CN115747675B - Manufacturing method of low-friction-coefficient corrosion-resistant blade material of quick skates - Google Patents
Manufacturing method of low-friction-coefficient corrosion-resistant blade material of quick skates Download PDFInfo
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- CN115747675B CN115747675B CN202211423575.5A CN202211423575A CN115747675B CN 115747675 B CN115747675 B CN 115747675B CN 202211423575 A CN202211423575 A CN 202211423575A CN 115747675 B CN115747675 B CN 115747675B
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- 239000000463 material Substances 0.000 title claims abstract description 32
- 230000007797 corrosion Effects 0.000 title claims abstract description 17
- 238000005260 corrosion Methods 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 17
- 238000005245 sintering Methods 0.000 claims abstract description 14
- 238000010791 quenching Methods 0.000 claims abstract description 13
- 230000000171 quenching effect Effects 0.000 claims abstract description 13
- 238000001513 hot isostatic pressing Methods 0.000 claims abstract description 12
- 238000005242 forging Methods 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 7
- 238000005098 hot rolling Methods 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 4
- 238000011049 filling Methods 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 238000004321 preservation Methods 0.000 claims description 4
- 239000010935 stainless steel Substances 0.000 claims description 4
- 229910001220 stainless steel Inorganic materials 0.000 claims description 4
- 238000005096 rolling process Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 abstract description 5
- 239000000956 alloy Substances 0.000 abstract description 4
- 229910045601 alloy Inorganic materials 0.000 abstract description 4
- 239000007769 metal material Substances 0.000 abstract description 2
- 239000006104 solid solution Substances 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 description 5
- 238000005496 tempering Methods 0.000 description 3
- 238000000889 atomisation Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 230000000386 athletic effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
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Abstract
A manufacturing method of a low friction coefficient corrosion-resistant blade material of an ice skates belongs to the field of metal materials. The invention designs a blade material composed of single components, which comprises the following components: c:1.8 to 2.1 percent, cr:13.5 to 14.5 percent, V:12 to 12.5 percent, mo:1.5 to 1.8 percent and the balance of Fe, and obtaining the blade narrow-band material through the procedures of atomizing powder preparation, hot isostatic pressing sintering, forging cogging, roll forming and heat treatment. The alloy of the invention contains a large amount of C, cr, mo and V elements in solid solution, the weight percentage of VC phase is 13-15%, the blade is ensured to have good wear resistance, and the friction coefficient with ice surface is not influenced by the excessively high content. The heat treatment process adopted by the invention only carries out quenching treatment on the basis of component design, ensures that the blade has low friction coefficient, and simultaneously has high hardness, strength and corrosion resistance.
Description
Technical Field
The invention belongs to the field of metal materials, and relates to a manufacturing method of a low-friction-coefficient corrosion-resistant blade material of an ice skates.
Background
Speed skating is a racing sport performed on ice by taking a skates as tools, and the sport efficiency of athletes is related to the technical actions of the athletes, and the performance of the skates has an important influence on the performance of the athletes. The performance of the blade as the part of the blade contacting the ice surface directly determines the usability of the blade. The ideal blade material should have high wear resistance, low friction coefficient with ice surface and high toughness, and simultaneously have good corrosion resistance. The blade for athletic is made of bimetal material and consists of a back material and a blade, wherein the back material has high elasticity, and the blade has high wear resistance. In spite of excellent mechanical properties and wear resistance, the corrosion resistance of the existing blade is slightly insufficient, and the blade is easy to rust when not used for a long time. In addition, the existing blade is formed by welding two materials, the working procedure is complex, a single-material blade is developed, and meanwhile, good mechanical property, wear resistance and corrosion resistance are all trends of future development.
Disclosure of Invention
The invention designs a blade material composed of single components, which comprises the following components: c:1.8 to 2.1 percent, cr:13.5 to 14.5 percent, V:12 to 12.5 percent, mo:1.5 to 1.8 percent and the balance of Fe, and the material has low friction coefficient and excellent corrosion resistance after heat treatment and has excellent mechanical property.
A manufacturing method of a low friction coefficient corrosion-resistant blade material of an ice skates is characterized by comprising the following steps:
1) The preparation mass ratio is C:1.8 to 2.1 percent, cr:13.5 to 14.5 percent, V:12 to 12.5 percent, mo:1.5 to 1.8 percent of spherical metal powder of which the balance is Fe and the granularity is less than 200 mu m;
2) Filling the powder into a stainless steel sheath, vacuumizing, and performing hot isostatic pressing sintering;
3) Removing the sheath from the sintered hot isostatic pressing ingot, and forging and rolling the hot isostatic pressing ingot into a narrow band;
4) Quenching the narrow band to obtain the high-performance blade material of the skates.
Further, the sintering temperature in the step 2) is 1180-1200 ℃, the sintering pressure is 120-130 MPa, and the sintering time is 90-120 minutes.
Further, in the step 3), the starting temperature of forging and hot rolling is 1150+/-10 ℃, the ending temperature is 950+/-10 ℃, and the thickness of the plate blank after hot rolling is 1.20-1.21 mm.
Further, the quenching temperature in the step 4) is 1180-1200 ℃, and the air cooling is performed after heat preservation for 8-10 minutes.
The invention is characterized in that a single material is used as the blade material, and the defect that the prior blade is formed by welding two materials and has complex working procedures is overcome. The VC phase in the material accounts for 13-15% by mass, and meanwhile, the heat treatment process is only quenching treatment and tempering is not needed. The blade is guaranteed to have low friction coefficient, and meanwhile, the blade also has high mechanical property and corrosion resistance.
The main mechanism of the design alloy composition of the invention is that a proper amount of four alloy elements of C, cr, mo and V are added into Fe, and a high-hardness matrix and a VC combined structure are obtained through quenching treatment, and the matrix has high hardness, strength and corrosion resistance due to the fact that a large amount of C, cr, mo and V elements are dissolved in the matrix, meanwhile, the alloy composition has a low friction coefficient with ice surface, the mass percentage of VC phase is 13-15%, the blade is ensured to have good wear resistance, and meanwhile, the friction coefficient with ice surface is not influenced due to the excessively high content. It is to be noted that the heat treatment process adopted by the invention only has quenching and no tempering, because the tempering can cause a large amount of carbide to be separated out from the matrix to affect the hardness of the matrix, and meanwhile, the separated carbide is granular, the friction coefficient of the blade and the ice surface can be increased, so that the quenching treatment is only carried out on the basis of component design, the blade is ensured to have low friction coefficient, and meanwhile, the blade also has high mechanical property and corrosion resistance.
Detailed Description
Example 1
Preparation of 1.2mm thick blade Material for an skates
Firstly, adopting a vacuum atomization powder preparation technology to prepare the powder with the mass ratio of C:1.8%, mo:1.5%, V:12%, cr:13.5% of spherical metal powder of Fe and the balance. And secondly, screening powder with the powder granularity smaller than 200 mu m, filling the powder into a stainless steel sheath, vacuumizing, and placing the sheath into a hot isostatic pressing furnace for sintering at 1180 ℃ under the sintering pressure of 120MPa for 90min. And thirdly, removing the sheath material on the surface of the hot isostatic pressing ingot obtained in the second step, forging and cogging and hot-rolling the hot isostatic pressing ingot into a narrow band, wherein the starting temperature of forging and hot-rolling is 1150 ℃, the ending temperature of forging and hot-rolling is 950 ℃, and the narrow band with the thickness of 1.2mm is obtained through multi-pass hot-rolling. And fourthly, quenching the narrow band, wherein the quenching temperature is 1180 ℃, and air cooling is carried out after 8 minutes of heat preservation, so as to obtain the blade material of the quick skates with the thickness of 1.2 mm.
Example 2
Preparation of 1.21mm thick blade Material for an skates
Firstly, adopting a vacuum atomization powder preparation technology to prepare the powder with the mass ratio of C:2.1%, cr:14.5%, V:12.5%, mo:1.8% of spherical metal powder of Fe and the balance. And secondly, screening powder with the powder granularity smaller than 200 mu m, filling the powder into a stainless steel sheath, vacuumizing, and placing the sheath into a hot isostatic pressing furnace for sintering at the temperature of 1200 ℃, the sintering pressure of 130MPa and the sintering time of 120min. And thirdly, removing the sheath material on the surface of the hot isostatic pressing ingot obtained in the second step, forging and cogging and hot-rolling the hot isostatic pressing ingot into a narrow band, wherein the starting temperature of forging and hot-rolling is 1150 ℃, the ending temperature of forging and hot-rolling is 950 ℃, and the narrow band with the thickness of 1.21mm is obtained through multi-pass hot-rolling. And fourthly, quenching the narrow band, wherein the quenching temperature is 1200 ℃, and air cooling is carried out after heat preservation for 10 minutes to obtain the blade material of the quick skates with the thickness of 1.21mm.
Claims (4)
1. A manufacturing method of a low friction coefficient corrosion-resistant blade material of an ice skates is characterized by comprising the following steps:
1) The preparation mass ratio is C:1.8 to 2.1 percent, cr:13.5 to 14.5 percent, V:12 to 12.5 percent, mo:1.5 to 1.8 percent of spherical metal powder of which the balance is Fe and the granularity is less than 200 mu m;
2) Filling the powder into a stainless steel sheath, vacuumizing, and performing hot isostatic pressing sintering;
3) Removing the sheath from the sintered hot isostatic pressing ingot, forging and rolling the ingot into a narrow band, wherein the thickness of a plate blank after hot rolling is 1.20-1.21 mm;
4) Quenching the narrow band to obtain the high-performance blade material of the skates, wherein the VC phase content in the material is 13-15% by mass.
2. The method for manufacturing a low friction coefficient corrosion resistant skates blade material according to claim 1, wherein in the step 2), the sintering temperature is 1180-1200 ℃, the sintering pressure is 120-130 MPa, and the sintering time is 90-120 minutes.
3. A method of manufacturing a low coefficient of friction corrosion resistant speed skating blade material according to claim 1, wherein in step 3) the forging and hot rolling start temperature 1150 ℃ ± 10 ℃ and end temperature 950 ℃ ± 10 ℃.
4. The method for manufacturing the low-friction-coefficient corrosion-resistant quick-skating skates blade material as claimed in claim 1, wherein in the step 4), the quenching temperature is 1180-1200 ℃, and the air cooling is carried out after the heat preservation for 8-10 minutes.
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107138725A (en) * | 2017-06-23 | 2017-09-08 | 太仓优捷特机械有限公司 | The compressing material of high-performance for booster |
CN111283204A (en) * | 2020-02-18 | 2020-06-16 | 北京科技大学 | Preparation method of chromium-molybdenum-vanadium type quick-skating skates material |
CN111593264A (en) * | 2020-06-28 | 2020-08-28 | 武汉钢铁有限公司 | Tempering-free wear-resistant hot-rolled strip steel and production method thereof |
CN113770361A (en) * | 2021-08-18 | 2021-12-10 | 北京科技大学 | Preparation method of high-performance blade of speed skating blade |
CN115156538A (en) * | 2022-06-06 | 2022-10-11 | 河北五维航电科技股份有限公司 | Method for manufacturing short-track speed skating blade material |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2003072206A2 (en) * | 2002-02-21 | 2003-09-04 | Nitinol Technologies, Inc. | Nitinol ice blades |
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107138725A (en) * | 2017-06-23 | 2017-09-08 | 太仓优捷特机械有限公司 | The compressing material of high-performance for booster |
CN111283204A (en) * | 2020-02-18 | 2020-06-16 | 北京科技大学 | Preparation method of chromium-molybdenum-vanadium type quick-skating skates material |
CN111593264A (en) * | 2020-06-28 | 2020-08-28 | 武汉钢铁有限公司 | Tempering-free wear-resistant hot-rolled strip steel and production method thereof |
CN113770361A (en) * | 2021-08-18 | 2021-12-10 | 北京科技大学 | Preparation method of high-performance blade of speed skating blade |
CN115156538A (en) * | 2022-06-06 | 2022-10-11 | 河北五维航电科技股份有限公司 | Method for manufacturing short-track speed skating blade material |
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