CN111053729B - Transparent hair conditioner with hair and hair scale repairing effect - Google Patents
Transparent hair conditioner with hair and hair scale repairing effect Download PDFInfo
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- CN111053729B CN111053729B CN202010091682.7A CN202010091682A CN111053729B CN 111053729 B CN111053729 B CN 111053729B CN 202010091682 A CN202010091682 A CN 202010091682A CN 111053729 B CN111053729 B CN 111053729B
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- hair
- hydrolyzed
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- conchiolin
- stearyl
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- 210000004209 hair Anatomy 0.000 title claims abstract description 98
- 230000000694 effects Effects 0.000 title abstract description 6
- 108010006161 conchiolin Proteins 0.000 claims abstract description 28
- VFKZECOCJCGZQK-UHFFFAOYSA-M 3-hydroxypropyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCO VFKZECOCJCGZQK-UHFFFAOYSA-M 0.000 claims abstract description 13
- 102000008186 Collagen Human genes 0.000 claims abstract description 13
- 108010035532 Collagen Proteins 0.000 claims abstract description 13
- 108010073771 Soybean Proteins Proteins 0.000 claims abstract description 13
- 229920001436 collagen Polymers 0.000 claims abstract description 13
- 125000001453 quaternary ammonium group Chemical class 0.000 claims abstract description 13
- -1 isopentyl glycol Chemical compound 0.000 claims description 40
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 claims description 12
- 229940035437 1,3-propanediol Drugs 0.000 claims description 12
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 12
- 239000004698 Polyethylene Substances 0.000 claims description 12
- 229940082500 cetostearyl alcohol Drugs 0.000 claims description 12
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 12
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 12
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 12
- 229920000573 polyethylene Polymers 0.000 claims description 12
- 229920000166 polytrimethylene carbonate Polymers 0.000 claims description 12
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 12
- 239000006228 supernatant Substances 0.000 claims description 12
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 claims description 12
- 102000004169 proteins and genes Human genes 0.000 claims description 9
- 108090000623 proteins and genes Proteins 0.000 claims description 9
- 229940001941 soy protein Drugs 0.000 claims description 9
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 8
- XPFCZYUVICHKDS-UHFFFAOYSA-N 3-methylbutane-1,3-diol Chemical compound CC(C)(O)CCO XPFCZYUVICHKDS-UHFFFAOYSA-N 0.000 claims description 7
- 108091005804 Peptidases Proteins 0.000 claims description 7
- 239000004365 Protease Substances 0.000 claims description 7
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 7
- 239000012510 hollow fiber Substances 0.000 claims description 7
- 230000007062 hydrolysis Effects 0.000 claims description 7
- 238000006460 hydrolysis reaction Methods 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 239000012528 membrane Substances 0.000 claims description 7
- 238000002791 soaking Methods 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 230000001105 regulatory effect Effects 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 239000000706 filtrate Substances 0.000 claims description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- VBOZFTYRQDFTKX-UHFFFAOYSA-N 3-methylbutane-1,1-diol Chemical compound CC(C)CC(O)O VBOZFTYRQDFTKX-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 9
- 235000019710 soybean protein Nutrition 0.000 abstract description 4
- 238000012360 testing method Methods 0.000 description 10
- 235000018102 proteins Nutrition 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 235000015097 nutrients Nutrition 0.000 description 5
- 238000009960 carding Methods 0.000 description 4
- 230000003648 hair appearance Effects 0.000 description 4
- 230000003779 hair growth Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 230000008439 repair process Effects 0.000 description 4
- 210000003780 hair follicle Anatomy 0.000 description 3
- 230000003699 hair surface Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 238000000635 electron micrograph Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 210000001519 tissue Anatomy 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- 201000004384 Alopecia Diseases 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 231100000360 alopecia Toxicity 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 210000001736 capillary Anatomy 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 210000002808 connective tissue Anatomy 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 210000002510 keratinocyte Anatomy 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 210000001640 nerve ending Anatomy 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
- 229920001184 polypeptide Polymers 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 210000001732 sebaceous gland Anatomy 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 230000036561 sun exposure Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/98—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
- A61K8/987—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin of species other than mammals or birds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/645—Proteins of vegetable origin; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/65—Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/002—Preparations for repairing the hair, e.g. hair cure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Zoology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a transparent hair conditioner with hair scale repairing effect, which comprises a hair conditioner composition with the mass percentage of 1.3-8%, wherein the hair conditioner composition comprises the following components in parts by mass: 1-5 parts of hydrolyzed conchiolin, 0.1-1 part of stearyl dimethyl ammonium hydroxypropyl hydrolyzed collagen, 0.1-1 part of quaternary ammonium salt-79 hydrolyzed silk, and 0.1-1 part of hydroxypropyl trimethyl ammonium chloride hydrolyzed soybean protein.
Description
Technical Field
The invention relates to the field of cosmetics, in particular to a transparent hair conditioner with the effect of repairing hair scales.
Background
The hair is an accessory fibrous tissue of a human body, is an important component of the human body, has the physiological functions of preserving heat in winter, preventing the head from being subjected to strong sun exposure and the like, and can beautify the image of an individual.
Hair grows in hair follicles, hair follicle tissues are divided into hair papilla, hair bulb and sebaceous glands, capillaries, nerve endings, connective tissues and the like grow in the hair papilla, nutrients are provided for hair growth, and the hair follicle tissue plays an important role in hair growth.
The portion of hair in the follicle is called the root, while the exposed portion is called the shaft, which is divided from inside to outside into medulla, cortex and Mao Xiaopi. Mao Xiaopi is the outermost layer of hair and is formed by tiling 6 to 10 layers of coreless squamous keratinocytes. The hair scales are the outermost layer tissues for protecting the hair, the smoothness of the hair scales determines the luster and the carding property of the hair, and the hair scales which are arranged flatly are lustrous, because when the light irradiates the hair from one direction, if the hair scales are tidy, the light reflection ratio is more, and the generated diffuse reflection ratio is less, so that the glossiness of the hair is higher. Mao Xiaopi when being influenced by the outside, the hair scales are seemed to be seemingly uneven due to warping or cracking, and more serious, the hair scales are peeled off, so that the outer surface of the hair is in an uneven state, the damaged hair is irradiated by illumination, and the hair surface is dull due to diffuse reflection of light. The damaged hair scales can also lead the hair to be easy to wind and knot and difficult to comb.
The conventional hair conditioner is used after washing hair, and is a rinse-off type hair conditioner or a resident type hair conditioner, and no obvious cleaning component exists, so that the hair conditioner can be effectively spread on the surface of hair without being washed away by water in the use process, and can smooth and smooth the hair surface by flattening hair scales tilted on the surface of hair, and reducing the negative charge intensity on the surface of hair. However, it belongs to the palliative products, and after the hair conditioner attached to the skin is gradually consumed with time, the hair returns to a dull, poor state in which it is easy to twist and tie.
Disclosure of Invention
The invention aims to solve the technical problem of providing a transparent hair conditioner with the effect of repairing hair and hair scales, which can provide nutrients for hair growth, moisten and repair hair and hair scales, so that the hair becomes glossy, smooth and elegant, and the hair quality is obviously improved.
The specific technical scheme of the invention is as follows:
the transparent hair conditioner comprises a hair care composition with the mass percent of 1.3-8%, wherein the hair care composition comprises the following components in parts by mass: 1-5 parts of hydrolyzed conchiolin, 0.1-1 part of stearyl dimethyl ammonium hydroxypropyl hydrolyzed collagen, 0.1-1 part of quaternary ammonium salt-79 hydrolyzed silk, and 0.1-1 part of hydroxypropyl trimethyl ammonium chloride hydrolyzed soybean protein.
Preferably, the hair care composition comprises the following components in parts by mass: 3 parts of hydrolyzed conchiolin, 0.5 part of stearyl dimethyl ammonium hydroxypropyl hydrolyzed collagen, 0.5 part of quaternary ammonium salt-79 hydrolyzed silk, and 0.5 part of hydroxypropyl trimethyl ammonium chloride hydrolyzed soybean protein.
Further, the transparent hair conditioner formula also comprises the following components in percentage by mass:
10-30% of isopentyl glycol
10-30% of 1, 3-propanediol
Cetostearyl alcohol 1-3%
1-5% of aminopropyl polydimethylsiloxane
Polyethylene glycol-90M 0.1-0.5%
Stearyl PG-dimethylamine 0.1-1%
Polyquaternium-61.1-1%
The balance of water.
Further, preferably, the transparent hair conditioner formula further comprises the following components in percentage by mass:
isoprene glycol 20%
1, 3-propanediol 20%
Cetostearyl alcohol 2%
Aminopropyl polydimethylsiloxane 3%
Polyethylene glycol-90M 0.3%
Stearyl PG-dimethylamine 0.5%
Polyquaternium-61.5%
The balance of water.
The embodiment of the invention also provides a preparation method of the hydrolyzed conchiolin, which comprises the following steps:
(1) Crushing shells, adding 2mol/L potassium hydroxide aqueous solution, and soaking under stirring to obtain a soaked product;
(2) Regulating the pH value of the soaked matter to 7.0, and adding protease with the mass of 1-2% of the raw material for enzymolysis to obtain enzymolysis liquid;
(3) Centrifuging the enzymolysis liquid to obtain supernatant, and filtering the supernatant with a hollow fiber membrane to obtain the hydrolyzed conchiolin.
In some embodiments, the aqueous potassium hydroxide solution of step (1) is added in an amount of 1 to 5 times the weight of the shell; the soaking time is 1-5 hours.
In some embodiments, the protease enzymolysis conditions in step (2) are 40 ℃ for 1-2 hours.
In some of these embodiments, the centrifugation conditions in step (3) are 2000rpm for 20 minutes; the specification of the hollow fiber membrane is protein with the molecular weight cutoff of more than 50 KD.
The technical scheme provided by the embodiment of the invention has the beneficial effects that:
the formula of the transparent hair conditioner disclosed by the invention contains a certain amount of components such as hydrolyzed conchiolin, stearyl dimethyl ammonium hydroxypropyl hydrolyzed collagen, quaternary ammonium salt-79 hydrolyzed silk, hydroxypropyl trimethyl ammonium chloride hydrolyzed soy protein and the like, and can provide nutrients for hair growth, moisten and repair hair scales, so that the hair becomes glossy, smooth and elegant, and the hair quality is obviously improved.
Drawings
FIG. 1 hair combing force test;
FIG. 2 shows an electron micrograph of hair before testing;
fig. 3 shows an electron micrograph of hair after testing.
Detailed Description
The embodiments in the specification are only for illustrating the present invention, and do not limit the scope of the present invention. The scope of the present invention is defined only by the claims, and any omission, substitution or modification made on the basis of the embodiments disclosed herein will fall within the scope of the present invention.
The contents of the present invention can be more easily understood by referring to the following detailed description of preferred embodiments of the present invention and examples included. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In case of conflict, the present specification, definitions, will control.
The term "prepared from …" as used herein is synonymous with "comprising". The terms "comprising," "including," "having," "containing," or any other variation thereof, as used herein, are intended to cover a non-exclusive inclusion. For example, a composition, step, method, article, or apparatus that comprises a list of elements is not necessarily limited to only those elements but may include other elements not expressly listed or inherent to such composition, step, method, article, or apparatus.
When an equivalent, concentration, or other value or parameter is expressed as a range, preferred range, or a range bounded by a list of upper preferable values and lower preferable values, this is to be understood as specifically disclosing all ranges formed from any pair of any upper range limit or preferred value and any lower range limit or preferred value, regardless of whether ranges are separately disclosed. For example, when ranges of "1 to 5" are disclosed, the described ranges should be construed to include ranges of "1 to 4", "1 to 3", "1 to 2 and 4 to 5", "1 to 3 and 5", and the like. When a numerical range is described herein, unless otherwise indicated, the range is intended to include its endpoints and all integers and fractions within the range.
Furthermore, the indefinite articles "a" and "an" preceding an element or component of the invention are not limited to the requirements of the number of elements or components (i.e. the number of occurrences). Thus, the use of "a" or "an" should be interpreted as including one or at least one, and the singular reference of an element or component also includes the plural reference unless the amount is obvious to the singular reference.
The present invention will be further described in detail with reference to examples, which are provided for the purpose of illustration only and are not intended to limit the scope of the present invention.
The transparent hair conditioner disclosed by the invention comprises a hair care composition with the mass percent of 1.3-8%, wherein the hair care composition comprises the following components in parts by mass: 1-5 parts of hydrolyzed conchiolin, 0.1-1 part of stearyl dimethyl ammonium hydroxypropyl hydrolyzed collagen, 0.1-1 part of quaternary ammonium salt-79 hydrolyzed silk, and 0.1-1 part of hydroxypropyl trimethyl ammonium chloride hydrolyzed soybean protein.
In particular, conchiolin is a characteristic class of water products that often binds tightly to the calcium in the shell to form an existing glossy nacreous layer. The hydrolyzed conchiolin is rich in amino acids, polypeptides and other nutrients.
The three cationic natural active substances, namely the stearyl dimethyl ammonium hydroxypropyl hydrolyzed collagen, the quaternary ammonium salt-79 hydrolyzed silk and the hydroxypropyl trimethyl ammonium chloride hydrolyzed soy protein, are used together with the hydrolyzed conchiolin, can provide nutrients for the growth of hair, moisten and repair hair scales, make the hair become glossy, smooth and elegant, and obviously improve the hair quality.
Example 1
A preparation method of hydrolyzed conchiolin comprises the following steps:
(1) Crushing shells, adding a potassium hydroxide aqueous solution with the concentration of 2mol/L which is 1 time of the weight of the shells, and soaking for 5 hours under stirring to obtain a soaked substance;
(2) Regulating the pH value of the soaked matter to 7.0, adding protease accounting for 1% of the mass of the raw material, and reacting for 2 hours at 40 ℃ to obtain enzymolysis liquid;
(3) Centrifuging the enzymolysis solution at 2000rpm for 20 min to obtain supernatant, and filtering the supernatant with hollow fiber membrane with molecular weight cutoff of protein over 50KD to obtain filtrate, i.e. hydrolyzed conchiolin.
Example 2
A preparation method of hydrolyzed conchiolin comprises the following steps:
(1) Crushing shells, adding a potassium hydroxide aqueous solution with the concentration of 2mol/L, which is 5 times the weight of the shells, and soaking for 1 hour under stirring to obtain a soaked substance;
(2) Regulating the pH value of the soaked matter to 7.0, adding protease accounting for 2% of the mass of the raw material, and reacting for 1 hour at 40 ℃ to obtain enzymolysis liquid;
(3) Centrifuging the enzymolysis solution at 2000rpm for 20 min to obtain supernatant, and filtering the supernatant with hollow fiber membrane with molecular weight cutoff of protein over 50KD to obtain filtrate, i.e. hydrolyzed conchiolin.
Example 3
Protein content determination was performed on the hydrolyzed conchiolin obtained in examples 1-2 using KjelMaster K-375 (fully automated KjelMaster Azometer).
The mechanism is as follows: the protein is an organic compound, a protein-containing organic compound sample, concentrated sulfuric acid and a catalyst are put into a test tube to be heated and digested together, so that the protein can be decomposed, decomposed ammonium ions and sulfate ions are combined to generate ammonium sulfate, then ammonia gas is dissociated under the action of alkaline distillation, and the dissociated ammonia gas and water vapor are cooled together by a condenser tube and then enter a titration cup filled with boric acid. And (3) after being absorbed by boric acid, titrating by hydrochloric acid titration solution with known concentration, and multiplying the conversion coefficient according to the consumption of acid to obtain the protein content.
The specific test results are shown in Table 1.
TABLE 1 protein content Table
。
Example 4
A transparent hair conditioner comprises the following components in percentage by mass:
10% of isopentyl glycol
1, 3-propanediol 30%
Cetostearyl alcohol 1%
Aminopropyl polydimethylsiloxane 5%
Polyethylene glycol-90M 0.1%
Stearyl PG dimethylamine 1%
Polyquaternium-61.1%
Hydrolyzed conchiolin produced in example 1 5%
Stearyl dimethyl ammonium hydroxypropyl collagen hydrolysis 0.1%
Quaternary ammonium salt-79 hydrolyzed silk 1%
Hydroxypropyl trimethyl ammonium chloride hydrolyzed soy protein 0.1%
The balance of water.
Example 5
A transparent hair conditioner comprises the following components in percentage by mass:
isopentanediol 30%
10% of 1, 3-propanediol
Cetostearyl alcohol 3%
Aminopropyl polydimethylsiloxane 1%
Polyethylene glycol-90M 0.5%
Stearyl PG dimethylamine 0.1%
Polyquaternium-61%
1% of hydrolyzed conchiolin obtained in example 2
Stearyl dimethyl ammonium hydroxypropyl collagen hydrolysis 1%
Quaternary ammonium salt-79 hydrolyzed silk 0.1%
Hydroxypropyl trimethyl ammonium chloride hydrolyzed soy protein 1%
The balance of water.
Example 6
A transparent hair conditioner comprises the following components in percentage by mass:
isoprene glycol 20%
1, 3-propanediol 20%
Cetostearyl alcohol 2%
Aminopropyl polydimethylsiloxane 3%
Polyethylene glycol-90M 0.3%
Stearyl PG-dimethylamine 0.5%
Polyquaternium-61.5%
3% of the hydrolyzed conchiolin obtained in example 2
Stearyl dimethyl ammonium hydroxypropyl collagen hydrolysis 0.5%
Quaternary ammonium salt-79 hydrolyzed silk 0.5%
Hydroxypropyl trimethyl ammonium chloride hydrolyzed soy protein 0.5%
The balance of water.
Comparative example 1
A transparent hair conditioner comprises the following components in percentage by mass:
isoprene glycol 20%
1, 3-propanediol 20%
Cetostearyl alcohol 2%
Aminopropyl polydimethylsiloxane 3%
Polyethylene glycol-90M 0.3%
Stearyl PG-dimethylamine 0.5%
Polyquaternium-61.5%
3% of the hydrolyzed conchiolin obtained in example 2
The balance of water.
Comparative example 2
A transparent hair conditioner comprises the following components in percentage by mass:
isoprene glycol 20%
1, 3-propanediol 20%
Cetostearyl alcohol 2%
Aminopropyl polydimethylsiloxane 3%
Polyethylene glycol-90M 0.3%
Stearyl PG-dimethylamine 0.5%
Polyquaternium-61.5%
Stearyl dimethyl ammonium hydroxypropyl collagen hydrolysis 0.5%
The balance of water.
Comparative example 3
A transparent hair conditioner comprises the following components in percentage by mass:
isoprene glycol 20%
1, 3-propanediol 20%
Cetostearyl alcohol 2%
Aminopropyl polydimethylsiloxane 3%
Polyethylene glycol-90M 0.3%
Stearyl PG-dimethylamine 0.5%
Polyquaternium-61.5%
Quaternary ammonium salt-79 hydrolyzed silk 0.5%
The balance of water.
Comparative example 4
A transparent hair conditioner comprises the following components in percentage by mass:
isoprene glycol 20%
1, 3-propanediol 20%
Cetostearyl alcohol 2%
Aminopropyl polydimethylsiloxane 3%
Polyethylene glycol-90M 0.3%
Stearyl PG-dimethylamine 0.5%
Polyquaternium-61.5%
Hydroxypropyl trimethyl ammonium chloride hydrolyzed soy protein 0.5%
The balance of water.
Example 7
The transparent hair conditioners prepared in examples 4 to 6 and comparative examples 1 to 4 were subjected to a combing property test.
The method is carried out by reference (Liu Peihua, mo Yuepeng, duan Haixia) for establishing and evaluating a novel moisturizing repair shampoo system [ J ]. Guangzhou chemical industry, 2010,38 (05): 176-178 ], and the specific test method is as follows:
(1) Measuring the dry comb combing force (F1) of the blank hair bundle;
(2) Automatically flushing the hair bundle by an instrument (S-2 combing force tester, TECHNO HASHIMOTO, co) to measure the wet combing force (F2) of the blank hair bundle;
(3) Treating the hair bundle twice by taking 0.1g of the hair conditioner to be tested, and measuring the wet comb combing force (F3) of the hair bundle;
(4) Airing, and measuring the combing force of the hair bundle and the comb (F4);
(5) The average value of 9 groups of continuous and stable carding forces is selected, and the ratio of the friction forces before and after the comparison is carried out.
Wet comb combing force lift% = (F2-F3)/f2×100%
Dry comb combing force lifting% = (F1-F4)/f1×100%
And under the dry state and the wet state of the hair, judging the merits of the hair combing performance by measuring the resistance and the change condition of the resistance of the mechanical comb in the hair combing process. The more friction force decrease indicates a higher degree of lift, indicating a better conditioning effect. The specific test results are shown in FIG. 1.
As shown by the test results in FIG. 1, the wet carding performance and the dry carding performance of the examples 4-6 are not significantly different, and are obviously superior to those of the control groups 1-4.
Example 8
Consumer sensory evaluation was performed on the transparent hair conditioner prepared in example 6.
The specific test method is as follows: hair conditioner was applied once every two days for 2 months to 10 volunteers with long hair and damaged hair. After the test is finished, the volunteers are asked to feel that the volunteers are dull, the problem that the volunteers are easy to wind and knot is obviously improved, the phenomena of alopecia and broken hair are reduced, and the hair quality becomes soft, bright and glossy.
The volunteers before and after the test are sampled, the condition of the hair scales on the hair surface is visually observed by using a scanning electron microscope, the condition of the hair scales before and after the product is used is obviously changed, the hair scales are tilted or broken to be uneven Ji Mao, and the hair scales are orderly arranged, and the specific effect is shown in figures 2 and 3.
The technical features of the above embodiments may be arbitrarily combined, and all possible combinations of the technical features in the above embodiments are not described for brevity of description, however, as long as there is no contradiction between the combinations of the technical features, they should be considered as the scope of the description.
The foregoing examples illustrate only a few embodiments of the invention, which are described in detail and are not to be construed as limiting the scope of the invention. It should be noted that it will be apparent to those skilled in the art that several variations and modifications can be made without departing from the spirit of the invention, which are all within the scope of the invention. Accordingly, the scope of protection of the present invention is to be determined by the appended claims.
Claims (3)
1. A transparent hair conditioner comprises the following components in percentage by mass:
10% of isopentyl glycol
1, 3-propanediol 30%
Cetostearyl alcohol 1%
Aminopropyl polydimethylsiloxane 5%
Polyethylene glycol-90M 0.1%
Stearyl PG dimethylamine 1%
Polyquaternium-61.1%
Hydrolyzed conchiolin 5%
Stearyl dimethyl ammonium hydroxypropyl collagen hydrolysis 0.1%
Quaternary ammonium salt-79 hydrolyzed silk 1%
Hydroxypropyl trimethyl ammonium chloride hydrolyzed soy protein 0.1%
The balance of water;
the preparation method of the hydrolyzed conchiolin comprises the following steps:
(1) Crushing shells, adding a potassium hydroxide aqueous solution with the concentration of 2mol/L which is 1 time of the weight of the shells, and soaking for 5 hours under stirring to obtain a soaked substance;
(2) Regulating the pH value of the soaked matter to 7.0, adding protease accounting for 1% of the mass of the raw material, and reacting for 2 hours at 40 ℃ to obtain enzymolysis liquid;
(3) Centrifuging the enzymolysis solution at 2000rpm for 20 min to obtain supernatant, and filtering the supernatant with hollow fiber membrane with molecular weight cutoff of protein over 50KD to obtain filtrate, i.e. hydrolyzed conchiolin.
2. A transparent hair conditioner comprises the following components in percentage by mass:
isopentanediol 30%
10% of 1, 3-propanediol
Cetostearyl alcohol 3%
Aminopropyl polydimethylsiloxane 1%
Polyethylene glycol-90M 0.5%
Stearyl PG dimethylamine 0.1%
Polyquaternium-61%
Hydrolyzed conchiolin 1%
Stearyl dimethyl ammonium hydroxypropyl collagen hydrolysis 1%
Quaternary ammonium salt-79 hydrolyzed silk 0.1%
Hydroxypropyl trimethyl ammonium chloride hydrolyzed soy protein 1%
The balance of water;
the preparation method of the hydrolyzed conchiolin comprises the following steps:
(1) Crushing shells, adding a potassium hydroxide aqueous solution with the concentration of 2mol/L, which is 5 times the weight of the shells, and soaking for 1 hour under stirring to obtain a soaked substance;
(2) Regulating the pH value of the soaked matter to 7.0, adding protease accounting for 2% of the mass of the raw material, and reacting for 1 hour at 40 ℃ to obtain enzymolysis liquid;
(3) Centrifuging the enzymolysis solution at 2000rpm for 20 min to obtain supernatant, and filtering the supernatant with hollow fiber membrane with molecular weight cutoff of protein over 50KD to obtain filtrate, i.e. hydrolyzed conchiolin.
3. A transparent hair conditioner comprises the following components in percentage by mass:
isoprene glycol 20%
1, 3-propanediol 20%
Cetostearyl alcohol 2%
Aminopropyl polydimethylsiloxane 3%
Polyethylene glycol-90M 0.3%
Stearyl PG-dimethylamine 0.5%
Polyquaternium-61.5%
Hydrolyzed conchiolin 3%
Stearyl dimethyl ammonium hydroxypropyl collagen hydrolysis 0.5%
Quaternary ammonium salt-79 hydrolyzed silk 0.5%
Hydroxypropyl trimethyl ammonium chloride hydrolyzed soy protein 0.5%
The balance of water;
the preparation method of the hydrolyzed conchiolin comprises the following steps:
(1) Crushing shells, adding a potassium hydroxide aqueous solution with the concentration of 2mol/L, which is 5 times the weight of the shells, and soaking for 1 hour under stirring to obtain a soaked substance;
(2) Regulating the pH value of the soaked matter to 7.0, adding protease accounting for 2% of the mass of the raw material, and reacting for 1 hour at 40 ℃ to obtain enzymolysis liquid;
(3) Centrifuging the enzymolysis solution at 2000rpm for 20 min to obtain supernatant, and filtering the supernatant with hollow fiber membrane with molecular weight cutoff of protein over 50KD to obtain filtrate, i.e. hydrolyzed conchiolin.
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103442683A (en) * | 2011-03-25 | 2013-12-11 | 汉高股份有限及两合公司 | Process for producing a conditioning cleaning agent |
| CN108066237A (en) * | 2017-12-29 | 2018-05-25 | 无限极（中国）有限公司 | It is a kind of that there are whitening, the composition of light spot effect and its application, skin care item |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103442683A (en) * | 2011-03-25 | 2013-12-11 | 汉高股份有限及两合公司 | Process for producing a conditioning cleaning agent |
| CN108066237A (en) * | 2017-12-29 | 2018-05-25 | 无限极（中国）有限公司 | It is a kind of that there are whitening, the composition of light spot effect and its application, skin care item |
Non-Patent Citations (1)
| Title |
|---|
| 安姬蜜奢华修复滋养护发素;蔻丝魅株式会社;国家药品监督管理局数据查询;全文 * |
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