after the above step. The temperature is suitably in a range slightly different depending on the type of fabric and the type of dye used, and is preferably in a range of approximately 100 to 110 ℃. In the case of cellulose fibers such as cotton and viscose rayon, the exposure time is preferably 10 to 20 minutes, and in the case of amide fibers such as silk, wool, and nylon, the exposure time is preferably about 20 to 40 minutes. By performing the fixing treatment in these ranges, the dye is favorably attached to the fiber.
2.5. Cleaning process
In the ink jet method of the present embodiment, it is preferable that the recording medium is washed after the fixing step and then dried. The specific process includes (1) washing with water (at normal temperature), (2) washing with hot water, (3) soaping, (4) drying, and any of (1) and (2) may be used. In the cases (1) to (3), it is preferable to wash the non-fixed dye sufficiently for several minutes or more. The temperature of the hot water used in (2) is preferably 40 to 60 ℃.
(3) Soaping refers to a process of stirring together with a cleaning assistant in a hot water bath. The hot water temperature varies depending on the type of dye used, and is preferably 40 to 70 ℃ when an acid dye or a direct dye is used, and 80 to 100 ℃ when a reactive dye is used. The cleaning assistant used can be a commercially available product, and specific examples thereof include ESKUDO M-200, ESKUDO RZ-30 (manufactured by Nissan Chemical Co., Ltd.), LACCOL STA, LACCOL ISF, MEISANOL KHM (manufactured by Ming Chemical Co., Ltd.), EMILL NW-1570, EMILL SHA-50, EMILL SK-D (manufactured by Kotani Chemical Industry Co., Ltd.), Anisole 300, Nonisole 501 (manufactured by Rikaku Chemical Co., Ltd.), SENKNOL C-80, SENKNOL CW, and SENKNOL GNW (manufactured by SENKA).
As for the drying (4), any method such as warm air drying in which warm air/hot air is blown or exposed to the recording medium, or pressure drying in which pressure heating is performed using an iron or a hot press can be employed as long as the form of the recording medium is not impaired.
2.6. Recording medium
The recording medium is not particularly limited, and for example, a fabric can be used. The fabric is not particularly limited, and examples thereof include natural fibers such as silk, cotton, wool, nylon, and rayon, and synthetic fibers.
Examples
The present invention will be described more specifically below with reference to examples and comparative examples. The present invention is not limited in any way by the following examples.
1. Preparation of inkjet compositions
The respective components were added to a tank for a mixture as a stainless steel container so as to have the compositions described in tables 1 to 2, and after completely dissolving the components by mixing and stirring, the mixture was further mixed and stirred at normal temperature for 1 hour, and further filtered by a 5 μm membrane filter, thereby obtaining the printing ink compositions of the respective examples. Unless otherwise specified, the numerical values of the components shown in the respective examples in the table represent mass%.
Water-soluble dyes
■ acid black 172
■ acid Red 249
■ acid yellow 79
■ acid blue 140
■ direct blue 199
■ acid orange 33
■ direct orange 26
■ acid Red 138
■ acid violet 54
■ acid orange 116
■ acid blue 290
■ reactive Black 39
■ reactive Black 5
■ active yellow 95
■ reactive Red 31
■ reactive Red 3: 1
■ reactive blue 49
■ reactive orange 13
■ activated yellow 15
■ reactive Red 123
■ reactive blue 222
Water soluble organic solvent
■ propylene glycol
■ diethylene glycol
■ 1, 2-hexanediol
■ 1, 3-butanediol
■ diethylene glycol monobutyl ether
■ 2 methyl-1, 3-propanediol-2
■ 2-pyrrolidone
■ Glycerol
■ triethylene glycol
■ 3 methyl-1, 5-pentanediol
■ triethylene glycol monobutyl ether
pH regulator
■ Triethanolamine (TEA)
■ Triisopropanolamine (TPA)
■ adipic acid
■ citric acid
Surface active agent
■ Surfynol 465 (Nissin chemical industry Co., Ltd., acetylenediol surfactant)
■ Surfynol 104H (Nissin chemical industry Co., Ltd., acetylenediol surfactant)
Others
■ Urea
2. Evaluation method
2.1. Evaluation of clogging recovery
Monna-Lisa EVO T16180 (manufactured by Robustelli) was prepared as the second ink jet recording apparatus. As a first inkjet recording apparatus, a recording apparatus in which a second inkjet recording apparatus is modified to include a liquid ejecting head having a circulation flow path as shown in fig. 1 was prepared. Using the first ink jet recording apparatus and the second ink jet recording apparatus, the printing ink composition was continuously ejected from the liquid ejecting head at 23 ℃ and 50% RH for 10 minutes, and then left in this state for 1 hour without covering a cap or the like.
After the standing, the printing ink composition is ejected onto the photographic paper and ejected until the printing ink composition is normally ejected from all the nozzles. At this time, the number of ink drops until the normal discharge is achieved is counted. Based on the number of ink droplets, the clogging recovery was evaluated by the following evaluation criteria. In the first ink jet recording apparatus and the second ink jet recording apparatus, the driving voltage of the PZT element is adjusted and used so that the amounts of the textile printing ink compositions discharged from the respective PZT elements are the same. It should be noted that there was no practical problem until the C evaluation. The results are shown in Table 3.
Evaluation criteria
S: normalization below 500
A: normalization at over 500 and under 2000
B: more than 2000 and less than 5000 patients with normalization
C: normalization of more than 5000 and less than 10000
D: failure to normalize at 10000 hairs, but normalization by nozzle cleaning
E: in 10000 cases, even when the nozzle was cleaned, some of the nozzles were not normalized
F: in 10000 cases, the jet was not normalized, and almost all the nozzles did not eject even when the nozzles were cleaned
2.2. Preparation of dyed cloth 1 (ink: A1-P1, A2, B2, F2, M2)
Using the first ink jet recording apparatus, full-size printing was performed on a fabric so that the amount of the printing ink composition deposited was 19.3g/m2. Further, as the fabric, a fabric obtained by treating a silk fabric (pure white spun silk 14 mesh (about 3.75 g in terms of old japanese weight unit, one mesh), manufactured by dyers) with a pretreatment liquid containing 1.0 mass% of sodium alginate, 1.0 mass% of guar gum, 4.0 mass% of ammonium sulfate, 10.0 mass% of urea, and water (balance) and press-drying the treated fabric at a 20% pass ratio by a mangle was used.
After the full-size printing, the plate was subjected to a steam treatment at 102 ℃ for 30 minutes using a steam machine (Mathis, model DHe), and then washed with water to remove the unfixed dye. Further, after hot water washing (40 ℃ C. for 10 minutes), the fabric was washed with hot water containing LACCOL STA (cleaning assistant, manufactured by Mingchi chemical) in an amount of 0.2 mass% at 55 ℃ C. for 10 minutes, rinsed with normal temperature water, and dried to obtain a printed and dyed fabric.
2.3. Preparation of dyeing cloth 2 (ink: A3-O3, A4, B4, F4, O4)
Using the first ink jet recording apparatus, full-size printing was performed on a fabric so that the amount of the printing ink composition deposited was 19.3g/m2. Further, as the fabric, a fabric made of 1.0 mass of sodium alginate using cotton cloth (mercerized cotton fine plain cloth, manufactured by dyer) was usedThe fabric was obtained by treating a pretreatment liquid of mass%, guar gum 1.0 mass%, ammonium sulfate 4.0 mass%, urea 10.0 mass%, and water (balance) and then press-drying the treated fabric with a mangle at a 20% discard rate.
After the full-size printing, the plate was steamed at 102 ℃ for 12 minutes using a steamer (manufactured by Mathis, model DHe), and then washed with water to remove the unfixed dye. Further, after hot water washing (50 ℃ C. for 10 minutes), the fabric was washed with 90 ℃ hot water containing 0.2 mass% of LACCOL STA (cleaning assistant, manufactured by Mingchi Chemicals) for 10 minutes, rinsed with normal temperature water, and dried to obtain a printed and dyed fabric.
2.4. Evaluation of printing concentration
The printed cloths 1 and 2 obtained as described above were measured for their density (OD value) using a spectral densitometer FD-7 (manufactured by Konikamet). In the measurement, a polarizing filter is used to match the color of each coloring material, and the values of the color areas (Dk, Dc, Dm, and Dy) suitable for each coloring material are determined. As measurement conditions, the following light sources were used: d65, viewing angle 10 degrees, Status-T, with UV filter. The results are shown in Table 4.
[ TABLE 4 ]
2.5. Evaluation of fastness
The dyed fabric obtained as described above was subjected to fastness tests in accordance with the respective standards of fastness to washing (JIS L0844: 2011A-2), fastness to perspiration (JIS L848: 2004) and fastness to water (JIS L846: 2004). In addition, for the standard white patch used in the test, for the ink: A1-P1, Silk (No. 2-1) according to JIS L0803 was used. In addition, for the ink: A3-O3, cotton (No. 3-1) described in JIS L0803 was used. In addition, a standard white cloth for lining was used as the standard white cloth for lining purchased from the japan standards association. The results are shown in Table 5. In addition, the numerical values in table 5 represent the number of grades of each firmness test result.
2.6. Evaluation of production of printed cloth with comparative example ink in which amount of applied dye per unit area was made uniform
Using the ink compositions (a2, B2, F2, and M2) of the comparative examples, the application amount was adjusted so that the amount of dye deposited per unit area was the same as that of the ink compositions (a1, B1, F1, and M1) of the examples, and full-page printing was performed to obtain printed cloths.
Specifically, the dye content ratio of each of A2, B2, and F2 to the inks A1, B1, and F1 was 1/2, and thus 19.3mg/m2The same procedure as in the above-described method for producing a printed cloth was followed except that the application amount of (b) was adjusted to be the same as the above-described method for producing a printed cloth. In addition, M2 contained 19.3mg/M because the dye content ratio to M1 was 1/52The same procedure as in a2, B2, and F2 was repeated except that the discharge was performed at the same amount and the application was performed 5 times in a superimposed manner at the same site.
In addition, the same recording was performed on the ink compositions of examples (A3, B3, F3, O3) and the ink compositions of comparative examples (a4, B4, F4, O4) using the reactive dyes, and printed cloths were prepared.
The printing density of each of the obtained printed cloths was measured, and the bleeding at the edge of the full-size printing was visually determined. Based on the results, the following evaluation criteria were used for evaluation. The results are shown in Table 6.
Evaluation criteria
A: no end infiltration, and clear and sharp outline.
B: slightly bleed, but the contours can be identified.
C: the color oozes out and the contour is blurred and difficult to recognize.
D: the bleeding is very large and it is not possible to tell where the contours are located.
[ TABLE 6 ]
3. Evaluation results
The compositions of the printing ink compositions used in the respective examples are shown in tables 1 to 2, and the evaluation results are shown in tables 3 to 6. From these tables, it is understood that a recording apparatus which ejects a printing ink composition containing a predetermined amount of a water-soluble dye from a predetermined liquid ejecting head is excellent in clogging recovery property, and can perform high-density printing without causing bleeding.
In detail, as is clear from a comparison of the first recording apparatus and the second recording apparatus in table 3, the jam recovery performance is excellent by using the first recording apparatus. On the other hand, although not shown in table 3, it is also understood that when the ink compositions of comparative examples (a2, B2, F2, M2, a4, B4, F4, and O4) were used, the clogging recovery properties of both the recording apparatuses were not problematic, and the clogging recovery properties were a problem unique to a printing ink composition containing a predetermined amount of a water-soluble dye.
In table 4, when the ink compositions of examples and comparative examples (a2, B2, F2, M2, a4, B4, F4, and O4) were used in comparison, it was found that the optical density (OD value) of the printed matters obtained from the ink compositions of comparative examples was poor.
In particular, as shown in table 6, when the inks of comparative examples were used in an overlapping manner at 2 times or 5 times for the purpose of matching the optical densities (OD values) of the ink compositions of examples and comparative examples, the OD values were close to each other, but did not reach the same level as in examples. This is considered to be because the coloring material penetrates into the back surface side of the cloth and does not sufficiently remain on the surface because a large amount of the solvent is similarly applied in addition to the coloring material.
As shown in table 6, when the coating was applied in a superimposed manner, a larger amount of solvent was applied to the fabric than in the examples. Therefore, in the portion where the printing portions were applied in the overlapping manner in the comparative example, the bleeding of the entire printing portion was deteriorated, and particularly, the end portions were completely blurred, and as a result, the boundary portion between the non-printing portions was completely broken.
Further, as shown in table 5, it was confirmed that all of the printed matters obtained using the ink compositions of examples exhibited excellent fastness.
Claims (9)
1. An ink jet recording apparatus comprising a textile printing ink composition and a liquid ejecting head having nozzles for ejecting the textile printing ink composition,
the printing and dyeing ink composition contains a water-soluble dye, a water-soluble organic solvent and water,
the content of the water-soluble dye is 10% by mass or more based on the total amount of the printing ink composition,
the liquid ejecting head includes the nozzle that ejects the printing ink composition, a pressure chamber to which the printing ink composition is supplied, and a circulation flow path that can circulate the printing ink composition in the pressure chamber,
all of the flow paths of the circulation flow path are located inside the liquid ejection head.
2. The inkjet recording apparatus according to claim 1,
the water-soluble dye is an acid dye, a reactive dye or a direct dye.
3. The inkjet recording apparatus according to claim 1 or 2,
the content of the water-soluble dye is 20% by mass or more based on the total amount of the printing ink composition.
4. The inkjet recording apparatus according to claim 1, wherein the water-soluble organic solvent includes a first water-soluble organic solvent having a vapor pressure at 20 ℃ of 1Pa or more and a second water-soluble organic solvent having a vapor pressure at 20 ℃ of less than 1 Pa.
5. The inkjet recording apparatus according to claim 4,
the content ratio of the second water-soluble organic solvent to the first water-soluble organic solvent is 0.02 to 2 on a mass basis.
6. The inkjet recording apparatus according to claim 1,
the printing ink composition contains urea.
7. The inkjet recording apparatus according to claim 6,
the content ratio of the urea to the water-soluble dye is 0.1-0.3 on a mass basis.
8. The inkjet recording apparatus according to claim 1,
the dye is at least one of acid blue 138, acid blue 290, acid violet 54, acid orange 116, reactive yellow 15, reactive red 123, or reactive blue 222.
9. An ink jet recording method, characterized in that the ink jet recording apparatus according to any one of claims 1 to 8 is used,
comprises a discharge step of discharging a liquid jet head for a printing ink composition and attaching the liquid jet head to a recording medium,
the printing and dyeing ink composition contains a water-soluble dye, a water-soluble organic solvent and water,
the content of the water-soluble dye is 10% by mass or more based on the total amount of the printing ink composition,
the liquid ejecting head includes the nozzle that ejects the printing ink composition, a pressure chamber to which the printing ink composition is supplied, and a circulation flow path that can circulate the printing ink composition in the pressure chamber,
all of the flow paths of the circulation flow path are located inside the liquid ejection head.
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| JP7434774B2 (en) | 2024-02-21 |
| CN112519416A (en) | 2021-03-19 |
| JP2021045926A (en) | 2021-03-25 |
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