CN116235860A - Chlorantraniliprole powder for preventing termites - Google Patents
Chlorantraniliprole powder for preventing termites Download PDFInfo
- Publication number
- CN116235860A CN116235860A CN202310274075.8A CN202310274075A CN116235860A CN 116235860 A CN116235860 A CN 116235860A CN 202310274075 A CN202310274075 A CN 202310274075A CN 116235860 A CN116235860 A CN 116235860A
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- China
- Prior art keywords
- powder
- chlorantraniliprole
- termites
- microcrystalline cellulose
- cellulose fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000843 powder Substances 0.000 title claims abstract description 81
- 241000256602 Isoptera Species 0.000 title claims abstract description 59
- 239000005886 Chlorantraniliprole Substances 0.000 title claims abstract description 50
- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 title claims abstract description 50
- 229920000168 Microcrystalline cellulose Polymers 0.000 claims abstract description 26
- 239000000835 fiber Substances 0.000 claims abstract description 26
- 239000008108 microcrystalline cellulose Substances 0.000 claims abstract description 26
- 235000019813 microcrystalline cellulose Nutrition 0.000 claims abstract description 26
- 229940016286 microcrystalline cellulose Drugs 0.000 claims abstract description 26
- 239000003814 drug Substances 0.000 claims abstract description 9
- 230000002147 killing effect Effects 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 239000002420 orchard Substances 0.000 claims description 2
- 238000003860 storage Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 21
- 230000005540 biological transmission Effects 0.000 abstract description 4
- 231100000419 toxicity Toxicity 0.000 abstract description 4
- 230000001988 toxicity Effects 0.000 abstract description 4
- 239000005871 repellent Substances 0.000 abstract description 3
- 230000002940 repellent Effects 0.000 abstract description 3
- 230000009471 action Effects 0.000 abstract description 2
- 239000011812 mixed powder Substances 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 12
- 238000000034 method Methods 0.000 description 4
- 238000012544 monitoring process Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 238000001926 trapping method Methods 0.000 description 3
- 241000488908 Torreya Species 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 244000144972 livestock Species 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 description 1
- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 description 1
- 239000005875 Acetamiprid Substances 0.000 description 1
- 239000005899 Fipronil Substances 0.000 description 1
- 239000005906 Imidacloprid Substances 0.000 description 1
- 244000061354 Manilkara achras Species 0.000 description 1
- 238000001550 Park test Methods 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000009412 basement excavation Methods 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229940013764 fipronil Drugs 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000012806 monitoring device Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M9/00—Special adaptations or arrangements of powder-spraying apparatus for purposes covered by this subclass
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P7/00—Arthropodicides
- A01P7/04—Insecticides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- General Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Toxicology (AREA)
- Insects & Arthropods (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Catching Or Destruction (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to termite control powder, and in particular relates to chlorantraniliprole powder for controlling termites, which consists of chlorantraniliprole raw medicine and microcrystalline cellulose fiber powder. The invention takes chlorantraniliprole as a raw material and microcrystalline cellulose fiber powder as a raw material, and the mixed powder has slow action on termites, has no repellent effect, is convenient for the transmission of toxicity of termites to the medicament, enhances the overall killing effect on termite colony, and has good contact killing and toxicity transmitting effects.
Description
Technical Field
The invention belongs to termite control powder, and in particular relates to chlorantraniliprole powder for controlling termites.
Background
Termites are one of five pests worldwide and have the characteristics of concealment, universality, significance and the like. Termites are killed by the termite monitoring trapping method, and the termite monitoring trapping method has a plurality of advantages: the killing effect is good, and the nest group can be killed as a whole; the building is not damaged, and excavation is not needed; labor is saved, the environment is not polluted, and the safety to people and livestock is realized; the formicary is not sought.
The prior art discloses termite powder comprising fipronil, imidacloprid and acetamiprid. However, the above powders have the following disadvantages: 1. the effective components of the powder are pesticides which are forbidden or limited to be used, and are unfavorable to the health of human bodies and the safety of the environment; 2. the termite-killing time of the powder is short, so that the medicine is not beneficial to spreading among nest groups, and the poison transmission effect is not feasible.
In view of this, the present invention has been proposed.
Disclosure of Invention
The invention provides termite control powder prepared from chlorantraniliprole raw powder which has slow action, no repellent effect and environmental safety.
In order to achieve the aim, the invention particularly provides chlorantraniliprole powder for preventing termites, which consists of chlorantraniliprole raw medicine and microcrystalline cellulose fiber powder.
The chlorantraniliprole is 0.05% -10% of the total mass of the powder.
The chlorantraniliprole is 0.5% -2.5% of the total mass of the powder, and is preferably 0.5%, 1.0%, 1.5% or 2.0%.
The particle size of the microcrystalline cellulose fiber powder is 100-300 meshes, and particularly preferably 200 meshes.
The chlorantraniliprole powder is prepared by uniformly mixing chlorantraniliprole raw medicine and microcrystalline cellulose fiber powder, and can be prepared by directly adsorbing and mixing the chlorantraniliprole raw medicine in the microcrystalline cellulose fiber powder or uniformly mixing the chlorantraniliprole raw medicine and the microcrystalline cellulose fiber powder by adopting a powder mixer.
The chlorantraniliprole powder is sprayed on the surface of termites to form a medicinal film for killing and transmitting other termites in the environment, habitat or storage area.
The chlorantraniliprole powder is applied to places such as orchards, buildings, gardens, ancient buildings and the like which are harmed by yellow chest termites or black chest termites.
The beneficial effects of the invention are as follows:
(1) The chlorantraniliprole is taken as a raw material, the microcrystalline cellulose fiber powder is taken as a raw material, the mixed powder has a slow effect on termites, has no repellent effect, is convenient for the transmission of toxicity of termites to the medicament, enhances the overall killing effect on termite colony, and has good contact killing and toxicity transmitting effects;
(2) The microcrystalline cellulose fiber powder adopted by the method has high porosity, large specific surface area, strong adsorption capacity and good dispersibility, so that the dosage of the microcrystalline cellulose fiber powder can be reduced, the drug effect is improved, and the production cost is reduced; meanwhile, the microcrystalline cellulose fiber powder is a food-grade additive, is more environment-friendly, does not pollute the environment, is safe to people and livestock, and has good environmental compatibility;
(3) The chlorantraniliprole powder for preventing and controlling termites disclosed by the application has a brand new insecticidal mechanism, can replace termite powder appearing in the existing market, has small influence on environment, and is safer to use.
Drawings
FIG. 1 is a graph showing the results of experiments on termite control effects of chlorantraniliprole powder according to examples 1 to 13 of the present invention.
Detailed Description
The invention will be described in further detail below with reference to the drawings by means of specific embodiments. In the following embodiments, numerous specific details are set forth in order to provide a better understanding of the present application. However, one skilled in the art will readily recognize that some of the features may be omitted in various situations, or replaced by other materials, methods. In some instances, some operations associated with the present application have not been shown or described in the specification to avoid obscuring the core portions of the present application, and may not be necessary for a person skilled in the art to describe in detail the relevant operations based on the description herein and the general knowledge of one skilled in the art.
Furthermore, the described features, operations, or characteristics of the description may be combined in any suitable manner in various embodiments. Also, various steps or acts in the method descriptions may be interchanged or modified in a manner apparent to those of ordinary skill in the art. Thus, the various orders in the description and drawings are for clarity of description of only certain embodiments, and are not meant to be required orders unless otherwise indicated.
Example 1: and (3) uniformly mixing 0.05% of chlorantraniliprole and 99.95% of microcrystalline cellulose fiber powder (the grain size of the microcrystalline cellulose fiber powder in all the embodiments is 200 meshes) by adopting a powder mixer, detecting and subpackaging.
Example 2: and uniformly mixing 0.1% chlorantraniliprole and 99.9% microcrystalline cellulose fiber powder by adopting a powder mixer, detecting and split charging.
Example 3: and uniformly mixing 0.25% of chlorantraniliprole and 99.75% of microcrystalline cellulose fiber powder by adopting a powder mixer, detecting and split charging.
Example 4: and uniformly mixing 0.5% chlorantraniliprole and 99.5% microcrystalline cellulose fiber powder by adopting a powder mixer, detecting and split charging.
Example 5: and uniformly mixing 1.0% chlorantraniliprole and 99.0% microcrystalline cellulose fiber powder by adopting a powder mixer, detecting and split charging.
Example 6: and uniformly mixing 2.5% chlorantraniliprole and 97.5% microcrystalline cellulose fiber powder by adopting a powder mixer, detecting and split charging.
Example 7: and uniformly mixing 5% chlorantraniliprole and 95% microcrystalline cellulose fiber powder by adopting a powder mixer, detecting and split charging.
Example 8: mixing 10% chlorantraniliprole and 90.0% microcrystalline cellulose fiber powder uniformly by adopting a powder mixer, detecting and split charging.
Example 9: and subpackaging is carried out by adopting microcrystalline cellulose fiber powder only.
Example 10: mixing 1.0% chlorantraniliprole and 99.0% water uniformly, detecting, and packaging.
Example 11: and uniformly mixing 0.02% of chlorantraniliprole and 99.98% of microcrystalline cellulose fiber powder by adopting a powder mixer, detecting and split charging.
Example 12: and uniformly mixing 12% chlorantraniliprole and 88.0% microcrystalline cellulose fiber powder by adopting a powder mixer, detecting and split charging.
Example 13: mixing 1.0% chlorantraniliprole and 99.0% flour uniformly by using a powder mixer, detecting and sub-packaging.
The applicant carried out trapping tests in 2022, 5-10 months on the chlorantraniliprole powder of examples 1-13 in forest parks, furun five-release gardens in Jiangxi cloud Bifeng countries and Zhao Guzhen Torreya Wang Cun in Zhujiu. The termite trapping method is to use the termite trapping device to trap termites, then the powder is sprayed onto the termites moving in the device by using a powder spraying tool (a powder spraying ball and a powder spraying machine), the powder is directly sprayed on the surface of the termites in the trapping and killing monitoring device, the termites can not be knocked down quickly, and the termites can be applied at the temperature of more than 20 ℃, so that the termite trapping device has a good poison transmission effect. Areas with more serious termite damage were selected as test points, and 40 test points were set for each test area. The activity of termites at each application point was observed and recorded after 15 days from the day of application. The termite activity changes before and after application are shown in tables 1-3.
TABLE 1 variation of termite activity before and after test in forest park test points in Jiangxi cloud Bifeng nations
TABLE 2 Change Table of termite Activity before and after Furun five-leakage Garden test points in Furun
TABLE 3 Change Table of termite Activity before and after test at test Point of Zhao Guzhen Torreya Wang Cun in Chiku
As can be seen from tables 1-3, a large number of termite monitoring trapping devices were experimentally pre-embedded in forest parks in Jiangxi cloud Bifeng countries, in Furun five-release gardens in the various and urban areas, and in Zhao Guzhen torrex Wang Cun in the various and urban areas, from which 120 termite damage devices were randomly selected. The treatment was performed with 13 different examples of powders, 15 test points for each example. After 15 days of application, all the devices were investigated, and the occurrence rate of termites in the devices at each test point was found to be generally reduced, even if termite damage was zero at the test points treated in examples 6 to 8, which indicated that the chlorantraniliprole powder had better controlled termite damage (wherein when the chlorantraniliprole active agent was more than 10% of the total mass of the powder, the concentration of 12% chlorantraniliprole as used in example 12 was too high, the contact killing effect was large, termites were immediately killed, no delivery effect was achieved, the effect of delivering the agent to other termite individuals up to the whole termite population was not achieved, termite nests were killed, and the toxic delivery effect was poor, so that use was not recommended).
As can be seen from fig. 1, the control effects of the chlorantraniliprole powder in the first 8 different embodiments are all remarkable after treatment, wherein the control effect of embodiment 4 (0.5%) reaches 86.7%; the control effect of the field test in the embodiment 5 (1%) reaches 93.33%, the trapping effect is very ideal, and the method is worthy of large-area popularization and application.
The foregoing is a further detailed description of the presently preferred embodiments of the present invention, and is not intended to limit the practice of the invention to the particular embodiments described, but rather to limit the scope of the invention.
Claims (7)
1. A chlorantraniliprole powder for controlling termites, which is characterized in that: the powder consists of chlorantraniliprole raw medicine and microcrystalline cellulose fiber powder.
2. A chlorantraniliprole powder for controlling termites as set forth in claim 1 wherein: the chlorantraniliprole is 0.05 percent ‒ percent of the total mass of the powder.
3. A chlorantraniliprole powder for controlling termites as set forth in claim 2 wherein: the chlorantraniliprole is 0.5% ‒ 2.5.5% of the total mass of the powder.
4. A chlorantraniliprole powder for controlling termites as set forth in claim 1 wherein: the grain size of the microcrystalline cellulose fiber powder is 100 ‒ meshes.
5. A chlorantraniliprole powder for controlling termites as set forth in claim 1 wherein: the chlorantraniliprole powder is prepared by uniformly mixing chlorantraniliprole raw material and microcrystalline cellulose fiber powder.
6. A chlorantraniliprole powder for controlling termites as set forth in claim 1 wherein: the chlorantraniliprole powder is sprayed on the surface of termites to form a medicinal film for killing and transmitting other termites in the environment, habitat or storage area.
7. The use of the chlorantraniliprole powder according to claim 1 in orchards, buildings, gardens and ancient buildings where termites are harmful to yellow chest and termites or black chest.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN202310274075.8A CN116235860A (en) | 2023-03-21 | 2023-03-21 | Chlorantraniliprole powder for preventing termites |
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CN202310274075.8A CN116235860A (en) | 2023-03-21 | 2023-03-21 | Chlorantraniliprole powder for preventing termites |
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Publication Number | Publication Date |
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CN116235860A true CN116235860A (en) | 2023-06-09 |
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CN202310274075.8A Pending CN116235860A (en) | 2023-03-21 | 2023-03-21 | Chlorantraniliprole powder for preventing termites |
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- 2023-03-21 CN CN202310274075.8A patent/CN116235860A/en active Pending
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