CN114302916B - 滑动部件用聚酰胺树脂组合物及滑动部件 - Google Patents
滑动部件用聚酰胺树脂组合物及滑动部件 Download PDFInfo
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- CN114302916B CN114302916B CN202080059795.7A CN202080059795A CN114302916B CN 114302916 B CN114302916 B CN 114302916B CN 202080059795 A CN202080059795 A CN 202080059795A CN 114302916 B CN114302916 B CN 114302916B
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- polyamide resin
- thermoplastic elastomer
- resin composition
- reactive functional
- sliding
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- 229920006122 polyamide resin Polymers 0.000 title claims abstract description 69
- 239000011342 resin composition Substances 0.000 title claims abstract description 37
- 229920002725 thermoplastic elastomer Polymers 0.000 claims abstract description 51
- 125000000524 functional group Chemical group 0.000 claims abstract description 39
- 229920005672 polyolefin resin Polymers 0.000 claims abstract description 39
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 29
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 19
- 229920005989 resin Polymers 0.000 claims abstract description 19
- 239000011347 resin Substances 0.000 claims abstract description 19
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 18
- 239000002245 particle Substances 0.000 claims abstract description 15
- 239000011159 matrix material Substances 0.000 claims abstract description 12
- 229920006039 crystalline polyamide Polymers 0.000 claims abstract description 11
- 125000003368 amide group Chemical group 0.000 claims abstract description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 18
- -1 fatty acid ester compound Chemical class 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 10
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 7
- 230000009849 deactivation Effects 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
- 150000008065 acid anhydrides Chemical class 0.000 claims description 2
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- 238000002156 mixing Methods 0.000 description 13
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- 125000003504 2-oxazolinyl group Chemical group O1C(=NCC1)* 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
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- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 229920005549 butyl rubber Polymers 0.000 description 2
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- 229920001971 elastomer Polymers 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
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- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
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- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 2
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- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 1
- GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920003354 Modic® Polymers 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920003189 Nylon 4,6 Polymers 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- 229920000572 Nylon 6/12 Polymers 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920006121 Polyxylylene adipamide Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 description 1
- 229920006100 Vydyne® Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910001508 alkali metal halide Inorganic materials 0.000 description 1
- 150000008045 alkali metal halides Chemical class 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
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- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- FIASKJZPIYCESA-UHFFFAOYSA-L calcium;octacosanoate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O FIASKJZPIYCESA-UHFFFAOYSA-L 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
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- 239000004927 clay Substances 0.000 description 1
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- 239000007822 coupling agent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- KEIQPMUPONZJJH-UHFFFAOYSA-N dicyclohexylmethanediamine Chemical compound C1CCCCC1C(N)(N)C1CCCCC1 KEIQPMUPONZJJH-UHFFFAOYSA-N 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
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- 239000004519 grease Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
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- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
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- 239000012778 molding material Substances 0.000 description 1
- ZETYUTMSJWMKNQ-UHFFFAOYSA-N n,n',n'-trimethylhexane-1,6-diamine Chemical compound CNCCCCCCN(C)C ZETYUTMSJWMKNQ-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
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- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L13/00—Compositions of rubbers containing carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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JP2019-177690 | 2019-09-27 | ||
JP2019177690 | 2019-09-27 | ||
PCT/JP2020/034549 WO2021060030A1 (ja) | 2019-09-27 | 2020-09-11 | 摺動部品用ポリアミド樹脂組成物、及び摺動部品 |
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Publication Number | Publication Date |
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CN114302916A CN114302916A (zh) | 2022-04-08 |
CN114302916B true CN114302916B (zh) | 2023-07-14 |
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CN202080059795.7A Active CN114302916B (zh) | 2019-09-27 | 2020-09-11 | 滑动部件用聚酰胺树脂组合物及滑动部件 |
Country Status (4)
Country | Link |
---|---|
JP (1) | JP6872155B1 (ja) |
CN (1) | CN114302916B (ja) |
TW (1) | TWI845760B (ja) |
WO (1) | WO2021060030A1 (ja) |
Citations (18)
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JPH08157714A (ja) * | 1994-12-12 | 1996-06-18 | Toyobo Co Ltd | ポリアミド樹脂成形物 |
CN1364827A (zh) * | 2000-12-26 | 2002-08-21 | 旭化成株式会社 | 聚甲醛树脂组合物及其成型体 |
JP2002363403A (ja) * | 2001-06-12 | 2002-12-18 | Kuraray Co Ltd | 摺動部材用ポリアミド樹脂組成物およびそれからなる摺動部材 |
JP2004217929A (ja) * | 2002-12-27 | 2004-08-05 | Sanyo Chem Ind Ltd | 帯電防止性樹脂組成物及びその成形体 |
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JP2010070701A (ja) * | 2008-09-22 | 2010-04-02 | Toray Ind Inc | ポリアミド樹脂組成物およびそれからなる成形品 |
CN101977998A (zh) * | 2008-03-28 | 2011-02-16 | 宇部兴产株式会社 | 聚酰胺树脂组合物 |
JP2012184280A (ja) * | 2011-03-03 | 2012-09-27 | Toyobo Co Ltd | ポリアミド樹脂組成物 |
JP2013112727A (ja) * | 2011-11-28 | 2013-06-10 | Polyplastics Co | ポリアセタール樹脂組成物 |
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CN109983079A (zh) * | 2016-11-18 | 2019-07-05 | 三菱瓦斯化学株式会社 | 树脂组合物、成形品及成形品的制造方法 |
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EP2692801B1 (en) * | 2011-03-31 | 2016-08-24 | Nitta Corporation | Thermoplastic resin composition having high durability |
KR20150129776A (ko) * | 2013-03-11 | 2015-11-20 | 도요보 가부시키가이샤 | 2축 배향 폴리아미드계 수지 필름 |
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2020
- 2020-09-11 WO PCT/JP2020/034549 patent/WO2021060030A1/ja active Application Filing
- 2020-09-11 CN CN202080059795.7A patent/CN114302916B/zh active Active
- 2020-09-11 JP JP2020566855A patent/JP6872155B1/ja active Active
- 2020-09-15 TW TW109131597A patent/TWI845760B/zh active
Patent Citations (19)
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JPH08157714A (ja) * | 1994-12-12 | 1996-06-18 | Toyobo Co Ltd | ポリアミド樹脂成形物 |
CN1364827A (zh) * | 2000-12-26 | 2002-08-21 | 旭化成株式会社 | 聚甲醛树脂组合物及其成型体 |
JP2002363403A (ja) * | 2001-06-12 | 2002-12-18 | Kuraray Co Ltd | 摺動部材用ポリアミド樹脂組成物およびそれからなる摺動部材 |
JP2004217929A (ja) * | 2002-12-27 | 2004-08-05 | Sanyo Chem Ind Ltd | 帯電防止性樹脂組成物及びその成形体 |
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JP6872155B1 (ja) | 2021-05-19 |
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