CN103924456A - Production process of reactive printing paste - Google Patents
Production process of reactive printing paste Download PDFInfo
- Publication number
- CN103924456A CN103924456A CN201410154209.3A CN201410154209A CN103924456A CN 103924456 A CN103924456 A CN 103924456A CN 201410154209 A CN201410154209 A CN 201410154209A CN 103924456 A CN103924456 A CN 103924456A
- Authority
- CN
- China
- Prior art keywords
- parts
- carboxymethyl starch
- naoh
- agitator
- reactive printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000007639 printing Methods 0.000 title claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 229920002472 Starch Polymers 0.000 claims abstract description 20
- 235000019698 starch Nutrition 0.000 claims abstract description 20
- 239000008107 starch Substances 0.000 claims abstract description 20
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims abstract description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 9
- 239000002002 slurry Substances 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 6
- 229920013818 hydroxypropyl guar gum Polymers 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 45
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 18
- 239000002562 thickening agent Substances 0.000 claims description 15
- 238000005516 engineering process Methods 0.000 claims description 11
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 9
- 229920002261 Corn starch Polymers 0.000 claims description 6
- 239000008120 corn starch Substances 0.000 claims description 6
- 229940099112 cornstarch Drugs 0.000 claims description 6
- 235000013312 flour Nutrition 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 108010073771 Soybean Proteins Proteins 0.000 claims description 3
- 240000004584 Tamarindus indica Species 0.000 claims description 3
- 235000004298 Tamarindus indica Nutrition 0.000 claims description 3
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 230000008030 elimination Effects 0.000 claims description 3
- 238000003379 elimination reaction Methods 0.000 claims description 3
- -1 farina Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 238000000746 purification Methods 0.000 claims description 3
- 239000013049 sediment Substances 0.000 claims description 3
- FDRCDNZGSXJAFP-UHFFFAOYSA-M sodium chloroacetate Chemical compound [Na+].[O-]C(=O)CCl FDRCDNZGSXJAFP-UHFFFAOYSA-M 0.000 claims description 3
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims description 3
- 235000019345 sodium thiosulphate Nutrition 0.000 claims description 3
- 235000019710 soybean protein Nutrition 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000661 sodium alginate Substances 0.000 abstract description 3
- 229940005550 sodium alginate Drugs 0.000 abstract description 3
- 102000004169 proteins and genes Human genes 0.000 abstract 2
- 108090000623 proteins and genes Proteins 0.000 abstract 2
- 235000012239 silicon dioxide Nutrition 0.000 abstract 2
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 230000007547 defect Effects 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 239000000985 reactive dye Substances 0.000 description 2
- 244000303965 Cyamopsis psoralioides Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Coloring (AREA)
- Printing Methods (AREA)
Abstract
The invention relates to a production process of reactive printing paste. The production process comprises the steps of preparing carboxymethyl starch, preparing a mixture of carboxymethyl starch and nano silicon dioxide, preparing protein slurry, and mixing the ingredients. The paste mainly comprises carboxymethyl starch, sodium alginate, hydroxypropyl guar gum, nano silicon dioxide and protein slurry as assistants, and all performance of the paste can meet the active printing requirements.
Description
Technical field
The present invention relates to a kind of production technology of reactive printing thickener.
Background technology
In printing with reactive dye, thickener is generally used as the rheological property that thickener regulates mill base.Sodium alginate because it does not react with REACTIVE DYES, tinctorial yield is high, chromatogram is complete, easily from fabric wash away, the advantage such as fabrics feel soft, be the first-selection of printing paste with active dye always.Therefore but its price is more expensive, stamp cost is relatively high, and finding the thickener that a kind of # with low cost can print meticulous colored type has become the task of top priority.
Starch is a kind of renewable resource, and its deposit is abundant, easily obtains, but has active hydroxyl on its molecule, easily reacts with dyestuff, therefore in the application of printing paste with active dye, is restricted.
Summary of the invention
The object of the invention is to: overcome the defect of above-mentioned prior art, propose a kind of production technology of reactive printing thickener.
In order to achieve the above object, the production technology of the reactive printing thickener that the present invention proposes, comprises the steps:
The first step, cornstarch and farina are fully mixed with NaOH, monoxone after, the extruding of use screw extruder, the second half at extruder is sprayed formaldehyde to material, final drying makes carboxymethyl starch, and described cornstarch, farina, NaOH, chloroacetic mass ratio are 50:50:5:8;
Second step, carboxymethyl starch add in deionized water after mixing with silica flour, and add NaOH and methyl alcohol, after being hydrolyzed, dry purification obtains the mixture of carboxymethyl starch and nano silicon, wherein, batching is by quality proportioning, 50 parts of carboxymethyl starch, 2.6 parts of silica flours, 0.1 part, NaOH, 0.2 part of methyl alcohol;
The 3rd step, soybean protein is added to concentration is in 0.2% sodium hydroxide solution, at the uniform velocity stirs after 15 minutes at 45 ℃ and obtains albumen slurry after elimination sediment;
The 4th step, according to weight proportion, by 56 parts, the mixture of carboxymethyl starch and nano silicon, 30 parts of sodium alginates, 20 parts of hydroxypropyl guar gum, 5 parts, albumen slurry, pours in agitator and is uniformly mixed, and obtains.
The production technology of reactive printing thickener of the present invention also has following improvement:
1,, in the 4th step, to agitator, also pour the tamarind gum of 10 parts by mass into.
2,, in the 4th step, to agitator, also pour the sodium thiosulfate of 4 parts by mass into.
3,, in the 4th step, to agitator, also pour the polyvinyl alcohol of 2 parts by mass into.
Technique of the present invention is simple, and the reactive printing of preparation mainly comprises carboxymethyl starch, sodium alginate, hydroxypropyl guar gum, and nano silicon, albumen slurry are auxiliary agent, and thickener various aspects of performance can meet active printing and dyeing demand.In thickener of the present invention, added modified guar, more traditional printing gum has more excellent performance.As good rheological characteristic, be difficult for knot and scraping on the edge of a knife, stamp cutter defect is less; Good penetrability, printed surface good level-dyeing property; Paste making rate is high, and washing performance is good; Water retention property is good, can be used for the stamp acid and alkali-resistance of hydrophobic fibre fabric, and electrolyte-resistant is good with all kinds of fastness.
The specific embodiment
Below in conjunction with specific embodiment, the present invention will be further described.
The production technology of the present embodiment reactive printing thickener, comprises the steps:
The first step, cornstarch and farina are fully mixed with NaOH, monoxone after, the extruding of use screw extruder, the second half at extruder is sprayed formaldehyde to material, final drying makes carboxymethyl starch, and described cornstarch, farina, NaOH, chloroacetic mass ratio are 50:50:5:8;
Second step, carboxymethyl starch add in deionized water after mixing with silica flour, and add NaOH and methyl alcohol, after being hydrolyzed, dry purification obtains the mixture of carboxymethyl starch and nano silicon, wherein, batching is by quality proportioning, 50 parts of carboxymethyl starch, 2.6 parts of silica flours, 0.1 part, NaOH, 0.2 part of methyl alcohol;
The 3rd step, soybean protein is added to concentration is in 0.2% sodium hydroxide solution, at the uniform velocity stirs after 15 minutes at 45 ℃ and obtains albumen slurry after elimination sediment;
The 4th step, according to weight proportion, by 56 parts, the mixture of carboxymethyl starch and nano silicon, 30 parts of sodium alginates, 20 parts of hydroxypropyl guar gum, 5 parts, albumen slurry, 4 parts, 10 parts of sodium thiosulfate of tamarind gum, 2 parts of polyvinyl alcohol are poured in agitator and are uniformly mixed, and obtain.
In addition to the implementation, the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of requirement of the present invention.
Claims (4)
1. a production technology for reactive printing thickener, comprises the steps:
The first step, cornstarch and farina are fully mixed with NaOH, monoxone after, the extruding of use screw extruder, the second half at extruder is sprayed formaldehyde to material, final drying makes carboxymethyl starch, and described cornstarch, farina, NaOH, chloroacetic mass ratio are 50:50:5:8;
Second step, carboxymethyl starch add in deionized water after mixing with silica flour, and add NaOH and methyl alcohol, after being hydrolyzed, dry purification obtains the mixture of carboxymethyl starch and nano silicon, wherein, batching is by quality proportioning, 50 parts of carboxymethyl starch, 2.6 parts of silica flours, 0.1 part, NaOH, 0.2 part of methyl alcohol;
The 3rd step, soybean protein is added to concentration is in 0.2% sodium hydroxide solution, at the uniform velocity stirs after 15 minutes at 45 ℃ and obtains albumen slurry after elimination sediment;
The 4th step, according to weight proportion, by 56 parts, the mixture of carboxymethyl starch and nano silicon, 30 parts of sodium alginates, 20 parts of hydroxypropyl guar gum, 5 parts, albumen slurry, pours in agitator and is uniformly mixed, and obtains.
2. the production technology of reactive printing thickener according to claim 1, is characterized in that: in the 4th step, also pour the tamarind gum of 10 parts by mass to agitator into.
3. the production technology of reactive printing thickener according to claim 2, is characterized in that: in the 4th step, also pour the sodium thiosulfate of 4 parts by mass to agitator into.
4. the production technology of reactive printing thickener according to claim 3, is characterized in that: in the 4th step, also pour the polyvinyl alcohol of 2 parts by mass to agitator into.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410154209.3A CN103924456B (en) | 2014-04-17 | 2014-04-17 | A kind of production technology of reactive printing thickener |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410154209.3A CN103924456B (en) | 2014-04-17 | 2014-04-17 | A kind of production technology of reactive printing thickener |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103924456A true CN103924456A (en) | 2014-07-16 |
| CN103924456B CN103924456B (en) | 2016-04-06 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410154209.3A Expired - Fee Related CN103924456B (en) | 2014-04-17 | 2014-04-17 | A kind of production technology of reactive printing thickener |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103924456B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105386340A (en) * | 2015-12-18 | 2016-03-09 | 常熟市爱尚纺织科技有限公司 | Active printing and dyeing paste |
| CN108708192A (en) * | 2018-06-08 | 2018-10-26 | 山东港源海洋生物工程有限公司 | A kind of reactive printing gum and preparation method thereof |
| CN112680985A (en) * | 2020-12-28 | 2021-04-20 | 太仓宝霓实业有限公司 | Ultra-stable active printing liquid thickener, preparation method thereof and active printing paste |
| CN114075795A (en) * | 2020-08-17 | 2022-02-22 | 东莞市凯迪克高分子材料有限公司 | Compound water-based printing paste and preparation method thereof |
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| JPH06212574A (en) * | 1984-08-30 | 1994-08-02 | Kelco Ail Internatl Ltd | Calcium control system |
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| CN1436891A (en) * | 2002-02-05 | 2003-08-20 | 张晓东 | Printing paste with active dye and its prepn |
| CN101768877A (en) * | 2009-01-05 | 2010-07-07 | 金军 | Sodium alginate composite printing paste and application thereof |
| CN102965981A (en) * | 2012-11-23 | 2013-03-13 | 张家港顺昌化工有限公司 | Thickening agent for printing and preparation method thereof |
| CN103184694A (en) * | 2013-03-19 | 2013-07-03 | 无锡翔隆高分子面料有限公司 | Nano microcapsule type dry garment piece, and preparation method and application thereof |
-
2014
- 2014-04-17 CN CN201410154209.3A patent/CN103924456B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06212574A (en) * | 1984-08-30 | 1994-08-02 | Kelco Ail Internatl Ltd | Calcium control system |
| CN1436891A (en) * | 2002-02-05 | 2003-08-20 | 张晓东 | Printing paste with active dye and its prepn |
| CN1382864A (en) * | 2002-06-12 | 2002-12-04 | 弘生集团有限公司 | Size composition for textile |
| CN101768877A (en) * | 2009-01-05 | 2010-07-07 | 金军 | Sodium alginate composite printing paste and application thereof |
| CN102965981A (en) * | 2012-11-23 | 2013-03-13 | 张家港顺昌化工有限公司 | Thickening agent for printing and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105386340A (en) * | 2015-12-18 | 2016-03-09 | 常熟市爱尚纺织科技有限公司 | Active printing and dyeing paste |
| CN108708192A (en) * | 2018-06-08 | 2018-10-26 | 山东港源海洋生物工程有限公司 | A kind of reactive printing gum and preparation method thereof |
| CN114075795A (en) * | 2020-08-17 | 2022-02-22 | 东莞市凯迪克高分子材料有限公司 | Compound water-based printing paste and preparation method thereof |
| CN112680985A (en) * | 2020-12-28 | 2021-04-20 | 太仓宝霓实业有限公司 | Ultra-stable active printing liquid thickener, preparation method thereof and active printing paste |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103924456B (en) | 2016-04-06 |
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Granted publication date: 20160406 |
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