CN110170231A - A kind of VOCs processing unit and its collecting and distributing type processing method of use - Google Patents
A kind of VOCs processing unit and its collecting and distributing type processing method of use Download PDFInfo
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- CN110170231A CN110170231A CN201910609403.9A CN201910609403A CN110170231A CN 110170231 A CN110170231 A CN 110170231A CN 201910609403 A CN201910609403 A CN 201910609403A CN 110170231 A CN110170231 A CN 110170231A
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- 239000012855 volatile organic compound Substances 0.000 title claims abstract description 97
- 238000003672 processing method Methods 0.000 title claims abstract description 8
- 238000001179 sorption measurement Methods 0.000 claims abstract description 66
- 230000008929 regeneration Effects 0.000 claims abstract description 50
- 238000011069 regeneration method Methods 0.000 claims abstract description 50
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 47
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 25
- 230000000694 effects Effects 0.000 claims abstract description 7
- 239000003463 adsorbent Substances 0.000 claims description 79
- 238000003795 desorption Methods 0.000 claims description 46
- 239000002250 absorbent Substances 0.000 claims description 36
- 230000002745 absorbent Effects 0.000 claims description 36
- 238000007781 pre-processing Methods 0.000 claims description 20
- 238000005070 sampling Methods 0.000 claims description 13
- 238000000746 purification Methods 0.000 claims description 7
- 238000007084 catalytic combustion reaction Methods 0.000 claims description 4
- 239000000428 dust Substances 0.000 claims description 4
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- 239000003638 chemical reducing agent Substances 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- 239000003595 mist Substances 0.000 claims description 3
- 239000000779 smoke Substances 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- 239000002808 molecular sieve Substances 0.000 claims description 2
- 238000011084 recovery Methods 0.000 claims description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 abstract description 6
- 230000001172 regenerating effect Effects 0.000 abstract description 4
- 239000003610 charcoal Substances 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 76
- 238000010521 absorption reaction Methods 0.000 description 11
- 238000000034 method Methods 0.000 description 10
- 238000002485 combustion reaction Methods 0.000 description 8
- 238000002156 mixing Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 230000007420 reactivation Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000010977 unit operation Methods 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
- F23G7/06—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
- F23G7/06—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
- F23G7/07—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases in which combustion takes place in the presence of catalytic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
- B01D2259/4009—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2209/00—Specific waste
- F23G2209/14—Gaseous waste or fumes
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Treating Waste Gases (AREA)
Abstract
The invention discloses a kind of VOCs processing unit and its collecting and distributing type processing methods of use, purpose is that solving more and small VOCs pollution sources carries out adsorption treatment to VOCs gas using active carbon, generated adsorption saturation active carbon is directly abandoned, and can there are problems that the wasting of resources and dangerous waste processing.The application is by the way of collecting and distributing type processing, based on (separated practices) establish activated carbon adsorption device to VOCs pollution sources on the spot, pass through regenerating unit (centralization regeneration), realize the regeneration to adsorption saturation active carbon, investment of the effectively save enterprise for combustive regeneration device, also avoids the problem of saturated activity charcoal is directly abandoned.The application can satisfy enterprise for small tolerance, the demand of the VOCs gas treatment of low concentration, application value with higher and preferable application prospect.The application is skillfully constructed, reasonable design, easy operation, the improvement for volatile organic compounds, improves environment, has important progress meaning.
Description
Technical field
The present invention relates to volatile organic compounds process field, the collection of specially a kind of VOCs processing unit and its use
Dissipate formula processing method.
Background technique
Volatile organic compounds (VOCs) is fine particle (PM2.5) and ozone (O3) key precursor object.Therefore, it controls
VOCs discharge processed is of great significance to improvement haze and ozone pollution, imperative.
And control in the end treatment method of VOCs, absorption method and combustion technology obtain the most because of its high treating effect
It is widely applied.Adsorbent is if being the significant wastage of resource using abandoning if once, therefore, absorption+burning group technology
More applications are obtained.For large-minded, the low enterprise of VOCs concentration usually selects zeolite runner concentration+catalysis burning
Treatment process.But there is VOCs pollution sources are more in some enterprises or region, narrow-minded, the low situation of gas concentration of generation.
Dispersing in view of pollution sources, cannot focus on, independent each pollution sources establish a set of absorption+burner to be handled,
It is technically feasible, but since burner once invests height, running cost is high, to the technology and management level of operator
Also high, economically for be unreasonable.
For this purpose, there is an urgent need to a kind of new methods and/or device, to solve the above problems.
Summary of the invention
Goal of the invention of the invention is: being inhaled using active carbon to VOCs gas for more and small VOCs pollution sources
Attached processing, generated adsorption saturation active carbon are directly abandoned, and can there are problems that the wasting of resources and dangerous waste processing, and if right
Combustive regeneration device individually established to the active carbon of every set adsorption saturation, the problem of high investment, provides a kind of VOCs processing dress
The collecting and distributing type processing method set and its used.The application is by the way of collecting and distributing type processing, in VOCs pollution sources (distributing on the spot
Processing) it establishes based on activated carbon adsorption device, by regenerating unit (centralization regenerates), realize to adsorption saturation active carbon
Regeneration, investment of the effectively save enterprise for combustive regeneration device also avoid the problem of saturated activity charcoal is directly abandoned.This
Application can satisfy enterprise for small tolerance, the demand of the VOCs gas treatment of low concentration, application value with higher and compared with
Good application prospect.The application is skillfully constructed, reasonable design, easy operation, the improvement for volatile organic compounds, improves
Environment has important progress meaning.
To achieve the goals above, the present invention adopts the following technical scheme:
A kind of VOCs processing unit, including for being adsorbed to VOCs absorbing unit, for the adsorbent of reproducing adsorbent
Regeneration unit;
The absorbing unit includes the gas sampling component for VOCs gas collection, pre-processing assembly, adsorption tower, places and take out
Drawer, adsorbent, exhaust emissions equipment, the gas sampling component is connected with exhaust gas pre-processing assembly and pre-processing assembly can remove
Dust or droplet in VOCs gas collected by gas sampling component, the pre-processing assembly be connected with adsorption tower by pipeline and
Treated that gas can enter in adsorption tower is adsorbed for preprocessed component, and the adsorbent setting is being placed in drawer and inhaled
Attached dose constitutes absorbent module with drawer is placed, and the absorbent module is at least one, and the absorbent module is arranged in adsorption tower
And adsorbent can be used to adsorb VOCs therein, the adsorption tower is connected with exhaust emissions equipment and handles through adsorption tower
Gas up to standard can be discharged through exhaust emissions equipment afterwards;
The adsorbent regeneration unit include for adsorbent in adsorption tower carry out regenerated desorption column, desorption unit blower,
Burner, fresh-air fan, exhaust emissions equipment, the desorption column, desorption unit blower, burner constitute heat by pipeline
The adsorbed VOCs of absorbent module can enter in burner after being desorbed by hot wind and burn in air circulating system and desorption column
Purification, the fresh-air fan is connected with hot air circulating system and fresh-air fan can pump air into hot air circulating system to meet
The burning of burner needs, the hot air circulating system be connected with exhaust emissions equipment and the part in hot air circulating system into
Gas is discharged after capable of being handled by exhaust emissions equipment clean.
The absorbing unit further includes absorbing unit blower, and the absorbing unit blower is arranged on the pipeline of absorbing unit
And absorbing unit blower can provide power for the operation of absorbing unit.
The number of the adsorbent regeneration unit and absorbing unit ratio is 1:1 ~ 50.
The placement drawer is in rectangle or circle or polygon, and the placement drawer is using standardization, modularized design, institute
Placement drawer is stated to be successively set in adsorption tower or desorption column.
The gas sampling component includes gas gathering mask, blower, and the gas gathering mask is connected by pipeline with pre-processing assembly, institute
Power can be provided for VOCs gas by stating blower.
The pre-processing assembly includes one of filter device, oil mist removing device, smoke temperature reducer or a variety of.
The adsorption tower is fixed-bed structure.
The adsorbent is one of active carbon, zeolite, molecular sieve or a variety of.
The burner is one of catalytic combustion system, flame combustion device or a variety of.
The energy that the burner provides supplemental heat source is one of electricity, oil gas, natural gas or a variety of.
The adsorbent regeneration unit is using fixed design or mobile design.
Based on the collecting and distributing type processing method of aforementioned VOCs processing unit, include the following steps:
(1) absorbent module that adsorbent and placement drawer are constituted is placed in absorbing unit, by absorbing unit to VOCs gas
It is adsorbed;
(2) after the adsorbent in unit to be adsorbed reaches saturation, the placement drawer with adsorbent is integrally taken out, the placement of taking-up
Drawer is placed in the desorption column of adsorbent regeneration unit;
(3) adsorbent regeneration unit regenerates the adsorbent for placing adsorption saturation in drawer, until adsorbent activity recovery;
(4) adsorbent after regeneration is integrally taken out with drawer is placed, it is spare;
In the step (1), absorbent module is at least one, and the absorbent module is successively set on the adsorption tower of absorbing unit
It is interior.
In the step (3), the absorbent module is successively set in the adsorption tower of absorbing unit.
After the completion of an absorption regeneration, step 2,3,4 are repeated, carry out the regeneration of adsorbent next time.
For foregoing problems, the application provides the collecting and distributing type processing method of a kind of VOCs processing unit and its use.This Shen
Please in, using on the spot absorbing unit handle VOCs, keep discharge gas up to standard, then reproducing adsorbent, make adsorbent be desorbed after
Again has absorption VOCs performance.It is exactly in some enterprise or region, each VOCs pollution-creating source establishes VOCs receipts on the spot
Collection, pretreatment, adsorption plant (corresponding absorbing unit is set), then unified foundation one or more VOCs regenerating unit is (i.e.
Adsorbent regeneration unit), it is regenerated by absorbent module of the adsorbent regeneration unit to some adsorption saturation.
Using the application, VOCs processing is carried out by absorbing unit, VOCs qualified discharge after processing meets environmental protection and wants
It asks, and multiple absorbing units can share a set of adsorbent regeneration unit.Compared with existing processing unit, the application small investment,
Land occupation saves, high treating effect;For single VOCs pollution sources, activated carbon adsorption system (absorbing unit) only on the spot,
Therefore, management is simple, so that operating cost is also low.Meanwhile the absorbent module of the application innovation constituted using placement drawer is set
Meter, both can guarantee that adsorbent was held, and had met the requirement of absorption, and facilitated the taking-up and installation of adsorbent.
In conclusion by adopting the above-described technical solution, the beneficial effects of the present invention are:
(1) in the application, absorbing unit can run the long period using designing on the spot, and usually handling only needs absorbing unit simple
It singly runs, day-to-day operation expense is low;
(2) in the application, adsorbent adsorbs the VOCs concentration height that VOCs amount is big, and regeneration is narrow-minded, is desorbed out, combustion heat value
Height needs auxiliary fuel only in booting and shutdown phase, and adsorbent regeneration unit operating cost is low;
(3) in the application, adsorbent regeneration unit and absorbing unit use one-to-many design, and device is once invested low;
(4) it in the application, is designed using the absorbent module that drawer is constituted is placed, interchangeability is good, and replacement is convenient, easy to operate;
(5) fixed or mobile design can be used in the adsorbent regeneration unit of the application, and burner is small in size, invests low, energy
Equipment cost is enough greatly reduced;
(6) in the application, in adsorbent regeneration unit, the VOCs for being desorbed out burns purification in burner, after purification
The discharge of gas a part, the gas and the gas mixing that blasts of fresh-air fan that a part returns, mixed hot wind enters de-
Attached tower, can satisfy the demand of continuous operation, and energy-saving effect is good.
Detailed description of the invention
Examples of the present invention will be described by way of reference to the accompanying drawings, in which:
Fig. 1 is the structural schematic diagram of absorbing unit in embodiment 1.
Fig. 2 is the structural schematic diagram of adsorbent regeneration unit in embodiment 1.
Marked in the figure: 1, gas gathering mask, 2, pre-processing assembly, 3, adsorption tower, 4, absorbing unit blower, 5, placement drawer, 6,
Desorption column, 7, desorption unit blower, 8, burner, 9, fresh-air fan.
Specific embodiment
All features disclosed in this specification or disclosed all methods or in the process the step of, in addition to mutually exclusive
Feature and/or step other than, can combine in any way.
Any feature disclosed in this specification unless specifically stated can be equivalent or with similar purpose by other
Alternative features are replaced.That is, unless specifically stated, each feature is an example in a series of equivalent or similar characteristics
?.
Embodiment 1
There are VOCs pollution sources at 11 in certain enterprise, apart there is certain distance.Wherein, exhausted air quantity 20000m3/ h's has at 3, and 15000
m3/ h's has at 6,10000m3/ h's has at 2, and pollution sources are to generate for 8 hours in working day, establishes 11 sets of active carbons on the spot and inhales
Coupon member, 1 set of adsorbent regeneration unit.
Wherein, absorbing unit includes the gas sampling component for VOCs gas collection, pre-processing assembly, adsorption tower, puts
Set drawer, adsorbent, exhaust emissions equipment.In the present embodiment, gas sampling component includes gas gathering mask, gas gathering mask by pipeline with
Pre-processing assembly is connected, and pre-processing assembly is connected by pipeline with adsorption tower, and adsorbent is arranged in placement drawer and adsorbent
Absorbent module is constituted with drawer is placed, absorbent module is arranged in adsorption tower and adsorbent can be used to inhale VOCs therein
Attached, adsorption tower is connected with blower, and blower is connected with exhaust emissions equipment.In the present embodiment, adsorbent is active carbon, and adsorption tower is adopted
With fixed-bed structure, pre-processing assembly is filter device, and exhaust emissions equipment is chimney.
Blower provides power for VOCs gas, so that VOCs gas is collected by gas gathering mask, and enters pretreated group
In part, then pass through the dust or droplet in VOCs gas collected by pre-processing assembly removal gas sampling component.Preprocessed group
Treated that gas enters in adsorption tower is adsorbed for part, and gas up to standard can be arranged through exhaust emissions equipment after adsorption tower is handled
Out.In the present embodiment, be based on VOCs pollution sources the characteristics of, 20000m3/ h and 15000 m3The absorbent module of/h adsorption tower is 4 groups,
10000 m3The absorbent module of/h adsorption tower is 2 groups, and absorbent module is arranged in adsorption tower.According to VOCs waste gas of pollutant amount
Difference can carry out appropriate adjustment to the absorbent module quantity in adsorption tower.Meanwhile adsorbent regeneration unit includes for absorption
Adsorbent carries out regenerated desorption column, desorption unit blower, burner, fresh-air fan, exhaust emissions equipment, desorption in tower
Tower, desorption unit blower, burner constitute hot air circulating system by pipeline.Fresh-air fan is connected with hot air circulating system,
Hot air circulating system is connected with exhaust emissions equipment.In the present embodiment, it is 20000m that adsorbent regeneration unit, which handles tolerance,3/ h,
Burner is catalytic combustion system, and 4 groups of placement drawers are arranged in desorption column, and placing drawer is in rectangle, places drawer and uses standard
Change, modularized design, places drawer and successively lie in a horizontal plane in adsorption tower or desorption column.
Adsorbent in component to be adsorbed after a period of work, takes out absorbent module out of adsorption tower, and is sent into de-
In attached tower.In desorption column, absorbent module is successively set in desorption column.Burner generates hot wind, and is sent by pipeline
In desorption column, and the absorbent module in desorption column is desorbed;After the VOCs of absorbent module absorption is desorbed by hot wind, it is being desorbed
Under the drive of unit blower, into burner in carry out burning purification;Purified gas a part is set by exhaust emissions
Standby discharge, the gas mixing that the gas and fresh-air fan that a part returns blast, mixed hot wind enter desorption column, Neng Gouman
The demand of sufficient continuous operation.
The course of work of the device is as follows.
Activated carbon adsorption unit operation, when the active carbon of certain device is close to be saturated or be saturated, by active carbon
And it places the absorbent module that drawer is constituted and takes out, and be placed in the desorption column of adsorbent regeneration unit;Then, adsorbent reactivation
Unit brings into operation, and burner work makes hot gas enter desorption column, Hot swapping goes out the VOCs of activated carbon adsorption, VOCs gas
Body generates CO in the reaction of the combustion chamber of burner2And water;After processing, gas is up to standard, and portion gas passes through adsorbent reactivation list
Enter active carbon after the cold air mixing that chimney (the i.e. exhaust emissions equipment) discharge of member, part hot gas and fresh-air fan are blown into
Desorption column.It is whole after VOCs concentration is lower than discharge standard in the gas that active carbon desorption column hot recycling comes out after several hours
A system regeneration is completed.After to be adsorbed dose is cooled to room temperature, adsorbent and placement drawer that regeneration is completed integrally are taken out, put back to
Absorbing unit.
To guarantee that the active carbon of each absorbing unit can regenerate in time, can the active carbon of monthly every absorbing unit regenerate in turn
Once.This adsorbent regeneration unit be it is fixed, since pollution sources VOCs property is similar, adsorbent and place drawer have it is standby
With, it is ensured that the operation of absorbing unit and adsorbent regeneration unit can be completely independent.
Through practical measurement, the concentration of VOCs is 50~80mg/m in exhaust gas before handling3, after activated carbon adsorption, exhaust gas is obtained
To purification, concentration≤10mg/m of VOCs in tail gas3, purified exhaust gas qualified discharge.After absorption 1 month, active carbon is taken out
It is regenerated, 90 DEG C of regeneration temperature, regenerates the VOCs concentration≤6000mg/m come3, VOCs is reacted in combustion chamber generates CO2With
Water, VOCs≤60mg/m in gas after burning3, treated gas qualified discharge.Device starts in system and stoppage in transit about half is small
When it is interior need to start combustor, burning petroleum gas to heat gas containing VOCs to catalyst light-off temperature, react by when normal operation
The heat of generation can maintain reaction to carry out, and not need oil gas, only blower power consumption.The VOCs processing unit of the application is stable
Reliably, it can satisfy the demand of VOCs processing.
Embodiment 2
, there are a VOCs pollution sources at 26 in certain industrial park, and waste gas of pollutant amount is from 5000~30000m3/ h establishes 26 sets just on the spot
The activated carbon adsorption unit on ground, 1 set of adsorbent regeneration unit.
Wherein, absorbing unit includes the gas sampling component for VOCs gas collection, pre-processing assembly, adsorption tower, puts
Set drawer, adsorbent, exhaust emissions equipment.In the present embodiment, adsorbent is active carbon, and adsorption tower uses fixed-bed structure, in advance
Processing component is one of filter device, oil mist removing device, smoke temperature reducer or a variety of.
Blower provides power for VOCs gas, so that VOCs gas is collected by gas gathering mask, and enters pretreated group
In part, then pass through the dust or droplet in VOCs gas collected by pre-processing assembly removal gas sampling component.Preprocessed group
Treated that gas enters in adsorption tower is adsorbed for part, and gas up to standard can be arranged through exhaust emissions equipment after adsorption tower is handled
Out.In the present embodiment, exhausted air quantity and concentration difference, the absorbent module of adsorption tower based on VOCs pollution sources are 1~6 group, absorption
Component is arranged in adsorption tower.
Meanwhile adsorbent regeneration unit includes for carrying out regenerated desorption column, desorption unit to adsorbent in adsorption tower
Blower, burner, fresh-air fan, exhaust emissions equipment, desorption column, desorption unit blower, burner are made up of pipeline
Hot air circulating system.Fresh-air fan is connected with hot air circulating system, and hot air circulating system is connected with exhaust emissions equipment.This implementation
In example, it is 30000m that adsorbent regeneration unit, which handles tolerance,3/ h, burner are catalytic combustion system, and desorption column is arranged 6 groups and puts
Drawer is set, placing drawer is in rectangle, places drawer using standardization, modularized design, places drawer and successively lie in a horizontal plane in suction
In attached tower or desorption column.
Adsorbent in component to be adsorbed after a period of work, takes out absorbent module out of adsorption tower, and is sent into de-
In attached tower.In desorption column, absorbent module is successively set in desorption column.Burner generates hot wind, and is sent by pipeline
In desorption column, and the absorbent module in desorption column is desorbed;After the VOCs of absorbent module absorption is desorbed by hot wind, it is being desorbed
Under the drive of unit blower, into burner in carry out burning purification;Purified gas a part is set by exhaust emissions
Standby discharge, the gas mixing that the gas and fresh-air fan that a part returns blast, mixed hot wind enter desorption column, Neng Gouman
The demand of sufficient continuous operation.
The course of work of the device is as follows.
Activated carbon adsorption unit operation, when the active carbon of certain device is close to be saturated or be saturated, by active carbon
And it places the absorbent module that drawer is constituted and takes out, and be placed in the desorption column of adsorbent regeneration unit;Then, adsorbent reactivation
Unit brings into operation, and burner work makes hot gas enter desorption column, Hot swapping goes out the VOCs of activated carbon adsorption, VOCs gas
Body generates CO in the reaction of the combustion chamber of burner2And water;After processing, gas is up to standard, and portion gas passes through adsorbent reactivation list
Enter active carbon after the cold air mixing that chimney (the i.e. exhaust emissions equipment) discharge of member, part hot gas and fresh-air fan are blown into
Desorption column.It is whole after VOCs concentration is lower than discharge standard in the gas that active carbon desorption column hot recycling comes out after several hours
A system regeneration is completed.After to be adsorbed dose is cooled to room temperature, adsorbent and placement drawer that regeneration is completed integrally are taken out, put back to
Absorbing unit.
The concentration of VOCs is 50~150mg/m in exhaust gas before handling in this example3, after activated carbon adsorption, exhaust gas is obtained only
Change, concentration≤60mg/m of VOCs in tail gas3, purified exhaust gas qualified discharge.When the adsorption saturation of activated carbon adsorption unit
Between be 1 month to half a year etc., to guarantee that the active carbon of each absorbing unit can regenerate in time, the active carbon of each absorbing unit
It should be according to pollution sources production regular regeneration.To improve reproducing adsorbent regeneration unit operational efficiency and further decreasing regeneration
Expense, the absorbent modules of different enterprises can simultaneously regenerative adsorption for a period of time after, take out active carbon and regenerated, regeneration temperature 80
DEG C~120 DEG C, regenerate the VOCs concentration≤6000mg/m come3, VOCs is reacted in combustion chamber generates CO2And water, gas after burning
Middle VOCs≤60mg/m3, treated gas qualified discharge.Device needs to start combustion in system starts and stop transport about half an hour
Burning machine, burns natural gas to heat gas containing VOCs to catalyst light-off temperature, and the heat that when normal operation reacts generation can be tieed up
It holds reaction to carry out, only blower power consumption.
The invention is not limited to specific embodiments above-mentioned.The present invention, which expands to, any in the present specification to be disclosed
New feature or any new combination, and disclose any new method or process the step of or any new combination.
Claims (10)
1. a kind of VOCs processing unit, which is characterized in that including for being adsorbed to VOCs absorbing unit, for regenerate inhale
Attached dose of adsorbent regeneration unit;
The absorbing unit includes the gas sampling component for VOCs gas collection, pre-processing assembly, adsorption tower, places and take out
Drawer, adsorbent, exhaust emissions equipment, the gas sampling component is connected with exhaust gas pre-processing assembly and pre-processing assembly can remove
Dust or droplet in VOCs gas collected by gas sampling component, the pre-processing assembly be connected with adsorption tower by pipeline and
Treated that gas can enter in adsorption tower is adsorbed for preprocessed component, and the adsorbent setting is being placed in drawer and inhaled
Attached dose constitutes absorbent module with drawer is placed, and the absorbent module is at least one, and the absorbent module is arranged in adsorption tower
And adsorbent can be used to adsorb VOCs therein, the adsorption tower is connected with exhaust emissions equipment and handles through adsorption tower
Gas up to standard can be discharged through exhaust emissions equipment afterwards;
The adsorbent regeneration unit include for adsorbent in adsorption tower carry out regenerated desorption column, desorption unit blower,
Burner, fresh-air fan, exhaust emissions equipment, the desorption column, desorption unit blower, burner constitute heat by pipeline
The adsorbed VOCs of absorbent module can enter in burner after being desorbed by hot wind and burn in air circulating system and desorption column
Purification, the fresh-air fan is connected with hot air circulating system and fresh-air fan can pump air into hot air circulating system to meet
The burning of burner needs, the hot air circulating system be connected with exhaust emissions equipment and the part in hot air circulating system into
Gas is discharged after capable of being handled by exhaust emissions equipment clean.
2. VOCs processing unit according to claim 1, which is characterized in that the adsorbent regeneration unit and absorbing unit
Number ratio is 1:1 ~ 50.
3. VOCs processing unit according to claim 1 or claim 2, which is characterized in that the placement drawer in rectangle or circle or
Polygon, the placement drawer are successively set in adsorption tower or desorption column.
4. any one VOCs processing unit according to claim 1 ~ 3, which is characterized in that the gas sampling component includes collection
Gas hood, blower, the gas gathering mask are connected by pipeline with pre-processing assembly, and the blower can provide power for VOCs gas.
5. any one VOCs processing unit according to claim 1 ~ 4, which is characterized in that the pre-processing assembly includes filtering
One of device, oil mist removing device, smoke temperature reducer are a variety of.
6. VOCs processing unit according to claim 1, which is characterized in that the adsorption tower is fixed-bed structure.
7. VOCs processing unit according to claim 1, which is characterized in that the adsorbent is active carbon, zeolite, molecular sieve
One of or it is a variety of.
8. VOCs processing unit according to claim 1, which is characterized in that the burner is catalytic combustion system, heat
One of power burner is a variety of.
9. any one VOCs processing unit according to claim 1 ~ 7, which is characterized in that the adsorbent regeneration unit uses
Fixed design or mobile design.
10. the collecting and distributing type processing method of VOCs processing unit according to claim 1, which comprises the steps of:
(1) absorbent module that adsorbent and placement drawer are constituted is placed in absorbing unit, by absorbing unit to VOCs gas
It is adsorbed;
(2) after the adsorbent in unit to be adsorbed reaches saturation, the placement drawer with adsorbent is integrally taken out, the placement of taking-up
Drawer is placed in the desorption column of adsorbent regeneration unit;
(3) adsorbent regeneration unit regenerates the adsorbent for placing adsorption saturation in drawer, until adsorbent activity recovery;
(4) adsorbent after regeneration is integrally taken out with drawer is placed, it is spare;
In the step (1), absorbent module is at least one, and the absorbent module is successively set on the adsorption tower of absorbing unit
It is interior.
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